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Journal articles on the topic 'Covalent organic framework'

Author: Grafiati

Published: 4 June 2021

Last updated: 26 July 2025

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1

Fan, Hongwei, Alexander Mundstock, Armin Feldhoff, et al. "Covalent Organic Framework–Covalent Organic Framework Bilayer Membranes for Highly Selective Gas Separation." Journal of the American Chemical Society 140, no. 32 (2018): 10094–98. http://dx.doi.org/10.1021/jacs.8b05136.

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2

Tao, You, Wenyan Ji, Xuesong Ding, and Bao-Hang Han. "Exfoliated covalent organic framework nanosheets." Journal of Materials Chemistry A 9, no. 12 (2021): 7336–65. http://dx.doi.org/10.1039/d0ta12122c.

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3

Wang, Song, Yuhao Yang, Haoran Zhang, et al. "Toward Covalent Organic Framework Metastructures." Journal of the American Chemical Society 143, no. 13 (2021): 5003–10. http://dx.doi.org/10.1021/jacs.0c13090.

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4

He, Guangwei, Runnan Zhang, and Zhongyi Jiang. "Engineering Covalent Organic Framework Membranes." Accounts of Materials Research 2, no. 8 (2021): 630–43. http://dx.doi.org/10.1021/accountsmr.1c00083.

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5

Li, Li-Hua, Xiao-Lin Feng, Xiao-Hui Cui, Yun-Xiang Ma, San-Yuan Ding, and Wei Wang. "Salen-Based Covalent Organic Framework." Journal of the American Chemical Society 139, no. 17 (2017): 6042–45. http://dx.doi.org/10.1021/jacs.7b01523.

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6

Guo, Hongxia, Junhua Wang, Qianrong Fang, et al. "A quaternary-ammonium-functionalized covalent organic framework for anion conduction." CrystEngComm 19, no. 33 (2017): 4905–10. http://dx.doi.org/10.1039/c7ce00042a.

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A new anion conducting covalent organic framework (COF) was prepared by covalently tethering quaternary ammonium (QA) ions onto the pore walls of COF 1,3,5-triformylphloroglucinol-o-tolidine (TpBD-Me) through bromination and quaternization.

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7

Zhang, Yeru. "Research Progress on Iodine Capture by Covalent Organic Framework Materials." Transactions on Materials, Biotechnology and Life Sciences 3 (March 24, 2024): 775–80. http://dx.doi.org/10.62051/12tcgb93.

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With the development of nuclear power, the removal of radionuclides is an important responsibility and task. Radioactive iodine, as one of the most radionuclide in nuclear wastes, its safe disposal is essential to ensure the sustainable development of the nuclear industry. Covalent organic framework materials are crystalline organic porous materials, which were constructed by covalent bonds. Because of their regular pore structure, large surface area and high chemical stability, covalent organic framework materials are selected as an ideal iodine capturing materials due to their structural cha

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8

Zhang, Weiwei, Linjiang Chen, Sheng Dai, et al. "Reconstructed covalent organic frameworks." Nature 604, no. 7904 (2022): 72–79. http://dx.doi.org/10.1038/s41586-022-04443-4.

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AbstractCovalent organic frameworks (COFs) are distinguished from other organic polymers by their crystallinity1–3, but it remains challenging to obtain robust, highly crystalline COFs because the framework-forming reactions are poorly reversible4,5. More reversible chemistry can improve crystallinity6–9, but this typically yields COFs with poor physicochemical stability and limited application scope5. Here we report a general and scalable protocol to prepare robust, highly crystalline imine COFs, based on an unexpected framework reconstruction. In contrast to standard approaches in which mono

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9

Yang, Heena, Iktae Kim, Youngdon Ko, Shindong Kim, and Whajung Kim. "Studies on Adsorption and Desorption of Ammonia Using Covalent Organic Framework COF-10." Applied Chemistry for Engineering 27, no. 3 (2016): 265–69. http://dx.doi.org/10.14478/ace.2016.1025.

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10

Zhu, Dongyang, Yifan Zhu, Qianqian Yan, et al. "Pure Crystalline Covalent Organic Framework Aerogels." Chemistry of Materials 33, no. 11 (2021): 4216–24. http://dx.doi.org/10.1021/acs.chemmater.1c01122.

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11

Dalapati, Sasanka, Shangbin Jin, Jia Gao, Yanhong Xu, Atsushi Nagai, and Donglin Jiang. "An Azine-Linked Covalent Organic Framework." Journal of the American Chemical Society 135, no. 46 (2013): 17310–13. http://dx.doi.org/10.1021/ja4103293.

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12

Liu, Yu, Weiqiang Zhou, Wei Liang Teo, et al. "Covalent-Organic-Framework-Based Composite Materials." Chem 6, no. 12 (2020): 3172–202. http://dx.doi.org/10.1016/j.chempr.2020.08.021.

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13

Zhang, Jian, Laibing Wang, Na Li, et al. "A novel azobenzene covalent organic framework." CrystEngComm 16, no. 29 (2014): 6547–51. http://dx.doi.org/10.1039/c4ce00369a.

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The first example of a novel Azo-linked 2D COF with a hexagonal skeleton, high crystallinity and permanent porosity. The trans-to-cis photoisomerization can lead to the decline of Azo-COF crystallinity but cannot impact the pore size of Azo-COF. The current results will provide a strategy for designing smart COF materials.

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14

Ding, San-Yuan, Li-Hua Li, Xiao-Lin Feng, and Wei Wang. "Salen-based crystalline covalent organic framework." Acta Crystallographica Section A Foundations and Advances 73, a2 (2017): C459. http://dx.doi.org/10.1107/s2053273317091148.

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15

Huang, Ning, Xuesong Ding, Jangbae Kim, Hyotcherl Ihee, and Donglin Jiang. "A Photoresponsive Smart Covalent Organic Framework." Angewandte Chemie International Edition 54, no. 30 (2015): 8704–7. http://dx.doi.org/10.1002/anie.201503902.

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16

Huang, Ning, Xuesong Ding, Jangbae Kim, Hyotcherl Ihee, and Donglin Jiang. "A Photoresponsive Smart Covalent Organic Framework." Angewandte Chemie 127, no. 30 (2015): 8828–31. http://dx.doi.org/10.1002/ange.201503902.

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17

Kim, Hyunwoo, Nayeong Kim, and Jungki Ryu. "Porous framework-based hybrid materials for solar-to-chemical energy conversion: from powder photocatalysts to photoelectrodes." Inorganic Chemistry Frontiers 8, no. 17 (2021): 4107–48. http://dx.doi.org/10.1039/d1qi00543j.

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18

Wang, Han, Hui Wang, Ziwei Wang, et al. "Covalent organic framework photocatalysts: structures and applications." Chemical Society Reviews 49, no. 12 (2020): 4135–65. http://dx.doi.org/10.1039/d0cs00278j.

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19

Cheng, Shi-Qi, Yi Liu, and Yue Sun. "Macrocycle-based metal–organic and covalent organic framework membranes." Coordination Chemistry Reviews 534 (July 2025): 216559. https://doi.org/10.1016/j.ccr.2025.216559.

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20

Zhu, Yao, Yue Qi, Xinghua Guo, et al. "A crystalline covalent organic framework embedded with a crystalline supramolecular organic framework for efficient iodine capture." Journal of Materials Chemistry A 9, no. 31 (2021): 16961–66. http://dx.doi.org/10.1039/d1ta03879f.

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A bicrystalline composite based on a triazine covalent organic framework (COF) and a bisbenzimidazole supramolecular organic framework (SOF) was prepared for the first time and used for adsorption of gaseous iodine.

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21

Bin Mahfouz, A. S., R. Nasir, H. A. Mannan, A. Abdulrahman, and D. F. Bt Mohshim. "Theoretical analysis of various permeation models for gas transport through a covalent organic framework (COF) mixed matrix membrane." Materialwissenschaft und Werkstofftechnik 54, no. 11 (2023): 1400–1406. http://dx.doi.org/10.1002/mawe.202300021.

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AbstractModeling and theoretical description of gas transport through mixed matrix membranes synthesized by including a covalent organic framework are essential for the efficient design of these membranes. This paper reports a theoretical analysis of various permeation models for gas transport through covalent organic framework‐based mixed matrix membranes. The existing models, such as Bruggeman, Maxwell, and Lewis Nielson, were analyzed. The Maxwell model calculated the permeation through voids and filler by considering interfacial defects in the covalent organic framework mixed matrix membra

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22

Li, Rebecca L., Anna Yang, Nathan C. Flanders, Michael T. Yeung, Daylan T. Sheppard, and William R. Dichtel. "Two-Dimensional Covalent Organic Framework Solid Solutions." Journal of the American Chemical Society 143, no. 18 (2021): 7081–87. http://dx.doi.org/10.1021/jacs.1c01683.

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23

Yao, Jin, Ya Lu, Huihui Sun, and Xin Zhao. "Pore Engineering for Covalent Organic Framework Membranes." Chemical Research in Chinese Universities 38, no. 2 (2022): 364–72. http://dx.doi.org/10.1007/s40242-022-1507-1.

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24

Ma, Yun-Xiang, Zhi-Jun Li, Lei Wei, San-Yuan Ding, Yue-Biao Zhang, and Wei Wang. "A Dynamic Three-Dimensional Covalent Organic Framework." Journal of the American Chemical Society 139, no. 14 (2017): 4995–98. http://dx.doi.org/10.1021/jacs.7b01097.

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25

Banerjee, Tanmay, Kerstin Gottschling, Gökcen Savasci, Christian Ochsenfeld, and Bettina V. Lotsch. "H2 Evolution with Covalent Organic Framework Photocatalysts." ACS Energy Letters 3, no. 2 (2018): 400–409. http://dx.doi.org/10.1021/acsenergylett.7b01123.

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26

Ding, Xuesong, Long Chen, Yoshihito Honsho, et al. "Ann-Channel Two-Dimensional Covalent Organic Framework." Journal of the American Chemical Society 133, no. 37 (2011): 14510–13. http://dx.doi.org/10.1021/ja2052396.

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27

Wang, Wei, Yun-Xiang Ma, Zhi-Jun Li, Tian-Qiong Ma, and Yue-Biao Zhang. "A dynamic three-dimensional covalent organic framework." Acta Crystallographica Section A Foundations and Advances 73, a2 (2017): C303. http://dx.doi.org/10.1107/s2053273317092701.

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28

Nagai, Atsushi, Xiong Chen, Xiao Feng, Xuesong Ding, Zhaoqi Guo, and Donglin Jiang. "A Squaraine-Linked Mesoporous Covalent Organic Framework." Angewandte Chemie 125, no. 13 (2013): 3858–62. http://dx.doi.org/10.1002/ange.201300256.

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29

Nagai, Atsushi, Xiong Chen, Xiao Feng, Xuesong Ding, Zhaoqi Guo, and Donglin Jiang. "A Squaraine-Linked Mesoporous Covalent Organic Framework." Angewandte Chemie International Edition 52, no. 13 (2013): 3770–74. http://dx.doi.org/10.1002/anie.201300256.

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30

Ding, Huimin, Yonghai Li, Hui Hu, et al. "A Tetrathiafulvalene-Based Electroactive Covalent Organic Framework." Chemistry - A European Journal 20, no. 45 (2014): 14614–18. http://dx.doi.org/10.1002/chem.201405330.

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31

Vazquez-Molina, Demetrius A., Giovanna M. Pope, Andrew A. Ezazi, Jose L. Mendoza-Cortes, James K. Harper, and Fernando J. Uribe-Romo. "Framework vs. side-chain amphidynamic behaviour in oligo-(ethylene oxide) functionalised covalent-organic frameworks." Chemical Communications 54, no. 50 (2018): 6947–50. http://dx.doi.org/10.1039/c8cc04292f.

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32

Wang, Zhifang, Sainan Zhang, Yao Chen, Zhenjie Zhang, and Shengqian Ma. "Covalent organic frameworks for separation applications." Chemical Society Reviews 49, no. 3 (2020): 708–35. http://dx.doi.org/10.1039/c9cs00827f.

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33

Zhang, Chen. "Visible-light-induced C-H Annulation by Metal-decorated Covalent Organic Frameworks with Fe-bipyridyl linkages." Highlights in Science, Engineering and Technology 69 (November 6, 2023): 455–62. http://dx.doi.org/10.54097/hset.v69i.12219.

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The integration of transition metal and photoredox catalyst achieves a harmonious cooperation between sophisticated chemical transformations and judicious utilization of light energy. The previous work was exclusively accomplished through employment of homogeneous transition-metal catalysts or photoredox catalysts. In this study, we present the synthesis of iron-decorated covalent organic frameworks (Fe-COF) and its application on C-H annulation of amides with alkynes by irradiation of visible light. The iron center prompts robust chelation with amides, leading to C-H activation, subsequently.

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34

Liang, Rong-Ran, Shu-Yan Jiang, Ru-Han A, and Xin Zhao. "Two-dimensional covalent organic frameworks with hierarchical porosity." Chemical Society Reviews 49, no. 12 (2020): 3920–51. http://dx.doi.org/10.1039/d0cs00049c.

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This review highlights the state-of-the-art progress achieved in two-dimensional covalent organic frameworks (COFs) with hierarchical porosity, an emerging class of COFs constructed by integrating different types of pores into one framework.

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35

Liu, Junxian, Kezhen Qi, Xianglin Xiang, Abdollah Jamal Sisi, Alireza Khataee, and Liqianyun Xu. "Covalent Organic Framework‐Based Photocatalysts from Synthesis to Applications." ENERGY & ENVIRONMENTAL MATERIALS, July 14, 2025. https://doi.org/10.1002/eem2.70071.

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Covalent organic frameworks have emerged as a hot spot in the field of photocatalysis due to their excellent structural tunability, high specific surface area, high porosity, and good chemical stability. Specifically, they exhibit distinctive optoelectronic features by integrating different molecular building blocks with appropriate links, constructing an π‐conjugated system, or introducing electron donor–acceptor units into the conjugated framework. The reasonably adjusted band structure yields excellent photocatalytic activity of covalent organic framework materials. In this review, we compr

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36

Tao, Xin, Zhen Wang, Qing-Pu Zhang, et al. "Covalent Organic Framework Nanohydrogels." Journal of the American Chemical Society, November 8, 2023. http://dx.doi.org/10.1021/jacs.3c10296.

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37

Liu, Minghao, Shuai Yang, Xiubei Yang, et al. "Post-synthetic modification of covalent organic frameworks for CO2 electroreduction." Nature Communications 14, no. 1 (2023). http://dx.doi.org/10.1038/s41467-023-39544-9.

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AbstractTo achieve high-efficiency catalysts for CO2 reduction reaction, various catalytic metal centres and linker molecules have been assembled into covalent organic frameworks. The amine-linkages enhance the binding ability of CO2 molecules, and the ionic frameworks enable to improve the electronic conductivity and the charge transfer along the frameworks. However, directly synthesis of covalent organic frameworks with amine-linkages and ionic frameworks is hardly achieved due to the electrostatic repulsion and predicament for the strength of the linkage. Herein, we demonstrate covalent org

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38

Marta, Martínez-Abadía, T. Stoppiello Craig, Strutynski Karol, et al. "A Wavy Two-Dimensional Covalent Organic Framework from Core-Twisted Polycyclic Aromatic Hydrocarbons." September 3, 2019. https://doi.org/10.5281/zenodo.5226366.

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A high degree of crystallinity is an essential aspect in two-dimensional covalent organic frameworks, as many properties depend strongly on the structural arrangement of the different layers and their constituents. We introduce herein a new design strategy based on core-twisted polycyclic aromatic hydrocarbon as rigid nodes that give rise to a two-dimensional covalent organic framework with a wavy honeycomb (chairlike) lattice. The concave–convex self-complementarity of the wavy two-dimensional lattice guides the stacking of framework layers into a highly stable and ordered covalent orga

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39

Martínez-Abadía, Marta, Craig T. Stoppiello, Karol Strutynski, et al. "A Wavy Two-Dimensional Covalent Organic Framework from Core- Twisted Polycyclic Aromatic Hydrocarbons." September 3, 2019. https://doi.org/10.1021/jacs.9b07383.

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A high degree of crystallinity is an essential aspect in two-dimensional covalent organic frameworks, as many properties depend strongly on the structural arrangement of the different layers and their constituents. We introduce herein a new design strategy based on core-twisted polycyclic aromatic hydrocarbon as rigid nodes that give rise to a two-dimensional covalent organic framework with a wavy honeycomb (chairlike) lattice. The concave−convex self- complementarity of the wavy two-dimensional lattice guides the stacking of framework layers into a hig

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40

"Three-Dimensional Covalent Organic Framework." Synfacts 19, no. 12 (2023): 1202. http://dx.doi.org/10.1055/s-0043-1763799.

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41

Kumar, Shubham, Kusum Kumari, Saurabh Kumar Kumar Singh, Bharatkumar Z. Dholakiya, and Ritambhara Jangir. "Amorphous Tetrazine-Triazine-Functionalized Covalent Organic Framework for Adsorption and Removal of Dyes." New Journal of Chemistry, 2023. http://dx.doi.org/10.1039/d3nj01913f.

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Environmental problems can potentially be solved by covalent organic frameworks (COFs) that contain predesigned porous architectures. Herein, we developed an amorphous Tetrazine-Triazine-functionalized Covalent Organic Framework (TzTPT-COF) by performing one-pot polycondensations...

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42

Zhou, Wei, Xiao Wang, Wenling Zhao, et al. "Photocatalytic CO2 reduction to syngas using metallosalen covalent organic frameworks." Nature Communications 14, no. 1 (2023). http://dx.doi.org/10.1038/s41467-023-42757-7.

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AbstractMetallosalen-covalent organic frameworks have recently gained attention in photocatalysis. However, their use in CO2 photoreduction is yet to be reported. Moreover, facile preparation of metallosalen-covalent organic frameworks with good crystallinity remains considerably challenging. Herein, we report a series of metallosalen-covalent organic frameworks produced via a one-step synthesis strategy that does not require vacuum evacuation. Metallosalen-covalent organic frameworks possessing controllable coordination environments of mononuclear and binuclear metal sites are obtained and ac

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43

Qin, Wei-Kang, Chen-Ho Tung, and Li-Zhu Wu. "Covalent organic framework and hydrogen-bonded organic framework for solar-driven photocatalysis." Journal of Materials Chemistry A, 2023. http://dx.doi.org/10.1039/d2ta09375h.

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The new emerging porous crystalline materials, covalent organic framework (COF) and hydrogen-bonded organic framework (HOF), are characterized for their large surface area, considerable structural diversity, and functional tailorability. Combining these...

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44

Martínez-Abadía, Marta, Karol Strutyński, Craig T. Stoppiello, et al. "Understanding charge transport in wavy 2D covalent organic frameworks." February 23, 2021. https://doi.org/10.5281/zenodo.7635634.

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Understanding charge transport in 2D covalent organic frameworks is crucial to increase their performance. Herein a new wavy 2D covalent organic framework has been designed, synthesized and studied to shine light on the structural factors that dominate charge transport.

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45

Martínez-Abadía, Marta, Karol Strutyński, Craig T. Stoppiello, et al. "Understanding charge transport in wavy 2D covalent organic frameworks." February 23, 2021. https://doi.org/10.1039/D0NR08962A.

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Understanding charge transport in 2D covalent organic frameworks is crucial to increase their performance. Herein a new wavy 2D covalent organic framework has been designed, synthesized and studied to shine light on the structural factors that dominate charge transport.

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46

Zhang, Lei, Qiu-Hong Zhu, Yue-Ru Zhou та ін. "Hydrogen-bonding and π-π interaction promoted solution-processable covalent organic frameworks". Nature Communications 14, № 1 (2023). http://dx.doi.org/10.1038/s41467-023-43905-9.

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AbstractCovalent organic frameworks show great potential in gas adsorption/separation, biomedicine, device, sensing, and printing arenas. However, covalent organic frameworks are generally not dispersible in common solvents resulting in the poor processability, which severely obstruct their application in practice. In this study, we develop a convenient top-down process for fabricating solution-processable covalent organic frameworks by introducing intermolecular hydrogen bonding and π-π interactions from ionic liquids. The bulk powders of imine-linked, azine-linked, and β-ketoenamine linked c

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47

Niu, Xiao, Shengda Qi, Jianong Sun, et al. "In situ growth of imine‐based covalent organic framework as stationary phase for open‐tubular capillary electrochromatographic separation." Journal of Separation Science 47, no. 2 (2024). http://dx.doi.org/10.1002/jssc.202300686.

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Designing advanced stationary phases to improve separation efficiency is essential in capillary electrochromatography. Due to their outstanding performance, covalent organic frameworks have recently demonstrated considerable promise in the field of separation science. Herein, an open‐tubular capillary electrochromatography method was reported using porous imine‐based covalent organic framework with sufficiently available interaction sites as stationary phase. The imine‐based covalent organic framework coated capillary was easily prepared via an in situ growth method at room temperature, and it

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48

Wei, Lei, Tu Sun, Zhaolin Shi, et al. "Guest-adaptive molecular sensing in a dynamic 3D covalent organic framework." Nature Communications 13, no. 1 (2022). http://dx.doi.org/10.1038/s41467-022-35674-8.

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AbstractMolecular recognition is an attractive approach to designing sensitive and selective sensors for volatile organic compounds (VOCs). Although organic macrocycles and cages have been well-developed for recognising organics by their adaptive pockets in liquids, porous solids for gas detection require a deliberate design balancing adaptability and robustness. Here we report a dynamic 3D covalent organic framework (dynaCOF) constructed from an environmentally sensitive fluorophore that can undergo concerted and adaptive structural transitions upon adsorption of gas and vapours. The COF is c

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49

Yadav, Kushagra, Praveen K. Budakoti, and S. R. Dhakate. "Unveiling the Electronic Properties of Metal-free and Undoped Covalent Organic Framework as a Semiconductor." Journal of Materials Chemistry C, 2023. http://dx.doi.org/10.1039/d3tc03648k.

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Covalent organic frameworks (COFs) are an emerging category of semiconducting material. In the present investigation, a conjugated covalent organic framework (PPDA-TFPT-COF) composed of p-phenylenediamine (PPDA) and 2,4,6-tris-(p-formylphenoxy)1,3,5-triazine (TFPT) was designed...

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50

Salemi, Hadi, Maarten Debruyne, Veronique Van Speybroeck, Pascal Van Der Voort, Matthias D'hooghe, and Christian V. Stevens. "Covalent Organic Framework supported Palladium Catalysts." Journal of Materials Chemistry A, 2022. http://dx.doi.org/10.1039/d2ta05234b.

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Covalent organic frameworks (COFs), as highly porous crystalline structures, are newly emerging materials designed with tuneable features. They have a high potential to be a host to immobilize metal catalysts....

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