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1
Lester, Kate Erin. "Quantifying Lingua-Palatal Contact Patterns of Fricative Productions by Non-native Students Enrolled in a University German Language Course: An Electropalatography Study." BYU ScholarsArchive, 2017. https://scholarsarchive.byu.edu/etd/6820.
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Electropalatography (EPG) is a computer-based tracking system designed to provide real-time visual biofeedback of articulatory contacts occurring during speech production. Historically, EPG technology has proven functional within the treatment and assessment of speech disorders however, application of EPG technology to assist in second language learning has remained limited. The present thesis is part of a larger study examining the effectiveness of using EPG as an advanced instructional tool for assisting second language (L2) learners of German. Fricative productions ([ç], [x], /s/, and /∫/) within real words were gathered from 12 native English speakers enrolled in a second semester university level course to learn German. Speech productions from student participants were compared against native German speakers' productions collected in a previous study, using electrode mappings, percentages of regional contact, and center of gravity measures. These measures revealed different patterns of palatal contact between fricative sounds, between individual subjects, and cross-linguistically. Fricative sound mappings varied visually as speakers generally produced [ç] and [x] with significantly less palatal contact than when producing /s/ and /∫/. Variation across individual subjects was identified as some produced sounds with nearly no posterior palatal contact while others produced sounds asymmetrically or with decreased overall contact. Cross-linguistic differences were apparent as non-native German speakers frequently contacted greater numbers of electrodes with greater force, compared to the natives. It is anticipated that the information included in this thesis will provide insights into the role of EPG technology as an instructional tool for L2 learners.
2
Nakagawa, Harumichi, Masatoshi Yamazaki, Motoki Nihei, Ryoko Niwa, Tatsuhiko Arafune, Akira Mishima, Shiho Nashimoto, et al. "Virtual Electrode Polarization-Induced Reentrant Activity." Research Institute of Environmental Medicine, Nagoya University, 2003. http://hdl.handle.net/2237/7595.
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3
Arafune, Tatsuhiko, Akira Mishima, Ichiro Sakuma, Hiroshi Inada, Nitaro Shibata, Harumichi Nakagawa, Masatoshi Yamazaki, Haruo Honjo, and Itsuo Kodama. "Virtual Electrode-induced Spiral Reentry in Ventricular Myocardium Perfused in-vitro." Research Institute of Environmental Medicine, Nagoya University, 2003. http://hdl.handle.net/2237/7602.
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4
Panagiotelis, Ioannis. "In-vivo oxygen mapping using LODESR imaging." Thesis, University of Aberdeen, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.367502.
Full textAbstract:
A novel imaging modality is introduced, using Radio-Frequency Longitudinally Detected Electron Spin Resonance (RF-LODESR), capable of providing qualitative and semi-quantitative information on a variety of parameters reflecting physiological function, the most significant being tissue oxygenation. Effective spin-lattice (T1e*) and spin-spin (T2e*) electronic relaxation time maps of the abdomen of living 200 g rats were generated after intravenous administration of a triarylmethyl free radical (TAM). These maps were used to evaluate oxygen distribution. Differences between the liver, kidneys and bladder were noted. Conclusions were made regarding distribution, perfusion and excretion rate of the contrast medium. Ligature induced anoxia in the kidney was also visualised. LODESR involves transverse ESR irradiation with a modulated excitation and observing oscillations in the spin magnetisation parallel to the main magnetic field. The T1e* and T2e* maps were calculated from a set of LODESR signal phase images collected at different detection frequencies. Each phase image also provides qualitative information on tissue oxygen level without any further processing. Additionally, a new method is introduced for measuring T1e, valid for inhomogeneous spectra, based on measuring the spectral area as a function of detection frequency. These methods present alternatives to the conventional transverse ESR linewidth-based oximetry methods, particularly for animal whole body imaging applications.
5
方頌恩 and Chung-yan Gardian Fong. "Electro-clinical study and gene mapping of epilepsies." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2002. http://hub.hku.hk/bib/B31981781.
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6
Fong, Chung-yan Gardian. "Electro-clinical study and gene mapping of epilepsies." Hong Kong : University of Hong Kong, 2002. http://sunzi.lib.hku.hk/hkuto/record.jsp?B24463826.
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7
Kim, Hak Jin. "Ion-selective electrodes for simultaneous real-time analysis for soil macronutrients." Diss., Columbia, Mo. : University of Missouri-Columbia, 2006. http://hdl.handle.net/10355/4471.
Full textAbstract:
Thesis (Ph.D.)--University of Missouri-Columbia, 2006.The entire dissertation/thesis text is included in the research.pdf file; the official abstract appears in the short.pdf file (which also appears in the research.pdf); a non-technical general description, or public abstract, appears in the public.pdf file. Title from title screen of research.pdf file viewed on (April 26, 2007) Vita. Includes bibliographical references.
8
Emmenegger, Leonidas Philip. "Kelvin Probe Electrode for Field Detection of Corrosion of Steel in Concrete." Scholar Commons, 2015. http://scholarcommons.usf.edu/etd/5944.
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While the Kelvin Probe (KP) has been used in a variety of surface scanning applications, the use of the KP in reinforced concrete structures to detect corrosion has been pioneered by previous work performed at the University of South Florida. However, in that work, the scale and construction of the probes was not suited to use in the field. This is primarily attributable to the small operating disk-to-concrete gap which would make the probe unable to accommodate road conditions, such as irregularities in the grading of the road, and local pitting of the surface. Therefore, it was important to investigate whether the KP can be scaled up while still maintaining resolution and fidelity of the measurements taken. The new mobile KP prototype (MKPP) constructed in this work, has a sensing disk that is approximately 10 cm in diameter and is capable of operating up to 2 cm above the concrete surface. Testing consisted of mapping an instrumented test slab simulating a corroding concrete bridge deck, at a rate of travel of about 0.6 mph (~1 ft/s) over the slab surface. The potential map generated through use of the MKPP successfully identified the corroding spot, the location of which was verified using the traditional half-cell potential mapping method outlined in ASTM C 876-09. The MKPP mapping in these trials was approximately 10 times faster than when using the traditional method. The faster potential mapping by the MKPP, while still identifying corroding sites, should allow for more economical and less intrusive survey of the condition of bridge decks. The work set the necessary proof of concept for future demonstration of an array of such probes which would further magnify the beneficial effect.
9
Yeager, John David. "Design and development of metal-polymer film systems for flexible electrodes used in cortical mapping in rats." Pullman, Wash. : Washington State University, 2008. http://www.dissertations.wsu.edu/Thesis/Summer2008/j_yeager_070908.pdf.
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Thesis (M.S. in materials science and engineering)--Washington State University, August 2008.Title from PDF title page (viewed on Mar. 11, 2009). "School of Mechanical and Materials Engineering." Includes bibliographical references.
10
Komjathy, A. "Global ionospheric total electron content mapping using the global positioning system." Thesis, University of New Brunswick, 1997. http://hdl.handle.net/1882/925.
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11
Komjathy, Attila. "Global ionospheric total electron content mapping using the global positioning system." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1997. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp04/nq29468.pdf.
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12
Nicoletti, Olivia. "Mapping surface plasmons of metal nanoparticles with electron energy-loss spectroscopy." Thesis, University of Cambridge, 2013. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.608025.
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13
Antypas, Ioanna. "Theoretical approaches to magnetic induction mapping in the transmission electron microscope." Thesis, University of Cambridge, 2008. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.611855.
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14
Meggs, Robert W. "Mapping of ionospheric total electron content using global navigation satellite systems." Thesis, University of Bath, 2005. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.410922.
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15
Blinn, Kevin Scott. "Investigation of electrode surfaces in solid oxide fuel cells using Raman mapping and enhanced spectroscopy techniques." Diss., Georgia Institute of Technology, 2012. http://hdl.handle.net/1853/50142.
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Solid oxide fuel cells (SOFCs) represent a much cleaner and more efficient method for harnessing fossil fuel energy than conventional combustion; however, the challenge with making SOFCs mainstream lies in reducing operating costs and staving off their rapid degradation. High cathode polarization remains a bottleneck for lowering operation temperature. On the anode side, supplying SOFCs with hydrocarbon-based fuels poses many problems for systems using state-of-the-art material specifications such as composites of Ni and yttria-stabilized zirconia (YSZ). Various novel materials and surface modifications have been found to mitigate these problems, but more information towards a more profound understanding the role of these materials is desired. In this work, advanced Raman spectroscopic techniques were applied toward this end. Raman spectroscopy was used for the tracking of the evolution of water, carbon, sulfur, and oxygen species as well as new phases at SOFC electrode surfaces following or during exposure to various temperatures, atmospheres, and electrochemical stimuli. This information, coupled with performance data and other characterizations, would help to clarify the mechanisms of anode contamination reactions and oxygen reduction reactions. Knowledge gained from this work would also help to connect electrode modifications with performance enhancement and poisoning tolerance, offering insights vital to design of better electrodes. In addition, lack of adequate Raman signal from certain species, which is one of Raman spectroscopy’s limitations, was addressed. Surface enhanced Raman scattering (SERS) techniques were used in both in situ and ex situ analyses to increase signal yield from gas species and phases that are found only in trace amounts on electrode surfaces. Finally, a more practical thrust of this work was the application of this study methodology and the knowledge gained from it to cells with NASA's bielectrode supported cell (BSC) architecture. These types of cells also offer great prospects for superior specific power density due to their low weight. Ultimately, the goal of this thrust was progress towards achieving optimum performance of SOFCs operating under hydrocarbon fuels.
16
Walsh, Michael Thomas. "Kelvin Probe Electrode for Contactless Potential Measurement on Concrete-Properties and Applications." Scholar Commons, 2013. http://scholarcommons.usf.edu/etd/4850.
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The practical feasibility of using a Kelvin Probe as a novel reference electrode in the measurement of both potential and polarization pulse response of reinforcing steel in concrete is demonstrated. Potential values measured using a KP reflect greater stability and repeatability than can typically be attained with conventional reference electrodes. Duplicate reinforced concrete beam test specimens with well-differentiated centrally corroding rebar segments were analyzed using both the Kelvin Probe (KP) and a conventional Saturated Calomel Electrode (SCE). Potential profile maps were developed using potential values recorded under static conditions with both the SCE and the KP. Nominal polarization resistance was obtained using potential values recorded under dynamic polarization in both the active and passive regions using the KP and the SCE in conjunction with a customized counter electrode that applied a small galvanostatic polarizing current. In all cases the observed static potential values and dynamic potential response and recovery curves observed using the KP were consistent in shape and magnitude with those observed using conventional reference electrodes.
17
Boudlali, Hana. "Analysis of Electroanatomic Mapping System Accuracy Using X-Ray Reconstruction of Electrode Locations in a Porcine Animal Model." DigitalCommons@CalPoly, 2020. https://digitalcommons.calpoly.edu/theses/2237.
Full textAbstract:
Fluoroscopy is considered the gold standard for locating catheters during cardiac electrophysiology (EP) procedures. However, fluoroscopy emits ionizing radiation which can lead to adverse health effects when exposed to in high doses (World Health Organization, 2016). Electroanatomic mapping (EAM) systems display the three-dimensional location of EP catheters and measure the local electrical activity of the heart. They can minimize a physician’s reliance on fluoroscopy and can help reduce radiation exposure during a case (Casella, 2011).
EAM systems are diagnostic medical devices that inform the placement of ablation therapy and must accurately locate catheters to be deemed safe. Test methods to determine EAM system accuracy should be compared back to a gold standard, such as fluoroscopy. Fluoroscopy only provides a two-dimensional image of the catheter location, which is not a suitable ground truth for measuring the three-dimensional accuracy of EAM systems. X-Ray Reconstruction of Electrode Locations (XRROEL) calculates the true three-dimensional catheter location by performing a coordinate transform on two-dimensional fluoroscopy images. This thesis outlines the development and validation of the XRROEL method in a porcine animal model, and describes how XRROEL can be applied to optimize the location accuracy of electroanatomic mapping system algorithms.
18
Wallrapp, Frank. "Mixed quantum and classical simulation techniques for mapping electron transfer in proteins." Doctoral thesis, Universitat Pompeu Fabra, 2011. http://hdl.handle.net/10803/22685.
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El
objetivo
de
esta
tesis
se
centra
en
el
estudio
de
la
transferencia
de
electrones
(ET),
una
de
las
reacciones
más
simples
y
cruciales
en
bioquímica.
Para
dichos
procesos,
obtener
información
directa
de
los
factores
que
lo
promueves,
asi
como
del
camino
de
transferencia
electronica,
no
es
una
tarea
trivial.
Dicha
información
a
un
nivel
de
conocimiento
detallado
atómico
y
electrónico,
sin
embargo,
es
muy
valiosa
en
términos
de
una
mejor
comprensión
del
ciclo
enzimático,
que
podría
conducir,
por
ejemplo,
a
un
diseño
más
eficaz
de
inhibidores.
El
objetivo
principal
de
esta
tesis
es
el
desarrollo
de
una
metodología
para
el
estudio
cuantitativo
de
la
ET
en
los
sistemas
biológicos.
En
este
sentido,
hemos
desarrollado
un
nuevo
método
para
obtener
el
camino
de
transferencia
electrónico,
llamado
QM/MM
e-‐
Pathway,
que
se
puede
aplicar
en
sistemas
complejos
con
ET
de
largo
alcance.
El
método
se
basa
en
una
búsqueda
sucesiva
de
residuos
importantes
para
la
ET,
utilizando
la
modificación
de
la
región
quantica
en
métodos
mixtos
QM/MM,
y
siguiendo
la
evolución
de
la
densidad
de
espín
dentro
de
la
zona
de
transferencia.
Hemos
demostrado
la
utilidad
y
la
aplicabilidad
del
algoritmo
en
el
complejo
P450cam/Pdx,
identificando
el
papel
clave
de
la
Arg112
(en
P450cam)
y
del
Asp48
(en
Pdx),
ambos
conocidos
en
la
literatura.
Además
de
obtener
caminos
de
ET,
hemos
cuantificado
su
importancia
en
términos
del
acoplamiento
electrónico
entre
el
dador
y
aceptor
para
los
diferentes
caminos.
En
este
sentido,
se
realizaron
dos
estudios
de
la
influencia
del
solvente
y
de
la
temperatura
en
el
acoplamiento
electrónico
para
sistemas
modelo
oligopéptidos.
Ambos
estudios
revelaron
que
los
valores
del
acoplamiento
electrónico
fluctúan
fuertemente
a
lo
largo
de
las
trayectorias
de
dinámica
molecular
obtenidas,
y
el
mecanismo
de
transferencia
de
electrones
se
ve
ampliamente
afectado
por
el
espacio
conformacional
del
sistema.
La
combinación
del
QM/MM
e-‐pathway
y
de
los
cálculos
de
acoplamiento
electronico
fueron
utilizados
finalmente
para
investigar
la
ET
en
el
complejo
CCP/Cytc.
Nuestros
hallazgos
indican
el
papel
fundamental
del
Trp191
en
localizar
un
estadio
intermedio
para
la
transferencia
electronica,
así
como
el
camino
ET
principal
que
incluye
Ala194,
Ala193,
Gly192
y
Trp191.
Ambos
hallazgos
fueron
confirmados
a
través
de
la
literatura.
Los
resultados
obtenidos
para
el
muestro
de
manios
de
ET,
junto
con
su
evaluación
a
través
de
cálculos
de
acoplamiento
electrónico,
sugieren
un
enfoque
sencillo
y
prometedor
para
investigar
ET
de
largo
alcance
en
proteínas.The focus of this PhD thesis lies on electron transfer (ET) processes, belonging to the simplest but most crucial reactions in biochemistry. Getting direct information of the forces driving the process and the actual electron pathway is not a trivial task. Such atomic and electronic detailed information, however, is very valuable in terms of a better understanding of the enzymatic cycle, which might lead, for example, to more efficient protein inhibitor design. The main objective of this thesis was the development of a methodology for the quantitative study of ET in biological systems. In this regard, we developed a novel approach to map long-‐range electron transfer pathways, called QM/MM e-‐Pathway. The method is based on a successive search for important ET residues in terms of modifying the QM region following the evolution of the spin density of the electron (hole) within a given transfer region. We proved the usefulness and applicability of the algorithm on the P450cam/Pdx complex, indicating the key role of Arg112 of P450cam and Asp48 of Pdx for its ET pathway, both being known to be important from the literature. Besides only identifying the ET pathways, we further quantified their importance in terms of electronic coupling of donor and acceptor incorporating the particular pathway residues. Within this regard, we performed two systematic evaluations of the underlying reasons for the influence of solvent and temperature onto electronic coupling in oligopeptide model systems. Both studies revealed that electronic coupling values strongly fluctuate throughout the molecular dynamics trajectories obtained, and the mechanism of electron transfer is affected by the conformational space the system is able to occupy. Combining both ET mapping and electronic coupling calculations, we finally investigated the electron transfer in the CcP/Cytc complex. Our findings indicate the key role of Trp191 being the bridge-‐localized state of the ET as well as the main pathway consisting of Ala194, Ala193, Gly192 and Trp191 between CcP and Cytc. Both findings were confirmed through the literature. Moreover, our calculations on several snapshots state a nongated ET mechanism in this protein complex. The methodology developed along this thesis, mapping ET pathways together with their evaluation through electronic coupling calculations, suggests a straightforward and promising approach to investigate long-‐range ET in proteins.
19
Larsen, Sara E. 1977. "Quantitative comparison of functional MRI and electro-cortical stimulation for function mapping." Thesis, Massachusetts Institute of Technology, 2003. http://hdl.handle.net/1721.1/28334.
Full textAbstract:
Thesis (S.M.)--Massachusetts Institute of Technology, Dept. of Electrical Engineering and Computer Science, February 2004.Includes bibliographical references (p. 61-63).
Mappinlg functional areas of the brain is of vital importance for plallnning tumor resectiol. A accurate mapping provides information to leurosurgeons about which areas of the brain are eloquent, and should be avoided while removinlg the tumor. With the recent increase in the use of functional MRI for such pre-surgical planning, there is a nleed to validate that fMRI activation mrapping is consistent with the map)ppillg obtainled durinlg surgery with the standard technique, direct electro-cortical stimulationl. To this end, this thesis quanltitatively comlpares functionlal MRI lnapping with electro-cortical stimulation mapping.
by Sara E. Larsen.
S.M.
20
Lyu, Haixia. "Contributions to ionospheric modeling with GNSS in mapping function, tomography and polar electron." Doctoral thesis, Universitat Politècnica de Catalunya, 2020. http://hdl.handle.net/10803/670334.
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This dissertation focuses on determining the vertical electron content distribution in low and high vertical resolution from ground-based and LEO on board GNSS data and improving the knowledge of ionosphere climatology in northern mid-latitude and polar regions. The novelty is summarized in the following four aspects:
The first contribution is to propose a new ionospheric mapping function concept - Barcelona Ionospheric Mapping Function (BIMF), in order to improve STEC (Slant Total Electron Content) conversion accuracy from any given VTEC (Vertical Total Electron Content) model. BIMF is based on the climatic modeling of the VTEC fraction in the second layer - µ2, which is the byproduct of UQRG generated by UPC. The first implementation of BIMF is BIMF-nml for the northern mid-latitudes, where the latitudinal variation of µ2 is neglected. µ2 is modeled as function of date and local time. From the user’s perspective, BIMF is the linear combination of µ2 and the standard ionospheric mapping function, and only needs 41 constant coefficients, making BIMF achieve the simplicity for application. The good performance has been demonstrated in the dSTEC assessment for different IGSGIMs: UQRG, CODG and JPLG.
The second contribution is to confirm the capability of UQRG GIMs to detect representative ionospheric features in polar regions through six case studies, including TOI (Tongue of Ionization), trough, flux transfer event, theta-aurora, ionospheric convection patterns and storm enhanced density. The long-term VTEC and µ2 data provide valuable databases for studying the morphology and climatology of polar ionospheric phenomena. The unsupervised clustering results of normalized VTEC distribution show that TOI and polar cap patches exhibit an annual dependence, i.e. most TOI and patches occurring in the North Hemisphere winter and the South Hemisphere summer.
The third contribution is to propose a hybrid method - AVHIRO (the Abel-VaryChap Hybrid modeling from topside Incomplete RO data), to solve an ill-posed rank-deficient problem in the Abel electron density retrieval. This work is driven by the future EUMETSAT Polar System 2nd Generation, which provides truncated ionospheric RO data, only below impact heights of 500 km, in order to guarantee a full data gathering of the neutral part. AVHIRO takes advantage of one Linear Vary-Chap model, where the scale height increases linearly with altitude above the F2 layer peak, and uses Powell search to solve the full electron densities, ambiguity term, and four parameters of the Vary-Chap model simultaneously, taking into account the nonlinear interactions between the unknown parameters.
The fourth contribution is to take advantage of the geometry brought by combining DORIS, ground-based Galileo, ground-based, LEO-POD and vessel-based GPS data and ingest the multi-source dual-frequency carrier phase measurements into the tomographic model to improve the GIM VTEC estimation precision. The impact of adding each type of measurements, which are Galileo data, vessel-based GPS data, DORIS and LEO-POD GPS data, to ground-based GPS data on GIM product is examined according to two complementing evaluation criteria, JASON-3 VTEC comparison and GPS dSTEC test. This study proves the expected better GIM performance by new data ingestion into tomographic model, which is a successful step forward from conception to initial experimental validation.electrones en resolución vertical baja y alta a partir de medidas GNSS terrestres y a bordo de satélites de órbita baja (LEO), además de utilizar medidas GNSS desde buques y medidas DORIS, además de mejorar el conocimiento de la climatología de la ionosfera en las regiones polares y en latitudes medias del hemisferio norte. Las contribuciones se pueden resumir en los siguientes cuatro aspectos: La primera contribución consiste en proponer un nuevo concepto de función de mapeo ionosférico: la función de mapeo ionosférico de Barcelona (BIMF), con el fin de mejorar la precisión de conversión de STEC (contenido total de electrones inclinado) a partir de cualquier modelo de VTEC (contenido total de electrones vertical). BIMF se basa en el modelado climático de la fracción VTEC en la segunda capa - μ2, que es el subproducto de UQRG generado por UPC. La primera implementación de BIMF es BIMF-nml para las latitudes medias del hemisferio norte. μ2 se modela en función del dia y la hora local. Desde la perspectiva del usuario, BIMF es la combinación lineal de μ2 y la función de mapeo ionosférico estándar, y solo necesita 41 coeficientes constantes, lo que hace que BIMF sea facilmente aplicable. Su buen comportamiento se demostró en la evaluación dSTEC para diferentes IGS GIM: UQRG, CODG y JPLG. La segunda contribución se centró en confirmar la capacidad de los GIM UQRG para detectar características ionosféricas representativas en regiones polares a través de seis estudios de casos, que incluyen lenguas de ionización (TOI), depresión de ionización en forma de canal, sucesos de transferencia de flujo, theta-aurora, patrones de convección ionosférica y densidad aumentada durante tormentas geomagnéticas. Los datos a largo plazo de VTEC y μ2 proporcionan valiosas bases de datos para estudiar la morfología y climatología de los fenómenos ionosféricos polares. Los resultados de agrupamiento no supervisados de la distribución normalizada de VTEC muestran que los TOI y los parches en los casquetes polares exhiben una dependencia anual, es decir, la mayoría de los TOI y parches ocurren en el invierno del Hemisferio Norte y el verano del Hemisferio Sur. La tercera contribución ha consistido en proponer un método híbrido: AVHIRO (el modelo híbrido Abel-VaryChap a partir de datos de RO incompletos en la parte superior), para resolver un problema de rango deficiente en la recuperación de la densidad electrónica con el modelo de Abel. Este trabajo está motivado por el futuro sistema polar EUMETSAT de segunda generación, que proporciona datos truncados de RO ionosférica, sólo por debajo de las alturas de impacto de 500 km, con el fin de garantizar una recopilación completa de medidas de la parte neutra. AVHIRO aprovecha un modelo Linear Vary-Chap, donde la altura de la escala aumenta linealmente con la altitud por encima del pico de la capa F2, y utiliza la búsqueda Powell para resolver las densidades completas de electrones, el término de ambig ¨ uedad y cuatro parámetros del modelo Vary-Chap simultáneamente, teniendo en cuenta las interacciones no lineales entre los parámetros desconocidos. La cuarta contribución es aprovechar la geometría aportada por la combinación de datos GPS DORIS, Galileo en tierra, LEO-POD y en barco, e incorporar las mediciones de la fase de la portadora de doble frecuencia de múltiples fuentes en el modelo tomográfico para mejorar la precisión de estimación de GIM VTEC. El impacto de agregar cada tipo de mediciones, que son datos de Galileo, datos de GPS basados en embarcaciones, datos de GPS DORIS y LEO-POD, a datos de GPS terrestres en productos GIM se examina de acuerdo con dos criterios de evaluación complementarios, comparación con VTEC[JASON-3] y con dSTEC[GPS]. Este estudio demuestra el mejor rendimiento esperado de GIM por la nueva ingesta de datos en el modelo tomográfico, que es un exitoso paso adelante desde la concepción hasta la validación experimental inicial.
21
Di, Gioacchino Fabio. "Characterization of mesoscopic crystal plasticity from high-resolution surface displacement and lattice orientation mappings." Thesis, University of Manchester, 2013. https://www.research.manchester.ac.uk/portal/en/theses/characterization-of-mesoscopic-crystal-plasticity-from-highresolution-surface-displacement-and-lattice-orientation-mappings(77c47c76-e2ee-44ff-bdef-c53e25bb6bc1).html.
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Being able to predict the evolution of plastic deformation at the microstructural scale is of paramount importance in the engineering of materials for advanced applications. However, this is not straightforward because of the multiscale nature of deformation heterogeneity, both in space and time . The present thesis combines four related studies in a coherent work, which is aimed to develop experimental methods for studying crystal plasticity at the micro and mesoscale. A novel methodology for gold remodelling is initially proposed and used to apply high-density speckle patterns on the surface of stainless steel specimens. The unique proprieties of the speckle pattern enabled plastic deformation mapping with submicron resolution using digital image correlation (HDIC). It was therefore possible to study the concomitant evolution of microbands and transgranular deformation bands in such alloy. High-resolution deformation mapping also enabled comparison with high-resolution electron backscatter diffraction (EBSD) observations. The only partial correspondence of results proved the limits of EBSD in characterizing plastic deformation. The cause of such limitation is later identified in the reduced sensitivity to lattice slip of the EBSD technique. Hence, a novel method of HDIC data analysis is proposed to separate the contributions of lattice slip and lattice rotation from the deformation mapping. The method is adopted to characterize plasticity in austenitic stainless steel and at the plastic deformation zone (PDZ) around a silicon particle embedded in a softer aluminum matrix. Results show that the proposed experimental methodology has the unique capability of providing a complete description of the micro and mesoscale mechanics of crystal plasticity. HDIC therefore emerges as a key technique in the development of accurate physical-based multiscale crystal plasticity models.
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Royle, Georgina. "Towards quantitative intra-nuclear dose mapping of auger emitting radionuclides used for targeted radiotherapy." Thesis, University of Oxford, 2016. https://ora.ox.ac.uk/objects/uuid:83c94d40-91a2-4175-b208-b5ea1bd5a207.
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Targeted radiotherapy (TRT) is a technique which allows for individual cancer cells to be targeted by radiation. However, there is variation in uptake at the whole body, organ, cellular and subcellular levels. This distribution affects the biological efficacy of the TRT agents. To address this problem, novel techniques have been developed and demonstrated. These aim to provide quantitative information about the spatial distribution of Auger electron (AE) emitting radiopharmaceuticals at the subcellular level. Two methods have been developed. The first, photoresist autoradiography (PAR), uses photoresists as an autoradiography substrate, and the second uses microautoradiography (MAR) and a transmission electron microscope (TEM). The techniques have been demonstrated using the AE emitter indium-111. Firstly, PAR is demonstrated using poly (methyl methacrylate) (PMMA). Photoresists were exposed to indium-111 which had been internalised into cells, and the photoresists were analysed using atomic force microscopy (AFM). The technique has a theoretical resolution in the nanometre range and was able to demonstrate cellular patterns on the micron scale. To gain quantitative information, the photoresist response (depth of pattern) was calibrated as a function of electron fluence and a model of the patterns was created. Combining the calibration data with the point source model allowed the position and intensity of the internalised source terms to be estimated using the PAR method. Secondly, a technique for electron microscope-microautoradiography (EM-MAR) was developed. The processing conditions of the MAR technique were determined and staining techniques developed, to produce high quality TEM micrographs. A time course experiment showed the distribution and variation in the uptake of the radiopharmaceutical at the cellular level. Both techniques are able to provide information about the subcellular distribution of the radioactivity at a higher resolution than current techniques. Both enable the collection of information which can be used in microdosimetric calculations.
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Hikita, M., M. Matsuoka, R. Shimizu, K. Kato, N. Hayakawa, and H. Okubo. "Kerr electro-optic field mapping and charge dynamics in impurity-doped transformer oil." IEEE, 1996. http://hdl.handle.net/2237/6874.
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Nukala, Haritha. "QUANTITATIVE THICKNESS MAPPING IN HIGH-ANGLE ANNULAR DARK-FIELD (HAADF) SCANNING TRANSMISSION ELECTRON MICROSCOPY (STEM)." Master's thesis, University of Central Florida, 2008. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/4292.
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Only a few methods are currently available for the measurement of sample thicknesses in Transmission Electron Microscopy (TEM). These methods, Convergent-Beam Electron Diffraction (CBED) and thickness mapping in Energy-Filtered TEM (EFTEM), are either elaborate or complex. In this present work, I have investigated and come up with a simple straight-forward method to measure the local thickness of a TEM sample with the atomic number (Z-contrast) imaging using High-Angle Annular Dark Field (HAADF) Scanning Transmission Electron Microscopy (STEM). HAADF STEM shows atomic number contrast for high scattering angles of the electrons, owing to predominant electron scattering at the potential of the nucleus similar to Rutherford scattering. The characterization of materials by STEM helps to identify microstructures and nanostructures within a sample and to analyze defects in samples. HAADF STEM imaging is capable of resolving atomic structures with better than 2 Å lateral resolution. However, HAADF STEM has so far not been systematically used to measure sample thicknesses. In Z-contrast imaging, it was known that the intensity of the electrons scattered to high angles increases with increase in the atomic number (Z) of the element/compound with increasing thickness of the sample based on the equation, I ~ t.Zα Where t, is the thickness and α, is a parameter between 1 and 2. This project was started with this simple approach, but the experimental results within the thesis show that the relation between the intensity and the atomic number is not well described by this equation. A more reliable parameter, σZ, the interaction coefficient of the material was calculated. Samples containing Ag2Al platelets in Al matrix were used for calibration purposes. Additional samples containing layers of known elements/compounds were obtained from TriQuint Semiconductors and from the Physics department of UCF to calculate σ for various elements/compounds. These experimental values were used to measure the local thicknesses in nanoparticles and also the total volume of the nanoparticles. This quantitative HAADF STEM analysis represents a new method, which can be added to the list of methods used for the purpose of measurement of the local thickness of a sample in the TEM. This method is especially useful for the thickness measurement of nanoparticles. The other two methods, CBED and thickness maps in EFTEM are strongly affected by the sample orientation and therefore not appropriate for the study of nanoparticle thicknesses, whereas orientation effects are negligible for the conditions used in this HAADF STEM analysis.M.S.
Department of Mechanical, Materials and Aerospace Engineering;
Engineering and Computer Science
Materials Science & Engr MSMSE
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Andersen, Ingrid Marie. "2D and 3D quantitative TEM mapping of CoNi nanowires." Thesis, Toulouse 3, 2020. http://www.theses.fr/2020TOU30205.
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Les nanofils magnétiques constituent un domaine de recherche en plein essor. De section cylindrique, ils permettent la propagation des parois de domaines magnétiques à très grandes vitesses et des interactions fortes avec les ondes de spin, ce qui les rend particulièrement intéressants pour le développement de futurs composants de la spintronique. L'objectif de ce travail de thèse est de fournir une analyse quantitative et qualitative complète de la configuration magnétique locale dans des nanofils magnétiques cylindriques d'alliage CoNi à anisotropie magnétocristalline perpendiculaire en utilisant les techniques d'imagerie magnétique avancées de la microscopie électronique à transmission (MET), principalement axées sur l'holographie électronique (HE). Une étude corrélative entre les propriétés structurales, les variations locales de composition et les configurations magnétiques de ces nanofils a été réalisée. De plus, les configurations tridimensionnelles (3D) complexes des domaines et des parois magnétiques ont été analysées par tomographie holographique de champ vectoriel (THCV) afin d'obtenir les trois composantes de l'induction magnétique. Enfin, un protocole a été développé pour étudier in situ par microscopie de Lorentz la configuration magnétique de ces nanofils lors de l'injection d'impulsions de courant. La première partie de ce travail est focalisée sur la corrélation des configurations magnétiques de nanofils individuels de CoNi avec les propriétés structurales et chimiques locales. L'orientation de la phase cristalline a été cartographiée en diffraction électronique par précession et combinée à des mesures de composition par spectroscopie de perte d'énergie des électrons. Les résultats révèlent une coexistence de grains de phase cfc et de phase hcp, cette dernière présente sa direction cristallographique c orientée presque perpendiculairement à l'axe du nanofil. Cette coexistence de phases cristallographiques est à l'origine de variations localisées et abruptes de la configuration magnétique. Deux nanofil configurations principales ont été observées : une chaîne d'états transversaux par rapport à l'axe du, de type vortex, et un état longitudinal. Nous avons observé que les états transversaux sont liés à la phase hcp possédant une forte anisotropie magnétocristalline perpendiculaire, ce que confirment les simulations micromagnétiques. Une autre partie de ce travail concerne l'étude de la structure magnétique 3D des domaines et des parois de domaines dans la phase hcp. Cette étude a été menée pour des états rémanents différents en fonction de l'application d'un champ de saturation perpendiculaire et parallèle à l'axe du nanofil. Les mesures ont été réalisées par la méthode THCV afin d'extraire les trois composantes de l'induction magnétique et reconstruire en 3D la configuration magnétique locale du nanofil. Les résultats montrent une stabilisation d'une chaîne de vortex dans le cas d'une saturation perpendiculaire, et des états d'enroulement longitudinaux séparés par des parois de domaine transversales après l'application d'un champ externe parallèle à l'axe du fils. La dernière partie du manuscrit présente les résultats obtenus en microscopie de Lorentz in situ démontrant la possibilité de manipuler les parois des domaines magnétiques d'un nanofil de CoNi par injection d'impulsions électriques. Cette preuve de concept est considérée comme le précurseur des observations in situ de la dynamique des parois de domaines en EH. Un protocole précis, axé sur les étapes cruciales de préparation des échantillons et les développements à poursuivre pour réaliser ces expériences délicates, est détailléCylindrical magnetic nanowires (NWs) are currently subjects of high interest due to fast domain wall velocities and interaction with spin-waves, which are considered interesting qualities for developing future spintronic devices. This thesis aims to provide a wholesome quantitative and qualitative analysis of the local magnetic configuration in cylindrical Co-rich CoNi NWs with perpendicular magnetocrystalline anisotropy using state-of-the-art transmission electron microscopy (TEM) magnetic imaging techniques, mainly focused on two-dimensional (2D) and three-dimensional (3D) electron holography (EH). A correlative study between the NW's texture, modulation in composition, and magnetic configuration has been conducted. Further, the complex 3D nature of the domain and domain wall configurations have been analyzed using holographic vector field electron tomography (VFET) to retrieve all three components of the magnetic induction. Finally, I have successfully manipulated the magnetic configuration observed by Lorentz microscopy in Fresnel mode by the in situ injection of a current pulse. A TEM study comparing the magnetic configuration to the local NW structure was performed on single NWs. The crystal phase analysis was done by precession electron diffraction assisted automated crystal orientation mapping in the TEM combined with compositional analysis by scanning-TEM (STEM) electron energy loss spectroscopy (EELS) for a detailed correlation with the sample's magnetic configuration. The results reveal a coexistence of fcc grains and hcp phase with its c-axis oriented close to perpendicular to the wire axis in the same NW, which is identified as the origin of drastic local changes in the magnetic configuration. Two main configurations are observed in the NW region: a chain of transversal vortex-like states and a longitudinal curling state. The chain or vortices are linked to the hcp grain with the perpendicular magnetocrystalline anisotropy, as confirmed by micromagnetic simulations. The 3D magnetic structure of the domains and domain walls observed in the hcp grain of the NWs has been studied for two different remnant states: after the application of a saturation field perpendicular (i) and parallel (ii) to the NW axis. The measurements were done using state-of-the-art holographic VFET to extract all three components of the magnetic induction in the sample, as well as a 3D reconstruction of the volume from the measured electric potentials, giving insight into the local morphology of the NW. The results show a stabilization of a vortex chain in the case of perpendicular saturation, but longitudinal curling states separated by transversal domain walls after applying a parallel external field. Finally, preliminary Lorentz microscopy results are presented, documenting the manipulation of magnetic domain walls by the in situ injection of electrical pulses on a single cylindrical CoNi nanowire contacted by focused ion beam induced deposition. This is believed to be the forerunner for quantitative electrical measurements and in situ observations of domain wall dynamics using EH at the CEMES. A detailed protocol focusing on the crucial steps and challenges ahead for such a delicate experiment is presented, together with suggestions for future work to continue the developments
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Martínez, Mateu Laura. "Mapping of the electrical activity of human atria. Multiscale modelling and simulations." Doctoral thesis, Universitat Politècnica de València, 2018. http://hdl.handle.net/10251/104604.
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La fibrilación auricular es una de las arritmias cardíacas más comunes observadas en la práctica clínica. Por lo tanto, es de vital importancia desarrollar nuevas tecnologías destinadas a diagnosticar y acabar con este tipo de arritmia, para mejorar la calidad de vida de los pacientes y reducir los costes de los sistemas nacionales de salud.
En los últimos años ha aumentado el uso de las nuevas técnicas de mapeo auricular, basadas en sistemas multi-electrodo para mapear la actividad eléctrica en humanos. Dichas técnicas permiten localizar y ablacionar los impulsores de la fibrilación auricular, como son las fuentes focales o los rotores. Sin embargo, todavía existe incertidumbre sobre su precisión y los procedimientos experimentales para su análisis están limitados debido a su carácter invasivo. Por lo tanto, las simulaciones computacionales son una herramienta muy útil para superar estas limitaciones, al permitir reproducir con fidelidad las observaciones experimentales, dividir el problema bajo estudio en sub-estudios más simples, y realizar investigaciones preliminares imposibles de llevar a cabo en el práctica clínica.
Esta tesis doctoral se centra en el análisis de la precisión de los sistemas de mapeo multi-electrodo a través de modelos y simulaciones computacionales. Para ello, desarrollamos modelos realistas multi-escala con el objetivo de simular actividad eléctrica auricular reentrante, en primer lugar en una lámina de tejido auricular, y en segundo lugar en las aurículas completas. Posteriormente, analizamos los efectos de las configuraciones geométricas multi-electrodo en la precisión de la localización de los rotores, mediante el uso de agrupaciones multi-electrodo con distancias inter-electrodo equidistantes, así como a través de catéteres de tipo basket con distancias inter-electrodo no equidistantes. Después de calcular los electrogramas unipolares intracavitarios, realizamos mapas de fase, detecciones de singularidad de fase para rastrear los rotores, y mapas de frecuencia dominantes. Finalmente, descubrimos que la precisión de los sistemas de mapeo multi-electrodo depende de su posición dentro de la cavidad auricular, de la distancia entre los electrodos y el tejido, de la distancia inter-electrodo, y de la contribución de las fuentes de campo lejano. Además, como consecuencia de estos factores que pueden afectar a la precisión de los sistemas de mapeo multi-electrodo, observamos la aparición de rotores falsos que podrían contribuir al fracaso de los procesos de ablación de la fibrilación auricular.Atrial fibrillation is one of the most common cardiac arrhythmias seen in clinical practice. Therefore, it is of vital importance to develop new technologies aimed at diagnosing and terminating this kind of arrhythmia, to improve the quality of life of patients and to reduce costs to national health systems. In the last years, new atrial mapping techniques based on multi-electrode systems are increasingly being used to map the atrial electrical activity in humans and localise and target atrial fibrillation drivers in the form of focal sources or rotors. However, significant concerns remain about their accuracy and experimental approaches to analyse them are limited due to their invasive character. Therefore, computer simulations are a helpful tool to overcome these limitations since they can reproduce with fidelity experimental observations, permit to split the problem to treat into more simple substudies, and allow the possibility of performing preliminary investigations impossible to carry out in the clinical practice. This PhD thesis is focused on the analysis for accuracy of the multielectrode mapping systems through computational models and simulations. For this purpose, we developed realistic multiscale models in order to simulate atrial electrical reentrant activity, first in a sheet of atrial tissue and, then, in the whole atria. Then, we analysed the effects of the multi-electrode geometrical configurations on the accuracy of localizing rotors, by using multi-electrode arrays with equidistant inter-electrode distances, as well as multi-electrode basket catheters with non-equidistant inter-electrode distances. After computing the intracavitary unipolar electrograms, we performed phase maps, phase singularity detections to track rotors, and dominant frequency maps. We finally found out that the accuracy of multi-electrode mapping systems depends on their position inside the atrial cavity, the electrode-to-tissue distance, the inter-electrode distance, and the contribution of far field sources. Furthermore, as a consequence of these factors, false rotors might appear and could contribute to failure of atrial fibrillation ablation procedures.
La fibril·lació auricular és una de les arítmies cardíaques més comuns observades en la pràctica clínica. Per tant, és de vital importància desenvolupar noves tecnologies destinades a diagnosticar i acabar amb aquest tipus d'arítmia, per tal de millorar la qualitat de vida dels pacients i reduir els costos dels sistemes nacionals de salut. En els últims anys, ha augmentat l'ús de les noves tècniques de mapeig auricular, basades en sistemes multielèctrode per a mapejar l'activitat elèctrica auricular en humans. Aquestes tècniques permeten localitzar i ablacionar els impulsors de la fibril·lació auricular, com són les fonts focals o els rotors. No obstant això, encara hi ha incertesa sobre la seua precisió i els procediments experimentals per al seu anàlisi estan limitats a causa del seu caràcter invasiu. Per tant, les simulacions computacionals són una eina molt útil per a superar aquestes limitacions, en permetre reproduir amb fidelitat les observacions experimentals, dividir el problema sota estudi en subestudis més simples, i realitzar investigacions preliminars impossibles de dur a terme en el pràctica clínica. Aquesta tesi doctoral es centra en l'anàlisi de la precisió del sistemes de mapeig multielèctrode mitjançant els models i les simulacions computacionals. Per a això, desenvolupàrem models realistes multiescala per tal de simular activitat elèctrica auricular reentrant, en primer lloc en una làmina de teixit auricular, i en segon lloc a les aurícules completes. Posteriorment, analitzàrem els efectes de les configuracions geomètriques multielèctrode en la precisió de la localització dels rotors, mitjançant l'ús d'agrupacions multielèctrode amb distàncies interelèctrode equidistants, així com catèters de tipus basket amb distàncies interelèctrode no equidistants. Després de calcular els electrogrames unipolars intracavitaris, vam realitzar mapes de fase, deteccions de singularitat de fase per a rastrejar els rotors, i mapes de freqüència dominants. Finalment, vam descobrir que la precisió dels sistemes de mapeig multielèctrode depèn de la seua posició dins de la cavitat auricular, de la distància entre els elèctrodes i el teixit, de la distància interelèctrode, i de la contribució de les fonts de camp llunyà. A més, com a conseqüència d'aquests factors, es va observar l'aparició de rotors falsos que podrien contribuir al fracàs de l'ablació de la fibril·lació auricular.
Martínez Mateu, L. (2018). Mapping of the electrical activity of human atria. Multiscale modelling and simulations [Tesis doctoral no publicada]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/104604
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Doyle, Liam A. "Density mapping of species in low temperature laser-produced plasmas." Thesis, Queen's University Belfast, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.287439.
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Halekas, J. S., D. L. Mitchell, R. P. Lin, S. Frey, L. L. Hood, M. H. Acuña, and A. B. Binder. "Mapping of crustal magnetic anomalies on the lunar near side by the Lunar Prospector electron reflectometer." American Geophysical Union, 2001. http://hdl.handle.net/10150/624000.
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Lunar Prospector (LP) electron reflectometer measurements show that surface fields are generally weak in the large mare basalt filled impact basins on the near side but are stronger over highland terranes, especially those lying antipodal to young large impact basins. Between the Imbrium and Nectaris basins, many anomalies correlate with the Cayley and Descartes Formations. Statistical analyses show that the most strongly magnetic nearside terranes are Cayley-type light plains, terra materials, and pre-Imbrian craters. Light plains and terrae include basin impact ejecta as a major component, suggesting that magnetization effects from basin-forming impacts were involved in their formation. The magnetization of pre-Imbrian craters, however, may be evidence of early thermal remanence. Relatively strong, small-scale magnetic anomalies are present over the Reiner Gamma feature on western Oceanus Procellarum and over the Rima Sirsalis rille on the southwestern border of Procellarum. Both Apollo subsatellite and LP data show that the latter anomaly is nearly aligned with the rille, though LP magnetometer and reflectometer data show that the anomaly peak is actually centered over a light plains unit. This anomaly and the Reiner Gamma anomaly are approximately radially aligned with the center of Imbrium, suggesting an association with ejecta from this basin.
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Soto-Iglesias, David. "Development and evaluation of mapping strategies for the integration and joint analysis of multi-modal data of the heart." Doctoral thesis, Universitat Pompeu Fabra, 2016. http://hdl.handle.net/10803/395191.
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The development of novel technologies is allowing a complete description of the heart structure and function, including geometrical, myocardial tissue viability and electrical activation information. The joint analysis of this information helps to improve clinical interventions such as radio-frequency ablation of cardiac arrhythmias. However, the acquired data and related indices need to be integrated onto a common reference space for its analysis. This integration is not straightforward due to the different characteristics of acquisition systems.
The aim of this thesis was to develop and evaluate different mapping strategies for the integration and joint analysis of multi-modal data of the heart. A new integration methodology was developed and compared with state-of-the-art techniques in several applications with synthetic and clinical data, within the framework of three different clinical scenarios: a) integration of electrical with tissue viability; b) analysis of electrical activation data; and c) validation of myocardial tissue characterization with histological data.El desarrollo de nuevas tecnologías permite una completa descripción de la estructura y funcionalidad cardíaca incluyendo la geometría la viabilidad del tejido y la información de activación eléctrica. Un análisis conjunto de esta información permite mejorar intervenciones clínicas como la ablación por radio frecuencia en arritmias. Sin embargo, los datos adquiridos deben ser integrados en un mismo sistema de referencia para su análisis. Esta integración no es trivial debido a las diferentes características de adquisición de datos. El objetivo de esta tesis es desarrollar y evaluar diferentes estrategias para la integración y el análisis de datos multimodales del corazón. La nueva metodología de integración ha sido comparada y evaluada con otras técnicas en datos sintéticos y clínicos. Se han evaluado en tres escenarios clínicos distintos: a) integración de datos eléctricos con viabilidad de tejido; b) análisis de activación eléctrica; y c) validación de la caracterización del tejido con datos histológicos.
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Shet, Keerthi Vishnudas. "Development Of Instrumentation And Techniques To Adapt Proton Electron Double Resonance Imaging For Biomedical Imaging." The Ohio State University, 2008. http://rave.ohiolink.edu/etdc/view?acc_num=osu1227731151.
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Schneider, Christian [Verfasser]. "Mapping of surface plasmon polariton fields by time-resolved photoemission electron microscopy: experiments, simulations, and applications / Christian Schneider." München : Verlag Dr. Hut, 2013. http://d-nb.info/1043892516/34.
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Takeuchi, Yoji, Kayo Horibuchi, Tetsu Ohsuna, Hiroki Kondo, Tsuyoshi Sasaki, Kazuyoshi Tatsumi, and Shunsuke Muto. "Mapping of Heterogeneous Chemical States of Lithium in a LiNiO2-Based Active Material by Electron Energy-Loss Spectroscopy." The Electrochemical Society, 2010. http://hdl.handle.net/2237/20790.
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Ibrahim, Hanna. "Clinical outcomes after using of Rhythmia mapping system in patients with differentcomplex arrhythmias." Thesis, Örebro universitet, Institutionen för medicinska vetenskaper, 2021. http://urn.kb.se/resolve?urn=urn:nbn:se:oru:diva-91082.
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Background: Rhythmia is a novel mapping system of cardiac arrhythmias, it utilizes a multielectrode catheter, Orion. Together these two instruments generate high accurate maps of the cardiac chamber which facilitate the identification of arrythmia focus and its ablation. Objective: our aim of this study was to evaluate the safety and feasibility of the Rhythmia system, mid-term recurrence rate and the predictors of recurrence from intervention and patients related factors. Methods: this was a retrospective cohort analysis on patients who underwent cardiac ablation with Rhythmia system at Örebro University Hospital between October 2017 and March 2020. The patients were followed-up to evaluate the recurrence. Results: 62 ablation procedures were included, premature ventricular contraction 20, atrial fibrillation 19, ectopic atrial tachycardia 10, ventricular tachycardia 6, atrial flutter 5 and accessory pathways 2. Rhythmia was feasible with 100% technically successful procedures. It had also low complications risk, with an overall 6.5% complications rate. Over a mean follow up of 5.1 months (Range 1-12), 59% of patients got recurrence. The highest recurrence rate of 75% was observed in the premature ventricular complex group. None of all studied variables showed any statistically significance association with the recurrence of the most three encountered arrhythmias. Conclusion: the use of Rhythmia was feasible and relatively safe. The recurrence rate of arrhythmias after using Rhythmia was high, and no reliable predictors could be found. However, there was a trend that atrial fibrillation which required long total procedure time and long fluoroscopy time had higher risk to recur.
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Khandelwal, Avinash 1987. "The wiring diagram of antennal lobe and mapping a brain circuit that controls chemotaxis behavior in the Drosophila larva." Doctoral thesis, Universitat Pompeu Fabra, 2017. http://hdl.handle.net/10803/663806.
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Drosophila larvae present unique opportunity for anatomical and functional mapping of their nervous system because of features such as numerical simplicity of neurons its nervous system is composed of, and ability to exhibit quantifiable behaviors such as chemotaxis. Here, we mapped entire antennal lobe of larval Drosophila with one of its circuits responsible for controlling sensorimotor transformation in lateral horn (LH) (higher brain) through a single brain descending neuron using electron microscopic 3D reconstruction.
In antennal lobe, we reported a canonical circuit with uniglomerular projection neurons (uPNs), working to relay gain-controlled ORN activity to higher brain centers like Mushroom body and lateral horn. We also found a parallel circuit with multiglomerular projection neurons (mPNs) and hierarchically organized local neurons (LNs) selectively integrating signal from multiple ORNs at the first synapse with LN-LN connectivity putatively implementing gain control mechanism that can potentially switch from computing distinguished odor signals through panglomerular inhibition to allowing system to respond to faint aversive odor in an environment rich with strong appetitive odors.
We also reconstructed and studied one of the olfactory connected circuits in the LH that was found to be influencing chemotaxis behavior in larva through a single brain descending neuron, PVM027. We found that this neuron was responsible in controlling stop response of chemotaxis behavior. EM reconstruction revealed its connection with variety of motor systems and SEZ descending neurons in the VNC. Connections were revealed with the peristaltic wave propagation circuit of larva, and PVM027 was found to be implementing stop by terminating and ceasing the origin of forward peristaltic waves.Las larvas de Drosophila ofrecen una oportunidad única para el mapeo anatómico y funcional de su sistema nervioso debido a propiedades como la simplicidad numérica de neuronas que componen su sistema nervioso y su habilidad de exhibir comportamientos cuantificables como la quimiotaxis. En este estudio hemos mapeado el lóbulo antenal de la larva de Drosophila con uno de sus circuitos responsable de controlar la transformación sensorial-motora en el asta lateral (LH) (cerebro superior) a través de una sola neurona descendiente usando la reconstrucción 3D para microscopia electrónica. Hemos presentado, en el lóbulo antenal, un circuito canónico con proyecciones neuronales uniglomerulares (uPNs) responsables de transmitir aumentos controlados de actividad desde sus ORN* hasta centros superiores del cerebro como el cuerpo fungiforme y el asta lateral del protocerebro. Hemos descubierto también un circuito paralelo formado por neuronas con proyecciones multiglomerulares (mPNs) y neuronas locales (Lns), organizadas jerárquicamente, que integran selectivamente señales desde múltiples ORNs a nivel de primera sinapsis con conectividad LN-LN implementando aparentemente un mecanismo de aumento de control que potencialmente puede intercambiar señales olfativas distintas computacionalmente a través de inhibición panglomerular permitiendo al sistema responder a olores vagamente aversivos en un ambiente rico en fuertes olores apetitosos. También hemos reconstruido y estudiado uno de los circuitos olfativos que conectan con el LH conocido por influenciar la quimiotaxis de la larva a través de un sola neurona cerebral descendiente, la PVM027. Hemos descubierto que dicha neurona es la responsable de controlar la respuesta stop en el comportamiento de quimiotaxis. La reconstrucción por EM revela su conexión con una variedad de sistemas motores así como neuronas descendientes SEZ en el VNC. Observamos dichas conexiones gracias al circuito de propagación de onda peristáltica de la larva, y descubrimos que la PVM027 implementa la señal de stop terminando e interrumpiendo el origen de la onda peristáltica.
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Lin, Chung-Han. "The Effects of Thermal, Strain, and Neutron Irradiation on Defect Formation in AlGaN/GaN High Electron Mobility Transistors and GaN Schottky Diodes." The Ohio State University, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=osu1371466261.
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Škvarenina, Ľubomír. "Charakterizácia tenkovrstvových solárnych článkov a analýza mikroštruktúrnych defektov." Doctoral thesis, Vysoké učení technické v Brně. Fakulta elektrotechniky a komunikačních technologií, 2021. http://www.nusl.cz/ntk/nusl-447549.
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Thin-film solar cells based on an absorber layer of chalcogenide compounds (CIGS, CdTe) are today among the most promising photovoltaic technologies due to their long-term ability to gain a foothold in mass commercial production as an alternative to conventional Si solar cells. Despite this success, the physical origin of the defects present in the thin films are still insufficiently elucidated, especially in the compounds of the chalcopyrite family Cu(In_{1x},Ga_{x})(S_{y},Se_{1y})_{2}. The research focuses on the identification and analysis of microstructural defects responsible for the electrical instability of chalcopyrite-based thin-film solar cells with a typical heterostructure arrangement ZnO:Al/i-ZnO/CdS/Cu(In,Ga)Se_{2}/Mo. The non-uniform polycrystalline nature of semiconductor materials in this complex multilayer structure requires a comprehensive analysis of electro-optical, structural and compositional properties associated with the actual morphology at the macroscopic, microscopic or even nanoscopic level. The observed predominant ohmic or non-ohmic current conduction in the dark transport characteristics was also reflected in the slope deviations of the excessive noise fluctuations, which were in the spectral domain exclusively in the form of flicker noise with dependency S_{i} ~ f^{1}. Spatially resolved electroluminescence based on stimulated photon emission by charge carriers injecting into the depletion region, not only showed a significantly inhomogeneous distribution of intensity in planar heterojunction under forward bias, but also revealed light emitting local spots in reverse bias due to a trap-assisted radiative recombination through the high density of defect states. Microscopic examination of the defect-related light emitting spots revealed rather extensive defective complexes with many interruptions through the layers, especially at the heterojunction CdS/Cu(In,Ga)Se_{2} interface. Besides, the high leakage current via these defective complexes subsequently led to a considerable local overheating, which caused a clearly observable structural and morphological changes, such as deviations in absorber layer stoichiometry due to Cu–In–Ga–Se segregation, Cu-rich and Ga-rich grains formation with an occurrence of Se-poor or Cu_{x}Se_{y} secondary phases regions, material redeposition accompanied by evaporation of ZnO:Al/i-ZnO/CdS layers together with the formation of Se structures on the surface around the defects. Within the research, analytical modelling of transport characteristics was implemented with parameters extraction of individual transport mechanisms to understand the non-ohmic shunt behaviour due to leakage current. In addition to the proper current path along the main heterojunction, the proposed model contains parasitic current pathways as a consequence of recombination-dominated charge transport or current conduction facilitated by multi-step tunnelling via high density of mid-gap defect states in the depletion region, ohmic leakage current caused by pinholes or low-resistance paths along grain boundaries in Cu(In,Ga)Se_{2}, or space-charge limited current due to metals diffusion from the ZnO:Al layer and grid Ag contacts through disruptions in i-ZnO/CdS layers.
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Ondračka, Václav. "Užití elektronové difrakce k mapování elastického napětí." Master's thesis, Vysoké učení technické v Brně. Fakulta strojního inženýrství, 2021. http://www.nusl.cz/ntk/nusl-449747.
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Electron backscatter diffraction is a method that is well described and commonly used for orientation image mapping, including grain size estimation. The use of this method for measuring elastic deformation and rotations caused by plastic deformations is not so well decribed. This diploma thesis first describes the typical EBSD system. The information regarding the standard coordinate systems, grain orientation notation and system calibration is then used to create an open-source software for mapping elastic deformations and rotations inside a single grain or a monocrystal. This software uses data acquired during standard EBSD mapping on a commercial system.
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Pfisterer, Jonas H. K. [Verfasser]. "Toward nanoscale reactivity mapping under electro-catalytic reaction conditions : Plasmon-enhanced vibrational spectroscopy of the electrochemical gold oxidation and gold oxide reduction / Jonas H. K. Pfisterer." Mainz : Universitätsbibliothek Mainz, 2019. http://d-nb.info/1199377449/34.
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Sickmann, Jan. "Ortsaufgelöste Messung der Gitterverspannungen in Halbleitern mittels Dunkelfeld off-axis Elektronenholographie." Doctoral thesis, Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2015. http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-160646.
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Die Dunkelfeld off-axis Elektronenholographie (DFH) im Transmissionselektronenmikroskop ist eine nanoskalige Interferometriemethode, die es erlaubt, eine ausgewählte Beugungswelle eines Kristalls aufzuzeichnen und anschließend als zweidimensionale Amplituden- und Phasenverteilung zu rekonstruieren. Da sich aus dem Gradientenfeld der Phasenverteilung geometrische Verzerrungen des Kristallgitters bestimmen lassen, ermöglicht die DFH, Deformationsfelder in Kristallen zu vermessen. Damit eröffnen sich der Halbleiterindustrie vielversprechende Analysemöglichkeiten von lokalen mechanischen Verspannungen in Halbleiterkristallen insbesondere im Kanalbereich von Transistoren. Dabei verspricht die DFH eine höhere Ortsauflösung als rasternde, auf Elektronenbeugung mit möglichst fein fokussierten Elektronensonden basierende Methoden wie Nanobeugung. Jedoch steht die DFH als Analysemethode für mechanische Verspannungen bisher noch nicht standardmäßig zur Verfügung. Forschungs- und Entwicklungsbedarf besteht insbesondere hinsichtlich der Anpassung der Methodik auf kompliziertere Halbleiterstrukturen. Am Beispiel des Elementargitters wird demonstriert, wie einerseits die Gitterverzerrung die Phase der Beugungswelle moduliert, und wie andererseits aus dem Gradient der Phase diese Deformation wieder rekonstruiert werden kann. Zusätzlich wird die Modulation der Beugungswelle mit Hilfe eines erst kürzlich veröffentlichten analytischen Modells für den Zweistrahlfall erläutert. Spezielle Anpassungen der DFH im TEM erlauben, die geometrische Phase entweder mit 3...5 nm Lateralauflösung bei 200 nm breitem Gesichtsfeld oder mit 8...10 nm Lateralauflösung bei 800 nm breitem Gesichtsfeld aufzuzeichnen. Da die Deformationskarte durch numerische Ableitung der geometrischen Phase bestimmt wird, hängt die Signalauflösung der Deformationsmessung direkt von der Signalqualität in der rekonstruierten geometrischen Phase ab. Da die Ableitung das Rauschen verstärkt, werden verschiedene Strategien zur Rauschminderung und Signalverbesserung untersucht, u.a. werden Methoden zur Rauschfilterung eines DF-Hologramms oder zur Glättung der Deformationskarte vorgestellt. Durch Rekonstruktion einer gemittelten geometrischen Phase aus einer Dunkelfeldhologrammserie lassen sich Deformationen E mit einer Messabweichung von lediglich Delta_E=+/-0,05% bestimmen. Bei Aufzeichnung und Rekonstruktion der geometrischen Phase treten eine Reihe von Artefakten auf, die durch Fresnelsche Beugungssäume, defekte Detektorpixel sowie Verzeichnungen durch Projektivlinsen und Detektoroptik hervorgerufen werden. Da sie die Bestimmung der Deformationskarte erschweren, werden geeignete Methoden zur Vermeidung oder Korrektur vorgestellt. Die Präparation von TEM-Lamellen mit fokussiertem Ionenstrahl (FIB) verursacht Schädigungen der Probenoberfläche. Durch Vergleiche von DFH-Messungen mit Finite-Elemente-Simulationen wird gezeigt, dass die auf Oberflächenrelaxation zurückzuführenden Abweichungen vom simulierten Deformationszustand bei 120...160 nm Lamellendicke bis zu 10% betragen können. Präparationsbedingte lokale Dickenvariationen (Curtaining) können zu ähnlich großen Abweichungen führen. Anwendbarkeit und Funktionalität der DFH werden an modernen Halbleiterstrukturen untersucht. Die Vermessung einer verspannten SiGe-Schicht auf Si-Substrat zeigt eine sehr gute Übereinstimmung mit einem analytischen Modell. Die Abweichung beträgt ca. 10% und kann durch Oberflächenrelaxation an der SiGe/Si-Grenzfläche erklärt werden. Mittels SiGe an Source und Drain verspannte Transistoren dienen als Testobjekte für einen Vergleich von DFH und Nanobeugung. Beide Methoden liefern identische Ergebnisse. Der Vorteil der DFH besteht jedoch darin, das Deformationsfeld vollständig in Form einer zweidimensionalen Karte abzubilden, anstatt wie die Nanobeugung lediglich einzelne Profilschnitte zu messen. Die Deformationsmessung an SOI-Strukturen wird durch die leicht unterschiedliche Kristallorientierung (Miscut) zwischen SOI und Si-Substrat, das als Referenzbereich dient, erschwert. Die Deformationswerte im SOI zeigen ein Offset von 0,2% Dehnung gegenüber dem Si-Substrat. Der Miscut zwischen SOI und Si-Substrat kann zu 0,3°bestimmt werden. Für Transistoren mit tensiler Deckschicht gelingt es, Dehnungen von +0,3% in perfekter Übereinstimmung mit FE-Simulationen zu messen. Bei Transistoren, bei denen gleichzeitig eine kompressive Deckschicht und SiGe an Source und Drain eingesetzt werden, gelingt es mittels DFH, Stauchungen von -(0,1+/-0,05)% im Transistorkanal 5 nm unterhalb des Gateoxids nachzuweisenDark-field off-axis electron holography (DFH) in a transmission electron microscope is based on the interference of a diffracted wave emanating from adjacent strained and unstrained sample areas to form a dark-field hologram, from which the phase of the diffracted wave can be reconstructed. Since the gradient of the phase parallel to the diffraction vector yields the lattice strain in this direction, a two-dimensional strain map can be derived. Therefore, DFH is considered to be a promising technique for strain metrology by semiconductor industry, especially for local strain measurements in the transistor channel. In particular, DFH offers better lateral resolution than scanning TEM-techniques based on electron diffraction with small focused electron probe like nano-beam diffraction. However, DFH is not yet available as a standard technique for strain metrology. Research is still needed to apply the method to complex devices. Using the example of a strained cosine lattice the phase modulation due to lattice distortions is discussed. In addition, modulation of the diffracted wave is approximated in two-beam diffraction condition. Adjustments of DFH in the TEM provide strain measurements with 3...5 nm lateral resolution at 200 nm field of view or 8...10 nm lateral resolution at 800 nm field of view. During recording and reconstruction of dark-field holograms several artifacts appear, for instance Fresnel diffraction, defective detector pixels, distortions of projective lenses or detector optics. Since they limit strain evaluation, suitable methods to either avoid or correct these artifacts are discussed. Sample preparation with focused ion beam (FIB) causes surface damage. Comparing DFH results with finite-element simulations reveals a deviation of 10% between simulation and experiment at 120...160 nm sample thickness due to surface relaxation. FIB-induced thickness variations (curtaining) lead to comparable deviations. Applicability of DFH for strain metrology is analyzed on several modern device structures. Strain measurements of SiGe-layers on Si-substrate correspond quite well with an analytic model. A residual deviation of 10% can be explained by surface relaxation close to the SiGe/Si-interface. Transistors strained by SiGe-source/drain serve as test objects for a comparison of DFH with nano-beam diffraction. Though both techniques reveal identical results, DFH is able to map the complete two-dimensional strain field, whereas nano-beam diffraction can only provide single line-scans. Strain mapping in silicon-on-insulator (SOI) is limited by the different crystal orientation (miscut) between the SOI layer and the Si-substrate, which serves as reference. Strain values in the SOI show an off-set of 0.2% in comparison to the unstrained Si-substrate. The miscut between SOI and Si-substrate is estimated to 0.3°. In transistor devices with tensile stress overlayers DFH is able to measure +0.3% tensile strain in excellent agreement with finite-element simulations. In devices with compressive overlayers and SiGe-source/drain a strain value of only -(0.1+/-0.05)% can be determined in the transistor channel 5nm beneath the gate oxide
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Barutcu, Mazi Isil. "Effects Of Different Batter Formulations On Physical And Chemical Properties Of Microwave And Conventionally Fried Chicken Fingers." Phd thesis, METU, 2009. http://etd.lib.metu.edu.tr/upload/3/12611495/index.pdf.
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The main objective of this study was to determine the effects of batters containing various flour types and frying methods on physical and chemical properties of chicken fingers.
To determine the effects of different flour types, 30 % of the corn and wheat flour mix in control batter was replaced with chickpea, rice or soy flours. Frying was performed in microwave oven at 365 W (70 %) power level and at 180
1°
C for different times. Samples were also fried in a conventional fryer at 180&
#61617
1°
C for comparison. The properties that were measured were coating pick-up and moisture content, oil content, color, hardness, porosity and acrylamide content of fried samples. In addition, microstructural analysis of batters and temperature distribution of fried samples during cooling were performed. Moisture content of chicken fingers decreased whereas the darkness, porosity and hardness of samples increased with increasing microwave frying time. Using microwaves decreased frying time by 70 %. Samples fried for 1.5 min using microwave provided similar moisture and oil contents in the coating part as compared to conventionally fried ones for 5min. However, the chicken part of microwave fried sample had lower moisture content. Lighter colored samples with higher porosity and lower hardness values were obtained with microwave frying. In microwave frying, soy flour addition to batter formulation decreased the moisture loss and oil absorption as compared to control by 19.3% and 20.7%, respectively. The lowest hardness, the highest porosity and oil content were obtained with the addition of chickpea flour. Flour type was not found to be effective on acrylamide content. Microwave frying provided lower acrylamide content as compared to those fried conventionally for all types of flours. The reduction in acrylamide level was the highest (34.5%) for rice flour containing batter. Color parameters of chicken fingers were not found to be a reliable indicator of acrylamide levels. Different types of frying method and flours used in batter formulation resulted in differences in the microstructure of fried batter. Variations in internal temperature distribution during cooling increased with frying time in both microwave and conventional frying. The sample fried in microwave oven for 1.5 min had a more nonuniform temperature distribution.
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Hu, Jing. "High resolution characterisation of corrosion and hydrogen pickup of Zr-Nb cladding alloys." Thesis, University of Oxford, 2016. http://ora.ox.ac.uk/objects/uuid:a986c6e5-bba4-48c2-8e30-7f77ebe5313e.
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Zr cladding alloys have been used for many years as the first safety barrier layer of a nuclear reactor. However, the recent Fukushima accidents and industrial demands to increase the burnup of fuels have led to increasing interest in a detailed mechanistic understanding of aqueous corrosion and hydrogen pickup and the performance at high temperatures. As part of an international MUZIC-2 programme (Mechanistic Understanding of Zr Corrosion and Hydrogen pickup), I have used a range of advanced microscopy techniques to study the microstructure, the nanoscale chemistry and the porosity in a series of zirconium alloys at different stages of corrosion and hydrogen pickup. Samples from both autoclave and in-reactor conditions were available to compare, I have focussed on RXA (recrystallised 580°C) Zr-1.0Nb and annealed (720°C) Zr-1.0Nb alloys. A set of samples from different exposures times were chosen to represent early, pre-transition and post-transition samples in order to compare the microstructure and microchemistry of the oxides, the metal-oxide interface and the metal. (Scanning) Transmission Electron Microscopy ((S)TEM), Transmission Kikuchi Diffraction (TKD) and automated crystal orientation mapping with TEM (ASTAR mapping) were used to study the grain structure and phase distribution. Significant differences in grain morphology were observed between samples oxidised in the autoclave with different corrosion rates, with more uneven metal-oxide interface, more parallel cracks and less organised oxide grains in the fast corroding samples. Comparing with autoclave samples, the in-reactor samples have shorter, less well-aligned monoclinic grains and more tetragonal grains. The rapidly oxidising annealed Zr-1.0Nb alloy also have much higher tetragonal grain fraction comparing with the slow corrosion rate RXA Zr-1.0Nb alloys. Porosity in the oxide is predicted to have a major influence on the overall rate of corrosion and hydrogen pickup, and there is much more porosity in the annealed Zr-1.0Nb alloy than found in either the RXA alloy or the similar alloy exposed to neutron irradiation. A combination of Energy Dispersion X-ray (EDX) mapping in STEM and Electron Energy Loss Spectroscopy (EELS) analysis of second phase particles can reveal the main and the minor element distributions respectively. The annealed Zr-1.0Nb alloys have Î2-Zr SPPs with nano crystalline structure and much larger size. Although they does not relate with the higher density of cracks in the oxide, the large SPP size can connect together all the small cracks that are generated by the huge amount of tetragonal to monoclinic phase transformation during corrosion and provides pathway for corrosion and hydrogen pickup. Two kinds of SPPs are found in the RXA Zr-1.0Nb alloys, one is Î2-Nb and another one is Zr-Nb-Fe Laves phase. Neutron irradiation seems to have little effect on promoting fast oxidation or dissolution of Î2-Nb precipitates, but encourages dissolution of Fe from Laves phase precipitates. Electron Energy Loss Spectroscopy (EELS) analysis of the oxidation state of Nb in Î2-Nb SPPs in the oxide revealed the fully oxidised Nb5+ state in the SPPs deep into the oxide, but Nb2+ in the crystalline SPPs near the metal-oxide interface. EELS, TKD and ASTAR mapping have also revealed the presence of suboxide layers with the hexagonal ZrO structure predicted by ab initio modelling. The combined thickness of the ZrO suboxide and oxygen-saturated layers at the metal-oxide interface correlates well to the estimated instantaneous oxidation rate, suggesting that the presence of this oxygen- rich zone combining with the part where porosity is not interconnected is the protective oxide that is rate limiting in the key in the transport processes involved in corrosion and hydrogen pickup.
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Bäckström, Ann. "Investigation of the correlation of fracture frequency and electric resistivity in impact craters in crystalline rocks." Licentiate thesis, KTH, Land and Water Resources Engineering, 2004. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-1725.
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Impact craters are formed when a large meteorite or comethits the Earth. At the impact a shock wave is released causingabundant fracturing in the surrounding bedrock. This type offracturing is intense and occurs throughout a very large volume(>100 km3) of the bedrock. Fractures of this type have beenobserved in deep drilling, to 5 km depth, in thePuchezh-Katunki Impact Crater. At theses depths the ambienttemperature is high. Thus impact structures are candidates forpotential heat-exchange sources for extraction of geothermalenergy.
There is a relation between fracture intensity and electricresistivity in bedrock predominated by impact-generatedfractures. In crystalline bedrock changes in electricresistivity is mainly due to fracturing which is the mainsource of porosity in these rocks. Electric resistivity methodsare highly sensitivity to porosity. Furthermore highfracture-intensities have generally been associated with lowelectric resistivity. Electro-magnetic methods like Very LowFrequency Resistivity (VLF-R) and Magnetotellurics (MT) canindirectly measure electric resistivity to relatively largedepths in the bedrock.
This study will quantify the relationship between fractureintensity and electric resistivity which can be used as aprospecting tool for geothermal energy resources at largedepth.
To meet that end, a method for fracture mapping on outcropsin Swedish terrain and a method to calculate thethree-dimensional fracture frequency from two-dimensionalfracture data has been developed. The fracture traces measuredin two dimensions on outcrops are assumed to represent avertical surface and must be converted to a three-dimensionalmeasure of the fracture frequency per unit volume. Spacing, dipand trace length of fractures have been accounted for. Thebiases associated with the mapping method have also beenaccounted for (II).
The correlation between impact-induced fracturing andelectric resistivity in crystalline rocks in the Lockne Areashows that the extent of impact fracturing in crystalline rockscan be measured with electro-magnetic or electric techniques.In addition the electric resistivity of crystalline basementand impact generated Tandsby Breccia from the Lockne Craterwere determined (I).
The relation between fracture frequency and electricresistivity in fresh water conditions using the VLF-R method isestablished from data collected from both two drill holes andfrom numerous outcrops in the Björkö region. Apreliminary quantification of the fracture frequency has beenmade. The MT resistivity models, related to the two drillholes, show that porosity and mineral-conductivity variationsof the bedrock affect this relation more than the salinityvariations in the bore-hole fluid. Further research is neededto establish a firm relation between fracture frequency,salinity of rock fluid, conductivity and porosity in order tovalidate the MT resistivity models (III).
Keywords:Electric resistivity, Fracture frequency,Impact generated fractures, Electro-magnetic techniques, VLF-Rmethod, MT method, Window-mapping technique, Three-dimensionalfracture calculations, heat-exchange structure, geothermalenergy.
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Risbridger, Thomas Arthur George. "Aqueous dye sensitized solar cells." Thesis, University of Bath, 2013. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.607628.
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Dye sensitized solar cells (DSSCs) have typically been produced using organic liquids such as acetonitrile as the electrolyte solvent. In real world situations water can permeate into the cell through sealing materials and is also likely to be introduced during the fabrication process. This is a problem as the introduction of water into cells optimized to use an organic solvent tends to be detrimental to cell performance. In this work DSSCs which are optimized to use water as the main electrolyte solvent are produced and characterized. Optimization of aqueous DSSCs resulted in cells with efficiencies up to 3.5% being produced. In terms of characterization, it is generally seen in this work that aqueous DSSCs produce a lower photocurrent but similar photovoltage compared to DSSCs made using acetonitrile and reasons for this are examined in detail. The decreased ability of the aqueous electrolyte to wet the nanoporous TiO2 compared to an acetonitrile electrolyte is found to be a key difficulty and several possible solutions to this problem are examined. By measuring the photocurrent output of aqueous cells as a function of xy position it can be seen that there is some dye dissolution near to the electrolyte filling holes. This is thought to be linked to pH and the effect of 4-tert-butylpyridine and may also decrease the photocurrent. It is found that there is little difference between the two types of cells in terms of the conduction band position and the reaction of electrons in the semiconductor with triiodide in the electrolyte, explaining the similarity in photovoltage. By altering the pH of the electrolyte in an aqueous cell it is found to be possible to change the TiO2 conduction band position in the DSSC. This has a significant effect on the open circuit voltage and short circuit current of the cell, though the pH range available is limited by the fact that dye desorbs at high pH values.
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Tiu, Glacialle. "Classification of Drill Core Textures for Process Simulation in Geometallurgy : Aitik Mine, Sweden." Thesis, Luleå tekniska universitet, Mineralteknik och metallurgi, 2017. http://urn.kb.se/resolve?urn=urn:nbn:se:ltu:diva-65207.
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This thesis study employs textural classification techniques applied to four different data groups: (1) visible light photography, (2) high-resolution drill core line scan imaging (3) scanning electron microscopy backscattered electron (SEM-BSE) images, and (4) 3D data from X-ray microtomography (μXCT). Eleven textural classes from Aitik ores were identified and characterized. The distinguishing characteristics of each class were determined such as modal mineralogy, sulphide occurrence and Bond work indices (BWI). The textural classes served as a basis for machine learning classification using Random Forest classifier and different feature extraction schemes. Trainable Weka Segmentation was utilized to produce mineral maps for the different image datasets. Quantified textural information for each mineral phase such as modal mineralogy, mineral association index and grain size was extracted from each mineral map. Efficient line local binary patterns provide the best discriminating features for textural classification of mineral texture images in terms of classification accuracy. Gray Level Co-occurrence Matrix (GLCM) statistics from discrete approximation of Meyer wavelets decomposition with basic image statistical features[PK1] (e.g. mean, standard deviation, entropy and histogram derived values) give the best classification result in terms of accuracy and feature extraction time. Differences in the extracted modal mineralogy were observed between the drill core photographs and SEM images which can be attributed to different sample size[PK2] . Comparison of SEM images and 2D μXCT image slice shows minimal difference giving confidence to the segmentation process. However, chalcopyrite is highly underestimated in 2D μXCT image slice, with the volume percentage amounting to only half of the calculated value for the whole 3D sample. This is accounted as stereological error. Textural classification and mineral map production from basic drill core photographs has a huge potential to be used as an inexpensive ore characterization tool. However, it should be noted that this technique requires experienced operators to generate an accurate training data especially for mineral identification and thus, detailed mineralogical studies beforehand is required.Primary Resource Efficiency by Enhanced Prediction (PREP)
Center for Advanced Mining and Metallurgy (CAMM)
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Bessière, Francis. "Amélioration des techniques d’ablation pour le traitement des arythmies cardiaques : nouvelles modalités diagnostiques et thérapeutiques par ultrasons." Thesis, Lyon, 2019. http://www.theses.fr/2019LYSE1225/document.
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A la croisée des chemins entre médecine et physique des ultrasons, ce travail de thèse s’est intéressé à l’apport de solutions diagnostiques et de thérapeutiques novatrices dans le domaine de l’électrophysiologie cardiaque. Un système capable de délivrer des ultrasons focalisés dans le cœur par voie transoesophagienne sous guidage par ultrasons a été développé et testé in vivo chez 6 porcs. Les tirs HIFU ont été délivrés sur les oreillettes et les ventricules. Lors de l'autopsie, une analyse visuelle a démontré la présence de lésions thermiques dans les zones ciblées chez 3 animaux. Ces lésions ont été confirmées par analyse histologique (taille moyenne: 5,5 mm2 x 11 mm2). Aucune lésion thermique œsophagienne n'a été observée. Un animal a présenté une bradycardie due à un bloc auriculo-ventriculaire, ce qui a permis de confirmer une réelle interaction entre les tirs HIFU et le tissu nodal cardiaque. Nous avons cependant observé un manque de précision, principalement lié aux mouvements cardiaques ainsi qu’aux structures anatomiques situées entre les zones ciblées et le transducteur de thérapie. Ces difficultés ont été principalement reliées à l’anatomie du modèle porcin, loin de celle de l’être humain. La recherche d'un meilleur modèle a conduit à des tests d'imagerie concluants sur des babouins.Des expériences supplémentaires ont été conduites afin d'améliorer la cartographie des arythmies ventriculaires et le suivi de la formation de lésions pendant l'ablation.Des expériences ont été menées sur les ventricules gauches de quatre coeurs de porcs en mode travaillant. Le protocole visait à démontrer que différents modèles d'activation mécanique pouvaient être observés, que le ventricule soit en rythme sinusal, stimulé depuis l'épicarde ou l'endocarde. Des acquisitions d’imagerie de déformation électromécanique (EWI) ont été enregistrées sur les faces antérieures, latérales et postérieures du ventricule gauche. Les boucles ont été ensuite analysées à l’aveugle par deux lecteurs indépendants.Les interprétations des séquences EWI étaient correctes dans 89% des cas. Le taux de concordance globale entre les deux lecteurs était de 83%. Dans un ventricule stimulé, l'origine du front d'onde était focale et provenait de l'endocarde ou de l'épicarde stimulé. En rythme sinusal, le front d'onde était activé depuis tout l'endocarde, en direction de l'épicarde, à une vitesse de 1,7 ± 0,28 m.s-1. Les vitesses du front d'onde ont été mesurées respectivement lorsque l'endocarde ou l'épicarde étaient stimulés à une vitesse de 1,1 ± 0,35 m.s -1 et 1,3 ± 0,34 m.s-1 (p = NS). Nous avons aussi démontré sur des échantillons ex-vivo que l'imagerie trans oesophagienne par analyse des ondes de cisaillement (élastographie) pouvait cartographier l'étendue des lésions HIFU. Des tirs HIFU ont été réalisés à l'aide de la sonde trans oesophagienne sur des échantillons de blancs de poulet (n = 3), puis sur un modèle porcin ex vivo d'oreillette (gauche, n = 2) et de ventricule gauche (n = 1). L’élastographie a fourni des cartes de rigidité des tissus avant et après l'ablation. Les zones des lésions ont été obtenues par analyse et quantification des changements de couleur des tissus puis ont été comparées aux images par élastographie. Dans le blanc de poulet, la rigidité est passée en moyenne de 4.8±1.1 kPa à 20.5±10.0 kPa (ratio 5.0±3.2). Dans le ventricule gauche, la rigidité est passée en moyenne de 21.2±3.3kPa à 73.8±13.9kPa (ratio 3.7±1.2). Dans l’oreillette gauche, la rigidité est passée en moyenne de 12.2±4.3 kPa à 30.3±10.3 (ratio 3.2±2.0). En histologie, la taille des lésions variait de 0.1 à 1.5 cm2 dans la zone du plan d'imagerie. Les caractéristiques morphométriques étaient similaires entre histologie et élastographieAt the crossroads of medicine and physics, this work aimed to provide innovative diagnostic and therapeutic tools based on ultrasound, in the field of cardiac electrophysiology. A system capable of delivering HIFU into the heart by a transesophageal route using ultrasound (US) imaging guidance was developed and tested in vivo in six male pigs. HIFU exposures were performed on atria and ventricles. At the time of autopsy, visual inspection identified thermal lesions in the targeted areas in three of the animals. These lesions were confirmed by histologic analysis (mean size: 5.5 mm2 x 11mm2). No esophageal thermal injury was observed. One animal presented with bradycardia due to an atrio-ventricular block, which provides real-time confirmation of an interaction between HIFU and the electrical circuits of the heart. There was still a lack of accuracy, mainly related to cardiac motion, and to anatomical structures in between the targets and the transducer. It was mainly related to the in vivo model and its anatomy, far from the human’s. The search for a better model led to conclusive imaging tests on baboons. Additional experiments were conduced in order to improve the mapping of ventricular arrhythmias and the monitoring of lesion formation during ablation. First, experiments were conducted on left ventricles of four isolated working mode swine hearts. The protocol aimed at demonstrating that different patterns of mechanical activation could be observed whether the ventricle was in sinus rhythm, paced from the epicardium, or from the endocardium. Electromechanical wave imaging (EWI) acquisitions were recorded on the anterior, lateral, and posterior segments of the left ventricle. Loop records were blindly assigned to two readers. EWI sequences interpretations were correct in 89% of cases. The overall agreement rate between the two readers was 83%. When in a paced ventricle, the origin of the wave front was focal and originating from the endocardium or the epicardium. In sinus rhythm, wave front was global and activated within the entire endocardium towards the epicardium at a speed of 1.7±0.28 m.s-1. Wave front speeds were respectively measured when the endocardium or the epicardium were paced at a speed of 1.1 ± 0.35 m.s-1 vs 1.3±0.34 m.s-1 (p=NS). Lastly, we investigated the feasibility of a dual therapy and imaging approach with the same transoesophageal device. We demonstrated on ex-vivo samples that transoesophageal shear wave imaging (SWE) can map the extent of the HIFU lesions. HIFU ablation was performed with the transoesophageal probe on ex-vivo chicken breast samples (n=3), then atrium (left, n=2) and ventricle (left n=1, right n=1) of swine heart tissues. SWE provided stiffness maps of the tissues before and after ablation. Areas of the lesions were obtained by tissue color change with gross pathology and compared to SWE. Shear modulus of the ablated zones increased from 4.8±1.1 kPa to 20.5+/-10.0 kPa (ratio 5.0±3.2) in the chicken breast, from 12.2±4.3 kPa to 30.3±10.3 (ratio 3.2±2.0) in the atria and from 21.2±3.3kPa to 73.8±13.9kPa (ratio 3.7±1.2) in the ventricles. On gross pathology, the size of the lesions ranged from 0.1 to 1.5cm2 in the imaging plane area and morphometric characteristics were fitting with elasticity-estimated depths and widths of the lesions
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Kopelvski, Maycon Max. "Desenvolvimento de um sistema de caracterização de emissores de elétrons baseado no mapeamento de corrente por imagem." Universidade de São Paulo, 2018. http://www.teses.usp.br/teses/disponiveis/3/3140/tde-12122018-152930/.
Full textAbstract:
Dispositivos de emissão de elétrons por efeito de campo elétrico (FE - Field Emission Devices) têm sido propostos para aplicações como fontes eficientes de elétrons em nanolitografia, microscopia eletrônica, sensores microeletrônicos de vácuo, entre outras. Atualmente os sistemas tradicionais utilizados para caracterização de dispositivos FE fornecem apenas o comportamento geral da emissão de elétrons, ou seja, não permitem efetuar uma investigação mais seletiva e precisa dos centros emissores que constituem o dispositivo, durante seu funcionamento como dispositivo. Frente a esta lacuna, este trabalho propõe o desenvolvimento de um sistema de caracterização de dispositivos emissores de elétrons através do processamento de imagens integrado ao tradicional levantamento da característica corrente-tensão (I-V) do dispositivo. Tais imagens são obtidas através do impacto dos elétrons em uma tela fosforescente. A plataforma LabVIEW foi aplicada para o desenvolvimento do algoritmo de processamento dos sinais, que incorpora desde a etapa de aquisição dos dados (ou seja, medições realizadas pelos instrumentos) até a apresentação dos resultados em diferentes formatos (imagem ou representações gráficas), à escolha do usuário. O sistema desenvolvido permitiu avaliar, quantificar e identificar a distribuição da corrente de emissão em distintas regiões de interesse de amostras compostas por microestruturas ou filmes emissores de elétrons, resultando em representações gráficas bi e tridimensionais. Complementarmente, o sistema também permitiu comparar o desempenho dos dispositivos de emissão de elétrons por efeito de campo elétrico e estudar os efeitos físicos relacionados ao impacto dos elétrons em diferentes tipos de telas fosforescentes. Esta proposta resultou em uma ferramenta inovadora para análise de emissão de elétrons, com a vantagem de manter o dispositivo dentro do seu ambiente de operação, em alto vácuo, representando um grande avanço na metodologia aplicada para se obter características operacionais de dispositivos FE e proporcionando uma caracterização com qualidade superior, visto que proporcionou uma avaliação localizada dos centros emissores numa dada matriz.Field emission devices (FE devices) have been proposed as efficient sources of electrons for applications in nanolithography, electron microscopy, microelectronic vacuum sensors, among others. Nowadays, the traditional FE characterization systems provide only information related to the general behavior of the electron emission, that is, they do not have specific tools to execute more selective and precise investigation of the emitting centers during their operation as device. As an alternative, this work proposes the development of a dedicated system for characterization of FE by integrating image processing with the traditional current-voltage (I-V) characteristics of the devices. Such images are obtained by the impact of electrons on a phosphorescent screen. The LabVIEW platform was applied to develop the algorithm of signal processing. This algorithm processes information from the data acquisition stage (instruments measurements) to the presentation of the results in different ways (image or graphical representation), according to the researcher´s choices. The developed system allowed evaluating, quantifying and identifying the emission current distribution in different regions of interest of samples composed by microstructures or thin emitting electron films, whose results could be represented in two and threedimensional graphics. Additionally, the system also allowed comparing the performance of electron emission devices by electrical field effect and studying physical effects related to the impact of electrons in different types of phosphorescent screens. This proposal resulted in an innovative tool for electron emission analysis, with the advantage of keeping the device inside its high vacuum characterization environment, which represents a significant advance in the methodology applied to obtain operational characteristics of FE devices and to provide a characterization with superior quality, since it provided a localized evaluation of the emitting centers in a given matrix.
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Lafond, Clément. "Cartographie d’orientations cristallines à partir du contraste de canalisation en microscopie électronique à balayage." Thesis, Lyon, 2020. http://www.theses.fr/2020LYSEI031.
Full textAbstract:
Les cartographies d’orientations cristallines sont aujourd’hui un outil incontournable de la caractérisation des matériaux cristallins, notamment des métaux. Les cartographies d’orientations permettent entre autre de quantifier la nature et la taille de phases en présence, l’état de déformation ou la texture. Ce travail de thèse porte sur le développement d’une technique de cartographie des orientations basée sur l’analyse de contrastes du au phénomène de canalisation. Ces contrastes sont obtenus par imagerie aux électrons rétrodiffusés dans un Microscope Electronique à Balayage. La méthode se nomme eCHORD, pour electron CHanneling Orientation Determination. Dans un premier temps, la preuve de concept de la méthode est présentée sur un alliage d’aluminium et l’influence des paramètres d’acquisition est détaillée. Puis, deux problématiques particulières sont abordées : la cartographie d’échantillons de grandes tailles, ainsi que la cartographie à basse tension (1kV). La méthode eCHORD présente de grands intérêts pour l’analyse de matériaux peu conducteurs, habituellement très difficiles à cartographier avec les techniques actuelles, et ouvre de grandes perspectives pour l’étude de matériaux céramiques notammentCrystalline orientation mapping is a key tool in material characterization, in particular for metals. For instance, orientation mapping allows to quantify the nature and size of phases in the presence, deformation state or texture. This thesis work focuses on the development of an orientation mapping approach based on the analysis of the electron channeling contrast. This contrast is obtained from electron back-scaterred imaging in a Scanning Electron Microscope. This method is called eCHORD for electron CHanneling Orientation Determination. First, the proof of concept of eCHORD is presented on an aluminum alloy and the influence of acquisition parameters is detailed. Then, two problematics are addressed: large scale orientation mapping and low voltage orientation mapping (1kV).eCHORD procedure present great interest concerning low conductivity materials on which orientation mapping are difficult to obtain and open wide perspective for ceramics studies
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Dallet, Corentin. "Caractérisation locale de la propagation de l’onde d’activation cardiaque pour l’aide au diagnostic des tachycardies atriales et ventriculaires : application à l’imagerie électrocardiographique non-invasive." Thesis, Bordeaux, 2017. http://www.theses.fr/2017BORD0757/document.
Full textAbstract:
Les tachycardies ventriculaires (TV) et atriales (TA) sont les arythmies les plus fréquemment diagnostiquées en clinique. En vue d’ablater les tissus pathologiques, deux techniques de diagnostic sont utilisées : la cartographie électro-anatomique pour un diagnostic précis à l’aide d’électrogrammes (EGM) mesurés par cathéters intracardiaques et repérés sur la géométrie tridimensionnelle (3-D) de la cavité étudiée ; et l’imagerie électrocardiographique non-invasive (ECGi) pour une vision globale de l’arythmie, avec des EGM reconstruits mathématiquement à partir des électrocardiogrammes et des géométries cardio-thoraciques 3-D obtenues par CT-Scan. Les TV et TA sont alors diagnostiquées en étudiant les cartes d’activation qui sont des représentations des temps de passage locaux de l’onde d’activation sur la géométrie 3-D cardiaque. Cependant, les zones de ralentissement favorisant les TV et TA, et leurs motifs de propagation spécifiques n’y sont pas facilement identifiables. Ainsi, la caractérisation locale de la propagation de l’onde d’activation peut être utile pour améliorer le diagnostic. L’objet de cette thèse est le développement d’une méthode de caractérisation locale de la propagation de l’onde d’activation. Pour cela, un champ vectoriel de vitesse est estimé et analysé. La méthode a en premier lieu été validée sur des données simulées issues de modélisation, puis appliquée 1) à des données cliniques issues de l’ECGi pour la localisation des cicatrices d’infarctus et pour améliorer le diagnostic des TA; et 2) sur des données obtenues par cartographie électro-anatomique pour caractériser les zones pathogènesVentricular (VT) and atrial (AT) tachycardias are some of the most common clinical cardiac arrhythmias. For ablation of tachycardia substrates, two clinical diagnosis methods are used : electro-anatomical mapping for an accurate diagnosis using electrograms (EGMs) acquired with intracardiac catheters and localized on the three-dimensional (3-D) mesh of the studied cavities ; and non-invasive electrocardiographic imaging (ECGi) for a global view of the arrhythmia, with EGMs mathematically reconstructed from body surface electrocardiograms and the 3-D cardio-thoracic meshes obtained with CT-scan. VT and AT are diagnosed studying activation time maps ; that are 3-D representations of the transit time of the activation wavefront on the cardiac mesh. Nevertheless, slow conduction areas, a well-known pro-arrhythmic feature for tachycardias, and the tachycardias specific propagation patterns are not easily identifiable with these maps. Hence, local characterization of the activation wavefront propagation can be helpful for improving VT and AT diagnosis. The purpose of this thesis is to develop a method to locally characterize the activation wavefront propagation. For that, a conduction velocity vector field is estimated and analyzed. The method was first validated on a simulated database from computer models, then applied to 1) a clinical database obtained from ECGi to localize infarct tissues and improve AT diagnosis ; and 2) a clinical database acquired with electro-anatomical mapping systems to define pathological areas
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Guiral, Vega Juan Sebastian. "Textural and Mineralogical Characterization of Li-pegmatite Deposit: Using Microanalytical and Image Analysis to Link Micro and Macro Properties of Spodumene in Drill Cores. : Keliber Lithium Project, Finland." Thesis, Luleå tekniska universitet, Mineralteknik och metallurgi, 2018. http://urn.kb.se/resolve?urn=urn:nbn:se:ltu:diva-70422.
Full textAbstract:
Lithium represents one of the strategic elements for the rest of the 21st century due to its increasing demand in technological applications. Therefore, new efforts should be focused on the optimization of mineral characterization processes, which link the ore properties with its behaviour during downstream processes. These efforts should result in reducing operational risks and increasing resources utilization. The methodology presented in this study is based on the application of several classification techniques, aiming the mineral and textural characterization of two spodumene pegmatite deposits within the Keliber Lithium Project. Twelve textural classes have been proposed for the textual classification of the ore, which have been defined through the recognition of the main mineral features at macro- and micro-scale. The textural classification was performed through the application of drill core logging and scanning electron microscopy. Six classes are proposed to describe the characteristics of the spodumene ore. Six additional classes describe the main properties of the rocks surrounding the ore zone. Image analysis was implemented for the generation of mineral maps and the subsequent quantification of spodumene and Li2O within the analysed drill core images. The image segmentation process was executed in Fiji-ImageJ and is based on eight mineral classes and a set of seven feature extraction procedures. Thus, quantification of spodumene and Li2O is estimated by textural class. Hyperspectral images were used as a reference for assessing the estimations made through images analysis. A machine learning model in Weka allowed forecasting the behaviour of the twelve textural classes during spodumene flotation. This model is fed by metallurgical data from previous flotation tests and uses Random Forest classifier. The proposed methodology serves as an inexpensive but powerful approach for the complete textural characterization of the ore at Keliber Lithium Project. It provides information about: (1) mineral features at different scales, (2) spatial distribution of textures within the pegmatite body, (3) quantification of spodumene and Li2O within the drill cores and (4) processing response of each textural class. However, its application requires wide knowledge and expertise in the mineralogy of the studied deposits.Thesis Presentation.
Textural and Mineralogical Characterization of Li-pegmatite Deposit: Using Microanalytical and Image Analysis to Link Micro and Macro Properties of Spodumene in Drill Cores. Keliber Lithium Project, Finland.
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Ruffilli, Roberta. "Modes de fatigue des métallisations à base d'aluminium dans les composants MOSFET de puissance." Thesis, Toulouse 3, 2017. http://www.theses.fr/2017TOU30256/document.
Full textAbstract:
Cette thèse, effectuée en collaboration entre le CEMES-CNRS, le laboratoire Satie (ENS Cachan) et NXP Semiconductors est motivée par la compréhension des mécanismes de défaillance des dispositifs MOSFET pour les applications dans l'industrie automobile. Un facteur limitant de la fiabilité à long terme des modules de puissance basse tension est le vieillissement électrothermique et/ou thermo-mécanique des parties métalliques de la source: métallisation en aluminium (ou alliage) et fils de connexion. A cause de la différence de coefficient de dilatation thermique entre la métallisation les oxydes et le substrat semi-conducteur, la température atteinte pendant les cycles de fonctionnement (quelques centaines de degrés), induit une déformation plastique inévitable dans le métal, qui est le matériau le plus mou dans l'architecture complexe du MOSFET. Nous avons caractérisé la microstructure métallique avant et après les tests de vieillissement électrothermique accélérés, en utilisant des techniques spécifiques du domaine de la métallurgie physique: microscopie électronique et ionique, cartographie d'orientation de grains et de la composition chimique. Pour la première fois, la métallisation de la source a été caractérisée sous les fils de connexion, qui sont cent fois plus épais que la métallisation. Cet emplacement est critique pour la fiabilité du composant, car le processus de soudure par ultrasons induit une déformation plastique importante qui peut affaiblir la métallisation initiale avant le vieillissement. Ceci est peu étudié dans la littérature en raison de la difficulté à accéder à la métallisation sous les fils sans altérer leur interface, souvent endommagée et fragilisée dans les modules vieillis. Nous avons mis en place des méthodes de préparation d'échantillon, basées sur le polissage ionique, pour étudier cette interface, sans introduire d'artefacts de préparation. Le processus de soudure à froid induit une déformation plastique sévère et non uniforme dans la métallisation sous les fils sans parvenir à recréer un bon contact électrique: de petites cavités et des résidus d'oxyde natif, ont été systématiquement observés à l'interface Al / Al, dans tous les modules analysés, avant et après vieillissement. Le mécanisme principal de défaillance des modules est la génération et la propagation de fissures de fatigue dans l'aluminium, associée à une oxydation locale qui empêche la fermeture de ces fissures. Sous et en dehors des fils de connexion, ces fissures traversent la métallisation perpendiculairement à la surface jusqu'au substrat en silicium en suivant les joints de grains. Cette fissuration est due à la diffusion intergranulaire accélérée des atomes d'aluminium. Dans la zone de soudure, le phénomène de fissuration parallèle à l'interface est favorisé par les imperfections initiales (cavités, oxyde). Les expériences de tomographie ionique ont montré que ces fissures sont confinées à l'interface fil-métal et ne se propagent pas dans le fil malgré sa plus faible résistance mécanique (Al pur, structure à grains plus grands). La propagation de la fissure le long de l'interface Al/Al peut provoquer une diminution du contact entre le fil et la métallisation de la source et éventuellement son décollement. Les fissures dans le métal source peuvent expliquer l'augmentation locale de la résistance et de la température du module qui accélère le processus de vieillissement jusqu'à l'échec. Cette étude a établi de nouvelles techniques dédiées et des méthodes de quantification pour évaluer le vieillissement des parties métalliques des modules MOSFET. La caractérisation complète de l'interface soudée, intrinsèquement défectueuse et la dégradation de la métallisation pendant le vieillissement électrothermique ouvrent la voie à l'amélioration possible les technologies actuelles et au développement potentiel de nouveaux procédésThis thesis, a collaboration between CEMES-CNRS, Satie laboratory (ENS Cachan) and NXP Semiconductors is motivated by the comprehension of the failure mechanisms of low voltage power MOSFET devices produced for ap- plications in the automotive industry. A limiting factor for the long-term reliability of power modules is the electro- thermal and/or thermo-mechanical aging of the metallic parts of the source: Al metallization and bonding wires. At the temperature reached during the on-off operating cycles (few hundred degrees), the difference in the coefficient of thermal expansion between the metallization and the oxide and semicon- ductor parts induces an inevitable plastic deformation in the metal, which is the softest material in the complex MOSFET architecture. We have characterized the metal microstructure before and after accelerated electro-thermal aging tests, by using specific techniques from the field of the physical metallurgy: electron and ion microscopy, grain orientation and chem- ical composition mapping. For the first time the source metallization has been characterized both away and under the bonding connections, which are one hundred times thicker than the metallization layer. The latter is a critical loca- tion for the reliability assessment because the ultrasonic bonding process may weaken the initial metallization microstructure by adding an important plas- tic deformation prior to aging. This is, however, poorly stated in the literature because of the difficulty to access the metallization under the wires without damaging their bonding, which is known to be particularly weak in case of aged modules. In order to investigate the wire-metallization interface, we have set up origi- nal sample preparations, based on ion polishing, that allowed us to disclose the metallization under the bonding wires without introducing preparation artifacts in the microstructure. The bonding process induces a severe and non- uniform plastic deformation in the metallization under the wires without re- creating a good electrical contact: small cavities and native oxide residues, have been systematically observed at the Al/Al interface, in all the analyzed mod- ules, before and after aging. The main mechanism behind the device failure is the generation and propa- gation of fatigue cracks in the aluminum metallization, associated to a local Al oxidation that prevents these crack from closing. Away and under the wire bonds, they run perpendicularly from the surface down to the silicon substrate following the grain boundaries, due to an enhanced intergranular diffusion of aluminum atoms. In the bonding area, the phenomenon of parallel cracking is favored by the initial imperfections in the wire-metallization bonding. Ion to- mography experiments have shown that these cracks are confined to the wire- metal interface and do not propagate in the wire despite its lower strength (pure Al, larger grain structure). Crack propagation along the Al/Al interface can cause a contact reduction between the wire and the source metallization and eventually its failure. Such discontinuities in the metal can explain the lo- cal increase in the device resistance and temperature that accelerates the aging process until failure. This study settled new, dedicated techniques and quantification methods to as- sess the aging of the metal parts of MOSFET devices. The full characterization of the intrinsically defective interface generated by the bonding process and the metallization degradation during electro-thermal aging indicated paths to possible improvements of current technologies and potential developments of new processes