Dissertations / Theses: 'GPS degradation'

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Jackson, James Scott. "Enabling Autonomous Operation of Micro Aerial Vehicles Through GPS to GPS-Denied Transitions." BYU ScholarsArchive, 2019. https://scholarsarchive.byu.edu/etd/8709.

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Micro aerial vehicles and other autonomous systems have the potential to truly transform life as we know it, however much of the potential of autonomous systems remains unrealized because reliable navigation is still an unsolved problem with significant challenges. This dissertation presents solutions to many aspects of autonomous navigation. First, it presents ROSflight, a software and hardware architure that allows for rapid prototyping and experimentation of autonomy algorithms on MAVs with lightweight, efficient flight control. Next, this dissertation presents improvments to the state-of-the-art in optimal control of quadrotors by utilizing the error-state formulation frequently utilized in state estimation. It is shown that performing optimal control directly over the error-state results in a vastly more computationally efficient system than competing methods while also dealing with the non-vector rotation components of the state in a principled way. In addition, real-time robust flight planning is considered with a method to navigate cluttered, potentially unknown scenarios with real-time obstacle avoidance. Robust state estimation is a critical component to reliable operation, and this dissertation focuses on improving the robustness of visual-inertial state estimation in a filtering framework by extending the state-of-the-art to include better modeling and sensor fusion. Further, this dissertation takes concepts from the visual-inertial estimation community and applies it to tightly-coupled GNSS, visual-inertial state estimation. This method is shown to demonstrate significantly more reliable state estimation than visual-inertial or GNSS-inertial state estimation alone in a hardware experiment through a GNSS-GNSS denied transition flying under a building and back out into open sky. Finally, this dissertation explores a novel method to combine measurements from multiple agents into a coherent map. Traditional approaches to this problem attempt to solve for the position of multiple agents at specific times in their trajectories. This dissertation instead attempts to solve this problem in a relative context, resulting in a much more robust approach that is able to handle much greater intial error than traditional approaches.

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Wheeler, David Orton. "Relative Navigation of Micro Air Vehicles in GPS-Degraded Environments." BYU ScholarsArchive, 2017. https://scholarsarchive.byu.edu/etd/6609.

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Most micro air vehicles rely heavily on reliable GPS measurements for proper estimation and control, and therefore struggle in GPS-degraded environments. When GPS is not available, the global position and heading of the vehicle is unobservable. This dissertation establishes the theoretical and practical advantages of a relative navigation framework for MAV navigation in GPS-degraded environments. This dissertation explores how the consistency, accuracy, and stability of current navigation approaches degrade during prolonged GPS dropout and in the presence of heading uncertainty. Relative navigation (RN) is presented as an alternative approach that maintains observability by working with respect to a local coordinate frame. RN is compared with several current estimation approaches in a simulation environment and in hardware experiments. While still subject to global drift, RN is shown to produce consistent state estimates and stable control. Estimating relative states requires unique modifications to current estimation approaches. This dissertation further provides a tutorial exposition of the relative multiplicative extended Kalman filter, presenting how to properly ensure observable state estimation while maintaining consistency. The filter is derived using both inertial and body-fixed state definitions and dynamics. Finally, this dissertation presents a series of prolonged flight tests, demonstrating the effectiveness of the relative navigation approach for autonomous GPS-degraded MAV navigation in varied, unknown environments. The system is shown to utilize a variety of vision sensors, work indoors and outdoors, run in real-time with onboard processing, and not require special tuning for particular sensors or environments. Despite leveraging off-the-shelf sensors and algorithms, the flight tests demonstrate stable front-end performance with low drift. The flight tests also demonstrate the onboard generation of a globally consistent, metric, and localized map by identifying and incorporating loop-closure constraints and intermittent GPS measurements. With this map, mission objectives are shown to be autonomously completed.

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Ellingson, Gary James. "Cooperative Navigation of Fixed-Wing Micro Air Vehicles in GPS-Denied Environments." BYU ScholarsArchive, 2019. https://scholarsarchive.byu.edu/etd/8706.

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Micro air vehicles have recently gained popularity due to their potential as autonomous systems. Their future impact, however, will depend in part on how well they can navigate in GPS-denied and GPS-degraded environments. In response to this need, this dissertation investigates a potential solution for GPS-denied operations called relative navigation. The method utilizes keyframe-to-keyframe odometry estimates and their covariances in a global back end that represents the global state as a pose graph. The back end is able to effectively represent nonlinear uncertainties and incorporate opportunistic global constraints. The GPS-denied research community has, for the most part, neglected to consider fixed-wing aircraft. This dissertation enables fixed-wing aircraft to utilize relative navigation by accounting for their sensing requirements. The development of an odometry-like, front-end, EKF-based estimator that utilizes only a monocular camera and an inertial measurement unit is presented. The filter uses the measurement model of the multi-state-constraint Kalman filter and regularly performs relative resets in coordination with keyframe declarations. In addition to the front-end development, a method is provided to account for front-end velocity bias in the back-end optimization. Finally a method is presented for enabling multiple vehicles to improve navigational accuracy by cooperatively sharing information. Modifications to the relative navigation architecture are presented that enable decentralized, cooperative operations amidst temporary communication dropouts. The proposed framework also includes the ability to incorporate inter-vehicle measurements and utilizes a new concept called the coordinated reset, which is necessary for optimizing the cooperative odometry and improving localization. Each contribution is demonstrated through simulation and/or hardware flight testing. Simulation and Monte-Carlo testing is used to show the expected quality of the results. Hardware flight-test results show the front-end estimator performance, several back-end optimization examples, and cooperative GPS-denied operations.

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Harrington, Tomas Seosamh. "Gas diffusion electrodes for environmental applications." Thesis, University of Southampton, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.297872.

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Nalin, Laura. "Degradation of environmental protection coatings for gas turbine materials." Thesis, Cranfield University, 2008. http://dspace.lib.cranfield.ac.uk/handle/1826/4522.

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Nowadays, problems of component materials reliability in gas and oil-fired gas turbines focus on assessing the potential behaviour of commonly employed coatings, in order to avoid expensive and unpredictable failure in service and producing new materials whose performance meets life time and manufacturing/ repairing requirements. This MPhil project has investigated the oxidative and corrosive degradation mechanisms for some of the alloy/coatings systems (CMSX-4, CMSX-4/ RT22, CMSX-4/ CN91 and CMSX-4/ “LCO22”), which are currently used for turbines blades and vanes, in order to achieve a better knowledge of materials behaviour and to improve models for the prediction of turbine components’ lives. To achieve this target the study has made use of realistic simulations of turbine exposure conditions in combined with pre- and post-exposure metrology of bar shape materials samples, while optical microscopy has been applied to describe the microstructural evolution during the exposure and the products of the degradation for the hot corrosion. For high temperature oxidation, over extended periods of time (up to 10,000 hours), the research has allowed to describe the morphological changes in respect of the exposure time and temperature and to determine the oxidation kinetics experienced by the alloy and coatings. A model has been presented for predicting θ- α-Al2O3 growth. Moreover, using NASA COSP spalling model, with rate constants values coming from this study, a comparison between experimental mass change data and prediction has been shown. The hot corrosion study has provided new quantitative metal loss data and observations that extend/validate an existing model for materials life prediction, based on defining the severity of the corrosion conditions through measures of gas composition and contaminant deposition flux.

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King, Sarah M. "Enhancement in Degradation of Environmental Pollutants: Fenton Degradation of 2,4,6-Trinitrotoluene and Photodegradation of Deepwater Horizon Crude Oil." ScholarWorks@UNO, 2012. http://scholarworks.uno.edu/td/1451.

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Pollution poses serious threats to both the environmental and the organisms that depend on their environment for survival. Due to the toxicity of most contaminants, there is a dire need for remediation of polluted sites. Remediation studies were conducted on two high priority pollutants: 2,4,6-trinitrotoluene (TNT) and crude oil. TNT was the most common explosive used in the 20th century. Continuous contamination has resulted in an urgent need for remediation. Fenton reagent provides an advanced oxidation process that is capable of remediating recalcitrant explosives, such as TNT. One drawback of Fenton chemistry is that the reaction requires acidic pH to prevent precipitation of iron. Our studies have investigated Fenton degradation of TNT at near neutral pH with several modifiers present: β-cyclodextrin, carboxymethyl-β-cyclodextrin, alcohols, and polyethylene glycol (PEG, MW 200, 400, or 600 g/mol). Fenton degradation was also carried out on other nitroaromatics to better understand the reaction mechanism with PEG 400. Further mechanistic studies investigated the production of nitrate and ammonium with and without PEG 400. The Deepwater Horizon oil spill devastated the Gulf of Mexico and the surrounding wetlands. There are several mechanisms for degradation of oil released into aquatic environments. Bioremediation is one of the most important remediation methods; however degradation becomes stagnant in low nutrient waters. Furthermore, larger molecular weight alkanes and polycyclic aromatic hydrocarbons (PAHs) are not readily available for biodegradation. Transformation of these molecules often requires initial photodegradation. We have investigated the photochemical transformation of oil films with and without photocatalysts present. To better understand the photochemical transformations that occur to the Deepwater Horizon oil, we have conducted additional studies with dispersants present.

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Heath, David John. "Characterisation of waxy gas-condensates by high temperature capillary gas chromatography and oxidative degradation." Thesis, University of Plymouth, 1995. http://hdl.handle.net/10026.1/460.

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High molecular weight (HMW) hydrocarbons (defined herein as C35+ compounds) are difficult to characterise by conventional analytical methods. Very few studies have reported precise and reproducible quantification of such compounds in fossil fuels. Nonetheless, such components have important effects on the physical and biological fate of fossil fuels in the geosphere. For example, the phase behaviour of waxy gas condensates is significantly affected by the varying proportions of HMW compounds. Similarly HMW compounds are amongst the most resistant petroleum components to biodegradation. The current study reports the development of reproducible quantitative high temperature capillary gas chromatography (HTCGC) methods for studying both these aspects of the chemistry of HMW hydrocarbons. In addition those hydrocarbons which remain unresolved when analysed by gas chromatography (so called unresolved complex mixtures UCMs) are also studied. UCMs may account for a large portion of the hydrocarbons in many fossil fuels yet very little is known about their composition. Knowledge of these compounds may be important in enhancing the prediction of phase behaviour. Oxidative degradation and GC-MS is used to elucidate the types of structures present within the UCM. The concentrations of C3S4h. ydrocarbons in two unusually waxy gas condensates from high temperature wells in the North Sea were determined by HTCGC. The whole C, 5+ fraction comprised about 20% of the total hydrocarbons and consisted of compounds with carbon numbers extending up to and beyond Coo. By paying particular attention to sample dissolution and injection, good reproducibility and precision were obtained. For example, for authentic n-C, to n-C60 alkanes a relative standard deviation of under 5% for manual injection, linear response factors (1.01 Cm to 0.99 C6), and a linear calibration for 5 ng to 25 ng on-column were found. Limits of detection are reported for the first time for HMW n-alkanes. The limits were found to be as low as 0.8 ng for Cto to 1.87 ng for C60. Tristearin is proposed as a suitable HTCGC internal standard for quantification since the FID response factor (1.1) was close to that of the HMW n-alkanes and response was linear. Importantly, when co-injected with the two waxy North Sea condensates, tristearin was adequately separated from the closest eluting alkanes, n-C59 and n-C60 under normal operating conditions. Qualitative characterisation of the HMW compounds in the waxy gas condensates and in synthetic wax blends (polywax 1000) using HTCGC-EI MS and HTCGC-CI MS produced molecular ions or pseudo molecular ions for n-alkanes up to n- C6o. The spectra of some HMW compounds contained fragment ions characteristic of branched compounds but detailed characterisation was very limited. This study has also shown, for the first time, the significance of the unresolved complex mixture in gas condensatesU. CM hydrocarbonsa ccountedf or over 20% of the total hydrocarbons in a waxy North sea condensateT. he condensatew as first distilled and the distillate UCMs isolated. Thesew ere found to be between 64 to 97 % unresolved after molecular sieving (5A) and urea adduction. The UCMs were oxidised using CrO3/AcOHw hich produced5 -12% C02, and 55-83% dichloromethane-solublep roducts. Thus 65-94% of the original UCMs were accounted for as oxidation products. The remainder were thought to be water soluble acids which could not be determined in the presence of the AcOH reagent. Of the recovered oxidised products, 27- 81 % were resolved and these comprised mainly n-monocarboxylic acids (19-48 %). The average chain length was found to be C12 indicating the average length of alkyl groups. Branched acids, ketones, ketoacids, ndicarboxylic acids, branched dicarboxylic acids, lactones, isoprenoid acids, alkylcyclohexane carboxylic acids and toluic acids accounted for the majority of the remaining resolved products. The distillate UCMs all showed variations in amountso f productsb ut not in composition. Retro-structurala nalysis suggestedth at the UCM in the gasc ondensatew as mainly aliphatic and branched.T he numbero f isomerso f simple brancheda lkaneso ver the UCM molecular weight range (determined by cryoscopy) was calculated to be over 15000. Overall, oxidation provided structural information for about half of the UCM. HTCGC was also used to measure the biodegradability of HMW alkanes in a waxy Indonesian oil. Traditional alkane isolation techniques (TLC and CC) discriminated against HMW compounds above C40 whereas adsorption onto alumina in a warm cyclohexane slurry provided an aliphatic fraction still rich in HMW compounds and suitable as a biodegradation substrate. A waxy Indonesian oil was subjected to 136 day biodegradation by Pseudomonas fluorescens. Extraction efficiencies of over 90 % (RSD <5 %) were obtained for n-alkanes up to C6o using continuous liquid-liquid extraction. Over 80 % of the oil aliphatic fraction was degraded within 14 days. After 136 days only 14% of the original aliphatic fraction remained, yet surprisingly no decreases in the concentrations of compounds above C45 were observed. However, the use of a rapid screening biodegradation method proved conclusively that Pseudomonasfluorescens was capable of utilising n-alkanes up to C60 once the bacteria had acclimated to the HMW alkanes. This is the first report of bacterial utilisation of an n-alkane as large as C.

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Lawrence, Bryce T. "Recreation related degradation in Kansas state parks : applying GIS models." Thesis, Manhattan, Kan. : Kansas State University, 2005. http://hdl.handle.net/2097/74.

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Morgenstern, Anne. "Thermokarst and thermal erosion : degradation of Siberian ice-rich permafrost." Phd thesis, Universität Potsdam, 2012. http://opus.kobv.de/ubp/volltexte/2012/6207/.

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Current climate warming is affecting arctic regions at a faster rate than the rest of the world. This has profound effects on permafrost that underlies most of the arctic land area. Permafrost thawing can lead to the liberation of considerable amounts of greenhouse gases as well as to significant changes in the geomorphology, hydrology, and ecology of the corresponding landscapes, which may in turn act as a positive feedback to the climate system. Vast areas of the east Siberian lowlands, which are underlain by permafrost of the Yedoma-type Ice Complex, are particularly sensitive to climate warming because of the high ice content of these permafrost deposits. Thermokarst and thermal erosion are two major types of permafrost degradation in periglacial landscapes. The associated landforms are prominent indicators of climate-induced environmental variations on the regional scale. Thermokarst lakes and basins (alasses) as well as thermo-erosional valleys are widely distributed in the coastal lowlands adjacent to the Laptev Sea. This thesis investigates the spatial distribution and morphometric properties of these degradational features to reconstruct their evolutionary conditions during the Holocene and to deduce information on the potential impact of future permafrost degradation under the projected climate warming. The methodological approach is a combination of remote sensing, geoinformation, and field investigations, which integrates analyses on local to regional spatial scales. Thermokarst and thermal erosion have affected the study region to a great extent. In the Ice Complex area of the Lena River Delta, thermokarst basins cover a much larger area than do present thermokarst lakes on Yedoma uplands (20.0 and 2.2 %, respectively), which indicates that the conditions for large-area thermokarst development were more suitable in the past. This is supported by the reconstruction of the development of an individual alas in the Lena River Delta, which reveals a prolonged phase of high thermokarst activity since the Pleistocene/Holocene transition that created a large and deep basin. After the drainage of the primary thermokarst lake during the mid-Holocene, permafrost aggradation and degradation have occurred in parallel and in shorter alternating stages within the alas, resulting in a complex thermokarst landscape. Though more dynamic than during the first phase, late Holocene thermokarst activity in the alas was not capable of degrading large portions of Pleistocene Ice Complex deposits and substantially altering the Yedoma relief. Further thermokarst development in existing alasses is restricted to thin layers of Holocene ice-rich alas sediments, because the Ice Complex deposits underneath the large primary thermokarst lakes have thawed completely and the underlying deposits are ice-poor fluvial sands. Thermokarst processes on undisturbed Yedoma uplands have the highest impact on the alteration of Ice Complex deposits, but will be limited to smaller areal extents in the future because of the reduced availability of large undisturbed upland surfaces with poor drainage. On Kurungnakh Island in the central Lena River Delta, the area of Yedoma uplands available for future thermokarst development amounts to only 33.7 %. The increasing proximity of newly developing thermokarst lakes on Yedoma uplands to existing degradational features and other topographic lows decreases the possibility for thermokarst lakes to reach large sizes before drainage occurs. Drainage of thermokarst lakes due to thermal erosion is common in the study region, but thermo-erosional valleys also provide water to thermokarst lakes and alasses. Besides these direct hydrological interactions between thermokarst and thermal erosion on the local scale, an interdependence between both processes exists on the regional scale. A regional analysis of extensive networks of thermo-erosional valleys in three lowland regions of the Laptev Sea with a total study area of 5,800 km² found that these features are more common in areas with higher slopes and relief gradients, whereas thermokarst development is more pronounced in flat lowlands with lower relief gradients. The combined results of this thesis highlight the need for comprehensive analyses of both, thermokarst and thermal erosion, in order to assess past and future impacts and feedbacks of the degradation of ice-rich permafrost on hydrology and climate of a certain region.
Die gegenwärtige Klimaerwärmung wirkt sich auf arktische Regionen stärker aus als auf andere Gebiete der Erde. Das hat weitreichende Konsequenzen für Permafrost, der weite Teile der terrestrischen Arktis unterlagert. Das Tauen von Permafrost kann zur Freisetzung erheblicher Mengen an Treibhausgasen sowie zu gravierenden Änderungen in der Geomorphologie, Hydrologie und Ökologie betroffener Landschaften führen, was wiederum als positive Rückkopplung auf das Klimasystem wirken kann. Ausgedehnte Gebiete der ostsibirischen Tiefländer, die mit Permafrost des Yedoma Eiskomplex unterlagert sind, gelten aufgrund des hohen Eisgehalts dieser Permafrostablagerungen als besonders empfindlich gegenüber Klimaerwärmungen. Thermokarst und Thermoerosion sind zwei Hauptformen der Permafrostdegradation in periglazialen Landschaften. Die zugehörigen Landschaftsformen sind auf der regionalen Skala bedeutende Indikatoren klimainduzierter Umweltvariationen. Thermokarstseen und senken (Alasse) sowie Thermoerosionstäler sind in den Küstentiefländern der Laptewsee weit verbreitet. Die vorliegende Dissertation untersucht die räumliche Verbreitung und die morphometrischen Eigenschaften dieser Degradationsformen mit dem Ziel, ihre Entwicklungsbedingungen während des Holozäns zu rekonstruieren und Hinweise auf potenzielle Auswirkungen zukünftiger Permafrostdegradation im Zuge der erwarteten Klimaerwärmung abzuleiten. Der methodische Ansatz ist eine Kombination aus Fernerkundungs-, Geoinformations- und Geländeuntersuchungen, die Analysen auf lokalen bis regionalen räumlichen Skalen integriert. Thermokarst und Thermoerosion haben die Untersuchungsregion tiefgreifend geprägt. Im Eiskomplexgebiet des Lena-Deltas nehmen Thermokarstsenken eine weitaus größere Fläche ein als Thermokarstseen auf Yedoma-Hochflächen (20,0 bzw. 2,2 %), was darauf hin deutet, dass die Bedingungen für die Entwicklung von großflächigem Thermokarst in der Vergangenheit wesentlich günstiger waren als heute. Die Rekonstruktion der Entwicklung eines einzelnen Alas im Lena-Delta belegt eine andauernde Phase hoher Thermokarstaktivität seit dem Übergang vom Pleistozän zum Holozän, die zur Entstehung einer großen und tiefen Senke führte. Nach der Drainage des primären Thermokarstsees im mittleren Holozän erfolgten Permafrostaggradation und degradation parallel und in kürzeren abwechselnden Etappen innerhalb des Alas und führten zu einer komplexen Thermokarstlandschaft. Trotzdem die spätholozäne Thermokarstentwicklung im Alas dynamischer ablief als die erste Entwicklungsphase, resultierte sie nicht in der Degradation großer Teile pleistozäner Eiskomplexablagerungen und einer wesentlichen Veränderung des Yedoma-Reliefs. Weitere Thermokarstentwicklung in bestehenden Alassen ist begrenzt auf geringmächtige Lagen holozäner eisreicher Alas-Sedimente, da die Eiskomplexablagerungen unter den großen primären Thermokarstseen vollständig getaut waren und die unterlagernden Sedimente aus eisarmen, fluvialen Sanden bestehen. Thermokarstprozesse auf ungestörten Yedoma-Hochflächen wirken am stärksten verändernd auf Eiskomplexablagerungen, werden aber in Zukunft auf geringere Ausmaße begrenzt sein, da die Verfügbarkeit großer ungestörter, schwach drainierter Yedoma-Hochflächen abnimmt. Auf der Insel Kurungnakh im zentralen Lena-Delta beträgt der für zukünftige Thermokarstentwicklung verfügbare Anteil an Yedoma-Hochflächen nur 33,7 %. Die zunehmende Nähe von sich entwickelnden Thermokarstseen auf Yedoma-Hochflächen zu bestehenden Degradationsstrukturen und anderen negativen Reliefformen verringert die Möglichkeit der Thermokarstseen, große Ausmaße zu erreichen bevor sie drainieren. Die Drainage von Thermokarstseen durch Thermoerosion ist in der Untersuchungsregion weit verbreitet, aber Thermoerosionstäler versorgen Thermokarstseen und –senken auch mit Wasser. Neben diesen direkten hydrologischen Wechselwirkungen zwischen Thermokarst und Thermoerosion auf der lokalen Ebene existiert auch eine Interdependenz zwischen beiden Prozessen auf der regionalen Ebene. Eine regionale Analyse weitreichender Netze von Thermoerosionstälern in drei Tieflandgebieten der Laptewsee mit einer Fläche von insgesamt 5800 km² zeigte, dass diese Formen häufiger in Gebieten mit höheren Geländeneigungen und Reliefgradienten auftreten, während Thermokarstentwicklung stärker in flachen Tiefländern mit geringeren Reliefgradienten ausgeprägt ist. Die kombinierten Ergebnisse dieser Dissertation zeigen die Notwendigkeit von umfassenden Analysen beider Prozesse und Landschaftsformen, Thermokarst und Thermoerosion, im Hinblick auf die Abschätzung vergangener und zukünftiger Auswirkungen der Degradation eisreichen Permafrosts auf Hydrologie und Klima der betrachteten Region und deren Rückkopplungen.

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Al-Hussein, Salem. "GIS modelling of land degradation in northern Jordan using satellite imagery." Thesis, University of Leicester, 2000. http://hdl.handle.net/2381/30386.

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Northern Jordan has undergone tremendous land cover change during the last three decades. This study tried to answer the following question: How have population growth and socio-economic influences affected soil quality in northern Jordan? The underlying factors that have led to the changes in land use and land cover are poorly documented, but efforts in this area started to be effective with the creation of the Badia Research and Development Programme. However, there has been little effort to spatially correlate the land cover changes with soil quality. An empirical model based on high resolution spatial and temporal remotely sensed data offers the ability to assess the degradation impacts of changes in land cover in a spatial context. In an attempt to assess the impacts of changing land cover on soil, a GIS-based erosion model has been developed to predict annual soil loss by water in northern Jordan. This model uses the Revised Universal Soil Loss Equation (RUSLE). Spatially distributed static (topographic and soil) parameters for this model are extracted from a regional GIS developed specifically for the Badia Programme area. The dynamic (vegetation cover) parameter is estimated from the land cover maps, derived by digital processing of multi-resolution, multi temporal Landsat MSS (14.9. 1972, 16. 7. 1985) and TM (28. 8. 1992). Mapping of vegetation cover was carried out by applying TM-Linear Mixture Modelling and NDVI, while mapping of fallow lands was carried out by both on-screen digitizing and sketch mapping in the field. The image difference technique was used in the change detection analysis. The erosion model predicts an increase in the amount of soil loss in the study area from 1972 to 1992, as a result of land cover changes. It was concluded that the degradation of the soil in the study area, observed during the last two decades, was caused by effects of these land cover changes.

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Ryan, David J. "High temperature degradation of combustion CVD coated thermal barrier coatings." Thesis, Georgia Institute of Technology, 1998. http://hdl.handle.net/1853/18909.

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Schwarze, Susann. "Volatile organic compounds in landfill gas as indicators of waste degradation processes." Thesis, Imperial College London, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.270125.

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Agyemang, Isaac. "Assessment of environmental degradation in Northern Ghana : a GIS based participatory approach." Thesis, University of Leeds, 2007. http://etheses.whiterose.ac.uk/602/.

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The task of understanding how human actions interact in a complex way to bring about environmental degradation requires a holistic research approach. This thesis examines the potential application of a GIS based participatory approach in the assessment of environmental degradation in northern Ghana. It is a development of GIS in participatory research earlier proposed by Abbot et al. (1998) and modified by Williams and Dunn (2003) to assess the impacts of landmines in Cambodia. Using the DPSIR (Driving force-Pressure-State-Impact-Response) framework of the European Environmental Agency as an assessment framework, conventional GIS techniques were integrated with participatory research tools, dubbed "community truthing", to assess the state of the environment, evaluate the driving forces, assess the impact, evaluate community coping strategies and their responses towards a better environment. The developed assessment framework was tested for its robustness in the Bolgatanga and Talensi-Nabdam districts of northern Ghana. While most of the study area was a healthy environment in 1990, by 2004 about 600 km2 of the land area was degraded to the point where it could not be used for any commercial purposes. Spatially, the problem was more pronounced in the mid-north of Bolgatanga and northeast of Talensi-Nabdam as identified from fieldwork and the interpretation of satellite images. It was observed that the problem of environmental degradation is aggravated by socio-economic and cultural processes that motivate individuals to engage in activities that exert many pressures on theenvironment. Impacts were evaluated to include threats of desertification, food shortages, cross-cultural tensions, health risk and reduction in living standards. Driving force reduction, effective environmental management practices, environmental awareness programmes and compensation to affected communities were responses participants perceived would help realise a better future environment. Based on the research findings, the thesis concludes that the developed assessment framework is an effective means of organising complex environmental information for environmental decision making.

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Davies, David Phillip. "Fatigue behaviour of gas-carburised, temper-resistant, low-alloy steels." Thesis, University of Liverpool, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.321168.

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Peng, Wu Tseng. "Evaluation of ceramic candle filters degradation and damage location using four-point bending tests." Morgantown, W. Va. : [West Virginia University Libraries], 1999. http://etd.wvu.edu/templates/showETD.cfm?recnum=1105.

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Thesis (M.S.)--West Virginia University, 1999.
Title from document title page. Document formatted into pages; contains x, 85 p. : ill. (some col.). Includes abstract. Includes bibliographical references (p. 81-82).

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Greene, Elizabeth Anne. "Microbial sulfolane degradation by environmental organisms isolated from contaminated sour gas plant sediments." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1999. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape7/PQDD_0034/NQ46841.pdf.

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Supap, Teeradet. "Kinetic study of oxidative degradation in gas treating unit using aqueous monoethanolamine solution." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 2000. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape3/PQDD_0018/MQ54749.pdf.

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Canciani, Giacomo Edi. "Beyond the light : a study on the nanophotocatalytic degradation of gas-phase contaminants." Thesis, University of Sussex, 2016. http://sro.sussex.ac.uk/id/eprint/65592/.

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Huang, Quanzhen. "THERMAL DEGRADATION OF AMINES FOR CO₂ CAPTURE." UKnowledge, 2015. http://uknowledge.uky.edu/chemistry_etds/51.

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In the selection of candidates for CO2 absorption, solvent thermal degradation has become a general concern due to the significant impact on operational cost and the intention to use thermal compression from high temperature stripping to minimize the overall process energy. In this research, the impact of flue gas contaminants on Monoethanolamine (MEA) thermal degradation was investigated at elevated temperatures consistent with those in the CO2 stripper. Nitrite, fly ash, sulfate and thiosulfate were each added to 5.0 M MEA and the contaminant-containing MEA solutions were degraded at 125 °C, 135 °C and 145 °C. MEA degrades significantly more in the presence of nitrite (5000 ppm) than MEA alone at the same amine molar concentration for all three temperatures. MEA degradation activation energy of MEA-nitrite solution is approximately one-seventh of that of MEA solution without nitrite. Fly ash was observed to inhibit nitrite-induced MEA degradation and greatly increase the MEA degradation activation energy of MEA-nitrite solution. Fly ash, sodium sulfate and sodium thiosulfate by themselves were not shown to impact MEA thermal degradation rate. Sodium salts of glycine, sarcosine, alanine and ß-alanine were thermally degraded at 125 °C, 135 °C and 145 °C, respectively, to discover the structural reasons for their thermal stability. These four amino acids have enhanced thermal degradation rates compared to MEA. The stability order for amino acid salts tested to date is: sarcosinate > alaninate > ß-alaninate. Calculated activation energies for the degradation processes are lower than that of MEA. ß-Alaninate (ß-Ala) thermal degradation generates ß-Ala dimer (major degradation product), ß-Ala dimer carbamate and tetrahydro-1,3-oxazin-6-one. Functional groups, amine orders and steric effect were investigated for their impact on amine thermal degradation. Primary amines with chain structures showed a thermal stability trend as diamine > alkanolamine > amino acid salt. For alknolamine and diamine structural isomers, the primary amines are more stable than the secondary amines. Steric hindrance around the amine group plays a global positive role in protecting amines against thermal degradation.

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Goat, Christopher. "Erosion resistance in metal - ceramic multilayer coatings for gas turbine compressor applications." Thesis, Cranfield University, 1995. http://dspace.lib.cranfield.ac.uk/handle/1826/10717.

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The erosion resistance of 50 m metal-ceramic multilayer coatings has been investigated under impact conditions comparable to those in a gas turbine compressor cascade. lt was possible to improve upon the erosion resistance of Ti-6Al-4V by a significant margin. The influence of layer mechanical properties, layer thickness, ceramic content and coating process on erosion resistance has been studied over a range of impact conditions. The most suitable coating formulation for maximum erosion resistance changed with particle impact energy. Under low energy impact conditions (<55 joules) coatings with a high ceramic content demonstrated the highest erosion resistance. As particle impact energy increased, coatings with a high ceramic content perfonned poorly, and those containing a high volume fraction (50%) ductile metal layer, with thin metal and ceramic layers become more successful. Three principal damage types were observed: lateral fracture, tensile fracture and plastic definition. The most severe coating losses resulted from spallation due to lateral fracture. Coatings containing a high proportion of ductile metal with thin metal and ceramic layers were successful because such coatings had a high resistance to lateral fracture. Erosion resistance was greatest when the metal layer had a high yield strength and elastic modulus; such a combination of properties also resisted plastic definition. Scratch testing was investigated as a simple alterative technique for assessing coating erosion resistance. Repeated pass scratch testing generated similar damage modes to those of particle impact, but there was poor correlation between coating erosion rate and the threshold load for scratch damage.

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21

Chapman, Greg John. "The use of a mathematical model of a marine gas turbine to investigate the effects of engine degradation." Ottawa, 1985.

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Abass, Kabir Oliade. "Techno-Economic Analysis of Gas Turbine Compressor Washing to Combat Fouling." Thesis, Cranfield University, 2015. http://dspace.lib.cranfield.ac.uk/handle/1826/9230.

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Among the major deterioration problems a gas turbine encountered while in operation is compressor blade fouling. This is the accumulation and adhesion of dirt and sediment on the compressor blade which contributes between 70 to 85% of gas turbine performance loss. Fouling reduces turbine air mass flow capacity, compressor pressure ratio and overall gas turbine efficiency. In most cases, its effect does not manifest immediately in gas turbine power output and efficiency since they are not measured directly. However, it is apparent on the gradual increase in Turbine Entry temperature (TET) and Exhaust Gas Temperature (EGT). More fuel is burnt in the combustion chamber to maintain turbine power output which leads to high combustion flame temperature and thus reduces creep life of hot components. This research seeks to analyse the technical and economic consequences of compressor fouling in overall gas turbine performance. The work begins with simulation of TS3000 engine and examination of its design and off design performance. Subsequently, medium size gas turbine engine was modelled, simulated and its performance at different condition was examined to validate the outcome of field data analysis. Three months field operating data of Hitachi H-25 gas turbine generator used for power generation at bonny oil and gas terminal in Nigeria was collected and corrected to international standard ambient condition, using thermodynamic calculations. These data were analysed to determine the effect of fouling on the engine fuel consumption, power output in order to determine the plant profitability. The above analysis gives an estimation of fuel cost saving benefit of $41,000 over the period of one year plant operation due to regular two weekly compressor online water wash which is a good indication of the engine efficiency.

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23

Metzger, Axel. "Chamber studies of secondary organic aerosol formation : from gas phase degradation to aerosol yields /." Zürich : ETH, 2008. http://e-collection.ethbib.ethz.ch/show?type=diss&nr=17853.

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24

Bradley, Gareth Richard. "Fatigue properties of metal inert gas and friction stir welded aluminium alloy 5383-H321." Thesis, University of Plymouth, 2003. http://hdl.handle.net/10026.1/2359.

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The following dissertation details the development of a simple defect-tolerant based model for determining the fatigue properties of a 5383-H321 aluminium alloy and metal inert gas and friction stir welded butt joints in the same alloy. The model considers the fatigue life to consist of three regimes, crack initiation and short and long crack growth, in contrast to the typical defect-tolerant approaches which only consider the long crack growth period. Crack initiation was considered to consist of an initial short crack, present prior to fatigue loading, identical in length to the crack initiator. The short crack growth rate was considered to be a function of the crack length and stress amplitude, whilst the long crack growth regime was described through the Paris equation, dcldN = C(AK)m. The model also considers the effect on the crack initiation and growth rates of the microstructure, macrostructure and residual stresses, with the latter being determined both through the conventional hole-drilling approach and the emerging technique of synchrotron strain scanning. The accuracy of the model was verified through integration of the short and long crack growth regimes, with the predicted lifespan being compared to results obtained from S-N testing of identical welded specimens. A good correlation between the experimental and theoretical results was observed for the parent material and friction stir welded joints for lives in the region 105-106 cycles, although the approach, in its current format, appeared less suitable for determining the fatigue properties of the MIG welded joints. 2

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Allison, Isaiah. "Techno-economic evaluation of associated gas usage for gas turbine power generation in the presence of degradation & resource decline." Thesis, Cranfield University, 2014. http://dspace.lib.cranfield.ac.uk/handle/1826/9233.

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This research examined the technical and economic feasibility of harnessing flare gas emissions from oil fields. The outcome would provide the basis for a substantial re-utilization of this waste energy due to the current practice of flaring and use it alternatively as energy for powering oil fields, rural electrification and desalination. Nigeria is used as a case study. Burning fossil fuels have grave environmental impact, amidst increasing global concerns over harmful emissions. This research addresses resource decline and suggests divestment as a partial cure. The gas turbine is subject to degradation of its components as it is used. Though several methods of assessing gas turbine degradation have been developed with varying degrees of success, no one method has addressed issues pertaining to associated gas and its effects on degradation with divestment. Simulation of two single shaft, heavy duty industrial gas turbines; and three aero-derivative industrial gas turbines of the heavy medium and light capacity ranges were carried out for varying operating conditions, to ascertain the effects of degradation when run on associated gas. Thereafter, optimizations for the best power plant engine mix and the least cost of electricity were carried out. Genetic algorithm was used to assess a population of 10,000 individuals over 500 generations; convergence was achieved for different configurations of the five study engines at discount rates of 5% and 10%, over three power ranges. The divestment pattern starts with the lightest aero-derivative industrial gas turbine; the best power plant selection was limited to the two lightest aero-derivatives in the fleet, completely ignoring the heavy engines. A techno-economic, environmental and risk assessment model comprising performance, emission, economics and risk modules was successfully developed to assess gas turbine degradation with divestment. Using this tool, it was confirmed that associated gas usage resulted in degradation of gas turbine performance, an increase in gas collection as well as operation and maintenance costs. Also there was increasingly higher creep life consumption during slow, medium and fast degradation scenarios for both engine sets. The novel technical contribution of the research work therefore is the influence of degradation on the economic use of associated gas as fuel in gas turbine power generation; and the implementation of divestment in the face of fuel decline.

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Palmer, Matthew. "Development of the in vitro gas production technique to estimate protein degradation in the rumen." Thesis, University of Edinburgh, 2006. http://hdl.handle.net/1842/1950.

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The purpose of this thesis was to adapt the in vitro gas production technique (IVGPT) to estimate the rumen degradation profile of feed protein and to investigate the effect of sample preparation on the estimated kinetics of silage carbohydrate and protein degradation in the rumen.

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Mohan, Prabhakar. "Environmental Degradation of Oxidation Resistant and Thermal Barrier Coatings for Fuel-Flexible Gas Turbine Applications." Doctoral diss., University of Central Florida, 2010. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/3013.

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The development of thermal barrier coatings (TBCs) has been undoubtedly the most critical advancement in materials technology for modern gas turbine engines. TBCs are widely used in gas turbine engines for both power-generation and propulsion applications. Metallic oxidation-resistant coatings (ORCs) are also widely employed as a stand-alone protective coating or bond coat for TBCs in many high-temperature applications. Among the widely studied durability issues in these high-temperature protective coatings, one critical challenge that received greater attention in recent years is their resistance to high-temperature degradation due to corrosive deposits arising from fuel impurities and CMAS (calcium-magnesium-alumino-silicate) sand deposits from air ingestion. The presence of vanadium, sulfur, phosphorus, sodium and calcium impurities in alternative fuels warrants a clear understanding of high-temperature materials degradation for the development of fuel-flexible gas turbine engines. Degradation due to CMAS is a critical problem for gas turbine components operating in a dust-laden environment. In this study, high-temperature degradation due to aggressive deposits such as V2O5, P2O5, Na2SO4, NaVO3, CaSO4 and a laboratory-synthesized CMAS sand for free-standing air plasma sprayed (APS) yttria stabilized zirconia (YSZ), the topcoat of the TBC system, and APS CoNiCrAlY, the bond coat of the TBC system or a stand-alone ORC, is examined. Phase transformations and microstructural development were examined by using x-ray diffraction, scanning electron microscopy, and transmission electron microscopy. This study demonstrated that the V2O5 melt degrades the APS YSZ through the formation of ZrV2O7 and YVO4 at temperatures below 747°C and above 747°C, respectively. Formation of YVO4 leads to the depletion of the Y2O3 stabilizer and the deleterious transformation of the YSZ to the monoclinic ZrO2 phase. The investigation on the YSZ degradation by Na2SO4 and a Na2SO4 + V2O5 mixture (50-50 mol. %) demonstrated that Na2SO4 itself did not degrade the YSZ, however, in the presence of V2O5, Na2SO4 formed vanadates such as NaVO3 that degraded the YSZ through YVO4 formation at temperature as low as 700°C. The APS YSZ was found to react with the P2O5 melt by forming ZrP2O7 at all temperatures. This interaction led to the depletion of ZrO2 in the YSZ (i.e., enrichment of Y2O3 in t' -YSZ) and promoted the formation of the fluorite-cubic ZrO2 phase. Above 1250°C, CMAS deposits were observed to readily infiltrate and significantly dissolve the YSZ coating via thermochemical interactions. Upon cooling, zirconia reprecipitated with a spherical morphology and a composition that depended on the local melt chemistry. The molten CMAS attack destabilized the YSZ through the detrimental phase transformation (t -> t -> f + m). Free standing APS CoNiCrAlY was also prone to degradation by corrosive molten deposits. The V2O5 melt degraded the APS CoNiCrAlY through various reactions involving acidic dissolution of the protective oxide scale, which yielded substitutional-solid solution vanadates such as (Co,Ni)3(VO4)2 and (Cr,Al)VO4. The molten P2O5, on the other hand, was found to consume the bond coat constituents significantly via reactions that formed both Ni/Co rich phosphates and Cr/Al rich phosphates. Sulfate deposits such as Na2SO4, when tested in encapsulation, damaged the CoNiCrAlY by Type I acidic fluxing hot corrosion mechanisms at 1000°C that resulted in accelerated oxidation and sulfidation. The formation of a protective continuous Al2O3 oxide scale by preoxidation treatment significantly delayed the hot corrosion of CoNiCrAlY by sulfates. However, CoNiCrAlY in both as-sprayed and preoxidized condition suffered a significant damage by CaSO4 deposits via a basic fluxing mechanism that yielded CaCrO4 and CaAl2O4. The CMAS melt also dissolved the protective Al2O3 oxide scale developed on CoNiCrAlY by forming anorthite platelets and spinel oxides. Based on the detailed investigation on degradation of the APS YSZ and CoNiCrAlY by various corrosive deposits, an experimental attempt was carried out to mitigate the melt-induced deposit attack. Experimental results from this study demonstrate, for the first time, that an oxide overlay produced by electrophoretic deposition (EPD) can effectively perform as an environmental barrier overlay for APS TBCs. The EPD protective overlay has a uniform and easily-controllable thickness, uniformly distributed closed pores and tailored chemistry. The EPD Al2O3 and MgO overlays were successful in protecting the APS YSZ TBCs against CMAS attack and hot corrosion attack (e.g., sulfate and vanadate), respectively. Furnace thermal cyclic oxidation testing of overlay-modified TBCs on bond-coated superalloy also demonstrated the good adhesive durability of the EPD Al2O3 overlay.
Ph.D.
Department of Mechanical, Materials and Aerospace Engineering
Engineering and Computer Science
Materials Science & Engr PhD

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28

Lindelöf, Åsa. "Metangasutsläpp från deponier och osäkerheter i beräkningsmodeller kring detta." Thesis, KTH, Industriell ekologi, 2012. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-96418.

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I Sverige finns uppskattningsvis mellan 4000 och 8000 stycken deponier. De flesta av deponierna är nedlagda och år 2001 fanns det 142 stycken aktiva deponier för hushållsavfall. År 2010 hade antalet minskat till 76 stycken. Vid nedbrytning av organiskt material i deponier bildas metanhaltig deponigas som bidrar till växthuseffekten. Utsläppens omfattning prognostiseras med hjälp av beräkningsmodeller, exempelvis IPCCs. Dessa modeller fordrar att antaganden görs av exempelvis andelen gas som utvinns via gasuppsamlingsutrustningen, det organiska materialets halveringstid och avfallets sammansättning och mängd. I Sverige görs antagandet att 60 procent av deponigasen samlas upp på deponier med gasuppsamlingsutrustning. Rapportens övergripande syfte var att undersöka hur osäkerheterna i de antaganden som görs kan inverka på de prognostiserade deponigasemissionerna. Syftet var också att bedöma om metangasutsläpp från deponier utgör ett stort eller försumbart tillskott av växthusgasutsläpp i jämförelse med andra källor. Detta gjordes genom en känslighetsanalys som baserades på en litteraturstudie, IPCC- prognostiserade metanmängder samt genom intervjuer med deponiägare. Prognostiserad metangasproduktion från landets deponier jämfördes med uppskattad metangasproduktion, där det senare baserades på utvunna mängder i landet och en uppskattad utvinningsgrad på 60 procent. Prognostiserad metangasmängd jämfördes med en uppskattad mängd metan, där den senare baserades på utvunna gasmängder i landet och uppskattad utvinningsgrad. Omfattningen av emissionerna gjordes genom känslighetsanalys där utvinningsgrad hos gasuppsamlingssystemets varierades mellan 30 och 80 procent. De utvunna gasmängderna har varit relativt konstanta de senaste tio åren trots att antalet deponier med gasuppsamlingsutrustning minskat från 75 till 47 stycken och att deponeringsförbud har instiftats. Den antagna halveringstiden på 7,5 år torde därför vara för lågt ansatt vilket också styrks av den dåliga nedbrytningen i flera äldre deponier, minskade mängder deponerat avfall samt att inget organiskt material deponeras sedan 2005. Sveriges huvudsakliga metankällor är jordbrukssektorn och deponier från avfallssektorn. År 1990 var de prognostiserade utsläppen från de två sektorerna ungefär lika stora. Fram till år 2010 har de prognostiserade utsläppen från deponier halverats medan utsläpp från jordbruket ligger på ungefär samma nivå som tidigare. Ur den enskilda deponins perspektiv kan det konstateras att utvinningsgraden hos gasuppsamlingssystemet varierar i både ett kortsiktigt och i ett långsiktigt perspektiv. Beroende på när en mätning utförs kommer en viss variation uppvisas i gasutvinningssystemets utvinningsgrad dvs både emitterade och uppsamlade gasmängder varierar mellan mättillfällena. Det kan konstateras att en stor osäkerhet byggs in i den beräknade årsproduktionen av metangas när metanmängderna beräknas med hjälp av medelvärden från ett fåtal mätningar utförda under korta mätperioder. Statistiska Centralbyrån har gjort beräkningar av den årliga utvinningsgraden. Dessa beräkningar har grundats på faktiska utvunna mängder som jämförts med beräknade totala mängder. För en enskild deponi kan skillnaderna mellan de beräknade och faktiska mängderna vara stora vilket medför att utvinningsgraden eller produktionen är svårbedömd både för den enskilda deponin och på nationell nivå. Potentialen för gasutvinning i deponier bedöms i det här examensarbetet vara större än vad som har prognostiserats. Perioden för gasuttag sträcker sig längre än vad man trott med anledning av att mycket av det organiska materialet i gamla deponier fortfarande inte har brutits ner, samt att gasproduktion fortfarande sker. Med anledning av de låga driftskostnaderna bör deponigasutvinning fortskrida så länge som det är tekniskt möjligt och ekonomiskt hållbart. Genom provtagningar av avfallet i kombination med mätningar som sträcker sig över längre perioder, skulle bättre kännedom om metangasproduktionen i deponier kunna fås.
There are a large number of landfill sites in Sweden. The total number is estimated to be somewhere between 4000 to 8000 landfills. In 2007 there were 142 landfill sites still operating, three years later the number of operating landfills decreased to 76. The municipalities are at present carrying out an inventory of old landfill sites in Sweden. The focus is on the location and risk classification of the landfill sites. There is a substantial uncertainty of the content and the progress of the degradation process unless the landfill is dug out. Methane containing landfill gas is produced when the organic matter in the waste is degraded. Since methane is a potent green house gas the emissions of landfill gas will contribute to the green house effect. The extent of the emissions is usually quantified using the IPCC model or similar. The models require certain estimations to be made such as the amount of gas that is extracted, the half-life of the organic matter and the composition of the waste. The aim of the report was therefore to look into these estimations and how these can effect the landfill gas production. The aim was also to evaluate whether the methane emissions from landfills is a major contributor to the green house gas emissions in comparison to other sources. The master thesis has been carried out through a literature study and interviews with landfill owners that resulted in a sensitivity analysis. The plausibility of the IPCC model was studied by carrying out a sensitivity analysis of the efficiency of the gas extraction system and how this will influence the total emissions of landfill gas. An overview of the connection between the land fill gas production and the decomposition of the organic matter could be realized by analyzing the material in the landfill through tests on different depths in the landfill when drilling new gas wells. The extracted amounts of landfill gas are also contradictive to the estimation of the half-life of 7,5 years that is assumption regularly made within the IPCC- model. This theory is supported by the inadequate decomposition of organic material in old landfill sites. The reduced amounts of waste that is landfilled and the prohibition of landfilling of organic and combustible waste in 2005 are also supporting this theory. The main methane sources in Sweden are ruminants from the agricultural sector and landfills. In 1990 the forecast of the methane emissions of the two sectors were equal. The forecast of today shows that the agricultural emissions are more or less the same but the emissions from landfill are halved. Another conclusion was that the efficiency of the gas extraction is varying in a short- term and in a long-term perspective. Depending on when a measurement is carried out there will be a variation of the efficiency of the gas extraction system. Anyhow annual values of the extracted amounts are calculated based on a few occasional measurements over very short time periods. Moreover, the yearly efficiency is determined based on real extracted values of methane and calculated total values of methane production that are non-comparable. The potential of gas extraction is probably larger than what has been predicted and the period of gas extraction is probably longer than expected. Supported by the low operation costs for the gas extraction the extraction should be carried out as long as it is technically possible and economically reasonable. Analyzing the material in the landfill site will increase the understanding of the gas production and the degradation of the waste in the landfill.

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Tummons, Michael A. "Testing environmental controls on methane generation during microbial degradation of coal and oil from the Cherokee basin, Kansas." Thesis, Kansas State University, 2017. http://hdl.handle.net/2097/35565.

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Master of Science
Department of Geology
Matthew Kirk
Biodegradation of crude oil to methane has long been known to exist in shallow petroleum reservoirs. It is only in the past decade, however, in which the concept of in-reservoir petroleum biodegradation has changed from a model emphasizing aerobic crude-oil degradation (with oxygen delivered down from meteoric waters) to a more recent model in which crude-oil degradation is driven by anaerobic processes (methanogenic microorganisms). In this study, we examine controls on microbial conversion of crude oil and coal into methane in middle-Pennsylvanian strata in the Cherokee Basin, Kansas, USA and how access to oil or coal influence microbial communities. Specifically, we considered the following hypotheses: 1) microorganisms in the basin are capable of generating methane by degrading crude oil or coal and 2) potential controls on the rate of methane formation include microbial diversity, formation water chemistry, nutrient abundance, and carbon dioxide abundance. To test these hypotheses, we used three sets of laboratory experiments constructed of materials from the Cherokee basin, Kansas. One set tested environmental controls on methane generation from oil, another from coal, and a third was a control experiment that utilized methanogenic substrates rather than oil or coal. In the experiments with oil and coal, environmental factors tested ammonium/phosphate availability, feedlot wastewater injection, and carbon dioxide abundance. Our experiments also tested the influence of salinity, by including materials from a well producing water with relatively low salinity and a well producing water with relatively high salinity. The cultures were allowed to incubate from approximately 75 to 170 days, during which headspace of oil and coal bioreactors were sampled periodically and analyzed for methane concentrations. Post incubation analyses included microbial DNA sequencing. We determined that a higher concertation of methanogens existed in the lower salinity well, which has higher potential for practical stimulatory injection. Of methane produced, the only significant (Mann Whitney) treatment had access to oil in lower salinity formation water. Access to coal resulted in no significant results. Microbial diversity, in the form of methanogenic archaea abundance, formation water chemistry (salinity), and wastewater nutrient often correlated with increased, yet insignificant, rates of methane production, while carbon dioxide abundance showed no benefit. Of methanogenic substrates consumed, we determined that most Cherokee basin methanogens preferred methanol over hydrogen and acetate.

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Menéndez, Flores Víctor Manuel. "Synthesis of semiconductor nanoparticles applied in photocatalysis for the degradation of pollutants in aqueous and gas phase." Hannover Technische Informationsbibliothek und Universitätsbibliothek Hannover, 2010. http://d-nb.info/1004000391/34.

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Abu, Amara Tamer Mossud Mahmoud. "Expression of the G-protein Gas in the human myometrium is modulated by ubiquitination and protein degradation." Thesis, University of Newcastle Upon Tyne, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.512026.

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32

Emil, Mustafa Kemal. "Land Degradation Assessment For An Abandoned Coal Mine With Geospatial Information Technologies." Master's thesis, METU, 2010. http://etd.lib.metu.edu.tr/upload/12612627/index.pdf.

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This study proposes an approach for land degradation assessment for an abandoned coal mine by using geospatial information technologies. The land degradation assessment focuses on two major changes: topographical and Land Use and Land Cover (LULC). For this purpose, stereo aerial photos, Worldview-1, Landsat and ASTER images, Terrestrial Laser Scanning (TLS) data, Global Positioning System (GPS) data, and ancillary maps were used for abandoned Ovacik surface coal mine. Volume of excavations and fillings, drainage network deviations, and slope instabilities were the investigated topographical disturbances by comparison of the Digital Elevation Models (DEM) for pre- and post-mining stages. Using aerial photos and Worldview-1 satellite image, LULC maps were prepared based on the same time period. Then areal extent and spatial pattern of the LULC change was calculated and mapped by post classification comparison method. The results of land degradation assessment show that there was a significant topographical disturbance and LULC change in the research area. Particularly, three dump areas with a total volume of 2,334,878 m3 were identified by DEM subtraction. It was found that stream network around the primary dump site shifted towards south with a maximum displacement of 60m. Slope analysis reveals that slopes higher that 60 degrees were mainly observed in excavation area with 81 percent. LULC change study showed that the forest area decreased an amount of 106,485 m2 from 1951 to 2008. However
by means of the forestation efforts in dump sites, an amount of 106,012 m2 forest land was recovered.

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Ibrahim, Ali Hano Abdelnasir. "Assessment of Impacts of Changes in Land Use Patterns on Land Degradation/Desertification in the Semi- arid Zone of White Nile State, Sudan, by Means of Remote Sensing and GIS." Doctoral thesis, Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2014. http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-157627.

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In Sudan, land degradation/desertification (LDD) has devastated large areas and consequently, it includes social, economic, and environmental aspects. LDD results from various factors, including climatic variation and human activities. Probably the LU practices and their changes have contributed to an increase of LDD in that area. Remote sensing technology has become unique and developed tool for providing temporal and spatial information for the LDD research and other environmental aspects. Determination of LDD and its relationship to land use pattern change (LUC) at spatiotemporal scale is rare, critical issue, and is one of the recommended research in semi-arid regions of Sudan. The study was carried out to derive accurate and improved spatiotemporal information: to assess the status of land LDD of vegetation and soil, to assess and model influences of the LUC on LDD, and moreover to analyse the synergistic factors that have caused the land use change and/or LDD in semi- arid zone of Elgeteina Locality in While Nile State, Sudan during the last 36 years, using appropriate remote sensing (RS) and GIS technology. The study used four-cloud free images of different sensors (MSS 1973, TM 1986, ASTER 2009 and TM 2010). The imageries were Geo-referenced and radiometrically corrected by using ENVI-FLAASH software. Then subsets of the study area were taken, ranging from 1600-2000 Km2. The study applied the new approach of integration between vegetation and soil indices and in situ data to assess the LDD. Comparison between pixel based image analysis (PBIA) and latterly approach of object based image analysis (OBIA) was done by selecting the best one for mapping LUC and LDD accurately. The change detection - matrix was applied to estimate the spatiotemporal of changes in land use and land degradation. Moreover, correlation and model approach was employed for fusing the climatic, socioeconomic and remote sensing data to determine the relationships between the different factors and to analyse the reasons for the LUC and LDD as well as for modelling LU effects on LDD. The study revealed that: The changes in land use patterns (RA, FWL and FML) took place in 1973 – 86 – 2009, and affecting thoroughly different patterns of the vegetation cover. Likewise the LUC affected soil degradation which led to the movement of sand dunes in 1973 – 2009. The agricultural activity is the dominant and has more effect on LDD particularly on the vegetation cover degradation. The population growth and the socioeconomic status of local people are the main indirect human inducing factors responsible for LUC and/or LDD. SARVI is slightly more efficient than NDVI, SAVI, ND4-25 and ND42-57, for detecting the vegetation status in semi-arid area, therefore the study selected it for the assessment. GSI proved highly efficient in determining the different types of soil degradation, and in producing the map of top soil grain size, which assisted in the assessment of land degradation and desertification. OBIA-fuzzy logic classification performed better than the PBIA- hybrid classification for assessing LU patterns impact on LDD. The study recommends to: replication of this study by using different imagery with high resolutions and sophisticated software, such as eCognition and Feature Analyst (FA) for increasing the validity and accuracy of the assessment and modelling of LU patterns and LDD status in dry land is important in the Sudan
Im Sudan hat Land Degradation/ Desertifikation (LDD) weite Gegenden verwüstet, wobei hierbei soziale, wirtschaftliche und Umweltaspekte eine Rolle spielen. LDD wird von verschiedenen Faktoren ausgelöst, darunter Klimavariationen und menschliche Aktivitäten. Wahrscheinlich haben Landnutzungspraktiken und ihre Änderungen zu erhöhter LDD in der untersuchten Gegend beigetragen. Fernerkundungstechnologien sind sehr gute und weit entwickelte Werkzeuge um zeitliche und räumliche Informationen zur Erforschung von LDD und anderen Umweltaspekten zu ermitteln. Die Bestimmung von LDD und ihre Beziehung zur Änderung von Landnutzungsmustern (LUC) im raum-zeitlichen Maßstab ist bislang noch selten erforscht und ist ein Forschungsbereich, der für die semi-ariden Regionen des Sudan empfohlen wird. Die Studie wurde durchgeführt, um genaue und verbesserte raum-zeitliche Informationen zu gewinnen: um den Status der LDD von Vegetation und Boden zu bewerten, um den Einfluss des Landnutzungswandels auf LDD zu beurteilen und zu analysieren, und außerdem um die synergetischen Faktoren die den Landnutzungswandel und/oder LDD verursacht haben zu analysieren. Dabei wurde die semi-ariden Zone des Elgeteina Gebietes im Staat Weisser Nil (Sudan) während der vergangenen 36 Jahren unter Verwendung von geeigneter Fernerkundungs- und GIS-Technologie untersucht. Für die Studie wurden vier wolkenfreie Bilder von verschiedenen Sensoren (MSS 1973, TM 1986, ASTER 2009 and TM 2010) verwendet. Die Bilder wurden georeferenziert und radiometrische korrigiert, wobei die ENVI-FLAASH Software verwendet wurde. Anschließend wurden Teilgebiete des Untersuchungsgebietes mit einer Größe zwischen 1.600 und 2.000 Km2 ausgewählt. In der Studie fand der neue Ansatz der Integration von Vegetation und Boden Indizes und in-situ Daten Verwendung, um LDD zu bewerten. Ein Vergleich von pixel-basierter Bildanalyse (PBIA) und einem Ansatz von objekt-basierter Bildanalyse (OBIA) wurde durchgeführt, um die beste Methode der Kartierung von LUC und LDD ermitteln. Veränderungsmatrizen wurden eingesetzt, um räumlich-zeitlichen Änderungen der Landnutzung und Land Degradation abzuschätzen. Außerdem wurde ein Korrelation- und Modellierungs-Ansatz eingesetzt, um die klimatischen, sozioökonomischen und Fernerkundungsdaten zu verschmelzen und das Verhältnis zwischen den unterschiedlichen Faktoren zu bestimmen und um die Gründe für LUC und LDD zu analysieren aber auch um die Auswirkungen der Landnutzung auf LDD zu modellieren. Die Studie hat folgendes gezeigt: Die Änderungen der Landnutzungsmuster (RA, FWL and FML) fand in 1973 – 86 – 2009 statt und betraf sehr unterschiedliche Vegetationsmuster. Ebenso hatte die LUC Auswirkungen auf die Bodendegradation, was zu einer Verschiebung von Sanddünen im Zeitraum 1973-2009 führte. Landwirtschaft dominiert und hat starke Auswirkungen auf LDD, insbesondere auf die Degradation der Vegetationsbedeckung. Die Bevölkerungszunahme und der sozioökonomische Status der lokalen Bevölkerung sind die wesentlichen indirekten menschlichen Faktoren die verantwortlich für LUC und/oder LDD sind. SARVI ist etwas effizienter als NDVI, SAVI, ND4-25 und ND42-57, um den Zustand der Vegetation in semi-ariden Gebieten zu bestimmen, deshalb wurde dieser für die Studie ausgewählt. Es stellte sich heraus, dass der GSI hoch-effizient war, sowohl bei der Bestimmung der unterschiedlichen Typen von Bodendegradation als auch bei der Erstellung von Karten der obersten Bodenkorngröße, die bei der Bewertung der Landdegradation und Desertifikation half. OBIA-Fuzzy Logic Classification arbeitete dabei etwas genauer und effizienter als die PBIA-Hybrid Classification, um die Auswirkungen der Landnutzungsmuster auf LDD zu beurteilen. Als Fortsetzung der durchgeführten Arbeiten empfiehlt sich eine nochmalige Durchführung der Studie wobei anderes, hochaufgelöstes Bildmaterial und anspruchsvolle Software, wie eCognition und Feature Analyst (FA) verwendet werden sollten, um die Gültigkeit und Genauigkeit der Bewertungen und Modellierung des LU und LDD Status von Trockenland im Sudan zu beurteilen

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34

Oztekin, Burak. "Assessment Of Degradation Mechanism And Stability Of A Cut Slope In Jointed And Sheared Limestone Along Ankara-eskisehir E90 Highway." Master's thesis, METU, 2004. http://etd.lib.metu.edu.tr/upload/12605631/index.pdf.

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Due to rapidly growing population of Ankara city (Turkey) and traffic load, it is required to widen some of the existing highways. One of them is Ankara-EskiSehir (E-90) highway that connects highly populated areas to the city center. During widening, several cut slopes were formed along the highway route. However, some instability problems such as small-sized rock falls and rock detachments have occurred along a cut slope in highly jointed, folded and sheared limestone. They caused local degradation of the cut slope. The cut slope has a slope angle varying from 71°
to 84°
and contains several shear zones. In this study, the relationships between the existing detachment zones and various parameters (e.g. block size, point load strength index, weathering, shear zone, daylight zone) considered to be important for slope instability were investigated using GIS-based statistical landslide susceptibility analyses in order to predict the further aerial extension of the detachment zones with time. During the overlay analyses, statistical index and weighting factor methods were used by means of TNT-MIPS software. The outcomes of the analyses using both methods are compared and evaluated together with the field observations to check the reliability of the methods and to assess the detachment zones that may develop in the future. Additionally, limit equilibrium analyses were also carried out for the determination of the possible large scale mass failures. The overlay analyses indicate some risky zones where detachments are likely to occur in the future. On the other hand, the limit equilibrium analysis of the rock mass using Bishop simplified method shows that except one section no mass failure is expected in the cut slope. Suitable remediation measures which include the use of wire mesh, shotcrete, toe support, and concrete barrier blocks or catch/barrier fences are recommended for these zones.

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35

Mhangara, Paidamwoyo. "Land use/cover change modelling and land degradation assessment in the Keiskamma catchment using remote sensing and GIS." Thesis, Nelson Mandela Metropolitan University, 2011. http://hdl.handle.net/10948/1467.

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Land degradation in most communal parts of the Keiskamma catchment has reached alarming proportions. The Keiskamma catchment is particularly predisposed to severe land degradation associated with soil erosion, thicket degradation and deteriorating riparian vegetation. There is a close coupling between land use/cover dynamics and degradation trends witnessed in the catchment. Soil erosion is prevalent in most of the communal areas in the catchment. The principal aim of this study was to investigate land use/cover trends, model the spatial patterns of soil loss and predict future land use/cover scenarios as a means of assessing land degradation in the Keiskamma catchment. Multi-temporal Landsat satellite imagery from 1972 to 2006 was used for land use/cover change analyses using object-oriented post-classification comparison. Fragmentation analysis was performed by computing and analyzing landscape metrics in the riparian and adjacent hillslope areas to determine the land cover structural changes that have occurred since 1972. The landscape function analysis was used to validate the current rangeland conditions in the communal areas and the former commercial farms. The current condition of the riparian zones and proximal hillslopes was assessed using the Rapid Appraisal of Riparian Condition and future land use/cover scenarios were simulated using the Markovcellular automata model. Spatial patterns of soil loss in the Keiskamma catchment were determined using the Sediment Assessment Tool for Effective Erosion Control (SATEEC), which is a GIS based RUSLE model that integrates sediment delivery ratios. Object oriented classification was used to map soil erosion surfaces and valley infill in ephemeral stream channels as a means of demonstrating the major sediment transfer processes operating in the Keiskamma catchment. The Mahalanobis distance method was used to compute the topographic thresholds for gully erosion. To understand the effect of soil characteristics in severe forms of erosion, laboratory analyses were undertaken to determine the physico-chemical soil properties. iv The temporal land use/cover analysis done using the post-classification change detection indicated that intact vegetation has undergone a significant decline from 1972 to 2006. The temporal changes within the intermediate years are characterized by cyclic transitions of decline and recovery of intact vegetation. An overall decline in intact vegetation cover, an increase in degraded vegetation and bare eroded soil was noted. Fragmentation analyses done in the communal villages of the central Keiskamma catchment indicated increasing vegetation fragmentation manifested by an increase in smaller and less connected vegetation patches, and a subsequent increase of bare and degraded soil patches which are much bigger and more connected. The Landscape Organisation Index revealed very low vegetation connectivity in the communal rangelands that have weak local traditional institutions. Fragmentation analyses in the riparian and proximal hillslopes revealed evidence of increasing vegetation fragmentation from 1972 to 2006. The Markov Cellular Automata simulation predicted a decline in intact vegetation and an increase in bare and degraded soil in 2019. The Keiskamma catchment was noted as experiencing high rates of soil loss that are above provincial and national averages. The classification of erosion features and valley infill showcased the vegetation enrichment in the ephemeral streams which is occurring at the expense of high soil losses from severe gully erosion on the hillslopes. This in turn has led to an inversion of grazing patterns within the catchment, such that grazing is now concentrated within the ephemeral stream channels. Soil chemical analyses revealed a high sodium content and low soluble salt concentration, which promote soil dispersion, piping and gully erosion. The presence of high amounts of illite-smectite in the catchment also accounts for the highly dispersive nature of the soil even at low SAR values. Significant amounts of swelling 2:1 silicate clays such as smectites cause cracking and contribute to the development of piping and gullying in the catchment. Given the worsening degradation trends in the communal areas, a systematic re-allocation of state land in sections of the catchment that belonged to the former commercial farms is recommended to alleviate anthropogenic pressure. Strengthening local institutions that effectively monitor and manage natural resources will be required in order to maintain v optimum flow regimes in rivers and curb thicket degradation. Measures to curb environmental degradation in the Keiskamma catchment should encompass suitable ecological interventions that are sensitive to the socio-economic challenges facing the people in communal areas.

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36

Choi, Narak. "Image degradation due to surface scattering in the presence of aberrations." Doctoral diss., University of Central Florida, 2012. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/5165.

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This dissertation focuses on the scattering phenomena by well-polished optical mirror surfaces. Specifically, predicting image degradation by surface scatter from rough mirror surfaces for a two-mirror telescope operating at extremely short wavelengths (9nm~30nm) is performed. To evaluate image quality, surface scatter is predicted from the surface metrology data and the point spread function in the presence of both surface scatter and aberrations is calculated. For predicting the scattering intensity distribution, both numerical and analytic methods are considered. Among the numerous analytic methods, the small perturbation method (classical Rayleigh-Rice surface scatter theory), the Kirchhoff approximation method (classical Beckman-Kirchhoff surface scatter theory), and the generalized Harvey-Shack surface scatter theory are adopted. As a numerical method, the integral equation method (method of moments) known as a rigorous solution is discussed. Since the numerical method is computationally too intensive to obtain the scattering prediction directly for the two mirror telescope, it is used for validating the three analytic approximate methods in special cases. In our numerical comparison work, among the three approximate methods, the generalized Harvey-Shack model shows excellent agreement to the rigorous solution and it is used to predict surface scattering from the mirror surfaces. Regarding image degradation due to surface scatter in the presence of aberrations, it is shown that the composite point spread function is obtained in explicit form in terms of convolutions of the geometrical point spread function and scaled bidirectional scattering distribution functions of the individual surfaces of the imaging system. The approximations and assumptions in this formulation are discussed. The result is compared to the irradiance distribution obtained using commercial non-sequential ray tracing software for the case of a two-mirror telescope operating at the extreme ultra-violet wavelengths and the two results are virtually identical. Finally, the image degradation due to the surface scatter from the mirror surfaces and the aberration of the telescope is evaluated in terms of the fractional ensquared energy (for different wavelengths and field angles) which is commonly used as an image quality requirement on many NASA astronomy programs.
ID: 031001439; System requirements: World Wide Web browser and PDF reader.; Mode of access: World Wide Web.; Title from PDF title page (viewed June 26, 2013).; Thesis (Ph.D.)--University of Central Florida, 2012.; Includes bibliographical references (p. 223-231).
Ph.D.
Doctorate
Optics and Photonics
Optics and Photonics
Optics

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37

Djongkah, Cissillia Young Chemical Sciences &amp Engineering Faculty of Engineering UNSW. "Effect of Pt and Ag metals to the degradation of trichloroethylene, ethylene, ethane, and toluene by gas phase photocatalysis." Awarded by:University of New South Wales. School of Chemical Sciences and Engineering, 2006. http://handle.unsw.edu.au/1959.4/26227.

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The photocatalytic oxidation of trichloroethylene (TCE), ethylene. ethane and toluene on TiO2, Pt/TiO2 and Ag/TiO2 were investigated in a dedicated reactor set-up operated at room temperature and ambient pressure condition. The gas phase experiments were carried out for both single and binary mixtures of these chemicals to identify the role of Pt and Ag metallisation in the photocatalytic oxidation of different contaminants. In a single contaminant system, the presence of Pt enhanced the oxidation of ethylene, ethane and toluene but detrimental to the oxidation of TCE. In the oxidation of ethylene, Pt enhanced the oxidation by acting as catalyst and as electron sink. However, in ethane oxidation, the enhancement was solely associated to the ability of Pt to act as electron sink. The detrimental effect observed in TCE oxidation was attributed to Pt and Cl interaction, which formed a persistent inorganic chlorine species decreasing the overall Pt/TiO2 photocatalyst performance. Interestingly, Ag did not show any significant effect to the oxidation of any single system degradation. In binary system degradation, where TCE and another organic compound either ethylene, ethane or toluene were degraded simultaneously, Pt always caused a detrimental effect due to its strong interaction with Cl. However, the presence of Ag and Cl gives a more synergetic effect. Ag was found to provide sites to temporarily trap chlorine radicals as AgCl. Under illumination, electrons transferred from Cl to Ag forming chlorine radicals that could react with the surface contaminant enhancing its breakdown and mineralization.

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38

Grima, N. M. M. "Kinetic and mass transfer studies of ozone degradation of organics in liquid/gas-ozone and liquid/solid-ozone systems." Thesis, University of Bradford, 2009. http://hdl.handle.net/10454/3351.

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This work was concerned with the determination of mass transfer and kinetic parameters of ozone reactions with four organic compounds from different families, namely reactive dye RO16, triclocarban, naphthalene and methanol. In order to understand the mechanisms of ozone reactions with the organic pollutants, a radical scavenger (t-butanol) was used and the pH was varied from 2 to 9. Ozone solubility (CAL*) is an important parameter that affects both mass transfer rates and chemical reaction kinetics. In order to determine accurate values of the CAL* in the current work, a set of experiments were devised and a correlation between CAL* and the gas phase ozone concentration of the form CAL*(mol/L) = 0.0456 CO3 (g/m3 NTP) was obtained at 20°C. This work has also revealed that t-butanol did not only inhibit hydroxyl radical reactions but also increased mass transfer due to it increasing the specific surface area (aL). Values of the aL were determined to be 2.7 and 3.5 m2/m3 in the absence and presence of t-butanol respectively. It was noticed that the volumetric mass transfer coefficient (kLa) has increased following the addition of t-butanol. Ozone decomposition was studied at pH values of 2 to 9 in a 500 mL reactor initially saturated with ozone. Ozone decomposition was found to follow a second order reaction at pH values less than 7 whilst it was first order at pH 9. When the t-butanol was added, the decomposition of ozone progressed at a lower reaction order of 1.5 for pH values less than 7 and at the same order without t-butanol at pH 9. Ozone decomposition was found significant at high pHs due to high hydroxide ion concentration, which promotes ozone decomposition at high pHs. The reaction rate constant (k) of RO16 ozonation in the absence of t-butanol was determined. The result suggests that RO16 degradation occurs solely by molecular ozone and indirect reactions by radicals are insignificant. The chemical reaction of triclocarban with ozone was found to follow second order reaction kinetics. The degradation of naphthalene using the liquid/gas-ozone (LGO) system was studied. This result showed that hydroxyl radicals seemed to have limited effect on naphthalene degradation which was also observed when a radical scavenger (t-butanol) was used. Reaction rate constants were calculated and were found around 100 times higher than values reported in the literature due to differences in experimental conditions. From the results of the experimental investigation on the degradation of methanol by ozone it was found that the rate constant (k) of the degradation reaction increased at pH 9. The reaction stoichiometry was found to have a value of 1 mol/mol. The two steps of the liquid/solid-ozone (LSO) system were studied on beds of silica gel and a zeolitic material (D915) and the ozone adsorption process was modeled and found that particle rate controls ozone adsorption step but liquid rate controls the water treatment step. Ozone desorption with pure deionised water was studied. The water flow rate was found to accelerate the desorption rates but pH was found to decrease the desorption rates. In contrast, the effect of pH was insignificant in the presence of t-butanol. Determination of the adsorption isotherms for RO16, naphthalene and methanol revealed that RO16 did not exhibit adsorption on silica gel, but both naphthalene and methanol showed adsorption on D915 described by Langmuir model.

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39

Al, Mohamed Ismail. "Erfassung und Bewertung von degradierten Böden mit Fernerkundung und GIS in Nordwest-Syrien." Doctoral thesis, Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2011. http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-70559.

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Due to a high population growth (approx. 2.5 % p.a) the food-sector in Syria is facing in-creasing problems. An enormous increase in population results in increased demand for food. This has adversely affected the socio-economic and ecological development in the country. Intensive use of various natural resources has led to significant changes in land use pattern, especially due to use of inappropriate methods in the agricultural sector. The increasing anthropogenic pressure on the sensitive ecological structure of the respective area causes environmental damages, in particular degradation of soil characteristics. In the semi-arid and arid eco-climatic zones vast areas are facing desertification. Soil erosion through water represents the main form of land degradation in the north-west of Syria. Particularly vulnerable are the soils with a shallow or no vegetation cover, such as the soils found in the Mediterranean hills, where olives are cultivated. For this research the Afrin region, located in the northwest of Syria, was selected as study area, in order to analyse and assess the extent of degradation. For estimation of erosion the relevant parameters of the “Universal Soil Loss Equation USLE” were used. These para-meters were adapted and integrated through remote sensing and GIS. LANDSAT TM and ASTER satellite imagery of the investigated area were used for this purpose. Data were acquired at the end of the dry season. In order to achieve an accurate evaluation and high-quality comparison of multi-temporal satellite data, imagery was firstly geometrically and atmospherically corrected and then analysed. The vegetation coverage and its current de-gradation level were investigated by spectral mixture analysis (SMA). The digital elevation model (DEM) derived from ASTER data was utilized to generate the slope gradient (S) and the slope length (L). In addition to the laboratory analysis, grain size index (GSI) and SMA were used for the characterization and mapping of soil erodibility. Land-use/land-cover classification and change detection were determined by using pixel-based classification procedures (maximum likelihood classification) and post classification methods respectively. Required samples for land cover classification of the remotely sensed data were collected during the field work, in addition to the soil samples for soil analysis. The results of this study show that advanced methods of remote sensing and GIS provide powerful tools not only for a better understanding of the land use changes, but also for an accurate assessment of land degradation and desertification. This knowledge, in turn, con-tributes highly towards developing effective and appropriate management strategies for sustainable use and conservation of natural resources in the north-west of Syria

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40

Chmelař, Vít. "Zařízení pro monitorování degradačních procesů u materiálů živočišného původu." Master's thesis, Vysoké učení technické v Brně. Fakulta elektrotechniky a komunikačních technologií, 2019. http://www.nusl.cz/ntk/nusl-399460.

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The diploma thesis introduces the reader to the problems of chemical sensors and the basics of degradation processes in materials of animal origin. It describes some types of sensors and their principles. Atmel ATmega328 microprocessor, its parameters and programming are described. In the next part of the thesis there is a proposal and production of equipment for monitoring of degradation processes in materials of animal origin. Sample sof chicken and milk were mesuared. From these measurements, the gas concentration values were determined, where samples can be considered suitable for consumation.

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41

Menéndez, Flores Victor Manuel [Verfasser]. "Synthesis of semiconductor nanoparticles applied in photocatalysis for the degradation of pollutants in aqueous and gas phase / Víctor Manuel Menéndez Flores." Hannover : Technische Informationsbibliothek und Universitätsbibliothek Hannover, 2010. http://d-nb.info/1004000391/34.

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42

Korzekwa, Dominika. "Filling in gaps of Drosophila melanogaster urate degradation metabolic pathway using metabolomics approaches : towards the core metabolome of the fruit fly." Thesis, University of Glasgow, 2016. http://theses.gla.ac.uk/7706/.

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The primary goal of systems biology is to integrate complex omics data, and data obtained from traditional experimental studies in order to provide a holistic understanding of organismal function. One way of achieving this aim is to generate genome-scale metabolic models (GEMs), which contain information on all metabolites, enzyme-coding genes, and biochemical reactions in a biological system. Drosophila melanogaster GEM has not been reconstructed to date. Constraint-free genome-wide metabolic model of the fruit fly has been reconstructed in our lab, identifying gaps, where no enzyme was identified and metabolites were either only produced or consume. The main focus of the work presented in this thesis was to develop a pipeline for efficient gap filling using metabolomics approaches combined with standard reverse genetics methods, using 5-hydroxyisourate hydrolase (5-HIUH) as an example. 5-HIUH plays a role in urate degradation pathway. Inability to degrade urate can lead to inborn errors of metabolism (IEMs) in humans, including hyperuricemia. Based on sequence analysis Drosophila CG30016 gene was hypothesised to encode 5- HIUH. CG30016 knockout flies were examined to identify Malpighian tubules phenotype, and shortened lifespan might reflect kidney disorders in hyperuricemia in humans. Moreover, LC-MS analysis of mutant tubules revealed that CG30016 is involved in purine metabolism, and specifically urate degradation pathway. However, the exact role of the gene has not been identified, and the complete method for gap filling has not been developed. Nevertheless, thanks to the work presented here, we are a step closer towards the development of a gap-filling pipeline in Drosophila melanogaster GEM. Importantly, the areas that require further optimisation were identified and are the focus of future research. Moreover, LC-MS analysis confirmed that tubules rather than the whole fly were more suitable for metabolomics analysis of purine metabolism. Previously, Dow/Davies lab has generated the most complete tissue-specific transcriptomic atlas for Drosophila – FlyAtlas.org, which provides data on gene expression across multiple tissues of adult fly and larva. FlyAtlas revealed that transcripts of many genes are enriched in specific Drosophila tissues, and that it is possible to deduce the functions of individual tissues within the fly. Based on FlyAtlas data, it has become clear that the fly (like other metazoan species) must be considered as a set of tissues, each 2 with its own distinct transcriptional and functional profile. Moreover, it revealed that for about 30% of the genome, reverse genetic methods (i.e. mutation in an unknown gene followed by observation of phenotype) are only useful if specific tissues are investigated. Based on the FlyAtlas findings, we aimed to build a primary tissue-specific metabolome of the fruit fly, in order to establish whether different Drosophila tissues have different metabolomes and if they correspond to tissue-specific transcriptome of the fruit fly (FlyAtlas.org). Different fly tissues have been dissected and their metabolome elucidated using LC-MS. The results confirmed that tissue metabolomes differ significantly from each other and from the whole fly, and that some of these differences can be correlated to the tissue function. The results illustrate the need to study individual tissues as well as the whole organism. It is clear that some metabolites that play an important role in a given tissue might not be detected in the whole fly sample because their abundance is much lower in comparison to other metabolites present in all tissues, which prevent the detection of the tissue-specific compound.

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43

Gade, Prabhavathi. "Investigation of Volatile Products from Wood Pyrolysis." TopSCHOLAR®, 2010. http://digitalcommons.wku.edu/theses/1076.

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In this research we are following the thermo-chemical degradation of wood in the absence of oxygen. The objectives are to evaluate the influence of heating rates on pyrolysis products obtained from wood pyrolysis and to evaluate the influence of acid pre-treatment on pyrolysis products. Depending on the wood heating rates, pyrolysis can be categorized as Flash pyrolysis, Fast pyrolysis, and Slow pyrolysis. We have evaluated the volatile products obtained at different heating rates and the volatile products obtained from sulfuric acid pre-treatment by using gas chromatography- mass spectrometry (GC-MS). We have also performed thermo-gravimetric analysis (TGA) of raw wood samples and sulfuric acid pre-treated wood samples of Yellow Pine to determine the changes in weight in relation to change in temperature. Our results indicated that by using the Flash, Fast, and Slow heating rates, the overall volatile products obtained from wood pyrolysis (i.e. the overall list of all the compounds obtained from different temperature ranges in wood pyrolysis by using different heating rates) were the same, but the volatile products obtained at different temperature ranges like Room temperature-300°C, 300°C - 400°C, and 400°C -500°C in Flash, Fast, and Slow pyrolysis were different. Most of the volatile products obtained from the pyrolysis of untreated wood were phenols. Our results also indicated that the pretreatment of wood with sulfuric acid alters the charcoal properties and releases gaseous products including furan derivatives that are useful as fuels or fuel additives. The sulfuric acid (10%) pretreatment of wood followed by slow pyrolysis produced maximum yield of charcoal, indicated by the lowest mass % decrease of 58.234. The production of furan derivatives increased by using sulfuric acid pre-treatment, which is a good improvement for the production of Furanics, the furan based biofuels. The furan based biofuels are of increasing research interest because of their significant advantages over the first generation biofuels. The thermogravimetric analysis (TGA) results indicated that the acid pre-treatment altered the decomposition rate of pyrolysis and lowered the onset of temperature for decomposition. The use of thermal degradation of plants for creating chemicals and fuels is seeing renewed interest across the globe as it is considered carbon-neutral and it uses a renewable feedstock. The information obtained from this research work will also be valued by industries, such as charcoal and activated carbon producers, which currently perform biomass pyrolysis, by allowing them to form approaches that optimize their energy use and minimize waste.

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Novikov, Yaroslav. "Development Of A High-fidelity Transient Aerothermal Model For A Helicopter Turboshaft Engine For Inlet Distortion And Engine Deterioration Simulations." Master's thesis, METU, 2012. http://etd.lib.metu.edu.tr/upload/12614389/index.pdf.

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Presented in this thesis is the development of a high-fidelity aerothermal model for GE T700 turboshaft engine. The model was constructed using thermodynamic relations governing change of flow properties across engine components, and by applying real component maps for the compressor and turbines as well as empirical relations for specific heats. Included in the model were bleed flows, turbine cooling and heat sink effects. Transient dynamics were modeled using inter-component volumes method in which mass imbalance between two engine components was used to calculate the inter-component pressure. This method allowed fast, high-accuracy and iteration-free calculation of engine states. Developed simulation model was successfully validated against previously published simulation results, and was applied in the simulation of inlet distortion and engine deterioration. Former included simulation of steady state and transient hot gas ingestion as well as transient decrease in the inlet total pressure. Engine deterioration simulations were performed for four different cases of component deterioration with parameters defining engine degradation taken from the literature. Real time capability of the model was achieved by applying time scaling of plenum volumes which allowed for larger simulation time steps at very little cost of numerical accuracy. Finally, T700 model was used to develop a generic model by replacing empirical relations for specific heats with temperature and FAR dependent curve fits, and scaling T700 turbine maps. Developed generic aerothermal model was applied to simulate steady state performance of the Lycoming T53 turboshaft engine.

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45

Rojas, de Gante Cecilia. "Effets de l'ionisation sur les materiaux polymeres : application a l'etude des transferts de masse (permeabilite et migration)." Reims, 1988. http://www.theses.fr/1988REIMS009.

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Influence de l'ionisation par irradiation electrons du polyethylene et du polypropylene sur la structure et les transferts de masse (permeabilite et migration). Etude des degagements de produits volatils

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46

Ouagne, Pierre. "Fracture property changes with oxidation and irradiation in nuclear graphites." Thesis, University of Bath, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.341675.

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47

Weidemann, Eva. "Waste incineration residues : Persistent organic pollutants in flue gas and fly ash from waste incineration." Doctoral thesis, Umeå universitet, Kemiska institutionen, 2014. http://urn.kb.se/resolve?urn=urn:nbn:se:umu:diva-92765.

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Modern societies produce large quantities of municipal solid waste (MSW), which is commonly disposed of by incineration. This has several advantages: it reduces the waste’s volume and sterilizes it while also enabling energy recovery. However, MSW incineration has some notable disadvantages, the most widely debated of which is probably the production and release of persistent organic pollutants (POP) such as polychlorinated dibenzofurans (PCDF), dibenzo-p-dioxins (PCDD), biphenyls (PCB) and naphthalenes (PCN). Of the 210 PCDF and PCDD congeners, 17 are toxic, with hormone-disrupting and carcinogenic properties. Twelve of the 209 PCB congeners and at least 2 of the 75 PCN also exhibit such properties. These POP form in the post-combustion zones of MSW incineration plants and are removed from the flue gas using filtering devices that trap them in the fly ash This thesis concerns the formation and degradation of POP in processes related to MSW incineration. The first paper describes a case study in which PCDD were forming in filters designed to remove them from flue gases, causing emission-related issues in a full-scale MSW incineration plant. It was shown that the PCDD formation was probably due to chlorophenol condensation on the filters’ surfaces. The second paper describes the validation of a cooling probe designed to prevent POP formation during high temperature (>450 °C) flue gas sampling. The results obtained also confirmed that PCDF and PCDD formation takes place at temperatures below 600 °C. In the third paper, three different fly ashes were subjected to thermal treatment under an inert atmosphere in a rotary kiln and in sealed ampoules at 400 °C. The concentrations, degrees of chlorination and congener profiles of the POP in the treated ashes and emitted gases were compared to those for the untreated ashes. The trends observed for PCDF mirrored those for PCN, while the trends for PCDD closely resembled those for PCB. The PCDF congener profiles of the kiln ash were similar regardless of the initial ash composition, suggesting that the mechanisms of PCDF formation were similar in all cases. The fourth paper describes the surface characterization of the three fly ashes studied in paper three by SEM, EDX, XPS and XRD. In addition, the thermal desorption and subsequent degradation of POP from the ashes was studied at temperatures of 300-900 °C. The composition of the gases released as the temperature increased differed between the ashes and depended on their composition. Doping experiments using isotopically labelled PCDF and PCDD suggests that PCDD desorbed at lower temperatures than PCDF. This thesis examines several problems relating to POP formation during MSW incineration, from sampling to the ultimate fate of incineration residues. The results obtained illustrate the wide range of processes that contribute to thermal POP formation and degradation during and after MSW incineration.
Förbränning av hushållssopor är en vanlig metod för att hantera ett växande avfallsproblem. Metoden har flera fördelar, såsom minskning av volym och vikt, sterilisering och energiåtervinning. Sopförbränning har dock vissa nackdelar och det mest debatterade är sannolikt utsläpp av persistenta organiska föroreningar (POPs) som polyklorerad dibensofuran (PCDF), dibenso-p-dioxin (PCDD), bifenyl (PCB) och naftalen (PCN). Det finns totalt 210 PCDF- och PCDD- kongener, med mellan ett till åtta klor på kolskelettet, varav 17 är giftiga med hormonstörande och cancerframkallande egenskaper. Även tolv av totalt 209 PCB-kongener samt minst två av totalt 75 PCN-kongener uppvisar liknande egenskaper. Dessa klorerade organiska föroreningar bildas då rökgaserna kyls ner i sopförbränningsanläggningarna och avlägsnas från rökgaserna med hjälp av filter och hamnar i flygaskan. Denna avhandling handlar om bildning och nedbrytning av POPs i sopförbränningsrelaterade processer. Den första artikeln är en fallstudie där PCDD bildas i filtren i en fullskalig sopförbränningsanläggning. Bildningen ledde till förhöjda halter organiska föroreningar i rökgaserna, vilket ledde till ökade utsläpp. Den funna bildningsvägen för PCDD i filtren befanns sannolikt bero på kondensation av klorfenoler på filterytorna. Den andra artikeln är en valideringsstudie av en kylprob avsedd att användas vid rökgasprovtagning vid hög temperatur (> 450 °C) för att undvika bildning av POPs under provtagningen. Studien bekräftade att majoriteten av PCDF- och PCDD- bildning i rökgaser från sopförbränning sker vid temperaturer under 600 °C. I den tredje artikeln berättas om behandling av tre olika flygaskor från olika sopförbränningsanläggningar. Askorna behandlades vid 400 °C i inert atmosfär i både en roterugn och i förseglade ampuller. De resulterande koncentrationerna, kloreringsgraderna och kongenprofilerna av de organiska föroreningarna jämfördes. Likheter hittades mellan PCDF och PCN, medan PCDD och PCB betedde sig på ett annat sätt. Studien fann också att PCDF kongenprofiler i aska som behandlats i roterugnen liknade varandra, oberoende av askornas sammansättning, vilket tyder på en liknande bildningsväg. För den fjärde artikeln, genomfördes ytkarakterisering (SEM, EDX, XPS och XRD) på de tre flygaskorna från artikel tre som sedan hettades upp från 30 °C till 900 °C i vacuum. Det som frigjordes på grund av uppvärmningen samt nedbrytningsprodukter från askorna studerades med hjälp av masspektrometri och infraröd spektroskopi. Studien fann att de gaser som frigjordes när temperaturen ökade skilde mellan askorna, beroende på deras sammansättning. Studien fann också att när aska dopad med isotopmärkt PCDF och PCDD utsattes för samma behandling, frigjordes PCDD vid lägre temperatur än PCDF. Denna avhandling berör flera aspekter av problematiken kring klorerade organiska föroreningar som bildas vid sopförbränning, från provtagning till hur man ska hantera flygaskan. Avhandlingen belyser även olika typer av bildning och nedbrytning av POPs i varma processer kopplade till sopförbränning.

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48

Harley, Grant L. "A GIS-based inventory of terrestrial caves in West Central Florida : implications on sensitivity, disturbance, ownership and management priority." [Tampa, Fla.] : University of South Florida, 2007. http://purl.fcla.edu/usf/dc/et/SFE0002234.

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49

Pombo, Gabriela do Vale. "Efeito da suplementação com levedura viva e levedura viva protegida sobre a digestibilidade aparente total e parâmetros fermentativos de equinos." Universidade de São Paulo, 2018. http://www.teses.usp.br/teses/disponiveis/10/10135/tde-18062018-153717/.

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O uso da suplementação com levedura viva em equinos tem sido estudado, pelo potencial de redução da produção de lactato no intestino grosso sendo relatado por alguns autores, melhora da digestibilidade aparente da proteína bruta. Porém, o uso de levedura viva protegida ainda não foi relatado para a espécie. O objetivo do trabalho foi avaliar a digestibilidade aparente dos nutrientes e parâmetros de fermentação intestinal e gástrica com a suplementação de levedura viva e levedura viva protegida em equinos em manutenção. O delineamento experimental foi o quadrado latino duplo balanceado com oito animais, quatro dietas avaliados por quatro períodos de 22 dias cada, sendo 15 dias de adaptação à dieta, 5 dias de coleta de fezes (CTF), 1 dia para coleta de conteúdo gástrico e 2 semanas de intervalo entre os períodos. As médias dos tratamentos foram comparadas através de contrastes ortogonais (C1: controle [CTR] versus levedura [LEV], levedura protegida [PROT] e levedura viva + levedura protegida [L + P]; C2: L + P versus LEV e PROT; C3: LEV versus PROT). O nível de significância do teste utilizado foi a 10%. Não foram observados efeitos para pH nas fezes, concentração sérica de fator tumoral alfa, concentrações de ácido lático e ácidos de cadeia curta nas diferentes dietas. Não foi observado significância para a digestibilidade aparente dos nutrientes da dieta quando se usou levedura viva ou protegida (P=0,0683). Houve aumento das concentrações de ácido acético com o uso de levedura no conteúdo gástrico (P=0,0082). Avaliando a técnica de coleta sugerida, a adaptação realizada para este procedimento de coleta de digesta gástrica apresentou fácil aplicabilidade, com alta tolerância pelos equinos, além de proporcionar perfeita precisão do local de coleta a ser avaliado. A levedura viva e levedura protegida não apresentam efeito quanto a degradabilidade in vitro da matéria seca e da fibra em detergente neutro (P > 0,05). A fermentação com inóculo de fezes possui maiores taxas de produção de gás quando se utiliza feno como substrato e suplementação com levedura viva (P=0,0190). Quando se utiliza de conteúdo gástrico como inóculo, a levedura protegida apresenta menor produção de gases (P=0,0484).
The use of live yeast supplementation in equines has been studied for the potential reduction of lactate production in the large intestine and is reported by some authors to improve the apparent digestibility of crude protein. However, the use of protected live yeast has not yet been reported for the species. The aim of this study was to evaluate the apparent digestibility of nutrients and parameters of intestinal and gastric fermentation with the supplementation of live yeast and protected live yeast in horses. The experimental design was the double balanced latin square with eight animals, four diets evaluated for four periods of 22 days each, being 15 days of adaptation to the diet, 5 days of collection of feces (CTF), 1 day for collection of gastric content and 2 weeks interval between periods. The treatments were compared by means of orthogonal contrasts (C1: control [CTR] versus yeast [LEV], protected yeast [PROT] and live yeast + protected yeast [L + P]; C3: LEV versus PROT). The level of significance of the test used was 10%. No effects were observed for faecal pH, serum concentration of alpha tumor factor, lactic acid concentrations and short chain acids in the different diets. It was no possible to observe a difference significance on apparent digestibility in nutrients of diets when living or protected yeast (P = 0.0683). There was an increase in acetic acid concentrations with the use of yeast in gastric contents (P = 0.0082). Evaluating the suggested collection technique, the adaptation performed for this procedure of gastric digestion was easy to apply, with high tolerance by the horses, besides providing perfect accuracy of the collection site to be evaluated. Live yeast and protected yeast have no effect on the in vitro degradability of dry matter and neutral detergent fiber (P> 0.05). Fermentation with fecal inoculum has higher rates of gas production when hay is used as a substrate and supplementation with live yeast (P = 0.0190). When gastric contents are used as the inoculum, the protected yeast presents lower gas production (P = 0.0484).

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Graw, Valerie Annemarie Martine [Verfasser]. "Interlinkages of Land Degradation, Marginality and Land Use Cover Change in Kenya : Development of an interdisciplinary framework using remote sensing and GIS / Valerie Graw." Bonn : Universitäts- und Landesbibliothek Bonn, 2015. http://d-nb.info/1080561285/34.

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Dissertations / Theses on the topic 'GPS degradation'

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