Academic literature on the topic 'Coats-Redfern method'

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Journal articles on the topic "Coats-Redfern method"

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Mal’ko, Mihail V., Sergej V. Vasilevich, Andrey V. Mitrofanov, and Vadim E. Mizonov. "AN INNOVATE METHOD OF THERMOGRAVIMETRIC DATA ANALYSIS." IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA KHIMICHESKAYA TEKHNOLOGIYA 64, no. 3 (2021): 24–32. http://dx.doi.org/10.6060/ivkkt.20216403.6348.

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The objective of the study is to examine the Coats-Redfern approximation and to propose an innovative kinetic calculation method for the complex process of the heavy tar thermal decomposition under non-isothermal process. The thermal decomposition process was examined using the thermogravimetric analysis. There are several kinetic models proposed to analyze pyrolysis mechanism in terms of the formal reaction. In this manner, the kinetic parameters of the pyrolysis process can be evaluated based on total mass loss (thermogravimetric analysis –TGA). The TGA procedures can be conducted with isoth
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Guo, Zhi Hong, Pei Jie Lin, Qing Yan Xu, et al. "Kinetics of Non-Isothermal Degradation of PFA." Applied Mechanics and Materials 268-270 (December 2012): 138–42. http://dx.doi.org/10.4028/www.scientific.net/amm.268-270.138.

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Thermal stability can reflect the thermal degradation speed of polymers during the melt processing. In this paper, we used Kissinger, Flynn-Wall-Ozawa and Coats-Redfern method to study the kinetics of non-isothermal degradation of PFA. The thermal degradation activation energy obtained from the Kissinger method, Flynn-Wall-Ozawa method and Coats-Redfern method is 228.5 kJ/mol, 213.9 kJ/mol and 237.4 kJ/mol respectively. The Flynn-Wall-Ozawa method indicates the thermal degradation reaction PFA is a secondary reaction.
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Dhaundiyal, Alok, Suraj B. Singh, Muammel M. Hanon, and Rekha Rawat. "Determination of Kinetic Parameters for the Thermal Decomposition of Parthenium hysterophorus." Environmental and Climate Technologies 22, no. 1 (2018): 5–21. http://dx.doi.org/10.1515/rtuect-2018-0001.

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Abstract A kinetic study of pyrolysis process of Parthenium hysterophorous is carried out by using thermogravimetric analysis (TGA) equipment. The present study investigates the thermal degradation and determination of the kinetic parameters such as activation E and the frequency factor A using model-free methods given by Flynn Wall and Ozawa (FWO), Kissinger-Akahira-Sonuse (KAS) and Kissinger, and model-fitting (Coats Redfern). The results derived from thermal decomposition process demarcate decomposition of Parthenium hysterophorous among the three main stages, such as dehydration, active an
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Ross, Kelly, and David Godfrey. "EFFECT OF EXTRACTIVES ON THE THERMAL DECOMPOSITION OF WHEAT, TRITICALE, AND FLAX CROP RESIDUES : A KINETIC STUDY." International Journal of Biomass and Renewables 1, no. 2 (2012): 19. http://dx.doi.org/10.61762/ijbrvol1iss2art13821.

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A kinetic study was performed using the Kissinger and Coats-Redfern methods to examine the effect of extractives on thermal decomposition of three crop residues, wheat straw, triticale straw and flax shives. The extractives-free crop residues required higher temperatures for the onset of thermal decomposition than the corresponding native/unextracted samples. Activation energy (Ea) values varied according to kinetic analysis and the extractives-free samples generally showed significantly higher Ea values (65-214 kJ.mol-1) than the native/unextracted samples (58-205 kJ.mol-1). This information
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Yang, Dong, Wei Zhang, Ru Liang Yao, and Ben Zheng Jiang. "Thermal Degradation Characteristics and Kinetics of High Temperature Vulcanized (HTV) Silicone Rubber/POSS Hybrid." Applied Mechanics and Materials 105-107 (September 2011): 1657–61. http://dx.doi.org/10.4028/www.scientific.net/amm.105-107.1657.

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A high temperature vulcanized (HTV) silicone rubber/octavinyl polyhedral oligomeric silsesquioxane (POSS) hybrid was prepared. The micromorphology of the cured hybrid was investigated by scanning electron microscopy (SEM); the thermal degradation stability of this hybrid was studied by means of thermal gravimetric analyses (TGA); the degradation kinetics of this hybrid was also studied using Doyle method and Coats-Redfern method. Results showed that aggregation of self-cross-linked octavinyl POSS appeared in the HTV silicon rubber/POSS hybrid. The incorporation of POSS into silicon rubber netw
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Nangarthody, Sindhu, and V. Sivasubramanian. "Kinetic and Thermodynamic Analysis of Pyrolysis of Coconut Wood Residue." Asian Journal of Chemistry 35, no. 1 (2022): 39–44. http://dx.doi.org/10.14233/ajchem.2023.24016.

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Physico-chemical properties, kinetics and thermodynamic analysis of biomass are important in designing an efficient pyrolysis process. The current study aims to investigate the physico-chemical behaviour, calorific value and kinetics of thermal decomposition of coconut wood (Cocos nucifera) at 10, 15, and 25 ºC/min using the thermogravimetric analysis (TGA) technique in nitrogen atmospheres. Kinetic parameters were estimated using the Kissinger-Akahira-Sunose (KAS), Flynn-Wall-Ozawa (FWO), Staring, Tang, Friedman and Coats-Redfern (CR) methods. Average activation energy estimated from Kissinge
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Altynbaeva, Dariga, Alexander Astafev, and Roman Tabakaev. "Kinetics of biomass low-temperature pyrolysis by coats–redfern method." MATEC Web of Conferences 194 (2018): 01058. http://dx.doi.org/10.1051/matecconf/201819401058.

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Energy is one of the main sources of environmental pollution. In this regard, the world scientific community seeks to reduce its negative impact on human health and nature. To do this, some of the organic raw materials, which are fuel for power plants, are gradually replaced by renewable resources, in particular - biomass. The combustion of biomass by traditional methods is accompanied by high operating costs, which leads to the conclusion that it is necessary to process it into energy-valuable products. The development of one of the most promising such directions - thermal processing - requir
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Wan, Haibo, and Zhen Huang. "Kinetic Analysis of Pyrolysis and Thermo-Oxidative Decomposition of Tennis String Nylon Wastes." Materials 14, no. 24 (2021): 7564. http://dx.doi.org/10.3390/ma14247564.

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Thermal degradation of nylon-6 tennis string nylon wastes in inert nitrogen and air atmospheres was investigated by means of multiple heating-rate thermogravimetric analyses. The results obtained under the heating rates of 5–20 K/min are compared in terms of degradation feature and specific temperature for two atmospheres. Using nonisothermal data, kinetic analysis was thoroughly conducted using various isoconversional model-free methods, including Starink, Madhusudanan–Krishnan–Ninan, Tang, Coats–Redfern, and Flynn–Wall–Ozawa methods. With these kinetic analysis methods, the activation energy
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Zhang, Pei, Zhaoyang Chen, Qiuli Zhang, Shuo Zhang, Xiaogang Ning, and Jun Zhou. "Co-pyrolysis characteristics and kinetics of low metamorphic coal and pine sawdust." RSC Advances 12, no. 34 (2022): 21725–35. http://dx.doi.org/10.1039/d2ra02461f.

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The research on the product distribution of the co-pyrolysis of coal and biomass and the use of the Coats–Redfern integral method and the Achar differential method to study the kinetic parameters and mechanism of the pyrolysis process.
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Wang, Xiangxi, Zhenzhong Hu, Inamullah Mian, et al. "Gasification Kinetics of Organic Solid Waste Pellets: Comparative Study Using Distributed Activation Energy Model and Coats–Redfern Method." Energies 15, no. 24 (2022): 9575. http://dx.doi.org/10.3390/en15249575.

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The gasification kinetics of pellets obtained from organic solid wastes (OWS) and raw materials were studied using the Coats–Redfern and DAEM methods. The different methods were comparatively analyzed for mutual verification, and the similar activation energies obtained by each method affirmed the accuracy of the kinetics calculation. Overall, the activation energies of the char gasification stage ranged from 200 to 265 kJ mol−1, higher than those of the devolatilization stage, which ranged from 130 to 200 kJ mol−1 for all pellets and raw materials. During the devolatilization stage, the activ
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Book chapters on the topic "Coats-Redfern method"

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Sukarni, Sukarni, Nandang Mufti, Avita Ayu Permanasari, Ardianto Prasetiyo, Poppy Puspitasari, and Anwar Johari. "Co-Combustion of Water Hyacinth (Eichhornia crassipes) and Coal: Thermal Behavior and Kinetics Analysis Under the Coats-Redfern Method." In Recent Advances in Renewable Energy Systems. Springer Nature Singapore, 2022. http://dx.doi.org/10.1007/978-981-19-1581-9_36.

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Mohamed, Alina Rahayu, and Nor Ashikin Ahmad. "Kinetics Analysis on Pyrolysis of Empty Fruit Bunch (EFB) Using Flynn-Wall-Ozawa and Coats-Redfern Methods." In Green Energy and Technology. Springer Nature Singapore, 2025. https://doi.org/10.1007/978-981-96-3785-0_10.

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Xiang, Baixiang, Jun Huang, Houzhang Tan, Xiaohe Xiong, Yan Li, and Binqiao Han. "Thermogravimetric Analysis and Kinetic Calculation on the Combustion Characteristics of Two Typical Shenhua Chars." In Advances in Transdisciplinary Engineering. IOS Press, 2021. http://dx.doi.org/10.3233/atde210320.

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Recently, a new ultra-low nitrogen combustion technology, pyrolysis and gasification coupling combustion, was proposed. The dependence on SCR or SNCR was reduced measurably with this technology. However, given the lower content of volatile matter in semi-chars, the burn-up ratio and combustion efficiency seemed to become lower. Thus, in this study, the combustion characteristics of the Shenhun and Carboniferous char were investigated under combustion conditions with the thermogravimetric method; meantime, kinetic calculation on the combustion characteristics were evaluated with Coats–Redfern m
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Conference papers on the topic "Coats-Redfern method"

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Mal’ko, Mihail V., Sergej V. Vasilevich, Andrey V. Mitrofanov, and Natalia S. Shpeynova. "A new approach for determination of reaction parameters of the liquid hydrocarbon thermal decomposition." In INTERNATIONAL SCIENTIFIC-TECHNICAL SYMPOSIUM (ISTS) «IMPROVING ENERGY AND RESOURCE-EFFICIENT AND ENVIRONMENTAL SAFETY OF PROCESSES AND DEVICES IN CHEMICAL AND RELATED INDUSTRIES». The Kosygin State University of Russia, 2021. http://dx.doi.org/10.37816/eeste-2021-1-113-117.

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Gayathri, K., K. Rajesh, P. Krishnan, et al. "A study on kinetic properties of brucinium hydrogen (s) malate pentahydrate single crystal by Coats Redfern method." In DAE SOLID STATE PHYSICS SYMPOSIUM 2019. AIP Publishing, 2020. http://dx.doi.org/10.1063/5.0017481.

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Džunuzović, Jasna V., Ivan S. Stefanović, Enis S. Džunuzović, and Carla Marega. "THERMAL DEGRADATION KINETICS OF URETHANE AND UREA LINKAGES OF WATERBORNE POLYURETHANES." In 17th International Conference on Fundamental and Applied Aspects of Physical Chemistry. Society of Physical Chemists of Serbia, 2024. https://doi.org/10.46793/phys.chem24ii.405dz.

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In this study, thermal degradation of urethane and urea bonds in waterborne polyurethanes (WBPUs) based on poly(dimethylsiloxane) (PDMS), isophorone diisocyanate (IPDI) and 2,2-bis- (hydroxymethyl)propionic acid (DMPA), was investigated. Three WBPUs with different DMPA/PDMS molar ratio were prepared using simplified procedure, without chain extension step. The kinetic of the first step of thermal degradation of WBPUs, during which the weakest urethane and urea linkages decomposed, was explored in detail. It was established that the average apparent activation energy of this step ranged from 13
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SUKARNI, Sukarni. "The TiO2 catalytic combustion of microalgae spirulina platensis-synthetic waste blend: Thermal characteristics, kinetic and thermodynamic investigation." In Decarbonization Technology: ICDT2024. Materials Research Forum LLC, 2025. https://doi.org/10.21741/9781644903575-34.

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Abstract. This paper evaluates the catalytic impact of TiO2 addition on the combustion behavior of the microalgae Spirulina platensis (SP) and synthetic waste (SW) blend using a thermogravimetric analyzer. The blend ratio of 30SP/70SW, 50SP/50SW, and 70SP/30SW (wt,%) with 5%TiO2 were used for each experiment. The results show that the blended fuels with and without 5%TiO2 decomposed in three stages, with the main combustion reaction taking place in the second stage. Assessment of the second stage revealed that the decomposition could be divided into two zones. Zone I started at 166-191 oC and
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Eggerstedt, Kyle, Xia Wang, James Leidel, and Krzytoff Kobus. "Initial Development of Optimum Biomass Pellets." In ASME 2011 5th International Conference on Energy Sustainability. ASMEDC, 2011. http://dx.doi.org/10.1115/es2011-54464.

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Renewable energy has become a major focus in today’s world of depleting energy resources. Biomass is starting to be utilized because it can be continually created within a reasonable period of time. Biomass particles are pressurized together in a pellet shape. The pellets are fed into a combustion chamber (stove) and burnt to create energy. The objective of this research is to test a range of pellet compositions and investigate their corresponding characteristics in the combustion process in order to maximize their energy output. The pellets investigated include single materials such as wood o
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