Academic literature on the topic 'Cyclopenta-1'

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Journal articles on the topic "Cyclopenta-1"

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Campbell, M., DJ Collins, and AM James. "Synthesis of 2-(5',5'-Ethylenedioxy-1'-methylcyclopent-2'-en-1'-yl)ethanol, and Some 2H-Cyclopenta[b]furan Derivatives Formed by Intramolecular Displacement Reactions." Australian Journal of Chemistry 42, no. 1 (1989): 17. http://dx.doi.org/10.1071/ch9890017.

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Exchange dioxolanation of 2-methyl-2-(prop-2′-enyl)cyclopentane-1,3-done (1b) gave 3,3- ethylenedioxy-2-methyl-2-(prop-2′-enyl) cyclopentan-1-one (2) which, upon reduction and esterification , afforded the epimeric 3,3-ethylenedioxy-2-methyl-2-(prop-2′-enyl) cyclopent-1-yl benzoates (6d). Oxidative cleavage of the terminal double bond in (6d),followed by sodium borohydride reduction yielded 3,3-ethylenedioxy-2-(2'-hydroxyethyl)-2-methylcyclopent-1-yl benzoate (4b) which underwent acid- catalysed rearrangement to 6a-(2′-hydroxyethoxy)-3a- methylhexahydrocyclopenta [b]furan-4-yl benzoate (8b). F
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Gataullin, Rail R., Ekaterina S. Mescheryakova, Rifkat M. Sultanov, Akhnef A. Fatykhov, and Leonard M. Khalilov. "An Unexpected Dihalogenation/Dehydrogenation Product Derived­ via Iodolactonization of an N-Tosyl-N-[6-(2-cyclopenten-1-yl)-2-methylphenyl]glycine." Synthesis 51, no. 18 (2019): 3485–90. http://dx.doi.org/10.1055/s-0039-1689971.

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The reaction between N-tosyl-N-[6-(2-cyclopenten-1-yl)phenyl]glycine (syn/anti atropisomeric mixture) and molecular iodine is studied. Along with the expected 8-exo-cyclization product possessing a 3-iodo-2,3,3a,6,7,11b-hexahydrobenzo[e]cyclopenta[g][1,4]oxazocine core, the unexpected 1,11b-dehydrogenated/1-iodinated analogue with a 1,3-diiodo-3,3a,6,7-tetrahydrobenzo[e]cyclopenta[g][1,4]oxazocine structure is observed for the first time in a conventional halolactonization reaction.
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Kotha, Sambasivarao, and Yellaiah Tangella. "Modular Approaches to Cyclopentanoids and their Heteroanalogs." Synlett 31, no. 20 (2020): 1976–2012. http://dx.doi.org/10.1055/a-1288-8240.

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AbstractCyclopentanoids and their derivatives are interesting targets in synthetic organic chemistry due to their extensive applications in various branches of chemical sciences like pharmaceuticals, natural and non-natural products. In view of these applications, several synthetic strategies have been developed in the past three to four decades. In this article, we describe our work towards the synthesis of cyclopentanoids and their heteroanalogs involving diverse synthetic strategies during the past two decades. Among these, photo-thermal olefin metathesis, ring-closing metathesis, ring-rear
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Si, Mrinal Kanti, and Bishwajit Ganguly. "A DFT study to design super- and hyperacids with 1-(cyclopenta-2,4-dien-1-yl)-4-nitrobenzene and 3-(cyclopenta-2,4-dien-1-ylmethylene)-6-methylenecyclohexa-1,4-diene molecules." New Journal of Chemistry 41, no. 4 (2017): 1425–29. http://dx.doi.org/10.1039/c6nj03529a.

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DFT calculations reveal that poly-cyano-substituted 1-(cyclopenta-2,4-dien-1-yl)-4-nitrobenzene and 3-(cyclopenta-2,4-dien-1-ylmethylene)-6-methylenecyclohexa-1,4-diene can function as super- to hyper-acids.
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Peipiņš, Uldis, Niks Freimanis, Dmitrijs Stepanovs, Anatoly Mishnev, and Māris Turks. "Betulin 3,28-di-O-tosylate." Acta Crystallographica Section E Structure Reports Online 70, no. 8 (2014): o879—o880. http://dx.doi.org/10.1107/s1600536814016602.

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The title compound, C44H62O6S2{systematic name: (1R,3aS,5aR,5bR,7aR,9S,11aR,11bR,13aR,13bR)-5a,5b,8,8,11a-pentamethyl-1-(prop-1-en-2-yl)-3a-[(tosyloxy)methyl]icosahydro-1H-cyclopenta[a]chrysen-9-yl 4-methylbenzenesulfonate}, was obtained by tosylation of naturally occurring betulin. All the cyclohexane rings adopt chair conformations and the cyclopentane ring adopts a twisted envelope conformation, with the C atom bearing the tosylmethyl substituent forming the flap. In the crystal, molecules form a three-dimensional network through multiple weak C—H...O hydrogen bonds.
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Çelik, Ísmail, Mehmet Akkurt, Ahmet Tutar, Ramazan Erenler, and Santiago García-Granda. "2,3-Dihydro-1H-cyclopenta[b]naphthalen-1-ol." Acta Crystallographica Section E Structure Reports Online 68, no. 3 (2012): o687. http://dx.doi.org/10.1107/s1600536812005181.

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Wardakhan, Wagnat Wahba, El-Sayed Nahed Nasser Eid, and Rafat Milad Mohareb. "Synthesis and anti-tumor evaluation of novel hydrazide and hydrazide-hydrazone derivatives." Acta Pharmaceutica 63, no. 1 (2013): 45–57. http://dx.doi.org/10.2478/acph-2013-0004.

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The reaction of cyclopentanone with cyanoacetylhydrazine gave 2-cyano-2-cyclopentylideneacetohydrazide (1). Treatment of compound 1 with elemental sulphur in the presence of triethylamine afforded 2-amino-5,6-dihydro- -4H-cyclopenta[b]thiophene-3-carbohydrazide (2), which in-turn formed the corresponding intermediate diazonium salt. The latter was coupled with either ethyl cyanoacetate or ethyl acetoacetate to form 2-cyano-2-(3-(hydrazinecarbonyl)- 5,6-dihydro-4H-cyclopenta[b]thiophen-2-yl)hydrazono) acetate (3) and ethyl 2-(2-(3-(hydrazinecarbonyl)-5,6-dihydro- 4H-cyclopenta[b]thiophen-2-yl)h
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Gelbrich, Thomas, Volker Kahlenberg, Christoph Langes, and Ulrich J. Griesser. "Telaprevir: helical chains based on three-point hydrogen-bond connections." Acta Crystallographica Section C Crystal Structure Communications 69, no. 2 (2013): 179–82. http://dx.doi.org/10.1107/s0108270113000954.

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The crystal structure of the title compound [systematic name: (1S,3aR,6aS)-2-((2S)-2-{[(2S)-2-cyclohexyl-2-(pyrazine-2-carbonylamino)acetyl]amino}-3,3-dimethylbutanoyl)-N-[(3S)-1-(cyclopropylamino)-1,2-dioxohexan-3-yl]-3,3a,4,5,6,6a-hexahydro-1H-cyclopenta[c]pyrrole-1-carboxamide], C36H53N7O6, contains two independent molecules, which possess distinct conformations and a disordered cyclopenta[c]pyrrolidine unit. In the crystal, molecules are linked into helical chainsviathree-point N—H...O hydrogen-bond connections in which three NH and three carbonyl groups per molecule are utilized. The chir
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Christensen, Torben Bo, Karl Anker Jørgensen, Finn Krebs Larsen, et al. "Formation of a 4H-cyclopenta-1,2,3-thiadiazole by rearrangement of a transient N-(thionitroso)cyclopenta-2,4-diene-1-imine." J. Chem. Soc., Chem. Commun., no. 6 (1993): 489–91. http://dx.doi.org/10.1039/c39930000489.

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Huo, Fang-Jun, Cai-Xia Yin, and Pin Yang. "7-Nitro-2,3-dihydro-1H-cyclopenta[b]chromen-1-one." Acta Crystallographica Section E Structure Reports Online 60, no. 11 (2004): o2087—o2089. http://dx.doi.org/10.1107/s1600536804026078.

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Dissertations / Theses on the topic "Cyclopenta-1"

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Grandin, Anna. "Synthetic Routes towards 2-thia-7,8-diaza-cyclopenta[l]phenanthrene and 1-thia-7,8-diaza-cyclopenta[l]phenanthrene for Molecular Electronics Applications." Thesis, Mälardalens högskola, Akademin för hållbar samhälls- och teknikutveckling, 2009. http://urn.kb.se/resolve?urn=urn:nbn:se:mdh:diva-7505.

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Electric current is known to flow through the π-bonds in oligothiophenes. In order to use them as molecular wires it is important to use a technique where the potential gradients can be generated and maintained in supramolecular networks. A solution to this problem can be the use of metal complexes as junction points within such a network.  In this project pathways to synthesize 2-thia-7,8-diaza-cyclopenta[l]phenanthrene (1) and 1-thia-7,8-diaza-cyclopenta[l]phenanthrene (2) for use in molecular electronic devices have been investigated. 4-(5-Bromo-thiophen-2-yl)2,2’-bipyridine (3) was prepare
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Dallemagne, Patrick. "Synthèse et étude de la réactivité chimique des premiers amino-4 cyclopenta[b] thiophènes ; application aux nouvelles séries de l'amino-3 indanone-1 et de l'amino-6 cyclopenta[b] thiophène." Caen, 1988. http://www.theses.fr/1988CAEN4071.

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Nadarajah, Sivakumar. "Synthesis and reactions of a 2-cyclopenten-1-one d³ synthon." Thesis, University of British Columbia, 1986. http://hdl.handle.net/2429/26010.

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This thesis describes the preparation of 3-trimethylstannyl-2-cyclo-penten-1-one 14 via the higher order stannylcuprate 78, a new reagent prepared to convert 3-iodo-2-cyclopenten-1-one 75 to the desired product. The observations made from this chemistry led to the development of "one-pot" cuprate formation which was demonstrated to be a viable and practically convenient way to generate such species compared with traditional methods. This thesis also describes the preparation of 3-tert-butyldimethyl-siloxy-1-trimethylstannylcyclopentene 83, its conversion into the corresponding lithio species,
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Perrard, Thierry. "Synthèse énantiosélective des énantiomères du dihydrojasmonate de méthyle." Rouen, 1999. http://www.theses.fr/1999ROUES054.

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Dans la première partie de ce travail, nous avons imaginé un projet de synthèse du (+)-dihydroépijasmonate de méthyle, un composé ayant des propriétés odorantes intéressantes dans lequel l'étape-clef est un dédoublement cinétique par des amidures de magnésium chiraux dans une réaction de déprotonation régiosélective. Nous avons suivi ce projet jusqu'à la synthèse du dihydrojasmonate de méthyle racémique de configuration trans. Des essais de protonation diastéréosélective et des essais de cis-hydrogénation n'ont pas donné le dihydroépijasmonate de méthyle pur de configuration cis désiré. Ce com
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Chen, Zhong-Yi, and 陳忠毅. "1. 1. Studies in Synthesis of C-1 Substituted Fulvenes via the Oxidation-Addition of Haloacetyl Halide to fulveneketene Acetal. 2. Traceless Solid-Phase Synthesis of Cyclopenta[c]quinolines and Cyclopenta[c]chromenes via Hetero [6+3] Cycloadditions of Fu." Thesis, 2003. http://ndltd.ncl.edu.tw/handle/12983595954471742161.

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博士<br>國立中正大學<br>化學研究所<br>91<br>1.Studies in Synthesis of C-1 Substituted Fulvenes via the Oxidation-Addition of Haloacetyl Halide to fulveneketene Acetal. In contrast to the [2+2] cycloaddition of fulvenes and ketenes, fulveneketene acetal, 2-chloropentadienylidene-1,3-dioxalane, reacts with a-halo acyl halides to give various C-1 substituted fulvene. Herein we describe the first example of oxidative-addition of a-chloroacetyl chloride to fulveneketene acetal, and formal synthesis of the carbocyclic analogs of Captopril. 2.Traceless Solid-Phase Synthesis of
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Hofmann, Thorsten. "Synthese und Reaktionen von Cyclopenta[c]1,2-diazepinen und Cyclopenta[d]1,2-diazepinen." Phd thesis, 2002. http://tuprints.ulb.tu-darmstadt.de/185/1/dissertation.pdf.

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Bei der Suche nach den Ursachen und der Natur von „Aromatizität“ erwiesen sich zahlreiche nicht-benzoide, carbocyclisch und heterocyclisch konjugierte pi-Elektronensysteme als wertvolle Prüfsteine für quantenchemische Berechnungen. Im Zusammenhang damit war ein Ziel dieser Arbeit, einen Syntheseweg für die bislang unbekannten 4,5-Diazaazulene und 5,6-Diazaazulene zu entwickeln. Durch Reaktionen von semicyclischen 1,5-Diketonen mit verschiedenen Hydrazinen gelang die Darstellung von teilgesättigten literaturunbekannten Cyclopenta[c]1,2-diazepinen, Cyclopenta[d]1,2-diazepinen, Tetraaza[14]annule
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Book chapters on the topic "Cyclopenta-1"

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Blake, Paul C., Michael F. Lappert, Richard C. Taylor, Paulette N. Hazin, and Joseph W. Bruno. "Bis[η5 -1, 3-Bis(Trimethylsilyl)Cyclopenta-Dienyl]Halouranium(IV) and-Thorium(IV), [MCp″2 Cl2 ] and [UCp″2 X2 ]." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132586.ch34.

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Lappert, Michael F., Anirudh Singh, and Josef Takats. "Bis[η5 -1, 3-Bis(Trimethylsilyl)Cyclopenta-Dienyl]Chlorolanthanide(III) Complexes, [{LnCp″2 (μ-Cl)}2 ] and [LnCp″2 Gi-Cl)2 Li(thf)2 ]." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132586.ch33.

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Demaison, J. "535 C5H6O 2-Cyclopenten-1-one." In Asymmetric Top Molecules. Part 2. Springer Berlin Heidelberg, 2011. http://dx.doi.org/10.1007/978-3-642-10400-8_283.

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Winkelmann, J. "Diffusion of cyclopentane (1); air (2)." In Gases in Gases, Liquids and their Mixtures. Springer Berlin Heidelberg, 2007. http://dx.doi.org/10.1007/978-3-540-49718-9_737.

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Winkelmann, J. "Diffusion of hydrogen (1); methyl-cyclopentane (2)." In Gases in Gases, Liquids and their Mixtures. Springer Berlin Heidelberg, 2007. http://dx.doi.org/10.1007/978-3-540-49718-9_1006.

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Winkelmann, J. "Diffusion of nitrogen (1); methyl-cyclopentane (2)." In Gases in Gases, Liquids and their Mixtures. Springer Berlin Heidelberg, 2007. http://dx.doi.org/10.1007/978-3-540-49718-9_1139.

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Winkelmann, J. "Diffusion of oxygen (1); methyl-cyclopentane (2)." In Gases in Gases, Liquids and their Mixtures. Springer Berlin Heidelberg, 2007. http://dx.doi.org/10.1007/978-3-540-49718-9_1189.

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Winkelmann, J. "Diffusion of argon (1); methyl-cyclopentane (2)." In Gases in Gases, Liquids and their Mixtures. Springer Berlin Heidelberg, 2007. http://dx.doi.org/10.1007/978-3-540-49718-9_450.

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Wohlfarth, Ch. "Viscosity of the mixture (1) cyclopentane; (2) cyclohexane." In Supplement to IV/18. Springer Berlin Heidelberg, 2008. http://dx.doi.org/10.1007/978-3-540-75486-2_1406.

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Wohlfarth, Ch. "Viscosity of the mixture (1) cyclopentane; (2) toluene." In Supplement to IV/18. Springer Berlin Heidelberg, 2008. http://dx.doi.org/10.1007/978-3-540-75486-2_1407.

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Conference papers on the topic "Cyclopenta-1"

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Ocola, Esther, та Jaan Laane. "VAPOR-PHASE INFRARED AND RAMAN SPECTRA AND THEORETICAL INVESTIGATIONS OF π-TYPE INTRAMOLECULAR HYDROGEN BONDING IN 3-CYCLOPENTEN-1-OL AND 3-CYCLOPENTEN-1-AMINE". У 2020 International Symposium on Molecular Spectroscopy. University of Illinois at Urbana-Champaign, 2020. http://dx.doi.org/10.15278/isms.2020.wa02.

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Claudio Herrera Braga, Antonio, and Rodrigo Veludo Malgueiro. "Study of 2-methyl-2-cyclopenten-1-one reductive ozonolysis reaction." In XXIII Congresso de Iniciação Científica da Unicamp. Galoá, 2015. http://dx.doi.org/10.19146/pibic-2015-37802.

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Reports on the topic "Cyclopenta-1"

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Forster, Nelson H. Carbon-Phenolic Cages for High-Speed Bearings. Part 1 - Friction and Wear Response of Phenolic Composite Impregnated with a Multiply-Alkylated Cyclopentane (MAC) Lubricant and MoS2 Solid Lubricant. Defense Technical Information Center, 2003. http://dx.doi.org/10.21236/ada416130.

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