Dissertations / Theses on the topic 'Blender Studios'
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Deb, Nabankur. "Morphological studies in polymer-fullerene blends." Diss., Georgia Institute of Technology, 2015. http://hdl.handle.net/1853/54381.
Full textKays, Cory Asher. "Multidisciplinary methods for performing trade studies on blended wing body aircraft." Thesis, Massachusetts Institute of Technology, 2013. http://hdl.handle.net/1721.1/82485.
Full textThis electronic version was submitted and approved by the author's academic department as part of an electronic thesis pilot project. The certified thesis is available in the Institute Archives and Special Collections.
Cataloged from department-submitted PDF version of thesis
Includes bibliographical references (p. 99-102).
Multidisciplinary design optimization (MDO) is becoming an essential tool for the design of engineering systems due to the inherent coupling between discipline analyses and the increasing complexity of such systems. An important component of MDO is effective exploration of the design space since this is often a key driver in finding characteristics of systems which perform well. However, many design space exploration techniques scale poorly with the number of design variables and, moreover, a large-dimensional design space can be prohibitive to designer manipulation. This research addresses complexity management in trade-space exploration of multidisciplinary systems, with a focus on the conceptual design of Blended Wing Body (BWB) aircraft. The objectives of this thesis are twofold. The first objective is to create a multidisciplinary tool for the design of BWB aircraft and to demonstrate the performance of the tool on several example trade studies. The second objective is to develop a methodology for reducing the dimension of the design space using designer-chosen partitionings of the design variables describing the system. The first half of this thesis describes the development of the BWB design tool and demonstrates its performance via a comparison to existing methods for the conceptual design of an existing BWB configuration. The BWB design tool is then demonstrated using two example design space trades with respect to planform geometry and cabin bay arrangement. Results show that the BWB design tool provides sufficient fidelity compared to existing BWB analyses, while accurately predicting trends in system performance. The second half of this thesis develops a bi-level methodology for reducing the dimension of the design space for a trade space exploration problem. In this methodology, the designer partitions the design vector into an upper- and lower-level set, wherein the lower-level variables essentially serve as parameters, in which their values are chosen via an optimization with respect to some lower-level objective. This reduces the dimension of the design space, thereby allowing a more manageable space for designer interaction, while subsequently ensuring that the lower-level variables are set to "good" values relative to the lower-level objective. The bi-level method is demonstrated on three test problems, each involving an exploration over BWB planform geometries. Results show that the method constructs surrogate models in which the sampled configurations have a reduction in the system objective by up to 4 % relative to surrogates constructed using a standard exploration. Furthermore, the problems highlight the potential for the framework to reduce the dimension of the design space such that the full space can be visualized.
by Cory Asher Kays.
S.M.
Chim, Tat-mei Alice, and 詹達美. "An instructional design theory guide for blended learning courses." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2004. http://hub.hku.hk/bib/B30406213.
Full textSaghafi, Mahmoud Reza. "A holistic blended design studio model: Exploring and expanding learning opportunities." Thesis, Queensland University of Technology, 2012. https://eprints.qut.edu.au/180769/3/Mahmoud_Saghafi_Thesis.pdf.
Full textMcNally, John Anthony. "Studies on blends of polymers with bitumen." Thesis, Queen's University Belfast, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.318801.
Full textFernandez, Fernandez Maria Luisa. "Mixing and demixing studies in polymer blends." Thesis, Imperial College London, 1989. http://hdl.handle.net/10044/1/47432.
Full textSham, C. K. "Studies of poly (vinyl chloride)/polyacrylate blends." Thesis, Imperial College London, 1985. http://hdl.handle.net/10044/1/37850.
Full textIzumitani, Tatsuo. "Studies of Spinodal Decomposition of Polymer Blends." 京都大学 (Kyoto University), 2002. http://hdl.handle.net/2433/149438.
Full textWu, Aiping. "Controlled Oxidation Studies of Coal/Refuse Fuel Blends." TopSCHOLAR®, 1994. http://digitalcommons.wku.edu/theses/956.
Full textCamiruaga, Elisa M. Elexpuru. "Miscibility studies of polymer blends involving acrylonitrile copolymers." Thesis, Heriot-Watt University, 1990. http://hdl.handle.net/10399/883.
Full textWatson, Linda M. "Miscibility studies in statistical copolymer and terpolymer blends." Thesis, Heriot-Watt University, 1994. http://hdl.handle.net/10399/1393.
Full textOliver, Sarah Louise. "Solid-state NMR studies of compatibilised polymer blends." Thesis, University of Nottingham, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.285638.
Full textLängin, Dirk. "Blended learning in der forstlichen Hochschullehre eine Untersuchung im südlichen Afrika." Freiburg i. Br. Rombach, 2005. http://deposit.d-nb.de/cgi-bin/dokserv?idn=979174457.
Full textBjörström, Cecilia. "Morphology studies of thin films of polyfluorene: fullerene blends." Licentiate thesis, Karlstad University, Division for Engineering Sciences, Physics and Mathematics, 2005. http://urn.kb.se/resolve?urn=urn:nbn:se:kau:diva-2361.
Full textThe formation of thin films of polymer blends by spin-coating from solution is characterised by rapid solvent quenching, a process that results in non-equilibrium morphologies. Thin films of conjugated polymer blends are used as the active material in polymer solar cells, in which the morphology may have drastic effects on device performance.
In this thesis results from morphology studies are presented for spin-coated thin films of polyfluorenes and co-polymers of polyfluorene blended with the fullerene derivative [6,6]-phenyl-C61-butyric acid methyl ester (PCBM). The surface morphology was investigated by atomic force microscopy (AFM) and was found to depend on the blend ratio as well as the chemical structure of the blend components. The spin speed, which determines the thickness of the spin-coated thin films, was also found to influence the morphology. Secondary ion mass spectrometry (SIMS) was used for depth profiling of the chemical composition in thin films of poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-5,5-(4´,7´-di-2-thienyl-2´,1´,3´-benzothiadiazole)] (LBPF5) blended with PCBM. The films were found to be vertically phase separated with a four-fold multilayered structure.
De, Luca Daniele. "Cortometraggio 3D per il progetto CINECA MDC - Museo della Città di Bologna Modellazione, rendering e studio delle fonti storiche." Master's thesis, Alma Mater Studiorum - Università di Bologna, 2011. http://amslaurea.unibo.it/1907/.
Full textHalverson, Taylor David. "Improving blended learning environments for biblical studies applications of the "innovations in distance education" theory /." [Bloomington, Ind.] : Indiana University, 2006. http://gateway.proquest.com/openurl?url_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:dissertation&res_dat=xri:pqdiss&rft_dat=xri:pqdiss:3238499.
Full text"Title from dissertation home page (viewed July 12, 2007)." Source: Dissertation Abstracts International, Volume: 67-10, Section: A, page: 3695. Adviser: Charles M. Reigeluth.
Okerberg, Brian. "Morphological Studies of Crystallization in Thin Films of PEO/PMMA Blends." Diss., Virginia Tech, 2005. http://hdl.handle.net/10919/29213.
Full textPh. D.
Adedeji, Adeyinka. "Morphological studies of homopolymer/block copolymer blends with exothermic interfacial mixing." Case Western Reserve University School of Graduate Studies / OhioLINK, 1995. http://rave.ohiolink.edu/etdc/view?acc_num=case1058451685.
Full textSohal, Nisha. "Solid state nuclear magnetic resonance studies of a polymer blend." Thesis, Imperial College London, 2009. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.501767.
Full textHodgson, Andrew William. "Solid-state nuclear magnetic resonance studies of a polymer blend." Thesis, Imperial College London, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.401862.
Full textDyer-Smith, Clare. "Spectroscopic studies of excited states in polyfluorene:small molecule blend films." Thesis, Imperial College London, 2011. http://hdl.handle.net/10044/1/7128.
Full textLucchi, Asia. "Studio e Sperimentazione di Chatbot Generative allo Stato dell’Arte con Applicazione alla Pandemia da Covid19." Bachelor's thesis, Alma Mater Studiorum - Università di Bologna, 2020. http://amslaurea.unibo.it/21611/.
Full textTakenaka, Mikihito. "Scattering Studies of Self-Assembling Processes of Polymer Blends in Spinodal Decomposition." Kyoto University, 1993. http://hdl.handle.net/2433/74617.
Full textO'Neill, Jason Michael. "Multidimensional Mass Spectrometry Studies on Amphiphilic Polymer Blends and Cross-Linked Networks." University of Akron / OhioLINK, 2021. http://rave.ohiolink.edu/etdc/view?acc_num=akron1624375174939496.
Full textFavi, Pelagie Marlene. "Electrospun Blends of Polydioxanone and Poly(lactic Acid): Mechanical, Morphological, and Permeability Studies." VCU Scholars Compass, 2007. http://hdl.handle.net/10156/1271.
Full textSweed, Muhamed. "Co-crystallization in polyolefin blends studied by various crystallization analysis techniques." Thesis, Link to the online version, 2006. http://hdl.handle.net/10019.1/2733.
Full textEnarsson, Anna. "New Blends in the English Language." Thesis, Karlstad University, Faculty of Arts and Education, 2007. http://urn.kb.se/resolve?urn=urn:nbn:se:kau:diva-674.
Full textTitel: New Blends in the English Language
Författare: Anna Enarsson
Antal sidor: 29
Abstract: The aim of this essay was to identify new blends that have entered the English language. Firstly six different word-formation processes, including blending, was described. Those were compounding, clipping, backformation, acronyming, derivation and blending. The investigation was done by using a list of blends from Wikipedia. The words were looked up in the Longman dictionary of 2005 and in a dictionary online. A google search and a corpus investigation were also conducted. The investigation suggested that most of the blends were made by clipping and the second most common form was clipping and overlapping. Blends with only overlapping was unusual and accounted for only three percent. The investigation also suggested that the most common way to create blends by clipping was to use the first part of the first word and the last part of the second word. The blends were not only investigated according to their structure but also according to the domains they occur in. This part of the investigation suggested that the blends were most frequent in the technical domain, but also in the domain of society
Sugimura, Kazuki. "Comparative Studies on Miscibility and Intermolecular Interaction for Cellulose Ester Blends with Vinyl Copolymers." Kyoto University, 2015. http://hdl.handle.net/2433/200460.
Full text0048
新制・課程博士
博士(農学)
甲第19197号
農博第2136号
新制||農||1034(附属図書館)
学位論文||H27||N4943(農学部図書室)
32189
京都大学大学院農学研究科森林科学専攻
(主査)教授 西尾 嘉之, 教授 木村 恒久, 教授 髙野 俊幸
学位規則第4条第1項該当
Faist, Mark Anton. "Spectroscopic studies of the charge transfer state and device performance of polymer:fullerene photovoltaic blends." Thesis, Imperial College London, 2012. http://hdl.handle.net/10044/1/11191.
Full textBenson, Jessica J. "Spectroscopic studies of organic donor-acceptor blend films for solar cell applications." Thesis, Imperial College London, 2007. http://hdl.handle.net/10044/1/11386.
Full textJannah, Maram Mohammed H. "Islamic studies teachers' perceptions of using a blended approach for teaching Islamic education modules in primary schools in Saudi Arabia." Thesis, Durham University, 2018. http://etheses.dur.ac.uk/12598/.
Full textDeranger, Brant. "Blurring the Lines Between Instructor-Led and Online Learning: an Evaluation of an Online Composition Curriculum on the Bleeding Edge." Thesis, University of North Texas, 2007. https://digital.library.unt.edu/ark:/67531/metadc3980/.
Full textBaena, Johanna. "PROCESSING AND KINETIC STUDIES OF THE REACTIVE BLENDS OF POLY(VINYL CHLORIDE) AND THERMOPLASTIC POLYURETHANES." University of Akron / OhioLINK, 2006. http://rave.ohiolink.edu/etdc/view?acc_num=akron1163727625.
Full textKummer, Christian, Romy Wolff, Claudia Lieske, and Eric Schoop. "Untersuchung der Wirksamkeit einer Lernhandlung in einem Blended-Learning-Arrangement in der universitären Ausbildung." Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2012. http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-101253.
Full textVorobyova, Olga. "Fluorescence studies of polymer association in water and droplet coalescence in polymer blend melts." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 2000. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape3/PQDD_0018/NQ53685.pdf.
Full textFok, Ping Sum (Teresa). "Understanding Stage Management in the 21st century in Australia: A Preliminary Survey." Thesis, Edith Cowan University, Research Online, Perth, Western Australia, 2021. https://ro.ecu.edu.au/theses/2419.
Full textKo, Chan Uk. "Studies of blends containing liquid crystalline polymers with PET and related investigations of hydroquinone/biphenol polysulfone systems." Thesis, Virginia Polytechnic Institute and State University, 1985. http://hdl.handle.net/10919/76036.
Full textMaster of Science
Roberge, Timothy Michael. "Novel blends of sulfur-tolerant water-gas shift catalysts for biofuel applications." Scholar Commons, 2012. http://scholarcommons.usf.edu/etd/4215.
Full textBridgman, Corrie. "Biodiversity and the South African wine sector: a successful blend?" Thesis, Stellenbosch : University of Stellenbosch, 2009. http://hdl.handle.net/10019.1/2789.
Full textThe acceleration of biodiversity loss is understood to threaten the ecosystems upon which life on earth depends. Existing conservation approaches have proved insufficient to stem global biodiversity losses. Mounting evidence indicates that responsible biodiversity conservation requires an integration of ecology with economics. Accordingly, contemporary conservation interventions incorporate a concept that ecosystems and biodiversity can be used and also conserved. In South Africa, such interventions can be appropriately applied in the Cape Floristic Region (CFR), an area containing severely endangered biodiversity where land use and conservation goals rarely mesh. More than 80% of land in the CFR is privately owned, with large tracts transformed for viticulture. Conservation challenges thus include the reconciliation of wine production needs with biodiversity protection necessities. This thesis comprises a case study of the Biodiversity and Wine Initiative, an organisation that simultaneously promotes biodiversity conservation in the South African wine sector, by a process of mainstreaming within an viticultural context. The overall study aim was to improve understanding of the BWI as a mainstreaming initiative. Specifically, the area of inquiry is an investigation into how effectively the BWI has protected biodiversity in the CFR between 2005 and 2008. Individual aims were to investigate reductions in threat to biodiversity in the CFR; to assess farmer adoption levels of BWI strategy; and to formulate a sustainability appraisal of the Biodiversity and Wine Initiative. A strategic triangulation of methods was employed. Stakeholder interviews were conducted to probe adoption levels and opinions of BWI strategy. Case studies of two BWI champion estates provided data on best practice. Towards a critical appraisal of sustainability, an assessment was made of the BWI as a functioning mainstreaming model, which included case studies of two model farms.
Nilsson, Anna-Lena. "Studies in Swedish sign language reference, real space blending, and interpretation /." Doctoral thesis, Stockholm : Department of Linguistics, Stockholm University, 2010. http://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-37026.
Full textOghide, Godwin O. "Miscibility studies of poly (methyl acrylate) poly (vinyl acetate) and poly (vinyl acetate)/ poly (vinylidene fluoride) blends using differential scanning calorimetry and fourier transform infra red spectroscopy." DigitalCommons@Robert W. Woodruff Library, Atlanta University Center, 1985. http://digitalcommons.auctr.edu/dissertations/3294.
Full textBenson, Kaitlyn Suzanne. "Assessment of Soil Quality Parameters of Long-Term Biosolids Amended Urban Soils and Dredge Blends." The Ohio State University, 2017. http://rave.ohiolink.edu/etdc/view?acc_num=osu1492601621133386.
Full textDoyle, Adrian. "Using Blender Studios as a Point of Reference to Examine the Intersection of Fine Art and Street Art." Thesis, 2021. https://vuir.vu.edu.au/43499/.
Full textBerriman, Garth. "Morphological studies of organic photovoltaic blends." Thesis, 2015. http://hdl.handle.net/1959.13/1059812.
Full textThe main focus of this thesis has been to develop techniques for probing the active layer morphology of organic photovoltaic devices, as well as to develop a model to explain the phase separation observed in blended film devices containing PCBM. The first chapter describes the use of a near-field scanning optical microscope (NSOM) to generate and map local photocurrents in phase segregated P3HT:PCBM organic photovoltaic devices. Photocurrents are generated at three wavelengths, which are then used to determine the composition of the film based on the absorption coefficient for each wavelength in the pure materials. Then, based on the composition profile (which is corroborated with the use of scanning transmission X-ray microscopy (STXM)), it is shown that the absorption coefficients for the pure materials are insufficient to explain the photocurrent generated by 633 nm light. The difference is attributed to the creation of interface states upon blending of the P3HT and PCBM. The second experimental chapter describes the development of a new characterisation technique based on the near-field scanning photocurrent mapping used in the first chapter. The goal was to develop a technique capable of generating photocurrent maps at multiple wavelengths simultaneously, rather than sequentially. By simultaneously measuring the photocurrent generated by each wavelength, the technique is able to overcome several shortcomings associated with sequentially scanning the device. Two approaches are trialled, the first being a method which involves sequentially exposing the device to each wavelength before moving the probe to the next point in the scan. An electronic shutter system is used to control which wavelength is transmitted through the tip. This simultaneous-sequential multi-wavelength NSPM technique suffered from several technical flaws which prevented routine use of the instrument. The second approach taken to achieve simultaneous photocurrent maps at multiple wavelengths is to use a frequency division multiplexing technique. Each wavelength is modulated, using an optical beam chopper, at a unique frequency which in turn modulates the photocurrent at the optical modulation frequency. The current generated by each wavelength is then obtained by demodulating the photocurrent signal based on the modulation frequencies. The third experimental chapter describes the development of a technique capable of generating composition and thickness maps of thin organic films. The technique works by focussing several wavelengths of light onto a film and measuring the intensity of the transmitted light at each wavelength. The intensity of the transmitted light is used to determine the optical absorption of each wavelength. Each wavelength is modulated at its own unique frequency, allowing the intensity of each wavelength to be recovered using the Welch technique for estimating the periodogram. This frequency division multiplexing technique allows for the simultaneous measurement of multiple wavelengths, and shows a reduction in the variance of the measured light intensity over the technique used in Chapter 4. The instrument is demonstrated on an annealed P3HT:PCBM film, as these results can readily be compared to composition maps generated using scanning transmission X-ray microscopy (STXM). The composition maps compare favourably with the published STXM results and the blend ratio used while the thickness maps are self-consistent and in agreement with the measured film thickness. The final experimental chapter is focussed on gaining an understanding of the PCBM phase which forms upon the thermal annealing of P3HT:PCBM bulk heterojunction devices. A variety of theoretical, experimental and modelling results are combined to create a model which describes the formation of PCBM aggregates. AFM, XRD and SEM are combined to show that the aggregates are actually porous and composed of elliptical nano-crystallites of PCBM and are not a dense single crystal as is sometimes assumed. The diffusion constant of PCBM is measured and used to show that the dominant form of PCBM diffusion within BHJ devices is not molecular diffusion but in fact involves the diffusion of these elliptical nano-crystallites. The nano-crystallite diffusion which takes place in BHJ devices is used to reconcile disparate values for the diffusion constant in the literature. Finally, a basic diffusion model is used to explain the shape of PCBM aggregates.
Reddy, Prasad A. "Studies In Low Density Polyethylene-Starch Blends." Thesis, 2004. http://etd.iisc.ernet.in/handle/2005/1153.
Full textTeng, Chih-Chun, and 鄧至均. "Studies of Poly (vinyl chloride) and Polyethylene Blended with Micro/Nano Particles." Thesis, 2004. http://ndltd.ncl.edu.tw/handle/02188074778699234299.
Full text南台科技大學
化學工程系
92
This study contains three sections. The first section is study of rigid poly (vinyl chloride) compounds blending with clay. The second section is study of rigid poly (vinyl chloride) compounds blending with micro/nano-CaCO3. The third section is study of high density polyethylene blending with micro/nano-CaCO3. In the first section, PVC/clay nanocomposites were successfully prepared by a Haake torque rheomix and examined by XRD and TEM. The fusion properties showed that the fusion time and the fusion temperature were increased, but the fusion torque was decreased, with the content of organic clay was increased. The opposite effect was occurred when the untreated clay was used. From the thermal results, the glass transition temperature of nanocomposite was increased and the thermal stability was decreased. From the mechanical property analyses, it showed that the clay improved the yield strength and elongation of two kinds of PVC/clay nanocomposites. The Young’s modulus of PVC/untreated-clay nanocomposite was increased. On the other hand, the organic clay had the opposite effects due to the organic chemical between the silicate layers and resulted in the Young’s modulus decreasing. In the second section, the fusion properties showed that the loading torque, the loading temperature, and the fusion torque were decreased with the content of calcium carbonate was increased. But the fusion time and fusion percolation threshold were increased with the content of calcium carbonate was increased. The effect of the nano-CaCO3 was more significant than that of the micro-CaCO3. From the thermal properties, Tg and thermal stability of PVC/CaCO3 nanocomposites were increased with the content of nano-CaCO3. The 10phr nano-CaCO3 had the best result. On the other hand, the micro-CaCO3 caused the opposite results. The SEM morphology results showed that CaCO3 were dispersed in the composite and resulted in voids. The PVC/nano-CaCO3 nanocomposites exhibited lightweight and good properties. In the third section, the variation is different kind of CaCO3, the content of CaCO3, and powder or pellet type HDPE. The fusion properties showed that the lower loading torque and the higher fusion time resulting from the HDPE powder. The HDPE/nano-CaCO3 nanocomposites displayed the higher loading torque and the shorter fusion time than those of the HDPE/micro-CaCO3 composites. From the TGA results, it showed the thermal stability of HDPE/nano- or micro- CaCO3 composites were improved, especially for the nano-CaCO3. From the DSC non-isothermal crystallization analysis, the crystallization temperature of HDPE was increased with the content of CaCO3 was increased. It implied the crystallization rate of HDPE was increased. The crystallinity of HDPE was decreased with the content of CaCO3 was increased. The melting point of HDPE was decreased due to its crystallinity was decreased.
Chu, Line-Hwa, and 邱聯華. "Studies on the Rheological Properties for Polymer Blends." Thesis, 1994. http://ndltd.ncl.edu.tw/handle/47509643596796491086.
Full text國立臺灣大學
材料科學(工程)研究所
82
The aim of this work was to study the rheological properties of both homogeneous and heterogeneous polymer blends. In general, the viscosity of homogeneous polymer blends changes monotonously with composition. In this work, we have modified the concentric multilayer model proposed by Lin to predict the flow behavior of homogeneous polymer blends. There are two types of viscosity- composition curves for heterogeneous polymer blends: For the first type, the viscosity-composition curves were concave upward. There is little interaction between the two phases and both phases are deformed along the direction of flow. Two-phase flow phenomenon is observed. For this type of flow, the modified concentric multilayer model was also used to predict the are deformed along flow behavior. Two parameters regarding the friction force correction and number of layer were introduced in this model and were estimated by curve fitting with the experimental viscosity data. For the second type, the viscosity-composition curves were convex. The viscosity of the dispersed phase is lower than that of the matrix phase, and there is rather strong interaction between the two phases. Then the domain size of the dispersed phase is small and uniform, and the strong interaction plays a role like surfactants, which will diminish most of the strain to the dispersed phase so the deformation of dispersed phase is negligible and the droplets will behave as rigid particles. For this type of flow, we have modified the filler model proposed by Chen et. al. to predict the flow behavior. The viscosity of a polymer blend is influenced by the composition, morphology, miscibility, and interfacial interaction . The correlation of interfacial interaction - miscibility - morphology - free volume of polymer blends was investigated.
Gironda, Linda Ann. "Cross-Cultural Practices of Adult Educators in Blended Global Education." Thesis, 2019. https://doi.org/10.7916/d8-xshj-1347.
Full textLiu, Yi-Hsun, and 劉義峋. "Studies on Compatibility and Biodegradability of PHB/PLA Blends." Thesis, 2011. http://ndltd.ncl.edu.tw/handle/17554675488298979854.
Full text淡江大學
化學工程與材料工程學系碩士班
99
Biodegradable polymers have recently attracted great attension because environmental pollution. PLA and PHB is a aliphatic thermoplastic polyester and a biodegradation plastic. In this study, we blended PLA with PHB. We hope it could have a good miscibility and increase the mechanical properties. Then we measure the physical properties and mechanical properties. Finally, we degrade the PHB/PLA blends by streptomyces 76T-1 to investigate the degradability of PHB/PLA blends. Because the miscibility was increased by reduceing the molecular weight of PHB, we blend PLA with PHB by mixer at 180oC for 20 min to obtain the low molecular weight PHB blend with PLA. We could increase the crystallinity of PLA by adding the low molecular weight PHB.The elongation at break was increased from 7% to 226% by blending 20 wt% PHB. We use Streptomyces sp. 76T-1 to degrade PLA and PHB/PLA blends. After degradating test in 72 hour, PLA could be degradating completely. Adding 5 wt% low molecular weight PHB could accelerate the degradating rate, because the low crystallinity of PLA after adding 5 wt% PHB. But adding PHB more then 10 wt% could slow down the degradating rate. After degradating test, we found that the crystallinity was changed by the environment temperature not by degrading of Streptomyces sp. 76T-1. In the other word, the crystallinity have not changing in the degrade behavior.
WU, WEN-CHAO, and 吳文超. "The studies of the properties of polypropylene (PP) blends." Thesis, 1990. http://ndltd.ncl.edu.tw/handle/88036956525897418534.
Full text