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Journal articles on the topic 'Cobaltocène'

Author: Grafiati

Published: 3 February 2023

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1

Yamashita, Yu, Samik Jhulki, Dinesh Bhardwaj, Elena Longhi, Shohei Kumagai, Shun Watanabe, Stephen Barlow, Seth R. Marder, and Jun Takeya. "Highly air-stable, n-doped conjugated polymers achieved by dimeric organometallic dopants." Journal of Materials Chemistry C 9, no. 12 (2021): 4105–11. http://dx.doi.org/10.1039/d0tc05931e.

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2

Zhang, Tao, Hao Li, Huaxia Ban, Qiang Sun, Yan Shen, and Mingkui Wang. "Efficient CsSnI3-based inorganic perovskite solar cells based on a mesoscopic metal oxide framework via incorporating a donor element." Journal of Materials Chemistry A 8, no. 7 (2020): 4118–24. http://dx.doi.org/10.1039/c9ta11794f.

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3

Kwak, In Hye, Hafiz Ghulam Abbas, Ik Seon Kwon, Yun Chang Park, Jaemin Seo, Min Kyung Cho, Jae-Pyoung Ahn, Hee Won Seo, Jeunghee Park, and Hong Seok Kang. "Intercalation of cobaltocene into WS2 nanosheets for enhanced catalytic hydrogen evolution reaction." Journal of Materials Chemistry A 7, no. 14 (2019): 8101–6. http://dx.doi.org/10.1039/c9ta01238a.

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Cobaltocene-intercalated WS₂ nanosheets exhibit excellent catalytic activity toward the hydrogen evolution reaction, which is supported by spin-polarized density functional theory calculations.

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4

Liu, Rui, San-Huang Ke, Weitao Yang, and Harold U. Baranger. "Cobaltocene as a spin filter." Journal of Chemical Physics 127, no. 14 (October 14, 2007): 141104. http://dx.doi.org/10.1063/1.2796151.

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5

Ding, Yu, Yu Zhao, Yutao Li, John B. Goodenough, and Guihua Yu. "A high-performance all-metallocene-based, non-aqueous redox flow battery." Energy & Environmental Science 10, no. 2 (2017): 491–97. http://dx.doi.org/10.1039/c6ee02057g.

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An all-metallocene based redox flow battery was constructed using ferrocene catholyte and cobaltocene anolyte with a working potential of ∼1.7 V. The potential can be lifted to 2.1 V via rational functionalization of metallocenes, showing the promise of metallocenes as electroactive materials for stationary energy storage.

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6

Knaak, Thomas, Manuel Gruber, Sarah Puhl, Florian Benner, Alejandra Escribano, Jürgen Heck, and Richard Berndt. "Interconnected Cobaltocene Complexes on Metal Surfaces." Journal of Physical Chemistry C 121, no. 48 (November 27, 2017): 26777–84. http://dx.doi.org/10.1021/acs.jpcc.7b07302.

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7

Hernán, Lourdes, Julián Morales, Luis Sánchez, José L. Tirado, and Agustin R. González-Elipe. "Cobaltocene intercalation into misfit layer chalcogenides." J. Chem. Soc., Chem. Commun., no. 9 (1994): 1081–82. http://dx.doi.org/10.1039/c39940001081.

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8

Beneš, L., J. Votinský, P. Lošťý, J. Kalousová, and J. Klikorka. "Cobaltocene Intercalate of the Layered SnSe2." physica status solidi (a) 89, no. 1 (May 16, 1985): K1—K4. http://dx.doi.org/10.1002/pssa.2210890144.

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9

Koley, Sayantanu, Sabyasachi Sen, and Swapan Chakrabarti. "A Novel Way to Enhance the Thermoelectric Efficiency of Carbon Nanotube through Cobaltocene‐decamethyl Cobaltocene Encapsulation." ChemistrySelect 5, no. 4 (January 31, 2020): 1539–46. http://dx.doi.org/10.1002/slct.201904866.

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10

YU, YINXI, HAOBIN WANG, and SHAOWEI CHEN. "COMPUTATIONAL STUDY OF BRIDGE-MEDIATED INTERVALENCE ELECTRON TRANSFER II: COUPLINGS IN DIFFERENT METALLOCENE COMPLEXES." Journal of Theoretical and Computational Chemistry 11, no. 06 (December 2012): 1341–56. http://dx.doi.org/10.1142/s0219633612500915.

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The constrained density functional theory (CDFT) was used to study bridge-mediated electron transfer processes in mixed-valence systems with two identical metallocene (cobaltocene, ruthenocene, and nickelocene) moieties linked by various bridge structures. Based on the electronic coupling matrix elements obtained from the CDFT calculations, the relationship between the bridge linkage and the effectiveness of intervalence transfer was discussed.

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11

Chauhan, Devika, Anuptha Pujari, Guangqi Zhang, Kinshuk Dasgupta, Vesselin N. Shanov, and Mark J. Schulz. "Effect of a Metallocene Catalyst Mixture on CNT Yield Using the FC-CVD Process." Catalysts 12, no. 3 (March 3, 2022): 287. http://dx.doi.org/10.3390/catal12030287.

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This work studies synthesis of carbon nanotube (CNT) sheet using the high temperature (1400 °C) floating catalyst chemical vapor deposition (FC-CVD) method. Three metallocenes—ferrocene, nickelocene, cobaltocene—and their combinations are used as precursors for metal catalysts in the synthesis process. For the carbon source, an alcohol fuel, a combination of methanol and n-hexane (9:1), is used. First, the metallocenes were dissolved in the alcohol fuel. Then, the fuel mixture was injected into a tube furnace using an ultrasonic atomizer with Ar/H2 carrier gas in a ratio of about 12/1. The synthesis of CNTs from a combination of two or three metallocenes reduces the percentage of metal catalyst impurity in the CNT sheet. However, there is an increase in structural defects in the CNTs when using mixtures of two or three metallocenes as catalysts. Furthermore, the specific electrical conductivity of the CNT sheet was highest when using a mixture of ferrocene and cobaltocene as the catalyst. Overall, the multi-catalyst method described enables tailoring certain properties of the CNT sheet. However, the standard ferrocene catalyst seems most appropriate for large-scale manufacturing at the lowest cost.

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12

Choi, Jaewu, and P. A. Dowben. "Cobaltocene adsorption and dissociation on Cu(111)." Surface Science 600, no. 15 (August 2006): 2997–3002. http://dx.doi.org/10.1016/j.susc.2006.05.013.

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13

Lewandowski, Andrzej, Lukasz Waligora, and Maciej Galinski. "Electrochemical Behavior of Cobaltocene in Ionic Liquids." Journal of Solution Chemistry 42, no. 2 (February 2013): 251–62. http://dx.doi.org/10.1007/s10953-013-9957-1.

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14

Sakai, Hiroshi, Takashi Yamazaki, Nobuya Machida, Toshihiko Shigematsu, and Saburo Nasu. "Mössbauer Spectra of FePS3-Cobaltocene Intercalation Compound." Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals 341, no. 2 (April 1, 2000): 105–10. http://dx.doi.org/10.1080/10587250008026125.

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15

Yan, Xun-Wang, Zhong-Bing Huang, Guo-Hua Zhong, and Hai-Qing Lin. "Pressure-induced ferromagnetic half-metallicity in cobaltocene." EPL (Europhysics Letters) 113, no. 2 (January 1, 2016): 27005. http://dx.doi.org/10.1209/0295-5075/113/27005.

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16

Manova, Elina, Anne Leaustic, Ivan Mitov, Danielle Gonbeau, and Rene Clement. "The NiPS3-Cobaltocene intercalation compound: A new ferromagnet." Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals 311, no. 1 (March 1998): 155–60. http://dx.doi.org/10.1080/10587259808042381.

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17

Ignatov, A. Yu, Ya B. Losovyj, L. Carlson, D. LaGraffe, J. I. Brand, and P. A. Dowben. "Pairwise cobalt doping of boron carbides with cobaltocene." Journal of Applied Physics 102, no. 8 (October 15, 2007): 083520. http://dx.doi.org/10.1063/1.2799053.

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18

Carlson, L., D. LaGraffe, S. Balaz, A. Ignatov, Y. B. Losovyj, J. Choi, P. A. Dowben, and J. I. Brand. "Doping of boron carbides with cobalt, using cobaltocene." Applied Physics A 89, no. 1 (June 26, 2007): 195–201. http://dx.doi.org/10.1007/s00339-007-4086-6.

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19

Sergentu, Dumitru-Claudiu, Frédéric Gendron, and Jochen Autschbach. "Similar ligand–metal bonding for transition metals and actinides? 5f1 U(C7H7)2−versus 3dn metallocenes." Chemical Science 9, no. 29 (2018): 6292–306. http://dx.doi.org/10.1039/c7sc05373h.

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A computational analysis of the electronic structure, bonding and magnetic properties in the 5f¹ U(C₇H₇)₂⁻ complex vs. 3d metallocenes is performed. Notably, it is shown that the proton hyperfine coupling constant in U(C₇H₇)₂⁻ is the same in sign and magnitude to that of the 3d⁷ cobaltocene, but the two systems do not share a similar covalent metal–ligand bonding.

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20

Wang, Baiquan, Yan Zhuang, Xiongxiong Luo, Shansheng Xu, and Xiuzhong Zhou. "Controlled/“Living” Radical Polymerization of MMA Catalyzed by Cobaltocene." Macromolecules 36, no. 26 (December 2003): 9684–86. http://dx.doi.org/10.1021/ma035334y.

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21

Kim, Chang Su, Stephanie Lee, Leonard L. Tinker, Stefan Bernhard, and Yueh-Lin Loo. "Cobaltocene-Doped Viologen as Functional Components in Organic Electronics." Chemistry of Materials 21, no. 19 (October 13, 2009): 4583–88. http://dx.doi.org/10.1021/cm901579h.

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22

Luo, Xiongxiong, Yan Zhuang, Xi Zhao, Min Zhang, Shansheng Xu, and Baiquan Wang. "Controlled/living radical polymerization of styrene catalyzed by cobaltocene." Polymer 49, no. 16 (July 2008): 3457–61. http://dx.doi.org/10.1016/j.polymer.2008.05.035.

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23

Pampaloni, Guido, and Ulrich Koelle. "Chemical and electrochemical studies on metal carbonyl/cobaltocene systems." Journal of Organometallic Chemistry 481, no. 1 (November 1994): 1–6. http://dx.doi.org/10.1016/0022-328x(94)85002-x.

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24

Inoue, Yoshio, Jiro Ishikawa, Masaaki Taniguchi, and Harukichi Hashimoto. "Cobaltocene-Catalyzed Reaction of Carbon Dioxide with Propargyl Alcohols." Bulletin of the Chemical Society of Japan 60, no. 3 (March 1987): 1204–6. http://dx.doi.org/10.1246/bcsj.60.1204.

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25

Urones-Garrote, E., D. Ávila-Brande, N. A. Katcho, A. Gómez-Herrero, A. R. Landa-Cánovas, E. Lomba, and L. C. Otero-Díaz. "Spherical carbon nanoparticles produced by direct chlorination of cobaltocene." Carbon 45, no. 8 (July 2007): 1699–701. http://dx.doi.org/10.1016/j.carbon.2007.04.022.

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26

Koo, Yun Hee, Ryo Yanagisawa, Won-Young Cha, Taniyuki Furuyama, Nagao Kobayashi, and Dongho Kim. "Electron photoejection from dianion of an expanded phthalocyanine." Journal of Porphyrins and Phthalocyanines 22, no. 05 (April 17, 2018): 437–42. http://dx.doi.org/10.1142/s1088424618500359.

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Photoelectron ejection from the dianion of pentabenzotriazasmaragdyrin (PBTAS) which is an expanded phthalocyanine, is observed using femtosecond transient absorption spectroscopy. The PBTAS dianion was produced by chemical reduction using excess cobaltocene as a reductant, which was confirmed by their steady-state absorption spectrum as compared to the absorption spectrum obtained by electrochemical reduction, and characterized by magnetic circular dichroism (MCD). Upon photoexcitation of the PBTASdianion, the generation of a radical anion was confirmed by the characteristic absorption peaks that are observed at 950 and 1000 nm. The radical anion was relaxed to form a dianion with a time constant of 0.7 ps.

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27

Wöhrle, Dieter, Natascha Baziakina, Olga Suvorova, Sergey Makarov, Valentina Kutureva, Elena Schupak, and Günter Schnurpfeil. "Phthalocyanine coatings on silica and zinc oxide: Synthesis and their activities in the oxidation of sulfide." Journal of Porphyrins and Phthalocyanines 08, no. 12 (December 2004): 1390–401. http://dx.doi.org/10.1142/s1088424604000751.

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The reactivity of phthalonitrile, tetrafluorophthalonitrile and 4,5-dibutoxyphthalonitrile with unmodified surfaces of ZnO and SiO 2 and with the modified systems SiO 2/ Cp 2 Co , ZnO / Cp 2 Co , SiO 2/ Zn ( AcAc )2 prepared by deposition of cobaltocene ( Cp 2 Co ) and zinc acetylacetonate Zn ( AcAc )2, was studied ("in-situ-synthesis") in processes of phthalocyanine coatings. The formation of structural uniform phthalocyanines on carriers were established by UV-vis and mass spectra. The compounds were used then to compare their catalytic and photocatalytic activities in the oxidation of sulfide as a test reaction.

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28

Schaper, T., and W. Preetz. "Darstellung, spektroskopische Charakterisierung und Kristallstruktur von Dicyclopentadienylcobalt-hexahydro-closo-hexaborat [(C5H5)Co(C5H4)B6H5Hfac]/ Synthesis, Spectroscopic Characterization and Crystal Structure of Dicyclopentadienyl- cobalt-hexahydro-closo-hexaborate [(C5H5)Co(C5H4)B6H5Hfac]." Zeitschrift für Naturforschung B 53, no. 8 (August 1, 1998): 819–22. http://dx.doi.org/10.1515/znb-1998-0806.

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Abstract By reaction of [B6H6Hfac]- with cobaltocene in acetonitrile [(C5H5)Co(C5H4)B6H5Hfac] is formed. Its crystal structure has been determined by single crystal X-ray diffraction analysis (monoclinic, space group P21/n with a = 9.786(2), b = 9.726(2), c = 13.938(2) A, β = 107.2850(3)°, Z = 4). The B6 octahedron is slightly compressedoin the direction of the B-C bond by about 1%, with B-B bond lengths between 1.69 and 1.87 A. The 11B NMR spectrum exhibits a 1:4:1 pattern of a monosubstituted B6 cage. In the IR and Raman spectra characteristic B-H vibrations are observed.

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29

Zlatar, Matija, Carl-Wilhelm Schläpfer, Emmanuel Penka Fowe, and Claude A. Daul. "Density functional theory study of the Jahn-Teller effect in cobaltocene." Pure and Applied Chemistry 81, no. 8 (July 31, 2009): 1397–411. http://dx.doi.org/10.1351/pac-con-08-06-04.

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A detailed discussion of the potential energy surface of bis(cyclopentadienyl)cobalt(II), cobaltocene, is given. Vibronic coupling coefficients are calculated using density functional theory (DFT). Results are in good agreement with experimental findings. On the basis of our calculation there is no second-order Jahn–Teller (JT) effect as predicted by group theory. The JT distortion can be expressed as a linear combination of all totally symmetric normal modes of the low-symmetry, minimum-energy conformation. The out-of-plane ring deformation is the most important mode. The JT distortion is analyzed by seeking the path of minimal energy of the adiabatic potential energy surface.

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30

Henrion, O., and W. Jaegermann. "Surface redox reactions of cobaltocene adsorbed onto pyrolytic graphite (HOPG)." Surface Science 387, no. 1-3 (October 1997): L1073—L1078. http://dx.doi.org/10.1016/s0039-6028(97)00514-1.

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31

MacInnes, Molly M., Sofiya Hlynchuk, Saurabh Acharya, Nicolai Lehnert, and Stephen Maldonado. "Reduction of Graphene Oxide Thin Films by Cobaltocene and Decamethylcobaltocene." ACS Applied Materials & Interfaces 10, no. 2 (December 14, 2017): 2004–15. http://dx.doi.org/10.1021/acsami.7b15599.

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32

Clerc, D. G., and D. A. Cleary. "Lithium intercalation into cobaltocene-intercalated tin disulfide (SnS2{CoCp2}x)." Chemistry of Materials 6, no. 1 (January 1994): 13–14. http://dx.doi.org/10.1021/cm00037a004.

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33

Bildstein, Benno, Andreas Hradsky, Karl-Hans Ongania, and Klaus Wurst. "Redox disproportionation and radical coupling products of formyl(pentamethyl)cobaltocene." Journal of Organometallic Chemistry 563, no. 1-2 (July 1998): 219–25. http://dx.doi.org/10.1016/s0022-328x(98)00567-1.

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34

Ibarz, Anna, Eliseo Ruiz, and Santiago Alvarez. "Theoretical study of the intercalation of cobaltocene in metal chalcogenides." Journal of Materials Chemistry 8, no. 8 (1998): 1893–900. http://dx.doi.org/10.1039/a802240b.

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35

Hwang, Byunghyun, Min-Sik Park, and Ketack Kim. "Ferrocene and Cobaltocene Derivatives for Non-Aqueous Redox Flow Batteries." ChemSusChem 8, no. 2 (November 26, 2014): 310–14. http://dx.doi.org/10.1002/cssc.201403021.

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36

Clerc, D. G., and D. A. Cleary. "A study of the mechanism of cobaltocene intercalation in Cd2P2S6." Journal of Physics and Chemistry of Solids 56, no. 1 (January 1995): 69–78. http://dx.doi.org/10.1016/0022-3697(94)00138-3.

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37

Fiaud, Jean-Claude, Remi Chauvin, and Robert Bloch. "Flash-vacuum pyrolysis of η5-cyclopentadienyl-dicarbonylcobalt. formation of cobaltocene." Journal of Organometallic Chemistry 315, no. 1 (November 1986): C32—C34. http://dx.doi.org/10.1016/0022-328x(86)80427-2.

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38

Richer, G., and C. Sandorfy. "The far-ultraviolet absorption spectra of ferrocene, cobaltocene, and nickelocene." Journal of Molecular Structure: THEOCHEM 123, no. 3-4 (August 1985): 317–27. http://dx.doi.org/10.1016/0166-1280(85)80174-3.

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39

Ruhlandt-Senge, Karin, Irina Sens, and Ulrich Müller. "Die Bildung von [Co(C5H5)2]NO3 und [Co(C5H5)2]2[Co(NCO)4] aus Cobaltocen, Ozon und Acetonitril sowie deren Kristallstrukturen / Formation of [Co(C5H5)2]NO3 and [Co(C5H5)2]2[Co(NCO)4] from Cobaltocene, Ozone and Acetonitrile and their Crystal Structures." Zeitschrift für Naturforschung B 46, no. 12 (December 1, 1991): 1689–93. http://dx.doi.org/10.1515/znb-1991-1218.

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The title compounds were obtained by the reaction of cobaltocene with ozone in acetonitrile at -40°C. Their crystal structures were determined by X-ray diffraction. [Co(C5H5)2]NO3: orthorhombic, space group Pnma, a = 1566.4(3), b = 831.6(2), c = 765.7(1) pm, Z = 4, R = 0.055 for 587 observed unique reflexions. [Co(C5H5)2]2[Co(NCO)4]: monoclinic, P 2,/c, a = 1792.6(8), b = 2079.2(9), c = 1311(1) pm, β = 99.18(6)°, Ζ = 8, R = 0.067 for 2994 reflexions. Both compounds contain sandwich-type cobalticenium ions. The cyanato group of the [Co(NCO)4]2- ions are bonded to Co via their N atoms with CoNC angles ranging between 160 and 173°.

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40

Garcia, Beatriz Ortega, Oxana Kharissova, Francisco Servando Aguirre-Tostado, and Rasika Dias. "Synthesis and Study of Carbon Nanotubes by the Spray Pyrolysis Method Using Different Carbon Sources." MRS Proceedings 1752 (2015): 31–38. http://dx.doi.org/10.1557/opl.2015.208.

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ABSTRACTAccording to the reports of Z.E. Horvath et al [1] and Liu Yun-quan et al [5], carbon nanotubes can be synthesized by spray pyrolysis from different carbon sources (n-pentane, n-hexane, n-heptane, cyclohexane, toluene and acrylonitrile) and several metallocene catalysts (ferrocene, cobaltocene and nickelocene). This paper describes two different existing methods for growth of carbon nanotubes and the influence of applied parameters (oven temperature, synthesis time, catalyst concentration, carrier gas flow and solution flow) on the CNT's morphology. Also, a possible influence of number of carbons in carbon sources and structures of their compounds (linear or aromatic) on properties of formed carbon nanotubes. Transmission Electron Microscopy (TEM), Infrared Spectroscopy (FTIR) and Raman spectroscopy were applied for characterization of obtained materials.

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41

Fronzoni, G., M. Stener, S. Furlan, and P. Decleva. "Theoretical study of the photoionization shape resonances of cobaltocene and nickelocene." Chemical Physics 273, no. 2-3 (November 2001): 117–33. http://dx.doi.org/10.1016/s0301-0104(01)00494-3.

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42

Formstone, C. A., E. T. FitzGerald, P. A. Cox, and D. O'Hare. "Photoelectron spectroscopy of the tin dichalcogenides SnS2-xSex intercalated with cobaltocene." Inorganic Chemistry 29, no. 19 (September 1990): 3860–66. http://dx.doi.org/10.1021/ic00344a041.

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43

Tanaka, H., H. Yamakado, and K. Ohno. "Penning ionization of cobaltocene by collision with He*(23S) metastable atoms." Journal of Electron Spectroscopy and Related Phenomena 88-91 (March 1998): 149–54. http://dx.doi.org/10.1016/s0368-2048(97)00227-2.

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44

Hernan, L., J. Morales, L. Sanchez, J. L. Tirado, J. P. Espinos, and A. R. Gonzalez Elipe. "Diffraction and XPS Studies of Misfit Layer Chalcogenides Intercalated with Cobaltocene." Chemistry of Materials 7, no. 8 (August 1995): 1576–82. http://dx.doi.org/10.1021/cm00056a026.

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45

Torres-Gómez, Luis Alfonso, Guadalupe Barreiro-Rodríguez, and Francisco Méndez-Ruíz. "Vapour pressures and enthalpies of sublimation of ferrocene, cobaltocene and nickelocene." Thermochimica Acta 124 (February 1988): 179–83. http://dx.doi.org/10.1016/0040-6031(88)87020-5.

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46

Chan, Calvin K., Antoine Kahn, Qing Zhang, Stephen Barlow, and Seth R. Marder. "Incorporation of cobaltocene as an n-dopant in organic molecular films." Journal of Applied Physics 102, no. 1 (July 2007): 014906. http://dx.doi.org/10.1063/1.2752145.

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47

Bochkarev, M. N., and M. E. Burin. "Neodymium and dysprosium diiodides in the synthesis of vanadocene and cobaltocene." Russian Chemical Bulletin 53, no. 10 (October 2004): 2179–81. http://dx.doi.org/10.1007/s11172-005-0094-x.

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48

Titov, A. N., O. N. Suvorova, S. Yu Ketkov, S. G. Titova, and A. I. Merentsov. "Synthesis and investigation of titanium diselenide intercalated with ferrocene and cobaltocene." Physics of the Solid State 48, no. 8 (August 2006): 1466–71. http://dx.doi.org/10.1134/s1063783406080075.

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49

DuBois, Daniel L., Charles W. Eigenbrot, Alex Miedaner, James C. Smart, and R. Curtis Haltiwanger. "Synthesis, molecular structure, and molybdenum complexes of 1,1'-bis(diphenylphosphino)cobaltocene." Organometallics 5, no. 7 (July 1986): 1405–11. http://dx.doi.org/10.1021/om00138a018.

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50

Hwang, Byunghyun, Min-Sik Park, and Ketack Kim. "Corrigendum: Ferrocene and Cobaltocene Derivatives for Non-Aqueous Redox Flow Batteries." ChemSusChem 8, no. 10 (May 22, 2015): 1641. http://dx.doi.org/10.1002/cssc.201500619.

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