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Journal articles on the topic 'Metal nitrosyl complexes'

Author: Grafiati

Published: 5 June 2025

Last updated: 1 August 2025

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1

Ford, Peter C. "Photochemical reactions of metal nitrosyl complexes. Mechanisms of NO reactions with biologically relevant metal centers." International Journal of Photoenergy 3, no. 3 (2001): 161–69. http://dx.doi.org/10.1155/s1110662x01000204.

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The discoveries that nitric oxide (a.k.a. nitrogen monoxide) serves important roles in mammalian bioregulation and immunology have stimulated intense interest in the chemistry and biochemistry of NO and derivatives such as metal nitrosyl complexes. Also of interest are strategies to deliver NO to biological targets on demand. One such strategy would be to employ a precursor which displays relatively low thermal reactivity but is photochemically active to release NO. This proposition led us to investigate laser flash and continuous photolysis kinetics of nitrosyl complexes such as the Roussin's

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2

Ashok, R. F. N., M. Gupta, K. S. Arulsamy та U. C. Agarwala. "Cyclopentadienyl ruthenium complexes. Part III. Reactivity of some η5-cyclopentadienylbis(triphenylphosphine)ruthenium(II) complexes with nitrosyl tribromide and dinitrogen trioxide". Canadian Journal of Chemistry 63, № 4 (1985): 963–70. http://dx.doi.org/10.1139/v85-160.

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Mixed ruthenium(II) nitrosyls have been synthesized in yields larger than 60% by a general reaction of [Ru(η5-C5H5)(PPh3)L]+X− (L = 2,2′-bipyridine or 1,10-phenanthroline, X = Cl or Br) or [Ru(η5-C5,H5)(PPh3)(L)X] (L = PPh3, pyridine, 3-picoline, 4-picoline, [Formula: see text], or [Formula: see text]; X− = Cl−, Br−, I−, CN−, NCS−, H−, or SnCl3−) with NOBr3 and N2O3. In these complexes NO seems to bind with the metal ion as NO+. The reactions of N2O3 gave either nitrito or nitrosyl dinitrito complexes. The reactions of NOBr3 with trichlorostannate complexes did not yield nitrosyl complexes, in

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3

Metzker, Gustavo, Inara de Aguiar, Maykon Lima Souza, Daniel Rodrigues Cardoso, and Douglas Wagner Franco. "Reaction of ruthenium(II) complexes with 2,2-diphenyl-1-picrylhydrazyl (DPPH•) and hydroxyl radicals." Canadian Journal of Chemistry 92, no. 8 (2014): 788–93. http://dx.doi.org/10.1139/cjc-2014-0082.

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The reaction of the complexes trans-[RuII(NO+)(NH3)4L] and [RuII(NO+)HEDTA] with 2,2-diphenyl-1-picrylhydrazyl (DPPH•) and hydroxyl (OH•) radicals has been investigated at 25.0 ± 0.1 °C using spectroscopic (UV-vis and electron paramagnetic resonance) and electrochemical techniques (differential pulse voltammetry and cyclic voltammetry). The redox potential of RuIII/RuII for the ruthenium nitrosyl complexes was determined and is in the range of +2.2 V (L = HEDTA) to +2.6 V (L = isn) versus the normal hydrogen electrode . The trans-[RuII(NO+)(NH3)4L]3+ and [RuII(NO+)HEDTA] complexes do not react

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4

Gäggeler, Heinz W., Ilya Usoltsev, and Robert Eichler. "Reactions of fission products from a 252Cf source with NO and mixtures of NO and CO in an inert gas." Radiochimica Acta 107, no. 7 (2019): 555–60. http://dx.doi.org/10.1515/ract-2018-3076.

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Abstract Fission products recoiling from a 252Cf spontaneous fission source were stopped in various mixtures of inert gases containing CO and NO. For the elements of the transisition metal series Mo, Tc, Ru, and Rh previous observations of pure carbonyl complexes were reproduced. However, no formation of volatile mixed nitrosyl-carbonyl complexes or pure nitrosyl complexes for these elements have been observed. Instead, efficient production of volatile nitrosyl compounds for single iodine atoms, presumably nitrosyl iodide, NOI, was detected. This observation is of interest as potential transpo

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5

Li, Lijuan, and Linlin Li. "Recent advances in multinuclear metal nitrosyl complexes." Coordination Chemistry Reviews 306 (January 2016): 678–700. http://dx.doi.org/10.1016/j.ccr.2015.03.026.

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6

Heilman, Brandon, and Pradip K. Mascharak. "Light-triggered nitric oxide delivery to malignant sites and infection." Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 371, no. 1995 (2013): 20120368. http://dx.doi.org/10.1098/rsta.2012.0368.

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The discovery of nitric oxide (NO) as a signalling molecule in various physiological and pathological pathways has spurred research in the design of exogenous NO donors as drugs. In recent years, metal nitrosyls (NO complexes of metals) have been investigated as NO-donating agents. Results from our laboratory during the past few years have demonstrated that metal nitrosyls derived from designed ligands can deliver NO under the total control of light of various frequencies. Careful incorporation of these photoactive nitrosyls into polymer matrices has afforded a set of nitrosyl–polymer composit

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7

Mayer, Tobias, and Hans-Christian Böttcher. "Protonation of metal–metal bonds in nitrosyl-bridged diruthenium complexes." Polyhedron 69 (February 2014): 240–43. http://dx.doi.org/10.1016/j.poly.2013.12.009.

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8

Daniel, Chantal, and Christophe Gourlaouen. "Structural and Optical Properties of Metal-Nitrosyl Complexes." Molecules 24, no. 20 (2019): 3638. http://dx.doi.org/10.3390/molecules24203638.

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The electronic, structural and optical properties (including Spin–Orbit Coupling) of metal nitrosyl complexes [M(CN)5(NO)]2− (M = Fe, Ru or Os) are investigated by means of Density Functional Theory, TD-DFT and MS-CASPT2 based on an RASSCF wavefunction. The energy profiles connecting the N-bound (η1-N), O-bound (η1-O) and side-on (η2-NO) conformations have been computed at DFT level for the closed shell singlet electronic state. For each structure, the lowest singlet and triplet states have been optimized in order to gain insight into the energy profiles describing the conformational isomerism

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9

Ambach, Eberhard, та Wolfgang Beck. "Metallkomplexe mit biologisch wichtigen Liganden XXVI : Reaktionen von Bis(α-aminoacidato)platin(II)-Komplexen mit Nitrosylsalzen: Nitrosylplatin-Komplexe[xxx] + X- (X = BF4 , PF6 , SbF6 )/Metal Complexes with Biologically Important Ligands XXXVI : Reaction of Bis(α-aminoacidato) Platinum(II) Complexes with Nitrosyl Salts: Nitrosyl Platinum Complexes[xxx]+X-(X = BF4 , PF6 , SbF 6)". Zeitschrift für Naturforschung B 40, № 2 (1985): 288–91. http://dx.doi.org/10.1515/znb-1985-0224.

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AbstractThe reactions of the glycinato, alaninato, or cyclo-leucinato chelate platinum complexes trans -[xxx] with nitrosyl salts NO+X- (X = BF4, PF6, SbF6) in acetonitrile at -20 °C give the blue nitrosyl compounds {(0N)Pt [xxx] X·nCH3CN. Nitrosation at the amino group is not observed. The spectroscopic data of the nitrosyl complexes (IR, XPE) are reported. [xxx] + PF6- reacts with lithium halides or halogens in DMF to give the platinum (IV) complexes X2Pt(NH2CH2CO2)2 (X = CI, Br, I).

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10

Song, Wenjing, Arkady Ellern, and Andreja Bakac. "Electron-Transfer Reactions of Nitrosyl and Superoxo Metal Complexes." Inorganic Chemistry 47, no. 18 (2008): 8405–11. http://dx.doi.org/10.1021/ic800867j.

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11

Hummel, Patrick, Jay R. Winkler, and Harry B. Gray. "Electronic structures of tetragonal nitrido and nitrosyl metal complexes." Theoretical Chemistry Accounts 119, no. 1-3 (2007): 35–38. http://dx.doi.org/10.1007/s00214-006-0236-8.

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12

Bohr, F., H. Chermette, and M. F. Ruiz-lópez. "A density functional study of pseudotetrahedral metal-nitrosyl complexes." International Journal of Quantum Chemistry 52, no. 4 (1994): 1039–49. http://dx.doi.org/10.1002/qua.560520429.

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13

Li, Lijuan, and Linlin Li. "ChemInform Abstract: Recent Advances in Multinuclear Metal Nitrosyl Complexes." ChemInform 47, no. 6 (2016): no. http://dx.doi.org/10.1002/chin.201606236.

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14

Sizova, O. V., L. V. Skripnikov, A. Yu Sokolov, and N. V. Ivanova. "Rhodium and ruthenium tetracarboxylate nitrosyl complexes: Electronic structure and metal-metal bond." Russian Journal of Coordination Chemistry 33, no. 8 (2007): 588–93. http://dx.doi.org/10.1134/s1070328407080076.

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15

Alvarez, M. Angeles, M. Esther García, Daniel García-Vivó, Miguel A. Ruiz та Adrián Toyos. "The doubly-bonded ditungsten anion [W2Cp2(μ-PPh2)(NO)2]−: an entry to the chemistry of unsaturated nitrosyl complexes". Dalton Transactions 45, № 34 (2016): 13300–13303. http://dx.doi.org/10.1039/c6dt02319c.

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The title complex, the first anionic nitrosyl complex featuring a metal-metal double bond, displays substantial nucleophilicity, thus providing synthetic access to different unsaturated hydride and heterometallic derivatives, as well as a variety of electron-precise molecules.

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16

Masters, A. P., M. Parvez, T. S. Sorensen та F. Sun. "Organometallic products from the reaction of the isoelectronic Mn(CO)5− and Cr(CO)4NO− metallate anions with bis-α-bromocyclopropyl ketone". Canadian Journal of Chemistry 71, № 2 (1993): 230–38. http://dx.doi.org/10.1139/v93-034.

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Mn(CO)5− and Cr(CO)4NO− react with the title ketone to give organometallic products. In the chromium case, a single metallofuran product is produced. In the manganese reaction, one can isolate a series of four complexes, two of which have a structure closely related to the chromium complex. The other two complexes are assigned an acyl manganese structure. The structures of the chromium complex and one of the acyl manganese complexes have been determined by X-ray methods. One finds a distorted octahedral bonding about the metal atom in each case. The chromium complex has bond lengths very simil

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17

Ford, P. C. "Probing fundamental mechanisms of nitric oxide reactions with metal centers." Pure and Applied Chemistry 76, no. 2 (2004): 335–50. http://dx.doi.org/10.1351/pac200476020335.

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Studies in this laboratory have been concerned with mapping the chemical properties and mechanisms of NO interactions with hemes and other metal centers. These are models relevant to the mammalian biology of nitric oxide, an important bioregulatory molecule. Presented here will be an overview of flash photolysis kinetics investigations of ferri- and ferro-heme nitrosyl formation in model complexes and several heme proteins. Also described will be ongoing studies of reductive nitrosylation mechanisms involving the reactions of NO with water-soluble Fe(III) porphyrins and ferri-heme proteins and

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18

Lopes, Luiz G. F., Maria G. Gomes, Simone S. S. Borges, and Douglas W. Franco. "Correlation Between the Lever Parameter and Electronic Properties of Nitrosyl Ruthenium(II) Complexes." Australian Journal of Chemistry 51, no. 9 (1998): 865. http://dx.doi.org/10.1071/c97216.

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The Lever parameter (EL), for a series of ruthenium nitrosyl complexes of the type [Ru(NH3)4NOL] n+, where ligand L = nicotinamide (nic), isonicotinamide (isn), pyrazine (pz), pyridine (py), imidazole (imN), L-histidine (L-hist), NH3, trimethyl phosphite [P(OMe)3] and triethyl phosphite [P(OEt)3], is correlated to Epc1 (the potential for the reduction RuNO++e- → RuNO 0) and v(NO) data. A correlation is observed between ∑EL and Epc1, and between ∑EL and v(NO), since these parameters are dependent on electronic characteristics of the nitrosyl group. For ∑EL v. Epc1, the slope, SL, and intercept,

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19

Wang, Yong-Xiang, Peter Legzdins, Jason S. Poon, and Catherine C. Y. Pang. "Vasodilator Effects of Organotransition-Metal Nitrosyl Complexes, Novel Nitric Oxide Donors." Journal of Cardiovascular Pharmacology 35, no. 1 (2000): 73–77. http://dx.doi.org/10.1097/00005344-200001000-00009.

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20

Coppens, Philip, Irina Novozhilova, and Andrey Kovalevsky. "Photoinduced Linkage Isomers of Transition-Metal Nitrosyl Compounds and Related Complexes." Chemical Reviews 102, no. 4 (2002): 861–84. http://dx.doi.org/10.1021/cr000031c.

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21

Ballivet-Tkatchenko, D., B. Nickel, A. Rassat, and J. Vincent-Vaucquelin. "Cationic metal nitrosyl complexes. 6. Characterization of the 19-electron iron nitrosyl radical cation [Fe(NO)2LL'2]+." Inorganic Chemistry 25, no. 19 (1986): 3497–501. http://dx.doi.org/10.1021/ic00239a034.

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22

Reglinski, J., A. R. Butler, and C. Glidewell. "Metal-Nitrosyl complexes as a source of new vasodilators: Strategies derived from systematic chemistry and nitrosyl ligand reactivity." Applied Organometallic Chemistry 8, no. 1 (1994): 25–31. http://dx.doi.org/10.1002/aoc.590080106.

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23

Ford, P. C., J. Bourassa, K. Miranda, et al. "Photochemistry of metal nitrosyl complexes. Delivery of nitric oxide to biological targets." Coordination Chemistry Reviews 171 (April 1998): 185–202. http://dx.doi.org/10.1016/s0010-8545(98)90031-5.

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24

Boulet, P., M. Buchs, H. Chermette, et al. "DFT Investigation of Metal Complexes Containing a Nitrosyl Ligand. 2. Excited States." Journal of Physical Chemistry A 105, no. 39 (2001): 8999–9003. http://dx.doi.org/10.1021/jp010989r.

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25

Crestoni, Maria Elisa, Barbara Chiavarino, and Simonetta Fornarini. "Nitrosyl–heme and anion–arene complexes: structure, reactivity and spectroscopy." Pure and Applied Chemistry 87, no. 4 (2015): 379–90. http://dx.doi.org/10.1515/pac-2014-1203.

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AbstractTwo topics are selected and illustrated to exemplify (i) a biological and (ii) an organic ionic intermediate. The reactivity behavior of NO adducts with ferric and ferrous hemes has shown remarkable similarities when examined in the gas phase, demonstrating that the largely different NO affinity displayed in solution and in biological media is due to the different coordination environment. In fact, ferrous hemes present a vacant or highly labile axial coordination site, prone to readily bind NO. The vibrational signatures of the NO ligand have also been probed in vacuo for the first ti

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26

Legzdins, Peter, Kevin M. Smith, and Steven J. Rettig. "Synthesis, characterization, and properties of some cyclopentadienyl molybdenum nitrosyl benzyl complexes." Canadian Journal of Chemistry 79, no. 5-6 (2001): 502–9. http://dx.doi.org/10.1139/v00-158.

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Reaction of CpMo(NO)(CH2Ph)Cl with Me2Mg, Ph2Mg, or PhCCLi reagents in THF affords the corresponding alkyl, aryl, or alkynyl CpMo(NO)(CH2Ph)R (R = hydrocarbyl) complexes as orange powders in good yields. Unlike related 16-electron CpMo(NO)R2 complexes, these 18-electron species exhibit good thermal stability due to their η2-benzyl-Mo interactions. Treatment of CpMo(NO)(CH2Ph)Cl with Na(DME)Cp provides dark green Cp2Mo(NO)(CH2Ph), whose solid-state molecular structure has been established by a single-crystal X-ray crystallographic analysis. The two Cp rings display different binding modes to th

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27

Mikhailov, Artem A., Vladislav Yu Komarov, Aleksandr S. Sukhikh, Denis P. Pishchur, Dominik Schaniel, and Gennadiy A. Kostin. "The impact of counterion on the metastable state properties of nitrosyl ruthenium complexes." New Journal of Chemistry 44, no. 41 (2020): 18014–24. http://dx.doi.org/10.1039/d0nj04436a.

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Complexes of the trans-[RuNO(NH<sub>3</sub>)<sub>4</sub>F]<sup>2+</sup> cation with noble-metal anions [PtCl<sub>6</sub>]<sup>2−</sup>, [PdCl<sub>4</sub>]<sup>2−</sup>, and [PtCl<sub>4</sub>]<sup>2−</sup>, and perchlorate ClO<sub>4</sub><sup>−</sup> were synthesized, the photo-generated linkage isomers were studied by spectroscopic and calorimetric methods.

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28

Murav’ev, V. I. "To Interpretation of the EPR Parameters of Nitrosyl Complexes of Transition Metal Ions." Russian Journal of Coordination Chemistry 31, no. 6 (2005): 398–400. http://dx.doi.org/10.1007/s11173-005-0110-6.

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29

Coppens, Philip, Irina Novozhilova, and Andrey Kovalevsky. "ChemInform Abstract: Photoinduced Linkage Isomers of Transition-Metal Nitrosyl Compounds and Related Complexes." ChemInform 33, no. 26 (2010): no. http://dx.doi.org/10.1002/chin.200226231.

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30

Han, Baocheng, Jianguo Shao, Zhongping Ou, et al. "Synthesis and Characterization of Nitrosyl Diruthenium Complexes. Interaction between NO and CO across the Metal−Metal Bond." Inorganic Chemistry 43, no. 24 (2004): 7741–51. http://dx.doi.org/10.1021/ic048983e.

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31

Hatcher, Lauren E., and Paul R. Raithby. "Solid-state photochemistry of molecular photo-switchable species: the role of photocrystallographic techniques." Acta Crystallographica Section C Crystal Structure Communications 69, no. 12 (2013): 1448–56. http://dx.doi.org/10.1107/s010827011303223x.

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Over the last 30 years, the single-crystal photocrystallographic technique has been developed to determine the three-dimensional crystal and molecular structures of metastable species which have been generated in the crystal photochemically. Transition-metal complexes that have been investigated using this methodology include complexes that contain nitrosyl, dinitrogen, sulfur dioxide and nitrite ligands, all of which form new linkage isomers in the solid state when photoactivated by light of the appropriate wavelength. Both steric and electronic factors determine the level of the conversion f

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32

Balcells, David, Jorge J. Carbó, Feliu Maseras, and Odile Eisenstein. "Self-Consistency versus “Best-Fit” Approaches in Understanding the Structure of Metal Nitrosyl Complexes." Organometallics 23, no. 25 (2004): 6008–14. http://dx.doi.org/10.1021/om049536+.

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33

Morlino, Elisabeth A., and Michael A. J. Rodgers. "Nitric Oxide Deligation from Nitrosyl Complexes of Two Transition Metal Porphyrins: A Photokinetic Investigation." Journal of the American Chemical Society 118, no. 47 (1996): 11798–804. http://dx.doi.org/10.1021/ja962510s.

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34

FORD, P. C., J. BOURASSA, K. MIRANDA, et al. "ChemInform Abstract: Photochemistry of Metal Nitrosyl Complexes. Delivery of Nitric Oxide to Biological Targets." ChemInform 29, no. 37 (2010): no. http://dx.doi.org/10.1002/chin.199837304.

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35

Frantz, Stéphanie, Biprajit Sarkar, Monika Sieger, et al. "EPR Insensitivity of the Metal-Nitrosyl Spin-Bearing Moiety in Complexes [LnRuII-NO·]k." European Journal of Inorganic Chemistry 2004, no. 14 (2004): 2902–7. http://dx.doi.org/10.1002/ejic.200400042.

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36

Ludbrook, S. B., M. C. Scrutton, C. L. Joannou, R. Cammack, and M. N. Hughes. "Inhibition of Platelet Aggregation by Roussin's Black Salt, Sodium Nitroprusside and Other Metal Nitrosyl Complexes." Platelets 6, no. 4 (1995): 209–12. http://dx.doi.org/10.3109/09537109509078457.

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37

Hu, Ching-Han, and Delano P. Chong. "Density functional calculation of core-electron binding energies of transition metal carbonyl and nitrosyl complexes." Chemical Physics Letters 262, no. 6 (1996): 733–36. http://dx.doi.org/10.1016/s0009-2614(96)01123-2.

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38

Fomitchev, Dmitry V., Irina Novozhilova, and Philip Coppens. "Photo-Induced Linkage Isomerism of Transition Metal Nitrosyl and Dinitrogen Complexes Studied by Photocrystallographic Techniques." Tetrahedron 56, no. 36 (2000): 6813–20. http://dx.doi.org/10.1016/s0040-4020(00)00503-2.

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39

Boulet, P., M. Buchs, H. Chermette, et al. "DFT Investigation of Metal Complexes Containing a Nitrosyl Ligand. 1. Ground State and Metastable States." Journal of Physical Chemistry A 105, no. 39 (2001): 8991–98. http://dx.doi.org/10.1021/jp010988z.

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40

Coppens, Philip, Dmitry V. Fomitchev, Michael D. Carducci, and Kirby Culp. "Crystallography of molecular excited states. Transition-metal nitrosyl complexes and the study of transient species." Journal of the Chemical Society, Dalton Transactions, no. 6 (1998): 865–72. http://dx.doi.org/10.1039/a708604k.

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41

Nasiri Sovari, Sara, Isabelle Kolly, Kevin Schindler та ін. "Efficient Direct Nitrosylation of α-Diimine Rhenium Tricarbonyl Complexes to Structurally Nearly Identical Higher Charge Congeners Activable towards Photo-CO Release". Molecules 26, № 17 (2021): 5302. http://dx.doi.org/10.3390/molecules26175302.

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The reaction of rhenium α-diimine (N-N) tricarbonyl complexes with nitrosonium tetrafluoroborate yields the corresponding dicarbonyl-nitrosyl [Re(CO)2(NO)(N-N)X]+ species (where X = halide). The complexes, accessible in a single step in good yield, are structurally nearly identical higher charge congeners of the tricarbonyl molecules. Substitution chemistry aimed at the realization of equivalent dicationic species (intended for applications as potential antimicrobial agents), revealed that the reactivity of metal ion in [Re(CO)2(NO)(N-N)X]+ is that of a hard Re acid, probably due to the strong

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42

Norman, David W., Michael J. Ferguson, Robert McDonald та Jeffrey M. Stryker. "s-trans-Diene Complexes of a First-Row Transition Metal. Half-Sandwichs-trans-η4-1,3-Diene Nitrosyl Complexes of Chromium". Organometallics 25, № 11 (2006): 2705–8. http://dx.doi.org/10.1021/om050847+.

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43

Sellmann, Dieter, Helmut Schillinger, and Falk Knoch. "Übergangsmetallkomplexe mit Schwefelliganden, LXXXVI. Säure-Base- und Redox-Reaktionen von [Ni(′MeS2′)2] mit H+, PMe3, NO+ und NO. Röntgenstrukturanalyse von [Ni(PMe3)(′MeS2′)2] (′MeS2′ = o-(Methylthio)thiophenolat(1–)) / Transition-Metal Complexes with Sulfur Ligands, LXXXVI. Acid-Base and Redox Reactions of [Ni(′MeS2')2] with H+, PMe3, NO+ and NO. X-Ray Structure Determination of [Ni(PMe3)(′MeS2′)2] (′MeS2′ = o-(methylthio)thiophenolate(1–))." Zeitschrift für Naturforschung B 47, no. 5 (1992): 748–54. http://dx.doi.org/10.1515/znb-1992-0523.

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In order to elucidate specific properties of nickel-sulfur complexes, addition and substitution reactions of [Ni(′MeS2′)2] (1) were investigated. 1 is rapidly hydrolyzed by aqueous HCl yielding ′MeS2′–H and Ni(II) ions. 1 coordinates phosphines as coligands, thioether donors decoordinate, however, simultaneously. The monophosphine complex [Ni(PMe3)(′MeS2′ )2] (2) was characterized by X-ray structure determination. It contains a square-planar NiS3P unit and one decoordinated thioether group. Redox reactions of 1 occur with NO+ and NO, yielding the binuclear nitrosyl complexes cis- and trans-[Ni

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44

Fergusson, Jack E., and Richard K. Coll. "Radiation induced reactions of some platinum metal nitrosyl complexes containing tertiary phosphine, arsine and stibine ligands." Inorganica Chimica Acta 207, no. 2 (1993): 191–97. http://dx.doi.org/10.1016/s0020-1693(00)90709-6.

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45

Van Stappen, Casey, and Nicolai Lehnert. "Mechanism of N–N Bond Formation by Transition Metal–Nitrosyl Complexes: Modeling Flavodiiron Nitric Oxide Reductases." Inorganic Chemistry 57, no. 8 (2018): 4252–69. http://dx.doi.org/10.1021/acs.inorgchem.7b02333.

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46

SIZOVA, OL'GA V., VICTOR I. BARANOVSKI, NINA V. IVANOVA, and VLADIMIR V. SIZOV. "Valence bond analysis of the bonding in transition metal compounds: the RuNO group in nitrosyl complexes." Molecular Physics 101, no. 6 (2003): 715–20. http://dx.doi.org/10.1080/0026897031000075606.

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47

Kudo, Setsuko, James L. Bourassa, Susan E. Boggs, Yuhkou Sato, and Peter C. Ford. "In SituNitric Oxide (NO) Measurement by Modified Electrodes: NO Labilized by Photolysis of Metal Nitrosyl Complexes." Analytical Biochemistry 247, no. 2 (1997): 193–202. http://dx.doi.org/10.1006/abio.1997.2097.

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48

Miguel, Daniel, Vı́ctor Riera, and Mei Wang. "The influence of nitrosyl and allyl ligands on the formation of metalmetal bonds in bimetallic complexes containing S2CPCy3 bridges." Inorganica Chimica Acta 307, no. 1-2 (2000): 82–87. http://dx.doi.org/10.1016/s0020-1693(00)00208-5.

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49

Saraiva, Juliana, Samantha S. Marotta-Oliveira, Simone Aparecida Cicillini, Josimar de Oliveira Eloy, and Juliana Maldonado Marchetti. "Nanocarriers for Nitric Oxide Delivery." Journal of Drug Delivery 2011 (August 22, 2011): 1–16. http://dx.doi.org/10.1155/2011/936438.

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Abstract:

Nitric oxide (NO) is a promising pharmaceutical agent that has vasodilative, antibacterial, and tumoricidal effects. To study the complex and wide-ranging roles of NO and to facilitate its therapeutic use, a great number of synthetic compounds (e.g., nitrosothiols, nitrosohydroxyamines, N-diazeniumdiolates, and nitrosyl metal complexes) have been developed to chemically stabilize and release NO in a controlled manner. Although NO is currently being exploited in many biomedical applications, its use is limited by several factors, including a short half-life, instability during storage, and pote

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50

Sellmann, Dieter, Michael Geck, and Matthias Moll. "Übergangsmetallkomplexe mit Schwefelliganden, LXXXI [Ru(NO)('S5')]Br, ein reaktiver Ruthenium-Schwefelligand- Nitrosyl-Komplex: Synthese und Reaktionen mit Azid und Amid/Transition Metal Complexes with Sulfur Ligands, LXXXI [Ru(NO)('S5')]Br, a Reactive Ruthenium Sulfur Ligand Nitrosyl Complex: Synthesis and Reactions with Azide and Amide." Zeitschrift für Naturforschung B 47, no. 1 (1992): 74–78. http://dx.doi.org/10.1515/znb-1992-0115.

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Abstract:

In order to investigate the potential conversion of coordinated NO into N2 ligands at Ru sulfur centers, the cationic Ru nitrosyl complex meso-[Ru(NO)('S5')]Br (1)** was synthesized by template alkylation of [NBu4][Ru(NO)('S2')2]** with (BrC2H4)2S. 1 is reactive towards nucleophiles. Reaction with azide yields N2O, N2 and [Ru('S5')]2 (2), reaction with LiNH2, NH3 and NEt3 leads to C-S bond cleavage in the 'S5' ligand of 1 and to the formation of a Ru nitrosyl vinylthioetherthiolate complex.

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