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1

Márquez-Benavides, Liliana, David García-Hernández, Juan Luis Ignacio-de La Cruz, Marco Aurelio Pardo-Galvan, and Juan Manuel Sánchez-Yañez. "Bioremediation of domestic water polluted by benzene of waste motor oil with crude extract of Pleurotus Florida and mineral solution." Brazilian Journal of Development 10, no. 3 (2024): e67717. http://dx.doi.org/10.34117/bjdv10n3-001.

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In Mexico and in the world, a problem of contamination in domestic water is due to petroleum derivatives such as waste motor oil (WMO), whose chemical composition is aliphatic and aromatic hydrocarbons. An ecological solution is to biostimulation with extracellular enzimes of Pleurotus florida and mineral solution to eliminate both by the aerobic native heterotrophic microbiota. The objective of this research was to analyze the bioremediation of domestic water polluted by benzene of WMO with an extract of P. florida and mineral solution. In that sense, P. florida was grown in straw with lignin
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2

Linse, Per. "Orientation-averaged benzene-benzene potential of mean force in aqueous solution." Journal of the American Chemical Society 115, no. 19 (1993): 8793–97. http://dx.doi.org/10.1021/ja00072a037.

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3

Qi, Hui Li, Ke Gai, and Dong Ping Ma. "Plasma-Induced Degradation of Benzene in Aqueous Solution." Advanced Materials Research 989-994 (July 2014): 55–59. http://dx.doi.org/10.4028/www.scientific.net/amr.989-994.55.

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Removal of benzene and effects of various parameters on the removal efficiency in the aqueous solution with plasma are studied. Results indicated that the degradation rate can be considerably raised by prolonging the discharge time, removal proceeded faster when the treatment was conducted in alkaline or acidic than in neutral media. Fe2+ shows an evident accelerated effect on the benzene elimination, and the presence of H2O2 benefited the degradation. It is demonstrated that the hydroxyl radicals were the most responsible oxidants in the benzene degradation. The major intermediate products re
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4

Lee, H. S., X. Q. Yang, J. McBreen, D. Vyprachticky, and Y. Okamoto. "Article." Canadian Journal of Chemistry 77, no. 5-6 (1999): 738–43. http://dx.doi.org/10.1139/v99-045.

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A new chloride anion receptor, derivatized oligoethylene oxide CF3SO2 substituted tetraamine (3), was synthesized. This compound exhibited strong Cl-1 ion binding properties in nonpolar solvents such as benzene. Neutral red and Nile blue chloride dye molecules do not dissolve in benzene. However, when compound (3) was added to a benzene solution containing the solid dye compounds, the color of the solution immediately turned to dark blue, and the intensity of the color proportionally increased with the concentration of (3). The phenomena indicated that the Cl- ions of Neutral red or Nile blue
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5

Boyle, Peter H., and Mary F. Kelly. "Hydrogenatiqn of silylated pteridines in benzene solution." Tetrahedron 44, no. 16 (1988): 5179–88. http://dx.doi.org/10.1016/s0040-4020(01)86024-5.

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6

Więckowska, Ewa, and Wiktor Pawłowski. "Hydration of Benzoic Acid in Benzene Solution." Zeitschrift für Physikalische Chemie 166, Part_2 (1990): 167–82. http://dx.doi.org/10.1524/zpch.1990.166.part_2.167.

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7

Pawłowski, Wiktor, and Ewa Więckowska. "Hydration of Benzoic Acid in Benzene Solution." Zeitschrift für Physikalische Chemie 168, Part_2 (1990): 205–15. http://dx.doi.org/10.1524/zpch.1990.168.part_2.205.

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8

Cieplak, Piotr, Wiktor Pawłowski, and Ewa Wiȩckowska. "Hydration of Benzoic Acid in Benzene Solution." Zeitschrift für Physikalische Chemie 177, Part_1 (1992): 63–74. http://dx.doi.org/10.1524/zpch.1992.177.part_1.063.

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9

Tschliessnig, Rupert, Werner Billes, Martin Wendland, Johann Fischer, and Jiří Kolafa. "Adsorption of benzene from an aqueous solution." Molecular Simulation 31, no. 9 (2005): 661–66. http://dx.doi.org/10.1080/08927020500108213.

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10

Ying, Qicong, James Marecek, and Benjamin Chu. "Solution behavior of buckminsterfullerene (C60) in benzene." Journal of Chemical Physics 101, no. 4 (1994): 2665–72. http://dx.doi.org/10.1063/1.467646.

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11

Ohkubo, Kei. "Visible-Light Induced C-H Oxygenation of Hydrocarbons Using Chlorine Dioxide as a Photoredox Catalyst." ECS Meeting Abstracts MA2024-02, no. 53 (2024): 3622. https://doi.org/10.1149/ma2024-02533622mtgabs.

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Photocatalytic oxygenation of benzene occurs in an oxygen-saturated acetonitrile solution containing acridnium ion or quinolinium ion derivatives as a photoredox catalyst, benzene and water under light irradiation to yield phenol and hydrogen peroxide selectively. The benzene radical cation, which is formed by photoinduced one-electron oxidation of benzene with the excited state of catalyst, reacts with H2O to yield phenol. Photocatalytic oxygenation of benzene with oxygen occurs under photoirradiation of an acetonitrile solution of 3-cyano-1-methylquinolinium perchlorate (QuCN+ClO4 –) in an o
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12

Qiao, Hui, Mingqi He, Qiushi Wang, Shuaishuai Han, Haiqian Zhao, and Zhonghua Wang. "Cost-effective method of benzene-containing wastewater treatment using floating electro-Fenton system." Water Science and Technology 83, no. 9 (2021): 2183–91. http://dx.doi.org/10.2166/wst.2021.124.

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Abstract Traditional electro-Fenton systems must continuously supply oxygen to the cathode, which leads to extensive volatilisation of benzene in solutions. In this study, we adopted a floating cathode electro-Fenton system without bubbling oxygen into the solution to treat benzene-containing wastewater. The effects of the floating cathode position and main reaction parameters on benzene degradation were analysed, and the degradation cost was estimated. The results indicated that the electro-Fenton system with floating cathode could effectively degrade benzene in solutions. For the cathode, th
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13

Koba, Motoharu. "Improved Results Using Higher Ratios of Scintillator Solution to Benzene in Liquid Scintillation Spectrometry." Radiocarbon 42, no. 2 (2000): 295–303. http://dx.doi.org/10.1017/s0033822200059105.

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Practical effects of the volumetric or weight ratio of scintillator solution to sample benzene in liquid scintillation spectrometry were examined here for radiocarbon dating. It is concluded, using a LKB-Wallac Quantulus™ 1220 and Teflon™-copper 3 mL vials with scintillator of toluene-based PPO and POPOP, that solutions containing the same concentrations of the same ratio, 1.3 or more, of scintillator solution to sample benzene show the same cpm/g and the same channel value of external standard spectrum, irrespective of different gross volumes of solutions. The addition of scintillator solutio
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14

Islam, Md Zahidul, Anyarat Watthanaphanit, Sangwoo Chae, and Nagahiro Saito. "Li–air battery and ORR activity of nanocarbons produced with good synthesis rate by solution plasma process." Materials Advances 2, no. 8 (2021): 2636–41. http://dx.doi.org/10.1039/d0ma00926a.

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15

Quynh Anh, Le Huu. "COMPARISON OF OXIDIZED CARBON NANOTUBES EFFICIENCIES FOR BENZENE AND TOLUENE REMOVAL FROM AQUEOUS SOLUTION." Vietnam Journal of Science and Technology 55, no. 4C (2018): 311. http://dx.doi.org/10.15625/2525-2518/55/4c/12169.

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Carbon nanotubes (CNTs) have been widely used as adsorbent in environmental treatment, especially for pollutants and volatile organic compounds (VOCs). The purpose of this work is to develop materials based on functionalized multiwalled carbon nanotubes (MWCNTs) for Benzene and Toluene removal. This will exploit adsorption propertiesof modified MWCNTS for Benzene and Toluene. In the first study, adsorption capacity of pristine MWCNTs to Benzene and Toluene in aqueous solution was investigated through isotherm study. The qe values of CNTs for Benzene and Toluene were 45,5 mg.g-1 and 56.3 mg.g-1
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16

Qin, Yu, Ying Xiong, Chun Li Kang, et al. "Comparison on the Adsorption Thermodynamics of Three Typical Petroleum Hydrocarbons in the Single and Mixed Solution on Aquifer Media." Advanced Materials Research 383-390 (November 2011): 3939–43. http://dx.doi.org/10.4028/www.scientific.net/amr.383-390.3939.

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This paper researched on the adsorption kinetics and thermodynamics of the typical components of petroleum hydrocarbon-benzene, naphthalene, phenanthrene and their mixed solution on the typical media-the medium sand from the aquifer in an oil contaminated field, with a self-made rotary adsorption device. The result showed that the adsorption of the three adsorbates on the media follows the Henry adsorption model, no matter when they are separated or mixed. The adsorption capacity order of benzene, naphthalene and phenanthrene on the medium sand is phenanthrene> naphthalene>benzene, when
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17

Dumele, Oliver, Dino Wu, Nils Trapp, Nancy Goroff, and François Diederich. "Halogen Bonding of (Iodoethynyl)benzene Derivatives in Solution." Organic Letters 16, no. 18 (2014): 4722–25. http://dx.doi.org/10.1021/ol502099j.

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18

Ying, Qicong, James Marecek, and Benjamin Chu. "Slow aggregation of buckminsterfullerene (C60) in benzene solution." Chemical Physics Letters 219, no. 3-4 (1994): 214–18. http://dx.doi.org/10.1016/0009-2614(94)87047-0.

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19

Haarmann, Klaus, Edwin Haselbach, and Paul Suppan. "Triplet State Lifetime of Anthracene in Benzene Solution." CHIMIA 41, no. 6 (1987): 198. https://doi.org/10.2533/chimia.1987.198.

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The decay kinetics of the triplet state absorption of anthracene in benzene have been measured in conditions of laser flash photolysis, as a function of anthracene concentration and of laser light intensity. It is concluded that concentration quenching of triplet state anthracene by ground state anthracene is the major bimolecular deactivation process.
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20

S., M. Yakout. "Adsorption kinetics modeling of benzene from aqueous solution onto rice husk activated carbon prepared by H3PO4 activation." Journal of Indian Chemical Society Vol. 91, Oct 2014 (2014): 1915–24. https://doi.org/10.5281/zenodo.5733877.

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Biochemistry Department, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Kingdom of Saudi Arabia Hot Laboratories Centre, Atomic Energy Authority, Cairo 13759, Egypt <em>E-mail</em> : sobhy.yakout@gmail.com Fax : 966-14675932 <em>Manuscript received online 10 March 2014, revised 27 April 2014, accepted 27 April 2014</em> Benzene is one of the most hazardous organic pollutants in groundwater. The removal of benzene from water is very important from health point of view and for environmental protection. Activated carbon from rice husk (RHC) with H<sub>3</sub>PO<sub>4</sub>
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21

Amira, E. Ali, Elmekabaty Ahmed, M. Elabbasy Hanaa, F. Atia Mohamed, E. Bad Gamila, and El-Aziz S. Fouda Abd. "Benzene Sulfonamide Derivatives as Inhibitors for Steel Dissolution in Sulfuric Acid Solution." Indian Journal of Science and Technology 16, no. 37 (2023): 3073–89. https://doi.org/10.17485/IJST/v16i37.259.

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Abstract <strong>Objectives:</strong>&nbsp;To examine the effectiveness of various benzene sulfonamide derivatives in preventing the corrosion of carbon steel in H2SO4 and to identify the dominating active form of the used compounds throughout the adsorption process in order to better understand the mechanism of their action.&nbsp;<strong>Methods:</strong>&nbsp;N-(4-(2-Aminothiazol-4-yl) phenyl) benzene sulfonamide (A) and N-(4-(2-thioxo-1, 2-dihydropyrimidim&mdash;4-yl) phenyl) benzene sulfonamide (B) were the tested compounds and were chosen based on molecular structure. To examine the effec
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22

Cheng, Tingting, Lan Xu, and Mingdi Wang. "Effect of surface active agent on bubble-electrospun polyacrylonitrile nanofibers." Thermal Science 23, no. 4 (2019): 2481–87. http://dx.doi.org/10.2298/tsci1904481c.

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Sodium dodecyl benzene sulfonates were used as a surfactant to obtain polyacrylonitrile nanofibers by a modified bubble-electrospinning using a copper cone-shaped air nozzle. The properties of the electrospun solutions were investigated using viscosity meter, conductivity meter and rheometer, and the effects of sodium dodecyl benzene sulfonates concentration on the morphology, mechanical property and production of polyacrylonitrile nanofibers were studied. The results showed the addition of sodium dodecyl benzene sulfonates could effectively decrease the viscosity of the solution, increase the
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23

Pourzamani, Hamidreza, Bijan Bina, Mohammad Mehdi Amin, and Alimorad Rashidi. "Monoaromatic Pollutant Removal by Carbon Nanotubes from Aqueous Solution." Advanced Materials Research 488-489 (March 2012): 934–39. http://dx.doi.org/10.4028/www.scientific.net/amr.488-489.934.

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The removal of monoaromatic (benzene (B) and toluene (T)) from aqueous solution by multi walled, single walled, and hybrid carbon nanotubes (MWCNTs, SWCNTs, and HCNTs) was evaluated for a nanomaterial dose of 1 g/l, concentration of 10-100 mg/l, and pH 7. The equilibrium amount removed by SWCNTs (B: 9.98 mg/g and T: 9.96 mg/g) was higher than for MWCNTs and HCNTs. Toluene has a higher adsorption tendency on CNTs than benzene, which is related to the increasing water solubility and the decreasing molecular weight of the compounds. The SWCNTs performed better for B and T sorption than the MWCNTs
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24

Liu, Qing Zhi, Deng Feng Yang, Ya Juan Yue, Zhen Bo Geng, and Yang Dong Hu. "Molecular Simulation of Solution Process of Organic Molecules in Polyethylene Membranes." Advanced Materials Research 781-784 (September 2013): 452–57. http://dx.doi.org/10.4028/www.scientific.net/amr.781-784.452.

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The dissolution process of benzene, toluene and ethylbenzene in amorphous polyethylene (PE) membrane was studied in this paper, and the solubility coefficients of the above organic molecules were analyzed and calculated by molecular dynamics simulation. The results showed: the solubility coefficient decreased with increasing molecular weights of organic molecules in the same temperature, and it also decreased with increasing temperature for the same organic molecule. Distribution of density field and energy field for organic molecules in PE were obtained. From the density distribution, the con
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25

Ling, Min Yan, and Hou He Chen. "Oxidation Chlorination of Thiophene in Coking Benzene." Applied Mechanics and Materials 130-134 (October 2011): 1066–69. http://dx.doi.org/10.4028/www.scientific.net/amm.130-134.1066.

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Thiophene is a typical thiophenenic sulfur compound that exists in coking benzene. In this paper, investigate oxidation chlorination of thiophene in coking benzene. Potassium permanganate was combined with hydrochloric acid for a new KMnO4/HCl system of oxidation desulfurization. The preliminary results show that the thiophene in the benzene cannot be deep oxidized desulfurization alone potassium permanganate solution even at acetum. The thiophene in the coking benzene could be mostly converted by using KMnO4/HCl system. In suitable reaction conditions thiophene’s removal rate can reach more t
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26

Mohammadi, Leili, Edris Bazrafshan, Meissam Noroozifar, Alireza Ansari-Moghaddam, Farahnaz Barahuie, and Davoud Balarak. "Adsorptive Removal of Benzene and Toluene from Aqueous Environments by Cupric Oxide Nanoparticles: Kinetics and Isotherm Studies." Journal of Chemistry 2017 (2017): 1–10. http://dx.doi.org/10.1155/2017/2069519.

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Removal of benzene and toluene, as the major pollutants of water resources, has attracted researchers’ attention, given the risk they pose to human health. In the present study, the potential of copper oxide nanoparticles (CuO-NPs) in eliminating benzene and toluene from a mixed aqueous solution was evaluated. For this, we performed batch experiments to investigate the effect of solution pH (3–13), dose of CuO-NPs (0.1–0.8 g), contact time (5–120 min), and concentration of benzene and toluene (10–200 mg/l) on sorption efficiency. The maximum removal was observed at neutral pH. By using the Lan
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27

Rasheed, Salam H., Salah S. Ibrahim, Qusay F. Alsalhy, and Issam K. Salih. "Separation of Soluble Benzene from an Aqueous Solution by Pervaporation Using a Commercial Polydimethylsiloxane Membrane." Membranes 12, no. 11 (2022): 1040. http://dx.doi.org/10.3390/membranes12111040.

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A developed polydimethylsiloxane (PDMS) membrane was used to separate soluble benzene compounds (C6H6) from an aqueous solution via a pervaporation (PV) process. This membrane was characterized by scanning electron microscopy (SEM), Fourier-transform infrared (FTIR) spectroscopy, contact angle (CA), and energy-dispersive spectroscopy (EDS). To evaluate the performance of the membrane, the separation factor and permeation flux were estimated in various operating conditions, including the feed temperature, initial benzene concentration, and feed flow rate. The experiments to maximize the separat
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28

Shoppee, CW, and WY Wu. "Photooxidation of Tetrabromofuran in Benzene." Australian Journal of Chemistry 40, no. 6 (1987): 1137. http://dx.doi.org/10.1071/ch9871137.

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Photooxidation in the solid state of tetrabromofuran (1) gave the tetrabromo -γ-lactone (2) (30%), but in benzene solution gave dibromomaleic anhydride (3) (85%). Possible radical chain mechanisms for the transformations (1) → (2) and (1) → (3) are suggested. A molecular orbital discussion attempts to explain how an initial π-π* transition of a C=C bond in (1) leads to a σ C-Br bond fission. Use of e.p.r . to detect radicals in the transformations (1) → (2) and (1) → (3) failed.
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29

Jiang, Xihao, Shuguang Lyu, Meesam Ali, et al. "Enhancement of benzene degradation by persulfate oxidation: synergistic effect by nanoscale zero-valent iron (nZVI) and thermal activation." Water Science and Technology 82, no. 5 (2020): 998–1008. http://dx.doi.org/10.2166/wst.2020.408.

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Abstract The feasibility of an advanced oxidation process based upon sodium persulfate (SPS) activated simultaneously by heat (50 °C) and nanoscale zero-valent iron (nZVI) on benzene removal was investigated. The experimental results strongly showed the synergistic effect of thermal and nZVI activation to SPS and benzene removal was enhanced with the increase of SPS/nZVI/benzene molar ratio. Specifically, 94% of benzene could be removed in 1 hr at 50 °C at the SPS/nZVI/benzene molar ratio of 10/5/1. The radical scavenger tests and electron paramagnetic resonance (EPR) analysis confirmed that S
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30

Figeys, Daniel, Maegorzata Koschmidder, and Robert L. Benoit. "Enthalpies of solution of naphthalene, N,N-dimethyl-1-naphthylamine, and 1,8-bis(dimethylamino)naphthalene in 16 organic solvents." Canadian Journal of Chemistry 70, no. 6 (1992): 1586–89. http://dx.doi.org/10.1139/v92-195.

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The enthalpies of solution of naphthalene, N,N-dimethyl-1-naphthylamine, and 1,8-bis(dimethylamino)naphthalene (proton sponge) were determined at 298.15 K in 16 organic solvents (n-hexane, cyclohexane, carbon tetrachloride, chloroform, 1,2-dichloroethane, benzene, chlorobenzene, dimethyl sulfoxide, N,N-dimethylformamide, ethyl acetate, 1,4-dioxane, anisole, nitrobenzene, benzonitrile, methanol, ethanol). Additional determinations were made with benzene. Useful linear relationships are observed between the molar enthalpies of solution of the four compounds in the solvents. The molar enthalpies
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31

Soldup, Sh N., and Yu F. Patrakov. "Thermal Solution of Kaa-Khem Coal in Supercritical Benzene." Coke and Chemistry 64, no. 1 (2021): 8–11. http://dx.doi.org/10.3103/s1068364x21010063.

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32

Mateus, Margarida P. S., Nuno Galamba, and Benedito J. Costa Cabral. "Structure and electronic properties of a benzene-water solution." Journal of Chemical Physics 136, no. 1 (2012): 014507. http://dx.doi.org/10.1063/1.3671947.

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33

Bagyo, Agustin N. M., Winarti Andayani, and Christina Tri Suhani. "Radiolysis of alkyl benzene sulfonat (ABS) in aqueous solution." Radiation Physics and Chemistry 69, no. 4 (2004): 317–19. http://dx.doi.org/10.1016/j.radphyschem.2003.07.002.

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34

Bensasson, R. V., T. Hill, C. Lambert, E. J. Land, S. Leach, and T. G. Truscott. "Triplet state absorption studies of C70 in benzene solution." Chemical Physics Letters 206, no. 1-4 (1993): 197–202. http://dx.doi.org/10.1016/0009-2614(93)85541-u.

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35

Contreras, Jes�s M., Pompilio Moreno, Mar�a P. Calcagno, Francisco L�pez, and Franco M. Rabagliati. "Epichlorohydrin polymerization using diphenylzinc-cocatalyst systems in benzene solution." Polymer Bulletin 23, no. 5 (1990): 483–89. http://dx.doi.org/10.1007/bf00419966.

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36

Katime, Issa A., Jose R. Quintana, and Luis C. Cesteros. "Interactions of polystyrene with n-alkanes in benzene solution." European Polymer Journal 26, no. 10 (1990): 1121–23. http://dx.doi.org/10.1016/0014-3057(90)90013-t.

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37

Lévesque, Pierre, and LeˆH Dao. "Alkylation of benzene using an aqueous solution of ethanol." Applied Catalysis 53, no. 2-3 (1989): 157–67. http://dx.doi.org/10.1016/s0166-9834(00)80018-4.

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38

Vugar Suleymanova, Leyla, Тurana Аllaz Babayeva, Elmir Magsad Babayev, and Arif Javanshir Afandi. "Catalytic solution for the neutralization of benzene series pollutants." Journal of Young Researcher, no. 1 (2025): 127. https://doi.org/10.59849/2409-4838.2025.1.127.

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39

Aghamaliyev, Z. Z., Mehriban V. Naghiyeva, and Ch K. Rasulov. "Synthesis of 2-Hydroxy-3-(Methyl­cyclo­hexenyl-Isopropyl)-5-Methylbenzyl­amino­ethylnonyl Imidazolines - The Thermostabilizers to Polypropylene." Materials Science Forum 935 (October 2018): 155–59. http://dx.doi.org/10.4028/www.scientific.net/msf.935.155.

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2-hydroxy-3-(methylcyclohexenyl-isopropyl)-5-methylbenzylaminoethylnonylimidazolines were synthesized by the interaction of 2-(methylcyclohexynylisopropyl-4-methylphenols and aminoethylnonylimidazoline. Aminocompounds are purified from cycloalkylphenol by transferring them to hydrochloride salt. Further, aqueous solution of the hydrochloric acid amine salt is treated with a concentrated solution of NH4OH and free aminecompounds are isolated. The resulting amine is separated from water by benzene extraction. After benzene distillation, the residue is undergone to distillation under vacuum. Its
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40

Pleskov, Yuri, Marina Krotova, Valerii Elkin, Valentin Varnin, and Irina Teremetskaya. "Benzene Oxidation on Boron-Doped Diamond Electrode: Electrochemical-Impedance Study of Adsorption Effects." International Journal of Electrochemistry 2012 (2012): 1–9. http://dx.doi.org/10.1155/2012/437063.

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Benzene oxidation at a boron-doped diamond anode in 0.5 M K2SO4aqueous solution is studied by cyclic voltammetry and electrochemical impedance spectroscopy. It is shown by measurements of differential capacitance and anodic current that in the ideal-polarizability potential region benzene either is not adsorbed at the diamond electrode or the benzene adsorption does not affect its capacitance. At more positive potentials, the adsorption of some intermediate of the benzene oxidation occurs at the electrode. The intermediate partially blocks the electrode surface and lowers the anodic current. T
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41

Yuan, Xin Hua, Wen Hua Guo, Yan Lei, et al. "Adsorption of Benzene and Aniline Using a Novel Hypercrosslinked Polymeric Adsorbent Modified by Phenolic Hydroxyl Group." Key Engineering Materials 575-576 (September 2013): 130–34. http://dx.doi.org/10.4028/www.scientific.net/kem.575-576.130.

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Using gelatin as dispersant, liquid paraffin as porogen, novel hypercrosslinked polymeric adsorbents of LM-5 and LM-6 were prepared by post-crosslinking reaction with phenol and 2-naphthol, respectively. Bromoethane was used as crosslinking reagent to substitute poisonous organic compound of chloromethyl methylether. 2-Naphthol was used in the post-crosslinking reaction to enhance phenolic hydroxyl group content. The experiments of selective adsorbing aniline on resins in mixture solution, which consisting of benzene and aniline, show that the adsorption of aniline and benzene on LM-6 in aqueo
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42

Hartshorn, MP, RJ Martyn, WT Robinson, KH Sutton, J. Vaughan, and JM White. "Reactions of 4-Methyl-2,6-diphenylphenol and 4-Nitro-2,6-diphenylphenol with Nitrogen Dioxide." Australian Journal of Chemistry 38, no. 11 (1985): 1613. http://dx.doi.org/10.1071/ch9851613.

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Reaction of 4-methyl-2,6-diphenylphenol (11a) with nitrogen dioxide in benzene solution gives the polysubstituted cyclohex-2-enones (14), (15), (16), (17) and (18) via the 4-nitro dienone (13). The reversibility of the 4-nitro dienone (13)/4-hydroxy dienone (19) conversion under these reaction conditions is demonstrated. Reaction of 4-nitro-2,6-diphenylphenol (11b) with nitrogen dioxide in benzene solution gives the C2-epimeric 2,6-dihydroxy-4,5-dinitrocyclohex-3- enones (32) and (33) via the 6-nitro-6-phenyl dienone (12b). X-ray crystal structure analyses are reported for compounds (14), (15)
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43

Uson-Finkenzeller, M., W. Bublak, B. Huber, G. Müller, and H. Schmidbaur. "Synthese und Kristallstruktur des Bis(benzol)gallium(I)-tetrabromogallat(III)-Dimeren / Synthesis and Crystal Structure of the Bis(benzene)gallium (I) Tetrabromogallate(III) Dimer." Zeitschrift für Naturforschung B 41, no. 3 (1986): 346–50. http://dx.doi.org/10.1515/znb-1986-0309.

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Anhydrous Ga[GaBr4] is readily dissolved in benzene. The resulting solutions show discrete 71Ga NMR signals for Ga(I) und Ga(III) centers. Narrow line-widths of the former indicate a small electric field gradient of the Ga(I) nucleus due to almost spherical shielding by the 4 s2 lone pair of electrons.Crystals obtained from the benzene solution on cooling have the stoichiometry [(C6H6)2Ga · GaBr4]2 ·3 C6H6, and are isomorphous with the analogous chloride compound: a = 9.390(2). b = 10.847(1), c = 13.118(2) Å; α = 85.54(1). β = 102.91(1). γ = 105.62(1)°; triclinic, space group Ρ1̄, Z = 1.The ce
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44

Peglow, Thiago Jacobsen, Marcelo Marques Vieira, Nathalia Batista Padilha, et al. "Pyridine-Based Small-Molecule Fluorescent Probes as Optical Sensors for Benzene and Gasoline Adulteration." Photochem 3, no. 1 (2023): 109–26. http://dx.doi.org/10.3390/photochem3010008.

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Here we present simple fluorophores based on the pyridine core, obtained with straightforward synthetic methodologies. These compounds present in solution absorption maxima in the UV region and fluorescence emission of between 300 and 450 nm, depending on the solvent and chemical structure of the fluorophore. The nature of the solvent was shown to play a fundamental role in their excite-state deactivation, which allowed successful exploration of these compounds as optical sensors for benzene and fuel adulteration in gasoline. In ethanolic solution, upon the addition of benzene, in general the
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45

Staun, Selena L., and Allen G. Oliver. "Crystal structure of benzene-1,3,5-tricarboxylic acid–4-pyridone (1/3)." Acta Crystallographica Section E Crystallographic Communications 71, no. 11 (2015): 1283–86. http://dx.doi.org/10.1107/s2056989015017867.

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Slow co-crystallization of a solution of benzene-1,3,5-tricarboxylic acid with a large excess of 4-hydroxypyridine produces an interpenetrating, three-dimensional, hydrogen-bonded framework consisting of three 4-pyridone and one benzene-1,3,5-tricarboxylic acid molecules, C9H6O6·3C5H5NO. This structure represents an orthorhombic polymorph of the previously reportedC-centered, monoclinic structure [Campos-Gaxiolaet al.(2014).Acta Cryst.E70, o453–o454].
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46

Song, Wen-Dong, De-Yun Ma та Chao-Hua Zhang. "Poly[[diaquabis(μ4-benzene-1,3-dicarboxylato)(μ3-benzene-1,3-dicarboxylato)dierbium(III)] monohydrate]". Acta Crystallographica Section E Structure Reports Online 63, № 11 (2007): m2826—m2827. http://dx.doi.org/10.1107/s1600536807051975.

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The title erbium coordination polymer, {[Er2(C8H4O4)3(H2O)2]·H2O} n , was obtained by the hydrothermal reaction of ErCl3 with benzene-1,3-dicarboxylic acid (1,3-BDC) in alkaline aqueous solution. Each of the two crystallographically independent ErIII ions is seven-coordinate and has a distorted pentagonal–bipyramidal geometry. One Er centre is coordinated by seven O atoms from six 1,3-BDC ligands and the other Er centre is surrounded by five O atoms from five 1,3-BDC ligands and two water molecules. The bridging ligands, which have two different coordination modes, link the metal centres to fo
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47

Kunitake, Masashi, Ryota Tanoue, Rintaro Higuchi, et al. "Monomolecular covalent honeycomb nanosheets produced by surface-mediated polycondensation between 1,3,5-triamino benzene and benzene-1,3,5-tricarbox aldehyde on Au(111)." Nanoscale Advances 2, no. 8 (2020): 3202–8. http://dx.doi.org/10.1039/d0na00180e.

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48

Znak, Z. О., P. R. Gogate, Yu V. Sukhatskyi, R. V. Mnykh, and P. Thanekar. "INTENSIFICATION OF OXIDATIVE DESTRUCTION OF BENZENE BY SODIUM HYPOCHLORITE UNDER THE EFFECT OF ULTRASONIC RADIATION." Chemistry, Technology and Application of Substances 6, no. 2 (2023): 22–28. http://dx.doi.org/10.23939/ctas2023.02.022.

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The process of the interaction of benzene with sodium hypochlorite in a model environment under the action of ultrasonic radiation of different power and under the metered supply of an oxidant solution was investigated. The course of the process was evaluated by the change in the value of the redox potential of the medium over time. By the method of spectrophotometric analysis, it was established that as a result of interaction with sodium hypochlorite in cavitation fields, almost complete mineralization of benzene occurs. It is shown that the oxidative destruction of benzene mainly occurs due
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49

Hahn, Josef. "Zusammensetzung von Rohsulfan, Nachweis der Sulfane H2S9 bis H2S35 Composition of Crude Sulfane Oil, Identification of the Sulfanes H2S9 to H2S35." Zeitschrift für Naturforschung B 40, no. 2 (1985): 263–72. http://dx.doi.org/10.1515/znb-1985-0220.

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In benzene solution the position of the 1H NMR signals of sulfanes, H2Sn, strongly depends on the sulfur chain length and on the sulfane concentration. Under proper conditions all sulfanes in a mixture are characterized by well-resolved NMR signals showing a downfield shift with increasing length of the sulfur chain. The shift differences between the higher homologues ( n &gt; 8 ) remain nearly constant, thus allowing the assignment of the signals up to H2S35 and the determination of the complete sulfane distribution in crude oils. In sulfane mixtures without solvent as well as in CS2 and CCl4
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50

Anjum, Hirra, Mansoor Abdullah Obaid, Muhammad Yasir Shamim, and Thanabalan Murugesan. "Adsorption of Benzene by “Green” functionalization of Montmorillonite." MATEC Web of Conferences 150 (2018): 02001. http://dx.doi.org/10.1051/matecconf/201815002001.

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The capacity of organically modified Montmorillonite (MMT) clay to adsorb nonpolar organic compound (benzene) in an aqueous solution, was investigated under the batch process. MMT was pretreated (centrifuged) and then functionalized with green intercalating agent i.e. 1-hexyl-3-methyl imadazolium chloride [HMim][Cl]. The characterization through Fourir Transoform Infrared Spectroscopy (FTIR), Differential Scanning Calorimeter (DSC) and Field Emission Scanning Electron Microscope (FE-SEM) confirmed the presence of the oxygen containing functional groups, changes in melting point and variation i
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