Academic literature on the topic 'Cobalt(II) alkoxides'

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Journal articles on the topic "Cobalt(II) alkoxides"

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Neetu, Agrawal, and Singh Anirudh. "Reactions of later 3d divalent transition metal chlorides with metal alkoxides and characterization of novel heterobimetallic alkoxide coordination compounds." Journal of Indian Chemical Society Vol. 84, Sep 2007 (2007): 856–60. https://doi.org/10.5281/zenodo.5826920.

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Department of Chemistry, University of Rajasthan, Jaipur-302 004, Rajasthan, India <em>E-mail </em>: anirudhsinghunivjpr@yahoo.co.in <em>Manuscript received 26 June 2007, accepted 27 June 2007</em> The interesting and somewhat unexpected solubilization of insoluble anhydrous divalent transition metal chlorides, MCI<sub>2</sub> (M = Co, Ni and Cu) in benzene in the presence of Ti(OEt)<sub>4</sub> or Zr(OPr<sup>i</sup>)<sub>4</sub> or AI(OPr<sup>i</sup>)<sub>3</sub> in 1 : 2 and 1 : 4 molar ratios, followed by usual workup yields quantitatively, novel complexes of the general formulae MM&#39; <s
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Raj, Kumar Dubey. "Synthesis, reactions and characterization of some mixed ligand (phenoxo-alkoxoand acetylacetonato-) complexes of cobalt(II) derived from Schiff bases." Journal of Indian Chemical Society Vol. 83, Nov 2006 (2006): 1087–92. https://doi.org/10.5281/zenodo.5832300.

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Synthetic Inorganic &amp; Metallo-Organic Research Laboratory, Department of Chemistry, University of Allahabad, Allahabad-211 002, Uttar Pradesh, India E-mail : rajalkoxy@yahoo.com <em>Manuscript received 28 February 2006, revised 1&nbsp;August 2006, accepted 23 August 2006</em> Some novel complexes of cobalt(ll) of the type, [(&mu;-CI)<sub>2</sub>Co<sub>2</sub>{ƞ<sup>2</sup>-(sb)hl (1) and (2) and Co<sub>2</sub>{ƞ<sup>2</sup>-{sb)}<sub>2</sub>] (3) and (4) [where sb = Schiff base {salicylidene-2-methyl-1-aminobenzene (smabH) for (1 and 3) and salicylidene-2-aminopyridene {sapH) for {2 and 4)
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Neetu, Agrawal, and Singh Anirudh. "Synthesis, spectroscopic and magnetic properties of the first heterotrimetallic complexes of cobalt(II) featuring nonaalkoxodistannate or -dititanate ligands." Journal of Indian Chemical Society Vol. 84, Jun 2007 (2007): 532–37. https://doi.org/10.5281/zenodo.5820513.

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Department of Chemistry, University of Rajasthan, Jaipur-302 004, Rajasthan, India <em>E-mail</em> : anirudhsinghunivjpr@yahoo.co.in <em>Manuscript received 19 February 2006, revised 4 April 2007, accepted 9 April 2007</em> Novel heterotrimetallic alkoxides of the type [Co{M<sub>2</sub>(OR)<sub>9</sub>}{M&#39;(OR&#39;)<sub>n</sub> }] [M=Sn, M&#39;=AI (n = 4), R=R&#39;=Pr<sup>j</sup> (1); M=Sn, M&#39;=Nb (n=6), R=R&#39;= Pr<sup>j</sup> (2); M=Ti, M&#39;=AI (n=4), R=R&#39; = Pr<sup>i</sup> (3); M=Ti, M&#39;=Nb (n=6), R=R&#39;=Pr<sup>i</sup> (4); M=Sn, M&#39;=AI (n=4), R=R&#39;=Et (5); M=Ti, M&#3
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Dubey, R. K., A. Singh, and R. C. Mehrotra. "Synthesis, reactions, spectral and magnetic studies of bimetallic alkoxides of cobalt(II) with zirconium(IV)." Inorganica Chimica Acta 118, no. 2 (1986): 151–56. http://dx.doi.org/10.1016/s0020-1693(00)81378-x.

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Garg, G., R. K. Dubey, A. Singh, and R. C. Mehrotra. "Synthetic, spectroscopic and magnetic studies of heterometal alkoxides of cobalt(II, nickel(II) and copper(II) containing the sterically crowded tetraalkoxoaluminate ligand." Polyhedron 10, no. 15 (1991): 1733–39. http://dx.doi.org/10.1016/s0277-5387(00)83793-6.

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Grass, Amanda, James A. Bellow, Gregory Morrison, Hans-Conrad zur Loye, Richard L. Lord, and Stanislav Groysman. "One electron reduction transforms high-valent low-spin cobalt alkylidene into high-spin cobalt(ii) carbene radical." Chemical Communications 56, no. 60 (2020): 8416–19. http://dx.doi.org/10.1039/d0cc03028g.

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Yamada, Tohru, and Tatsuyuki Tsubo. "Enantioselective Michael Addition Catalyzed by an Optically Active 1-Chlorovinyl Cobalt(III) Complex." Synlett 26, no. 08 (2015): 1111–15. http://dx.doi.org/10.1055/s-0034-1380265.

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The optically active 1-chlorovinyl cobalt(III) complex was prepared from the ketoiminatocobalt(II) complex upon treatment with sodium borohydride in the presence of 1,1,1-trichloroethane. The obtained complex was found to catalyze the enantioselective Michael addition of various malonates on cyclic or acyclic enones to afford the corresponding adduct. In this reaction, the use of sodium alkoxide as a base with 1-chlorovinyl cobalt(III) complex catalyst was crucial to improving both the reactivity and enantioselectivity.
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Bartyzel, Agata, Beata Cristóvão та Dariusz Osypiuk. "Bis(μ2-2,2′-((2-(hydroxy)propane-1,3-diyl)bis((nitrilo)eth-1-yl-1-ylidene))diphenolato)-dicobalt(III)". Molbank 2023, № 3 (2023): M1690. http://dx.doi.org/10.3390/m1690.

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A new cobalt(III) complex with a pentadentate Schiff base was synthesized using a reaction of 2,2′-{(2-hydroxypropane-1,3-diyl)bis(nitriloeth-1-yl-1-ylidene)}diphenol (H3L) and cobalt(II) acetate in a methanolic solution. This synthesis resulted in the isolation of dinuclear compound [CoIII2L2] (1), which was characterized using elemental analyses and XRF, FTIR, and TG/DSC techniques. The molecular structure of the complex was confirmed using single-crystal X-ray diffraction. The structure of 1 consists of a centrosymmetric dimer in which two crystallographically equivalent cobalt(III) ions ar
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Sigel, Gary A., Ruth A. Bartlett, David Decker, Marilyn M. Olmstead, and Philip P. Power. "Synthesis and spectroscopic and x-ray structural characterization and dynamic solution behavior of the neutral cobalt(II) alkoxides [Co{OC(C6H11)3}2]2.CH3OH.1/2C6H12.THF, [Co(OCPh3)2]2.n-C6H14, [Co(OSiPh3)2(THF)]2, and Co(OCPh3)2(THF)2." Inorganic Chemistry 26, no. 11 (1987): 1773–80. http://dx.doi.org/10.1021/ic00258a028.

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Wang, Peng, Glenn P. A. Yap, and Charles G. Riordan. "Iron(II)–alkoxide and –aryloxide complexes of a tris(thioether)borate ligand: synthesis, molecular structures, and implications on the origin of instability of their iron(II)–catecholate counterpart." Acta Crystallographica Section C Structural Chemistry 77, no. 9 (2021): 544–50. http://dx.doi.org/10.1107/s2053229621008500.

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The phenyltris[(tert-butylthio)methyl]borate ligand, [PhTt tBu], has been studied extensively as a platform for coordination, organometallic, and bioinorganic chemistry, especially with 3d metals. While [PhTt tBu]Co(3,5-DBCatH) (3,5-DBCatH is 3,5-di-tert-butylcatecholate), a CoII–monoanionic catecholate complex, was successfully isolated to model the active site of cobalt(II)-substituted homoprotocatechuate 2,3-dioxygenase (Co-HPCD) [Wang et al. (2019). Inorg. Chim. Acta, 488, 49–55], its iron(II) counterpart, [PhTt tBu]Fe(3,5-DBCatH), was not accessible via similar synthetic routes. Switching
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Dissertations / Theses on the topic "Cobalt(II) alkoxides"

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Freeman, Jonathan D. "Cobalt(II) complexes and carbon dioxide fixation." Thesis, University of York, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.341473.

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