Academic literature on the topic 'Bromomethyl'

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Journal articles on the topic "Bromomethyl"

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Jones, Peter G., Piotr Kuś та Ina Dix. "X-Ray Structure Determinations of Bromo- and/or Bromomethylsubstituted Benzenes: C–H···Br, C–Br···Br, and C–Br···π Interactions". Zeitschrift für Naturforschung B 67, № 12 (2012): 1273–81. http://dx.doi.org/10.5560/znb.2012-0249.

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The structures of seven benzene derivatives [1,2,3-tri(bromomethyl)benzene, (1); 3,5- di(bromomethyl)bromobenzene, (2); 2,5-di(bromomethyl)bromobenzene, (3); 4-(bromomethyl)-2,5- dibromotoluene, (4); 4-(bromomethyl)bromobenzene, (5); 2,3-di(bromomethyl)bromobenzene, (6) and (bromomethyl)-p-dibromobenzene, (7)] with bromo and bromomethyl (and in one case methyl) substituents are presented and analysed in terms of Br···Br interactions up to 4.0 A° , supported by hydrogen bonds H···Br. Some interactions of the type Br···π and π···π are encountered and play a subordinate role in the packing. Despi
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Jones, Peter G., та Piotr Kuś. "Secondary Interactions in Bromomethyl-substituted Benzenes: Crystal Structures of Three α,α′-Bis-bromoxylenes, 1,2,3,5-Tetrakis(bromomethyl)benzene, and 1,2,4,5-Tetrakis(bromomethyl)benzene". Zeitschrift für Naturforschung B 62, № 5 (2007): 725–31. http://dx.doi.org/10.1515/znb-2007-0517.

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Abstract X-Ray structure determinations of all three isomers of bis(bromomethyl)benzene and of two isomeric tetrakis(bromomethyl)benzenes show that the packing of the molecules is determined principally by interactions of the bromomethyl groups (C-H· · ·Br and Br· · ·Br), except for ortho-bis (bromomethyl)benzene, in which C-H· · ·π interactions play a major role.
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Brecknell, Douglas J., Raymond M. Carman, Ross A. Edwards, Karl A. Hansford, Tomislav Karoli, and Ward T. Robinson. "Halogenated Terpenoids. XXIX The 1-Bromo 1-Bromomethyl Cyclohexyl System." Australian Journal of Chemistry 50, no. 7 (1997): 689. http://dx.doi.org/10.1071/c96188.

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Bromination of methylene groups exocyclic to cyclohexyl systems normally affords two isomeric products; the axial 1-bromo equatorial 1-bromomethyl compound and the axial 1-bromomethyl equatorial 1-bromo derivative. Free energy differences between these two isomers, and the conformations adopted by the axial 1-bromomethyl group, have been explored by n.m.r. spectroscopy, by X-ray crystallography and by MM3 calculations. Evidence is presented to show that the ax-bromomethyl group exists primarily as those rotamers which site the bromine atom synclinal to the vicinal bromine. The A value for a br
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Papavassiliou, G. C., G. A. Mousdis, and I. B. Koutselas. "Some Organic-Inorganic Hybrid Compounds Based on iso– Thiuronium Cations and Lead Halide Anions." Zeitschrift für Naturforschung B 56, no. 1 (2001): 57–61. http://dx.doi.org/10.1515/znb-2001-0109.

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Abstract Using 1-chlorodecane (C10H21CI), benzyl chloride (C6H5CH2CI), a,a'-dichloro-p-xylene (CICH2C6H4CH2CI), 4-phenylbenzyl chloride (C6H5C6H4CH2CI), 2-bromomethyl-naphthal-ene (C10H7CH2Br), 4-bromomethyl-7-methoxycoumarin (C10H7O3CH2Br), 2-bromomethyl-anthraquinone (C14H7CH2Br), 9-chloromethyl-anthracene (C14H9CH2CI), thiourea and halides as starting materials, the organic-inorganic hybrid compounds [C10H21SC(NH2)2]2Pbl4, [C6H5CH2SC(NH2)2]4Pb3l10 [(H2N2)CSCH2C6H4CH2SC(NH2)2]0.5PbI3, [C6H5C6H4CH2S-C(NH2)2]PbI3, [C10H7CH2SC(NH2)2]Pbl3, [C14H7 O2CH2SC(NH2)2]Pbl3, [C14H9CH2SC(NH2)2]PbI3, and [
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Nestler, Robert, Anke Schwarzer, and Tobias Gruber. "Different supramolecular interactions mediated by Br atoms in the crystal structures of three anisole derivatives." Acta Crystallographica Section C Structural Chemistry 74, no. 3 (2018): 283–88. http://dx.doi.org/10.1107/s2053229618001997.

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Three anisole building blocks featuring bis(hydroxymethyl) or bis(bromomethyl) pendants have been analyzed with regard to their molecular structures and packing behaviour. The compounds are ethyl 3,5-bis(hydroxymethyl)-4-methoxybenzoate, C12H16O5, (I), [5-bromo-3-(hydroxymethyl)-2-methoxyphenyl]methanol [or 4-bromo-2,6-bis(hydroxymethyl)anisole], C9H11BrO3, (II), and 5-bromo-1,3-bis(bromomethyl)-2-methoxybenzene [or 4-bromo-2,6-bis(bromomethyl)anisole], C9H9Br3O, (III). A typical supramolecular pattern involved C—H...π interactions generating molecular stacks, while π–π interactions were only
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Fletcher Claville, Michelle O., Roosevelt J. Payne, Brandon C. Parker, and Frank R. Fronczek. "(Bromomethyl)trimethylammonium bromide." Acta Crystallographica Section E Structure Reports Online 63, no. 5 (2007): o2601. http://dx.doi.org/10.1107/s1600536807018235.

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Fletcher Claville, Michelle O., Roosevelt J. Payne, and Frank R. Fronczek. "(Bromomethyl)trimethylammonium tetrafluoroborate." Acta Crystallographica Section E Structure Reports Online 62, no. 8 (2006): o3452—o3454. http://dx.doi.org/10.1107/s1600536806027188.

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Černochová, Jarmila, Andrea Čablová, Michal Rouchal, Marek Nečas, and Robert Vícha. "1-(Bromomethyl)adamantane." Acta Crystallographica Section E Structure Reports Online 67, no. 7 (2011): o1820. http://dx.doi.org/10.1107/s1600536811023695.

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Xu, Wei-Jian, Yang-Ling Zang, Guo-Liang Wu, Sheng-Pei Su, and De-Yue Qiu. "4-(Bromomethyl)benzophenone." Acta Crystallographica Section E Structure Reports Online 63, no. 3 (2007): o1188—o1189. http://dx.doi.org/10.1107/s160053680700534x.

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The title compound, C14H11BrO, was synthesized by the reaction of 4-methylbenzophenone and bromine in carbon tetrachloride. X-ray crystal structure analysis reveals that the benzene and phenyl rings form a dihedral angle of 59.53 (6)°, and the crystal packing is stabilized by intermolecular C—H...π interactions.
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Guo, Jianyu, Yan Lu, and Jin Wang. "Efficient synthesis of 3-(bromomethyl)-5-methylpyridine hydrobromide." Heterocyclic Communications 21, no. 4 (2015): 203–5. http://dx.doi.org/10.1515/hc-2015-0107.

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Abstract5-Methyl-3-(bromomethyl)pyridine is the key intermediate in the synthesis of rupatadine. In this article, a new preparation of 5-methyl-3-(bromomethyl)pyridine hydrobromide is reported, which used 5-methylnicotinic acid as the starting material, with a 65.9% overall yield. This method has the merits of being simple, efficient and environmentally friendly.
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Dissertations / Theses on the topic "Bromomethyl"

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XU-WU, SASHUANG. "Cyclisations radicalaires d'ethers propargyliques de (bromomethyl)-dimethylsilyle. Leurs applications a la synthese d'hydrindenes et d'un squelette steroidique." Paris 6, 1995. http://www.theses.fr/1995PA066753.

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Le memoire decrit et montre la grande capacite synthetique de la reaction de cyclisation radicalaire de differentes structures d'ethers propargyliques de bmdms. Nos travaux, qui ont consiste en l'application de cette reaction en synthese avec pour cible finale l'acide fusidique, ont permis de montrer que nous pouvions acceder a: ? des doubles liaisons trisubstituees de facon totalement regio- et stereoselective en presence d'un groupe electroattracteur sur le carbone acetylenique terminal. ? des derives cyclopenteniques fonctionnalises de facon hautement regio- et totalement diastereoselective
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EL, ALAMI NAJAT. "Isolement et reactivite du derive zincique de (bromomethyl-2) acrylate d'ethyle : synthese de methylene-3 pyrrolidinone-3 potentiellement antineoplasique." Nantes, 1987. http://www.theses.fr/1987NANT2016.

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Reaction de l'organozinicique allylique prepare, avec divers electrophiles conduisant a des methylene-3 perhydrofurannones-2 et -pyrrolidones-2. Etude de l'activite de ces composes sur la leucamie p388
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Kong, Weixi. "Oxidative DNA Damage and DNA Binding Induced by 2, 2-Bis (Bromomethyl)-1, 3-Propanediol: Possible Mode of Action Implicated in its Carcinogenicity." Diss., The University of Arizona, 2012. http://hdl.handle.net/10150/223375.

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The studies in this dissertation research were conducted to investigate the possible mode of action by which a brominated flame retardant, 2, 2-Bis (bromomethyl)-1, 3-propanediol (BMP) causes genotoxicity. Binding of BMP to DNA and BMP induced DNA strand breaks were investigated in SV-40 immortalized human uroepithelial cells (UROtsa) as an in vitro model for the bladder (a tissue that developed cancer after two year exposure to BMP in rodents). Results showed binding of [¹⁴C]-BMP equivalents to DNA increased with increased exposure time and concentration of [¹⁴C]-BMP. Comet analysis indicated
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Monmoton, Sophie. "Polyélectrolytes linéaires et hyperramifiés par poly(N-alkylation) de pyridines substituées." Paris 6, 2007. http://www.theses.fr/2007PA066163.

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Ce travail est consacré à la synthèse et à la caractérisation de nouveaux polyélectrolytes de type polypyridiniums linéaires et hyperramifiés, ces derniers pouvant ouvrir la voie à la préparation de « micelles monomoléculaires ». La synthèse des polymères a été réalisée par poly(N-alkylation) de pyridines substituées. Les polymères linéaires sont obtenus à partir de deux monomères commerciaux de type AB : la 3-bromométhylpyridine hydrobromée et la 4-bromométhylpyridine hydrobromée. La modification de leur contre-ion permet de moduler leurs propriétés thermiques et leurs solubilités. De nouveau
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AUVRAY, PATRICK. "Utilisation de reactifs de multi-couplages allyliques sulfonyles en synthese organique." Paris 6, 1988. http://www.theses.fr/1988PA066030.

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La synthese et la reactivite du (bromomethyl-"1" vinyl phenyl) sulfone sont etudiees ainsi que celle du zincique correspondant. La synthese et la reactivite d'une famille de reactifs allyliques analogues mais polysubstitues sont ensuite envisagees. Applications dans le domaine de la synthese de produits naturels et la synthese diastereoselective
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Lanson, Marc. "Isoxazoles polyalkyles : synthese, etude structurale et comportement en milieu biologique." Paris 6, 1987. http://www.theses.fr/1987PA066468.

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Sanchez, Ovando Erika. "“Estudio de la Síntesis de Dendrímeros de Primera Generación Basados en 1,2,3-triazoles-4- sustituidos a partir de 1,3,5- tris(bromometil)benceno”." Tesis de Licenciatura, Medicina-Quimica, 2014. http://ri.uaemex.mx/handle/123456789/14464.

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Grison, Claude. "Généralisation de la réaction d'alpha halogénation-carbonyloléfination et nouvelles applications en synthèse des acides dialkylphosphono-2-alcanoiques et des acides voisins apparentés alpha brome, alpha chlore et alpha fluore." Nancy 1, 1987. http://www.theses.fr/1987NAN10340.

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La réaction d'α -halogénation-carbonyloléfination a été étendue à la préparation de vinylséléniures α -chlorés et généralisée à l'α -bromation -carbonyloléfination. Les dianions des acides dialkylphosphonofluoracétiques réagissent avec les dérivés carbonylés par réaction de wittig-horner et conduisent stéréosélectivement aux acides α, β -éthyléniques α -fluorés. La réaction est généralisable aux dérivés chrysanthémiques. Ces acides permettent également un accès très efficace aux β -cétophosphonates α -fluorés et cétones α, β -éthyléniques α -fluorées. La réaction d'organocuprates sur les chlor
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Books on the topic "Bromomethyl"

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Martinez, Luis Escriche. Estudio de complejos con ligandos aciclicos y macrociclicos derivados de la 2,6-bis(bromometil)piridina. 1988.

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Book chapters on the topic "Bromomethyl"

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Hirota, E., K. Kuchitsu, T. Steimle, J. Vogt, and N. Vogt. "34 CH2Br Bromomethyl." In Molecules Containing No Carbon Atoms and Molecules Containing One or Two Carbon Atoms. Springer Berlin Heidelberg, 2014. http://dx.doi.org/10.1007/978-3-540-70614-4_235.

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Xu, Wei, and William R. Dolbier. "Synthesis of Difluorocyclopropyl Building Blocks: 2,2-Difluorocyclopropylmethanol and 2-(Bromomethyl)-1,1-difluorocyclopropane." In Efficient Preparations of Fluorine Compounds. John Wiley & Sons, Inc., 2012. http://dx.doi.org/10.1002/9781118409466.ch52.

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Burgot, Jean-Louis. "Iodometry in Alkaline Medium, Iodatometry, Periodimetry, and Bromometry." In Ionic Equilibria in Analytical Chemistry. Springer New York, 2012. http://dx.doi.org/10.1007/978-1-4419-8382-4_19.

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"5-(Bromomethyl)fluorescein." In Handbook of Fluorescent Dyes and Probes. John Wiley & Sons, Inc, 2015. http://dx.doi.org/10.1002/9781119007104.ch36.

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"4-Bromomethyl-6,7-dimethoxycoumarin." In Handbook of Fluorescent Dyes and Probes. John Wiley & Sons, Inc, 2015. http://dx.doi.org/10.1002/9781119007104.ch35.

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"4-Bromomethyl-7-methoxycoumarin." In Handbook of Fluorescent Dyes and Probes. John Wiley & Sons, Inc, 2015. http://dx.doi.org/10.1002/9781119007104.ch37.

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Olpp, T. "Oxidation via Bromomethyl Ketones." In Aldehydes. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-025-00282.

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Murphy, P. J. "From 2-(Bromomethyl)benzoyl Chloride." In Fused Five-Membered Hetarenes with One Heteroatom. Georg Thieme Verlag KG, 2001. http://dx.doi.org/10.1055/sos-sd-010-00418.

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Murphy, P. J. "From 2-(Bromomethyl)benzoyl Halides." In Fused Five-Membered Hetarenes with One Heteroatom. Georg Thieme Verlag KG, 2001. http://dx.doi.org/10.1055/sos-sd-010-00520.

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Meigh, J. P. K. "From 2,2′-Bis(bromomethyl)diphenylamine." In Six-Membered Hetarenes with Two Unlike or More than Two Heteroatoms and Fully Unsaturated Larger-Ring Heterocycles. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-017-01404.

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Conference papers on the topic "Bromomethyl"

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D’Hooghe, Matthias, and Norbert De Kimpe. "Reactivity of 1-arenesulfonyl- and 1-alkyl-2-(bromomethyl)aziridines towards Lithium Cuprate Reagents." In The 9th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2005. http://dx.doi.org/10.3390/ecsoc-9-01474.

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Gerold, David J., Ray T. Chen, William A. Farone, and David G. Pelka. "Poled electro-optic photolime gel polymer doped with chlorophenol red and bromomethyl-blue chromophores." In SPIE's 1994 International Symposium on Optics, Imaging, and Instrumentation, edited by Massood Tabib-Azar, Dennis L. Polla, and Ka-Kha Wong. SPIE, 1994. http://dx.doi.org/10.1117/12.190926.

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Xu, Hui-Tao, Xue Li, Gang Li, and Gang Liu. "Synthesis and properties of a new material 1-[2-methyl-5-hydroxymethyl-3-thienyl]-2-[2-methyl-5- bromomethyl-3-thienyl] perfluorocyclopentene." In 2016 International Conference on Advanced Materials and Energy Sustainability (AMES2016). WORLD SCIENTIFIC, 2017. http://dx.doi.org/10.1142/9789813220393_0006.

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