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Journal articles on the topic 'Fe(phen)2(NCS)2'

Author: Grafiati

Published: 4 June 2021

Last updated: 12 February 2022

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1

Garcia, Y., V. Ksenofontov, S. J. Campbell, J. S. Lord, Y. Boland, and P. G�tlich. "Spin transition in [Fe(phen)2(NCS)2] - �SR study." physica status solidi (a) 201, no. 15 (2004): 3309–13. http://dx.doi.org/10.1002/pssa.200405458.

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2

Shioyasu, N., K. Kagetsu, K. Mishima, et al. "Positive muons in spin-crossover complex [Fe(NCS)2(phen)2]." Hyperfine Interactions 84, no. 1 (1994): 477–81. http://dx.doi.org/10.1007/bf02060697.

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3

Ellingsworth, Edward C., Brittany Turner, and Greg Szulczewski. "Thermal conversion of [Fe(phen)3](SCN)2 thin films into the spin crossover complex Fe(phen)2(NCS)2." RSC Advances 3, no. 11 (2013): 3745. http://dx.doi.org/10.1039/c3ra22534h.

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4

Gruber, Manuel, Toshio Miyamachi, Vincent Davesne, et al. "Spin crossover in Fe(phen)2(NCS)2 complexes on metallic surfaces." Journal of Chemical Physics 146, no. 9 (2017): 092312. http://dx.doi.org/10.1063/1.4973511.

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5

Laisney, J., A. Tissot, G. Molnár, et al. "Nanocrystals of Fe(phen)2(NCS)2 and the size-dependent spin-crossover characteristics." Dalton Transactions 44, no. 39 (2015): 17302–11. http://dx.doi.org/10.1039/c5dt02840j.

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We describe the preparation of nano- and microcrystals of the Fe(phen)<sub>2</sub>(NCS)<sub>2</sub> spin-crossover prototypical compound based on the solvent-assisted technique applied to an ionic and soluble precursor and analyze the size-dependent characteristics of the thermal spin-crossover.

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6

Shi, S., G. Schmerber, J. Arabski, et al. "Study of molecular spin-crossover complex Fe(phen)2(NCS)2 thin films." Applied Physics Letters 95, no. 4 (2009): 043303. http://dx.doi.org/10.1063/1.3192355.

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7

Zhang, Yachao. "Surface effects on temperature-driven spin crossover in Fe(phen)2(NCS)2." Journal of Chemical Physics 153, no. 13 (2020): 134704. http://dx.doi.org/10.1063/5.0027641.

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8

Matar, Samir, Philippe Guionneau, and Guillaume Chastanet. "Multiscale Experimental and Theoretical Investigations of Spin Crossover FeII Complexes: Examples of [Fe(phen)2(NCS)2] and [Fe(PM-BiA)2(NCS)2]." International Journal of Molecular Sciences 16, no. 2 (2015): 4007–27. http://dx.doi.org/10.3390/ijms16024007.

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9

Ksenofontov, V., A. B. Gaspar, G. Levchenko, B. Fitzsimmons, and P. Gütlich. "Pressure Effect on Spin Crossover in [Fe(phen)2(NCS)2] and [CrI2(depe)2]." Journal of Physical Chemistry B 108, no. 23 (2004): 7723–27. http://dx.doi.org/10.1021/jp049512g.

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10

Kulshreshtha, S. K., and B. Maiti. "Spin state transition in Fe(1,10-phen)(2,2′-bipy)(NCS)2." Inorganica Chimica Acta 134, no. 1 (1987): 131–33. http://dx.doi.org/10.1016/s0020-1693(00)84467-9.

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11

von Ranke, P. J., B. P. Alho, E. P. Nobrega, et al. "The refrigerant capacity in spin-crossover materials: Application to [Fe(phen)2(NCS)2]." Journal of Magnetism and Magnetic Materials 489 (November 2019): 165421. http://dx.doi.org/10.1016/j.jmmm.2019.165421.

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12

Levchenko, G. G., G. V. Bukin, A. B. Gaspar, and J. A. Real. "The pressure-induced spin transition in the Fe(phen)2(NCS)2 model compound." Russian Journal of Physical Chemistry A 83, no. 6 (2009): 951–54. http://dx.doi.org/10.1134/s0036024409060144.

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13

Garcia, Y., V. Ksenofontov, S. J. Campbell, J. S. Lord, Y. Boland, and P. Gütlich. "Muon Spin Relaxation Study of the Spin Transition Compound [Fe(Phen)2(NCS)2]⊥." Journal of Physical Chemistry B 108, no. 46 (2004): 17838–44. http://dx.doi.org/10.1021/jp046695y.

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14

Granier, Thierry, Bernard Gallois, Jacques Gaultier, Jose Antonio Real, and Jacqueline Zarembowitch. "High-pressure single-crystal x-ray diffraction study of two spin-crossover iron(II) complexes: Fe(Phen)2(NCS)2 and Fe(Btz)2(NCS)2." Inorganic Chemistry 32, no. 23 (1993): 5305–12. http://dx.doi.org/10.1021/ic00075a058.

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15

Bučko, Tomáš, Jürgen Hafner, Sébastien Lebègue, and János G. Ángyán. "Spin crossover transition of Fe(phen)2(NCS)2: periodic dispersion-corrected density-functional study." Physical Chemistry Chemical Physics 14, no. 16 (2012): 5389. http://dx.doi.org/10.1039/c2cp40111h.

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16

Morsali, Ali. "Syntheses and Characterization of Two New Mixed-Ligand Bismuth(III) Complexes, Crystal Structure of [Bi(phen)2(NO3)(NCS)2(MeOH)]." Zeitschrift für Naturforschung B 60, no. 4 (2005): 389–92. http://dx.doi.org/10.1515/znb-2005-0405.

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Complexes [Bi(phen)2(NO3)(NCS)2(MeOH)] and [Bi(phen)2(NO3)2(NCS)] have been synthesized and characterized by their IR spectra and elemental analyses. The structure of the [Bi(phen)2(NO3)(NCS)2(MeOH)] complex has been confirmed by X-ray crystallography. The Bi atoms are unsymmetrically eight-coordinated, N6O2. The arrangement of the ligands does not show a gap in the coordination geometry around the Bi(III) ion, indicating that its lone pair of electrons is not active. The thiocyanate ligands are coordinated to the bismuth atom via the nitrogen atom. There is π-π stacking interactions between t

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17

Real, Jose Antonio, Bernard Gallois, Thierry Granier, Franz Suez-Panama, and Jacqueline Zarembowitch. "Comparative investigation of the spin-crossover compounds Fe(btz)2(NCS)2 and Fe(phen)2(NCS)2 (where btz = 2,2'-bi-4,5-dihydrothiazine and phen = 1,10-phenanthroline). Magnetic properties and thermal dilatation behavior and crystal structure of Fe(btz)2(NCS)2 at 293 and 130 K." Inorganic Chemistry 31, no. 24 (1992): 4972–79. http://dx.doi.org/10.1021/ic00050a013.

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18

Collison, David, C. David Garner, Catherine M. McGrath, et al. "Soft X-ray induced excited spin state trapping and soft X-ray photochemistry at the iron L2,3 edge in [Fe(phen)2(NCS)2] and [Fe(phen)2(NCSe)2] (phen = 1,10-phenanthroline) ‡." Journal of the Chemical Society, Dalton Transactions, no. 22 (1997): 4371–76. http://dx.doi.org/10.1039/a703728g.

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19

Mondal, Chaitali, and Swapan K. Mandal. "Electrically controllable molecular spin crossover switching in Fe(phen)2(NCS)2thin film." European Physical Journal Applied Physics 75, no. 3 (2016): 30201. http://dx.doi.org/10.1051/epjap/2016160258.

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20

Baranović, Goran, and Darko Babić. "Vibrational study of the Fe(phen)2(NCS)2 spin-crossover complex by density-functional calculations." Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 60, no. 5 (2004): 1013–25. http://dx.doi.org/10.1016/s1386-1425(03)00333-0.

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21

Enachescu, Cristian, Radu Tanasa, Alexandru Stancu, Antoine Tissot, Jérôme Laisney, and Marie-Laure Boillot. "Matrix-assisted relaxation in Fe(phen)2(NCS)2 spin-crossover microparticles, experimental and theoretical investigations." Applied Physics Letters 109, no. 3 (2016): 031908. http://dx.doi.org/10.1063/1.4959262.

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22

Matar, Samir F., and Jean-François Létard. "Ab initio Molecular and Solid-state Studies of the Spin Crossover System [Fe(phen)2(NCS)2]." Zeitschrift für Naturforschung B 65, no. 5 (2010): 565–70. http://dx.doi.org/10.1515/znb-2010-0505.

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Ab initio computations are reported for both the isolated molecule and the extended solid within the density functional theory to assess the electronic structure and derived physical properties of [Fe(phen)2(NCS)2] inwhich FeII is characterized by either one of two spin states, i. e. high spin (HS, t2g4eg2) and low spin (LS, t2g6eg0). For molecular HS and LS configurations, the characteristic IR and Raman spectra have been computed with vibrational frequencies magnitudes and their assignments in relative agreement with the experiment. For the extended solid, the equilibrium total energies repr

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23

Bertoni, Roman, Marco Cammarata, Maciej Lorenc, et al. "Ultrafast Light-Induced Spin-State Trapping Photophysics Investigated in Fe(phen)2(NCS)2 Spin-Crossover Crystal." Accounts of Chemical Research 48, no. 3 (2015): 774–81. http://dx.doi.org/10.1021/ar500444d.

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24

Saha, Saroj, and Swapan K. Mandal. "Spin transition properties of metal (Zn, Mn) diluted Fe(phen)2(NCS)2 spin-crossover thin films." European Physical Journal Applied Physics 91, no. 2 (2020): 20301. http://dx.doi.org/10.1051/epjap/2020200056.

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We report here the effect of metal (Zn and Mn) dilution on the spin transition of Fe(phen)2(NCS)2 thin film spin-crossover (SCO) complex. The SCO complexes are deposited on glass and indium-tin-oxide (ITO) coated glass by dip-coating technique. The growth of the films is clearly confirmed by the appearance of the sharp optical absorption band at 521–540 nm corresponding to 1A1g to 1T1g ligand field absorption of the SCO complex. Although the microstructure of the films remains unaffected by metal dilution, substitution of Fe(II) by either Zn(II) (diamagnetic) or Mn(II) (paramagnetic) results i

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25

Mondal, Chaitali, M. L. Nanda Goswami, and Swapan K. Mandal. "Frequency Dependent Charge Transport and Spin State Switching Characteristics of Fe(phen)2(NCS)2 in Polymer." Journal of Nanoscience and Nanotechnology 20, no. 5 (2020): 2803–12. http://dx.doi.org/10.1166/jnn.2020.17444.

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We report on the bistability in spin states of spin crossover (SCO) compound Fe(phen)2(NCS)2 in polymer (polypyrrole) by frequency (1–100 kHz) and temperature dependent (305–457 K) electrical conductivity measurements. The structure and growth of SCO compounds in conducting polymer are obtained by scanning electron microscopy, X-ray diffraction and optical absorption measurements. The thermal dependence of ac conductivity σ(ω) shows the clear formation of a hysteresis loop in its cooling and heating cycle due to the difference in conductivity in high spin and low spin state. The size, shape an

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26

Wang, C. C., H. S. Sheu, C. R. Lee, et al. "Electron-density distribution of Fe(Phen)2(NCS)2using the synchrotron radiation light source." Acta Crystallographica Section A Foundations of Crystallography 52, a1 (1996): C356. http://dx.doi.org/10.1107/s0108767396085273.

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27

Reiher, Markus. "Theoretical Study of the Fe(phen)2(NCS)2Spin-Crossover Complex with Reparametrized Density Functionals." Inorganic Chemistry 41, no. 25 (2002): 6928–35. http://dx.doi.org/10.1021/ic025891l.

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28

Beniwal, Sumit, Suchetana Sarkar, Felix Baier, Birgit Weber, Peter A. Dowben, and Axel Enders. "Site selective adsorption of the spin crossover complex Fe(phen)2(NCS) on Au(111)." Journal of Physics: Condensed Matter 32, no. 32 (2020): 324003. http://dx.doi.org/10.1088/1361-648x/ab808d.

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29

Tsuchiya, N., T. Isobe, M. Senna, N. Yoshioka, and H. Inoue. "Mechanochemical effects on the structures and chemical states of [Fe(Phen)3](NCS)2 · H2O." Solid State Communications 99, no. 8 (1996): 525–29. http://dx.doi.org/10.1016/0038-1098(96)00359-6.

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30

Sankar, G., John Meurig Thomas, Vijay Varma, G. U. Kulkarni, and C. N. R. Rao. "An investigation of the first-order spin-state transition in Fe(Phen)2(NCS)2 EXAFS and infrared spectroscopy." Chemical Physics Letters 251, no. 1-2 (1996): 79–83. http://dx.doi.org/10.1016/0009-2614(96)00071-1.

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31

Maddock, Alfred G. "The complex [Fe(phen)2(CN)2](phen = 1,10-phenanthroline) and its solutions." Journal of the Chemical Society, Dalton Transactions, no. 11 (1986): 2349. http://dx.doi.org/10.1039/dt9860002349.

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32

Paulsen, Hauke. "Periodic Density Functional Calculations in Order to Assess the Cooperativity of the Spin Transition in Fe(phen)2(NCS)2." Magnetochemistry 2, no. 1 (2016): 14. http://dx.doi.org/10.3390/magnetochemistry2010014.

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33

Bertoni, R., M. Lorenc, T. Graber, et al. "Cooperative elastic switching vs. laser heating in [Fe(phen)2(NCS)2] spin-crossover crystals excited by a laser pulse." CrystEngComm 18, no. 38 (2016): 7269–75. http://dx.doi.org/10.1039/c6ce00659k.

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34

Mondal, Chaitali, Suvra Pal, and Swapan K. Mandal. "Probing Spin-State Switching in Fe(phen)2(NCS)2 Thin Film Nanocrystals on Different Substrates by Electrical Conductivity Measurements." Journal of Nanoscience and Nanotechnology 18, no. 1 (2018): 347–52. http://dx.doi.org/10.1166/jnn.2018.14602.

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35

Gaultier, J., T. Granier, B. Gallois, J. A. Real, and J. Zarembowitch. "High pressure single crystal X-ray diffraction study of the spin crossover iron(II) complex Fe(Phen)2(NCS)2." High Pressure Research 7, no. 1-6 (1991): 336–38. http://dx.doi.org/10.1080/08957959108245585.

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36

Mahanta, Abhinandan, Koushik Barman, and Sk Jasimuddin. "Electrocatalytic oxidation of water by the immobilized [CuII(l-ala)(Phen)(H2O)]+ complex on a self-assembled NCS− modified gold electrode." RSC Advances 9, no. 41 (2019): 23939–43. http://dx.doi.org/10.1039/c9ra02547b.

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Copper(ii) complex [Cu<sup>II</sup>(l-ala)(Phen)(H<sub>2</sub>O)]<sup>+</sup> (l-ala = l-phenylalanine, phen = phenanthroline) was immobilized over a self-assembled NCS<sup>−</sup> modified gold electrode for the electrocatalytic oxidation of water.

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37

Tłaczała, T., and A. Bartecki. "Studies on the solvatochromism of Fe(CN)2(phen)2." Monatshefte für Chemie - Chemical Monthly 128, no. 3 (1997): 225–34. http://dx.doi.org/10.1007/bf00807888.

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38

Parker, O. J., J. L. Manson, and G. L. Breneman. "Isothiocyanatobis(1,10-phenanthroline)copper(II) perchlorate, [Cu(NCS)(phen)2]ClO4." Acta Crystallographica Section C Crystal Structure Communications 50, no. 8 (1994): 1201–3. http://dx.doi.org/10.1107/s0108270194003057.

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39

Bousseksou, Azzedine, Gábor Molnár, Jean-Pierre Tuchagues, Nieves Menéndez, Épiphane Codjovi, and François Varret. "Triggering the spin-crossover of Fe(phen)2(NCS)2 by a pressure pulse. Pressure and magnetic field induce ‘mirror effects’." Comptes Rendus Chimie 6, no. 3 (2003): 329–35. http://dx.doi.org/10.1016/s1631-0748(03)00042-0.

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40

Nasser, J. A., S. Topçu, L. Chassagne, A. Bousseksou, T. Guillon, and Y. Alayli. "3d Electrons-molecular vibrations coupling in spin conversion compounds molecules: A quantitative study for the [Fe(phen)2(NCS)2] molecules." Chemical Physics Letters 446, no. 4-6 (2007): 385–90. http://dx.doi.org/10.1016/j.cplett.2007.07.109.

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41

Naik, Anil D., Marinela M. Dîrtu, and Yann Garcia. "Effect of texture alteration by thin film fabrication on the spin crossover of [Fe(3-Br-phen)2(NCS)2]·0.5CH3OH." Journal of Physics: Conference Series 217 (March 1, 2010): 012032. http://dx.doi.org/10.1088/1742-6596/217/1/012032.

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42

Pálfi, Villő K., Thomas Guillon, Hauke Paulsen, Gábor Molnár, and Azzedine Bousseksou. "Isotope effects on the vibrational spectra of the Fe(Phen)2(NCS)2 spin-crossover complex studied by density functional calculations." Comptes Rendus Chimie 8, no. 8 (2005): 1317–25. http://dx.doi.org/10.1016/j.crci.2004.11.032.

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43

Hauser, Andreas. "Excited-state lifetimes of [Fe (bipy)3]2+ and [Fe(phen)3]2+." Chemical Physics Letters 173, no. 5-6 (1990): 507–12. http://dx.doi.org/10.1016/0009-2614(90)87244-l.

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44

Baldé, Chérif, Cédric Desplanches, Alain Wattiaux, Philippe Guionneau, Philipp Gütlich, and Jean-François Létard. "Effect of metal dilution on the light-induced spin transition in [FexZn1−x(phen)2(NCS)2] (phen = 1,10-phenanthroline)." Dalton Transactions, no. 20 (2008): 2702. http://dx.doi.org/10.1039/b800248g.

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45

Müller, Andressa V., Luiz D. Ramos, Karina P. M. Frin, Kleber T. de Oliveira, and André S. Polo. "A high efficiency ruthenium(ii) tris-heteroleptic dye containing 4,7-dicarbazole-1,10-phenanthroline for nanocrystalline solar cells." RSC Advances 6, no. 52 (2016): 46487–94. http://dx.doi.org/10.1039/c6ra08666g.

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cis-[Ru(cbz<sub>2</sub>-phen)(dcbH<sub>2</sub>)(NCS)<sub>2</sub>] sensitized cells exhibited higher performance than those by N3. The efficiency is discussed in terms of its thermodynamic and structure.

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46

Datta, Amitabha, Sébastien Pillet, Nien-Tsu Chuang, Hon Man Lee, and Jui-Hsien Huang. "Synthesis and Structural Aspects of Two Trinuclear Cyano-bridged Heterometallic Complexes with Monodentate Coordination of Perchlorate and Acetate Anions." Zeitschrift für Naturforschung B 65, no. 9 (2010): 1106–12. http://dx.doi.org/10.1515/znb-2010-0909.

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Two new cyano-bridged trinuclear heterometallic complexes [Ca2(phen)4(ClO4)(H2O)3- Fe(CN)6]・H2O (1) and [Ca2 (phen)4(CH3COO)(H2O)3Fe(CN)6]・2H2O (2) (where phen = 1,10- phenanthroline) have been synthesized and characterized by single-crystal X-ray diffraction techniques, IR spectroscopy and thermogravimetric analysis. The structure of complex 1 features a central [Fe(CN)6]3− unit that links a monocation [Ca(phen)2(H2O)(ClO4)]+ and a dication [Ca(phen)2- (H2O)2]2+ via two trans cyanide bridges. Similarly, complex 2 also features a central [Fe(CN)6]3− unit that links a monocation [Ca(phen)2(H2O)

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47

Engelhardt, LM, JM Patrick, and AH White. "Lewis-Base Adducts of Lead(II) Compounds. III. Synthesis and Structural Characterization of Mononuclear (Nitrato-O,O′)bis(1,10-phenanthroline)-(thiocyanato-N)lead(II)." Australian Journal of Chemistry 42, no. 2 (1989): 335. http://dx.doi.org/10.1071/ch9890335.

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The isolation and single-crystal X-ray structure determination of the title compound, [(phen)2Pb(NCS)(O2NO)] is described; crystals are triclinic, P1, a 15.554(7), b 9-670(4), c 8.429(3) α 72.53(3), β 81.90(3), γ 72.88(3)� Z = 2, yielding R 0.052 for 3405 independent 'observed' reflections. The lead atom is seven-coordinate [Pb-N 2.49(1)-2.60(1) (phen), 2.89(1) (NCS); Pb-O 2.75(1), 2.89(1) �] with a large vacancy in the coordination sphere, possibly indicative of a stereochemically active lone pair.

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48

Tokinobu, Satoshi, Haruka Dote, and Satoru Nakashima. "Threefold Spiral Structure Constructed by 1D Chains of [[M(NCS)2(bpa)2]·biphenyl]n (M = Fe, Co; bpa = 1,2-bis(4-pyridyl)ethane)." Crystals 9, no. 2 (2019): 97. http://dx.doi.org/10.3390/cryst9020097.

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Assembled complexes [[M(NCS)2(bpa)2]·biphenyl]n (M = Fe, Co; bpa = 1,2-bis(4-pyridyl)ethane) have been synthesized because [Fe(NCBH3)2(bpa)2·biphenyl]n has a novel threefold spiral structure and shows stepwise spin-crossover phenomenon. We attempted to obtain spiral structures for [[Fe(NCS)2(bpa)2]·biphenyl]n and [[Co(NCS)2(bpa)2]·biphenyl]n using a one-step diffusion method, while the reported spiral structure of [[Fe(NCBH3)2(bpa)2]·biphenyl]n was obtained by diffusion method after synthesizing Fe(II)-pyridine complex. X-ray structural analysis revealed that [[Fe(NCS)2(bpa)2]·biphenyl]n and [

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49

Mahjoub, Ali Reza, Ali Morsali, and Ramin Ebrahim Nejad. "Syntheses and Characterization of New Mixed-Ligand Mercury(II) Complexes, Hg(bpy)n(SCN)X (X = CH3COO–, NO3– and ClO4–), Crystal Structure of [Hg(bpy)2(SCN)]NO3." Zeitschrift für Naturforschung B 59, no. 10 (2004): 1109–13. http://dx.doi.org/10.1515/znb-2004-1005.

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AbstractThe 1:2 and 1:1 mixed-ligand mercury(II) complexes with 2,2’-bipyridine (bpy) containing two different anions, Hg(bpy)n(SCN)X (X= CH3COO−, NO3− and ClO4−), have been synthesized and characterized by elemental analysis, and IR, 1H and 13C NMR spectroscopy. The structure of [Hg(bpy)2(SCN)]NO3 was confirmed by X-ray crystallography. The complex is monomeric and the Hg atom has an unsymmetrical five-coordinate geometry, with four nitrogen atoms of two bpy ligands and one sulfur atom of the thiocyanate ligand as donor atoms. This is in contrast to lead(II) complexes, [Pb(phen)2(NO3)(NCS)],

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50

Potočňák, Ivan, Lucia Váhovská та Peter Herich. "Low-dimensional compounds containing cyanide groups. XXV. Synthesis, spectroscopic properties and crystal structures of two ionic iron(II) complexes with tricyanomethanide: tris(1,10-phenanthroline-κ2 N,N′)iron(II) bis(tricyanomethanide) and tris(2,2′-bipyridine-κ2 N,N′)iron(II) bis(tricyanomethanide) sesquihydrate". Acta Crystallographica Section C Structural Chemistry 70, № 5 (2014): 432–36. http://dx.doi.org/10.1107/s2053229614006512.

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Abstract:

Two new diamagnetic coordination compounds, [Fe(phen)3][C(CN)3]2, (I), and [Fe(bpy)3][C(CN)3]2·1.5H2O, (II), have been synthesized and characterized by single-crystal X-ray diffraction analysis, and IR and UV–Vis spectroscopy (phen is 1,10-phenanthroline, C12H8N2, and bpy is 2,2′-bipyridine, C10H8N2). Both compounds are ionic with distorted octahedral [Fe(phen)3]2+ or [Fe(bpy)3]2+ complex cations, with average Fe—N distances of 1.977 (2) and 1.971 (3) Å, respectively, and two uncoordinated planar tricyanomethanide, or [C(CN)3]−, counter-anions balancing the positive charges of the cations. Sol

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