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Relevant bibliographies by topics / Nitroxide radicals

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Academic literature on the topic 'Nitroxide radicals'

Author: Grafiati

Published: 4 June 2021

Last updated: 1 February 2022

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Journal articles on the topic "Nitroxide radicals"

1

Bognár, Balázs, Györgyi Úr, Cecília Sár, Olga H. Hankovszky, Kálmán Hideg, and Tamás Kálai. "Synthesis and Application of Stable Nitroxide Free Radicals Fused with Carbocycles and Heterocycles." Current Organic Chemistry 23, no. 4 (2019): 480–501. http://dx.doi.org/10.2174/1385272823666190318163321.

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Stable nitroxide free radicals have traditionally been associated with 2,2,6,6- tetramethylpiperidine-1-oxyl (TEMPO) or its 4-substituted derivatives as relatively inexpensive and readily accessible compounds with limited possibilities for further chemical modification. Over the past two decades, there has been a resurgence of interest in stable free radicals with proper functionalization tuned for various applications. The objective of this review is to present recent results with synthetic methodologies to achieve stable nitroxide free radicals fused with aromatic carbocycles and heterocycle

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Romanov, Vasily, Irina Bagryanskaya, Dmitry Gorbunov, et al. "A Crystallographic Study of a Novel Tetrazolyl-Substituted Nitronyl Nitroxide Radical." Crystals 8, no. 9 (2018): 334. http://dx.doi.org/10.3390/cryst8090334.

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Spin-labelled compounds are widely used in chemistry, physics, biology, and material sciences, but the directed synthesis of some functionalized organic radicals is still a challenge. We succeeded in the preparation of a tetrazolyl-substituted nitronyl nitroxide radical in pure crystalline form. According to the single-crystal X-ray data, intra- (NH…O, 2.43 Å) and inter-molecular hydrogen bonds (NH…O, 1.91 Å) are formed between NH groups of the tetrazole cycles and O atoms of the paramagnetic moieties. The intermolecular H-bonds connect the molecules forming chains along the a-axis. Moreover,

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Hussain, Hamza A. "The effect of cation concentration on the nitrogen splitting constant of nitroxide free radicals." Collection of Czechoslovak Chemical Communications 55, no. 10 (1990): 2377–80. http://dx.doi.org/10.1135/cccc19902377.

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Nitroxide free radicals prepared from diethylamine, piperidine and pyrrolidine by oxidation with hydrogen peroxide were studied by ESR spectroscopy. The changes in the 14N splitting constant (aN) caused by the addition of KBr or tetraethylammonium bromide were measured in dependence on the concentration of the ions. For diethylamine nitroxide and piperidine nitroxide, the results are discussed in terms of two equilibria: the one, involving the anion, is associated with a gain or loss of hydrogen bonds to the nitroxide oxygen atom, the other is associated with the formation of solvent shared un

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Kokorin, Alexander I., and Igor A. Grigor’ev. "Fluorinated nitroxide radicals." Mendeleev Communications 16, no. 4 (2006): 195–200. http://dx.doi.org/10.1070/mc2006v016n04abeh002329.

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Constantinescu, Titus, Petre Ionita, Ion Chiorescu, and Gabriela Ionita. "Hydrazyl, Nitronyl-, and imino-nitroxides: Synthesis, properties and reaction with nitric oxide and nitrogen dioxide." Open Chemistry 1, no. 4 (2003): 465–76. http://dx.doi.org/10.2478/bf02475228.

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AbstractTen novel and stable free radicals of nitronyl-, imino-nitroxide and hydrazyl type compounds were synthesized and their physico-chemical properties investigated. UV-Vis and ESR spectroscopic data, as well as the lipophilicities and specific hydrophobic areas of the compounds are compiled. The reaction of these radical compounds with nitric oxide and nitrogen dioxide was also investigated. The radicals synthesized, show selectivity in their reaction with these nitric oxides, depending on their structure (nitronyl-nitroxide radicals react with NO, while hydrazyl radicals react with NO2).

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Kulis, Jakov, Craig A. Bell, Aaron S. Micallef, and Michael J. Monteiro. "Ultrafast and Reversible Multiblock Formation by the SET-Nitroxide Radical Coupling Reaction." Australian Journal of Chemistry 63, no. 8 (2010): 1227. http://dx.doi.org/10.1071/ch10092.

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The single electron transfer-nitroxide radical coupling (SET-NRC) reaction has been used to produce multiblock polymers with high molecular weights in under 3 min at 50°C by coupling a difunctional telechelic polystyrene (Br-PSTY-Br) with a dinitroxide. The well known combination of dimethyl sulfoxide as solvent and Me6TREN as ligand facilitated the in situ disproportionation of CuIBr to the highly active nascent Cu0 species. This SET reaction allowed polymeric radicals to be rapidly formed from their corresponding halide end-groups. Trapping of these carbon-centred radicals at close to diffus

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Politanskaya, Larisa V., Pavel A. Fedyushin, Tatyana V. Rybalova, Artem S. Bogomyakov, Nargiz B. Asanbaeva, and Evgeny V. Tretyakov. "Fluorinated Organic Paramagnetic Building Blocks for Cross-Coupling Reactions." Molecules 25, no. 22 (2020): 5427. http://dx.doi.org/10.3390/molecules25225427.

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New stable polyfluorinated nitroxide radicals for use in cross-coupling reactions, namely, N-tert-butyl-N-oxyamino-2,3,5,6-tetrafluoro-4-iodobenzene and N-tert-butyl-N-oxyamino-2,3,5,6-tetrafluoro-4-ethynylbenzene, were prepared from perfluoroiodobenzene. The reaction of the polyfluoro derivative with tert-butylamine under autoclaving conditions leading to the formation of N-tert-butyl-2,3,5,6-tetrafluoro-4-iodoaniline proved to be the key stage of the whole process. The fluorinated tert-butyl iodophenyl nitroxide was found to form in a solid state via N–O···I halogen bonds, a one-dimensional

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Bekö, Sándor L., Silke D. Thoms, and Martin U. Schmidt. "4,4′-{Diazenediylbis[(1,4-phenylene)bis(carbonyloxy)]}bis(2,2,6,6-tetramethylpiperidinyloxidanyl): the first crystal structure determination from powder data of a nitroxide radical." Acta Crystallographica Section C Crystal Structure Communications 69, no. 12 (2013): 1513–15. http://dx.doi.org/10.1107/s0108270113029211.

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The title compound, C32H42N4O6, is a novel nitroxide radical used for pulsed electron-electron double resonance (PELDOR) spectroscopy. Its crystal structure was determined from laboratory X-ray powder diffraction data. The attractive forces between the molecules in the crystal structure are mainly of dispersive nature. A special interaction of the nitroxide radicals was not observed.

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Al-Bala'a, Imad, and Richard D. Bates. "Effects of Multiple Binding Sites on Studies of Hydrogen Bonding between Nitroxide Radicals and Solvent Molecules." Collection of Czechoslovak Chemical Communications 58, no. 1 (1993): 47–52. http://dx.doi.org/10.1135/cccc19930047.

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The role of more than one binding site on a nitroxide free radical in magnetic resonance determinations of the properties of the complex formed with a hydrogen donor is examined. The expression that relates observed hyperfine couplings in EPR spectra to complex formation constants and concentrations of each species in solution becomes much more complex when multiple binding sites are present, but reduces to a simpler form when binding at the two sites occurs independently and the binding at the non-nitroxide site does not produce significant differences in the hyperfine coupling constant in th

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Lu, Jiao, Pei Jing, Chaoyi Jin, Junfang Xie, and Licun Li. "Modulating the magnetization dynamics in Ln–Cu-Rad hetero-tri-spin complexes through cis/trans coordination of nitronyl nitroxide radicals around the metal center." Dalton Transactions 50, no. 9 (2021): 3280–88. http://dx.doi.org/10.1039/d1dt00090j.

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Dissertations / Theses on the topic "Nitroxide radicals"

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Krudopp, Heimke [Verfasser]. "Free lipid radicals and nitroxide radicals in dispersed systems studied by EPR spectroscopy / Heimke Krudopp." Kiel : Universitätsbibliothek Kiel, 2018. http://d-nb.info/1173163212/34.

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Reginsson, Gunnar Widtfeldt. "Distance measurements using pulsed EPR : noncovalently bound nitroxide and trityl spin labels." Thesis, University of St Andrews, 2013. http://hdl.handle.net/10023/3680.

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The function of biomacromolecules is controlled by their structure and conformational flexibility. Investigating the structure of biologically important macromolecules can, therefore, yield information that could explain their complex biological function. In addition to X ray crystallography and nuclear magnetic resonance (NMR) methods, pulsed electron paramagnetic resonance (EPR) methods, in particular the pulsed electron electron double resonance (PELDOR) technique has, during the last decade, become a valuable tool for structural determination of macromolecules. Long range distance constrai

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Gonçalves, Maria Cecilia. "Estudo experimental da polimerização via radical livre controlada em presença de radicais nitroxido (NMRP)." [s.n.], 2006. http://repositorio.unicamp.br/jspui/handle/REPOSIP/266346.

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Orientador: Liliane Maria Ferrareso Lona<br>Dissertação (mestrado) - Universidade Estadual de Campinas. Faculdade de Engenharia Quimica<br>Made available in DSpace on 2018-08-07T10:01:06Z (GMT). No. of bitstreams: 1 Goncalves_MariaCecilia_M.pdf: 1216282 bytes, checksum: 2482b360196051d5ed291cc3d7fa0ccc (MD5) Previous issue date: 2006<br>Resumo: A polimerização via radical livre controlada mediante radicais nitróxido (NMRP) tem recebido cada vez mais atenção como uma técnica para produção de polímeros com estrutura altamente controlada. Distribuições de pesos moleculares estreitas são obtidas

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Uchida, Yoshiaki. "Studies on Magnetic, Electric, and Optical Properties in the Condensed Phase of Nitroxide Radicals." Kyoto University, 2009. http://hdl.handle.net/2433/123946.

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Kyoto University (京都大学)<br>0048<br>新制・課程博士<br>博士(人間・環境学)<br>甲第14731号<br>人博第467号<br>新制||人||114(附属図書館)<br>20||人博||467(吉田南総合図書館)<br>UT51-2009-D443<br>京都大学大学院人間・環境学研究科相関環境学専攻<br>(主査)教授田村類, 教授山口良平, 教授山本行男, 准教授津江広人<br>学位規則第4条第1項該当

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Fernandes, Denise de Castro. "Efeitos do tempol sobre a interação entre peroxinitrito/CO2 com albumina e macrófagos: inibição da nitração de tirosinas e da oxidação de cisteínas e amplificação da nitrosação de cisteínas." Universidade de São Paulo, 2004. http://www.teses.usp.br/teses/disponiveis/46/46131/tde-17112014-160500/.

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O tempol (TP) tem se mostrado um eficiente protetor em modelos inflamatórios. Os mecanismos de proteção contra espécies reativas de oxigênio foi bastante estudado mas sua interação com espécies reativas de nitrogênio ainda permanece pouco explorada. Recentemente, propusemos que o TP re-direciona a nitração de fenol mediada por peroxintrito (PN)/CO2 para nitrosação, pela sua reação com o radical CO3•‾. O produto desta reação, o cátion oxamônio, oxidaria PN para O2 e •NO. Este último produziria uma espécie nitrosante (N2O3) pela reação com o radical derivado do PN, •NO2 [

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Majzlík, Petr. "Radikálové reakce rozpadu N-H, O-H a O-O vazeb účinkem homogenních a heterogenních redox činidel." Doctoral thesis, Vysoké učení technické v Brně. Fakulta chemická, 2010. http://www.nusl.cz/ntk/nusl-233309.

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The Ph.D. thesis was focused on EPR study of redox reactions of selected types of phenols, secondary amines and diperoxy coumpounds. Within the study some redox agents were employed in nonpolar, in some special cases also in polar solvents. EPR spectra of generated radical products were interpreted using spectral simulation. Study of radical reactions under participation of phenols was preferentially concentrated on the behavior of para methyl substituted phenols, where the instability of this substituent in relation to the applied redox agents was evaluated. The tendency towards the abstracti

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Harrison, Kareem. "Inhibition of Hydrocarbon Autoxidation by Nitroxide Catalyzed Cross Dismutation of Alkylperoxyl and Hydroperoxyl Radicals & a Novel Approach Toward Fluorinated Polyunsaturated Lipids." Thesis, Université d'Ottawa / University of Ottawa, 2020. http://hdl.handle.net/10393/40026.

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Nitroxides are intermediates in the accepted reaction mechanisms of the antioxidant activity of diarylamines and hindered alkyl amines. The parent amines are used as additives to preserve synthetic and natural hydrocarbon-based materials from oxidative degradation. New methodology which enables monitoring of hydrocarbon autoxidations at low rates of radical generation has revealed that diarylnitroxides and hindered nitroxides are far better inhibitors of unsaturated hydrocarbon autoxidation than their precursor amines, implying intervention of a previously overlooked mechanism. Experimental a

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Meyer, Andreas [Verfasser]. "EPR-Based Distance Measurements on Metal Nitroxide Model Complexes as Well as EPR Spectroscopic Characterization of [Si2]-Radicals and Titanocene Complexes / Andreas Meyer." Bonn : Universitäts- und Landesbibliothek Bonn, 2017. http://d-nb.info/1132711258/34.

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Belincanta, Juliana. "Homopolimerização e copolimerização via radical livre controlada por radicais nitroxidos." [s.n.], 2008. http://repositorio.unicamp.br/jspui/handle/REPOSIP/266269.

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Orientador: Liliane Maria Ferrareso Lona<br>Tese (doutorado) - Universidade Estadual de Campinas, Faculdade de Engenharia Quimica<br>Made available in DSpace on 2018-08-11T08:06:10Z (GMT). No. of bitstreams: 1 Belincanta_Juliana_D.pdf: 4082238 bytes, checksum: 20349198a1d8e13a5e2eddcf8d16e5ba (MD5) Previous issue date: 2008<br>Resumo: A polimerização viva/controlada é uma área que vem se desenvolvendo rapidamente no escopo de polímeros e engenharia. A habilidade para preparar copolímeros bem definidos do tipo bloco, estrela, redes poliméricas, bem como outros materiais pelo mecanismo da poli

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Rosero, Mesa Paola Viviana. "Modelagem da homopolimerização via radical livre controlada em presença de radicais nitroxido." [s.n.], 2003. http://repositorio.unicamp.br/jspui/handle/REPOSIP/267475.

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Orientador: Liliane M. Ferrareso Lona<br>Dissertação (mestrado) - Universidade Estadual de Campinas, Faculdade de Engenharia Quimica<br>Made available in DSpace on 2018-08-03T18:36:21Z (GMT). No. of bitstreams: 1 RoseroMesa_PaolaViviana_M.pdf: 5952280 bytes, checksum: 09b01c247830a67ec0b6df187b843097 (MD5) Previous issue date: 2003<br>Resumo: Neste trabalho foi desenvolvido um modelo matemático para a polimerização via radical livre controlada em presença de radicais nitróxidos (NMRP), que inclui a obtenção dos pesos moleculares médios e o índice de polidispersidade para polímeros de estrutu

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Books on the topic "Nitroxide radicals"

1

Fischer, H., ed. Nitroxide Radicals. Part 1. Springer-Verlag, 1989. http://dx.doi.org/10.1007/b33549.

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Fischer, H., ed. Nitroxide Radicals. Part 2. Springer-Verlag, 1989. http://dx.doi.org/10.1007/b36651.

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Fischer, H., ed. Nitroxide Radicals and Nitroxide Based High-Spin Systems. Springer-Verlag, 2005. http://dx.doi.org/10.1007/b83037.

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Volodarsky, Leonid B. Synthetic chemistry of stable nitroxides. CRC Press, 1994.

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Alberti, A. Nitroxide Radicals and Nitroxide Based High-Spin Systems (Numerical Data). Springer, 2005.

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Chan-Seng, Delphine. "Living"/controlled radical group polymerization: From emulsion atom transfer radical polymerization to the synthesis of new nitroxides for stable free radical polymerization. 2007.

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J, Rhodes Christopher, ed. Toxicology of the human environment: The critical role of free radicals. Taylor & Francis, 2000.

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Rhodes, Chris J. Toxicology of the Human Environment. CRC, 2000.

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Book chapters on the topic "Nitroxide radicals"

1

Karoui, Hakim, François Le Moigne, Olivier Ouari, and Paul Tordo. "Nitroxide Radicals: Properties, Synthesis and Applications." In Stable Radicals. John Wiley & Sons, Ltd, 2010. http://dx.doi.org/10.1002/9780470666975.ch5.

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Brückner, Christian. "Nitroxide-Catalyzed Alcohol Oxidations in Organic Synthesis." In Stable Radicals. John Wiley & Sons, Ltd, 2010. http://dx.doi.org/10.1002/9780470666975.ch12.

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Ovcharenko, Victor. "Metal-Nitroxide Complexes: Synthesis and Magnetostructural Correlations." In Stable Radicals. John Wiley & Sons, Ltd, 2010. http://dx.doi.org/10.1002/9780470666975.ch13.

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Naz, Sarwat, John A. Cook, Murali C. Krishna, and James B. Mitchell. "Chapter 14. Biological Applications of Nitroxide Stable Free Radicals." In Nitroxides. Royal Society of Chemistry, 2021. http://dx.doi.org/10.1039/9781788019651-00519.

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Khramtsov, Valery V., and Jay L. Zweier. "Functional in vivo EPR Spectroscopy and Imaging Using Nitroxide and Trityl Radicals." In Stable Radicals. John Wiley & Sons, Ltd, 2010. http://dx.doi.org/10.1002/9780470666975.ch16.

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Atskanov, A. M., A. B. Burdukov, A. A. Savelov, V. I. Ovcharenko, A. V. Podoplelov, and R. Z. Sagdeev. "NMR of Paramagnetic Metals Complexes with Stable Imidazoline Nitroxide Radicals." In 25th Congress Ampere on Magnetic Resonance and Related Phenomena. Springer Berlin Heidelberg, 1990. http://dx.doi.org/10.1007/978-3-642-76072-3_301.

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Berliner, Lawrence J. "Compilation of Hyperfine Splittings andg-Factors for Aminoxyl (Nitroxide) Radicals." In Multifrequency Electron Paramagnetic Resonance. Wiley-VCH Verlag GmbH & Co. KGaA, 2014. http://dx.doi.org/10.1002/9783527672431.ch5.

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Lenk, W., M. Riedl, and L. O. Andersson. "Relevance of primary and secondary nitroxide radicals in biological oxidations." In N-Oxidation of Drugs. Springer Netherlands, 1991. http://dx.doi.org/10.1007/978-94-011-3112-4_23.

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Cirujeda, J., C. Rovira, J. L. Stanger, P. Turek, and J. Veciana. "The Self-Assembly of Hydroxylated Phenyl α-Nitronyl Nitroxide Radicals." In Magnetism: A Supramolecular Function. Springer Netherlands, 1996. http://dx.doi.org/10.1007/978-94-015-8707-5_13.

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Suzuki, Shuichi. "Recent Progress in Stable High-Spin Molecules Based on Nitroxide Radicals". У Chemical Science of π-Electron Systems. Springer Japan, 2015. http://dx.doi.org/10.1007/978-4-431-55357-1_19.

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Conference papers on the topic "Nitroxide radicals"

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Sapunov, V. A., I. V. Kashin, V. A. Ushakov, A. V. Sergeev, and O. V. Denisova. "Little-known aspects of overhauser DNP at zero and low magnetic fields stimulated by parallel electron pumping of nitroxide radicals solutions." In PHYSICS, TECHNOLOGIES AND INNOVATION (PTI-2019): Proceedings of the VI International Young Researchers’ Conference. AIP Publishing, 2019. http://dx.doi.org/10.1063/1.5134263.

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Kollár, Jozef, Štefan Chmela, Ľudmila Hrčková, and Pavol Hrdlovič. "Fluorescent dye-labelled polymer synthesis by nitroxide mediated radical polymerization." In 6TH INTERNATIONAL CONFERENCE ON TIMES OF POLYMERS (TOP) AND COMPOSITES. AIP, 2012. http://dx.doi.org/10.1063/1.4738438.

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Nakamura, Takeshi, and Takayuki Ishida. "Magnetic exchange interaction in gadolinium(III) complex having aliphatic nitroxide radical TEMPO." In PROGRESS IN APPLIED MATHEMATICS IN SCIENCE AND ENGINEERING PROCEEDINGS. AIP Publishing LLC, 2016. http://dx.doi.org/10.1063/1.4941215.

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Waskitoaji, Wihatmoko, Takeo Suga, Hiroyuki Nishide, L. T. Handoko, and Masbah R. T. Siregar. "Redox-Active Nitroxide Radical Polymers: From Green Catalysts to Energy Storage Devices." In INTERNATIONAL WORKSHOP ON ADVANCED MATERIAL FOR NEW AND RENEWABLE ENERGY. AIP, 2009. http://dx.doi.org/10.1063/1.3243242.

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Aqil, Mohamed, Mouad Dahbi, Ismael Saadoune, Abderahman El Idrissi, Abdelhafid Aqil, and Christine Jerome. "Functionalized Graphite Nanoplatelet by Nitroxide Radical PILs as Anode Materials for Li-ion Battery." In 2019 7th International Renewable and Sustainable Energy Conference (IRSEC). IEEE, 2019. http://dx.doi.org/10.1109/irsec48032.2019.9078322.

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Hu, Peng, Fengping Xiao, Xiange Wu, and Zhongqiang Zhi. "A hydroxyl-containing nitronyl nitroxide radical and its Dy (III) complex: Structure and magnetic properties." In 2ND INTERNATIONAL CONFERENCE ON MATERIALS SCIENCE, RESOURCE AND ENVIRONMENTAL ENGINEERING (MSREE 2017). Author(s), 2017. http://dx.doi.org/10.1063/1.5005292.

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Hosokoshi, Y., M. Tamura, K. Nozawa, et al. "Magnetic properties and crystal structures of 2-hydro and 2-halo nitronyl nitroxide radical crystals." In International Conference on Science and Technology of Synthetic Metals. IEEE, 1994. http://dx.doi.org/10.1109/stsm.1994.835484.

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Kusumawati, Yuly, Leli D. Astuti, Eko Santoso, and Syafsir Akhlus. "The comparison of nitroxide radical derivative compound interaction with brookite and anatase surface: A guide to choose the best photoanode for DSSC application." In THE 14TH JOINT CONFERENCE ON CHEMISTRY 2019. AIP Publishing, 2020. http://dx.doi.org/10.1063/5.0005271.

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Puteri, Zahra R., Yuly Kusumawati, Athar L. Ivansyah, and Muhamad A. Martoprawiro. "Computational study to determine redox potential of nitroxide radical and their derivatives compounds along with their analysis as redox-coupe in dye sensitized solar cell’s (DSSC)." In THE 3RD INTERNATIONAL SEMINAR ON CHEMISTRY: Green Chemistry and its Role for Sustainability. Author(s), 2018. http://dx.doi.org/10.1063/1.5082498.

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