Academic literature on the topic 'Intramolecular dehydrogenative coupling (IDC)'

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Journal articles on the topic "Intramolecular dehydrogenative coupling (IDC)"

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Kumar, Nivesh, Santanu Ghosh, Subhajit Bhunia, and Alakesh Bisai. "Synthesis of 2-oxindoles via 'transition-metal-free' intramolecular dehydrogenative coupling (IDC) of sp2 C–H and sp3 C–H bonds." Beilstein Journal of Organic Chemistry 12 (June 8, 2016): 1153–69. http://dx.doi.org/10.3762/bjoc.12.111.

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The synthesis of a variety of 2-oxindoles bearing an all-carbon quaternary center at the pseudo benzylic position has been achieved via a ‘transition-metal-free’ intramolecular dehydrogenative coupling (IDC). The construction of 2-oxindole moieties was carried out through formation of carbon–carbon bonds using KOt-Bu-catalyzed one pot C-alkylation of β-N-arylamido esters with alkyl halides followed by a dehydrogenative coupling. Experimental evidences indicated toward a radical-mediated path for this reaction.
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Saina, Shaheeda M. K., Kumar Nivesh, Maity Arindam, and Bisai Alakesh. "Synthesis of fluorinated 2-oxindoles via intramolecular dehydrogenative coupling." Journal of Indian Chemical Society Vol. 97, No. 12a, Dec 2020 (2020): 2567–78. https://doi.org/10.5281/zenodo.5655879.

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Department of Chemistry, Indian Institute of Science Education and Research Bhopal, Bhauri, Bhopal-462 066, Madhya Pradesh, India Department of Chemical Sciences, Indian Institute of Science Education and Research Kolkata, Mohanpur-741 246, Nadia, West Bengal, India <em>E-mail:</em> alakesh@iiserkol.ac.in <em>Manuscript received online 14 November 2020, revised and accepted 20 December 2020</em> An expedient synthesis of fluorinated 2-oxindoles bearing an all carbon quaternary center at the pseudobenzylic position is envisioned under &ldquo;transition metal free&rdquo; intramolecular dehydroge
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Bhunia, Subhajit, Santanu Ghosh, Dhananjay Dey, and Alakesh Bisai. "DDQ-mediated Direct Intramolecular-Dehydrogenative-Coupling (IDC): Expeditious Approach to the Tetracyclic Core of Ergot Alkaloids." Organic Letters 15, no. 10 (2013): 2426–29. http://dx.doi.org/10.1021/ol400899e.

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Henry, Martyn, Mohamed Mostafa, and Andrew Sutherland. "Recent Advances in Transition-Metal-Catalyzed, Directed Aryl C–H/N–H Cross-Coupling Reactions." Synthesis 49, no. 20 (2017): 4586–98. http://dx.doi.org/10.1055/s-0036-1588536.

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Amination and amidation of aryl compounds using a transition-metal-catalyzed cross-coupling reaction typically involves prefunctionalization or preoxidation of either partner. In recent years, a new class of transition-metal-catalyzed cross-dehydrogenative coupling reaction has been developed for the direct formation of aryl C–N bonds. This short review highlights the substantial progress made for ortho-C–N bond formation via transition-metal-catalyzed chelation-directed aryl C–H activation and gives an overview of the challenges that remain for directed meta- and para-selective reactions.1 In
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Zhang, Liang, Michael Lepper, Michael Stark, et al. "Self-assembly and coverage dependent thermally induced conformational changes of Ni(ii)-meso-tetrakis (4-tert-butylphenyl) benzoporphyrin on Cu(111)." Physical Chemistry Chemical Physics 17, no. 19 (2015): 13066–73. http://dx.doi.org/10.1039/c5cp01490e.

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Song, Xianheng, Xiang Luo, Jianfei Sheng, et al. "Copper-catalyzed intramolecular cross dehydrogenative coupling approach to coumestans from 2′-hydroxyl-3-arylcoumarins." RSC Advances 9, no. 30 (2019): 17391–98. http://dx.doi.org/10.1039/c9ra01909j.

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Wang, Pan, Shan Tang, and Aiwen Lei. "Electrochemical intramolecular dehydrogenative C–S bond formation for the synthesis of benzothiazoles." Green Chemistry 19, no. 9 (2017): 2092–95. http://dx.doi.org/10.1039/c7gc00468k.

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Firmansyah, Dikhi, Marzena Banasiewicz, and Daniel T. Gryko. "Vertically-expanded imidazo[1,2-a]pyridines and imidazo[1,5-a]pyridine via dehydrogenative coupling." Organic & Biomolecular Chemistry 13, no. 5 (2015): 1367–74. http://dx.doi.org/10.1039/c4ob02383h.

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Wen, Li-Rong, Cheng-Cheng Zhou, Ming-Zhe Zhu, Shu-Guang Xie, Wei-Si Guo, and Ming Li. "Intramolecular dehydrogenative C–S bond coupling of thioamides to form 1,3-benzothiazines under metal-free conditions." Organic & Biomolecular Chemistry 17, no. 13 (2019): 3356–60. http://dx.doi.org/10.1039/c9ob00237e.

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Tripathi, Krishna N., Devalina Ray, and Ravi P. Singh. "Pd-Catalyzed regioselective intramolecular dehydrogenative C-5 cross coupling in anN-substituted pyrrole-azole system." Organic & Biomolecular Chemistry 15, no. 47 (2017): 10082–86. http://dx.doi.org/10.1039/c7ob02676e.

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Dissertations / Theses on the topic "Intramolecular dehydrogenative coupling (IDC)"

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Hung, Pei-Yu, and 洪珮瑜. "Synthesis of Indole-Benzimidazole Scaffold Derivatives through Palladium-Catalyzed Intramolecular Cross-Dehydrogenative Coupling." Thesis, 2018. http://ndltd.ncl.edu.tw/handle/a233cq.

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碩士<br>國立中興大學<br>化學系所<br>106<br>This research has synthesized novel indole-benzimidazole derivatives via pallidium-catalyzed intramolecular cross-dehydrogenative coupling reaction. Reduction of aminoalcohol 23 with NaBH4 gave diamine 24. Under the acid catalytic conditions, 24 reacted with CH(OEt)3 to provide compound 25. Tosylate 26 was obtained by the protection of the hydroxyl group on 25. Subsequent substitution of 26 provided compound 28, which has indole-benzimidazole structure. Finally, the palladium-catalyzed intramolecular cross-dehydrogenative coupling reaction occurred to genera
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Huang, Shu-Jyun, and 黃書焌. "Palladium-Catalyzed Intramolecular Dehydrogenative Coupling Reaction—Synthesis of Bis-Benzimidazole Compounds and Their Applications in Asymmetric Catalysis." Thesis, 2019. http://ndltd.ncl.edu.tw/handle/wgbp5g.

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碩士<br>國立中興大學<br>化學系所<br>107<br>Disadvantages of synthesizing bis-heterocyclic compounds were generally required high reaction temperature or aromatic halides as starting materials. Therefore, the development of a method for synthesizing bis-indole and bis-benzimidazole compounds has been a challenge for many scientists. Novel bis-benzimidazole compound 17 was synthesized via palladium-catalyzed intramolecular dehydrogenative coupling reaction. L-Valinol was utilized as the starting material and chiral source. Chiral bis-benzimidazole compound 27 was synthesized in five steps. The palladium
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Book chapters on the topic "Intramolecular dehydrogenative coupling (IDC)"

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Manojveer, Seetharaman, and Magnus T. Johnson. "Inter- and Intramolecular Cross-Dehydrogenative Coupling of Alcohols Through the Hydrogen-Borrowing Approach." In Heterocycles via Cross Dehydrogenative Coupling. Springer Singapore, 2019. http://dx.doi.org/10.1007/978-981-13-9144-6_7.

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Lambert, Tristan H. "Synthesis of Heteroaromatics." In Organic Synthesis. Oxford University Press, 2015. http://dx.doi.org/10.1093/oso/9780190200794.003.0069.

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Peter Wipf at the University of Pittsburgh utilized (J. Org. Chem. 2013, 78, 167) an alkynol-furan Diels-Alder reaction to convert 1 into the hydroxyindole 2. An intramolecular Larock indole synthesis was employed (Angew. Chem. Int. Ed. 2013, 52, 4902) by Yanxing Jia at Peking University for the conversion of aniline 3 to tricyclic indole 4. The reaction of boronodiene 5 with nitrosobenzene to produce pyrrole 6 was reported (Chem. Commun. 2013, 49, 5414) by Bertrand Carboni at CNRS University of Rennes and Andrew Whiting at Durham University. The merger of imine 7 with propargyl amine 8 in the
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