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Journal articles on the topic 'Bifunctional catalysis'

Author: Grafiati

Published: 4 June 2021

Last updated: 25 July 2025

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1

Dixon, Darren J. "Bifunctional catalysis." Beilstein Journal of Organic Chemistry 12 (May 25, 2016): 1079–80. http://dx.doi.org/10.3762/bjoc.12.102.

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2

Elsby, Matthew R., and R. Tom Baker. "Strategies and mechanisms of metal–ligand cooperativity in first-row transition metal complex catalysts." Chemical Society Reviews 49, no. 24 (2020): 8933–87. http://dx.doi.org/10.1039/d0cs00509f.

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3

Gao, Jing, Dan Ren, Xueyi Guo, Shaik Mohammed Zakeeruddin, and Michael Grätzel. "Sequential catalysis enables enhanced C–C coupling towards multi-carbon alkenes and alcohols in carbon dioxide reduction: a study on bifunctional Cu/Au electrocatalysts." Faraday Discussions 215 (2019): 282–96. http://dx.doi.org/10.1039/c8fd00219c.

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4

Murzin, D. Yu. "Mesolevel Bifunctional Catalysis." Kinetics and Catalysis 61, no. 1 (2020): 80–92. http://dx.doi.org/10.1134/s0023158420010073.

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5

Zhong, Chenglin, Qingwen Zhou, Shengwen Li, et al. "Enhanced synergistic catalysis by a novel triple-phase interface design of NiO/Ru@Ni for the hydrogen evolution reaction." Journal of Materials Chemistry A 7, no. 5 (2019): 2344–50. http://dx.doi.org/10.1039/c8ta11171e.

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High-efficiency synergistic catalysis was realized by a novel triple-phase interface design of the bifunctional catalysts of NiO and Ru nanoparticles, leading to simultaneous enhancement of all elementary steps.

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6

Tan, Kian, Xixi Sun, and Amanda Worthy. "Scaffolding Catalysis: Expanding the Repertoire of Bifunctional Catalysts." Synlett 23, no. 03 (2012): 321–25. http://dx.doi.org/10.1055/s-0031-1290321.

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7

Choudhury, Joyanta, and Shrivats Semwal. "Emergence of Stimuli-Controlled Switchable Bifunctional Catalysts." Synlett 29, no. 02 (2017): 141–47. http://dx.doi.org/10.1055/s-0036-1591741.

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Can a single catalyst perform more than one ‘type’ of reaction? If we consider traditional design of catalysts, then the answer would probably be ‘no’. However, with the advancement of catalyst design concepts, chemists have been able to demonstrate the above task, thanks to ‘stimuli-switchable bifunctional catalysts’. Within the nascent research area of ‘artificial switchable catalysis’, this new type of system offers the potential to achieve complex functions which are otherwise difficult or impossible. This Synpacts article highlights the rise of these new-generation catalysts.1 Introductio

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8

Breslow, Ronald. "Bifunctional binding and catalysis." Supramolecular Chemistry 1, no. 2 (1993): 111–18. http://dx.doi.org/10.1080/10610279308040656.

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9

KIKUCHI, K., R. HANNAK, M. GUO, A. KIRBY, and D. HILVERT. "Toward bifunctional antibody catalysis." Bioorganic & Medicinal Chemistry 14, no. 18 (2006): 6189–96. http://dx.doi.org/10.1016/j.bmc.2006.05.071.

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10

Jahan, Maryam, Satoshi Tominaka та Joel Henzie. "Phase pure α-Mn2O3 prisms and their bifunctional electrocatalytic activity in oxygen evolution and reduction reactions". Dalton Transactions 45, № 46 (2016): 18494–501. http://dx.doi.org/10.1039/c6dt03158g.

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Synthesizing manganese oxide nanomaterials with exact control of shape and phase is difficult, making it challenging to understand the influence of the surface structure on catalysis. We show that phase pure bixbyite crystals can function as bifunctional non-precious metal catalysts for OER and ORR.

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11

Chen, Jianfeng, Xing Gong, Jianyu Li, et al. "Carbonyl catalysis enables a biomimetic asymmetric Mannich reaction." Science 360, no. 6396 (2018): 1438–42. http://dx.doi.org/10.1126/science.aat4210.

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Chiral amines are widely used as catalysts in asymmetric synthesis to activate carbonyl groups for α-functionalization. Carbonyl catalysis reverses that strategy by using a carbonyl group to activate a primary amine. Inspired by biological carbonyl catalysis, which is exemplified by reactions of pyridoxal-dependent enzymes, we developed an N-quaternized pyridoxal catalyst for the asymmetric Mannich reaction of glycinate with aryl N-diphenylphosphinyl imines. The catalyst exhibits high activity and stereoselectivity, likely enabled by enzyme-like cooperative bifunctional activation of the subst

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12

Udaya, V., S. Rao, and Robert J. Gormley. "Bifunctional catalysis in syngas conversions." Catalysis Today 6, no. 3 (1990): 207–34. http://dx.doi.org/10.1016/0920-5861(90)85003-7.

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13

Roessner, Frank, and Ulf Roland. "Hydrogen spillover in bifunctional catalysis." Journal of Molecular Catalysis A: Chemical 112, no. 3 (1996): 401–12. http://dx.doi.org/10.1016/1381-1169(96)00180-x.

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14

Tan, Kian L., Xixi Sun, and Amanda D. Worthy. "ChemInform Abstract: Scaffolding Catalysis: Expanding the Repertoire of Bifunctional Catalysts." ChemInform 43, no. 16 (2012): no. http://dx.doi.org/10.1002/chin.201216240.

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15

Bing, Zezheng, Yuanyuan Gao, Zhongyi Liu, and Qiaoyun Liu. "The Improved Cooperation of Metal–Acid Catalysis Using Encapsulation and P Doping Enhances the Preparation of 3-Acetyl-1-Propanol." Catalysts 15, no. 4 (2025): 390. https://doi.org/10.3390/catal15040390.

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Biomass, as a renewable carbon resource, holds broad application prospects. Among various bio-based platform molecules, furan derivatives play a significant role in green chemical production. Notably, the conversion of 2-methylfuran (2-MF) to 3-acetyl-1-propanol (3-AP) over bifunctional catalysts has attracted considerable interest. In this study, a Pd@PHZSM-5 catalyst was prepared by encapsulating Pd nanoparticles within P-doped HZSM-5 for 2-MF conversion. The encapsulation improved Pd dispersion and metal–acid synergy, enhancing both catalytic activity and 3-AP selectivity. Additionally, pho

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16

Wu, Jia-Hong, Jianke Pan, and Tianli Wang. "Dipeptide-Based Phosphonium Salt Catalysis: Application to Enantioselective Synthesis of Fused Tri- and Tetrasubstituted Aziridines." Synlett 30, no. 19 (2019): 2101–6. http://dx.doi.org/10.1055/s-0039-1690192.

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Over the past decades, phase-transfer catalysis (PTC), generally based on numerous chiral quaternary ammonium salts, has been recognized as a powerful and versatile tool for organic synthesis in both industry and academia. In sharp contrast, PTC involving chiral phosphonium salts as the catalysts is insufficiently developed. Recently, our group realized the first enantioselective aza-Darzens reaction for preparing tri- and tetrasubstituted aziridine derivatives under bifunctional phosphonium salt catalysis. This article briefly discusses the recent development in asymmetric reactions (mainly i

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17

Cheng, Hengxu, Haojie Sun, Meizhen Dai, et al. "Optimizing the Ratio of Metallic and Single-Atom Co in CoNC via Annealing Temperature Modulation for Enhanced Bifunctional Oxygen Evolution Reaction/Oxygen Reduction Reaction Activity." Molecules 29, no. 23 (2024): 5721. https://doi.org/10.3390/molecules29235721.

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Developing low-cost, efficient alternatives to catalysts for bifunctional oxygen electrode catalysis in the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) is critical for advancing the practical applications of alkaline fuel cells. In this study, Co particles and single atoms co-loaded on nitrogen-doped carbon (CoNC) were synthesized via pyrolysis of a C3N4 and cobalt nitrate mixture at varying temperatures (900, 950, and 1000 °C). The pyrolysis temperature and precursor ratios were found to significantly influence the ORR/OER performance of the resulting catalysts. The op

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18

Artús Suàrez, Lluís, David Balcells, and Ainara Nova. "Computational Studies on the Mechanisms for Deaminative Amide Hydrogenation by Homogeneous Bifunctional Catalysts." Topics in Catalysis 65, no. 1-4 (2021): 82–95. http://dx.doi.org/10.1007/s11244-021-01542-w.

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AbstractThe deaminative hydrogenation of amides is one of the most convenient pathways for the synthesis of amines and alcohols. The ideal source of reducing equivalents for this reaction is molecular hydrogen, though, in practice, this approach requires high pressures and temperatures, with many catalysts achieving only small turnover numbers and frequencies. Nonetheless, during the last ten years, this field has made major advances towards larger turnovers under milder conditions thanks to the development of bifunctional catalysts. These systems promote the heterolytic cleavage of hydrogen i

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19

TANABE, K. "ChemInform Abstract: Acid-Base Bifunctional Catalysis." ChemInform 26, no. 31 (2010): no. http://dx.doi.org/10.1002/chin.199531290.

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20

Andersen, Mie, Andrew J. Medford, Jens K. Nørskov, and Karsten Reuter. "Analyzing the Case for Bifunctional Catalysis." Angewandte Chemie International Edition 55, no. 17 (2016): 5210–14. http://dx.doi.org/10.1002/anie.201601049.

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21

Andersen, Mie, Andrew J. Medford, Jens K. Nørskov, and Karsten Reuter. "Analyzing the Case for Bifunctional Catalysis." Angewandte Chemie 128, no. 17 (2016): 5296–300. http://dx.doi.org/10.1002/ange.201601049.

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22

Carlier, Samuel, Walid Baaziz, Ovidiu Ersen, and Sophie Hermans. "Synergy between Sulfonic Functions and Ru Nanoparticles Supported on Activated Carbon for the Valorization of Cellulose into Sorbitol." Catalysts 13, no. 6 (2023): 963. http://dx.doi.org/10.3390/catal13060963.

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The production of sorbitol from biomass, and especially from its cellulosic component, has been studied as a sustainable method for producing platform molecules. Because it requires two steps, namely, hydrolysis and hydrogenation, bifunctional materials are required as catalysts for this transformation. This study reports a bifunctional catalyst composed of sulfonic functions grafted onto a carbon support for the hydrolysis step and RuO2 nanoparticles for the hydrogenation step. As sulfur can easily poison Ru, synthetic optimization is necessary to obtain an efficient bifunctional catalyst tha

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23

Moczulski, Marek, Piotr Drelich, and Łukasz Albrecht. "Bifunctional catalysis in the stereocontrolled synthesis of tetrahydro-1,2-oxazines." Organic & Biomolecular Chemistry 16, no. 3 (2018): 376–79. http://dx.doi.org/10.1039/c7ob02894f.

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24

Zhang, Wenfeng, Hanying Gu, Zhen Li, et al. "General acid and base bifunctional graphene oxide for cooperative catalysis." J. Mater. Chem. A 2, no. 26 (2014): 10239–43. http://dx.doi.org/10.1039/c4ta01446d.

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25

Kano, Taichi, and Keiji Maruoka. "Design of chiral bifunctional secondary amine catalysts for asymmetric enamine catalysis." Chemical Communications, no. 43 (2008): 5465. http://dx.doi.org/10.1039/b809301f.

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26

Zhang, Rui, Han Wu, Jiantao Li, et al. "Waste Incineration Fly Ash-Based Bifunctional Catalyst for Upgrading Glucose to Levulinic Acid." Catalysts 15, no. 4 (2025): 402. https://doi.org/10.3390/catal15040402.

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The safe and resource-efficient utilization of waste incineration fly ash (WIFA) has emerged as a pressing challenge in solid waste management. In this work, WIFA was used to prepare a bifunctional catalyst (Metalsx/4@WIFA-S) for the production of levulinic acid (LA) from glucose. The yield of LA was 42.3% with water as the solvent. Moreover, adding 20% γ-valerolactone (GVL) to the system increased the yield to 50.7%. Reaction kinetics and molecular dynamics simulations were applied to elucidate the mechanism by which the solvent system enhanced the catalytic performance of the Metalsx/4@WIFA-

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27

Deng, Jingyuan, Manussada Ratanasak, Yuma Sako, et al. "Aluminum porphyrins with quaternary ammonium halides as catalysts for copolymerization of cyclohexene oxide and CO2: metal–ligand cooperative catalysis." Chemical Science 11, no. 22 (2020): 5669–75. http://dx.doi.org/10.1039/d0sc01609h.

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28

Liu, Chang, and Zhongwen Liu. "Perspective on CO2 Hydrogenation for Dimethyl Ether Economy." Catalysts 12, no. 11 (2022): 1375. http://dx.doi.org/10.3390/catal12111375.

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The CO2 hydrogenation to dimethyl ether (DME) is a potentially promising process for efficiently utilizing CO2 as a renewable and cheap carbon resource. Currently, the one-step heterogeneous catalytic conversion of CO2 to value-added chemicals exhibits higher efficiency than photocatalytic or electrocatalytic routes. However, typical catalysts for the one-step CO2 hydrogenation to DME still suffer from the deficient space–time yield and stability in industrial demonstrations/applications. In this perspective, the recent development of the one-step CO2 hydrogenation to DME is focused on differe

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29

Hu, Hao, Yuhua Xie, Farhad M. D. Kazim, et al. "Synergetic FeCo nanorods embedded in nitrogen-doped carbon nanotubes with abundant metal–NCNT heterointerfaces as efficient air electrocatalysts for rechargeable zinc–air batteries." Sustainable Energy & Fuels 4, no. 10 (2020): 5188–94. http://dx.doi.org/10.1039/d0se01023e.

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30

Zhang, Jing, Yong S. Choi, and Brent H. Shanks. "Catalytic deoxygenation during cellulose fast pyrolysis using acid–base bifunctional catalysis." Catalysis Science & Technology 6, no. 20 (2016): 7468–76. http://dx.doi.org/10.1039/c6cy01307d.

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31

Javed, Fahed, Muhammad Rizwan, Maryam Asif, et al. "Intensification of Biodiesel Processing from Waste Cooking Oil, Exploiting Cooperative Microbubble and Bifunctional Metallic Heterogeneous Catalysis." Bioengineering 9, no. 10 (2022): 533. http://dx.doi.org/10.3390/bioengineering9100533.

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Waste resources are an attractive option for economical the production of biodiesel; however, oil derived from waste resource contains free fatty acids (FFA). The concentration of FFAs must be reduced to below 1 wt.% before it can be converted to biodiesel using transesterification. FFAs are converted to fatty acid methyl esters (FAMEs) using acid catalysis, which is the rate-limiting reaction (~4000 times slower than transesterification), with a low conversion as well, in the over biodiesel production process. The study is focused on synthesizing and using a bifunctional catalyst (7% Sr/ZrO2)

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32

Zhou, Li, Datai Liu, Haiyi Lan, et al. "The origin of different driving forces between O–H/N–H functional groups in metal ligand cooperation: mechanistic insight into Mn(i) catalysed transfer hydrogenation." Catalysis Science & Technology 10, no. 1 (2020): 169–79. http://dx.doi.org/10.1039/c9cy02112d.

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33

Wang, Yong, Xin Guan, Fangyan Chen, et al. "Noncovalent immobilization of pyrene-terminated hyperbranched triazole-based polymeric ionic liquid onto graphene for highly active and recyclable catalysis of CO2/epoxide cycloaddition." Catalysis Science & Technology 7, no. 18 (2017): 4173–81. http://dx.doi.org/10.1039/c7cy01259d.

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34

Vera, Elizabeth, Brenda Alcántar-Vázquez, Yuhua Duan, and Heriberto Pfeiffer. "Bifunctional application of sodium cobaltate as a catalyst and captor through CO oxidation and subsequent CO2 chemisorption processes." RSC Advances 6, no. 3 (2016): 2162–70. http://dx.doi.org/10.1039/c5ra22749f.

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35

McGuirk, C. Michael, Jose Mendez-Arroyo, Andrea I. d'Aquino, Charlotte L. Stern, Yuan Liu, and Chad A. Mirkin. "A concerted two-prong approach to the in situ allosteric regulation of bifunctional catalysis." Chemical Science 7, no. 11 (2016): 6674–83. http://dx.doi.org/10.1039/c6sc01454b.

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36

Li, Yuxuan, Xingbo Ge, Leidanyang Wang, Jia Liu, Yong Wang, and Lanxiang Feng. "A free standing porous Co/Mo architecture as a robust bifunctional catalyst toward water splitting." RSC Advances 7, no. 19 (2017): 11568–71. http://dx.doi.org/10.1039/c7ra00007c.

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37

Lu, Linfang, Zhiqiang Wang, Shihui Zou, et al. "Ligand-mediated bifunctional catalysis for enhanced oxygen reduction and methanol oxidation tolerance in fuel cells." Journal of Materials Chemistry A 6, no. 39 (2018): 18884–90. http://dx.doi.org/10.1039/c8ta06071a.

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38

Pandey, Jay, Bin Hua, Wesley Ng, et al. "Developing hierarchically porous MnOx/NC hybrid nanorods for oxygen reduction and evolution catalysis." Green Chemistry 19, no. 12 (2017): 2793–97. http://dx.doi.org/10.1039/c7gc00147a.

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39

Noyori, Ryoji, Christian A. Sandoval, Kilian Muñiz, and Takeshi Ohkuma. "Metal–ligand bifunctional catalysis for asymmetric hydrogenation." Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 363, no. 1829 (2005): 901–12. http://dx.doi.org/10.1098/rsta.2004.1536.

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Chiral diphosphine/1,2-diamine–Ru(II) complexes catalyse the rapid, productive and enantioselective hydrogenation of simple ketones. The carbonyl-selective hydrogenation takes place via a non-classical metal–ligand bifunctional mechanism. The reduction of the C=O function occurs in the outer coordination sphere of an 18e trans -RuH 2 (diphosphine)(diamine) complex without interaction between the unsaturated moiety and the metallic centre. The Ru atom donates a hydride and the NH 2 ligand delivers a proton through a pericyclic six-membered transition state, directly giving an alcoholic product

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40

Li, Yang, Qingshan Zhao, Junyi Ji, Guoliang Zhang, Fengbao Zhang, and Xiaobin Fan. "Cooperative catalysis by acid–base bifunctional graphene." RSC Advances 3, no. 33 (2013): 13655. http://dx.doi.org/10.1039/c3ra41970c.

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41

Guisnet, Michel. "“Ideal” bifunctional catalysis over Pt-acid zeolites." Catalysis Today 218-219 (December 2013): 123–34. http://dx.doi.org/10.1016/j.cattod.2013.04.028.

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42

Setoyama, Tohru. "Acid–base bifunctional catalysis: An industrial viewpoint." Catalysis Today 116, no. 2 (2006): 250–62. http://dx.doi.org/10.1016/j.cattod.2006.01.031.

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43

Herrmann, J. M. "From catalysis by metals to bifunctional photocatalysis." Topics in Catalysis 39, no. 1-2 (2006): 3–10. http://dx.doi.org/10.1007/s11244-006-0032-7.

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44

Morris, Robert H. "Iron Group Hydrides in Noyori Bifunctional Catalysis." Chemical Record 16, no. 6 (2016): 2644–58. http://dx.doi.org/10.1002/tcr.201600080.

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45

Leeuwen, Piet W. N. M., Israel Cano, and Zoraida Freixa. "Secondary Phosphine Oxides: Bifunctional Ligands in Catalysis." ChemCatChem 12, no. 16 (2020): 3982–94. http://dx.doi.org/10.1002/cctc.202000493.

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46

Liebig, Timo, Michael Abbass, and Ulrich Lüning. "Concave Pyridines for Bifunctional Acid–Base Catalysis." European Journal of Organic Chemistry 2007, no. 6 (2007): 972–80. http://dx.doi.org/10.1002/ejoc.200600842.

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47

Sun, Jia, Ning Wang, Zhaozhong Qiu, Lixin Xing, and Lei Du. "Recent Progress of Non-Noble Metal Catalysts for Oxygen Electrode in Zn-Air Batteries: A Mini Review." Catalysts 12, no. 8 (2022): 843. http://dx.doi.org/10.3390/catal12080843.

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Oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) play crucial roles in energy conversion and storage devices. Particularly, the bifunctional ORR/OER catalysts are core components in rechargeable metal–air batteries, which have shown great promise in achieving "carbon emissions peak and carbon neutrality" goals. However, the sluggish ORR and OER kinetics at the oxygen cathode significantly hinder the performance of metal–air batteries. Although noble metal-based catalysts have been widely employed in accelerating the kinetics and improving the bifunctionality, their scarcity

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48

Zhang, Wen-Hui, Yan-you Zhou, Xue-Wen He, Yi Gong, Xiong-Li Liu, and Ying Zhou. "An asymmetric iminium ion catalysis-enabled cascade cycloaddition reaction of chromone-oxindole synthons with enals: construction of a spirooxindole–hexahydroxanthone framework." Organic & Biomolecular Chemistry 17, no. 36 (2019): 8369–73. http://dx.doi.org/10.1039/c9ob01670h.

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49

Zhou, Wei, Kang Cheng, Jincan Kang, et al. "New horizon in C1 chemistry: breaking the selectivity limitation in transformation of syngas and hydrogenation of CO2 into hydrocarbon chemicals and fuels." Chemical Society Reviews 48, no. 12 (2019): 3193–228. http://dx.doi.org/10.1039/c8cs00502h.

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50

Al-Naji, Majd, Joost Van Aelst, Yuhe Liao та ін. "Correction: Pentanoic acid from γ-valerolactone and formic acid using bifunctional catalysis". Green Chemistry 22, № 2 (2020): 564. http://dx.doi.org/10.1039/c9gc90122a.

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