Academic literature on the topic 'Coordinat polydente'

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Journal articles on the topic "Coordinat polydente"

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Andjelkovic, Katarina, Gordana Jakovljevic, Mario Zlatovic, et al. "Synthesis and characterization of zinc(II), palladium(II) and platinum(II) complexes with 2’-[1-(2-pyridinyl)- ethylidene]oxamohydrazide: The crystal structure of biss2'-[1-(2-pyridinyl)ethylidene]oxa." Journal of the Serbian Chemical Society 69, no. 8-9 (2004): 651–60. http://dx.doi.org/10.2298/jsc0409651a.

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Complexes of Zn(II), Pd(II) and Pt(II) with 2?-[1-(2-pyridinyl)ethylidene ]oxamohydrazide (Hapsox) were synthesized and their structures were determined. All the complexes are of a neutral type with two apsox ligands coordinated to Zn(II) and one apsox ligand coordinated to Pd(II) or Pt(II). In each case, the polydentate was coordinated via pyridine and hydrazone nitrogens and ?-oxyazine oxygen, forming an octahedral geometry around Zn(II), and a square planar one around Pd(II) and Pt(II). The structure determination was performed by IR, 1H-NMR and 13C-NMR spectroscopy, and for the Zn(II) comp
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Avecilla, Fernando, Pedro Adão, Isabel Correia, and João Costa Pessoa. "Influence of polydentate ligands in the structure of dinuclear vanadium compounds." Pure and Applied Chemistry 81, no. 7 (2009): 1297–311. http://dx.doi.org/10.1351/pac-con-08-09-16.

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A review discussing general structural features of oxygen-bridged dinuclear vanadium(IV and/or V) complexes is presented, covering those that have been characterized by single-crystal X-ray diffraction. Many of these compounds contain functional Schiff bases or amines as ligands, this work illustrating the high propensity of the V center to increase its coordination number via dimerization of two tetra- or penta-coordinate monomers, if the steric and electronic control exerted by the ligands allows it. We also report the synthesis and characterization by single-crystal X-ray diffraction of two
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Mautner, Franz A., Roland C. Fischer, Ana Torvisco, et al. "Five-Coordinated Geometries from Molecular Structures to Solutions in Copper(II) Complexes Generated from Polydentate-N-Donor Ligands and Pseudohalides." Molecules 25, no. 15 (2020): 3376. http://dx.doi.org/10.3390/molecules25153376.

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A novel series of mononuclear five-coordinated pseudohalido-Cu(II) complexes displaying distorted square bipyramidal: [Cu(L1)(NCS)2] (1), [Cu(L2)(NCS)2] (2) and [Cu(L3)(NCS)]ClO4 (5) as well as distorted trigonal bipyramidal: [Cu(isp3tren)(N3)]ClO4 (3), [Cu(isp3tren)(dca)]ClO4 (4) and [Cu(tedmpza)(dca)]ClO4·0.67H2O (6) geometries had been synthesized and structurally characterized using X-ray single crystal crystallography, elemental microanalysis, IR and UV-vis spectroscopy, and molar conductivity measurements. Different N-donor amine skeletons including tridentate: L1 = [(2-pyridyl)-2-ethyl)
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Shihada, Abdel-Fattah, Frank Weller, and Werner Massa. "Between MOFs and molecules: organolead(IV) compounds with chain structures." Acta Crystallographica Section C Structural Chemistry 74, no. 5 (2018): 523–28. http://dx.doi.org/10.1107/s2053229618004850.

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Organolead compounds are of interest mainly as catalysts and organolead halides have proved to be very efficient materials for solar cells. Two organolead(IV) dimethylarsinates, namely catena-poly[[triphenyllead(IV)]-μ-chlorido-[triphenyllead(IV)]-μ-dimethylarsinato-κ2 O:O′], [Pb2(C6H5)6(C2H6AsO2)Cl] n or [(Ph3Pb)2Cl(O2AsMe2)], (1), and poly[chlorido(μ3-dimethylarsinato-κ3 O:O,O′:O′)diphenyllead(IV)], [Pb(C6H5)2(C2H6AsO2)Cl] n or [(Ph2ClPb)(O2AsMe2)], (2), together with the triphenyllead(IV) diphenylphosphinate catena-poly[[triphenyllead(IV)]-μ-diphenylphosphinato-κ2 O:O′], [Pb(C6H5)3(C12H10O2
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Rybak-Akimova, Elena V., Alexander Y. Nazarenko, Lisa Chen, et al. "Synthesis, characterization, redox properties, and representative X-ray structures of four- and five-coordinate copper(II) complexes with polydentate aminopyridine ligands." Inorganica Chimica Acta 324, no. 1-2 (2001): 1–15. http://dx.doi.org/10.1016/s0020-1693(01)00495-9.

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Coulter, Kevin R., Alexander McAuley, and Steven Rettig. "Synthesis and characterization of the pentadentate macrobicyclic ligand, 14-thia-1,4,8,11-tetraazabicyclo[9.5.3]nonadecane (L1) and its nickel(II) complexes. X-ray crystal structure of [Ni(L1)(ClO4)](ClO4)·2[Ni(L1)(OH2)](ClO4)2·6H2O." Canadian Journal of Chemistry 79, no. 5-6 (2001): 930–37. http://dx.doi.org/10.1139/v00-207.

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The pentadentate macrobicycle,14-thia-1,4,8,11-tetraazabicyclo[9.5.3]nonadecane (L1), has been synthesized by high dilution cyclization of 1-thia-4,8-diazacyclododecane ([10]aneN2S) (2) with N,N'-bis(α-chloro acetamido) propane (3) and subsequent reduction of the di-oxo intermediate. The structure of the [Ni(L1)(ClO4)](ClO4)·2[Ni(L1)(OH2)](ClO4)2·6H2O complex (monoclinic, P21/c, a = 13.9261(4) Å, b = 30.279(2) Å, c = 17.1248(3) Å, β = 94.5065(3)°) at R = 0.039 (Rw = 0.034) for 911 parameters using 18 266 reflections with I > 3σI has been determined. The ligand adopts a trans-III configurati
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Boere, Rene T., W. Mark Brown, Douglas W. Stephan, and Christopher J. Willis. "Coordination modes of polydentate ligands. 3. Five-coordinate complexes of cobalt(2+), copper(2+), and nickel(2+) containing a tridentate thioether-alkoxy ligand." Inorganic Chemistry 24, no. 4 (1985): 593–97. http://dx.doi.org/10.1021/ic00198a032.

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Solihah Khaidir, Siti, Hadariah Bahron, Amalina Mohd Tajuddin, Kalavathy Ramasamy, and Siong Meng Lim. "High Nuclearity Cu(II) and Co(II) complexes of Schiff Base Derived from o-vanillin with substituted m-phenylenediamine." International Journal of Engineering & Technology 7, no. 3.11 (2018): 72. http://dx.doi.org/10.14419/ijet.v7i3.11.15933.

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In the present work, a polydentate Schiff base ligand (SB) was synthesized via condensation reaction between o-vanillin and Cl-m-phenylenediamine. Dinuclear complexes of Co(II) and Cu(II) were prepared by conventional method with SB:metal ratio of 1:1 whereas tetranuclear complexes were obtained via microwave-assisted synthesis with SB:metal ratio of 1:2. Characterization was carried out through elemental analysis (C,H,N), molar conductivity, magnetic susceptibility, Fourier Transform Infrared (FTIR), and Nuclear Magnetic Resonance (NMR) spectroscopy. The experimental data indicated that the m
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Mikhalyova, Elena A., Swiatoslaw Trofimenko, Matthias Zeller, Anthony W. Addison, and Vitaly V. Pavlishchuk. "New homodinuclear tris(3-alkylpyrazolyl)borate complexes of CoIIand NiIIwith a tetraacetylethane dianion as a bridging ligand." Acta Crystallographica Section C Structural Chemistry 72, no. 11 (2016): 777–85. http://dx.doi.org/10.1107/s205322961601398x.

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Polynuclear complexes and coordination polymers of 3dmetals have attracted significant interest evoked by a number of their unique properties. One of the most common approaches to the directed synthesis of coordination polymers is the linking of pre-prepared discrete coordination units by polydentate ligands. The formation of polynuclear complexes is usually a spontaneous process and precise prediction of the products of such reactions is virtually impossible in most cases. Tris(pyrazolyl)borates (Tp) act as tripodal `capping' ligands which form stable complexes with 3dmetal ions. In such 1:1
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MacBeth, Cora E., Seth B. Harkins, and Jonas C. Peters. "Synthesis and characterization of cationic iron complexes supported by the neutral ligands NPi-Pr3, NArPi-Pr3, and NSt-Bu3." Canadian Journal of Chemistry 83, no. 4 (2005): 332–40. http://dx.doi.org/10.1139/v05-017.

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This paper compares the local geometries, spin states, and redox properties of a series of iron complexes supported by neutral, tetradentate NP3 (tris(phosphine)amine) and NS3 (tris(thioether)amine) ligands. Our consideration of an Fe-mediated N2 fixation scheme similar to that proposed by Chatt for molybdenum motivates our interest in systems of these types. This report specifically describes the synthesis and characterization of cationic Fe(II) chloride complexes supported by the neutral ligands NPi-Pr3 (NPi-Pr3 = [N(CH2CH2P-i-Pr2)3]), NArPi-Pr3 (NArPi-Pr3 = [N(2-diisopropylphosphine-4-methy
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Dissertations / Theses on the topic "Coordinat polydente"

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Mabad, Bouchra. "Modelisation du site d'oxydation de l'eau en photosynthese : complexes du manganese avec des bases de schiff polydentees." Toulouse 3, 1987. http://www.theses.fr/1987TOU30103.

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