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1

van Pee, Karl-Heinz. "Halogenating Enzymes for Selective Halogenation Reactions." Current Organic Chemistry 16, no. 21 (2012): 2583–97. http://dx.doi.org/10.2174/138527212804004607.

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2

Cantillo, David, and C. Oliver Kappe. "Halogenation of organic compounds using continuous flow and microreactor technology." Reaction Chemistry & Engineering 2, no. 1 (2017): 7–19. http://dx.doi.org/10.1039/c6re00186f.

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3

Holub, Josef, Mario Bakardjiev, and Bohumil Štíbr. "Some Halogenation Reactions of nido-7,8,9,11-P2C2B7H9." Collection of Czechoslovak Chemical Communications 67, no. 6 (2002): 783–90. http://dx.doi.org/10.1135/cccc20020783.

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Halogenations of the diphosphadicarbaborane nido-7,8,9,11-P2C2B7H9 using the AlCl3/CCl4, and I2/AlCl3/C6H6 halogenation systems resulted in the formation of a mixture of mono- and disubstituted derivatives 10-X-nido-7,8,9,11-P2C2B7H8 (for X = Cl and I, yields 6 and 21%, respectively) and 5,10-X2-nido-7,8,9,11-P2C2B7H7 (for X = Cl and I, yields 57 and 46%, respectively). These results show that the halogenation under electrophilic conditions takes place at positions most distant from the P atoms, but at sites adjacent to the CH units. In contrast, the bromination with N-bromosuccinimide in CH2C
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4

Boyle, Benjamin T., Jeffrey N. Levy, Louis de Lescure, Robert S. Paton, and Andrew McNally. "Halogenation of the 3-position of pyridines through Zincke imine intermediates." Science 378, no. 6621 (2022): 773–79. http://dx.doi.org/10.1126/science.add8980.

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Pyridine halogenation reactions are crucial for obtaining the vast array of derivatives required for drug and agrochemical development. However, despite more than a century of synthetic endeavors, halogenation processes that selectively functionalize the carbon–hydrogen bond in the 3-position of a broad range of pyridine precursors remain largely elusive. We report a reaction sequence of pyridyl ring opening, halogenation, and ring closing whereby the acyclic Zincke imine intermediates undergo highly regioselective halogenation reactions under mild conditions. Experimental and computational me
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5

Ibrahim, Hasim, and Antonio Togni. "Enantioselective halogenation reactions." Chemical Communications, no. 10 (2004): 1147. http://dx.doi.org/10.1039/b317004g.

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6

Konaklieva, Monica I., Michele L. Dahl, and Edward Turos. "Halogenation reactions of epoxides." Tetrahedron Letters 33, no. 47 (1992): 7093–96. http://dx.doi.org/10.1016/s0040-4039(00)60844-4.

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7

Crespo, Lívia T. C., Mônica R. Senra, Pierre M. Esteves та Marcio C. S. de Mattos. "Tribromoisocyanuric Acid as a Green Cohalogenating Reagent: An Efficient Transformation of Alkynes into α,α-Dibromoketones and Vicinal Dibromoalkenes". Letters in Organic Chemistry 16, № 8 (2019): 627–32. http://dx.doi.org/10.2174/1570178615666180803152951.

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The co-halogenation reaction of alkynes with tri-bromoisocyanuric acid in acetic acid, followed by aqueous work-up produced α,α-di-bromoketones (44-84%), while the reaction in aqueous acetonitrile in the presence of KBr produced vicinal di-bromoalkenes (66-86%). The usefulness of the methodology was demonstrated employing green metrics for the comparison of TBCA with analogous N-halo reagents in co-halogenation reactions of alkynes.
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8

Luu, Truong Giang, Yongju Jung, and Hee-Kwon Kim. "Visible-Light-Induced Catalytic Selective Halogenation with Photocatalyst." Molecules 26, no. 23 (2021): 7380. http://dx.doi.org/10.3390/molecules26237380.

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Halide moieties are essential structures of compounds in organic chemistry due to their popularity and wide applications in many fields such as natural compounds, agrochemicals, and pharmaceuticals. Thus, many methods have been developed to introduce halides into various organic molecules. Recently, visible-light-driven reactions have emerged as useful methods of organic synthesis. Particularly, halogenation strategies using visible light have significantly improved the reaction efficiency and reduced toxicity, as well as promoted reactions under mild conditions. In this review, we have summar
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9

Lectka, T. "Stereoselective and catalyzed halogenation reactions." Tetrahedron 62, no. 30 (2006): 7149. http://dx.doi.org/10.1016/j.tet.2006.05.035.

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10

van Pée, Karl-Heinz, and Susanne Unversucht. "Biological dehalogenation and halogenation reactions." Chemosphere 52, no. 2 (2003): 299–312. http://dx.doi.org/10.1016/s0045-6535(03)00204-2.

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11

Bajec, David, Matic Grom, Damjan Lašič Jurković, et al. "A Review of Methane Activation Reactions by Halogenation: Catalysis, Mechanism, Kinetics, Modeling, and Reactors." Processes 8, no. 4 (2020): 443. http://dx.doi.org/10.3390/pr8040443.

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Methane is the central component of natural gas, which is globally one of the most abundant feedstocks. Due to its strong C–H bond, methane activation is difficult, and its conversion into value-added chemicals and fuels has therefore been the pot of gold in the industry and academia for many years. Industrially, halogenation of methane is one of the most promising methane conversion routes, which is why this paper presents a comprehensive review of the literature on methane activation by halogenation. Homogeneous gas phase reactions and their pertinent reaction mechanisms and kinetics are pre
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12

Franssen, M. C. R. "Halogenation and Oxidation Reactions with Haloperoxidases." Biocatalysis 10, no. 1-4 (1994): 87–111. http://dx.doi.org/10.3109/10242429409065220.

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13

KONAKLIEVA, M. I., M. L. DAHL, and E. TUROS. "ChemInform Abstract: Halogenation Reactions of Epoxides." ChemInform 24, no. 15 (2010): no. http://dx.doi.org/10.1002/chin.199315133.

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14

Gao, Haixiang, and Jean'ne M. Shreeve. "Recent progress in taming FOX-7 (1,1-diamino-2,2-dinitroethene)." RSC Advances 6, no. 61 (2016): 56271–77. http://dx.doi.org/10.1039/c6ra12412g.

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15

Hussein, Mohanad A., and Thanh Vinh Nguyen. "Promotion of Appel-type reactions by N-heterocyclic carbenes." Chemical Communications 55, no. 55 (2019): 7962–65. http://dx.doi.org/10.1039/c9cc02132a.

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16

Weidlich, Tomáš. "The Influence of Copper on Halogenation/Dehalogenation Reactions of Aromatic Compounds and Its Role in the Destruction of Polyhalogenated Aromatic Contaminants." Catalysts 11, no. 3 (2021): 378. http://dx.doi.org/10.3390/catal11030378.

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The effect of copper and its compounds on halogenation and dehalogenation of aromatic compounds will be discussed in the proposed article. Cu oxidized to appropriate halides is an effective halogenation catalyst not only for the synthesis of halogenated benzenes or their derivatives as desired organic fine chemicals, but is also an effective catalyst for the undesirable formation of thermodynamically stable and very toxic polychlorinated and polybrominated aromatic compounds such as polychlorinated biphenyls, dibenzo-p-dioxins and dibenzofurans accompanied incineration of waste contaminated wi
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17

Zeng, Zhigang, Xianke Sang, Bo Yuan, Minghu Wu, and Wuyuan Zhang. "Advances of Haloperoxidases-Catalyzed Green Halogenation Reactions." Chinese Journal of Organic Chemistry 41, no. 3 (2021): 959. http://dx.doi.org/10.6023/cjoc202009007.

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18

Kanters, Jacqueline, and Robert Louw. "Thermal and catalysed halogenation in combustion reactions." Chemosphere 32, no. 1 (1996): 89–97. http://dx.doi.org/10.1016/0045-6535(95)00230-8.

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19

Qu, Zheng‐Wang, Hui Zhu, and Stefan Grimme. "Mechanistic Insights for Aniline‐Catalyzed Halogenation Reactions." ChemCatChem 12, no. 21 (2020): 5369–73. http://dx.doi.org/10.1002/cctc.202000981.

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20

Stamm, Reiner, and Henning Hopf. "Polar reactions of acyclic conjugated bisallenes." Beilstein Journal of Organic Chemistry 9 (January 8, 2013): 36–48. http://dx.doi.org/10.3762/bjoc.9.5.

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The chemical behaviour of various alkyl-substituted, acyclic conjugated bisallenes in reactions involving polar intermediates and/or transition states has been investigated on a broad scale for the first time. The reactions studied include lithiation, reaction of the thus formed organolithium salts with various electrophiles (among others, allyl bromide, DMF and acetone), oxidation to cyclopentenones and epoxides, hydrohalogenation (HCl, HBr addition), halogenation (Br2 and I2 addition), and [2 + 2] cycloaddition with chlorosulfonyl isocyanate. The resulting adducts were fully characterized by
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21

Aghahosseini, Hamideh, Ali Ramazani, Farideh Gouranlou, and Sang Woo Joo. "Nanoreactors Technology in Green Organic Synthesis." Current Organic Synthesis 14, no. 6 (2017): 810–64. http://dx.doi.org/10.2174/1570179413666161008200641.

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Background: Nanoreactors technology represents a promising tool for efficient and selective organic synthesis typically under “green” and sustainable reaction conditions. These structures with generating a confined reaction environment to accommodate that both reactants and catalysts can change the reaction pathways and induce new activities and selectivities. Objective: The paper reviews literature examples in which nanoreactors were employed in various types of organic and metal catalyzed reactions including multicomponent reactions, palladium-catalyzed coupling reactions, olefin metathesis,
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22

Höfler, Georg T., Andrada But, and Frank Hollmann. "Haloperoxidases as catalysts in organic synthesis." Organic & Biomolecular Chemistry 17, no. 42 (2019): 9267–74. http://dx.doi.org/10.1039/c9ob01884k.

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23

Tyrra, W., and D. Naumann. "On pentavalent perfluoroorgano bismuth compounds." Canadian Journal of Chemistry 67, no. 11 (1989): 1949–51. http://dx.doi.org/10.1139/v89-303.

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The reactions of Bi(Rf)3 (Rf = CF3, C6F5) with a series of oxidizing halogenation reagents have been investigated. From the reactions of Bi(Rf)3 with Cl2, Br2, I2, ICl, and IF5 no oxidation to Bi(V) compounds can be detected; in all cases the Bi(III) halides and the corresponding RfX compounds are formed. Only the reaction of Bi(C6F5)3 with XeF2 yields the perfluoroorganobismuth(V) compound Bi(C6F5)3F2. Keywords: bismuth perfluoroorganic compounds, polar perfluoroorganylations, oxidation with xenon difluoride.
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24

Zaytsev, Vladimir, Ekaterina Revutskaya, Tatiana Nikanorova, et al. "An Intramolecular Diels–Alder Furan (IMDAF) Approach towards the Synthesis of Isoindolo[2,1-a]quinazolines and Isoindolo[1,2-b]quinazolines." Synthesis 49, no. 16 (2017): 3749–67. http://dx.doi.org/10.1055/s-0036-1588812.

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An efficient approach to bridged pentacyclic nitrogen heterocycles via the tandem acylation/intramolecular Diels–Alder furan (IMDAF) reaction of 2-furylquinazolinones is described. Reactions of α,β-unsaturated acid anhydrides with 2-furyl-2,3-dihydroquinazolin-4-ones give 6b,9-epoxyisoindolo[2,1-a]quinazolines in average yields. In this case, the exo-IMDAF reactions proceed with excellent diastereoselectivity giving five stereogenic centers and three new rings in one synthetic step. Isomeric 2,4a-epoxyisoindolo[1,2-b]quinazolines are obtained by one-pot, three-component condensation reactions
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25

Kumar, Rakesh, Leonard I. Wiebe, and Edward E. Knaus. "A mild and efficient methodology for the synthesis of 5-halogeno uracil nucleosides that occurs via a 5-halogeno-6-azido-5,6-dihydro intermediate." Canadian Journal of Chemistry 72, no. 9 (1994): 2005–10. http://dx.doi.org/10.1139/v94-256.

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A mild and efficient methodology for the synthesis of 5-halogeno (iodo, bromo, or chloro) uracil nucleosides has been developed. 5-Halo-2′-deoxyuridines 4a–c (84–95%), 5-halouridines 7a–c (45–95%), and 5-haloarabinouridines 8a–c (65–95%) were synthesized in good to excellent yields by the reaction of 2′-deoxyuridine (2), uridine (5), and arabinouridine (6), respectively, with iodine monochloride, or N-bromo (or chloro)succinimide, and sodium azide at 25–45 °C. These C-5 halogenation reactions proceed via a 5-halo-6-azido-5,6-dihydro intermediate (3), from which HN3 is eliminated, to yield the
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26

Kannan, Neppoliyan, Akshay R. Patil, and Arup Sinha. "Direct C–H bond halogenation and pseudohalogenation of hydrocarbons mediated by high-valent 3d metal-oxo species." Dalton Transactions 49, no. 41 (2020): 14344–60. http://dx.doi.org/10.1039/d0dt02533j.

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27

Bedford, Robin B., Jens U. Engelhart, Mairi F. Haddow, Charlotte J. Mitchell, and Ruth L. Webster. "Solvent-free aromatic C–H functionalisation/halogenation reactions." Dalton Transactions 39, no. 43 (2010): 10464. http://dx.doi.org/10.1039/c0dt00385a.

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28

Khan, Riaz, and Gita Patel. "Halogenation reactions of derivatives ofd-glucose and sucrose." Carbohydrate Research 205 (September 1990): 211–23. http://dx.doi.org/10.1016/0008-6215(90)80141-o.

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29

Sauer, Jürgen, Dieter K. Heldmann, Klaus-Jürgen Range та Manfred Zabel. "Stannylated α-pyrones: Synthesis, halogenation and destannylation reactions". Tetrahedron 54, № 42 (1998): 12807–22. http://dx.doi.org/10.1016/s0040-4020(98)00754-6.

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30

Tanner, Dennis D., Jeffrey E. Rowe, and Alan Potter. "Gas-phase atomic halogenation reactions using iodine monochloride." Journal of Organic Chemistry 51, no. 4 (1986): 457–60. http://dx.doi.org/10.1021/jo00354a008.

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31

Franssen, M. C. R. "Haloperoxidases: useful catalysts for halogenation and oxidation reactions." Catalysis Today 22, no. 3 (1994): 441–57. http://dx.doi.org/10.1016/0920-5861(94)80117-7.

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32

Qu, Zheng‐Wang, Hui Zhu, and Stefan Grimme. "Mechanistic Insights for Iodane Mediated Aromatic Halogenation Reactions." ChemCatChem 12, no. 24 (2020): 6186–90. http://dx.doi.org/10.1002/cctc.202001392.

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33

FRANSSEN, M. C. R. "ChemInform Abstract: Halogenation and Oxidation Reactions with Haloperoxidases." ChemInform 26, no. 26 (2010): no. http://dx.doi.org/10.1002/chin.199526314.

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34

Hodin, Fredrik, Hans Borén, Anders Grimvall, and Susanne Karlsson. "Formation of Chlorophenols and Related Compounds in Natural and Technical Chlorination Processes." Water Science and Technology 24, no. 3-4 (1991): 403–10. http://dx.doi.org/10.2166/wst.1991.0496.

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Surface water was halogenated by the addition of: (i) chloroperoxidase, hydrogen peroxide and chloride; (ii) hydrogen peroxide and chloride or bromide; (iii) hypochlorite. Analysis of adsorbable organic halogen (AOX), halogenated phenols and purgeable organic compounds showed that reactions (i) and (ii) produced almost the same halogenated compounds. It was also shown that active chlorine occurred as an intermedi-ate in reaction (i). Reaction (ii) implied a marked halogenation only after the addition of bromide, and this reaction was enhanced by a low pH. Existing evidence that 2,4,6-trichloro
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35

Lepšík, Martin, Martin Srnec, Drahomír Hnyk, et al. "exo-Substituent effects in halogenated icosahedral (B12H122–) and octahedral (B6H62–) closo-borane skeletons: chemical reactivity studied by experimental and quantum chemical methods." Collection of Czechoslovak Chemical Communications 74, no. 1 (2009): 1–27. http://dx.doi.org/10.1135/cccc2008189.

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The exo-substituent effects in halogenated icosahedral B12H122– (B12) and octahedral B6H62– (B6) closo-borane skeletons were studied both experimentally and theoretically. Firstly, the equilibrium geometries of exo-substituted B12 and B6 clusters were obtained using quantum chemical calculations at the MP2/def2-SVP level. A comparison with the available X-ray crystallographic data revealed a very good agreement between the theoretical and experimental values. Secondly, other descriptors of the molecular structure of these borane compounds – 11B NMR chemical shifts – were experimentally determi
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36

Tao, Yaping, Zixian Li, Yiman Zhang, kexi Sun, and Zhaojun Liu. "Determining the inherent selectivity for carbon radical hydroxylation versus halogenation with high-spin oxoiron(iv)–halide complexes: a concerted rebound step." RSC Advances 12, no. 16 (2022): 9891–97. http://dx.doi.org/10.1039/d2ra01384c.

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DFT calculation for the hydroxylation versus halogenation of propylene by [FeIV(O)(TQA)X]+ (X = F, Cl and Br) reveals that after hydrogen abstraction, halogen and oxygen rebound reactions are a synergistic process.
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37

D’Aleo, Danielle N., Sheena R. Allard, Cassandra C. Foglia, et al. "Green halogenation of aromatic heterocycles using ammonium halide and hydrogen peroxide in acetic acid solvent." Canadian Journal of Chemistry 91, no. 8 (2013): 679–83. http://dx.doi.org/10.1139/cjc-2013-0058.

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The green generation of X+ (X = Br, I) using hydrogen peroxide in aqueous acetic acid allows access to aromatic heterocyclic halides in yields and purities comparable to syntheses employing N-bromosuccinimide. In activated and unsubstituted thiophene rings, regioselectivity is quantitative for positions α to the sulfur; pyrroles also give quantitative reactions, at least initially. Deactivated rings, including furans and thiazoles, as well as thiophenes with strongly electron-withdrawing groups showed little to no reactivity under the conditions investigated. The reaction shows remarkable func
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38

Ou, Xiaobo, Guy M. Bernard, and Alexander F. Janzen. "Oxidative addition and isomerization reactions. The synthesis of cis- and trans-ArSF4Cl and cis- and trans-PhTeF4Cl." Canadian Journal of Chemistry 75, no. 12 (1997): 1878–84. http://dx.doi.org/10.1139/v97-621.

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The stereoselective synthesis and isomerization of cis- and trans-ArSF4Cl is described, where Ar = Ph, p-MeC6H4, and p--O2NC6H4. Also briefly described is the synthesis of ArSF5, cis- and trans-PhTeF4Cl, and PhTeF5. The oxidative halogenating reagent is a mixture of XeF2 and Cl−, and suitable starting compounds are ArSSAr, ArSF3, and PhTeTePh. Products were characterized by 19F, 13C, and 125Te NMR spectroscopy, and by the 37Cl/35Cl and 34S/32S isotope effects on the 19F NMR chemical shifts. A mechanism of oxidative halogenation is proposed to account for the stereoselective synthesis of cis- a
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39

Inoue, Chieri, Yumi Okamoto, Christopher J. Vavricka, Hiromasa Kiyota, and Minoru Izumi. "Synthesis of Halogenated-4-Nitrophenyl 2-deoxy-2-halogeno-pyranosides via N -Halogenosuccinimide Activated Glucal." Natural Product Communications 13, no. 1 (2018): 1934578X1801300. http://dx.doi.org/10.1177/1934578x1801300125.

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Reaction of 3,4,6-tri- O -acetyl-D-glucal with silver 4-nitrophenolate in the presence of N -iodosuccinimide and N -bromosuccinimide produced (2,6-dihalo-4-nitro)phenyl 2-halo-2-deoxy-α-D-glycopyranosides. Although bromination and iodination of the 4-nitrophenyl group could not be avoided, the resulting (2,6-dihalo-4-nitro)phenylated compounds can be used as substrates or covalent glycosidase inhibitors after deprotection. The stereoselectivity and regioselectivity of the halogenation reactions are described.
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40

Lee, Sunwoo, and Muhammad Aliyu Idris. "Recent Advances in Decarboxylative Reactions of Alkynoic Acids." Synthesis 52, no. 16 (2020): 2277–98. http://dx.doi.org/10.1055/s-0040-1707600.

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Alkynoic acids have been widely employed as alkyne and alkene sources in decarboxylative reactions. Alkynoic acid coupling leads to the formation of direct coupling products and cyclized products through sequential reactions. Moreover, homocoupling and multicomponent reactions have been developed. The decarboxylative addition of alkynoic acids generates the corresponding alkene products. A number of synthetic methods are utilized for the preparation of arylpropynoic acids including the Sonogashira coupling and the carboxylation of terminal alkynes. Recently, the use of decarboxylative halogena
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41

Guo, Shu-Ting, Peng-Fei Cui, Run-Ze Yuan, and Guo-Xin Jin. "Transition metal-mediated B(4)–H hydroxylation/halogenation of o-carboranes bearing a 2-pyridylsulfenyl ligand." Chemical Communications 57, no. 19 (2021): 2412–15. http://dx.doi.org/10.1039/d0cc08290b.

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Regioselective rhodium-induced B(4)–H hydroxylation and halogenation reactions of o-carboranes are reported. The key intermediate has been isolated. Iridium-induced B(3)/B(4)–H activation of o-carboranes has been achieved through steric control.
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42

Ríos-Lombardía, Nicolás, Joaquín García-Álvarez, and Javier González-Sabín. "One-Pot Combination of Metal- and Bio-Catalysis in Water for the Synthesis of Chiral Molecules." Catalysts 8, no. 2 (2018): 75. http://dx.doi.org/10.3390/catal8020075.

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During the last decade, the combination of different metal- and bio-catalyzed organic reactions in aqueous media has permitted the flourishing of a variety of one-pot asymmetric multi-catalytic reactions devoted to the construction of enantiopure and high added-value chemicals under mild reaction conditions (usually room temperature) and in the presence of air. Herein, a comprehensive account of the state-of-the-art in the development of catalytic networks by combining metallic and biological catalysts in aqueous media (the natural environment of enzymes) is presented. Among others, the combin
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43

Keglevich, András, László Hegedus, Lilla Péter, et al. "Anomalous Products in the Halogenation Reactions of Vinca Alkaloids." Current Organic Chemistry 20, no. 24 (2016): 2639–46. http://dx.doi.org/10.2174/1385272820666160617080202.

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44

Rojas-Buzo, Sergio, Patricia Concepción, José Luis Olloqui-Sariego, Manuel Moliner, and Avelino Corma. "Metalloenzyme-Inspired Ce-MOF Catalyst for Oxidative Halogenation Reactions." ACS Applied Materials & Interfaces 13, no. 26 (2021): 31021–30. http://dx.doi.org/10.1021/acsami.1c07496.

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45

Escalante, Jaime, Claudia Ortíz-Nava, Perla Román-Bravo, Marco A. Leyva, and Fanny A. Cabrera-Rivera. "Direct Halogenation Reactions in 2,3-Dihydro-4(1H)-quinazolinones." HETEROCYCLES 85, no. 9 (2012): 2173. http://dx.doi.org/10.3987/com-12-12473.

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46

Gopalakrishnan, Janarthanan, Ulaganathan Swarnalatha, and Sudheendra M. N. Rao. "Halogenation Reactions of Phosphiniminocyclotrithiazenes: Search for New Inorganic Heterocycles." Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry 46, no. 9 (2016): 1324–31. http://dx.doi.org/10.1080/15533174.2015.1066804.

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47

Handy, Scott. "One-Pot Halogenation-Heck Coupling Reactions in Ionic Liquids." Synlett 2006, no. 18 (2006): 3176–78. http://dx.doi.org/10.1055/s-2006-948192.

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48

Agarwal, Vinayak, Zachary D. Miles, Jaclyn M. Winter, Alessandra S. Eustáquio, Abrahim A. El Gamal, and Bradley S. Moore. "Enzymatic Halogenation and Dehalogenation Reactions: Pervasive and Mechanistically Diverse." Chemical Reviews 117, no. 8 (2017): 5619–74. http://dx.doi.org/10.1021/acs.chemrev.6b00571.

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49

Brittain, William D. G., and Steven L. Cobb. "Protecting Group-Controlled Remote Regioselective Electrophilic Aromatic Halogenation Reactions." Journal of Organic Chemistry 85, no. 11 (2020): 6862–71. http://dx.doi.org/10.1021/acs.joc.9b03322.

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Lao, Zhiqi, Huimiao Zhang та Patrick H. Toy. "Reductive Halogenation Reactions: Selective Synthesis of Unsymmetrical α-Haloketones". Organic Letters 21, № 20 (2019): 8149–52. http://dx.doi.org/10.1021/acs.orglett.9b02324.

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