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Journal articles on the topic '3-Chloronitrobenzene'

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1

Zhu, Donghong, Xin Weng, Yuqiong Tang, Jingya Sun, Shourong Zheng, and Zhaoyi Xu. "Pt/Al2O3 coated with N-doped carbon as a highly selective and stable catalyst for catalytic hydrogenation of p-chloronitrobenzene to p-chloroaniline." RSC Advances 10, no. 24 (2020): 14208–16. http://dx.doi.org/10.1039/d0ra01578d.

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2

Kosandal, Kantilal, A. K. S. Bhujanga Rao, C. Gundu Rao, and B. B. Singh. "A NEW AND CONVENIENT PREPARATION OF 3-BROMO-4-CHLORONITROBENZENE." Organic Preparations and Procedures International 23, no. 3 (1991): 395–96. http://dx.doi.org/10.1080/00304949109458221.

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3

Angeloff, Ariane, Jean-Jacques Brunet, Pierre Legars, Denis Neibecker, and Denis Souyri. "Regioselective dechlorination of 2,3-dichloronitrobenzene into 3-chloronitrobenzene and regioselective dechlorination–hydrogenation into 3-chloroaniline." Tetrahedron Letters 42, no. 12 (2001): 2301–3. http://dx.doi.org/10.1016/s0040-4039(01)00103-4.

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4

KOSANDAL, K., A. K. S. B. RAO, C. G. RAO, and B. B. SINGH. "ChemInform Abstract: A New and Convenient Preparation of 3-Bromo-4-chloronitrobenzene." ChemInform 23, no. 1 (2010): no. http://dx.doi.org/10.1002/chin.199201111.

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5

Brookes, P. R., and A. G. Livingston. "Biological detoxification of a 3-chloronitrobenzene manufacture wastewater in an extractive membrane bioreactor." Water Research 28, no. 6 (1994): 1347–54. http://dx.doi.org/10.1016/0043-1354(94)90301-8.

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6

Angeloff, Ariane, Jean-Jacques Brunet, Pierre Legars, Denis Neibecker, and Denis Souyri. "ChemInform Abstract: Regioselective Dechlorination of 2,3-Dichloronitrobenzene into 3-Chloronitrobenzene and Regioselective Dechlorination-Hydrogenation into 3-Chloroaniline." ChemInform 32, no. 27 (2010): no. http://dx.doi.org/10.1002/chin.200127082.

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7

Mir, Abid Ali, and Vinata V. Mulwad. "Synthesis and anti-bacterial screening of ethyl 6-oxo-3-phenyl-1,6-dihydropyrano[3,2-e]indole-2-carboxylate and 7-phenyl-5H-pyrano [3′,2′:4,5]indolo[1,2-a]quinoxaline-6,10-dione." Journal of Chemical Research 2009, no. 5 (2009): 290–92. http://dx.doi.org/10.3184/030823409x447691.

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Ethyl 6-oxo-3-phenyl-1,6-dihydropyrano[3,2- e]indole-2-carboxylate 3a-c were synthesised from ethyl 2-[(2-oxo-2 H-1-benzopyran-6-yl)-hydrazono]-3-phenylpropanoate 2a-c. Compounds 2a-c was in turn prepared by reacting diasotised solution of 6-aminocoumarin and ethyl-2-benzylacetoacetate. N-nitroarylation of ethyl 6-oxo-3-phenyl-1,6-dihydropyrano[3,2- e]indole-2-carboxylate 3a-c was carried out with 2-chloronitrobenzene to give ethyl 1-(2-nitrophenyl)-6-oxo-3-phenyl-1,6-dihydropyrano[3,2- e]indole-2-carboxylate 4a-c, which on catalytic reductive cyclisation with H2/Ni affords 7-phenyl-5 H-pyrano
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8

Ge, Xianghong, Hui Liu, Xingxing Ding, et al. "Ru@Carbon Nanotube Composite Microsponge: Fabrication in Supercritical CO2 for Hydrogenation of p-Chloronitrobenzene." Nanomaterials 12, no. 3 (2022): 539. http://dx.doi.org/10.3390/nano12030539.

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Novel heterogeneous catalysts are needed to selectively anchor metal nanoparticles (NPs) into the internal space of carbon nanotubes (CNTs). Here, supercritical CO2 (SC-CO2) was used to fabricate the Ru@CNT composite microsponge via impregnation. Under SC-CO2 conditions, the highly dispersive Ru NPs, with a uniform diameter of 3 nm, were anchored exclusively into the internal space of CNTs. The CNTs are assembled into a microsponge composite. The supercritical temperature for catalyst preparation, catalytic hydrogenation temperature, and time all have a significant impact on the catalytic acti
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9

Zhao, Jing, Qing-Song Hu, Yan-Xu Zhou, Ling Peng, and Ying-Zhong Shen. "Preparation and properties of highly organosoluble polyimides derived from 2,2′-disubstituted-4,4′-oxydianilines." High Performance Polymers 30, no. 4 (2017): 456–64. http://dx.doi.org/10.1177/0954008317701550.

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Four novel aromatic, symmetrical ether diamines (2,2′-bis(biphenyl)-4,4′-oxydianiline, 2,2′-bis[4′-(3″,4″,5″-trifluorophenyl)phenyl]-4,4′-oxydianiline, 2,2′-bis[4-(naphthalene-1-yl)phenyl]-4,4′-oxydianiline, and 2,2′-bis[4″-(diphenylamino)phenyl]-4,4′-oxydianiline), were successfully synthesized through four steps using p-chloronitrobenzene as a starting material. Highly organosoluble polyimides were obtained by the reaction of these diamines with 2′2 ′-bis[4′-(3″,4″,5″-trifluorophenyl)phenyl]-4,4′,5,5′-biphenyltetracarboxylic dianhydride via a conventional two-step chemical imidization method
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10

Livingston, Andrew Guy. "A novel membrane bioreactor for detoxifying industrial wastewater: II. Biodegradation of 3-chloronitrobenzene in an industrially produced wastewater." Biotechnology and Bioengineering 41, no. 10 (1993): 927–36. http://dx.doi.org/10.1002/bit.260411003.

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11

Liu, Hong, Shu-Jun Wang, Jun-Jie Zhang, Hui Dai, Huiru Tang, and Ning-Yi Zhou. "Patchwork Assembly ofnag-Like Nitroarene Dioxygenase Genes and the 3-Chlorocatechol Degradation Cluster for Evolution of the 2-Chloronitrobenzene Catabolism Pathway in Pseudomonas stutzeri ZWLR2-1." Applied and Environmental Microbiology 77, no. 13 (2011): 4547–52. http://dx.doi.org/10.1128/aem.02543-10.

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ABSTRACTPseudomonas stutzeriZWLR2-1 utilizes 2-chloronitrobenzene (2CNB) as a sole source of carbon, nitrogen, and energy. To identify genes involved in this pathway, a 16.2-kb DNA fragment containing putative 2CNB dioxygenase genes was cloned and sequenced. Of the products from the 19 open reading frames that resulted from this fragment, CnbAc and CnbAd exhibited striking identities to the respective α and β subunits of the Nag-like ring-hydroxylating dioxygenases involved in the metabolism of nitrotoluene, nitrobenzene, and naphthalene. The encoding genes were also flanked by two copies of i
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12

Qu, Ruiyang, Margherita Macino, Sarwat Iqbal, et al. "Supported Bimetallic AuPd Nanoparticles as a Catalyst for the Selective Hydrogenation of Nitroarenes." Nanomaterials 8, no. 9 (2018): 690. http://dx.doi.org/10.3390/nano8090690.

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The solvent-free selective hydrogenation of nitrobenzene was carried out using a supported AuPd nanoparticles catalyst, prepared by the modified impregnation method (MIm), as efficient catalyst >99% yield of aniline (AN) was obtained after 15 h at 90 °C, 3 bar H2 that can be used without any further purification or separation, therefore reducing cost and energy input. Supported AuPd nanoparticles catalyst, prepared by MIm, was found to be active and stable even after four recycle experiments, whereas the same catalyst prepared by SIm was deactivated during the recycle experiments. The most
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13

Huang, Xing, Mang Zheng, Yu Xiang Wang, Dan Dan Li, and Ya Juan Zhao. "Selective Reduction of Chloronitrobenzene to Chloroaniline on Ni/Al2O3 Catalysts Got-up Ionic Liquids." Advanced Materials Research 233-235 (May 2011): 2904–8. http://dx.doi.org/10.4028/www.scientific.net/amr.233-235.2904.

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Ionic liquids-modified Ni/Al2O3 catalysts are found to be alternatively excellent media for the heterogeneously catalyzed hydrogenation of halonitrobenzenes to corresponding haloanilines.It gives rise to higher selectivity and lower dehalogenation in the hydrogenating process compared with that observed in conventional nickel catalyst.
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14

Fan, Guang Yin. "Poly(Vinylpyrrolidone)-Anchored Iridium Nanoparticles Supported on Al2O3 as Ultra-Selective Catalyst for the Hydrogenation of p-Chloronitrobenzene." Advanced Materials Research 726-731 (August 2013): 683–86. http://dx.doi.org/10.4028/www.scientific.net/amr.726-731.683.

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Poly (vinylpyrrolidone)-anchored iridium nanoparticles (PVP-Ir) were prepared via the reduction of H2IrCl6·nH2O in ethanol/water mixtures. The catalytic properties of the colloidal nanoparticles that dispersed on Al2O3(PVP-Ir/Al2O3) were investigated in the selective hydrogenation ofp-chloronitrobenzene (p-CNB) top-chloroaniline (p-CAN). The results indicated that the selectivity top-CAN remained on the level of 100 % at complete conversion ofp-CNB at lower temperature of 288 K. Moreover, the side reaction of hydrogenolysis of the carbon-halogen bond was completely inhibited in the absence of
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15

Le, Chen, Junqian Liang, Jinhua Wu, et al. "Effective degradation of para-chloronitrobenzene through a sequential treatment using zero-valent iron reduction and Fenton oxidation." Water Science and Technology 64, no. 10 (2011): 2126–31. http://dx.doi.org/10.2166/wst.2011.803.

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In this study, zero-valent iron (ZVI) was used to pretreat para-chloronitrobenzene (p-CNB), and the major product was para-chloroaniline (p-CAN). By adding H2O2 directly, further p-CAN degradation can be attributed to Fenton oxidation because ferrous ions (Fe2+) released during the ZVI corrosion could be used as an activator for H2O2 decomposition. In the reduction process, the reduction efficiency of p-CNB as well as Fe2+ concentration increased with increasing iron dosage and decreasing solution pH. Under the optimal conditions, 25 mg L−1 of p-CNB could be transformed in 3 h when initial sol
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16

Campos, Cristian H., Bruno F. Urbano, Cecilia C. Torres, and Joel A. Alderete. "A Novel Synthesis of Gold Nanoparticles Supported on Hybrid Polymer/Metal Oxide as Catalysts for p-Chloronitrobenzene Hydrogenation." Journal of Chemistry 2017 (2017): 1–9. http://dx.doi.org/10.1155/2017/7941853.

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This contribution reports a novel preparation of gold nanoparticles on polymer/metal oxide hybrid materials (Au/P[VBTACl]-M metal: Al, Ti or Zr) and their use as heterogeneous catalysts in liquid phase hydrogenation of p-chloronitrobenzene. The support was prepared by in situ radical polymerization/sol gel process of (4-vinyl-benzyl)trimethylammonium chloride and 3-(trimethoxysilyl)propyl methacrylate in conjunction with metal-alkoxides as metal oxide precursors. The supported catalyst was prepared by an ion exchange process using chloroauric acid (HAuCl4) as gold precursor. The support provid
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17

Liang, Jing, Zhixue Li, Emmanuella Anang, Hong Liu, and Xianyuan Fan. "Coupling Removal of P-Chloronitrobenzene and Its Reduction Products by Nano Iron Doped with Ni and FeOOH (nFe/Ni-FeOOH)." Materials 15, no. 5 (2022): 1928. http://dx.doi.org/10.3390/ma15051928.

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The removal of chlorinated pollutants from water by nanoparticles is a hot topic in the field of environmental engineering. In this work, a novel technique that includes the coupling effect of n-Fe/Ni and its transformation products (FeOOH) on the removal of p-chloronitrobenzene (p-CNB) and its reduction products, p-chloroaniline (p-CAN) and aniline (AN), were investigated. X-ray diffraction (XRD) and transmission electron microscopy (TEM) were employed to characterize the nano-iron before and after the reaction. The results show that Fe0 is mainly oxidized into lath-like lepidocrocite (γ-FeOO
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18

McManus, Iain J., Helen Daly, Haresh G. Manyar, S. F. Rebecca Taylor, Jillian M. Thompson, and Christopher Hardacre. "Selective hydrogenation of halogenated arenes using porous manganese oxide (OMS-2) and platinum supported OMS-2 catalysts." Faraday Discussions 188 (2016): 451–66. http://dx.doi.org/10.1039/c5fd00227c.

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Porous manganese oxide (OMS-2) and platinum supported on OMS-2 catalysts have been shown to facilitate the hydrogenation of the nitro group in chloronitrobenzene to give chloroaniline with no dehalogenation. Complete conversion was obtained within 2 h at 25 °C and, although the rate of reaction increased with increasing temperature up to 100 °C, the selectivity to chloroaniline remained at 99.0%. Use of Pd/OMS-2 or Pt/Al<sub>2</sub>O<sub>3</sub> resulted in significant dechlorination even at 25 °C and 2 bar hydrogen pressure giving a selectivity to chloroaniline of 34.5% and 77.8%, respectivel
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19

Ya-Nan, WANG, YANG Yu-Xia, LI Yong-Wen, LAI Jun-Hua, and SUN Kun-Peng. "Preparation of Fe3O4 Modified Pt-Ru/C Nanocatalysts and Their Catalytic Properties for the Selective Hydrogenation of ortho-Chloronitrobenzene under Solvent-Free Conditions." Acta Physico-Chimica Sinica 29, no. 10 (2013): 2239–44. http://dx.doi.org/10.3866/pku.whxb201308151.

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20

Chen, Yin-Zu, and Yih-Chung Chen. "Hydrogenation of para-chloronitrobenzene over nickel borides." Applied Catalysis A: General 115, no. 1 (1994): 45–57. http://dx.doi.org/10.1016/0926-860x(94)80377-3.

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21

Liu, Hong, Shu-Jun Wang, and Ning-Yi Zhou. "A new isolate of Pseudomonas stutzerithat degrades 2-chloronitrobenzene." Biotechnology Letters 27, no. 4 (2005): 275–78. http://dx.doi.org/10.1007/s10529-004-8293-3.

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22

Meriles, C. A., J. F. Schneider, Y. P. Mascarenhas, and A. H. Brunetti. "X-ray diffraction study of polycrystallinep-chloronitrobenzene." Journal of Applied Crystallography 33, no. 1 (2000): 71–81. http://dx.doi.org/10.1107/s0021889899012571.

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The X-ray diffraction pattern of powdered 1-Cl-4-NO2-benzene was measured at several temperatures in order to characterize the structure of two different phases. ForT&lt; 282 K, the crystal array is ordered and exhibitsP21symmetry with two molecules in the unit cell; the observed lattice parameters atT= 190 K area= 5.838 (4),b= 5.218 (3),c= 10.716 (5) Å and β = 96.43 (5)°. A molecular arrangement inside the unit cell which minimizes the crystalline packing energy was calculated and, in combination with the Rietveld method, was used to reproduce the observed diffraction pattern. The refined str
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23

Pietrowski, Mariusz, Michał Zieliński, and Maria Wojciechowska. "Selective Reduction of Chloronitrobenzene to Chloroaniline on Ru/MgF2 Catalysts." Catalysis Letters 128, no. 1-2 (2008): 31–35. http://dx.doi.org/10.1007/s10562-008-9702-3.

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24

Chen, Zhijun, Yanhua Wang, Wenjiang Li, Jingyang Jiang, and Zilin Jin. "Thermoregulated phase-transfer Rh nanoparticle catalyst for selective hydrogenation of ortho-chloronitrobenzene." Chinese Journal of Catalysis 35, no. 12 (2014): 1917–20. http://dx.doi.org/10.1016/s1872-2067(14)60216-3.

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25

Krátky, Vieroslav, Milan Králik, Alexander Kaszonyi, et al. "Reaction Pathways and the Role of Solvent in the Hydrogenation of Chloronitrobenzenes." Collection of Czechoslovak Chemical Communications 68, no. 10 (2003): 1819–32. http://dx.doi.org/10.1135/cccc20031819.

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Liquid phase hydrogenation of chloronitrobenzenes to corresponding chloroanilines over Pd on carbon (Pd/C) under mild reaction conditions was studied. On the basis of 1H, 13C NMR, GC-MS and HPLC analyses of reaction mixtures, the reaction pathways were evaluated. The reduction of substrates proceeds via the formation of chloronitrosobenzenes and N-(chlorophenyl)hydroxylamines and mainly results in the formation of the chloroanilines and aniline. Aniline is formed by hydrogenolysis of chlorine (dechlorination) in benzene ring. Other compounds (mono- and disubstituted azobenzenes and azoxybenzen
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26

Li, Feng, Bo Cao, Rui Ma, Hualin Song, and Hua Song. "Polyvinylpyrrolidone-stabilized Pt colloidal catalysts in chloronitrobenzene hydrogenation and modification with rare earth ions." Reaction Kinetics, Mechanisms and Catalysis 116, no. 2 (2015): 479–89. http://dx.doi.org/10.1007/s11144-015-0907-3.

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27

Park, Hee-Sung, Sung-Jin Lim, Young Keun Chang, Andrew G. Livingston, and Hak-Sung Kim. "Degradation of Chloronitrobenzenes by a Coculture of Pseudomonas putida and a Rhodococcussp." Applied and Environmental Microbiology 65, no. 3 (1999): 1083–91. http://dx.doi.org/10.1128/aem.65.3.1083-1091.1999.

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ABSTRACT A single microorganism able to mineralize chloronitrobenzenes (CNBs) has not been reported, and degradation of CNBs by coculture of two microbial strains was attempted. Pseudomonas putidaHS12 was first isolated by analogue enrichment culture using nitrobenzene (NB) as the substrate, and this strain was observed to possess a partial reductive pathway for the degradation of NB. From high-performance liquid chromatography-mass spectrometry and1H nuclear magnetic resonance analyses, NB-grown cells ofP. putida HS12 were found to convert 3- and 4-CNBs to the corresponding 5- and 4-chloro-2-
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28

Xiao, Yi, Jian-Feng Wu, Hong Liu, Shu-Jun Wang, Shuang-Jiang Liu, and Ning-Yi Zhou. "Characterization of genes involved in the initial reactions of 4-chloronitrobenzene degradation in Pseudomonasputida ZWL73." Applied Microbiology and Biotechnology 73, no. 1 (2006): 166–71. http://dx.doi.org/10.1007/s00253-006-0441-3.

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29

XU, Qiong, Lei WANG, Junru CHEN, Xianjun LI та Ruixiang LI. "Selective Hydrogenation of p-Chloronitrobenzene over Ru–Ir/γ-Al2O3 Catalyst Modified by Organic Amines". Chinese Journal of Catalysis 28, № 7 (2007): 579–81. http://dx.doi.org/10.1016/s1872-2067(07)60047-3.

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30

Yan, Xiaoping, Manhong Liu, Hanfan Liu, and Kong Yong Liew. "Role of boron species in the hydrogenation of o-chloronitrobenzene over polymer-stabilized ruthenium colloidal catalysts." Journal of Molecular Catalysis A: Chemical 169, no. 1-2 (2001): 225–33. http://dx.doi.org/10.1016/s1381-1169(00)00565-3.

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31

Li, Haixiang, Zhiqiang Zhang, Xiaoyin Xu, Jun Liang, and Siqing Xia. "Bioreduction of para-chloronitrobenzene in a hydrogen-based hollow-fiber membrane biofilm reactor: effects of nitrate and sulfate." Biodegradation 25, no. 2 (2013): 205–15. http://dx.doi.org/10.1007/s10532-013-9652-3.

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32

P., Muralidhar Reddy, Shanker K., Usha Rani P., Krishna Rao B., and Ravinder V. "Spectral and catalytic hydrogenation studies of RuII organometallics containing substituted tertiary phosphines." Journal of Indian Chemical Society Vol. 84, May 2007 (2007): 411–17. https://doi.org/10.5281/zenodo.5819446.

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Department of Chemistry, Kakatiya University, Warangal-506 009, Andhra Pradesh, India <em>E-mail </em>: ravichemku@rediffmail.com <em>Manuscript received 6 March 2007, accepted 14 March 2007</em> The reaction of (RuCI<sub>2</sub>(COD)<sub>2</sub>] with acetylacetone (acac)/Na<sub>2</sub>CO<sub>3</sub> in the presence of dimethylformamide produces the precursor, (Ru(acac)<sub>2</sub>(COD)]. Using this precursor two series of organometallics were prepared by adopting different experimental conditions. The first series of Ru<sup>II</sup> organomctallics with the formula [Ru(acac)<sub>2</sub>L<sub
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33

Trivedi, Mahendra Kumar, Alice Branton, Dahryn Trivedi, Gopal Nayak, Ragini Singh, and Snehasis Jana. "Characterization of Biofield Energy Treated 3-Chloronitrobenzene: Physical, Thermal, and Spectroscopic Studies." International Journal of Waste Resources 5, no. 4 (2015). https://doi.org/10.5281/zenodo.50025.

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The chloronitrobenzenes are widely used as the intermediates in the production of pharmaceuticals, pesticides and rubber processing chemicals. However, due to their wide applications, they are frequently released into the environment thereby creating hazards. The objective of the study was to use an alternative strategy i.e. biofield energy treatment and analysed its impact on the physical, thermal and spectral properties of 3-chloronitrobenzene (3-CNB). For the study, the 3-CNB sample was taken and divided into two groups, named as control and treated. The analytical techniques used were X-ra
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34

Trivedi, Mahendra Kumar, Alice Branton, Dahryn Trivedi, Gopal Nayak, Ragini Singh, and Snehasis Jana. "Characterization of Biofield Energy Treated 3-Chloronitrobenzene: Physical, Thermal, and Spectroscopic Studies." International Journal Of Waste Resources 5, no. 4 (2015). https://doi.org/10.5281/zenodo.168369.

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The chloronitrobenzenes are widely used as the intermediates in the production of pharmaceuticals, pesticides and rubber processing chemicals. However, due to their wide applications, they are frequently released into the environment thereby creating hazards. The objective of the study was to use an alternative strategy i.e. biofield energy treatment and analysed its impact on the physical, thermal and spectral properties of 3-chloronitrobenzene (3-CNB). For the study, the 3-CNB sample was taken and divided into two groups, named as control and treated. The analytical techniques used were X-ra
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35

Xu, Zhi-Jing, Jim C. Spain, Ning-Yi Zhou, and Tao Li. "Biodegradation of 3-Chloronitrobenzene and 3-Bromonitrobenzene by Diaphorobacter sp. Strain JS3051." Applied and Environmental Microbiology, March 28, 2022. http://dx.doi.org/10.1128/aem.02437-21.

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Halonitroaromatic compounds are persistent environmental contaminants, and some of them have been demonstrated to be degraded by bacteria. Natural isolates that degrade 3-chloronitrobenzene and 3-bromonitrobenzene have not been reported.
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36

Mahendra, Kumar Trivedi. "Characterization of Biofield Energy Treated 3-Chloronitrobenzene: Physical, Thermal, and Spectroscopic Studies." International Journal Of Waste Resources 5, no. 4 (2015). https://doi.org/10.5281/zenodo.35187.

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The chloronitrobenzenes are widely used as the intermediates in the production of pharmaceuticals, pesticides and rubber processing chemicals. However, due to their wide applications, they are frequently released into the environment thereby creating hazards. The objective of the study was to use an alternative strategy i.e. biofield energy treatment and analysed its impact on the physical, thermal and spectral properties of 3-chloronitrobenzene (3-CNB). For the study, the 3-CNB sample was taken and divided into two groups, named as control and treated. The analytical techniques used were X-ra
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37

Trivedi, Mahendra. "Characterization of Biofield Energy Treated 3-Chloronitrobenzene: Physical, Thermal, and Spectroscopic Studies." www.omicsonline.com, October 8, 2015. https://doi.org/10.5281/zenodo.813569.

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The chloronitrobenzenes are widely used as the intermediates in the production of pharmaceuticals, pesticides and rubber processing chemicals. However, due to their wide applications, they are frequently released into the environment thereby creating hazards. The objective of the study was to use an alternative strategy i.e. biofield energy treatment and analysed its impact on the physical, thermal and spectral properties of 3-chloronitrobenzene (3-CNB). For the study, the 3-CNB sample was taken and divided into two groups, named as control and treated. The analytical techniques used were X-ra
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38

Kumar Trivedi, Mahendra, and Alice Branton. "Characterization of Biofield Energy Treated 3-Chloronitrobenzene: Physical, Thermal, and Spectroscopic Studies." International Journal of Waste Resources 05, no. 04 (2015). http://dx.doi.org/10.4172/2252-5211.1000183.

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39

Králik, Milan, Zuzana Vallušová, Peter Major, Adriana Takáčová, Milan Hronec, and Dana Gašparovičová. "Hydrogenation of chloronitrobenzenes over Pd and Pt catalysts supported on cationic resins." Chemical Papers 68, no. 12 (2014). http://dx.doi.org/10.2478/s11696-014-0565-3.

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AbstractLiquid phase hydrogenation of chloronitrobenzene isomers (x-CNB x = 2, 3, 4) to the corresponding chloroanilines (x-CAN) at mild reaction conditions (0.6 MPa, 25°C, diethyl ether-methanol as solvents) over palladium and platinum catalysts containing 1 mass % of metal on trimethylammonium functionalized poly{styrene-co-divinylbenzene} (Dowex-D) was studied. The average selectivities to x-CAN over Pd/D-Cl and Pd/D-OH catalysts were 72 % and 42 %, respectively, at the x-CNB conversion of about 80 %. The average selectivities of 81 % and 84 % were achieved using Pt/D-Cl and Pt/D-OH, respec
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40

Yang, Di, Weijie Li, Xin Deng, Yuchao Chai, Guangjun Wu, and Landong Li. "Foam Ti supported Pd catalysts for the selective hydrogenation of nitroaromatics." Chemistry – An Asian Journal, August 21, 2024. http://dx.doi.org/10.1002/asia.202400878.

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The selective hydrogenation of nitroaromatics plays an essential role in the chemical industry for the synthesis of anilines and their derivatives, which are known as crucial fine chemicals and pharmaceuticals. In this study, we demonstrate the preparation of Pd/Ti monolith catalyst containing well‐isolated metallic Pd sites on Ti substrate through a simple impregnation method, showing remarkable catalytic properties in the selective hydrogenation of nitroaromatics containing various functional groups. Kinetic analyses reveal an apparent activation energy of 61 kJ/mol and the kinetic isotope e
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41

Zubenko, A. A., L. N. Divaeva, L. N. Fetisov, et al. "Search for fungistatics in the imidazole series." Veterinaria i kormlenie, no. 5 (October 2022). http://dx.doi.org/10.30917/att-vk-1814-9588-2022-5-4.

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New imidazole derivatives with fungistatic activity were synthesized at the NCRSRVI branch of FSBSC Federal Rostov Agrarian Scientific Center. The initial compound 4,5-dichlorimidazole was obtained according to the method described in the literature [3]. Structures 1, 4, 6, 7, 8 - 11, 14 - 17, 19, 20, 22, 24 they were synthesized by alkylation of 4,5-dichlorimidazole with corresponding halide alkyls in an alkaline medium. Alcohol 5 was obtained by reducing ketone with sodium borohydride in ethanol. Bigeterocycles 10, 13 were obtained by the reaction of 4,5-dichlorimidazole with corresponding c
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42

Trivedi, Dahryn, Mahendra Trivedi, Gopal Nayak, and Alice Branton. "Determination of Isotopic Abundance of 13C/12C or 2H/1H and 18O/16O in Biofield Energy Treated 1-Chloro-3-Nitrobenzene (3-CNB) Using Gas Chromatography-Mass Spectrometry." July 23, 2016. https://doi.org/10.5281/zenodo.166418.

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1-Chloro-3-nitrobenzene (3-CNB) is an aromatic halo-amine compound used as chemical intermediate for the production of several fine chemicals like pharmaceuticals, dyes, agricultural chemicals, etc. The stable isotope ratio analysis has drawn attention in numerous fields such as agricultural, food authenticity, biochemistry, etc. The objective of the current research was to investigate the impact of the biofield energy treatment on the isotopic abundance ratios of P<sub>M+1</sub>/P<sub>M</sub>, P<sub>M+2</sub>/P<sub>M</sub> and P<sub>M+3</sub>/P<sub>M</sub> in 3-CNB using gas chromatography –
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43

Andreeva, Anastasia V., Rose K. Baimuratova, Victor G. Dorokhov, et al. "Rational Synthesis of UiO-66 and its Application in the Hydrogenation Reaction of p-Chloronitrobenzene." EURASIAN JOURNAL OF CHEMISTRY, August 20, 2024. http://dx.doi.org/10.31489/2959-0663/3-24-10.

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Hydrogenation is a widely used reaction in the oil processing and industrial organic synthesis. UiO-66 is a prom-ising porous organic-inorganic material that can be used as a support for catalytically active particles. The key part in the application of highly porous UiO-66 is the search of a simple synthesis method that meets international environmental standards. In this study, a "rational" method for the synthesis of MOFs was used to produce UiO-66. The use of pre-synthesized multinuclear zirconia clusters facilitates the synthesis of the desired network to-pology, enabling the process to b
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44

Sun, Yu, Jie Gan, Bing Du, You Wang, Jieyi Yin, and Sai Zhang. "Investigation of hydrogen spillover in atomically dispersed metal on WO3 for selective hydrogenation." AIChE Journal, February 4, 2025. https://doi.org/10.1002/aic.18749.

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AbstractOptimizing kinetic barriers of hydrogen spillover for selective hydrogenation on supported catalysts with dual‐active sites faces a significant challenge due to inherent contradiction between H2 activation and *H transformation from metal to support. Herein, the adsorption energy of *H (Ead(H)) on metal has been demonstrated as a viable descriptor for understanding hydrogenation on the WO3 surface with dual‐active sites of single‐atom metals and oxygen vacancies. Theoretical simulations rationalize the optimized value of Ead(H) of −2.49 eV for these dual‐active sites. Furthermore, the
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Guo, Leilei, Quanxiu Wang, Qingqing Shi, Ruolin Guan, Liping Zhao, and Hanmin Yang. "Controlled synthesis of dendritic ruthenium nanostructures under microwave irradiation and their catalytic properties for p-chloronitrobenzene hydrogenation." Transition Metal Chemistry, August 17, 2020. http://dx.doi.org/10.1007/s11243-020-00419-3.

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46

Pope, Deborah, Connor Tyree, Christopher Racine, Dianne K. Anestis, and Gary O. Rankin. "In vitro nephrotoxicity induced by 2,4,5- and 2,4,6-trichloronitrobenzenes." Proceedings of the West Virginia Academy of Science 88, no. 1 (2016). http://dx.doi.org/10.55632/pwvas.v88i1.20.

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Chloronitrobenzenes are key chemical intermediates used in the manufacture of dyes, agricultural agents and industrial compounds. Although some data exists on the toxicity of mono- and dichloronitrobenzenes, there is a paucity of data on the toxicity profile of trichloronitrobenzenes (TCNBs). One of the target organs for mono- and dichloronitrobenzenes is the kidney. The purpose of this study was to examine the in vitro nephrotoxic potential of two TCNBs, 2,4,5-trichloronitrobenzene (2,4,5-TCNB) and 2,4,6- trichloronitrobenzene (2,4,6-TCNB), using freshly isolated rat renal cortical cells (IRC
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