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Journal articles on the topic 'Deoxygenation of sulfoxides'

Author: Grafiati

Published: 5 June 2025

Last updated: 1 August 2025

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1

Ho, Tse-Lok, and C. WONG. "Deoxygenation of Sulfoxides." Synthesis 1973, no. 04 (2002): 206–7. http://dx.doi.org/10.1055/s-1973-22175.

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2

Shiri, Lotfi, and Mosstafa Kazemi. "Deoxygenation of sulfoxides." Research on Chemical Intermediates 43, no. 11 (2017): 6007–41. http://dx.doi.org/10.1007/s11164-017-2976-6.

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3

Mohanazadeh, Farajollah, Ahmad Reza Momeni, and Yousef Ranjbar. "Deoxygenation of sulfoxides with silica chloride." Tetrahedron Letters 35, no. 33 (1994): 6127–28. http://dx.doi.org/10.1016/0040-4039(94)88094-8.

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4

Kukushkin, Vadim Yu. "Metal-ion mediated deoxygenation of sulfoxides." Coordination Chemistry Reviews 139 (February 1995): 375–407. http://dx.doi.org/10.1016/0010-8545(94)01116-s.

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5

Suzuki, Kosuke, Jinu Jeong, Kazuya Yamaguchi, and Noritaka Mizuno. "Photoredox catalysis for oxygenation/deoxygenation between sulfides and sulfoxides by visible-light-responsive polyoxometalates." New Journal of Chemistry 40, no. 2 (2016): 1014–21. http://dx.doi.org/10.1039/c5nj01045d.

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6

García, Nuria, Manuel A. Fernández-Rodríguez, Patricia García-García, María R. Pedrosa, Francisco J. Arnáiz, and Roberto Sanz. "A practical and chemoselective Mo-catalysed sulfoxide reduction protocol using a 3-mercaptopropyl-functionalized silica gel (MPS)." RSC Advances 6, no. 32 (2016): 27083–86. http://dx.doi.org/10.1039/c6ra03106d.

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7

Sakai, Norio, Retsu Shimada, and Yohei Ogiwara. "Indium‐Catalyzed Deoxygenation of Sulfoxides with Hydrosilanes." Asian Journal of Organic Chemistry 10, no. 4 (2021): 845–50. http://dx.doi.org/10.1002/ajoc.202100063.

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8

Edinger, Carolin, and Siegfried R. Waldvogel. "Electrochemical Deoxygenation of Aromatic Amides and Sulfoxides." European Journal of Organic Chemistry 2014, no. 24 (2014): 5144–48. http://dx.doi.org/10.1002/ejoc.201402714.

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9

Porwal, Digvijay, and Martin Oestreich. "B(C6F5)3-Catalyzed Reduction of Sulfoxides and Sulfones to Sulfides with Hydrosilanes." Synthesis 49, no. 20 (2017): 4698–702. http://dx.doi.org/10.1055/s-0036-1588476.

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B(C6F5)3 is shown to catalyze the deoxygenation of sulfoxides and sulfones to the corresponding sulfides with Et3SiH as the stoichiometric hydride source. While the method is limited in terms of functional group tolerance, it is applicable to the reduction of alkyl/aryl-, aryl/aryl-, and alkyl/alkyl-substituted sulfoxides, including the benzyl/benzyl-substituted derivative. The same protocol converts alkyl/aryl- but not aryl/aryl-substituted sulfones into sulfides.

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10

Nagasawa, Kazuo, Akemi Yoneta, Toshiyuki Umezawa, and Keiichi Ito. "Facile Deoxygenation of Sulfoxides by Using Metal/Chiloromethylsilanes." HETEROCYCLES 26, no. 10 (1987): 2607. http://dx.doi.org/10.3987/r-1987-10-2607.

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11

Khurana, Jitender M., Abhijit Ray, and Sarika Singh. "Deoxygenation of sulfoxides and selenoxides with nickel boride." Tetrahedron Letters 39, no. 22 (1998): 3829–32. http://dx.doi.org/10.1016/s0040-4039(98)00623-6.

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12

Amos, Richard A. "Poly(styryldiphenylphosphine) as a deoxygenation reagent for sulfoxides." Journal of Organic Chemistry 50, no. 8 (1985): 1311–13. http://dx.doi.org/10.1021/jo00208a036.

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13

KUKUSHKIN, V. YU. "ChemInform Abstract: Metal-Ion Mediated Deoxygenation of Sulfoxides." ChemInform 26, no. 31 (2010): no. http://dx.doi.org/10.1002/chin.199531284.

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14

MOHANAZADEH, F., A. R. MOMENI, and Y. RANJBAR. "ChemInform Abstract: Deoxygenation of Sulfoxides with Silica Chloride." ChemInform 26, no. 1 (2010): no. http://dx.doi.org/10.1002/chin.199501104.

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15

Fujita, Shu, Sho Yamaguchi, Seiji Yamazoe, Jun Yamasaki, Tomoo Mizugaki, and Takato Mitsudome. "Nickel phosphide nanoalloy catalyst for the selective deoxygenation of sulfoxides to sulfides under ambient H2 pressure." Organic & Biomolecular Chemistry 18, no. 43 (2020): 8827–33. http://dx.doi.org/10.1039/d0ob01603a.

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Abstract:

A titanium-dioxide-supported nickel phosphide nanoalloy (nano-Ni<sub>2</sub>P/TiO<sub>2</sub>) functions as a highly active non-precious-metal-based heterogeneous catalyst for the selective deoxygenation of sulfoxides to sulfides under just 1 bar of H<sub>2</sub>.

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16

Enthaler, Stephan. "Zinc-Catalyzed Deoxygenation of Sulfoxides to Sulfides Applying [B(Pin)]2 as Deoxygenation Reagents." Catalysis Letters 142, no. 11 (2012): 1306–11. http://dx.doi.org/10.1007/s10562-012-0897-y.

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17

Atabaki, Fariborz, Ebrahim Abedini, and Arash Shokrolahi. "Efficient Oxidation of Sulfides to Sulfoxides and Deoxygenation of Sulfoxides over Carbonaceous Solid Acid." Phosphorus, Sulfur, and Silicon and the Related Elements 190, no. 7 (2015): 1169–76. http://dx.doi.org/10.1080/10426507.2014.978325.

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18

Bahrami, Kiumars, Mohammad M. Khodaei, and Mehdi Sheikh Arabi. "TAPC-Promoted Oxidation of Sulfides and Deoxygenation of Sulfoxides." Journal of Organic Chemistry 75, no. 18 (2010): 6208–13. http://dx.doi.org/10.1021/jo1011784.

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19

Cha, Jin Soon, Jin Euog Kim, and Jong Dae Kim. "Selective deoxygenation of sulfoxides with thexylchloroborane-methyl sulfide complex." Tetrahedron Letters 26, no. 52 (1985): 6453–56. http://dx.doi.org/10.1016/s0040-4039(00)99025-7.

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20

Abo, Mitsuru, Makiko Dejima, Fumioki Asano, Akira Okubo, and Sunao Yamazaki. "Electrochemical enzymatic deoxygenation of chiral sulfoxides utilizing DMSO reductase." Tetrahedron: Asymmetry 11, no. 3 (2000): 823–28. http://dx.doi.org/10.1016/s0957-4166(00)00004-5.

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21

Shimizu, Makoto, Katsuhiko Shibuya, and Ryuuichirou Hayakawa. "ChemInform Abstract: Chemoselective Deoxygenation of Sulfoxides with Titanium Tetraiodide." ChemInform 32, no. 5 (2001): no. http://dx.doi.org/10.1002/chin.200105047.

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22

Somasundaram, N., and C. Srinivasan. "ChemInform Abstract: Deoxygenation of Sulfoxides on Irradiated TiO2 Surfaces." ChemInform 33, no. 43 (2010): no. http://dx.doi.org/10.1002/chin.200243062.

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23

Yoo, Byung-Woo, Hyung-Min Kim, Duck-Il Kim, and Kyoung-Sun Seok. "Rapid and Efficient Deoxygenation of Sulfoxides with NbCl5/NaI System." Bulletin of the Korean Chemical Society 32, no. 8 (2011): 2525–26. http://dx.doi.org/10.5012/bkcs.2011.32.8.2525.

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24

Yoo, Byung Woo, Hyung Min Kim, and Duckil Kim. "Selective and Efficient Deoxygenation of Sulfoxides with NbCl5/Indium System." Synthetic Communications 43, no. 15 (2013): 2057–61. http://dx.doi.org/10.1080/00397911.2012.684756.

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25

Yoo, Byung Woo, Min Suk Song, and Min Chol Park. "Mild and Efficient Deoxygenation of Sulfoxides with MoCl5/Indium System." Synthetic Communications 37, no. 18 (2007): 3089–93. http://dx.doi.org/10.1080/00397910701544729.

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26

Takahashi, Yusuke, Takato Mitsudome, Tomoo Mizugaki, Koichiro Jitsukawa, and Kiyotomi Kaneda. "Highly Efficient Deoxygenation of Sulfoxides Using Hydroxyapatite-supported Ruthenium Nanoparticles." Chemistry Letters 43, no. 4 (2014): 420–22. http://dx.doi.org/10.1246/cl.131077.

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27

Yadav, Jhillu S., Basi V. Subba Reddy, C. Srinivas, and P. Srihari. "ChemInform Abstract: Ultrasound-Promoted Deoxygenation of Sulfoxides by Samarium-NH4Cl." ChemInform 32, no. 39 (2010): no. http://dx.doi.org/10.1002/chin.200139054.

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28

KHURANA, J. M., A. RAY, and S. SINGH. "ChemInform Abstract: Deoxygenation of Sulfoxides and Selenoxides with Nickel Boride." ChemInform 29, no. 33 (2010): no. http://dx.doi.org/10.1002/chin.199833094.

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29

Boyd, Derek R., Narain D. Sharma, Alistair W. T. King, et al. "Stereoselective reductase-catalysed deoxygenation of sulfoxides in aerobic and anaerobic bacteria." Organic & Biomolecular Chemistry 2, no. 4 (2004): 554. http://dx.doi.org/10.1039/b313714g.

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30

Pandey, Lokesh Kumar, Uma Pathak, and A. Narasimha Rao. "Silica–PSCl3: A Mild and Efficient Reagent for Deoxygenation of Sulfoxides." Synthetic Communications 37, no. 23 (2007): 4105–9. http://dx.doi.org/10.1080/00397910701572753.

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31

Zhang, Jianghua, Xinqin Gao, Chengyi Zhang, Cheng Zhang, Jiming Luan, and Defeng Zhao. "Mild and Efficient Deoxygenation of Sulfoxides to Sulfides Using HfCl4/KBH4System." Synthetic Communications 40, no. 12 (2010): 1794–801. http://dx.doi.org/10.1080/00397910903161819.

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32

Hua, Guoxiong, and J. Derek Woollins. "The syntheses of sulfides by deoxygenation of sulfoxides using Woollins’ reagent." Tetrahedron Letters 48, no. 21 (2007): 3677–79. http://dx.doi.org/10.1016/j.tetlet.2007.03.132.

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33

Woo Yoo, Byung, Min Chol Park, and Min Suk Song. "Mild and Efficient Deoxygenation of Sulfoxides with a WCl6/Indium System." Synthetic Communications 37, no. 22 (2007): 4079–83. http://dx.doi.org/10.1080/00397910600773676.

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34

Abo, Mitsuru, Makiko Dejima, Fumioki Asano, Akira Okubo, and Sunao Yamazaki. "ChemInform Abstract: Electrochemical Enzymatic Deoxygenation of Chiral Sulfoxides Utilizing DMSO Reductase." ChemInform 31, no. 24 (2010): no. http://dx.doi.org/10.1002/chin.200024042.

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35

Bahrami, Kiumars, Mohammad M. Khodaei, and Mehdi Sheikh Arabi. "ChemInform Abstract: TAPC-Promoted Oxidation of Sulfides and Deoxygenation of Sulfoxides." ChemInform 42, no. 3 (2010): no. http://dx.doi.org/10.1002/chin.201103080.

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36

Wang, Xingyue, Changlin Xu, Hongyu Guan, Mi Lin, and Peng Huang. "Deoxygenation of Sulfoxides with Dimethylthiocarbamoyl Chloride in the Absence of Additional Solvent." Chinese Journal of Organic Chemistry 41, no. 8 (2021): 3330. http://dx.doi.org/10.6023/cjoc202102004.

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37

Kukushkin, Vadim Yu, Elena A. Aleksandrova, and Boris V. Zhadanov. "Pt(II) ASSISTED DEOXYGENATION OF COORDINATED SULFOXIDES BY HYDROCHLORIC- OR HYDROBROMIC ACID." Phosphorus, Sulfur, and Silicon and the Related Elements 53, no. 1-4 (1990): 433–35. http://dx.doi.org/10.1080/10426509008038055.

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38

Yoo, Byung Woo, and Sang Ki Min. "Mild and Efficient Deoxygenation of Sulfoxides to Sulfides with Cp2TiCl2/Gallium System." Synthetic Communications 41, no. 20 (2011): 2993–96. http://dx.doi.org/10.1080/00397911.2010.516382.

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39

Karimi, Babak, and Daryoush Zareyee. "Rapid, Efficient and Chemoselective Deoxygenation of Sulfoxides to Thioethers Using NaBH4/I2." Synthesis 2003, no. 03 (2003): 0335–36. http://dx.doi.org/10.1055/s-2003-37349.

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40

Clarke, Aimee K., Alison Parkin, Richard J. K. Taylor, William P. Unsworth, and James A. Rossi-Ashton. "Photocatalytic Deoxygenation of Sulfoxides Using Visible Light: Mechanistic Investigations and Synthetic Applications." ACS Catalysis 10, no. 10 (2020): 5814–20. http://dx.doi.org/10.1021/acscatal.0c00690.

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41

Sousa, Sara C. A., Joana R. Bernardo, Carlos C. Romão, and Ana C. Fernandes. "Highly efficient rhenium-catalyzed deoxygenation of sulfoxides without adding any reducing agent." Tetrahedron 68, no. 39 (2012): 8194–97. http://dx.doi.org/10.1016/j.tet.2012.07.071.

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42

Khurana, Jitender M., Vandana Sharma, and Silvi A. Chacko. "Deoxygenation of sulfoxides, selenoxides, telluroxides, sulfones, selenones and tellurones with Mg–MeOH." Tetrahedron 63, no. 4 (2007): 966–69. http://dx.doi.org/10.1016/j.tet.2006.11.027.

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43

Abo, Mitsuru, Akira Okubo, and Sunao Yamazaki. "Preparative asymmetric deoxygenation of alkyl aryl sulfoxides by Rhodobacter sphaeroides f.sp. denitrificans." Tetrahedron: Asymmetry 8, no. 3 (1997): 345–48. http://dx.doi.org/10.1016/s0957-4166(96)00530-7.

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44

Sanz, Roberto, Francisco Arnáiz, Jaime Escribano, Rafael Aguado, and María Pedrosa. "Selective Deoxygenation of Sulfoxides to Sulfides with Phosphites Catalyzed by Dichlorodioxomolybdenum(VI)." Synthesis 2004, no. 10 (2004): 1629–32. http://dx.doi.org/10.1055/s-2004-829104.

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45

Yoo, Byung Woo, Hyung Min Kim, and Duckil Kim. "ChemInform Abstract: Selective and Efficient Deoxygenation of Sulfoxides with NbCl5/Indium System." ChemInform 44, no. 40 (2013): no. http://dx.doi.org/10.1002/chin.201340077.

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46

Takahashi, Yusuke, Takato Mitsudome, Tomoo Mizugaki, Koichiro Jitsukawa, and Kiyotomi Kaneda. "ChemInform Abstract: Highly Efficient Deoxygenation of Sulfoxides Using Hydroxyapatite-Supported Ruthenium Nanoparticles." ChemInform 45, no. 49 (2014): no. http://dx.doi.org/10.1002/chin.201449087.

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47

Uematsu, Tsubasa, Yoshiyuki Ogasawara, Kosuke Suzuki, Kazuya Yamaguchi, and Noritaka Mizuno. "Platinum-supporting hollandite-type vanadium–chromium mixed oxides as efficient heterogeneous catalysts for deoxygenation of sulfoxides under atmospheric H2 pressure." Catalysis Science & Technology 7, no. 9 (2017): 1912–20. http://dx.doi.org/10.1039/c7cy00547d.

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48

Jabbari, Arida, Morteza Zarei, and Azar Jamaleddini. "I2as a mild and efficient catalyst in deoxygenation of sulfoxides with thioacetic acid." Journal of Sulfur Chemistry 33, no. 4 (2012): 413–18. http://dx.doi.org/10.1080/17415993.2012.693491.

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49

Bahrami, Kiumars, Mohammad M. Khodaei, and Samira Sohrabnezhad. "Cyanuric chloride as promoter for the oxidation of sulfides and deoxygenation of sulfoxides." Tetrahedron Letters 52, no. 48 (2011): 6420–23. http://dx.doi.org/10.1016/j.tetlet.2011.09.073.

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50

Mikami, Yusuke, Akifumi Noujima, Takato Mitsudome, Tomoo Mizugaki, Koichiro Jitsukawa, and Kiyotomi Kaneda. "Highly Efficient Gold Nanoparticle Catalyzed Deoxygenation of Amides, Sulfoxides, and Pyridine N-Oxides." Chemistry - A European Journal 17, no. 6 (2011): 1768–72. http://dx.doi.org/10.1002/chem.201003109.

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