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Dissertations / Theses on the topic 'MADIX controlled radical polymerization'

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Published: 25 May 2024

Last updated: 31 July 2025

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1

Simms, Ryan W. "Living/controlled Polymerization Conducted in Aqueous Based Systems." Thesis, Kingston, Ont. : [s.n.], 2007. http://hdl.handle.net/1974/700.

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2

Miguel-Arricau, Sophie. "Corrélation structure/propriété de polymères à base d'acrylamide pour des applications en récupération assistée des hydrocarbures (RAH)." Electronic Thesis or Diss., Pau, 2022. https://theses.hal.science/tel-04010751.

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La connaissance des propriétés physico-chimiques des solutions de polymères utilisées en récupération assistée des hydrocarbures (RAH) est essentielle pour une bonne efficience du procédé. Ces travaux avaient pour but de conforter et enrichir un modèle de viscosité universelle dépendant du paramètre de recouvrement C[η] qui permet de prendre en compte l'occupation du milieu par les chaînes macromoléculaires (concentration d'enchevêtrement critique, C*, régimes dilué et semi-dilué). Les effets des microstructures, de la taille et de la composition des polymères ont été étudiés via la synthèse d

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3

Wang, Aileen Ruiling Zhu Shiping. "Diffusion-controlled atom transfer radical polymerization." *McMaster only, 2005.

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4

Mochizuki, Shuto. "Controlled radical polymerization in designed porous materials." Kyoto University, 2019. http://hdl.handle.net/2433/242535.

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5

Qi, Genggeng. "Unconventional radical miniemulsion polymerization." Diss., Atlanta, Ga. : Georgia Institute of Technology, 2008. http://hdl.handle.net/1853/26547.

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Thesis (Ph.D)--Chemical Engineering, Georgia Institute of Technology, 2009.<br>Committee Chair: Jones, Christopher W.; Committee Chair: Schork, F. Joseph; Committee Member: Koros, William J.; Committee Member: Lyon, Andrew; Committee Member: Nenes, Athanasios. Part of the SMARTech Electronic Thesis and Dissertation Collection.

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6

Yin, Meizhen. "Synthesis and controlled radical polymerization of multifunctional monomers." Doctoral thesis, Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2004. http://nbn-resolving.de/urn:nbn:de:swb:14-1091453146703-47835.

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Multifunctional monomers on the basis of acryl- and methacryl derivatives were synthesized and different protective groups were used. After polymerization the protective groups were removed by different methods. Various initiators for the NMP of the monomers were synthesized and the reaction conditions were optimized. The results showed that NMP was not a suitable method for multifunctional acryl- and methacryl derivatives to achieve well-defined homopolymers, although it was successful for control of polymerization of styrene and block copolymerization of multifunctional acryl- and methacryl

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7

Heredia, Karina Lynn. "Synthesis of polymer bioconjugates using controlled radical polymerization." Diss., Restricted to subscribing institutions, 2008. http://proquest.umi.com/pqdweb?did=1583873071&sid=37&Fmt=2&clientId=1564&RQT=309&VName=PQD.

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8

Minaux, Eric. "Controlled radical polymerization at pressures up to 2000 bar." Doctoral thesis, [S.l.] : [s.n.], 2001. http://deposit.ddb.de/cgi-bin/dokserv?idn=962677035.

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9

Carlmark, Anna. "Complex Macromolecular Architectures by Atom Transfer Radical Polymerization." Doctoral thesis, KTH, Fibre and Polymer Technology, 2004. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-3740.

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<p>Controlled radical polymerization has proven to be a viableroute to obtain polymers with narrow polydispersities (PDI's)and controlled molecular weights under simple reactionconditions. It also offers control over the chain-]ends of thesynthesized polymer. Atom transfer radical polymerization(ATRP) is the most studied and utilized of these techniques. Inthis study ATRP has been utilized as a tool to obtain differentcomplex macromolecular structures.</p><p>In order to elaborate a system for which a multitude ofchains can polymerize in a controlled manner and in closeproximity to one another,

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10

Aksakal, Resat. "Functional polymers via Cu-mediated radical polymerization." Thesis, Queen Mary, University of London, 2018. http://qmro.qmul.ac.uk/xmlui/handle/123456789/36215.

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This work reports the investigation of Cu-mediated polymerization systems and its limits, in order to obtain functional branched polymers, in particular star-shaped and graft-shaped polymers. A novel initiator structure has allowed developing a new approach to synthesise sequence controlled multiblock star polymers via Cu-mediated reversible deactivation radical polymerization (RDRP) in water. This technique allows the preparation of pentablock star shaped polymers in just under 90 minutes of reaction time. The obtained polymers had a good agreement between theoretical and experimental molecul

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11

Aran, Bengi. "Polymerization And Characterization Of Methylmethacrylate By Atom Transfer Radical Polymerization." Master's thesis, METU, 2004. http://etd.lib.metu.edu.tr/upload/12605042/index.pdf.

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In this work, methylmethacrylate, MMA was polymerized by ATRP method to obtain low molecular weight living polymers. The initiator was p-toluenesulfonylchloride and catalyst ligand complex system were CuCl-4,4&rsquo<br>dimethyl 2,2&rsquo<br>bipyridine. Polymers with controlled molecular weight were obtained. The polymer chains were shown by NMR investigation to be mostly syndiotactic. The molecular weight and molecular weight distribution of some polymer samples were measured by GPC method. The K and a constants in [h]=K Ma equation were measured as 9.13x10-5 and 0.74, respectively. FT-IR a

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12

Özyürek, Zeynep. "Thermoresponsive Glycopolymers via Controlled Radical Polymerization (RAFT) for Biomolecular Recognition." Doctoral thesis, Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2007. http://nbn-resolving.de/urn:nbn:de:swb:14-1190291104620-73670.

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Stimuli responsive polymers (SRP) have attracted a lot of attention, due to their potential and promising applications in many fields, as protein-ligand recognition, on-off switches for modulated drug delivery or artificial organs. Poly(N-isopropylacrylamide) (PNIPAM) is one of the most widely studied polymers due to its lower critical solution temperature (LCST) at ~ 32° C in aqueous solution. Additionally, glycopolymers, where free sugar units are present, have potentially interesting applications especially in bio-recognition where sugars play an important role. In this work, our interest w

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13

Yu, Bonan. "Optimization of Benzocyclobutene Containing Methacryalte Structure for Controlled Radical Polymerization." University of Akron / OhioLINK, 2014. http://rave.ohiolink.edu/etdc/view?acc_num=akron1398938075.

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14

Russum, James. "Controlled Radical Polymerizations in Miniemulsions: Advances in the Use of RAFT." Diss., Available online, Georgia Institute of Technology, 2005, 2005. http://etd.gatech.edu/theses/available/etd-10112005-105314/.

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Thesis (Ph. D.)--Chemical and Biomolecular Engineering, Georgia Institute of Technology, 2006.<br>Jones, Christopher, Committee Chair ; Schork, F. Joseph, Committee Co-Chair ; Weck, Marcus, Committee Member ; Meredith, Carson, Committee Member ; Agrawal, Pradeep, Committee Member.

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15

Ejaz, Muhammad. "Controlled Surface Grafting of Well-Defined Polymers by Living Radical Polymerization Techniques." 京都大学 (Kyoto University), 2001. http://hdl.handle.net/2433/150698.

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16

De, Camargo Chaparro Thaissa. "Synthesis of nanocomposites with anisotropic properties by controlled radical emulsion polymerization Lorena." Thesis, Lyon, 2016. http://www.theses.fr/2016LYSE1045/document.

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L'objectif de ce travail de thèse est de préparer des latex nanocomposites à base d’argile, la Laponite RD, en émulsion aqueuse, à l'aide de la polymérisation radicalaire contrôlée par transfert de chaîne réversible par addition-fragmentation (RAFT). Les plaquettes de Laponite ont été choisies comme charge inorganique surtout pour leur anisotropie de forme, ce qui pourrait permettre l’elaboration de films nanostructurés, mais aussi pour leurs propriétés thermiques et mécaniques, leur pureté chimique élevée et la distribution uniforme en taille des plaquettes. Des polymères hydrophiles (macroRA

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17

Higashimura, Hideyuki. "Radical-controlled oxidative polymerization of phenols : a new methodology for polymer synthesis." 京都大学 (Kyoto University), 2005. http://hdl.handle.net/2433/144858.

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18

Bortolamei, Nicola. "Electrochemistry for atom transfer radical polymerization: from mechanism to more controlled synthesis." Doctoral thesis, Università degli studi di Padova, 2012. http://hdl.handle.net/11577/3422094.

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Living/controlled radical polymerizations (L/CRPs) have been developed in the second half of the nineties and nowadays are among the most powerful and effective polymerization techniques for the preparation of advanced polymeric materials with well defined properties and high value. Atom Transfer Radical Polymerization (ATRP) has recorded the highest success in the field of L/CRP, thanks to its versatility and easiness of application. The first goal of this Ph.D. thesis is to understand and develop Cu-catalyzed ATRP through an electrochemical approach, with particular regard to the properties

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19

Çakir, Pinar. "Molecularly imprinted polymer nanostructures by controlled / living radical polymerization with multi-iniferters." Compiègne, 2012. http://www.theses.fr/2012COMP2018.

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Les polymères à empreintes moléculaires (MIPs) sont des matériaux synthétiques contenant des cavités capables de reconnaître spécifiquement une molécule cible. Ils se présentent comme une alternative intéressante face aux anticorps biologiques en raison de leur meilleure stabilité chimique et physique, leur meilleure disponibilité et leur moindre coût. Traditionnellement, les MIPs sont synthétisés par polymérisation de monolithes, qui sont ensuite broyés mécaniquement, engendrant des particules de taille micrométrique et de formes irrégulières. Durant ces dernières années, de nombreuses techni

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20

Vosloo, Johannes Jacobus. "Controlled free radical polymerization in miniemulsion using Reversible Addition-Fragmentation Chain Transfer (RAFT)." Thesis, Stellenbosch : Stellenbosch University, 2001. http://hdl.handle.net/10019.1/52174.

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Thesis (MSc)--Stellenbosch University, 2001.<br>ENGLISH ABSTRACT: A novel approach to conducting controlled free radical polymerization in aqueous systems using Reversible Addition-Fragmentation Chain Transfer (RAFT) has been studied. When conducting RAFT in aqueous systems, reaction conditions must be chosen such that monomer transport across the aqueous-phase is either eliminated or facilitated. This is to prevent the formation of the red layer associated with RAFT in emulsions. The formation of the red layer is ascribed to the inability of waterinsoluble, dithiobenzoate-endcapped oli

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21

Gonzato, Carlo. "Chemical nanosensors based on molecularly imprinted polymer nanocomposites synthesized by controlled radical polymerization." Compiègne, 2012. http://www.theses.fr/2012COMP2035.

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Les polymères à empreintes moléculaires (MIP, pour molecularly imprinted polymers en anglais) sont des récepteurs synthétiques, parfois appelés "anticorps en plastique", capables de reconnaitre et fixer spécifiquement une molécule cible. L’impression moléculaire s’est imposée, durant les trente dernières années, comme une technique pour la synthèse des structures réticulées possédant une remarquable affinité et sélectivité vis-à-vis d’une espèce chimique utilisée comme molécule empreinte dans un procédé de moulage au niveau moléculaire. La grande variété de matériaux et de formats accessibles

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22

Ono, Isamu. "Optimization of the Structure of Benzocyclobutene Containing Methacrylate Monomer for Controlled Radical Polymerization." University of Akron / OhioLINK, 2016. http://rave.ohiolink.edu/etdc/view?acc_num=akron1468500945.

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23

Morin, Aurélie. "Controlled radical polymerization of vinyl esters and vinyl amides : experimental and theoretical studies." Thesis, Toulouse, INPT, 2013. http://www.theses.fr/2013INPT0117/document.

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Ces travaux de thèse portent sur la polymérisation radicalaire contrôlée (PRC) des esters et amides de vinyle. L’une des possibilités de contrôle est le piégeage dynamique réversible des chaînes radicalaires croissantes (P•) par un agent de contrôle (T) formant une espèce dormante (P─T’). La concentration en radicaux dans le milieu peut alors diminuer dramatiquement de sorte que les réactions indésirables de terminaisons soient négligeables et que le contrôle de la masse molaire des polymères soit atteint avec un faible indice de dispersité. L’utilisation de complexes métalliques, pouvant s’ox

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24

Park, Sangwoo. "Electrochemically Controlled Atom Transfer Radical Polymerization and Synthesis of Polymers with Complex Architectures." Research Showcase @ CMU, 2016. http://repository.cmu.edu/dissertations/1031.

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Atom transfer radical polymerization (ATRP) is one of the most broadly applied reversible deactivation radical polymerization (RDRP) technique that provide well-defined polymers with predetermined molecular weight (MW) and narrow molecular weight distribution (MWD). The functional polymers synthesized by ATRP showed a potential promise in the fields of biomedical applications such as smart drug delivery, tissue engineering, and diagnostic sensors. In general, conventional ATRP requires a large amount of transition metal catalysts (> 1000 parts per million (ppm) versus molar ratio of monomers)

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25

Bompart, Marc. "Molecularly imprinted polymers and nano-composites by free radical and controlled/living radical polymerization : applications in optical sensors." Compiègne, 2010. http://www.theses.fr/2010COMP1870.

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Cette thèse est organisée en trois chapitres basés sur trois publications et deux manuscrits en cours de soumission. Les polymères à empreintes moléculaires (MIP) sont des récepteurs produits à façon qui sont obtenues par polymérisation en présence de molécules modèles. Le premier papier décrit l'utilisation de la spectroscopie Raman pour la détection et la quantification de molécules modèles au sein d'une particule unique de polymères a empreintes moléculaires de taille micrométrique. Les particules de polymères ont eté imprimées avec comme molécules modèles S-propranolol. Des particules de t

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26

Bergenudd, Helena. "Understanding the mechanisms behind atom transfer radical polymerization : exploring the limit of control." Doctoral thesis, KTH, Kärnkemi, 2011. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-32104.

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Atom transfer radical polymerization (ATRP) is one of the most commonly employed techniques for controlled radical polymerization. ATRP has great potential for the development of new materials due to the ability to control molecular weight and polymer architecture. To fully utilize the potential of ATRP as polymerization technique, the mechanism and the dynamics of the ATRP equilibrium must be well understood. In this thesis, various aspects of the ATRP process are explored through both laboratory experiments and computer modeling. Solvent effects, the limit of control and the use of iron as t

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27

Jordan, Rainer, Tao Zhang, Yunhao Du, Felix Müller, and Ihsan Amin. "Surface-initiated Cu(0) mediated controlled radical polymerization (SI-CuCRP) using a copper plate." Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2015. http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-188989.

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Surface engineering with polymer brushes has become one of the most versatile techniques to tailor surface properties of substrates for a broad variety of (bio-) technological applications. We report on a new facile approach to prepare defined and dense polymer brushes on planar substrates by surface-initiated Cu(0) mediated controlled radical polymerization (SI-CuCRP) of numerous vinyl monomers using a copper plate at room temperature. The fabrication of a variety of homo-, block, gradient and patterned polymer brushes as well as polymer brush arrays is demonstrated. The SI-CuCRP was found to

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28

Qiao, Xiaoguang. "Synthesis of silica-polymer hybrid particles via controlled radical polymerization in aqueous dispersed media." Thesis, Lyon 1, 2013. http://www.theses.fr/2013LYO10332/document.

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Des polymères à base de méthacrylate de poly(oxyde d'éthylène) (PEOMA) avec des chaînes pendantes PEO (Mn = 300 ou 950 g mol-1) ou des copolymères de PEOMA300 et d'acide méthacrylique (AMA) ont été synthétisés par polymérisation radicalaire contrôlée par les nitroxydes en utilisant une alkoxyamine (BlocBuilder®) comme amorceur en présence de SG1 et d'une faible quantité de styrène. Les copolymères à base de PEOMA300 et d'AMA sont thermo- et pH-sensibles. Les deux types de macroalkoxyamines ont été utilisés pour amorcer la copolymérisation en émulsion du méthacrylate de n-butyle et du styrène e

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29

Lang, Andreas [Verfasser], and Mukundan [Akademischer Betreuer] Thelakkat. "Semiconductor Polymer Architectures using Click Chemistry and Controlled Radical Polymerization / Andreas Lang. Betreuer: Mukundan Thelakkat." Bayreuth : Universitätsbibliothek Bayreuth, 2011. http://d-nb.info/101923458X/34.

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30

Lessard, Benoît. "Advances in Nitroxide-mediated controlled radical polymerization from Poly(Methacrylate)s to perfectly alternating copolymers." Thesis, McGill University, 2012. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=110396.

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Nitroxide mediated controlled radical polymerization (NMP) has been utilized since the early 1990s, as a simple and robust technique for the synthesis of various new polymeric architectures. Since the development of second generation initiators based on SG1 and TIPNO stable radicals, NMP is no longer restricted to the polymerization of just styrenics as it was initially and can now homopolymerize a plethoraof monomers such as acrylates and acrylamides. In this thesis, several advances in NMP due to these second generation initiators, were explored. The homopolymerization of methacrylates, by N

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31

Li, Guang-Zhao. "Synthesis and application of some novel functional polymers via controlled radical polymerization and click chemistry." Thesis, University of Warwick, 2012. http://wrap.warwick.ac.uk/54118/.

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The objective of this thesis was to prepare thermoresponsive PEG-based homopolymers and copolymers by combination of cobalt-mediated catalytic chain-transfer polymerization (CCTP) and thiol-ene “click” chemistry and prepare well-defined glycopolymers via “living” polymerization and “click” chemistry. The effect of different catalysts for the nucleophilic mediated thiol-ene reaction was investigated using model compounds, both monomers and oligomers obtained by CCTP. Different catalysts, including pentylamine and hexylamine (primary amines), triethylamine (tertiary amine), and two different pho

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32

Saoud, Fozi. "Superparamagnetic nanoparticles for synthesis and purification of polymers prepared via controlled/"living" radical polymerization (CLRP)." Thesis, Stellenbosch : University of Stellenbosch, 2010. http://hdl.handle.net/10019.1/3998.

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Thesis (PhD (Chemistry and Polymer Science))--University of Stellenbosch, 2010.<br>ENGLISH ABSTRACT: Living chains prepared by RAFT polymerization and NMP reactions using Z-carboxylate and Z-phosphate RAFT agents, and X-phosphate NMP initiators, were efficiently attached to the surface of magnetic nanoparticles (MNPs) and used for the separation of dead chains formed in these polymerization reactions prior to the attachment of the RAFT agents and NMP initiators to the surface of MNPs. All the living chains that attach selectively to the surface of MNPs contained RAFT or NMP functionalities, h

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33

El, Achi Nassim. "Photochemical and photoredox reactions in continuous microreactors : application to cycloaddition, controlled polymerization and radical chemistry." Thesis, Lille 1, 2016. http://www.theses.fr/2016LIL10044/document.

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Ce travail consiste à étudier différentes réactions photochimiques en dispositifs microfluidiques en utilisant la lumière UV/visible, par le biais de catalyseurs recyclables métalliques et non-métalliques, pour la synthèse organique aux applications pharmaceutiques et industrielles. En outre, l’utilisation des systèmes microfluidiques dans des chemins optiques miniaturisés de 500 µm résultant en une amélioration d’illumination. Les mesures d’actinométrie chimique confirment que ≈ 98% de la lumière émise atteint le mélange de réaction dans un réacteur fluidique Mikroglas® Dwell Device largement

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34

Radzinski, Scott Charles. "Synthesis of Bottlebrush Polymers Using the Grafting-Through and Transfer-To Methods." Diss., Virginia Tech, 2017. http://hdl.handle.net/10919/77574.

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Bottlebrush polymers are interesting topologies that have become increasingly relevant in various applications including rheology modifiers, super-soft elastomers, photonic crystals, anti-fouling coatings, the in vivo delivery of therapeutic agents, and as promising substrates in lithographic printing. These macromolecules are comprised of numerous polymeric side-chains densely grafted to a polymer backbone. The densely grafted nature of bottlebrush polymers results in steric repulsion between neighboring polymer chains, forcing these macromolecules to adopt a chain-extended conformation. Alth

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35

Nozari, Samira. "Towards understanding RAFT aqueous heterophase polymerization." Phd thesis, Universität Potsdam, 2005. http://opus.kobv.de/ubp/volltexte/2005/580/.

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Reversible addition-fragmentation transfer (RAFT) was used as a controlling technique for studying the aqueous heterophase polymerization. The polymerization rates obtained by calorimetric investigation of ab initio emulsion polymerization of styrene revealed the strong influence of the type and combination of the RAFT agent and initiator on the polymerization rate and its profile. The studies in all-glass reactors on the evolution of the characteristic data such as average molecular weight, molecular weight distribution, and average particle size during the polymerization revealed the importa

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36

Jones, Jason William. "Enhanced Architectural and Structural Regulation Using Controlled Free Radical Polymerization Techniques; Supramolecular Assemblies: Pseudorotaxanes and Polypseudorotaxanes." Thesis, Virginia Tech, 2001. http://hdl.handle.net/10919/31766.

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Due in large part to the growth and development of reliable surface characterization techniques, as well as to advances in the physical and chemical techniques used to modify surfaces, the technology of surface modification has seen rapid expansion over the past two decades. A major thrust of this research is the growth of controlled/"living" polymeric brushes from the surface of various substrates, an advance that promises to be a facile and reproducible way of altering surface properties. A unique initiator bearing ATRP (atom transfer radical polymerization), cleavage, and condensation fun

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37

Krivorotova, Tatjana. "Synthesis of polyelectrolytes contaiting poly(ethylene oxide) side chains by living radical polymerization." Doctoral thesis, Lithuanian Academic Libraries Network (LABT), 2010. http://vddb.laba.lt/obj/LT-eLABa-0001:E.02~2010~D_20100915_162344-10990.

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The main goal of this work was to synthesize polyelectrolyte brushes containing poly(ethylene oxide) side chains by living polymerization. Brush-like macromolecules are unique polymer molecules whose conformation and physical properties are controlled by steric repulsion of densely grafted side chains. Molecules can be either flexible or stiff, depending on the grafting density and the length of the side chains. Polymerization of macromonomers is one of the most useful ways to prepare brush copolymers. However, with the macromonomer method, the distribution of the spacing of the side chains ca

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38

Allen, Michael H. Jr. "Imidazole-Containing Polymerized Ionic Liquids for Emerging Applications: From Gene Delivery to Thermoplastic Elastomers." Diss., Virginia Tech, 2013. http://hdl.handle.net/10919/49593.

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Novel imidazole-containing polyelectrolytes based on poly(1-vinylimidazole) (poly(1VIM)) were functionalized with various hydroxyalkyl-substituents to investigate the influence of charge density and hydrogen bonding on nonviral DNA delivery. Copolymers with higher charge densities exhibited increased cytotoxicity, whereas increased hydroxyl concentrations remained nontoxic. DNA binding affinity increased with increased charge densities and increased hydroxyl content. Dynamic light scattering determined the copolymers which delivered DNA most effectively maintained an intermediate binding af

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39

Ott, Marcus [Verfasser], Markus [Akademischer Betreuer] Biesalski, and Annette [Akademischer Betreuer] Andrieu-Brunsen. "Tailor-made cellulose graft copolymers by controlled radical polymerization techniques / Marcus Ott ; Markus Biesalski, Annette Andrieu-Brunsen." Darmstadt : Universitäts- und Landesbibliothek Darmstadt, 2017. http://d-nb.info/112415521X/34.

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40

Sidi, Zhao. "Synthesis, Characterization and High-throughput Screening of Photoiniferter/RAFT Agent for Well-controlled Radical Polymerization of Block Copolymers." University of Akron / OhioLINK, 2019. http://rave.ohiolink.edu/etdc/view?acc_num=akron1555435272696644.

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41

Scholte, Jon Paul. "Effects of prepolymer structure on photopolymer network formation and thermomechanical properties." Diss., University of Iowa, 2017. https://ir.uiowa.edu/etd/5624.

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Photopolymerization is a growing field within the realms of polymer and material science. With diverse applications, ranging from coatings and adhesives to newer technologies such as 3D printing photopolymerization continues to increase its prevalence and influence. This research examines fundamental structure property relationships between large prepolymer structures within a formulation and the resulting impact on thermo-mechanical properties in photocurable resins. Most prepolymer molecules utilize a “one pot” synthesis with little to no control over the placement of photoreactive moieties

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42

Lin, Anna. "Nitroxide-mediated photo-polymerization." Electronic Thesis or Diss., Aix-Marseille, 2019. http://www.theses.fr/2019AIXM0264.

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De nos jours, la photopolymérisation est devenue un procédé important dans le domaine de la science des polymères. Cette méthode présente de nombreux avantages : la rapidité de la réaction, l‘aspect environnemental (formation limitée de composés organiques volatils et possibilité de réaction à température ambiante) ou encore un contrôle spatial et temporel. Ce mode d‘activation photochimique appliqué pendant les dernières décennies aux techniques de polymérisation radicalaire contrôlée telles que l‘ATRP, la RAFT ou la NMP permet de contrôler les propriétés des polymères mais aussi la préparati

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43

Dommanget, Cédric. "Polymérisation radicalaire contrôlée : le défi de l'éthylène." Thesis, Lyon 1, 2013. http://www.theses.fr/2013LYO10216/document.

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Les travaux présentés dans cette thèse portent sur le contrôle de la polymérisation radicalaire de l'éthylène à basse pression (200 bar) et basse température (70 °C) et sur la synthèse de copolymères à blocs contenant au moins un segment de polyéthylène. Quatre techniques de polymérisation, couramment utilisées en ingénierie macromoléculaire, ont été étudiées : NMP, CMRP, RAFT/MADIX et ESCP. Nos études sur le nitroxyde SG1 (NMP) et le bis(acétylacétonate) de cobalt (CMRP) ont montré que ces composés sont inefficaces pour contrôler la polymérisation de l'éthylène. Un comportement inattendu du b

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44

Dréan, Mathilde. "Controlled synthesis of polyvinylamine-based (co)polymers for gene transfection." Thesis, Paris 6, 2016. http://www.theses.fr/2016PA066444.

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Le transfert de gènes consiste en l’introduction d’acides nucléiques au sein de cellules afin de modifier leur activité dans un but essentiellement thérapeutique. Pour préserver le matériel génétique de toute dégradation, il faut recourir à des vecteurs. Parmi ceux-ci, les polymères cationiques sont très prometteurs, en particulier, la polyéthylènimine, considérée comme le vecteur non-viral de référence. Néanmoins, il présente une cytotoxicité élevée. Ainsi, de nombreuses recherches ont pour but d’identifier et de développer de nouveaux polymères combinant efficacité de transfection et haute v

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Kir, Onur [Verfasser], Wolfgang H. [Akademischer Betreuer] Binder, and Guido [Akademischer Betreuer] Kickelbick. "Surface initiated polymerization of isoprene from silica nano- and glass particles via living anionic and controlled radical polymerization techniques / Onur Kir. Betreuer: Wolfgang H. Binder ; Guido Kickelbick." Halle, Saale : Universitäts- und Landesbibliothek Sachsen-Anhalt, 2013. http://d-nb.info/1050977734/34.

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AllenJr, Michael Harry. "Imidazole-Containing Polymerized Ionic Liquids for Emerging Applications: From Gene Delivery to Thermoplastic Elastomers." Diss., Virginia Tech, 2001. http://hdl.handle.net/10919/49593.

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Novel imidazole-containing polyelectrolytes based on poly(1-vinylimidazole) (poly(1VIM)) were functionalized with various hydroxyalkyl-substituents to investigate the influence of charge density and hydrogen bonding on nonviral DNA delivery. Copolymers with higher charge densities exhibited increased cytotoxicity, whereas increased hydroxyl concentrations remained nontoxic. DNA binding affinity increased with increased charge densities and increased hydroxyl content. Dynamic light scattering determined the copolymers which delivered DNA most effectively maintained an intermediate binding af

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Lu, Yangtian. "Synthesis of structurally controlled hyperbranched polymers through the design of new monomers with hierarchical reactivity." Kyoto University, 2019. http://hdl.handle.net/2433/243314.

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48

Dréan, Mathilde. "Controlled synthesis of polyvinylamine-based (co)polymers for gene transfection." Electronic Thesis or Diss., Paris 6, 2016. http://www.theses.fr/2016PA066444.

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Abstract:

Le transfert de gènes consiste en l’introduction d’acides nucléiques au sein de cellules afin de modifier leur activité dans un but essentiellement thérapeutique. Pour préserver le matériel génétique de toute dégradation, il faut recourir à des vecteurs. Parmi ceux-ci, les polymères cationiques sont très prometteurs, en particulier, la polyéthylènimine, considérée comme le vecteur non-viral de référence. Néanmoins, il présente une cytotoxicité élevée. Ainsi, de nombreuses recherches ont pour but d’identifier et de développer de nouveaux polymères combinant efficacité de transfection et haute v

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49

Östmark, Emma. "Tuning Properties of Surfaces and Nanoscopic Objects using Dendronization and Controlled Polymerizations." Doctoral thesis, KTH, Fiber- och polymerteknik, 2007. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-4550.

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In this study, dendronization and grafting via controlled polymerization techniques, atom transfer radical polymerization (ATRP) and ring-opening polymerization (ROP), have been explored. Modification of surfaces and cellulose using these techniques, which enable grafting of well-defined polymer architectures, has been investigated. The interest in using cellulose stems from its renewability, biocompatibility, high molecular weight, and versatile functionalization possibilities. Dendronization was performed using disulfide-cored didendrons of 2,2-bis(methylol)propionic acid (bis-MPA) on gold s

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Gonçalves, Maria Cecilia. "Estudo experimental da polimerização via radical livre controlada em presença de radicais nitroxido (NMRP)." [s.n.], 2006. http://repositorio.unicamp.br/jspui/handle/REPOSIP/266346.

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Orientador: Liliane Maria Ferrareso Lona<br>Dissertação (mestrado) - Universidade Estadual de Campinas. Faculdade de Engenharia Quimica<br>Made available in DSpace on 2018-08-07T10:01:06Z (GMT). No. of bitstreams: 1 Goncalves_MariaCecilia_M.pdf: 1216282 bytes, checksum: 2482b360196051d5ed291cc3d7fa0ccc (MD5) Previous issue date: 2006<br>Resumo: A polimerização via radical livre controlada mediante radicais nitróxido (NMRP) tem recebido cada vez mais atenção como uma técnica para produção de polímeros com estrutura altamente controlada. Distribuições de pesos moleculares estreitas são obtidas

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