Academic literature on the topic 'Heterometallic Coordination Architectures'

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Journal articles on the topic "Heterometallic Coordination Architectures"

1

Saloutin, Viktor I., Yulia O. Edilova, Yulia S. Kudyakova, Yanina V. Burgart та Denis N. Bazhin. "Heterometallic Molecular Architectures Based on Fluorinated β-Diketone Ligands". Molecules 27, № 22 (2022): 7894. http://dx.doi.org/10.3390/molecules27227894.

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This review summarizes the data on the synthesis of coordination compounds containing two or more different metal ions based on fluorinated β-diketonates. Heterometallic systems are of high interest in terms of their potential use in catalysis, medicine and diagnostics, as well as in the development of effective sensor devices and functional materials. Having a rich history in coordination chemistry, fluorinated β-diketones are well-known ligands generating a wide variety of heterometallic complexes. In this context, we focused on both the synthetic approaches to β-dicarbonyl ligands with addi
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2

Andruh, Marius. "Binuclear complexes as tectons in designing supramolecular solid-state architectures." Pure and Applied Chemistry 77, no. 10 (2005): 1685–706. http://dx.doi.org/10.1351/pac200577101685.

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Oligonuclear complexes as well as coordination polymers with various network topologies can be obtained by using homo- or heterobinuclear complexes as starting materials. These building blocks are stable complexes, where the metal ions are held together by compartmental ligands, or alkoxo-bridged Cu(II) species. The binuclear nodes can be connected through appropriate exo-dentate ligands, or through metal-containing anions (e.g., [M(CN)6]3-, M = CrIII, FeIII, CoIII). A rich variety of 3d-3d and 3d-4f heterometallic complexes, with interesting architectures and topologies of the spin carriers,
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3

Zigon, Nicolas, Nathalie Kyritsakas, and Mir Wais Hosseini. "Molecular tectonics: heterometallic coordination networks based on a Pt(ii) organometallic metallatecton." Dalton Transactions 44, no. 32 (2015): 14204–7. http://dx.doi.org/10.1039/c5dt02404h.

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4

Kang, Yi-Fan, Ping Liu, Chao Yuan, Lin Cui, Yang Liu, and Yao-Yu Wang. "An intriguing 4d–4f heterometallic coordination polymer with 1D pseudo-nanotube architectures." Inorganic Chemistry Communications 36 (October 2013): 4–7. http://dx.doi.org/10.1016/j.inoche.2013.07.006.

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5

Han, Lizhi, Longyi Jin, Enbo Wang, and Zhongmin Su. "Synthesis and characterization of two isostructural 3d–4f coordination compounds based on pyridine-2,6-dicarboxylic acid and 4,4′-bipyridine." Acta Crystallographica Section C Structural Chemistry 75, no. 6 (2019): 723–27. http://dx.doi.org/10.1107/s2053229619006004.

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The design and synthesis of 3d–4f heterometallic coordination polymers have attracted much interest due to the intriguing diversity of their architectures and topologies. Pyridine-2,6-dicarboxylic acid (H2pydc) has a versatile coordination mode and has been used to construct multinuclear and heterometallic compounds. Two isostructural centrosymmetric 3d–4f coordination compounds constructed from pyridine-2,6-dicarboxylic acid and 4,4′-bipyridine (bpy), namely 4,4′-bipyridine-1,1′-diium diaquabis(μ2-pyridine-2,6-dicarboxylato)tetrakis(pyridine-2,6-dicarboxylato)bis[4-(pyridin-4-yl)pyridinium]co
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6

Xu, Bo, Senwen Yuan, Xiutao Zhang, and Cuncheng Li. "A Yb(III)–Zn(II) heterometallic coordination polymer with interesting three-fold 1D pseudo-nanotube architectures." Journal of Molecular Structure 1068 (June 2014): 53–57. http://dx.doi.org/10.1016/j.molstruc.2014.03.058.

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7

Zhao, Jiong-Peng, Bo-Wen Hu, Xiao-Feng Zhang, et al. "One Pot Synthesis of Heterometallic 3d−3d Azide Coordination Architectures: Effect of the Single-Ion Anisotropy." Inorganic Chemistry 49, no. 24 (2010): 11325–32. http://dx.doi.org/10.1021/ic101089n.

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8

Moutier, F., A. M. Khalil, S. A. Baudron, and C. Lescop. "Gleaned snapshots on the road to coordination polymers: heterometallic architectures based on Cu(i) metallaclips and 2,2′-bis-dipyrrin metalloligands." Chemical Communications 56, no. 72 (2020): 10501–4. http://dx.doi.org/10.1039/d0cc04862c.

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The assembly of binuclear Cu(i) metallaclips with 2,2′-bis-dipyrrin based metalloligands affords recurrent π-stacked compact tetranuclear metallacycles organizing into discrete or infinite architectures.
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9

Santanni, Fabio, Laura Chelazzi, Lorenzo Sorace, Grigore A. Timco, and Roberta Sessoli. "Structural and Magnetic Properties of the {Cr(pybd)3[Cu(cyclen)]2}(BF4)4 Heteronuclear Complex." Crystals 13, no. 6 (2023): 901. http://dx.doi.org/10.3390/cryst13060901.

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Heterotopic ligands containing chemically different binding centers are appealing candidates for obtaining heteronuclear metal complexes. By exploiting this strategy, it is possible to introduce different paramagnetic centers characterized by specific anisotropic magnetic properties that make them distinguishable when weakly magnetically coupled. This molecular approach has great potential to yield multi-spin adducts capable of mimicking logical architectures necessary for quantum information processing (QIP), i.e., quantum logic gates. A possible route for including a single-ion magnetic cent
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10

Artizzu, Flavia, Luca Pilia, Angela Serpe, et al. "Anion-Induced Structural Diversity and Optical Chromism in a Series of Cyano-Bridged Heterometallic 3d-4f Coordination Polymers." Molecules 28, no. 6 (2023): 2871. http://dx.doi.org/10.3390/molecules28062871.

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The self-assembly reaction of the neutral dicyano-bis(1,10-phenanthroline) iron(II) complex with lanthanide ions (Ln = Eu(III), Gd(III), Er(III)) provided two different classes of heterometallic cyano-bridged 3d-4f architectures depending on the nature of the counteranion, irrespective of the size of the 4f metal ion. Tetranuclear oligomers with a squared Fe2Ln2 core were isolated when using nitrate salts, whereas unusual 1D polymeric chains were obtained when resorting to triflate salts under the same synthetic conditions. It is shown that the different structural motifs have a remarkable imp
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