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Dissertations / Theses on the topic 'Cyclocondensation'

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1

Leftwich, Timothy Ray. "Modification of silicon-based substrates with cyclocondensation and cycloaddition reactions." Access to citation, abstract and download form provided by ProQuest Information and Learning Company; downloadable PDF file, 111 p, 2010. http://proquest.umi.com/pqdweb?did=1992491831&sid=7&Fmt=2&clientId=8331&RQT=309&VName=PQD.

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2

Rocheville-Divorne, Catherine. "Etude de la réactivité de Delta² thiazolines avec les esters acétyléniques addition cycloaddition cyclocondensation /." Grenoble 2 : ANRT, 1987. http://catalogue.bnf.fr/ark:/12148/cb376094479.

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3

Ghirardi, Elena. "Enantio- and Diastereoselective Cyclocondensation Reactions. Stereocontrolled Access to Azabicycles and Application to Natural Product Synthesis." Doctoral thesis, Universitat de Barcelona, 2016. http://hdl.handle.net/10803/398789.

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The first objective of this Thesis was the study of the preparation of octhydro-1H-cyclopenta[b]pyridines and octahydro-1H-indoles, through the synthesis of (R)-phenylglycinol derived tricyclic lactams. Following the previous reported methodology a carbon substituent would be present at the carbocyclic ring and we planned to find the conditions for controlling its absolute configuration. Unfortunately, the reaction of ketoester 4 and ketoacid 7, provided undesired enamines 8 and 9. On the other hand, the reaction of ketoacid derivatives 16 and 17 with (R)-phenylglycinol led to a mixture of epi
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4

Rocheville-Divorne, Catherine. "Etude de la réactivité de delta 2 thiazolines avec les esters acétyléniques : addition cycloaddition cyclocondensation." Aix-Marseille 3, 1987. http://www.theses.fr/1987AIX30003.

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5

Roze, Jean-Claude. "Réactions de cyclocondensation méthodes d'accès à des dérivés thiaziniques, application à la synthèse de céphèmes polysubstitués /." Grenoble 2 : ANRT, 1986. http://catalogue.bnf.fr/ark:/12148/cb37600897s.

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6

Muraro, Paulo Isaias Rossato. "Uso de microondas na síntese de 3-alquil(aril)-5-hidróxi-5-triclorometil-4,5-diidro-1h-pirazol-1-carboxiamida." Universidade Federal de Santa Maria, 2005. http://repositorio.ufsm.br/handle/1/10399.

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A series of 3-alkyl and 3-aryl-5-hydroxy-5-trichloromethyl-4,5-dihydro-1Hpirazoles-1-carboxiamide that possess biological activity they were synthesized, in good yeld, through the cyclocondensation, in microwaves, of 4-alcoxi-1,1,1-trihalometyl-3alquen-2-onas with semicarbazyde chloride using MeOH/H2O as solvent. The advantage obtained with the use of irradiation of microwaves in relation to the classic methodology it is the decrease of the time reacional and revenue increase as it will be demonstrated.<br>Uma série de 3-alquil(aril) 5-hidroxi 5-triclorometil-4,5-diidropirazol-1-carboxiamida,
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7

Hamid, Abdulkareem. "Synthèse des analogues hétérocycliques des alcaloïdes, Camptothécine, Rutaecarpine, et Luotonine : agents à fort potentiel cytotoxique." Le Havre, 2006. http://www.theses.fr/2006LEHA0010.

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Dans le cadre d'une nouvelle thématique de recherche dans notre laboratoire, nous avons investi la synthèse des analogues d'alcaloïdes Camptothécine, Rutaecarpine et Luotonine reconnus pour leur fort potentiel cytotoxique. Dans la première partie de ce travail, consacrée à la synthèse d’analogues de la Camptothécine, nous avons exposé une nouvelle stratégie pour la construction des squelettes quinoléinopyrrolo-isoquinoléine, contenant l'enchaînement cyclique A→B→C→D→E de la Camptothécine et la 22-hydroxyacuminatine. Celle-ci est basée sur l'utilisation de la chimie des ions N-acyliminiums en a
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8

Prola, Liziê Daniela Tentler. "Síntese de 3-haloacetil-4-metilquinolinas utilizando líquido iônico sob irradiação de micro-ondas." Universidade Federal de Santa Maria, 2011. http://repositorio.ufsm.br/handle/1/10492.

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Conselho Nacional de Desenvolvimento Científico e Tecnológico<br>The synthesis of a series of 3-haloacetyl-4-methyl-quinolines from the cyclocondensation reaction of 4-alkoxyvinyl ketones [R1C(O)CH=C(R2)(OCH3), where R1 = CF3, CCl3, CHCl2, CF2Cl, CF2CF3 and R2 = Me, Et, Pr, Bu, i-Bu, i- Pent] with 2-aminoacetophenone is reported. The reaction was performed in the presence of p-toluene sulphonic acid (p-TsOH), ionic liquid ([HMIM][TsO]) and under microwave irradiation. The molar ratio of the reactants 4-alkoxyvinyl ketone and 2-aminoacetophenone was of 1:1, respectively, for the quinoline with
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9

Nasr, El Dine Assaad. "Développement de nouvelles méthodes de synthèse en chimie de fluor et préparation de molécules bioactives." Thesis, Rennes 1, 2015. http://www.theses.fr/2015REN1S158/document.

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Ce travail s'inscrit dans le cadre d'un programme de collaboration entre l'Université Libanaise et l'université de Rennes 1. La thèse est divisée en deux parties :Chimie du fluor : synthèse de nouveaux hétérocycles portant des chaînes latérales fluorées ; chimie médicinale : recherche de nouvelles molécules à visées anticancéreuses. La première partie se compose de trois chapitres : dans le premier chapitre, des intermédiaires de synthèse de type énones fluorées ont été synthétisés par une voie originale, et leur réactivité en cyclocondensation a été étudiée pour obtenir de pyrazolines et de p
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10

Vargas, Pâmela Schütz de. "Reações de β-enaminodicetonas com ncn dinucleófilos: obtenção de pirimidinas e sistemas heterocíclicos fundidos". Universidade Federal de Santa Maria, 2016. http://repositorio.ufsm.br/handle/1/4288.

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Conselho Nacional de Desenvolvimento Científico e Tecnológico<br>In this study the reactivity of β-enamino diketones [RC(O)C(=CHNMe2)C(O)CO2Et, R = C6H5, 4-Me-C6H4, 4-MeO-C6H4, 4-F-C6H4, 4-Br-C6H4, 4-NO2-C6H4, tien-2-il] with NCN bisnucleophiles as amidine and guanidine was investigated. The tiopirimidines ethyl 2-benzylthio-pyrimidine-4-carboxylates, (65-91 %) and Ethyl 2-metiltiopirimidine-4-carboxylates (69-91 %) were obtained in a highly regioselective manner by cyclocondensation reaction of β-enamino diketones with benzylisothiourea hydrochloride and methylisothiourea sulfate, respectivel
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11

Vargas, Pâmela Schütz de. "Síntese de 1-aril-4-[(dimetilamino)metileno] pirrolidino-2,3,5-trionas utilizando irradiação de micro-ondas." Universidade Federal de Santa Maria, 2011. http://repositorio.ufsm.br/handle/1/10489.

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Conselho Nacional de Desenvolvimento Científico e Tecnológico<br>The synthesis of a series of 1-aryl-4-[(dimethylamino)methylene] pyrrolidine- 2,3,5-trione from the cyclocondensation reaction between b-enaminodiketone [Cl3C(O)C(=CHNMe2)C(O)CO2Et] and aniline derivatives [R = Ph, 3-Me-C6H4, 3- MeO-C6H4, 3-HO-C6H4, 4-Me-C6H4, 4-F-C6H4, 4-Cl-C6H4, 4-Br-C6H4, 4-O2N-C6H4, 4- MeCO-C6H4] was performed. The reaction conditions used to synthesize the pyrrolidine-2,3,5-triones involved environmentally benign techniques, as the use of microwave irradiation, employing the reactants b-enaminodiketone and a
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12

Moreira, Dayse das Neves. "Síntese de pirazóis e desenvolvimento de novos líquidos iônicos derivados de componentes farmacologicamente ativos." Universidade Federal de Santa Maria, 2011. http://repositorio.ufsm.br/handle/1/4214.

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior<br>The synthesis of two series of N-substituted pyrazoles from the cyclocondensation reaction of β-enaminones ([R1C(O)C(R2)=CHN(Me2)], where R1 = Me, C6H5, 3-MeOC6H4, 4-Me-C6H4, 4-MeO-C6H4, 4-F-C6H4, 4-Cl-C6H4, 4-Br-C6H4, 4-O2N-C6H4, fur-2-il, thien-2-il; R2 = H, 2-MeO-C6H4) and 2-hydroxyethylhydrazine or 1-pentafluorophenylhydrazine was demonstrated. The reactions were performed in five ionic liquids ([BMIM][BF4], [BMIM][Br], [BMIM][OH], [HMIM][HSO4] e [BPy][BF4]) with different physical and chemical properties to establish the
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13

Piovesan, Luciana Almeida. "Síntese de novos heterociclos a partir do ácido levulínico." Universidade Federal de Santa Maria, 2009. http://repositorio.ufsm.br/handle/1/4233.

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Conselho Nacional de Desenvolvimento Científico e Tecnológico<br>The synthesis of new compounds alkyl 3-azolyl propanoate e alkyl 3-azolyl propanoic acid structurally analogues to gamma-aminobutiric acid (GABA) is reported. One more time using the acetal acylation method, now the acetal derivative of 4-oxopentanoic acid (levulinic acid), the methyl 4,4- dimethoxypentanoate, were obtained the precursors methyl 7,7,7-trifluoro[chloro]-4- methoxy-6-oxo-heptenoates, 1,3-dieletrophilic precursor with alcanoate substituent. Are presented efficient and regioespecific synthetic routes from reactions o
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14

LE, MENN JEAN-CHRISTO. "Etude electrochimique de la reactivite de carbanions phosphonate et halogenomalonate : reactions de wittig-horner ou de darzens, alkylations, formylations, cyclocondensations." Rennes 1, 1989. http://www.theses.fr/1989REN10091.

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15

Zhu, Yen-Ruei, та 朱彥睿. "Catalyst-Free Synthesis of 1,5-Benzodiazepines by Cyclocondensation of β,γ-Unsaturated Ketones with o-Phenylenediamine". Thesis, 2014. http://ndltd.ncl.edu.tw/handle/5a793c.

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碩士<br>淡江大學<br>化學學系碩士班<br>102<br>The benzodiazepines have attracted much attentions as pharmacophoric scaffold of heterocycles with a wide range of biological applications. These compounds are served as potentially biological compound with antianxiety, anti-depress, anti-inflammatory, anti-viral, anti-HIVand anti-microbial activities.Many synthetic methods for benzodiazepines have been reported,and mostly with the introduction of catalyst. We developed a novel catalyst-free method synthetic of 1,5-benzodiazepines which was obtained under sonochemical Barbier-type reaction conditions. A reat
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16

Sher, Muhammad [Verfasser]. "Synthesis of functionalized homophthalates, salicylates, diaryl ethers and dihydroisocoumarins based on cyclocondensation reactions of 1,3-Dicarbonyl compounds and 1,3-Bis(silyloxy)-1,3-butadienes / vorgelegt von Muhammad Sher." 2008. http://d-nb.info/991886887/34.

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17

Petrov-Gueorguiev, Nino. "Nouveaux tétraoxa[8]circulènes ayant une géométrie de double-bol : synthèse, cristallisation et interactions avec invités électropauvres." Thesis, 2020. http://hdl.handle.net/1866/25437.

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L’aromaticité et l’antiaromaticité demeurent un sujet d’actualité au niveau fondamental puisque ces concepts permettent d’expliquer la réactivité de diverses classes de molécules. Certains composés polycycliques ayant une conjugaison π étendue, comme par exemple les tétraoxa[8]circulènes, ont des cycles aromatiques et antiaromatiques qui affectent leurs propriétés physicochimiques. Les oxacirculènes sont formés d’un anneau de quatre furanes et de quatre benzènes positionnés en alternance et créant un cœur formellement antiaromatique de cyclooctatétraène (COT). Malgré cela, ces composés démontr
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18

Asad, Ali [Verfasser]. "Synthesis of sterically encumbered biaryls by [3+3] cyclocondensation reactions and synthesis of arylated pyrazoles, bis(diaryl)sulfones, and bis(alkenyl)pyridines by Pd(0)-catalysed cross-coupling reactions / vorgelegt von Ali Asad." 2010. http://d-nb.info/1010726609/34.

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19

Karapetyan, Vahuni [Verfasser]. "Synthesis of bridged and non-bridged N-heterocycles, dichloromethyl- and formyl-salicylates, pyran-4-ones, chromanes and isochromanes based on cyclocondensation reactions of 1,3-bis(silyloxy)-1,3-butadienes and oxime dianions / vorgelegt von Vahuni Karapetyan." 2009. http://d-nb.info/1001599659/34.

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20

Imran, Muhammad [Verfasser]. "Synthesis of functionalized diaryl sulfides by cyclocondensation of 3-arylthio-1-silyloxy-1,3-butadienes with 1,1,3,3-tetramethoxypropane, dimethyl allene-1,3-dicarboxylate, 1,1-bis(methylthio)-1-en-3-ones and 3-oxo-orthoesters / vorgelegt von Muhammad Imran." 2009. http://d-nb.info/995965218/34.

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Abid, Obaid-ur-Rahman [Verfasser]. "Synthesis of functionalized 4-chlorophthalates, 2-naphthoates, 2-fluorobiaryls, and arylpyridines by cyclocondensation reactions of 1,3-bis(silyloxy)-1,3-butadienes and related dienes and by palladium(0) catalyzed cross coupling reactions / vorgelegt von Obaid-ur-Rahman Abid." 2010. http://d-nb.info/100780808X/34.

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22

Yawer, Mirza Arfan [Verfasser]. "Synthesis of functionalized 6-(pyridyl)salicylates, bis(benzophenones), chlorinated 6H-benzo[c]chromen-6-ones based on new cyclocondensations of 1,3-bis(silyloxy)-1,3-butadienes / vorgelegt von Mirza Arfan Yawer." 2008. http://d-nb.info/991250540/34.

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23

Adeel, Muhammad [Verfasser]. "Synthesis of functionalized biaryls, benzophenones, phenols, fluorenones, fluoarenes, and chloroarenes based on formal [3+3] cyclocondensations of 1,3-bis(silyloxy)-1,3-butadienes and 1,3,5-tris(silyloxy)-1,3,5-hexatrienes / vorgelegt von Muhammad Adeel." 2009. http://d-nb.info/995556660/34.

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Dang, Thanh Tung [Verfasser]. "Regioselective palladium(0)-catalyzed cross coupling reactions of brominated furans, thiophenes, pyrroles and selenophenes and synthesis of N,O-heterocycles by cyclocondensations of hydrazone and oxime dianions / vorgelegt von Dang Than Tung." 2009. http://d-nb.info/995272794/34.

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Ahmad, Rasheed [Verfasser]. "Synthesis of functionalized triarylmethanes based on cyclocondensations of 1,3-Bis(silyloxy)-1,3-butadienes, one-pot synthesis of functionalized pyranones and synthesis of functionalized indoles and pyrroles based on Pd(0)-catalyzed reactions / vorgelegt von Rasheed Ahmad." 2009. http://d-nb.info/997079835/34.

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