Relevant bibliographies by topics / Corey-Chaykovsky reaction

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Academic literature on the topic 'Corey-Chaykovsky reaction'

Author: Grafiati
Published: 4 June 2021
Last updated: 25 July 2025

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Journal articles on the topic "Corey-Chaykovsky reaction"

1

Connon, S., S. Kavanagh, and A. Piccinini. "Organocatalytic Corey-Chaykovsky Reaction of Ketones." Synfacts 2010, no. 12 (2010): 1418. http://dx.doi.org/10.1055/s-0030-1258931.

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Suchandra, Chakraborty, Basu Kaushik, and Saha Chandan. "Distinction between the reactivity of phosphorus ylide vs sulfur ylide with the carbonyl compounds : Simplicity and logic." Education in Chemical Science and Technology Vol. 2, Aug 2022 (2022): 9–24. https://doi.org/10.5281/zenodo.6813268.

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Department of Clinical and Experimental Pharmacology, School of Tropical Medicine, Kolkata-700 073, India E-mail : cskatichandan@gmail.com Department of Chemistry, St. Paul's Cathedral Mission College, Kolkata-700 009, India Wittig olefination and Corey-Chaykovsky epoxidation of carbonyl compounds are well-documented classical and synthetically useful name reactions which are taught in great details in both undergraduate and post-graduate curricula of organic chemistry. Whilst similar reagents (a phosphorus ylide in Wittig olefination and a sulfur ylide in Corey-Chaykovsky epoxidation) and
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Cheng, Bin, Bing Zu, Yuntong Li, et al. "Synthesis of CF3-containing spiro-epoxyoxindoles via the Corey–Chaykovsky reaction of N-alkyl isatins with Ph2S+CH2CF3OTf−." Organic & Biomolecular Chemistry 16, no. 19 (2018): 3564–67. http://dx.doi.org/10.1039/c8ob00602d.

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CF<sub>3</sub>-containing spiro-epoxyoxindoles were successfully prepared via Corey–Chaykovsky reaction of N-alkyl isatins with the ylide generated from Ph<sub>2</sub>S<sup>+</sup>CH<sub>2</sub>CF<sub>3</sub>OTf<sup>−</sup> with almost exclusive diastereoselectivity.
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4

Ciaccio, James A., and Courtney E. Aman. "“Instant Methylide” Modification of the Corey–Chaykovsky Cyclopropanation Reaction." Synthetic Communications 36, no. 10 (2006): 1333–41. http://dx.doi.org/10.1080/00397910500521837.

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Suigo, Lorenzo, Giulia Lodigiani, Valentina Straniero, and Ermanno Valoti. "(3-Methylene-2,3-dihydronaphtho[2,3-b][1,4]dioxin-2-yl)methanol." Molbank 2022, no. 4 (2022): M1521. http://dx.doi.org/10.3390/m1521.

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(3-Methylene-2,3-dihydronaphtho[2,3-b][1,4]dioxin-2-yl)methanol was unexpectedly achieved as the main reaction product while applying a standard Johnson–Corey–Chaykovsky procedure to the 2,3-dihydronaphtho[2,3-b][1,4]dioxine-2-carbaldehyde, aiming at obtaining the corresponding epoxide. The structure of the recovered compound was confirmed through NMR and HRMS, the melting point was measured by DSC, and the organic purity was assessed using HPLC. We hypothesized the possible mechanism for the obtainment of this side product, which should involve the opening of the dioxane ring soon after the n
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Alfonzo, Edwin, Jesse W. L. Mendoza, and Aaron B. Beeler. "One-pot synthesis of epoxides from benzyl alcohols and aldehydes." Beilstein Journal of Organic Chemistry 14 (September 3, 2018): 2308–12. http://dx.doi.org/10.3762/bjoc.14.205.

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A one-pot synthesis of epoxides from commercially available benzyl alcohols and aldehydes is described. The reaction proceeds through in situ generation of sulfonium salts from benzyl alcohols and their subsequent deprotonation for use in Corey–Chaykovsky epoxidation of aldehydes. The generality of the method is exemplified by the synthesis of 34 epoxides that were made from an array of electronically and sterically varied alcohols and aldehydes.
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Ivanova, Olga A., Vitaly V. Shorokhov, Ivan A. Andreev, et al. "Synthesis of 2-[2-(Ethoxymethoxy)phenyl]spiro[cyclopropane-1,2′-indene]-1′,3′-dione." Molbank 2023, no. 1 (2023): M1604. http://dx.doi.org/10.3390/m1604.

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An 1,3-indanedione-derived donor–acceptor cyclopropane, bearing the ethoxymethyl-protected phenolic group at the ortho-position of the donor aryl substituent, has been synthesized using a reaction sequence involving the Knoevenagel condensation of 1,3-indanedione with the corresponding protected salicylaldehyde followed by the Corey–Chaykovsky cyclopropanation of the obtained adduct with dimethylsulfoxonium methylide. The structure of the synthesized cyclopropane was unambiguously proved by single-crystal X-ray diffraction data.
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Hajra, Saumen, Sayan Roy, and SK Abu Saleh. "Domino Corey–Chaykovsky Reaction for One-Pot Access to Spirocyclopropyl Oxindoles." Organic Letters 20, no. 15 (2018): 4540–44. http://dx.doi.org/10.1021/acs.orglett.8b01840.

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Jamieson, Megan, Nicola Brant, Margaret Brimble, and Daniel Furkert. "Remarkable Influence of Cobalt Catalysis on Epoxide Ring-Opening with Sulfoxonium Ylides." Synthesis 49, no. 17 (2017): 3952–56. http://dx.doi.org/10.1055/s-0036-1588814.

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Cobalt demonstrates a remarkable ability to catalytically divert the course of epoxide to oxetane ring expansion via reaction with a sulfoxonium ylide. An expanded survey of transition-metal catalysts has confirmed that cobalt salts uniquely instead deliver homoallylic alcohol products from epoxides, with retention of the original epoxide stereochemistry. The reaction is an unusual example of cobalt-catalysed epoxide­ ring-opening by a carbon nucleophile. A tandem Corey–Chaykovsky/epoxide olefination sequence giving homoallylic alcohols from aldehydes is further demonstrated along with prelimi
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10

Mihara, Yurina, Haruki Kadoya, Soki Kakihana, and Naoyuki Kotoku. "Concise and Stereospecific Total Synthesis of Arenastatin A and Its Segment B Analogs." Molecules 29, no. 17 (2024): 4058. http://dx.doi.org/10.3390/molecules29174058.

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A novel and concise synthetic method for arenastatin A, a cytotoxic cyclic depsipeptide of marine origin, was developed in this study. The convergent assembly of the four segments, including the cross-metathesis reaction, gave a cyclization precursor, and Fmoc deprotection caused simultaneous macrocyclization. The Corey–Chaykovsky reaction using a chiral sulfur ylide afforded arenastatin A with complete stereoselectivity in the longest linear sequence of seven reaction steps from the known compound. Using this synthetic method, some analogs of segment B were prepared through a late-stage diver
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Dissertations / Theses on the topic "Corey-Chaykovsky reaction"

1

Myllymäki, V. (Vesa). "Design, synthesis and testing of new chiral sulfide catalysts for Corey-Chaykovsky reaction." Doctoral thesis, University of Oulu, 2001. http://urn.fi/urn:isbn:9514265718.

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Abstract The first part of this monograph discusses the asymmetric, ylide based, reagent controlled epoxidations. Both different chiral ylides and epoxidation processes, stoichiometric and catalytic, are reviewed. In the following part, new chiral sulfide catalysts were discovered as enantioselective catalysts for the Corey-Chaykovsky reaction (epoxidation of aldehydes via sulfonium ylides). Using a crystal structure of an oxazolidine derivative as a starting point, a thiazolidine ligand family was designed, synthesized and finally employed as catalysts in the asymmetric epoxidation
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2

Liu, Ting-Chun, and 劉庭均. "The substituent effect on the reaction of 2-hydroxybenzophenones with Corey-Chaykovsky reagents." Thesis, 2007. http://ndltd.ncl.edu.tw/handle/17366160386166342745.

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碩士<br>國立清華大學<br>化學系<br>95<br>This thesis aims at the studies on the novel rearrangement of 2-hydroxybenzophenone on reaction with Corey-Chaykovsky reagent. The first part is concerned with the effects of substituents on 2-hydroxybenzophenone and the second part describes the plausible mechanism for the observed products. 　　When n-butyllithium (n-BuLi) was used as base in tetrahydrofuran (THF) to generate Corey-Chaykovsky reagent, it was found that the reagent had totally different reactivity towards the substrate in comparison to Corey-Chaykovsky reagent prepared using sodium hydride (NaH) as
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Book chapters on the topic "Corey-Chaykovsky reaction"

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Li, Jie Jack. "Corey-Chaykovsky reaction." In Name Reactions. Springer Berlin Heidelberg, 2003. http://dx.doi.org/10.1007/978-3-662-05336-2_70.

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Li, Jie Jack. "Corey–Chaykovsky reaction." In Name Reactions. Springer International Publishing, 2014. http://dx.doi.org/10.1007/978-3-319-03979-4_70.

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Li, Jie Jack. "Corey–Chaykovsky reaction." In Name Reactions. Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-642-01053-8_63.

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Li, Jie Jack. "Corey−Chaykovsky Reaction." In Name Reactions. Springer International Publishing, 2021. http://dx.doi.org/10.1007/978-3-030-50865-4_35.

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Li, Jie Jack. "Corey-Chaykovsky epoxidation." In Name Reactions. Springer Berlin Heidelberg, 2002. http://dx.doi.org/10.1007/978-3-662-04835-1_64.

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6

Brière, Jean-François, Stéphane Perrio, and Vincent Reboul. "Corey-Chaykovsky Reaction and Related Processes." In Reference Module in Chemistry, Molecular Sciences and Chemical Engineering. Elsevier, 2024. http://dx.doi.org/10.1016/b978-0-323-96025-0.00039-9.

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