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Journal articles on the topic 'Hydrolyzed poly-methyl methacrylate'

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Published: 5 June 2025
Last updated: 1 August 2025

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1

Mikeš, František, and Jan Pecka. "Determination of the Tacticity of Poly(methyl methacrylate) by Hydrolysis Rate Measurements." Collection of Czechoslovak Chemical Communications 57, no. 2 (1992): 349–56. http://dx.doi.org/10.1135/cccc19920349.

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The rate of hydrolysis of poly(methyl methacrylate) increases with the content of meso(isotactic) diads in the polymer. The increase in the rate of hydrolysis of isotactic polymers is due to an intramolecular nucleophilic attack by the adjacent carboxylic ion on the carbonyl carbon atom in the ester group. An analysis of the content of sequences of variously arranged ester and carboxylic groups shows that the hydrolysis of s-poly(methyl methacrylate) is a random process, while i-poly(methyl methacrylate) is hydrolyzed gradually (by zip mechanism), starting from the carboxylate group formed by
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2

Meyvacı, Ergül, and Temel Öztürk. "Acrylonitrile-Containing Copolymer Synthesis and Magnesium Ions Adsorption of the Copolymer." Karadeniz Fen Bilimleri Dergisi 14, no. 2 (2024): 879–90. http://dx.doi.org/10.31466/kfbd.1446325.

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Poly(acrylonitrile-co-methyl methacrylate) [P(AN-MMA)] copolymer was obtained in the presence of 2,2'-azobisisobutyronitrile by using acrylonitrile and methyl methacrylate monomers via free radical polymerization. The surface of the synthesized copolymer was hydrolyzed in sodium hydroxide solution. Nitrile groups (-C≡N) on the P(AN-MMA) copolymer surface were converted into conjugated imine groups (-C=N-). Hydrolyzed poly(acrylonitrile-co-methyl methacrylate) [HP(AN-MMA)] copolymer was used in the adsorption of magnesium ions. Magnesium ion was determined with ethylenediaminetetraacetic acid i
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3

Wang, Chun, Qing Li, Jian Hua Yang, et al. "Synthesis and Characterization of Poly(Methyl Methacrylate) -Grafted-Cellulose Nanofiber." Applied Mechanics and Materials 423-426 (September 2013): 159–62. http://dx.doi.org/10.4028/www.scientific.net/amm.423-426.159.

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Poly (methyl methacrylate) (PMMA)-graft-cellulose nanofibers (CeNFs) (PMMA-g-CeNF) were synthesized by means of graft-polymerization using Azo initiator in aqueous medium. The synthesized grafted fibers were characterized by Fourier transform infrared spectroscopy (FT-IR). Then, PMMA-g-CeNF were hydrolyzed by acid hydrolysis method with different acid constant and hydrolysis time and characterized by gel permeation chromatography (GPC). Finally, PMMA-g-CeNF was characterized by thermo-gravimetric and differential thermal analyses (TG-DTA).
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4

Atul, Kumar Kushwaha, Gupta Neha, and C. Chattopadhyaya M. "Dynamics of adsorption of lead from aqueous solution by hydrolyzed poly-methyl methacrylate." Journal of Indian Chemical Society Vol. 89, Apr 2012 (2012): 523–28. https://doi.org/10.5281/zenodo.5760958.

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Environmental Chemistry Research Laboratory, Department of Chemistry, University of Allahabad, Allahabad-211 002, Uttar Pradesh, India <em>E-mail</em> : mcc46@rediffmail.com <em>Manuscript received 29 November 2010, accepted 16 August 2011</em> In present work hydrolyzed poly-methyl methacrylate (HPMMA) was tested for the removal of lead from aqueous solution. Effect of various parameters such as pH, adsorbent dose, initial Pb ion concentration, contact time and temperature on adsorption of Pb<sup>II</sup>&nbsp;onto HPMMA was investigated. Equilibrium studies show that the adsorption follows b
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5

ZHANG, Y., H. YANG, X. F. WEN, J. CHENG, and J. XIONG. "FACILE FABRICATION OF GRADIENT SURFACE BASED ON (METH)ACRYLATE COPOLYMER FILMS." Surface Review and Letters 23, no. 01 (2016): 1550080. http://dx.doi.org/10.1142/s0218625x15500808.

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This paper describes a simple and economic approach for fabrication of surface wettability gradient on poly(butyl acrylate – methyl methacrylate) [P (BA–MMA)] and poly(butyl acrylate – methyl methacrylate – 2-hydroxyethyl methacrylate) [P (BA–MMA–HEMA)] films. The (meth)acrylate copolymer [including P (BA–MMA) and P (BA–MMA–HEMA)] films are hydrolyzed in an aqueous solution of NaOH and the transformation of surface chemical composition is achieved by hydrolysis in NaOH solution. The gradient wetting properties are generated based on different functional groups on the P (BA–MMA) and P (BA–MMA–H
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6

Cheng, Shijie, Yongxian Zhao, and Yumin Wu. "Surfactant-free hybrid latexes from enzymatically hydrolyzed starch and poly(butyl acrylate-methyl methacrylate) for paper coating." Progress in Organic Coatings 118 (May 2018): 40–47. http://dx.doi.org/10.1016/j.porgcoat.2018.01.015.

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7

Jiang, Guocan, Chris Guhrenz, Anton Kirch, et al. "Highly Luminescent and Water-Resistant CsPbBr3–CsPb2Br5 Perovskite Nanocrystals Coordinated with Partially Hydrolyzed Poly(methyl methacrylate) and Polyethylenimine." ACS Nano 13, no. 9 (2019): 10386–96. http://dx.doi.org/10.1021/acsnano.9b04179.

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8

Shin, Min Jae, and Jae Sup Shin. "Two-Dimensional Estrone-Imprinted System on a Self-Assembled Monolayer." Polymers 16, no. 14 (2024): 2035. http://dx.doi.org/10.3390/polym16142035.

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In this study, a thin poly (methyl methacrylate) coating was formed on a self-assembled monolayer formed on a gold plate after chemically binding estrone. Subsequently, the estrone molecules were hydrolyzed and extracted using a solvent to form a molecular-imprinted system. The estrone-imprinted gold plate was then used as a working electrode to measure the estrone recognition ability through electrochemical methods. The recognition ability of this working electrode was evaluated for similar compounds. The selectivity factors for the seven estrone analogs were measured, and these values ranged
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9

Kun, Qiu, Song Yi-hu, Zhu Xiao-nan, and Zheng Qiang. "INFLUENCE OF PARTIALLY HYDROLYZED POLY(METHYL METHACRYLATE)/Ca(OH)2 COMPOSITES ON THERMAL STABILITY, TRANSPARENCY AND FUSION BEHAVIORS OF RIGID POLY(VINYL CHLORIDE) COMPOUNDS." Acta Polymerica Sinica 013, no. 4 (2013): 556–62. http://dx.doi.org/10.3724/sp.j.1105.2013.12317.

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10

Rodrigues, Lina D. A., Carolina R. Hurtado, Erenilda F. Macedo, Dayane B. Tada, Lília M. Guerrini, and Maurício P. Oliveira. "Colloidal properties and cytotoxicity of enzymatically hydrolyzed cationic starch-graft-poly(butyl acrylate-co-methyl methacrylate) latex by surfactant-free emulsion polymerization for paper coating application." Progress in Organic Coatings 145 (August 2020): 105693. http://dx.doi.org/10.1016/j.porgcoat.2020.105693.

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11

Moaref, Roxana, Saeed Pourmahdian, Farzad Zahedi, and Mohammad Mehdi Tehranchi. "Synthesis and characterization of nearly monodisperse superparamagnetic (Fe3O4/Poly(methyl methacrylate))-SiO2 nanoparticles with raspberry-like morphology." Polymers and Polymer Composites 30 (January 2022): 096739112210922. http://dx.doi.org/10.1177/09673911221092296.

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Uniform and nearly monodisperse superparamagnetic Fe3O4/Poly(methyl methacrylate) (core)/SiO2 (shell) nanoparticles with raspberry-like morphology and high saturation magnetization were prepared in three different steps. At first, a facile, one-shot procedure to synthesize hydrophobic Fe3O4 nanoparticles through a modified co-precipitation method was implemented. Based on the hydrophobic interactions, these nanoparticles were used directly in a mini-emulsion polymerization resulting in encapsulation with PMMA. Then, for the covering with a silica shell, the surfaces of the Fe3O4/PMMA nanospher
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12

Biermann, Christopher J., and Ramani Narayan. "Grafting of partially hydrolysed poly(methyl methacrylate) onto mesylated cellulose acetate." Polymer 28, no. 13 (1987): 2176–78. http://dx.doi.org/10.1016/0032-3861(87)90371-5.

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13

Kavda, Stefani, Emma Richardson, and Stavroula Golfomitsou. "The Use of Solvent-Gel Systems for the Cleaning of PMMA." MRS Advances 2, no. 39-40 (2017): 2179–87. http://dx.doi.org/10.1557/adv.2017.249.

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ABSTRACT This paper discusses the use of solvent-gel systems for the cleaning of poly (methyl methacrylate) (PMMA) surfaces. Aqueous polymer gel systems have been introduced to the conservation field with a particular focus on paintings, painted surfaces of wooden artefacts and stone. However, their application on plastics is very recent. Statistically designed experiments aimed to assess the efficiency and damage potential of materials constituting selected solvent-gel cleaning systems. The effect of the free solvents (deionized water, ethanol, isopropanol and petroleum ether), the hydrogel c
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14

Brinkhuis, R. H. G., and A. J. Schouten. "Thin-film behavior of poly(methyl methacrylates) (PMMA). 7. Stereocomplexation in mixed monolayers of isotactic PMMA and partially hydrolyzed syndiotactic PMMA." Macromolecules 25, no. 23 (1992): 6173–78. http://dx.doi.org/10.1021/ma00049a013.

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15

Pu, Jingyang, Na Zhang, Quyang Liu, et al. "Temperature-Triggered Release of Chromium Chloride from Nanocapsules for Controlled Burst Release and Gelation of Hydrolyzed Polyacrylamide to Plug High-Permeability Channels." SPE Journal, December 1, 2022, 1–11. http://dx.doi.org/10.2118/212872-pa.

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Summary Chromium(III) (Cr3+)-hydrolyzed polyacrylamide (HPAM) gels have been applied extensively as blocking agents for sweep efficiency improvement. Previous studies focused on delaying the gelation time and ignored the diffusion of the crosslinkers during the transportation process. The gelation time of Cr3+-HPAM was too long to be controlled. This study systematically describes a novel approach of using thermoresponsive nanocapsules to precisely control the release of Cr3+. The nanocapsules are successfully prepared by a controlled nanoprecipitation of hydrophobic polymers [poly (methyl met
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16

Jiang, Guocan, Onur Erdem, René Hübner, et al. "Mechanosynthesis of polymer-stabilized lead bromide perovskites: insight into the formation and phase conversion of nanoparticles." Nano Research, November 2, 2020. http://dx.doi.org/10.1007/s12274-020-3152-7.

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Abstract The application of polymers to replace oleylamine (OLA) and oleic acid (OA) as ligands for perovskite nanocrystals is an effective strategy to improve their stability and durability especially for the solution-based processing. Herein, we report a mechanosynthesis of lead bromide perovskite nanoparticles (NPs) stabilized by partially hydrolyzed poly(methyl methacrylate) (h-PMMA) and high-molecular-weight highly-branched poly(ethylenimine) (PEI-25K). The as-synthesized NP solutions exhibited green emission centered at 516 nm, possessing a narrow full-width at half-maximum of 17 nm and
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17

Pu, Jingyang, Ming-liang Luo, Kai Wang, et al. "Fabrication and Release Mechanism Study of a Nanocapsule Breaker for Controlling Degradation Rate of Insoluble Residue in Slickwater at Moderate-Temperature Reservoirs." SPE Journal, October 1, 2023, 1–12. http://dx.doi.org/10.2118/217981-pa.

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Summary In an ideal hydraulic fracturing project, the viscosity of hydraulic fracturing fluid (HFF) should drop to facilitate an efficient and quick fracture cleanup once proppants have been placed. Ammonium persulfate (APS) is widely used as an oxidizer breaker to degrade the insoluble residue of the HFF. However, a complex network of artificial fractures with sizes ranging from millimeters to micrometers restricts the transportation application and reaction time of standard breakers and current millimeter-sized capsule breakers. In this study, we introduce an APS nanocapsule (APS-NC) breaker
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18

sprotocols. "Biofunctionalization of PDMS-based microfluidic systems." January 18, 2015. https://doi.org/10.5281/zenodo.14013.

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Authors: Bergoi Ibarlucea, Cesar Fernández-Sánchez, Stefanie Demming, Stephanus Büttgenbach &amp; Andreu Llobera ### Abstract Three simple approaches for the selective immobilization of biomolecules on the surface of poly(dimethylsiloxane) (PDMS) microfluidic systems that do not require any specific instrumentation, are described and compared. They are based in the introduction of hydroxyl groups on the PDMS surface by direct adsorption of either polyethylene glycol (PEG) or polyvinyl alcohol (PVA) as well as by a liquid-based oxidation step. The hydroxyl groups are then silanized using a sila
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