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Journal articles on the topic 'Hexaphyrins'

Author: Grafiati

Published: 24 May 2025

Last updated: 31 July 2025

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1

Mori, Hirotaka, Masaaki Suzuki, Woojae Kim, Jong Min Lim, Dongho Kim та Atsuhiro Osuka. "5,20-Bis(α-oligothienyl)-substituted [26]hexaphyrins possessing electronic circuits strongly perturbed by meso-oligothienyl substituents". Chemical Science 6, № 3 (2015): 1696–700. http://dx.doi.org/10.1039/c4sc03394a.

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A series of [26]hexaphyrins(1.1.1.1.1.1) bearing two α-oligothienyl substituents at 5,20-positions have been synthesised and are shown to have a dumbbell hexaphyrin conformation, to which the α-oligothienyl groups are linked to form an acyclic helix-like conjugated network.

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2

Lopes, Susana M. M., Marta Pineiro, and Teresa M. V. D. Pinho e Melo. "Corroles and Hexaphyrins: Synthesis and Application in Cancer Photodynamic Therapy." Molecules 25, no. 15 (2020): 3450. http://dx.doi.org/10.3390/molecules25153450.

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Corroles and hexaphyrins are porphyrinoids with great potential for diverse applications. Like porphyrins, many of their applications are based on their unique capability to interact with light, i.e., based on their photophysical properties. Corroles have intense absorptions in the low-energy region of the uv-vis, while hexaphyrins have the capability to absorb light in the near-infrared (NIR) region, presenting photophysical features which are complementary to those of porphyrins. Despite the increasing interest in corroles and hexaphyrins in recent years, the full potential of both classes o

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3

Sinha, Avisikta, and Mangalampalli Ravikanth. "Phenothiazine-Embedded Hexaphyrins." Organic Letters 24, no. 6 (2022): 1335–40. http://dx.doi.org/10.1021/acs.orglett.1c04374.

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4

Yadav, Bharti, and Mangalampalli Ravikanth. "Bis-(Fluorene)-Embedded Hexaphyrins." Journal of Organic Chemistry 87, no. 5 (2022): 2543–50. http://dx.doi.org/10.1021/acs.joc.1c02488.

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5

Suzuki, Masaaki, and Atsuhiro Osuka. "Cross-Bridging Reaction of 5,20-Diethynyl Substituted Hexaphyrins to Vinylene-Bridged Hexaphyrins." Journal of the American Chemical Society 129, no. 3 (2007): 464–65. http://dx.doi.org/10.1021/ja067102v.

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6

Rath, Harapriya, Naoki Aratani, Jong Min Lim, et al. "Bis-rhodium hexaphyrins: metalation of [28]hexaphyrin and a smooth Hückel aromatic–antiaromatic interconversion." Chemical Communications, no. 25 (2009): 3762. http://dx.doi.org/10.1039/b905859a.

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7

Lim, Jong Min, Karthik Ganesan, Young Mo Sung, Alagar Srinivasan, Tavarekere K. Chandrashekar, and Dongho Kim. "Photophysical properties of bridged core-modified hexaphyrins: conjugational perturbation of thiophene bridges." Chem. Commun. 50, no. 33 (2014): 4358–60. http://dx.doi.org/10.1039/c4cc00309h.

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8

Fliegl, Heike, Dage Sundholm, Stefan Taubert, and Fabio Pichierri. "Aromatic Pathways in Twisted Hexaphyrins." Journal of Physical Chemistry A 114, no. 26 (2010): 7153–61. http://dx.doi.org/10.1021/jp1021517.

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9

Oh, Juwon, Hirotaka Mori, Young Mo Sung, Woojae Kim, Atsuhiro Osuka та Dongho Kim. "Switchable π-electronic network of bis(α-oligothienyl)-substituted hexaphyrins between helical versus rectangular circuit". Chemical Science 7, № 3 (2016): 2239–45. http://dx.doi.org/10.1039/c5sc04263a.

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The switching phenomena of conformation with π-electronic network through deprotonation–protonation processes were investigated by employing a series of 5,20-bis(α-oligothienyl) substituted hexaphyrins(1.1.1.1.1.1).

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10

Higashino, Tomohiro, Mitsunori Inoue, and Atsuhiro Osuka. "SinglyN-Fused Möbius Aromatic [28]Hexaphyrins(1.1.1.1.1.1)." Journal of Organic Chemistry 75, no. 22 (2010): 7958–61. http://dx.doi.org/10.1021/jo1018156.

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11

Suzuki, Masaaki, and Atsuhiro Osuka. "Improved Synthesis ofmeso-Aryl-Substituted [26]Hexaphyrins." Organic Letters 5, no. 21 (2003): 3943–46. http://dx.doi.org/10.1021/ol035650x.

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12

Ishida, Shin-ichiro, Tomohiro Higashino, Shigeki Mori, et al. "Diprotonated [28]Hexaphyrins(1.1.1.1.1.1): Triangular Antiaromatic Macrocycles." Angewandte Chemie 126, no. 13 (2014): 3495–99. http://dx.doi.org/10.1002/ange.201400301.

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13

Higashino, Tomohiro, Jong Min Lim, Takahiro Miura, et al. "Möbius Antiaromatic Bisphosphorus Complexes of [30]Hexaphyrins." Angewandte Chemie International Edition 49, no. 29 (2010): 4950–54. http://dx.doi.org/10.1002/anie.201001765.

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14

Alonso, Mercedes, Balazs Pinter, Paul Geerlings, and Frank De Proft. "Metalated Hexaphyrins: From Understanding to Rational Design." Chemistry - A European Journal 21, no. 49 (2015): 17631–38. http://dx.doi.org/10.1002/chem.201502894.

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15

Alonso, Mercedes, Balazs Pinter, Paul Geerlings, and Frank De Proft. "Metalated Hexaphyrins: From Understanding to Rational Design." Chemistry - A European Journal 21, no. 49 (2015): 17525. http://dx.doi.org/10.1002/chem.201504169.

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16

Higashino, Tomohiro, Jong Min Lim, Takahiro Miura, et al. "Möbius Antiaromatic Bisphosphorus Complexes of [30]Hexaphyrins." Angewandte Chemie 122, no. 29 (2010): 5070–74. http://dx.doi.org/10.1002/ange.201001765.

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17

Ishida, Shin-ichiro, Tomohiro Higashino, Shigeki Mori, et al. "Diprotonated [28]Hexaphyrins(1.1.1.1.1.1): Triangular Antiaromatic Macrocycles." Angewandte Chemie International Edition 53, no. 13 (2014): 3427–31. http://dx.doi.org/10.1002/anie.201400301.

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18

Ahn, Tae Kyu, Jung Ho Kwon, Deok Yun Kim, et al. "Comparative Photophysics of [26]- and [28]Hexaphyrins(1.1.1.1.1.1): Large Two-Photon Absorption Cross Section of Aromatic [26]Hexaphyrins(1.1.1.1.1.1)." Journal of the American Chemical Society 127, no. 37 (2005): 12856–61. http://dx.doi.org/10.1021/ja050895l.

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19

Sinha, Avisikta, Ankit Kumar, and Mangalampalli Ravikanth. "Bis‐ (Dibenzothiophene) Embedded Hexaphyrins: Synthesis, Structure and Properties." Asian Journal of Organic Chemistry 10, no. 6 (2021): 1463–71. http://dx.doi.org/10.1002/ajoc.202100157.

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20

Neves, Maria G. P. M. S., Rosália M. Martins, Augusto C. Tomé, et al. "meso-Substituted expanded porphyrins: new and stable hexaphyrins." Chemical Communications, no. 4 (1999): 385–86. http://dx.doi.org/10.1039/a808952c.

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21

Suzuki, Masaaki, Ryuichiro Taniguchi, and Atsuhiro Osuka. "Doubly N-fused meso-aryl substituted hexaphyrins(1.1.1.1.1.1)." Chemical Communications, no. 23 (2004): 2682. http://dx.doi.org/10.1039/b410011e.

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22

Higashino, Tomohiro, and Atsuhiro Osuka. "2,3,17,18-Tetrahalohexaphyrins and the First Phlorin-type Hexaphyrins." Chemistry - An Asian Journal 8, no. 9 (2013): 1994–2002. http://dx.doi.org/10.1002/asia.201300474.

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23

Naoda, Koji, Young Mo Sung, Jong Min Lim, Dongho Kim, and Atsuhiro Osuka. "Cross-Conjugated Hexaphyrins and Their Bis-Rhodium Complexes." Chemistry - A European Journal 20, no. 25 (2014): 7698–705. http://dx.doi.org/10.1002/chem.201402328.

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24

Suzuki, Masaaki, Min-Chul Yoon, Deok Yun Kim, et al. "A New Entry to Doubly N-Confused [26]Hexaphyrins(1.1.1.1.1.1) from Normal [26]Hexaphyrins(1.1.1.1.1.1) through an Unprecedented Double Pyrrolic Rearrangement." Chemistry - A European Journal 12, no. 6 (2006): 1754–59. http://dx.doi.org/10.1002/chem.200501061.

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25

Alonso, Mercedes, Paul Geerlings, and Frank de Proft. "Viability of Möbius Topologies in [26]- and [28]Hexaphyrins." Chemistry - A European Journal 18, no. 35 (2012): 10916–28. http://dx.doi.org/10.1002/chem.201200511.

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26

Suzuki, Masaaki, and Atsuhiro Osuka. "Conformational Control of [26]Hexaphyrins(1.1.1.1.1.1) bymeso-Thienyl Substituents." Chemistry - A European Journal 13, no. 1 (2006): 196–202. http://dx.doi.org/10.1002/chem.200601147.

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27

Naoda, Koji, Daiki Shimizu, Jun Oh Kim, Ko Furukawa, Dongho Kim, and Atsuhiro Osuka. "Thienylquinonoidal Porphyrins and Hexaphyrins with Singlet Diradical Ground States." Chemistry - A European Journal 23, no. 37 (2017): 8969–79. http://dx.doi.org/10.1002/chem.201701355.

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28

Le Gac, Stéphane, Elsa Caytan, Vincent Dorcet, and Bernard Boitrel. "Acid–base controlled multiple conformation and aromaticity switches in tren-capped hexaphyrins." Organic & Biomolecular Chemistry 17, no. 15 (2019): 3718–22. http://dx.doi.org/10.1039/c9ob00489k.

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Upon protonation, a tren-capped hexaphyrin undergoes simple conformational exchanges between rectangular, Möbius and triangular shapes affording different aromaticities and cage environments, and ultimately leading to a host–guest complex.

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29

Cinar, Seda, Dilek Isik Tasgin, and Canan Unaleroglu. "Substituent-controlled construction of A₄B₂-hexaphyrins and A₃B-porphyrins: a mechanistic evaluation." Beilstein Journal of Organic Chemistry 19 (December 6, 2023): 1832–40. http://dx.doi.org/10.3762/bjoc.19.135.

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A substituent-dependent construction of novel A3B-porphyrins along with A4B2-hexaphyrins was realized by the reactions of N-tosylimines and meso-aryl-substituted tripyrranes in the presence of Cu(OTf)2 as the catalyst. The reaction mechanism of the presented method was studied on model reactions by electrospray-ionization time-of-flight (HRESI–TOF) mass spectral analysis in a timely manner. The analytical results indicated that the observed azafulvene-ended di- and tripyrrolic intermediates are responsible for the formation of porphyrinogen and hexaphyrinogen forms.

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30

Misra, Rajneesh, Rajeev Kumar, Tavarekere K. Chandrashekar та Bhawani S. Joshi. "26π Aromatic Core-Modified Hexaphyrins: Syntheses, Characterization, and Structural Diversities". Journal of Organic Chemistry 72, № 4 (2007): 1153–60. http://dx.doi.org/10.1021/jo061861e.

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31

Neves, Maria G. P. M. S., Rosalia M. Martins, Augusto C. Tome, et al. "ChemInform Abstract: meso-Substituted Expanded Porphyrins: New and Stable Hexaphyrins." ChemInform 30, no. 26 (2010): no. http://dx.doi.org/10.1002/chin.199926114.

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32

Higashino, Tomohiro, and Atsuhiro Osuka. "ChemInform Abstract: 2,3,17,18-Tetrahalohexaphyrins and the First Phlorin-Type Hexaphyrins." ChemInform 45, no. 2 (2013): no. http://dx.doi.org/10.1002/chin.201402106.

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33

Plamont, Rémi, Teodor Silviu Balaban, and Gabriel Canard. "Straightforward Syntheses That Avoid Scrambling of meso -Substituted [28]Hexaphyrins." European Journal of Organic Chemistry 2017, no. 3 (2017): 593–99. http://dx.doi.org/10.1002/ejoc.201601342.

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34

Pushpan, S. K., and T. K. Chandrashekar. "Aromatic core-modified expanded porphyrinoids with meso-aryl substitutents." Pure and Applied Chemistry 74, no. 11 (2002): 2045–55. http://dx.doi.org/10.1351/pac200274112045.

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Porphyrins are the most widespread of all prosthetic groups found in Nature. The ubiquity of their functions in Nature led researchers around the globe to focus their attention on these highly colored macrocycles. The interdisciplinary interest generated by porphyrins resulted in the syntheses of modified porphyrins, which can be put to a variety of uses in medicine and industry. A brief overview of the synthetic methodologies resulting in the formation of aromatic meso-aryl-substituted core-modified aromatic heterocyclic ring-inserted expanded porphyrinoids like sapphyrins, smaragdyrins, ruby

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35

Xue, Songlin, Daiki Kuzuhara, Naoki Aratani, and Hiroko Yamada. "Substituent Effect on Structures of Hexaphyrins(2.1.2.1.2.1) and Their Metal Complexes." ECS Meeting Abstracts MA2021-01, no. 16 (2021): 742. http://dx.doi.org/10.1149/ma2021-0116742mtgabs.

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36

Sankar, Jeyaraman, Shigeki Mori, Shohei Saito, et al. "Unambiguous Identification of Möbius Aromaticity formeso-Aryl-Substituted [28]Hexaphyrins(1.1.1.1.1.1)." Journal of the American Chemical Society 130, no. 41 (2008): 13568–79. http://dx.doi.org/10.1021/ja801983d.

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37

Mori, Shigeki, and Atsuhiro Osuka. "Aromatic and Antiaromatic Gold(III) Hexaphyrins with Multiple Gold−Carbon Bonds." Journal of the American Chemical Society 127, no. 22 (2005): 8030–31. http://dx.doi.org/10.1021/ja051662x.

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38

Gossauer, Albert, Roland Charriere, Titus A. Jenny, and Hnas Rexhausen. "The Chemistry of Polyphyrins 2. Synthesis of Hexaphyrins and Their Metal Complexes." HETEROCYCLES 36, no. 7 (1993): 1561. http://dx.doi.org/10.3987/com-93-6339.

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39

Figueira, Flávio, Andreia S. F. Farinha, Augusto C. Tomé, José A. S. Cavaleiro, Filipe A. Almeida Paz, and João P. C. Tomé. "Synthesis of hexaphyrins and N-fused pentaphyrins bearing pyridin-4-ylsulfanyl groups." Journal of Porphyrins and Phthalocyanines 18, no. 08n09 (2014): 824–31. http://dx.doi.org/10.1142/s1088424614500606.

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In recent years much attention has been devoted to expanded macrocyclic chemistry. Nevertheless, while several advancements were achieved in the synthesis of novel expanded porphyrin architectures, not much has been developed in the functionalization of these macrocycles. This report shows the selective replacement of the p-fluorine atoms of meso-pentakis(pentafluorophenyl) N-fused [22]pentaphyrin and meso-hexakis(pentafluorophenyl) [26]hexaphyrin with 4-mercaptopyridine moieties, thus increasing their potential as ligands for coordination chemistry and catalysis or electronic transfer applica

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40

Rzepa, Henry S. "Lemniscular Hexaphyrins as Examples of Aromatic and Antiaromatic Double-Twist Möbius Molecules." Organic Letters 10, no. 5 (2008): 949–52. http://dx.doi.org/10.1021/ol703129z.

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41

Mori, Hirotaka, Jong Min Lim, Dongho Kim, and Atsuhiro Osuka. "Modulation of Dual Electronic Circuits of [26]Hexaphyrins Using Internal Aromatic Straps." Angewandte Chemie 125, no. 49 (2013): 13235–39. http://dx.doi.org/10.1002/ange.201308545.

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42

Xie, Yong-Shu, Keisuke Yamaguchi, Motoki Toganoh, et al. "Triply N-Confused Hexaphyrins: Near-Infrared Luminescent Dyes with a Triangular Shape." Angewandte Chemie International Edition 48, no. 30 (2009): 5496–99. http://dx.doi.org/10.1002/anie.200900596.

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43

Mori, Hirotaka, Jong Min Lim, Dongho Kim, and Atsuhiro Osuka. "Modulation of Dual Electronic Circuits of [26]Hexaphyrins Using Internal Aromatic Straps." Angewandte Chemie International Edition 52, no. 49 (2013): 12997–3001. http://dx.doi.org/10.1002/anie.201308545.

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44

Xie, Yong-Shu, Keisuke Yamaguchi, Motoki Toganoh, et al. "Triply N-Confused Hexaphyrins: Near-Infrared Luminescent Dyes with a Triangular Shape." Angewandte Chemie 121, no. 30 (2009): 5604–7. http://dx.doi.org/10.1002/ange.200900596.

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45

Fliegl, Heike, Dage Sundholm, and Fabio Pichierri. "Aromatic pathways in mono- and bisphosphorous singly Möbius twisted [28] and [30]hexaphyrins." Physical Chemistry Chemical Physics 13, no. 46 (2011): 20659. http://dx.doi.org/10.1039/c1cp21935a.

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46

Yoon, Min-Chul, Sung Cho, Masaaki Suzuki, Atsuhiro Osuka, and Dongho Kim. "Aromatic versus Antiaromatic Effect on Photophysical Properties of Conformationally Lockedtrans-Vinylene-Bridged Hexaphyrins." Journal of the American Chemical Society 131, no. 21 (2009): 7360–67. http://dx.doi.org/10.1021/ja9000536.

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47

Naoda, Koji, Hirotaka Mori, and Atsuhiro Osuka. "Selective Mono- and Bis-Au(III) Metalations of 5,10,15,20,25,30-Hexaaryl-[26]hexaphyrins(1.1.1.1.1.1)." Chemistry Letters 42, no. 1 (2013): 22–24. http://dx.doi.org/10.1246/cl.2013.22.

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48

Kim, Kil Suk, Zin Seok Yoon, Annie Butler Ricks, et al. "Temperature-Dependent Conformational Change ofmeso-Hexakis(pentafluorophenyl) [28]Hexaphyrins(1.1.1.1.1.1) into Möbius Structures†." Journal of Physical Chemistry A 113, no. 16 (2009): 4498–506. http://dx.doi.org/10.1021/jp8111205.

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49

Mori, Hirotaka, Young Mo Sung, Byung Sun Lee, Dongho Kim, and Atsuhiro Osuka. "Antiaromatic Hexaphyrins and Octaphyrins Stabilized by the Hydrogen-Bonding Interactions ofmeso-Imidazolyl Groups." Angewandte Chemie 124, no. 50 (2012): 12627–31. http://dx.doi.org/10.1002/ange.201207212.

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50

Mori, Hirotaka, Young Mo Sung, Byung Sun Lee, Dongho Kim, and Atsuhiro Osuka. "Antiaromatic Hexaphyrins and Octaphyrins Stabilized by the Hydrogen-Bonding Interactions ofmeso-Imidazolyl Groups." Angewandte Chemie International Edition 51, no. 50 (2012): 12459–63. http://dx.doi.org/10.1002/anie.201207212.

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