Academic literature on the topic 'Heterocyclic compounds Heterocyclic compounds Ring formation (Chemistry) Nitriles'

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Journal articles on the topic "Heterocyclic compounds Heterocyclic compounds Ring formation (Chemistry) Nitriles"

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Hanusek, Jiří, and Vladimír Macháček. "Intramolecular base-catalyzed reactions involving interaction between benzene nitro groups and ortho carbon chains." Collection of Czechoslovak Chemical Communications 74, no. 5 (2009): 811–33. http://dx.doi.org/10.1135/cccc2008216.

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The review is focused on the understanding of processes involving chemical interaction between benzene nitro group and ortho carbon chain containing heteroatom (N, O, S) adjacent to the ring. In most cases these compounds undergo base-catalyzed cyclization to give heteroaromatic N-oxides that can be subsequently transformed to related heterocycles under the same conditions. However, in some cases, depending on substitution of the benzene ring, side chain or the base used, the formation of other compounds – both heterocyclic and non-heterocyclic such as nitroso and azoxy compounds, spiro Meisen
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Hemalatha, Kanagarajan, Gunabalan Madhumitha, Amir Kajbafvala, Narayanan Anupama, Rajesh Sompalle, and Selvaraj Mohana Roopan. "Function of Nanocatalyst in Chemistry of Organic Compounds Revolution: An Overview." Journal of Nanomaterials 2013 (2013): 1–23. http://dx.doi.org/10.1155/2013/341015.

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Heterocyclic motif is an important scaffold which has both industrial and pharmaceutical applications. These motifs can be prepared using wide variety of reaction conditions such as the use of expensive catalyst, toxic solvent, harsh reaction condition like the use of base, high temperature, and multistep reaction. Although various methods are involved, the chemistry arena is now shifted towards the greener way of synthesis. Nanocatalyst constitutes an important role in the green synthesis. This is because the activity of the catalyst resides in the exposed portion of the particles. By decreas
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Guan, Zong, Jan C. Namyslo, Martin H. H. Drafz, Martin Nieger, and Andreas Schmidt. "Dimerisation, rhodium complex formation and rearrangements of N-heterocyclic carbenes of indazoles." Beilstein Journal of Organic Chemistry 10 (April 10, 2014): 832–40. http://dx.doi.org/10.3762/bjoc.10.79.

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Deprotonation of indazolium salts at low temperatures gives N-heterocyclic carbenes of indazoles (indazol-3-ylidenes) which can be trapped as rhodium complexes (X-ray analysis). In the absence of Rh, the indazol-3-ylidenes spontaneously dimerize under ring cleavage of one of the N,N-bonds and ring closure to an indazole–indole spiro compound which possesses an exocyclic imine group. The E/Z isomers of the imines can be separated by column chromatography when methanol is used as eluent. We present results of a single crystal X-ray analysis of one of the E-isomers, which equilibrate in solution
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Francke, Robert. "Recent advances in the electrochemical construction of heterocycles." Beilstein Journal of Organic Chemistry 10 (December 3, 2014): 2858–73. http://dx.doi.org/10.3762/bjoc.10.303.

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Due to the fact that the major portion of pharmaceuticals and agrochemicals contains heterocyclic units and since the overall number of commercially used heterocyclic compounds is steadily growing, heterocyclic chemistry remains in the focus of the synthetic community. Enormous efforts have been made in the last decades in order to render the production of such compounds more selective and efficient. However, most of the conventional methods for the construction of heterocyclic cores still involve the use of strong acids or bases, the operation at elevated temperatures and/or the use of expens
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Bhattacharyya, Aditya. "Synthetic Routes to 1,4,5,6-Tetrahydropyrimidines: An Overview and Recent Advances." Current Organic Chemistry 23, no. 17 (2019): 1843–56. http://dx.doi.org/10.2174/1385272823666191007163310.

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Partially reduced heterocyclic compounds such as 1,4,5,6-tetrahydropyrimidines are often found to possess interesting pharmacological properties. Yet, the synthetic routes towards such systems are less developed than their fully aromatic counterparts. In this review article, the biological significance of 1,4,5,6-tetrahydropyrimidines is discussed and the existing literature reports describing various preparative routes to access 1,4,5,6-tetrahydropyrimidine derivatives have been categorically described. The focus has been expanded to present an overview of the chronological development of the
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Charushin, Valery N., and Henk C. van der Plas. "Ring transformations in reactions of heterocyclic compounds with nucleophiles. The conversion of 5-nitropyrimidine into pyridine derivatives by CH-acitve nitriles." Recueil des Travaux Chimiques des Pays-Bas 102, no. 7-8 (2010): 373–77. http://dx.doi.org/10.1002/recl.19831020708.

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Tan, Xiaojun, and Xiuhui Lu. "Ab initio study of mechanism of forming a Si-heterocyclic spiro-Sn-heterocyclic ring compound by cycloaddition reaction of Me2Si=Sn: and ethene." Progress in Reaction Kinetics and Mechanism 44, no. 2 (2019): 114–21. http://dx.doi.org/10.1177/1468678319825898.

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X2Si=Sn: (X = H, Me, F, Cl, Br, Ph, Ar, etc.) are a new chemical species. The cycloaddition reactions of X2Si=Sn: are a new field of stannylene chemistry. The mechanism of the cycloaddition reaction between singlet state Me2Si=Sn: and ethene has been investigated for the first time here using second-order Møller-Plesset perturbation theory together with the 6-311++G** basis set for C, H and Si atoms and the LanL2dz basis set for Sn atoms. From the potential energy profile, it could be predicted that the reaction has one dominant reaction channel. The reaction process presented is that the 5p u
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Fershtat, Leonid L., Daniil A. Chaplygin, Ivan V. Ananyev, and Nina N. Makhova. "Divergent Synthesis of Five-Membered Nitrogen Heterocycles via Cascade Reactions of 4-Arylfuroxans." Synthesis 52, no. 18 (2020): 2667–78. http://dx.doi.org/10.1055/s-0040-1707393.

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A novel method for the synthesis of a diverse series of functionally substituted five-membered heterocyclic compounds via atom-economic, regio-, and diastereoselective one-pot reaction cascade was developed. This approach involves a ring opening in 4-arylfuroxans to α-oximinoarylacetonitrile oxides followed by [3+2] cycloaddition to various dipolarophiles to afford multisubstituted isoxazoles and isoxazolines. Subsequent azole–azole rearrangement of (oximino)isoxazolines/-isoxazoles, which can be conducted in a one-pot manner, results into functionally substituted furazans formation. The devel
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Tan, Xiaojun, and Xiuhui Lu. "Ab initio study of the mechanism of formation of a spiro-Sn-heterocyclic ring compound by the cycloaddition reaction of H2C=Sn: and ethylene." Journal of the Serbian Chemical Society 84, no. 3 (2019): 293–301. http://dx.doi.org/10.2298/jsc180603072t.

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X2C=Sn: (X = H, Me, F, Cl, Br, Ph, Ar?) are new species of chemistry. The cycloaddition reactions of X2C=Sn: is a new study field of stannylene chemistry. The mechanism of cycloaddition reaction of singlet H2C=Sn: with ethylene is studied for the first time using the MP2/GENECP (C, H in 6-311++G**; Sn in LanL2dz) method in this paper. From the potential energy profile, it could be predicted that the reaction has one dominant reaction channel. The reaction rule presented is that the 5p unoccupied orbital of tin in H2C=Sn: sidewise overlaps with the bonding ? orbital of ethylene resulting in the
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Höpfl, Herbert, and Norberto Farfán. "Article." Canadian Journal of Chemistry 76, no. 12 (1998): 1853–59. http://dx.doi.org/10.1139/v98-192.

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Boron chelates obtained from salicylaldehyde and 2prime-hydroxyacetophenone azines are colored compounds with potential applications in analytical chemistry. Up to now these complexes have not been studied by X-ray crystallography, although two structures with a six- or a seven-membered chelate ring are possible. This contribution presents the X-ray analysis of 2prime-hydroxyacetophenone azine and its corresponding new mono(diphenylboron) chelate with a six-membered boron heterocyclic ring. With these data structural changes of the ligand on chelate formation and structural differences in comp
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Dissertations / Theses on the topic "Heterocyclic compounds Heterocyclic compounds Ring formation (Chemistry) Nitriles"

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Zhu, Shuguang. "Generation of 1,3-dipoles containing carbon, nitrogen, sulphur and phosphorus." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1997. http://www.collectionscanada.ca/obj/s4/f2/dsk2/tape16/PQDD_0008/NQ34250.pdf.

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姚大源 and Tai-yuen Yue. "Cycloaddition reactions of 2-vinylchromones." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1992. http://hub.hku.hk/bib/B31210661.

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Abás, Prades Sònia. "Isocyanide as a key functional group for the synthesis of biologically active compounds." Doctoral thesis, Universitat de Barcelona, 2018. http://hdl.handle.net/10803/586039.

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The distinctive reactivity of isocyanides has been recognised as an advantageous characteristic for the formation of heterocyclic compounds. In the present manuscript new synthetic possibilities are explored involving the isocyanide group as the key point for the development of new reactions that allow the access to unpublished compounds. In particular, some of them show very promising pharmacological properties. According to the different final products accessed, the pharmacological studies and the resulting publications, this dissertation has been classified into six sections. Synthesis of
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"Studies on the construction of O-heterocycles from carbohydrates via 1,3-dipolar cycloaddition." Chinese University of Hong Kong, 1994. http://library.cuhk.edu.hk/record=b5887280.

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by Fung Wing-chuen.<br>Thesis (M.Phil.)--Chinese University of Hong Kong, 1994.<br>Includes bibliographical references (leaves 57-59).<br>Abstract --- p.i<br>Acknowledgments --- p.ii<br>Biography --- p.iii<br>Abbreviation --- p.v-vi<br>Chapter 1. --- Introduction<br>Chapter 1.1 --- Natural O-heterocycles --- p.1<br>Chapter 1.2 --- Methods for the construction of O-heterocycles --- p.5<br>Chapter 1.3 --- Intramolecular nitrone cycloaddition in the construction of O-heterocycles --- p.9<br>Chapter 2. --- Results and discussion<br>Chapter 2.1 --- Introduction --- p.12<br>Chapter 2.2 --- S
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Song, Eunho Krafft Marie E. "Ring-closing metathesis for the synthesis of carbocyclic and heterocyclic intramolecular Baylis-Hillman adducts." Diss., 2005. http://etd.lib.fsu.edu/theses/available/etd-05062005-172529.

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Thesis (M.S.)--Florida State University, 2005.<br>Advisor: Dr. Marie E. Krafft, Florida State University, College of Arts and Sciences, Dept. of Chemistry and Biochemistry. Title and description from dissertation home page (viewed Sept. 19, 2005). Document formatted into pages; contains 147 pages. Includes bibliographical references.
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"Studies on the construction of heterocycles from carbohydrates via intramolecular cyclization." 1998. http://library.cuhk.edu.hk/record=b6073081.

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by Yong-li Zhong.<br>Thesis (Ph.D.)--Chinese University of Hong Kong, 1998.<br>Includes bibliographical references (p. 234-246).<br>Electronic reproduction. Hong Kong : Chinese University of Hong Kong, [2012] System requirements: Adobe Acrobat Reader. Available via World Wide Web.<br>Mode of access: World Wide Web.
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Li, Yang. "Tandem intramolecular photocycloaddition-retro-Mannich fragmentation as a route to indole and oxindole." Thesis, 2012. http://hdl.handle.net/1957/28312.

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Irradiation of a tryptamine linked through its side-chain nitrogen to an alkylidene malonate residue results in an intramolecular [2 + 2] cycloaddition to the indole 2,3-double bond. The resultant cyclobutane undergoes spontaneous retro-Mannich fission to produce a spiro[indoline-3,3-pyrrolenine] with relative configuration defined by the orientation of substituents in the transient cyclobutane. The novel tandem intramolecular photocycloaddition- retro-Mannich (TIPCARM) sequence leads to a spiropyrrolidine which is poised to undergo a second retro-Mannich fragmentation [TIPCA(RM)₂] that expels
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Books on the topic "Heterocyclic compounds Heterocyclic compounds Ring formation (Chemistry) Nitriles"

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Zugrăvescu, Ion. Cicloadiții 3+2 dipolare. Editura Academiei Republicii Socialiste România, 1987.

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Ring nitrogen and key biomolecules: The biochemistry of N-heterocycles. Kluwer Academic, 1998.

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Boger, Dale L. Hetero Diels-Alder methodology in organic synthesis. Academic Press, 1987.

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Boger, Dale L. Hetero Diels-Alder methodology inorganic synthesis. Academic Press, 1987.

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Y, Thebtaranonth, ed. Cyclization reactions. CRC Press, 1994.

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Synthetic applications of 1,3-dipolar cycloaddition chemistry toward heterocycles and natural products. Wiley, 2003.

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D’hooghe, Matthias, and Hyun-Joon Ha. Synthesis of 4- to 7-membered Heterocycles by Ring Expansion: Aza-, oxa- and thiaheterocyclic small-ring systems. Springer, 2015.

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D’hooghe, Matthias, and Hyun-Joon Ha. Synthesis of 4- to 7-membered Heterocycles by Ring Expansion: Aza-, oxa- and thiaheterocyclic small-ring systems. Springer, 2019.

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Ring Nitrogen Key Biomolecules. Chapman & Hall, 2001.

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Hassner, Alfred. Synthesis of Heterocycles via Cycloadditions II. Springer, 2010.

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Book chapters on the topic "Heterocyclic compounds Heterocyclic compounds Ring formation (Chemistry) Nitriles"

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"Formation of Quinoxalines from Compounds Containing a Furan Ring." In Chemistry of Heterocyclic Compounds: A Series Of Monographs. John Wiley & Sons, Inc., 2008. http://dx.doi.org/10.1002/9780470186558.ch35.

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