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Dissertations / Theses on the topic 'Kinetics'

Author: Grafiati

Published: 4 June 2021

Last updated: 25 July 2025

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1

Leung, Suet-ying, and 梁雪瑩. "A study of step kinetics by kinetic Monte Carlo simulation." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2002. http://hub.hku.hk/bib/B31226322.

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2

JUNIOR, JOSE HENRIQUE NOLDIN. "THE REDUCTION KINETICS KINETICS OF SELF-REDUCING BRIQUETTES." PONTIFÍCIA UNIVERSIDADE CATÓLICA DO RIO DE JANEIRO, 2002. http://www.maxwell.vrac.puc-rio.br/Busca_etds.php?strSecao=resultado&nrSeq=3667@1.

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PONTIFÍCIA UNIVERSIDADE CATÓLICA DO RIO DE JANEIRO<br>O presente trabalho, apresenta uma análise do impacto das variáveis, temperatura, tipo de atmosfera e composição dos materiais ferrosos e carbonosos, sobre a cinética da auto- redução, em dois tipos de briquetes auto-redutores, na faixa de temperatura de 1000 à 1300 graus Celsius. É apresentado um breve histórico da ciência de redução dos óxidos de ferro, além das características relevantes dos principais processos de auto-redução e uma análise dos principais trabalhos correlatos disponíveis na literatura, procurando evidenciar o

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3

Rodway, G. H. "Interface kinetics." Thesis, University of Oxford, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.258163.

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4

Maguire, N. "Transient Kinetics." Thesis, Queen's University Belfast, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.527839.

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5

Lang, Matthew H. "Polyelectrolyte adsorption kinetics." Diss., Georgia Institute of Technology, 1994. http://hdl.handle.net/1853/5792.

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6

Morin, Bertrand. "Kinetics of quenches." Thesis, McGill University, 1993. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=41218.

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Order-disorder transitions have been studied for many years. The great number of experiments done on binary alloys makes condensed matter physics very appealing since it allows theory and experiment to progress side by side.<br>Using field theoretic methods, we study many aspects of physical systems such as binary alloys, which are taken out of thermodynamic equilibrium. In the introduction, an expose of basic notions is given. In the second chapter, we review an analytical method describing phase separation processes resulting from a critical quench. Physically, the latter phenomena could rep

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7

Whyte, Andrew Robert. "Laser photofragment kinetics." Thesis, University of Canterbury. Chemistry, 1988. http://hdl.handle.net/10092/8319.

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We report here several studies of the kinetics of reactions of free radical species in the gas phase. The radicals were produced by ultraviolet laser photolysis of stable precursor molecules in the presence of various reactant gases together with an excess of inert bath gas. The ensuing reactions were followed by means of either time-resolved laser-induced fluorescence (LIF) measurements of relative radical concentrations, or time-resolved resonance fluorescence measurements of the relative concentrations of product atoms. From the LIF measurements, bimolecular rate coefficients have been obta

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8

Lee, Khai S. "Kinetics of wetting." Thesis, Loughborough University, 2008. https://dspace.lboro.ac.uk/2134/33866.

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Wetting and de-wetting processes play an important role in many natural and technological processes. In many cases, wetting is an essential prerequisite for application, for example in paint films, crop sprays, cosmetics, pharmaceutical tablets and in preparation of suspensions. Both equilibrium and dynamic processes of wetting are important in coatings. In many industrial and medical applications, some strategies to control drop-spreading on solid surfaces are being developed. One possibility is that a surfactant, a surface-active polymer, a polyelectrolyte or their mixture are added to a liq

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9

Lin, Chuhong. "Interfacial electrochemical kinetics." Thesis, University of Oxford, 2017. http://ora.ox.ac.uk/objects/uuid:03207db0-6625-4b20-9c10-ba69ee21d8c6.

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The first two chapters in this thesis introduce the fundamental knowledge underpinning electrochemistry and numerical simulation. The rest of the thesis comprises three parts: investigation of charge transfer at the electrode-electrolyte interface; a kinetic study of electrocatalytic reactions at micro- and nano-electrodes; and the evaluation of electrochemical detection of single enzymes. In the first part the inner-sphere electron transfer is discussed under different situations where the breakage or formation of the chemical bond, the reorganization of the solvent and the influence of the e

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10

Kotchoubey, Jurij. "POLCA-T Neutron Kinetics Model Benchmarking." Thesis, KTH, Reaktorteknologi, 2015. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-176096.

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The demand for computational tools that are capable to reliably predict the behavior of a nuclear reactor core in a variety of static and dynamic conditions does inevitably require a proper qualification of these tools for the intended purposes. One of the qualification methods is the verification of the code in question. Hereby, the correct implementation of the applied model as well as its flawless implementation in the code are scrutinized. The present work concerns with benchmarking as a substantial part of the verification of the three-dimensional, multigroup neutron kinetics model employ

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11

Rivera, Díaz del Castillo Pedro Eduardo José. "Kinetics of precipitation reactions." Thesis, University of Cambridge, 2002. https://www.repository.cam.ac.uk/handle/1810/221870.

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12

Trejo-Gallardo, Jaime. "Modeling chalcopyrite leaching kinetics." Thesis, University of British Columbia, 2007. http://hdl.handle.net/2429/240.

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Chalcopyrite (CuFeS2) is the most abundant of the copper sulfides and also one of the most refractory for leaching. Several processing routes have been proposed to overcome drawbacks associated with environmental problems related to copper extraction from this mineral. Atmospheric leaching in acidic ferric sulfate is regarded as being particularly attractive over other hydrometallurgical systems. However, the challenge has been to overcome the problem of slow extraction rates due to passivity encountered at high solution potentials in this system. This highlights the need to investigate better

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13

Song, Zhiqiang. "Kinetics of emulsion polymerization." Diss., Georgia Institute of Technology, 1988. http://hdl.handle.net/1853/10148.

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14

Seddon, N. "Mercury bromide laser kinetics." Thesis, University of Hull, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.377398.

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15

Zaman, Flora. "Kinetics of enzyme models." Thesis, University of Kent, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.263701.

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16

Camplejohn, Richard Stephen. "Cell kinetics and cancer." Thesis, University of Newcastle Upon Tyne, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.327272.

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17

Mas, Elodie A. "Exploiting kinetics in nanoscience." Thesis, University of Bristol, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.440269.

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18

Rushworth, Philip John. "Quantitative asymmetric reaction kinetics." Thesis, University of Warwick, 2011. http://wrap.warwick.ac.uk/45827/.

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The comparison of catalysts for producing chiral materials is of vital importance in the improvement of reaction scope and efficacy. Here we describe a new method of analysing the kinetics of the stereodetermining steps in asymmetric reactions by performing ligand/catalyst competition experiments against an internal standard and measuring the enantiomeric excess obtained at a variety of ratios of ligand/catalyst to internal standard. From these enantiomeric excess measurements, we can establish the relative rate of reaction between the ligand/catalyst systems and the internal standard, allowin

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19

Yang, Li-yin 1952. "Crystallization kinetics of diphenylhydantoin." Thesis, The University of Arizona, 1989. http://hdl.handle.net/10150/277190.

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The crystallization kinetics of diphenylhydantoin (DPH) has been studied at constant conditions in a small mixed suspension mixed product removal (MSMPR) crystallizer. Supersaturation is created by changing the pH of a DPH solution in the crystallization vessel. Crystal size distributions (CSD's) are measured by an in situ zone sensing method. Effects of pH and supersaturation on crystallization kinetics and CSD are summarized. The effect of an additive on the crystal growth of DPH has been studied in a batch system. Avoidance of nucleation in the early stages of crystallization is essential t

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20

Henstridge, Martin Carl. "Studies in electrode kinetics." Thesis, University of Oxford, 2013. http://ora.ox.ac.uk/objects/uuid:562136fd-3a23-464e-8829-c1b37052a29a.

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This thesis is concerned with the study of electrode kinetics, which we shall examine via comparison between theory with experiment. As such the first two chapters outline the basic principles of electrochemical experiments and their simulation. First, we examine the properties of voltammetry at porous electrodes by means of both simulations and experiments. We then introduce the symmetric Marcus-Hush (SMH) model of electrode kinetics as an alternative to the empirical Butler-Volmer model. First, we examine different methods for modeling the voltammetry of kinetically inhomogeneous electroacti

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21

Sililo, Bernard Liswani. "Modelling uranium leaching kinetics." Diss., University of Pretoria, 2016. http://hdl.handle.net/2263/61336.

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The uranium price decline has negatively impacted on the uranium mining industry. This decline in price requires that uranium metallurgical processes be made to operate more efficiently. Some key parameters that influence the dissolution and kinetics of leaching uraninite (one of the main minerals from which uranium can be extracted) are pH, oxidationreduction potential and iron concentration. A good understanding of the effect these parameters have on the leach kinetics would lead to an efficient operation of metallurgical processes. The objective of this work was therefore to investiga

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22

Olinde, Lindsay. "Sediment Oxygen Demand Kinetics." Thesis, Virginia Tech, 2007. http://hdl.handle.net/10919/42437.

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Hypolimnetic oxygen diffusers increase sediment oxygen demand (SOD) and, if not accounted for in design, can further exacerbate anoxic conditions. A study using extracted sediment cores, that included both field and laboratory experiments, was performed to investigate SOD kinetics in Carvinâ s Cove Reservoir, a eutrophic water supply reservoir for Roanoke, Virginia. A bubble-plume diffuser is used in Carvinâ s Cove to replenish oxygen consumed while the reservoir is thermally stratified. The applicability of zero-order, first-order, and Monod kinetics to describe transient and steady stat

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23

Ebanks, Keira C. "Kinetics of Peptide Aggregation." Thesis, Virginia Tech, 2011. http://hdl.handle.net/10919/31830.

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The most thermodynamically stable biological structure is the cross-beta secondary structure of the "amyloid"or "prion". As a testament to its stability, the amyloid occurs naturally in 2 rare instances: as a mechanism to protect or destroy life. Pathogenic amyloids are the signature of neurological disorders such as Alzheimer's and Parkinson's disease and bovine spongiform encephalopathy (BSE), which have no effective treatments or known cures. Pathogenic amyloids appear as nanometer sized "plaques" that self-assemble over time. The plaques usually are well-organized crystalline/fibrous struc

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24

Viselgienė, Gintarė. "The kinetics of silver electrodeposition from sulfite solutions." Doctoral thesis, Lithuanian Academic Libraries Network (LABT), 2010. http://vddb.laba.lt/obj/LT-eLABa-0001:E.02~2010~D_20100623_093628-71686.

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Silver electrodeposition from sulfite electrolytes is considered to be one of the most promising processes to replace the extremely toxic traditional cyanide-based silver plating solutions with the additional advantage, that sulfite electrolytes can be successfully applied for silver deposition for micro-electro-mechanical systems (MEMSs). Mechanism of metal complexes electroreduction is an important result, especially when it may have a wide range of applications in the future. However, electrodeposition also has several shortcomings, including sulfite ion oxidation by oxygen in air and relat

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25

Setta, Feth-Allah. "Calcium carbonate and barium sulphate scale formation kinetics : a surface scale deposition kinetic model." Thesis, University of Leeds, 2013. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.595798.

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Scale formation is one of the major flow assurance problems in the water treatment and in the oil and gas sectors. Calcium carbonate (CaCO3) is the most common scale encountered in industry. Barium sulphate (BaSO4) scale is the most difficult to deal with as it is highly insoluble and requires chemical and/or physical treatments. Scale build up results in reduced water flow through pipes and could lead to an entire shutdown of installations leading to important financial losses. Nowadays, the main ways to treat and prevent scale formation are periodic squeeze treatments and/or the continuous i

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26

Zhang, Ziji. "Theoretical and computational study of coupling of soot, gas kinetics and radiation in diffusion flames using reduced mechanisms /." Digital version accessible at:, 1998. http://wwwlib.umi.com/cr/utexas/main.

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27

Boström, Fredrik. "Single-cycle kinetics for QCM biosensors for high throughput nanoparticle characterization application." Thesis, Uppsala universitet, Institutionen för biologisk grundutbildning, 2016. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-298942.

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Characterizing nanoparticles to be able to understand how they functions in the body is important for development of drugs. Furthermore with increasing number of nanoparticle product the nanotoxicity of nanoparticles is important to understand. This report is a part of the EU-project Nanoclassifier which purpose is to “develop a cost effective, high throughput screening platform for characterization of the bionanointerface and its cell-binding partners”. Single-cycle kinetic was used to determine the number of binding epitopes on polystyrene nanoparticle with transferrin corona. The number of

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28

WATKINS, JOSEPH ABRA. "SPECTRAL AND KINETIC PROPERTIES OF CHLOROBIUM THIOSULFATOPHILUM CYTOCHROME C-555 (ELECTROSTATICS, REDOX KINETICS, CIRCULAR DICHROISM)." Diss., The University of Arizona, 1986. http://hdl.handle.net/10150/183975.

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The spectral and kinetic properties of Chlorobium thiosulfatophilum cytochrome c-555 have been investigated and are compared to analogous properties of procaryotic and eucaryotic c-type cytochromes. The circular dichroism spectra are similar for c-type cytochromes of a given class and effects arising from specific amino acid substitutions are determined. The oxidation-reduction state dependence of the spectra in the near-ultraviolet region is interpreted in terms of changes in hydrogen bonding and polarity of the environment of aromatic amino acid residues in close proximity to heme iron resul

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29

Boddapati, Aparna. "Modeling cure depth during photopolymerization of multifunctional acrylates." Thesis, Georgia Institute of Technology, 2010. http://hdl.handle.net/1853/33934.

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The photopolymerization of multifunctional acrylates leads to the formation of a complex and insoluble network due to cross-linking. This characteristic is a useful property for stereolithography applications, where solid parts of the desired shape are cured using a pre-determined energy exposure profile. Traditionally, the required energy exposure is determined using a critical energy--depth of penetration, or Ec--Dp, model. The parameters Ec and Dp, are usually fit to experimental data at a specific resin composition and cure intensity. As a result, since the Ec--Dp model does not explicitly

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30

Marais, Charles Guillaume. "Thermodynamics and kinetics of sorption /." Link to the online version, 2008. http://hdl.handle.net/10019/1944.

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31

Kempen, Antoine. "Solid state phase transformation kinetics." [S.l.] : [s.n.], 2002. http://deposit.ddb.de/cgi-bin/dokserv?idn=964251191.

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32

Tacon, Geoffrey Reginald Russell. "Mathematical modelling of liver kinetics /." [St. Lucia, Qld.], 2005. http://www.library.uq.edu.au/pdfserve.php?image=thesisabs/absthe19399.pdf.

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33

Hedfors, Cecilia. "Lipase chemoselectivity - kinetics and applications." Licentiate thesis, KTH, School of Biotechnology (BIO), 2009. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-10232.

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<p> </p><p>A chemoselective catalyst is preferred in a chemical reaction where protecting groups otherwise are needed. The two lipases <em>Candida antarctica </em>lipase B and <em>Rhizomucor miehei</em> lipase showed large chemoselectivity ratios, defined as (<em>k<sub>cat</sub></em>/<em>K</em><sub>M</sub>)<sub>OH </sub>/ (<em>k<sub>cat</sub></em>/<em>K</em><sub>M</sub>)<sub>SH</sub>, in a transacylation reaction with ethyl octanoate as acyl donor and hexanol or hexanethiol as acyl acceptor (<strong>paper I</strong>). The chemoselectivity ratio of the uncatalyzed reaction was 120 in favour of

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34

Gheorghita, Ligia. "Passivation kinetics at semiconductor interfaces." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1999. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape7/PQDD_0016/NQ46347.pdf.

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35

Xia, Qi. "Gas absorption kinetics in STR's." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 2000. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape4/PQDD_0032/NQ64694.pdf.

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36

Vaidyaraman, Sundar. "Kinetics of the bosch reaction." Thesis, Georgia Institute of Technology, 1992. http://hdl.handle.net/1853/10277.

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37

Lance, Christine Marie. "Repassivation kinetics of dental amalgam." Thesis, Georgia Institute of Technology, 1992. http://hdl.handle.net/1853/19648.

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38

Ozdemir, Metin. "Morphological kinetics of facetted crystals." Diss., Georgia Institute of Technology, 1991. http://hdl.handle.net/1853/27898.

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39

Xia, Qi 1962. "Gas absorption kinetics in STR's." Thesis, McGill University, 2000. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=36732.

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Experiments were carved out in a stirred tank reactor with both two phase and three phase systems. A systematic examination of the effect of solid particles on parameters such as volumetric liquid-side mass transfer coefficient kLa, specific interfacial area a, gas holdup epsilong, bubble size dB, and average bubble residence time tau, was conducted. Both dimensional and dimensionless correlations were generated and conclusions were drawn.<br>The work was carried out in the context of the industrial experience that stirred tank reactors are widely used in both metallurgical and chemical engine

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40

Moonga, B. S. "The kinetics of protiodecarbonylation reactions." Thesis, Brunel University, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.375474.

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41

Harding, Mark S. "The kinetics of interfacial processes." Thesis, University of Oxford, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.336113.

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42

Heard, Dwayne Ellis. "Laser studies of chemical kinetics." Thesis, University of Oxford, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.258025.

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43

Till, Ulrike. "Recombination kinetics of radical pairs." Thesis, University of Oxford, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.267949.

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44

Lewis, L. A. "Oxidation kinetics of zinc vapour." Thesis, University of Manchester, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.487650.

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45

Kononova, Anna. "Memetic computing in chemical kinetics." Thesis, University of Leeds, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.531526.

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46

Demetriou, D. A. "Numerical simulations of interface kinetics." Thesis, University of Cambridge, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.598490.

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This dissertation's goal is concerned with the development and numerical study of a continuum model, that describes a variety of interface growth phenomena such as fluid displacement in porous media, crystal growth and flux-lines in type-II superconductors. The continuum model is the Quenched-Edwards-Wilkinson (QEW), which is well established in the literature and we restrict ourselves in providing a brief 'derivation' in terms of symmetry considerations. A crucial part of the model is the quenched random medium where the interface moves. The 'adequate' generation of the random background is a

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47

Suwatchara, Danu. "Experimental advances in electrode kinetics." Thesis, University of Oxford, 2013. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.639734.

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At the present, numerous kinetic theories are available to electrochemists in describing chemical reactions at the electrode. These exist in varying degree of complexity, ranging from simplistic empirical formulae to more rigorous models that account for microscopic physical phenomena pertiaining to the reactive species and their environment. However, experimental work documented in support of the validity and comparison between these theories is scarce. This is largely due to difficulty in attaining and controlling the experimental conditions where applicability of the theories break down. As

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48

Daly, P. J. "Dissolution kinetics of calcium carbonate." Thesis, University of Liverpool, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.372693.

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49

Brownless, George Peter. "The combustion kinetics of hydrofluorocarbons." Thesis, University of Leeds, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.343477.

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50

Nelson, Dorothy Caroline. "Reaction kinetics of gasless pyrotechnics." Thesis, University of Leeds, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.293701.

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