Academic literature on the topic 'Hexene-1'

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Journal articles on the topic "Hexene-1"

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Jewell, Deborah Rae, Lukose Mathew, and John Warkentin. "Rate constant for chlorine abstraction from CCl4 by the 5-hexenyl radical." Canadian Journal of Chemistry 65, no. 2 (1987): 311–15. http://dx.doi.org/10.1139/v87-052.

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Cyclization of the 5-hexenyl free radical to the cyclopentylmethyl free radical was used to clock chlorine atom abstraction by 5-hexenyl from carbon tetrachloride in solution. The source of 5-hexenyl radicals was 5-hexenyl[1-hydroxy-1-methyl-ethyl]diazene ((CH3)2C(OH)N=N(CH2)4CH=CH2), which decomposes thermally in CCl4 by a radical chain mechanism to afford chloroform, acetone, nitrogen, 6-chloro-1-hexene, cyclopentylchloromethane, 1-hexene, and methylcyclopentane as primary products. 6-Chloro-1-hexene is converted, in part, to a secondary product, 1,1,1,3,7-pentachloroheptane, by radical chai
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Connor, Atkinson. "1-hexenes & 1-octenes Industrial Catalysis for Polymerization: A Brief Literature Review." Chemistry Research Journal 9, no. 2 (2024): 114–20. https://doi.org/10.5281/zenodo.11282296.

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<strong>Abstract </strong> 1-hexenes and 1-octenes are in growing demand, for the production of LLDPE and LDPE. Selective 1-hexene and 1-octene production is assessed via the catalyst/ligand design of Bis(imino) pyridine-chromium(III) chloride and chromium&ndash;bis(diarylphosphino)amine catalyst systems. 1-butene, 1-hexene, 1-octene and Polyethylene yields are reported and compared. Proposing the relative stability of 5-, 7-, and 9-member rings and the relative rates of competing processes such as alkene insertion or &beta;-H elimination, control selectivity, with catalyst selection and their
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Takeuchi, Daisuke, Yoshi-aki Tojo, and Kohtaro Osakada. "Synthesis of a Ni Complex Chelated by a [2.2]Paracyclophane-Functionalized Diimine Ligand and Its Catalytic Activity for Olefin Oligomerization." Molecules 26, no. 9 (2021): 2719. http://dx.doi.org/10.3390/molecules26092719.

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A diimine ligand having two [2.2]paracyclophanyl substituents at the N atoms (L1) was prepared from the reaction of amino[2.2]paracyclophane with acenaphtenequinone. The ligand reacts with NiBr2(dme) (dme: 1,2-dimethoxyethane) to form the dibromonickel complex with (R,R) and (S,S) configuration, NiBr2(L1). The structure of the complex was confirmed by X-ray crystallography. NiBr2(L1) catalyzes oligomerization of ethylene in the presence of methylaluminoxane (MAO) co-catalyst at 10–50 °C to form a mixture of 1- and 2-butenes after 3 h. The reactions for 6 h and 8 h at 25 °C causes further incre
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Alizade, Shahla, IbragimovHikmet Jamal, AmirovFariz Ali, and AliyevFariz Ramik. "INVESTIGATION THE OLIGOMERIZATION PROCESS OF HEXENE-1." JOURNAL OF ADVANCES IN CHEMISTRY 14, no. 1 (2017): 6041–45. http://dx.doi.org/10.24297/jac.v14i1.6455.

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In article for oligomerization and alkylation processes, to obtain a useful and highly stable active catalyst, New Catalytic Complex (NCC) synthesized which is based on aluminum metal using C2H4Cl2 and this complex has shown high stability in alkylation, oligomerization processes compared to other aluminum-containing catalysts. It is difficult to regulate the molecular mass distribution of received products during oligomerization, either Intensificate the oligomerization process of olefins that is why this process take place in presence of obtaining of bimetal catalytic complex with a highly s
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Soficheva, О. S., G. E. Bekmukhamedov та D. G. Yakhvarov. "Catalytic Synthesis of Butene-1 and Hexene-1 in the Homogeneous Oligomerization of Ethylene in the Presence of Nickel Complexes Based on N-Heteroaryl-Substituted α-Diphenylphosphinoglycines". Кинетика и катализ 65, № 1 (2024): 12–21. http://dx.doi.org/10.31857/s0453881124010029.

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It has been experimentally shown that N-heteroaryl-substituted α-diphenylphosphinoglycines N-(pyrazin-2-yl)-α-diphenylphosphinoglycine, N-(pyridin-2-yl)-α-diphenylphosphinoglycine and N-(pyrimidin-2-yl)-α-diphenylphosphinoglycine obtained by the reaction of three-component condensation of diphenylphosphine, the corresponding primary amine and glyoxylic acid monohydrate are capable in combination with Ni(COD)₂, where COD is cyclooctadiene-1,5, to form active forms of catalysts for selective homogeneous dimerization and trimerization of ethylene with the formation of butene-1 and hexene-1 as the
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Sun, Yuting, Xinyu Chang, Junling Zhan, et al. "Synthesis of High-Quality TS-1 Zeolites Using Precursors of Diol-Based Polymer and Tetrapropylammonium Bromide for 1-Hexene Epoxidation." Catalysts 14, no. 12 (2024): 939. https://doi.org/10.3390/catal14120939.

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To synthesize high-quality TS-1 zeolites with enhanced catalytic performance for 1-hexene epoxidation is highly attractive for meeting the increased need for sustainable chemistry. Herein, we report that a series of framework Ti-enriched TS-1 zeolites with high crystallinity can be effectively synthesized by the hydrothermal crystallization of a composite precursor composed of diol-based polymer (containing titanium and silicon) and tetrapropylammonium bromide (TPABr). The pre-addition of a certain amount of TPABr into the polymer-based precursor plays a very positive role in maintaining the h
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Kim, Hye Yeon, Hye-Yeon Do, Saitbyul Park, et al. "2,4,6-Triphenyl-1-hexene, an Anti-Melanogenic Compound from Marine-Derived Bacillus sp. APmarine135." Marine Drugs 22, no. 2 (2024): 72. http://dx.doi.org/10.3390/md22020072.

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Although melanin protects against ultraviolet radiation, its overproduction causes freckles and senile lentigines. Recently, various biological effects of metabolites derived from marine microorganisms have been highlighted due to their potential for biological and pharmacological applications. In this study, we discovered the anti-melanogenic effect of Bacillus sp. APmarine135 and verified the skin-whitening effect. Fractions of APmarine135 showed the melanin synthesis inhibition effect in B16 melanoma cells, and 2,4,6-triphenyl-1-hexene was identified as an active compound. The melanogenic c
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Ali, Amjad, Jamile Mohammadi Moradian, Ahmad Naveed, et al. "Progress toward Polymerization Reaction Monitoring with Different Dienes: How Small Amounts of Dienes Affect ansa-Zirconocenes/Borate/Triisobutylaluminium Catalyst Systems." Polymers 14, no. 16 (2022): 3239. http://dx.doi.org/10.3390/polym14163239.

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The objectives of this work were to address the fundamental characteristics of ansa-zirconocene catalyzed E/diene copolymerization and E/diene/1-hexene and E/diene/propylene terpolymerizations, and the quantitative relationship between diene structure and polymer chain propagation rate constant in term of quantifiable catalytic active sites. One of the most important but unknown factors in olefins ansa-zirconocene complexes is the distribution of the catalyst between sites actively participating in polymer chain formation and dormant sites. A set of ethylene/dienes copolymerizations, and ethyl
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Salakhov, Ildar I., Tatiana B. Mikenas, Vladimir A. Zakharov, Valeriy G. Kozlov, Mikhail A. Matsko, and Tatiana N. Suslova. "Effect of Mono- and Multichlorinated Organic Compounds—Chlorocyclohexane and Hexachloro-p-xylene—On the Catalytic Properties of Titanium–Magnesium Catalysts in the Homo- and Copolymerization of Ethylene with 1-Hexene." International Journal of Molecular Sciences 23, no. 18 (2022): 10335. http://dx.doi.org/10.3390/ijms231810335.

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Ethylene polymerization and ethylene/1-hexene copolymerization over the titanium–magnesium catalytic system in the presence of chlorocyclohexane (CHC) and hexachloro-p-xylene (HCPX) has been studied. Modification of TMC with chlorocyclohexane and hexachloro-p-xylene increased catalyst activity severalfold for both ethylene polymerization and ethylene/1-hexene copolymerization. The key kinetic regularities of ethylene homopolymerization and ethylene/1-hexene copolymerization in the presence of CHC and HCPX were determined, and the copolymerization constants were measured. Molecular characterist
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Swart, Marthinus Rudi, Charlene Marais, and Elizabeth Erasmus. "1H NMR Analysis of the Metathesis Reaction between 1-Hexene and (E)-Anethole Using Grubbs 2nd Generation Catalyst: Effect of Reaction Conditions on (E)-1-(4-Methoxyphenyl)-1-hexene Formation and Decomposition." Catalysts 11, no. 12 (2021): 1483. http://dx.doi.org/10.3390/catal11121483.

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The metathesis of 1-hexene and (E)-anethole in the presence of Grubbs 2nd generation catalyst was monitored by in situ 1H NMR spectroscopy at different temperatures (15 °C, 25 °C, and 45 °C) and anethole mol fractions (XAnethole ≈ 0.17, 0.29, 0.5, 0.71, 0.83). Time traces confirmed the instantaneous formation of (E)-1-(4-methoxyphenyl)-1-hexene, the cross-metathesis product. A maximum concentration of (E)-1-(4-methoxyphenyl)-1-hexene is reached fairly fast (the time depending on the reaction conditions), and this is followed by a decrease in the concentration of (E)-1-(4-methoxyphenyl)-1-hexen
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Dissertations / Theses on the topic "Hexene-1"

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Mbuce, Babalwa Vuyokazi. "Hydroesterification of 1-hexene." Thesis, University of Cape Town, 2003. http://hdl.handle.net/11427/6776.

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Includes bibliographical references.<br>Hydroesterification is the carbonylation of an olefin and the successive addition of an alcohol or water yielding an ester or acid. A variety of soluble palladium complexes are widely used for the hydroesterification of olefins due to their high activity and selectivity. Branched and linear carboxylic acid esters are formed in these reactions and the regioselectivity is strongly dependent on the catalytic system and reaction conditions used. For potential industrial applications, there is a need to understand the effect of catalyst and reaction parameter
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Brown, Tiffany. "Selective hydrogenation for industrial 1-hexene purification." Master's thesis, University of Cape Town, 2005. http://hdl.handle.net/11427/5359.

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Bibliography: leaves [95]-99.<br>Previous reports identified selective catalytic hydrogenation as a possible route to the purification of industrial 1-hexene streams. Even so, reported performance has been poor and, consequently, the principal aim of this study is to adjust operating conditions so as to improve process performance to an industrially interesting level. In particular, the influence of hydrogen excess and competitive adsorbates (CO and ethanol) on overall process performance is evaluated for representative (1,5-hexadiene and 1-hexyne) impurity removal from a 1-hexene stream over
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Ramasary, Abinash. "Selective hydrogenation for industrial 1-hexene purification." Master's thesis, University of Cape Town, 2008. http://hdl.handle.net/11427/5411.

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Bibliography: leaves [95]-99.<br>Previous reports identified selective catalytic hydrogenation as a possible route to the purification of industrial 1-hexene streams. Even so, reported performance has been poor and, consequently, the principal aim of this study is to adjust operating conditions so as to improve process performance to an industrially interesting level. In particular, the influence of hydrogen excess and competitive adsorbates (CO and ethanol) on overall process performance is evaluated for representative (1,5-hexadiene and 1-hexyne) impurity removal from a 1-hexene stream over
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Mulder, Mark Henry. "Solubility of ethylene, 1-butene and 1-hexene in polyethylenes." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1999. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape8/PQDD_0020/MQ47073.pdf.

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Messinis, Antonios Marinou. "Metal imido-catalyzed ethylene and 1-hexene dimerization." Thesis, Durham University, 2013. http://etheses.dur.ac.uk/9449/.

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This thesis investigates the development of well-defined ethylene and 1-hexene dimerization pro-initiators related to the industrially important SASOL α-olefin dimerization system, which consists of WCl6/RNH2/Et3N activated by EtAlCl2. The role of Et3N in the SASOL system is to remove HCl generated from the reaction of the amine with WCl6, something that is suggestive of the possible in situ formation of tungsten imido complexes. To probe the potential role of tungsten imido species, here a range of ethylene and 1-hexene dimerization experiments are described using discrete tungsten, niobium,
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McEwan, Lynsey. "Selective catalytic hydrogenation for industrial 1-hexene purification." Master's thesis, University of Cape Town, 2010. http://hdl.handle.net/11427/10852.

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Includes abstract.<br>Includes bibliographical references (leaves 79-82).<br>Linear alpha-olefins, including 1-hexene, are used mainly as co-monomers in the production of polymers. The very low tolerance of the polymerisation catalyst to highly unsaturated impurities makes removal of these impurities from the olefin feedstock crucial. In South Africa, linear alpha-olefins are a major product of Fischer-Tropsch synthesis. A complex extractive distillation process is used to separate impurities from the product stream. A final polishing step by adsorption results in a significant loss of valuabl
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Kirova, Margarita. "The Palladium (II) –Catalyzed Homogeneous Oxidation of 1-Hexene." TopSCHOLAR®, 1992. http://digitalcommons.wku.edu/theses/1781.

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The Palladium(II)-catalyzed homogeneous oxidation of 1-hexene in methanolic medium has been studied, copper(II) chloride being used as cocatalyst. Aspects of the kinetics, mechanism and product composition were investigated in several series of oxidations involving variation of hexene concentration, oxygen partial pressure, Cu(II): Pd(II) ratio and concentration and temperature. The progress of the reaction was studied in the course of periodic sampling runs. Reaction products were identified by gas chromatography, and verified by means of GC/mass spectrometry. The expected product of 1-hexene
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Nieuwoudt, Josias Jakobus. "Mathematical Modelling of Catalytic Distillation in a 1-Hexene Hydrogenation System." Doctoral thesis, University of Cape Town, 2010. http://hdl.handle.net/11427/5425.

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Subramaniam, Chitra P. "Morphology, Crystallization and Melting Behaviors of Random Copolymers of Ethylene with 1-Butene, 1-Pentene and 1-Hexene." Diss., Virginia Tech, 1999. http://hdl.handle.net/10919/28064.

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The morphology, crystallization and melting behaviors of a series of ethylene/alpha-olefin copolymers were investigated as a function of comonomer content, comonomer type and processing conditions, including crystallization temperature and time. This was achieved by using a combination of techniques such as Nuclear Magnetic Resonance Spectroscopy (NMR), Differential Scanning Calorimetry (DSC), Atomic Force Microscopy (AFM) and Fourier Transform Infrared Spectroscopy (FTIR). The results from the thermal analysis studies clearly indicated the existence of two distinct regions of crystallization
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Mlimi, Kenneth Mpemane. "Metal modified mesoporous ZSM-5 as catalysts for the oligomerization of 1- hexene." University of Western Cape, 2021. http://hdl.handle.net/11394/8423.

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>Magister Scientiae - MSc<br>The use of diesel engines in vehicles and heavy machinery throughout the world has been slowly increasing in the past few decades. This has led to high demand for diesel and gasoline with high octane number. Diesel and gasoline are in high demand due to its qualities as fuels containing low or no sulfur and nitrogen compounds, making them environmentally friendly and the anti- knocking properties respectively. With these reasons and more, researchers have been studying processes like the catalytic oligomerization of olefins to produce synthetic fuels with aug
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Books on the topic "Hexene-1"

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Cele, Lindiwe Y. Reactions of 1-hexene over AlPOb4s-11. National Library of Canada = Bibliothèque nationale du Canada, 1992.

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Chang, Chin-Hsiang. Reaction of 1-hexene over FAPO-11 and MAPO-11. National Library of Canada, 1995.

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Hohn, Ida Marcia. Kinetic studies of the metathesis of 1-hexene using Re2O7/y-Al2O3 and the synthesis and metathesis of oxazolines. Aston University. Department of Chemical Engineering and Applied Chemistry., 1991.

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1943-, Valentinitsch Helfried, Schwarzkogler Ileane, and Steirische Landesausstellung (1987 : Riegersburg), eds. Hexen und Zauberer: Katalog der Steirischen Landesausstellung 1987, Riegersburg/Oststeiermark, 1. Mai-26. Oktober. Leykam, 1987.

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Arnold, J. Douglas. Nintendo 64: Survival Guide Volume Two. Sandwich Islands Publishing Company, 1998.

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Zuzich, Anne Helene. The mechanism of the homogeneous oxidation of 1-hexene by RhC13 and Rh(III)/Cu(II). 1986.

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Schwartz, Theo. Bibi Blocksberg, Bd.1, Hexen gibt es doch. Egmont Franz Schneider Verlag, 2002.

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Harzer-Hexen-Stieg Radwander- und Wanderkarte 1 : 30 000: Der beliebte Wanderweg von Osterode über den Brocken und das Bodetal nach Thale. Barthel Dr., 2014.

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Lovegood, Neville. Taschenkalender 2020: Dein Inoffizieller Hogwarts Kalender 2020 - Hommage Fanartikel - ein Magischer Terminkalender Mit Wochenplaner and Monatskalender 1 Woche 2 Seiten, to Do Listen, Feiertage - Softcover - Als Geschenk Für Zauberer and Hexen. Independently Published, 2019.

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Lovegood, Neville. Taschenkalender 2020: Dein Inoffizieller Hogwarts Bibliothek Kalender 2020 - Hommage Fanartikel - ein Magischer Terminkalender Mit Wochenplaner and Monatskalender 1 Woche 2 Seiten, to Do Listen, Feiertage - Softcover - Als Geschenk Für Zauberer and Hexen. Independently Published, 2019.

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Book chapters on the topic "Hexene-1"

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Lide, David R. "1-Hexene." In Handbook of Organic Solvents. CRC Press, 2024. http://dx.doi.org/10.1201/9781003575191-267.

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Vogt, J. "628 C6H12 1-Hexene." In Asymmetric Top Molecules. Part 3. Springer Berlin Heidelberg, 2011. http://dx.doi.org/10.1007/978-3-642-14145-4_50.

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Gooch, Jan W. "Poly(5-methyl-hexene-1)." In Encyclopedic Dictionary of Polymers. Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_9150.

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Vogt, J. "587 C6H4 1-Hexene-3,5-diyne." In Asymmetric Top Molecules. Part 3. Springer Berlin Heidelberg, 2011. http://dx.doi.org/10.1007/978-3-642-14145-4_9.

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Gooch, Jan W. "Poly(1-butene co ethylene co 1-hexene)." In Encyclopedic Dictionary of Polymers. Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_8995.

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Wohlfarth, Ch. "Second virial coefficient of poly(1-hexene)." In Polymer Solutions. Springer Berlin Heidelberg, 2010. http://dx.doi.org/10.1007/978-3-642-02890-8_548.

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Wohlfarth, Ch. "High pressure fluid phase equilibrium data of poly(ethylene-co-1-hexene) in ethene and 1-hexene." In Polymer Solutions. Springer Berlin Heidelberg, 2013. http://dx.doi.org/10.1007/978-3-642-32057-6_228.

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Wohlfarth, Ch. "High pressure fluid phase equilibrium data of poly(ethylene-co-1-hexene) in 2-methylpropane and 1-hexene." In Polymer Solutions. Springer Berlin Heidelberg, 2013. http://dx.doi.org/10.1007/978-3-642-32057-6_232.

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Wohlfarth, Ch. "Dielectric constant of the mixture (1) tetrachloromethane; (2) 3-hexene-1-ol." In Supplement to IV/6. Springer Berlin Heidelberg, 2008. http://dx.doi.org/10.1007/978-3-540-75506-7_388.

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Wohlfarth, Ch. "Refractive index of the mixture (1) tetrachloromethane; (2) 3-hexene-1-ol." In Refractive Indices of Pure Liquids and Binary Liquid Mixtures (Supplement to III/38). Springer Berlin Heidelberg, 2008. http://dx.doi.org/10.1007/978-3-540-75291-2_412.

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Conference papers on the topic "Hexene-1"

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Токранов, А. А., В. С. Носова, Е. О. Токранова, Р. В. Шафигулин, and А. В. Буланова. "MESOPOROUS SILICA GEL DOPED WITH CERIUM AND MODIFIED WITH SILVER AS AN EFFECTIVE CATALYST FOR SELECTIVE HYDROGENATION OF HEXYNE-1/HEXENE-1 MIXTURE." In Инновации и «зелёные» технологии : IV Всероссийская научно-практическая конференция. Crossref, 2024. http://dx.doi.org/10.34830/sounb-conf.2023.44.36.034.

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Изучено селективное гидрирование смеси углеводородов гексин-1/гексен-1 в температурном интервале 140–160 оС и давлении водорода 3 атм на катализаторе на основе мезопористого силикагеля, допированного церием и модифицированного серебром. Физико-химические характеристики катализатора изучены методами сканирующей электронной микроскопии, рентгенофлуоресцентного и рентгенодифракционного анализа, масс-спектрометрии с индуктивно связанной плазмой. Показано, что полученный катализатор является эффективным и селективным по гексену при гидрировании смеси гексин-1/гексен-1. The selective hydrogenation o
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Токранов, А. А., Д. В. Овчинникова, Е. О. Токранова, Р. В. Шафигулин, and А. В. Буланова. "STUDYING THE ADSORPTORY PROPERTIES OF MESOPOROUS SILICA GEL DOPED WITH TERBIUM AND MODIFIED WITH SILVER." In Инновации и «зелёные» технологии : IV Всероссийская научно-практическая конференция. Crossref, 2024. http://dx.doi.org/10.34830/sounb-conf.2023.65.17.033.

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Методом обращенной газовой хроматографии изучены адсорбционные свойства мезопристого силикагеля, допированного требием, модифицированного серебром (Tb-Ag/MC). Физико-химические характеристики катализатора изучены методами сканирующей электронной микроскопии, рентгенофлуоресцентного и рентгенодифракционного анализа, масс-спектрометрии с индуктивно связанной плазмой. Показано, что полученный катализатор является эффективным и селективным по гексену при гидрировании смеси гексин-1/гексен-1. The adsorption properties of mesoprist silica gel doped with trebium and modified with silver (Tb-Ag/MC) we
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Dasgupta, Chanchal. "New Materials for Protection of City Gas Distribution Networks." In ASME 2019 India Oil and Gas Pipeline Conference. American Society of Mechanical Engineers, 2019. http://dx.doi.org/10.1115/iogpc2019-4520.

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Polyethylene pipes and Steel pipes with 3LPE coatings are integral part of a citygas distribution network. These are being used in India since late 80’s. Standard MDPE and HDPE materials are Butene copolymers of Ethylene, where Butene (C4) is added as comonomer to form the side branches of linear Polyethylene (C2) chains. The research on PE materials have improved various attributes of the polymer, providing them with higher durability, pressure resistance and service life. One such development is use of Hexene (C6) as a copolymer replacing Butene (C4) to make an Ethylene Hexene copolymer prov
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WU, SIZHU, JUN YI, LISHU ZHANG, LIQUN ZHANG, and JAMES E. MARK. "THE STUDY ON THE GAS PERMEABILITIES OF THE ETHYLENE/1-HEXENE COPOLYMER BY MOLECULAR DYNAMICS SIMULATION." In Proceedings of the 9th AEPA2008. WORLD SCIENTIFIC, 2009. http://dx.doi.org/10.1142/9789814261579_0077.

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Wang, Zhiyuan, Yasuo Moriyoshi, and Tatsuya Kuboyama. "Effect of Olefin Component Mixed to Gasoline on Thermal Efficiency in EGR Diluted Conditions Using Single-Cylinder Engine." In 2023 JSAE/SAE Powertrains, Energy and Lubricants International Meeting. Society of Automotive Engineers of Japan, 2023. http://dx.doi.org/10.4271/2023-32-0084.

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&lt;div class="section abstract"&gt;&lt;div class="htmlview paragraph"&gt;In internal combustion engine development, the ongoing research can be mainly classified into two categories based on the purpose: limiting exhaust emissions and searching for alternative fuels. One of the effective approaches reduce emissions is the improvement of thermal efficiency. Certain types of alternative fuels derived from renewable resources were estimated to confirm the thermal efficiency. This study uses a single-cylinder engine added with olefin and oxygenated additive fuel, such as 1-hexene, ethanol, and ET
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Shinabuth, Dittapoom, Yuya Ohmori, Katsuki Kitajima, et al. "Effect of Olefin Content in Gasoline on Knock Characteristics and HCHO Emission in Lean Burn Spark Ignition Engine." In 2023 JSAE/SAE Powertrains, Energy and Lubricants International Meeting. Society of Automotive Engineers of Japan, 2023. http://dx.doi.org/10.4271/2023-32-0083.

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&lt;div class="section abstract"&gt;&lt;div class="htmlview paragraph"&gt;In transportation sector, higher engine thermal efficiency is currently required to solve the energy crisis and environmental problems. In spark ignition (SI) engine, lean-burn strategy is the promising approach to improve thermal efficiency and lower emissions. Olefins are the attractive component for gasoline additives, because they are more reactive and have advantage in lean limit extension. However, owing to lower research octane number (RON), it is expected to exhibit the drawback to reducing the anti-knock perform
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Singh, Navdeep, V. U. Unnikrishnan, J. N. Reddy, and Debjyoti Banerjee. "Molecular Dynamics Simulation of Interfacial Thermal Resistance of Nanofins." In ASME 2008 3rd Energy Nanotechnology International Conference collocated with the Heat Transfer, Fluids Engineering, and Energy Sustainability Conferences. ASMEDC, 2008. http://dx.doi.org/10.1115/enic2008-53049.

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In this study molecular dynamic (MD) simulations are performed to study the interfacial thermal resistance between a nanofin and a working fluid. A (5, 5) carbon nanotube (CNT) of diameter 6.78 Å and various lengths are immersed in different fluids in these analyses. For this simulation the total numbers of the fluid molecules, and the breath and the height of the cell are kept constant. In these simulations, the nanotube is placed at the centre of the cell and the matrix molecules surround the nanotube. Periodic boundary conditions are applied in all the directions. So the system under consid
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Ekoto, Isaac W., Benjamin M. Wolk, William F. Northrop, Nils Hansen, and Kai Moshammer. "Tailoring Charge Reactivity Using In-Cylinder Generated Reformate for Gasoline Compression Ignition Strategies." In ASME 2016 Internal Combustion Engine Division Fall Technical Conference. American Society of Mechanical Engineers, 2016. http://dx.doi.org/10.1115/icef2016-9458.

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In-cylinder reforming of injected fuel during an auxiliary negative valve overlap (NVO) period can be used to optimize main-cycle combustion phasing for low-load Low-Temperature Gasoline Combustion, where highly dilute mixtures can lead to poor combustion stability. The objective of this work is to examine the effects of reformate composition on main-cycle engine performance for a research gasoline. A custom alternate-fire sequence with nine pre-conditioning cycles was used to generate a common exhaust temperature and composition boundary condition for a cycle-of-interest. Performance metrics
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Singh, Navdeep, and Debjyoti Banerjee. "Effect of Polymer Chains on Heat Transfer on Nanofins." In ASME 2008 Heat Transfer Summer Conference collocated with the Fluids Engineering, Energy Sustainability, and 3rd Energy Nanotechnology Conferences. ASMEDC, 2008. http://dx.doi.org/10.1115/ht2008-56390.

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Recent experimental results show that precipitation of nanoparticles on heater surfaces can result in heat flux enhancements observed in nanofluids. These precipitated nanoparticles can potentially act as nano-fins. Hence, in this study molecular dynamic simulations are performed to study the interfacial thermal resistance between a nanofin and a working fluid. A (5, 5) carbon nanotube (CNT) of diameter 6.78 Å and various lengths are immersed in various fluids in these analyses. For this simulation the total numbers of the fluid molecules, and the breath and the height of the cell are kept con
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Stephens, Susanna, S. Cooke, Stewart Novick, Robert Bohn, and Zain Khanna. "2-METHYl-1-HEXEN-3-YNE AND 3-HEXYN-2-ONE ADVENTURES IN METHYL GROUP INTERNAL ROTATION." In 73rd International Symposium on Molecular Spectroscopy. University of Illinois at Urbana-Champaign, 2018. http://dx.doi.org/10.15278/isms.2018.fd06.

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Reports on the topic "Hexene-1"

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Naim, Michael, Gary R. Takeoka, Haim D. Rabinowitch, and Ron G. Buttery. Identification of Impact Aroma Compounds in Tomato: Implications to New Hybrids with Improved Acceptance through Sensory, Chemical, Breeding and Agrotechnical Techniques. United States Department of Agriculture, 2002. http://dx.doi.org/10.32747/2002.7585204.bard.

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The tomato, a profitable vegetable crop in both the USA and Israel, has benefited significantly from intensive breeding efforts in both countries, and elsewhere (esp. Holland). : Modem hybrids are highly prolific and resistant to a variety of major pests. They produce attractive, firm fruit for both processing and fresh-marketing. In all cases, however, reduction in flavor and aroma have occurred concomitantly with the increase in yield. Sugars-acids ratio dominate fruit taste, whereas aroma volatiles (potent at minute ppb and ppt levels) contribute to the total characteristic tomato flavor. A
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O'Neill, Sharman, Abraham Halevy, and Amihud Borochov. Molecular Genetic Analysis of Pollination-Induced Senescence in Phalaenopsis Orchids. United States Department of Agriculture, 1991. http://dx.doi.org/10.32747/1991.7612837.bard.

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The project investigated the molecular genetic and biochemical basis of pollination-induced senescence of Phalaenopsis flowers. This experimental system offered unique advantages in that senescence is strictly regulated by pollination, providing the basis to experimentally initiate and synchronize senescence in populations of flowers. The postpollination syndrome in the Phalaenopsis orchid system was dissected by investigating the temporal and spatial regulation of ACC synthase gene expression. In the stigma, pollen-borne auxin induces the expression of the auxin-regulated ACC synthase (PS-ACS
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