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Dissertations / Theses on the topic 'Chemistry|Organic chemistry|Nanotechnology'

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1

Border, Sarah Elaine Border. "Light Responsive Molecular Baskets." The Ohio State University, 2018. http://rave.ohiolink.edu/etdc/view?acc_num=osu1543329849092005.

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2

Cao, Pengfei Dr. "POLY(CAPROLACTONE) WITH UNCONVENTIONAL ARCHITECTURES: DESIGN, SYNTHESIS, CHARACTERIZATION AND POTENTIAL APPLICATIONS." Case Western Reserve University School of Graduate Studies / OhioLINK, 2016. http://rave.ohiolink.edu/etdc/view?acc_num=case1448548779.

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3

Jones, Derek R. "Design, Synthesis, and Photophysical Properties of Corannulene-based Organic Molecules." University of Cincinnati / OhioLINK, 2011. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1323350004.

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4

Chapman, James Vincent III. "Design and Synthesis of Organic Small Molecules for Industrial and Biomedical Technology Nanomaterial Augmentation." Thesis, University of Colorado at Denver, 2017. http://pqdtopen.proquest.com/#viewpdf?dispub=10272651.

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<p> Organic chemistry used to augment nanoparticles and nanotubes, as well as more traditional materials, is a subject of great interest across multiple fields of applied chemistry. Herein we present an example of both nanoparticle and nanotube augmentation with organic small molecules to achieve an enhanced or otherwise infeasible application. The first chapter discusses the modification of two different types of Microbial Fuel Cell (MFC) anode brush bristle fibers with positive surface charge increasing moieties to increase quantitative bacterial adhesion to these bristle fibers, and therefo
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5

Dahl, Jennifer Ann. "Synthesis of functional nanomaterials within a green chemistry context /." Connect to title online (Scholars' Bank) Connect to title online (ProQuest), 2007. http://hdl.handle.net/1794/6131.

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Thesis (Ph. D.)--University of Oregon, 2007.<br>Typescript. Includes vita and abstract. Includes bibliographical references (leaves 158-183). Also available online in Scholars' Bank; and in ProQuest, free to University of Oregon users.
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6

Kherde, Yogesh A. "Green Synthesis and Evaluation of Catalytic Activity of Sugar Capped Gold Nanoparticles." TopSCHOLAR®, 2014. http://digitalcommons.wku.edu/theses/1388.

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Owing to the importance of gold nanoparticles in catalysis, designing of them has become a major focus of the researchers. Most of the current methods available for the synthesis of gold nanoaprticles (GNPs) suffer from the challenges of polydispersity, stability and use of toxic and harmful chemicals. To overcome these limitations of conventional methods, in our present study, we made an attempt to design a method for the green synthesis of monodispersed and stable gold nanoparticles by sugars which act as reducing and stabilizing agent. Characterization of synthesized nanoparticles was done
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7

Abeywickrama, Thulitha Madawa. "Metal-Organic Hybrid Nanocomposites For Energy Harvesting Applications." TopSCHOLAR®, 2016. http://digitalcommons.wku.edu/theses/1748.

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Various synthetic methods have been developed to produce metal nanostructures including copper and iron nanostructures. Modification of nanoparticle surface to enhance their characteristic properties through surface functionalization with organic ligands ranging from small molecules to polymeric materials including organic semiconducting polymers is a key interest in nanoscience. However, most of the synthetic methods developed in the past depend widely on non-aqueous solvents, toxic reducing agents, and high temperature and high-pressure conditions. Therefore, to produce metal nanostructures
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8

Pfeiffer, Conrad T. "CONSTRUCTING NANOSTRUCTURES WITH ATOMIC PRECISION: THE SYNTHESIS OF SPIROLIGOMER-BASED MACROCYCLES." Diss., Temple University Libraries, 2016. http://cdm16002.contentdm.oclc.org/cdm/ref/collection/p245801coll10/id/417145.

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Chemistry<br>Ph.D.<br>This dissertation presents the development of a synthetic strategy to produce various spiroligomer-based macrocycles that bridge the gap between organic molecules and small proteins. “Spiroligomers” (formerly known as “bis-peptides”) are a class of molecules produced by the assembly of “bis-amino acids”, molecules containing two amino acid regions on a single cyclic core. Each bis-amino acid is connected through pairs of amide bonds to form a diketopiperazine consequently eliminating single bond rotation and, therefore, avoids the complicated folding process common to the
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9

Elbatal, Hany. "Terpyridine-Based Metallo-Supramolecular Architectures: From Structure to Function." University of Akron / OhioLINK, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=akron1384367887.

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10

Twomey, Megan. "Conjugated Polymer-Based Biomaterials Through Controlled Self-Assembly." FIU Digital Commons, 2016. http://digitalcommons.fiu.edu/etd/2452.

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Synthetic polymeric materials have gained significant use as biological materials (biomaterials) in biomedical and pharmaceutical applications. As a result, a demand for well-defined polymers with tunable properties has emerged. The synthetic versatility of polymeric biomaterials allows the opportunity to understand the structure-property relationship of materials and their cellular interactions. A novel class of polymeric biomaterials are conjugated polymers (CPs), which possess desirable physicochemical and excellent photophysical properties, including inherent fluorescence. The synthetic ve
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11

Mendez, Eladio A. "Conjugated Polymer Nanoparticles for Biological Labeling and Delivery." FIU Digital Commons, 2015. http://digitalcommons.fiu.edu/etd/1837.

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Cancer remains one of the world’s most devastating diseases, with more than 10 million new cases every year. However, traditional treatments have proven insufficient for successful medical management of cancer due to the chemotherapeutics’ difficulty in achieving therapeutic concentrations at the target site, non-specific cytotoxicity to normal tissues, and limited systemic circulation lifetime. Although, a concerted effort has been placed in developing and successfully employing nanoparticle(NP)-based drug delivery vehicles successfully mitigate the physiochemical and pharmacological limitati
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12

Weingart, Jacob J. "Synthesis and Interfacial Chemistry of Supramolecular Assemblies." University of Akron / OhioLINK, 2010. http://rave.ohiolink.edu/etdc/view?acc_num=akron1289842486.

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13

Knapp, Amanda R. "Antimicrobial and Antitumor Properties of Free and Poly(Ethylene Glycol)-Poly(Lactic Acid) Encapsulated Silver N-Heterocyclic Carbene Complexes." University of Akron / OhioLINK, 2011. http://rave.ohiolink.edu/etdc/view?acc_num=akron1309211795.

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14

Zhang, Jianxia. "Active Response of Polymer Materials from External Stimuli – Solvents and Light; Grafting Reactions on Perovskite Layers." ScholarWorks@UNO, 2012. http://scholarworks.uno.edu/td/1498.

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The active response of a series of polymeric materials was investigated. Both solvent activated and light activated thin films and wire systems show dynamic behaviors when exposed to different stimuli. Solvent mediated fluxional behavior of polymer thin films involved extensive, rapid curling both on infusion and evaporation of good solvents. These films can be either lab-fabricated ones or commercial ones, and the curling behavior can be as fast as seconds. Conditions including polymer materials, chosen solvents, and film geometry can affect the behavior. Methods that allowed for the creation
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15

Theibert, Dustin. "Organic Photovoltaic Optimization: A Functionalized Device Based Approach." Bowling Green State University / OhioLINK, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=bgsu1383508741.

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16

Lott, Joseph Robert. "Design, Synthesis and Incorporation of Functional Additives into Multilayered Polymer Films." Case Western Reserve University School of Graduate Studies / OhioLINK, 2011. http://rave.ohiolink.edu/etdc/view?acc_num=case1295673932.

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17

Elhaj, Baddar Zeinah. "ENGINEERING ZINC OXIDE NANOPARTICLES TO BE USED AS NANOFERTILIZERS." UKnowledge, 2018. https://uknowledge.uky.edu/pss_etds/109.

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Zinc deficient soils, or soils with low Zn bioavailability, are widespread, which exacerbates Zn deficiency in human as crops grown on these soils have low Zn content. Often crop yields are also compromised. Fertilizers based on soluble Zn salts often have limited efficacy in such soils. In this research, we evaluate the performance of polymer coated and bare ZnO nanoparticles (NPs) in an attempt to overcome limitations of soluble Zn salts in alkaline soils. We first synthesized 20-30 nm bare ZnO NPs with different surface chemistries to impart colloidal stability to the particles. Bare ZnO we
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18

Rathnayake, Sewwandi. "TRANSFORMATIONS, BIOAVAILABILITY AND TOXICITY OF MANUFACTURED ZnO NANOMATERIALS IN WASTEWTER." UKnowledge, 2013. http://uknowledge.uky.edu/pss_etds/25.

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In order to properly evaluate the ecological and human health risks of ZnO Manufactured nanomaterials (MNMs) released to the environment, it is critical to understand the likely transformation products in the wastewater treatment process and in soils receiving biosolids. To address this critical knowledge gap, we examined the transformation reactions of 30 nm ZnO MNMs in single component and multi-component systems, with phosphate and natural organic matter (NOM). We also assessed the influence of nano ZnO transformation on the bioavailability, and toxicity of ZnO transformation products to Tr
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19

Lally, Parminder. "Construction of a synthetic ribosome using DNA as the building material." Thesis, University of Oxford, 2010. http://ora.ox.ac.uk/objects/uuid:26573255-79bc-482d-9dd9-8c9f771ccbd8.

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This thesis forms part of an ongoing project in the DNA Group to build and operate a synthetic ribosome. We present two synthetic ribosome designs that can be combined with DNA-templated chemistry to generate libraries of functional synthetic small molecules. In Chapter 2 we use the DNA strand displacement technique to construct a mechanism that is capable of moving along a DNA track. We explore ways to control the speed and the driving force of the mechanism, and present a mathematical model of the system. We discuss the ability of the design to incorporate chemically-functionalised DNA stran
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20

Guttman, Jeremy. "Polymer-based Tunnel Diodes Fabricated using Ultra-thin, ALD Deposited, Interfacial Films." The Ohio State University, 2016. http://rave.ohiolink.edu/etdc/view?acc_num=osu1469125487.

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21

Bludin, Alexey O. "Peptide-Porphyrin Self-Assembled Materials." Bowling Green State University / OhioLINK, 2011. http://rave.ohiolink.edu/etdc/view?acc_num=bgsu1308097842.

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22

Newsome, Bradley J. "Addressing Public Health Risks of Persistent Pollutants Through Nutritional Modulation and Biomimetic Nanocomposite Remediation Platforms." UKnowledge, 2014. http://uknowledge.uky.edu/chemistry_etds/38.

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Due to their relative chemical stability and ubiquity in the environment, chlorinated organic contaminants such as polychlorinated biphenyls (PCBs) pose significant health risks and enduring remediation challenges. Engineered nanoparticles (NPs) provide a novel platform for sensing/remediation of these toxicants, in addition to the growing use of NPs in many industrial and biomedical applications, but there remains concern for their potential long-term health effects. Research highlighted herein also represents a transdisciplinary approach to address human health challenges associated with exp
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23

Narayanan, Amal. "Physicochemical Cues for the Design of Underwater Adhesives." University of Akron / OhioLINK, 2021. http://rave.ohiolink.edu/etdc/view?acc_num=akron1616164088200956.

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24

Silva, Mojica Ernesto. "Polymer-silica Hybrids for Separation of CO2 and Catalysis of Organic Reactions." University of Akron / OhioLINK, 2014. http://rave.ohiolink.edu/etdc/view?acc_num=akron1398439043.

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25

Halldin, Stenlid Joakim. "Computational Studies of Chemical Interactions: Molecules, Surfaces and Copper Corrosion." Doctoral thesis, KTH, Tillämpad fysikalisk kemi, 2017. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-213028.

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The chemical bond – a corner stone in science and a prerequisite for life – is the focus of this thesis. Fundamental and applied aspects of chemical bonding are covered including the development of new computational methods for the characterization and rationalization of chemical interactions. The thesis also covers the study of corrosion of copper-based materials. The latter is motivated by the proposed use of copper as encapsulating material for spent nuclear fuel in Sweden. In close collaboration with experimental groups, state-of-the-art computational methods were employed for the study of
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26

Ducay, Rey Nann Mark Abaque. "Direct Detection of Aggregates in Turbid Colloidal Suspensions." Miami University / OhioLINK, 2015. http://rave.ohiolink.edu/etdc/view?acc_num=miami1439434385.

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27

Watson, Venroy George. "Decoration of Graphene Oxide with Silver Nanoparticles and Controlling the Silver Nanoparticle Loading on Graphene Oxide." University of Dayton / OhioLINK, 2014. http://rave.ohiolink.edu/etdc/view?acc_num=dayton1396879714.

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28

Chaparro, Francisco Javier. "Biocompatible Electrospun Vehicles To Enhance the Effectiveness Of Anti-Fertility Strategies And Their Biomimetic Properties As Blood Vessel Scaffolds." The Ohio State University, 2018. http://rave.ohiolink.edu/etdc/view?acc_num=osu1514986344784852.

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29

Lee, Kwang Soo. "Stimuli Responsive Self-Assembly of Functional Organic Nanomaterials." The Ohio State University, 2016. http://rave.ohiolink.edu/etdc/view?acc_num=osu1452106891.

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30

Osama, Mohammad. "Function of Vascular Endothelial Cells in Aging and Hypothermia: Clinical Implications." Ohio University / OhioLINK, 2018. http://rave.ohiolink.edu/etdc/view?acc_num=ohiou1534939514503588.

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31

ALRASHED, MAHER M. "ORGANIC/INORGANIC HYBRID COATINGS FOR ANTICORROSION APPLICATIONS." University of Akron / OhioLINK, 2017. http://rave.ohiolink.edu/etdc/view?acc_num=akron1491226580793534.

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32

Jha, Kshitij Chandra. "Polarization and Self-Assembly at Metal-Organic Interfaces: Models and Molecular-Level Processes." University of Akron / OhioLINK, 2012. http://rave.ohiolink.edu/etdc/view?acc_num=akron1333644685.

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33

Subramani, Chandramouleeswaran. "Engineering functional nanostructures for materials and biological applications." 2013. https://scholarworks.umass.edu/dissertations/AAI3556292.

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Engineering nanostructures with complete control over the shape, composition, organization of the surface structures, and function remains a major challenge. In my work, I have fabricated nanostructures using functional polymer motifs and nanoparticles (NPs) via supramolecular and non-supramolecular interactions. In one of the approaches to generate nanostructures, I have integrated top-down approaches such as nanoimprint lithography, electron-beam lithography, and photolithography with the self-assembly (bottom-up) of NPs to provide nanostructures with tailored shape and function. In this str
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34

Miranda-Sanchez, Oscar Ramon. "Engineering nanoparticles surface for biosensing: “Chemical noses” to detect and identify proteins, bacteria and cancerous cells." 2011. https://scholarworks.umass.edu/dissertations/AAI3445171.

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Rapid and sensitive detection of biomolecules is an important issue in nanomedicine. Many disorders are manifested by changes in protein levels of serum and other biofluids. Rapid and effective differentiation between normal and cancerous cells is an important challenge for the diagnosis and treatment of tumor. Likewise, rapid and effective identification of pathogens is a key target in both biomedical and environmental monitoring. Most biological recognition processes occur via specific interactions. Gold nanoparticles (AuNP s) feature sizes commensurate with biomacromolecules, coupled with u
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35

Jiwpanich, Siriporn. "Design and synthesis of a new class of self-cross-linked polymer nanogels." 2011. https://scholarworks.umass.edu/dissertations/AAI3465020.

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The design and engineering of nanoscopic drug delivery vehicles that stably encapsulate lipophilic drug molecules, transport their loaded cargo to specific target sites, and release their payload in a controlled manner are of great interest in therapeutic applications, especially for cancer chemotherapy. This dissertation focuses on chemically cross-linked, water-soluble polymer nanoparticles, termed nanogels, which constitute a promising scaffold and offer the potential to circumvent encapsulation stability issues. A facile synthetic method for a new class of self-cross-linked polymer nanogel
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36

"Dimension Controlled Self-Assembly of Perylene Based Molecules." Thesis, 2011. http://hdl.handle.net/1911/70432.

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Recent advances in the self-assembly of highly organized structures of organic semiconducting molecules by controlled non-covalent interactions has opened avenues for creating materials with unique optical and electrical properties. The main focus of this thesis lies in the synthesis and self-assembly of n-type perylene based organic semiconducting molecules into highly organized materials. Perylene based molecules used in this study are perylene diimide (PTCDI, two side-chains), perylene mono imide (m-PTCI, one side-chain), perylene tetracarboxylic acid (PTCA, no side-chain) and tetra-alkali
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37

(9605984), Teng Chi. "THIOXANTHONE BASED PHOTOINITIATORS FOR TWO-PHOTON NANOLITHOGRAPHIC PRINTING." Thesis, 2020.

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Printing of 3-dimensional nanostructures with high-resolution by two-photon polymerization has gained significant attention recently. Isopropyl thioxanthone (ITX) has been studied and used as a photoinitiator because of its unique property in initiating and depleting polymerization, but to further improve the resolution of 3D structures, new photoinitiating materials are necessary to decrease the power requirements especially in industrial world. In this dissertation, different new types of thioxanthone-based photoinitiators were synthesized and our new initiators possessed a clear enhancement
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38

Duong, Adam. "Contrôle de l'organisation moléculaire en 2D et 3D par l’utilisation de liaisons hydrogène, de coordination métallique et d'autres interactions." Thèse, 2011. http://hdl.handle.net/1866/5324.

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La stratégie de la tectonique moléculaire a montré durant ces dernières années son utilité dans la construction de nouveaux matériaux. Elle repose sur l’auto-assemblage spontané de molécule dite intelligente appelée tecton. Ces molécules possèdent l’habilité de se reconnaitre entre elles en utilisant diverses interactions intermoléculaires. L'assemblage résultant peut donner lieu à des matériaux moléculaires avec une organisation prévisible. Cette stratégie exige la création de nouveaux tectons, qui sont parfois difficiles à synthétiser et nécessitent dans la plupart des cas de nombreuses étap
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