Academic literature on the topic 'Aldolic reaction'

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Journal articles on the topic "Aldolic reaction"

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Medina-Navarro, R., E. Mercado-Pichardo, O. Herńndez-Pérez, and J. J. Hicks. "Identification of acrolein from the ozone oxidation of unsaturated fatty acids." Human & Experimental Toxicology 18, no. 11 (1999): 677–82. http://dx.doi.org/10.1191/096032799678839527.

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By-products of lipoperoxidation reactions may be associated with the genesis or the progression of several diseases as arteriosclerosis, diabetes and cancer, among many others. Acrolein, at first a widely distributed environmental pollutant, is currently known as a compound capable of being generated as a result of metabolic reactions within biological systems, highly toxic and the most electrophilic of the a, b-unsaturated aldehydes formed during lipoperoxidation. In the present study: 1 The separation of acrolein and malondialdehyde was achieved at alkaline pH with the use of high voltage ca
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Cruz, Alejandro, Itzia I. Padilla-Martínez, and Maria E. Bautista-Ramirez. "Ephedrines as Chiral Auxiliaries in Enantioselective Alkylation Reactions of Acyl Ephedrine Amides and Esters: A Review." Current Organic Synthesis 15, no. 1 (2018): 38–83. http://dx.doi.org/10.2174/1570179414666170830125915.

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Background: In modern chemistry, the asymmetric synthesis for the preparation of high purity chiral compounds to be used as pharmaceuticals or additives in foods have been of capital importance. Chiral auxiliary reagents are used to control the stereochemistry of the reaction in the generation of new chiral compounds, in this context, Ephedra compounds (ephedrines and pseudoephedrines) and some of their derivatives have been broadly used as chiral ligands in catalysis or chiral inductors in asymmetric synthesis. Objective: This review focuses on recent progress in the use of ephedra compounds
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Hernández-Rodríguez, Marcos, Claudia Gabriela Avila-Ortiz, Jorge M. del Campo, Delia Hernández-Romero, María J. Rosales-Hoz, and Eusebio Juaristi. "Synthesis of Novel Chiral (Thio)ureas and Their Application as Organocatalysts and Ligands in Asymmetric Synthesis." Australian Journal of Chemistry 61, no. 5 (2008): 364. http://dx.doi.org/10.1071/ch08116.

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The synthesis of novel chiral (thio)ureas 1–10 and 14–26 is described. These (thio)ureas incorporate chiral auxiliaries derived from (R)- or (S)-α-phenylethylamine, (R)-phenylglycine, or (1R,2S)-ephedrine. The phenylethyl group in compounds 1–10 and 21–24 adopts a particular orientation in the molecular structure as a consequence of 1,3-allylic strain with the (thio)carbonyl group. Ureas 1–10 were tested as Lewis basic organocatalysts in epoxide ring opening and in aldolic condensation, and it was found that the tetrasubstituted urea (R,R)-2 afforded the best results in terms of reaction yield
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Dammene Debbih, Ouafa, Assia Sid, Rafika Bouchene, Sofiane Bouacida, Wissam Mazouz, and Noureddine Gherraf. "Two hydrazones derived from 1-aryl-3-(p-substituted phenyl)prop-2-en-1-one: synthesis, crystal structure, Hirshfeld surface analysis andin vitrobiological properties." Acta Crystallographica Section C Structural Chemistry 74, no. 6 (2018): 703–14. http://dx.doi.org/10.1107/s2053229618006812.

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Two chalcones were synthesized by the aldolic condensation of enolizable aromatic ketones with substituted benzaldehydes under Claisen–Schmidt reaction conditions and then treated with 2,4-dinitrophenylhydrazine to yield their corresponding hydrazones. The two (E,Z)-2,4-dinitrophenylhydrazone structures, namely (Z)-1-(2,4-dinitrophenyl)-2-[(E)-3-(4-methylphenyl)-1-phenylallylidene]hydrazine, C22H18N4O4, (H1), and (Z)-1-[(E)-3-(4-chlorophenyl)-1-(naphthalen-1-yl)allylidene]-2-(2,4-dinitrophenyl)hydrazine, C25H17ClN4O4, (H2), were isolated by recrystallization and characterized by FT–IR, UV–Vis,
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Schreyer, Lucas, Philip S. J. Kaib, Vijay N. Wakchaure, et al. "Confined acids catalyze asymmetric single aldolizations of acetaldehyde enolates." Science 362, no. 6411 (2018): 216–19. http://dx.doi.org/10.1126/science.aau0817.

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Reactions that form a product with the same reactive functionality as that of one of the starting compounds frequently end in oligomerization. As a salient example, selective aldol coupling of the smallest, though arguably most useful, enolizable aldehyde, acetaldehyde, with just one partner substrate has proven to be extremely challenging. Here, we report a highly enantioselective Mukaiyama aldol reaction with the simple triethylsilyl (TES) andtert-butyldimethylsilyl (TBS) enolates of acetaldehyde and various aliphatic and aromatic acceptor aldehydes. The reaction is catalyzed by recently dev
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Hayashi, Yujiro, and Itaru Sato. "Mukaiyama Aldol Reaction ^|^mdash; 40th Anniversary Symposium." Journal of Synthetic Organic Chemistry, Japan 72, no. 3 (2014): 309–13. http://dx.doi.org/10.5059/yukigoseikyokaishi.72.309.

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Müller, Tobias, Kristina Djanashvili, Joop A. Peters, Isabel W. C. E. Arends, and Ulf Hanefeld. "Tetrahedral boronates as basic catalysts in the aldol reaction." Zeitschrift für Naturforschung B 70, no. 8 (2015): 587–95. http://dx.doi.org/10.1515/znb-2015-0029.

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Abstractβ-Hydroxyketones are versatile building blocks in organic synthesis, which can be conveniently synthesized from ketones and aldehydes by aldol reactions. Unfortunately, these reactions often suffer from dehydration of the initially formed β-hydroxyketones. Previously, tetrahedral 3,5-difluorophenylborate was shown to be an efficient and selective catalyst for this reaction. The present investigation concerns the catalytic performance of phenyl borates with different substitution patterns in the aldol reaction. It appears that the dehydration reaction can be suppressed by selecting subs
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Huang, Wen-Ping, Jia-Rong Chen, Xin-Yong Li, Yi-Ju Cao, and Wen-Jing Xiao. "Asymmetric organocatalytic direct aldol reactions of cyclohexanone with aldehydes in brine." Canadian Journal of Chemistry 85, no. 3 (2007): 208–13. http://dx.doi.org/10.1139/v07-012.

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Organocatalytic asymmetric direct aldol reactions in brine with high diastereo- and enantioselectivities, using a readily available bifunctional amide catalyst, were developed.Key words: aldol reaction, organocatalyst, asymmetric catalysis, water.
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Inegbenebor, Adedayo I., Raphael C. Mordi, and Oluwakayode M. Ogunwole. "Zeolite Catalyzed Aldol Condensation Reactions." International Journal of Applied Sciences and Biotechnology 3, no. 1 (2015): 1–8. http://dx.doi.org/10.3126/ijasbt.v3i1.12291.

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The review is based on the description of zeolite structure, uses, synthesis, and catalytic aldol reaction in aldol condensation. An internal aldolcondensation reaction has been achieved over ZSM-5 zeolite with high silica-alumina ratio at 350oC. It therefore follows that zeolite canfunction as a catalyst in aldol type condensation reactions and that weak acid sites as well as a small number of active sites favor the aldolcondensation reaction of carbonyl compounds. However, the mixed condensation product was found to be favored at temperatures above 300oCand the self-condensation of ethanal t
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Rougeot, Céline, Henry Situ, Blessing Huynh Cao, Vaso Vlachos, and Jason E. Hein. "Automated reaction progress monitoring of heterogeneous reactions: crystallization-induced stereoselectivity in amine-catalyzed aldol reactions." Reaction Chemistry & Engineering 2, no. 2 (2017): 226–31. http://dx.doi.org/10.1039/c6re00211k.

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Dissertations / Theses on the topic "Aldolic reaction"

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Lima, Dimas José da Paz. "Síntese do fragmento C11-C26 do potente agente antitumoral (-)-dictiostatina." [s.n.], 2010. http://repositorio.unicamp.br/jspui/handle/REPOSIP/248476.

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Orientador: Luiz Carlos Dias<br>Tese (doutorado) - Universidade Estadual de Campinas, Instituto de Química<br>Made available in DSpace on 2018-08-16T13:59:46Z (GMT). No. of bitstreams: 1 Lima_DimasJosedaPaz_D.pdf: 6787500 bytes, checksum: 4cdb1c2dbc5967cdef9ab7564d8c0118 (MD5) Previous issue date: 2010<br>Resumo: A (-)-dictiostatina (1) é uma macrolactona de origem marinha, que foi isolada por Pettit e col. em 1994 da esponja Spongia sp. e posteriormente, por Wright e col. a partir da esponja Lithistida. A (-)-dictiostatina (1) exibe uma potente atividade antitumoral, inibindo a proliferação
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Hansch, Markus. "Die Zirconiumalkoxid-katalysierte Aldol-Tishchenko-Reaktion von Keton-Aldolen." Doctoral thesis, [S.l.] : [s.n.], 2005. http://deposit.ddb.de/cgi-bin/dokserv?idn=975299727.

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Mahal, Amrik Singh. "Asymmetric aldol reactions." Thesis, University of Kent, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.302987.

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Tang, Gongkun [Verfasser]. "Novel Organocatalysts with Pyrrolidine and Brönsted Acids for Aldol Reaction and other Reactions / Gongkun Tang." Wuppertal : Universitätsbibliothek Wuppertal, 2013. http://d-nb.info/1038029023/34.

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Maggiotti, Virginie. "Direct biocatalytic asymmetric aldol reactions." Thesis, University of Oxford, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.275468.

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Tan, Duygu. "Silicon Tetrachloride Mediated Asymmetric Aldol Addition Reaction." Master's thesis, METU, 2013. http://etd.lib.metu.edu.tr/upload/12615396/index.pdf.

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Aldol addition reaction is one of the most important and most studied carbon-carbon bond forming reactions in organic chemistry. Recent studies focused on the catalytic version of this chemistry. Different from the classical Mukaiyama-type aldol reactions, chiral lewis bases have been used as promoters. In the presence of SiCl4, these reactions proceed through a cyclic transition state leading to anti aldol product as a major product with moderate-to-good diastereo and enantioselectivities. Phosphoramide derivatives, BINAPO, BINAPO derivatives, N,N-dioxides and N-oxides have been extensively u
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Goodman, J. M. "Studies on the boron-mediated aldol reaction." Thesis, University of Cambridge, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.316774.

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Tokuda, Osamu. "Studies on organocatalytic direct asymmetric aldol reaction." 京都大学 (Kyoto University), 2007. http://hdl.handle.net/2433/136966.

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Vickery, Benjamin David. "New strategies for asymmetric Aldol reactions." Thesis, Imperial College London, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.301299.

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Nixon, Tracy Dawn. "Catalyst design for the asymmetric phospho-aldol reaction." Thesis, University of Leeds, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.424504.

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Books on the topic "Aldolic reaction"

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Mahrwald, Rainer. Aldol Reactions. Springer Netherlands, 2009.

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Mahrwald, Rainer, ed. Aldol Reactions. Springer Netherlands, 2009. http://dx.doi.org/10.1007/978-1-4020-8701-1.

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Mahrwald, Rainer, ed. Modern Methods in Stereoselective Aldol Reactions. Wiley-VCH Verlag GmbH & Co. KGaA, 2013. http://dx.doi.org/10.1002/9783527656714.

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Fish, Joshua. Pyrite as a catalyst for aldol condensation reactions. Laurentian University, 2001.

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Mahrwald, Rainer, ed. Modern Aldol Reactions. Wiley, 2004. http://dx.doi.org/10.1002/9783527619566.

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A, Evans David, and Rainer Mahrwald. Modern Aldol Reactions. Wiley & Sons, Limited, John, 2008.

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Mahrwald, Rainer. Modern Methods in Stereoselective Aldol Reactions. Wiley & Sons, Incorporated, John, 2013.

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Mahrwald, Rainer. Modern Methods in Stereoselective Aldol Reactions. Wiley & Sons, Incorporated, John, 2013.

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Mahrwald, Rainer. Modern Methods in Stereoselective Aldol Reactions. Wiley & Sons, Limited, John, 2013.

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Mahrwald, Rainer. Modern Methods in Stereoselective Aldol Reactions. Wiley & Sons, Incorporated, John, 2013.

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Book chapters on the topic "Aldolic reaction"

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Li, Jie Jack. "Aldol condensation." In Name Reactions. Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-642-01053-8_2.

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Li, Jie Jack. "Aldol condensation." In Name Reactions. Springer International Publishing, 2014. http://dx.doi.org/10.1007/978-3-319-03979-4_2.

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Li, Jie Jack. "Aldol condensation." In Name Reactions. Springer Berlin Heidelberg, 2003. http://dx.doi.org/10.1007/978-3-662-05336-2_3.

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Li, Jie Jack. "Aldol Condensation." In Name Reactions. Springer International Publishing, 2021. http://dx.doi.org/10.1007/978-3-030-50865-4_2.

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Schetter, Bernd, and Rainer Mahrwald. "Aldol Reactions." In Quaternary Stereocenters. Wiley-VCH Verlag GmbH & Co. KGaA, 2006. http://dx.doi.org/10.1002/3527606858.ch3.

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Fessner, Wolf-Dieter. "Aldol Reactions." In Enzyme Catalysis in Organic Synthesis. Wiley-VCH Verlag GmbH & Co. KGaA, 2012. http://dx.doi.org/10.1002/9783527639861.ch21.

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Li, Jie Jack. "Mukaiyama aldol reaction." In Name Reactions. Springer Berlin Heidelberg, 2002. http://dx.doi.org/10.1007/978-3-662-04835-1_193.

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Li, Jie Jack. "Evans aldol reaction." In Name Reactions. Springer Berlin Heidelberg, 2002. http://dx.doi.org/10.1007/978-3-662-04835-1_94.

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Li, Jie Jack. "Mukaiyama aldol reaction." In Name Reactions. Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-642-01053-8_170.

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Li, Jie Jack. "Evans aldol reaction." In Name Reactions. Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-642-01053-8_92.

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Conference papers on the topic "Aldolic reaction"

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Soares, Bruna Miranda, and Andréa Maria Aguilar. "Studies in Organocatalysts Synthesis for Direct Aldol Reaction." In 14th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-14bmos-r0252-1.

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Sousa, Bruno A. de, Fábio G. Zanin, and Alcindo A. Dos Santos. "Lithium Organochalcogenides Promoting Michael-aldol Tandem Reactions." In 14th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-14bmos-r0297-1.

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SASAKI, M., T. HAYAKAWA, K. ARAI, and T. ADSCHIRI. "MEASUREMENT OF THE RATE OF RETRO-ALDOL CONDENSATION OF D-XYLOSE IN SUBCRITICAL AND SUPERCRITICAL WATER." In Proceedings of the Seventh International Symposium on Hydrothermal Reactions. WORLD SCIENTIFIC, 2003. http://dx.doi.org/10.1142/9789812705228_0022.

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Jacoby, Caroline Gross, Raoní Scheibler Rambo, Tiago Lima da Silva, and Paulo Henrique Schneider*. "New Thiazolidine-Based Organocatalysts for Enantio- and Diastereoselective Aldol Reaction." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_2013915193943.

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Silva, Tiago Lima da, and Paulo Henrique Schneider. "Multicomponent Synthesis of Bifunctional Thiourea Organocatalysts for the Enantioselective Aldol Reaction." In 14th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-14bmos-r0012-1.

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Tabatabaeian, Khalil, Elahe Keshavarz, Nosrat O. Mahmoodi, and Manouchehr Mamaghani. "Simple and fast ruthenium catalyzed direct aldol reaction: scope and limitations." In The 15th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2011. http://dx.doi.org/10.3390/ecsoc-15-00670.

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Cahyana, A. H., B. Ardiansah, and M. B. Maloka. "Magnetite - activated chicken eggshell (Fe3O4-ACE) composite for aldol condensation reaction." In PROCEEDINGS OF THE 3RD INTERNATIONAL SYMPOSIUM ON CURRENT PROGRESS IN MATHEMATICS AND SCIENCES 2017 (ISCPMS2017). Author(s), 2018. http://dx.doi.org/10.1063/1.5064075.

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Silva, Rúbia Yano da, and Andréa Maria Aguilar. "Studies in Organocatalyzed Direct Aldol Reactions under Solvent-Free Conditions." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_201382113529.

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Sakae, George H., Leandro M. Takata, Antonio S. Paulino, et al. "A high enantioselective Proline-based helical polymer catalyst for aldol type reaction." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_2013912163332.

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Li, Guigen, Han-Xun Wei, and Subramanian Karur. "Halo Aldol Reaction of a,b-Unsaturated Ketones and Aldehydes Mediated by Titanium Tetrachloride." In The 4th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2000. http://dx.doi.org/10.3390/ecsoc-4-01838.

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