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Journal articles on the topic 'Organic compounds Organometallic chemistry'

Author: Grafiati

Published: 4 June 2021

Last updated: 1 February 2022

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1

Salzer, A. "Nomenclature of Organometallic Compounds of the Transition Elements (IUPAC Recommendations 1999)." Pure and Applied Chemistry 71, no. 8 (1999): 1557–85. http://dx.doi.org/10.1351/pac199971081557.

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Organometallic compounds are defined as containing at least one metal-carbon bond between an organic molecule, ion, or radical and a metal. Organometallic nomenclature therefore usually combines the nomenclature of organic chemisty and that of coordination chemistry. Provisional rules outlining nomenclature for such compounds are found both in Nomenclature of Organic Chemistry, 1979 and in Nomenclature of Inorganic Chemistry, 1990This document describes the nomenclature for organometallic compounds of the transition elements, that is compounds with metal-carbon single bonds, metal-carbon multi

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2

Kwofie, Samuel K., Emmanuel Broni, Bismark Dankwa, et al. "Review of Atypical Organometallic Compounds as Antimalarial Drugs." Journal of Chemistry 2020 (May 20, 2020): 1–9. http://dx.doi.org/10.1155/2020/9414093.

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Organometallic compounds are molecules that contain at least one metal-carbon bond. Due to resistance of the Plasmodium parasite to traditional organic antimalarials, the use of organometallic compounds has become widely adopted in antimalarial drug discovery. Ferroquine, which was developed due to the emergence of chloroquine resistance, is currently the most advanced organometallic antimalarial drug and has paved the way for the development of new organometallic antimalarials. In this review, a general overview of organometallic antimalarial compounds and their antimalarial activity in compa

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3

Cadierno, Victorio. "Recent Advances in Organometallic Chemistry and Catalysis." Catalysts 11, no. 5 (2021): 646. http://dx.doi.org/10.3390/catal11050646.

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4

Dong, Zhi-Bing, and Jin-Quan Chen. "Recent Progress in Utilization of Functionalized Organometallic Reagents in Cross Coupling Reactions and Nucleophilic Additions." Synthesis 52, no. 24 (2020): 3714–34. http://dx.doi.org/10.1055/s-0040-1706550.

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AbstractOrganometallic compounds have become increasingly important in organic synthesis because of their high chemoselectivity and excellent reactivity. Recently, a variety of organometallic reagents were found to facilitate transition-metal-catalyzed cross-coupling reactions and nucleophilic addition reactions. Here, we have summarized the latest progress in cross-coupling reactions and in nucleophilic addition reactions with functionalized organometallic reagents present to illustrate their application value. Due to the tremendous contribution made by the Knochel group towards the developme

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5

Smith, J. David. "Colin Eaborn. 15 March 1923 – 22 February 2004." Biographical Memoirs of Fellows of the Royal Society 51 (January 2005): 101–18. http://dx.doi.org/10.1098/rsbm.2005.0007.

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Colin Eaborn was a distinguished chemist, best known for his wide–ranging contributions to organosilicon chemistry. His 566 publications, published over a 56–year period, covered a broad area that included physical organic chemistry, organometallic compounds generally, and coordination chemistry. He was a founding professor at the new University of Sussex and exercised considerable influence on the development of university education in chemistry during the big expansion of the 1960s. He served on a number of public committees, including the Council of the Royal Society from 1978 to 1980 and 1

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6

TOKUDA, Masao. "Organometallic compounds in electroorganic synthesis." Journal of Synthetic Organic Chemistry, Japan 43, no. 6 (1985): 522–32. http://dx.doi.org/10.5059/yukigoseikyokaishi.43.522.

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7

Schrock, Richard. "Dictionary of Organometallic Compounds." Organometallics 5, no. 3 (1986): 607. http://dx.doi.org/10.1021/om00134a905.

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8

Ali, Fayaz, Narayan S Hosmane, and Yinghuai Zhu. "Boron Chemistry for Medical Applications." Molecules 25, no. 4 (2020): 828. http://dx.doi.org/10.3390/molecules25040828.

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Boron compounds now have many applications in a number of fields, including Medicinal Chemistry. Although the uses of boron compounds in pharmacological science have been recognized several decades ago, surprisingly few are found in pharmaceutical drugs. The boron-containing compounds epitomize a new class for medicinal chemists to use in their drug designs. Carboranes are a class of organometallic compounds containing carbon (C), boron (B), and hydrogen (H) and are the most widely studied boron compounds in medicinal chemistry. Additionally, other boron-based compounds are of great interest,

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9

UTIMOTO, Kiitiro. "Highly Selective Reactions Using Organometallic Compounds." Journal of Synthetic Organic Chemistry, Japan 51, no. 11 (1993): 1064–73. http://dx.doi.org/10.5059/yukigoseikyokaishi.51.1064.

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10

Eaborn, Colin. "Dictionary of organometallic compounds." Journal of Organometallic Chemistry 503, no. 1 (1995): C36. http://dx.doi.org/10.1016/0022-328x(95)90002-v.

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11

Hevia, Eva. "Towards a Paradigm Shift in Polar Organometallic Chemistry." CHIMIA International Journal for Chemistry 74, no. 9 (2020): 681–88. http://dx.doi.org/10.2533/chimia.2020.681.

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Core tools of synthetic chemistry, polar organometallic reagents (typified by organolithium and Grignard reagents) are used worldwide for constructing compounds, especially aromatic compounds, which are ubiquitous in organic chemistry and thus in numerous commodities essential to everyday life. By isolation and characterisation of key organometallic intermediates, research in our group has led to the design of polar mixed-metal reagents imbued with synergistic effects that display chemical properties and reactivity profiles far exceeding the limits of traditional single-metal reagents. These s

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12

Minkin, V. I. "Glossary of terms used in theoretical organic chemistry." Pure and Applied Chemistry 71, no. 10 (1999): 1919–81. http://dx.doi.org/10.1351/pac199971101919.

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The glossary contains definitions and explanatory notes for more than 450 terms used in the context of multidisciplinary research and publications related to applications of modern theoretical concepts, computational and graph-theoretical methods to investigation into structure, reactivity, spectroscopic and other physical and physicochemical properties of organic, organometallic and metal coordination compounds. The aim of the glossary is to provide guidance on terminology used in theoretical organic chemistry and to contribute to the elimination of inconsistencies and ambiguities in the mean

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13

Bellama, Jon. "Organometallic Compounds in the Environment." Organometallics 6, no. 4 (1987): 903–4. http://dx.doi.org/10.1021/om00147a606.

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14

Ishida, Hitoshi, Jean-Claude Bünzli, and Andrew Beeby. "Guidelines for measurement of luminescence spectra and quantum yields of inorganic and organometallic compounds in solution and solid state (IUPAC Technical Report)." Pure and Applied Chemistry 88, no. 7 (2016): 701–11. http://dx.doi.org/10.1515/pac-2014-0706.

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AbstractGuidelines for measuring the luminescence of inorganic compounds, metal complexes, and organometallic compounds are described. Common textbooks and manuals describing luminescence measurements are usually targeted for organic compounds, and are not always suitable for inorganic and organometallic compounds, which emit room-temperature phosphorescence. The report describes problems that researchers may confront while recording emission data and elaborates clear procedures to avoid these problems and provide adequate standardized protocols.

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15

OGASAWARA, Masamichi, Makoto KOIKE, and Masahiko SABURI. "Application of NMR Techniques to Organometallic Compounds." Journal of Synthetic Organic Chemistry, Japan 51, no. 6 (1993): 484–90. http://dx.doi.org/10.5059/yukigoseikyokaishi.51.484.

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16

Omae, Iwao. "FIVE-MEMBERED RING COMPOUNDS IN ORGANOMETALLIC INTRAMOLECULAR-COORDINATION COMPOUNDS." Phosphorus, Sulfur, and Silicon and the Related Elements 179, no. 4-5 (2004): 891–97. http://dx.doi.org/10.1080/10426500490427817.

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17

Schumann, Herbert, Ilse Albrecht, Michael Gallagher, Ekkehardt Hahn, Christine Muchmore, and Joachim Pickardt. "Organometallic compounds of the lanthanides." Journal of Organometallic Chemistry 349, no. 1-2 (1988): 103–15. http://dx.doi.org/10.1016/0022-328x(88)80441-8.

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18

Eisch, John J., Stephen R. Sexsmith, and Kenneth C. Fichter. "Organometallic compounds of Group III." Journal of Organometallic Chemistry 382, no. 1-2 (1990): 273–93. http://dx.doi.org/10.1016/0022-328x(90)85232-n.

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19

Fakhr, A., Y. Mugnier, B. Gautheron, and E. Laviron. "Electrochemical studies on organometallic compounds." Journal of Organometallic Chemistry 302, no. 1 (1986): C7—C9. http://dx.doi.org/10.1016/0022-328x(86)80070-5.

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20

Boudier, Andreas, Lars O. Bromm, Matthias Lotz, and Paul Knochel. "New Applications of Polyfunctional Organometallic Compounds in Organic Synthesis." Angewandte Chemie International Edition 39, no. 24 (2000): 4414–35. http://dx.doi.org/10.1002/1521-3773(20001215)39:24<4414::aid-anie4414>3.0.co;2-c.

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21

E, Siyu, Jialin Liu, Yuting Yan, et al. "A New Scaffold for Molecular Design: The Preparative Scale-Syntheses of Ru- Centered Arene Compounds." Current Organic Chemistry 24, no. 10 (2020): 1148–59. http://dx.doi.org/10.2174/1385272824999200608134129.

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Carbon centered molecules have been very well recognized in the past for both academic and industrial purposes. Utilizing inert element instead of carbon atom could bring more molecular complexity as well as potential binding in medicinal chemistry. We report, herein, a number of strategies for the syntheses of Ru-centered molecules starting from commercially available [RuCl2(η6-p-cymene)] dimer substituted phenyl-heterocycles via Concerted Metalation Deprotonation (CMD) processes. Halogen atom ligand exchange and arene ligand exchange from the skeleton have been achieved. Under such procedure

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22

Suhr, H. "Applications and trends of nonequilibrium plasma chemistry with organic and organometallic compounds." Plasma Chemistry and Plasma Processing 9, S1 (1989): 7S—28S. http://dx.doi.org/10.1007/bf01015871.

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23

Gómez, Johana, Diego Sierra, Constanza Cárdenas, and Fanny Guzmán. "Bio-organometallic Peptide Conjugates: Recent Advances in Their Synthesis and Prospects for Biomedical Application." Current Organic Chemistry 24, no. 21 (2020): 2508–23. http://dx.doi.org/10.2174/1385272824666200309093938.

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One area of organometallic chemistry that has attracted great interest in recent years is the syntheses, characterization and study of organometallic complexes conjugated to biomolecules with different steric and electronic properties as potential therapeutic agents against cancer and malaria, as antibiotics and as radiopharmaceuticals. This minireview focuses on the unique structural diversity that has recently been discovered in α- amino acids and the reactions of metallocene complexes with peptides having different chemical behavior and potential medical applications. Replacing α-amino acid

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24

Chan, T. H., C. J. Li, M. C. Lee, and Z. Y. Wei. "1993 R.U. Lemieux Award Lecture Organometallic-type reactions in aqueous media—a new challenge in organic synthesis." Canadian Journal of Chemistry 72, no. 5 (1994): 1181–92. http://dx.doi.org/10.1139/v94-151.

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The development of organometallic-type reactions in aqueous media is reviewed. Coupling reactions of allyl halides with carbonyl compounds mediated by zinc, or tin, or indium in aqueous media to give homoallylic alcohols are discussed. The stereochemical outcome is compared with similar reactions in organic solvents. A concise synthesis of (+)-muscarine is used to illustrate the usefulness of aqueous organometallic-type reactions in organic synthesis. The procedure to protect–deprotect hydroxy functional groups may not be necessary in these reactions. An application in the carbohydrate area is

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25

Schrock, Richard R. "Book Review: Dictionary of Organometallic Compounds." Organometallics 5, no. 3 (1986): 607. http://dx.doi.org/10.1021/om00134a605.

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26

Pignon, Antoine, Erwan Le Gall, and Thierry Martens. "A new manganese-mediated, cobalt-catalyzed three-component synthesis of (diarylmethyl)sulfonamides." Beilstein Journal of Organic Chemistry 10 (February 17, 2014): 425–31. http://dx.doi.org/10.3762/bjoc.10.39.

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The synthesis of (diarylmethyl)sulfonamides and related compounds by a new manganese-mediated, cobalt-catalyzed three-component reaction between sulfonamides, carbonyl compounds and organic bromides is described. This organometallic Mannich-like process allows the formation of the coupling products within minutes at room temperature. A possible mechanism, emphasizing the crucial role of manganese is proposed.

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27

Eaborn, Colin. "Dictionary of organometallic compounds. First supplement." Journal of Organometallic Chemistry 306, no. 2 (1986): C59. http://dx.doi.org/10.1016/s0022-328x(00)99722-5.

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28

Dahlenburg, Lutz, Markus Ernst, Michèle Dartiguenave, and Yves Dartiguenave. "Organometallic compounds of iridium and rhodium." Journal of Organometallic Chemistry 463, no. 1-2 (1993): C8—C10. http://dx.doi.org/10.1016/0022-328x(93)83430-4.

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29

Feshin, Valentin P., and Elena V. Feshina. "Correlation between the 35CI NQR Parameters of Chloro-containing Organic and Organometallic Compounds and the Results of ab initio Calculations." Zeitschrift für Naturforschung A 55, no. 5 (2000): 555–59. http://dx.doi.org/10.1515/zna-2000-0513.

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Abstract The results of comparison of experimental 35C1 NQR parameters for a great number of organic and organometallic compounds and estimated ones using ab initio calculations at the RHF/6-31G(d) level were systematized. The NQR frequency changes on going from one compound to another depend, in general, on the changes of populations of the CI atom po-orbitals in these compounds and, first of all, of populations of their less diffuse parts

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30

Bruland, Kenneth W. "Trace element speciation: organometallic compounds and metal-organic ligand complexes." Applied Geochemistry 3, no. 1 (1988): 75. http://dx.doi.org/10.1016/0883-2927(88)90049-2.

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31

Minkin, V. I. "Bistable organic, organometallic, and coordination compounds for molecular electronics and spintronics." Russian Chemical Bulletin 57, no. 4 (2008): 687–717. http://dx.doi.org/10.1007/s11172-008-0111-y.

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32

Mbaba, Mziyanda, Taryn M. Golding, and Gregory S. Smith. "Recent Advances in the Biological Investigation of Organometallic Platinum-Group Metal (Ir, Ru, Rh, Os, Pd, Pt) Complexes as Antimalarial Agents." Molecules 25, no. 22 (2020): 5276. http://dx.doi.org/10.3390/molecules25225276.

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In the face of the recent pandemic and emergence of infectious diseases of viral origin, research on parasitic diseases such as malaria continues to remain critical and innovative methods are required to target the rising widespread resistance that renders conventional therapies unusable. The prolific use of auxiliary metallo-fragments has augmented the search for novel drug regimens in an attempt to combat rising resistance. The development of organometallic compounds (those containing metal-carbon bonds) as antimalarial drugs has been exemplified by the clinical development of ferroquine in

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33

Peter, Sijongesonke, and Blessing Atim Aderibigbe. "Ferrocene-Based Compounds with Antimalaria/Anticancer Activity." Molecules 24, no. 19 (2019): 3604. http://dx.doi.org/10.3390/molecules24193604.

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Malaria and cancer are chronic diseases. The challenge with drugs available for the treatment of these diseases is drug toxicity and resistance. Ferrocene is a potent organometallic which have been hybridized with other compounds resulting in compounds with enhanced biological activity such as antimalarial and anticancer. Drugs such as ferroquine were developed from ferrocene and chloroquine. It was tested in the 1990s as an antimalarial and is still an effective antimalarial. Many researchers have reported ferrocene compounds as potent compounds useful as anticancer and antimalarial agents wh

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34

Kuznetsova, O. V., A. N. Egorochkin, N. M. Khamaletdinova, and L. G. Domratcheva-Lvova. "Reactivity of organometallic compounds and polarizability effect." Journal of Organometallic Chemistry 779 (March 2015): 73–80. http://dx.doi.org/10.1016/j.jorganchem.2014.12.004.

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35

Collins, Scott, Yaping Hong, Gordon J. Hoover, and Jennifer R. Veit. "Additions of alkyllathanum triflates to carbonyl compounds: reactive organometallic nucleophiles." Journal of Organic Chemistry 55, no. 11 (1990): 3565–68. http://dx.doi.org/10.1021/jo00298a035.

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36

Nikitin, Kirill V., and Nonna P. Andryukhova. "Synthesis of 5-alkyl- and 5-aryl-1,5-dihydro-2H-pyrrol-2-ones via coupling of 5-chloro-1,5-dihydro-2H-pyrrol-2-ones with organometallic compounds." Canadian Journal of Chemistry 78, no. 10 (2000): 1285–88. http://dx.doi.org/10.1139/v00-127.

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5-Chloro-1,5-dihydro-2H-pyrrol-2-ones are easily alkylated at the 5-position by organomagnesium or organozinc compounds and diethyl sodiomalonate leading to corresponding 5-alkyl-1,5-dihydro-2H-pyrrol-2-ones in high yields.Key words: organometallic compounds, alkylation, 1,5-dihydro-2H-pyrrol-2-one.

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37

Berton, Mateo, Kevin Sheehan, Andrea Adamo, and D. Tyler McQuade. "Disposable cartridge concept for the on-demand synthesis of turbo Grignards, Knochel–Hauser amides, and magnesium alkoxides." Beilstein Journal of Organic Chemistry 16 (June 19, 2020): 1343–56. http://dx.doi.org/10.3762/bjoc.16.115.

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Magnesium organometallic reagents occupy a central position in organic synthesis. The freshness of these compounds is the key for achieving a high conversion and reproducible results. Common methods for the synthesis of Grignard reagents from metallic magnesium present safety issues and exhibit a batch-to-batch variability. Tubular reactors of solid reagents combined with solution-phase reagents enable the continuous-flow preparation of organomagnesium reagents. The use of stratified packed-bed columns of magnesium metal and lithium chloride for the synthesis of highly concentrated turbo Grign

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38

Nicholas, Kenneth. "Sterochemistry of Organometallic and Inorganic Compounds. Vol.1." Organometallics 5, no. 8 (1986): 1756. http://dx.doi.org/10.1021/om00139a601.

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39

Hisatome, Masao, Masamichi Yoshihashi, Kenji Masuzoe, Koji Yamakawa, and Yoichi Iitaka. "Organometallic compounds. 41. [2]Metacyclo[2](1,1')ferrocenophane." Organometallics 6, no. 7 (1987): 1498–502. http://dx.doi.org/10.1021/om00150a022.

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40

Leman, John T., Henry A. Roman, and Andrew R. Barron. "Five- and six-coordinate organometallic compounds of indium." Organometallics 12, no. 8 (1993): 2986–90. http://dx.doi.org/10.1021/om00032a021.

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41

Kimura, Tsutomu, Koto Sekiguchi, Akane Ando, and Aki Imafuji. "Fritsch–Buttenberg–Wiechell rearrangement of magnesium alkylidene carbenoids leading to the formation of alkynes." Beilstein Journal of Organic Chemistry 17 (May 28, 2021): 1352–59. http://dx.doi.org/10.3762/bjoc.17.94.

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A series of 1-heteroatom-substituted vinyl p-tolyl sulfoxides were prepared and treated with organometallic reagents to evaluate which combination of sulfoxides and organometallic reagents yielded alkynes the most efficiently. The use of 1-chlorovinyl p-tolyl sulfoxide and isopropylmagnesium chloride was optimal for this purpose. A variety of 1-chlorovinyl p-tolyl sulfoxides were prepared from carbonyl compounds and chloromethyl p-tolyl sulfoxide and were converted into alkynes via the sulfoxide/magnesium exchange reaction and subsequent Fritsch–Buttenberg–Wiechell (FBW) rearrangement of the r

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42

Jutzi, P., and J. Dahlhaus. "Organometallic Compounds with Bridged or (Dimethylaminoethyl)-Substituted Cyclopentadienyl Ligands." Phosphorus, Sulfur, and Silicon and the Related Elements 87, no. 1-4 (1994): 73–82. http://dx.doi.org/10.1080/10426509408037441.

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43

Fujdala, Kyle L., David W. K. Gracey, Erica F. Wong, and Kim M. Baines. "The addition of organometallic reagents to tetramesityldigermene." Canadian Journal of Chemistry 80, no. 11 (2002): 1387–92. http://dx.doi.org/10.1139/v02-128.

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The thermolysis and photolysis of hexamesitylcyclotrigermane in the presence of ethylmagnesium bromide has been investigated. Under photochemical conditions, ethyldimesitylgermane, 1,2-diethyl-1,1,2-trimesityldigermane and ethyl-1,1,2,2-tetramesityldigermane were isolated and, under thermal conditions, 1,2,2-triethyl-1,1-dimesityl digermane and 2,2-diethyl-1,1,1-trimesityldigermane were isolated. The photolysis of hexamesitylcyclotrigermane in the presence of methyllithium has also been investigated. In both cases, the organometallic reagent adds to tetramesityl digermene and dimesitylgermylen

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44

Kabalka, George W., and Rajender S. Varma. "The synthesis of radiolabeled compounds via organometallic intermediates." Tetrahedron 45, no. 21 (1989): 6601–21. http://dx.doi.org/10.1016/s0040-4020(01)89131-6.

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45

Gečiauskaitė, Agota A., and Felipe García. "Main group mechanochemistry." Beilstein Journal of Organic Chemistry 13 (October 5, 2017): 2068–77. http://dx.doi.org/10.3762/bjoc.13.204.

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Over the past decade, mechanochemistry has emerged as a powerful methodology in the search for sustainable alternatives to conventional solvent-based synthetic routes. Mechanochemistry has already been successfully applied to the synthesis of active pharmaceutical ingredients (APIs), organic compounds, metal oxides, coordination compounds and organometallic complexes. In the main group arena, examples of synthetic mechanochemical methodologies, whilst still relatively sporadic, are on the rise. This short review provides an overview of recent advances and achievements in this area that further

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46

Novikova, O. V., O. V. Kuznetsova, and A. N. Egorochkin. "Electrochemical reduction of organic and organometallic compounds. Polarization effect in radical anions." Russian Journal of Organic Chemistry 43, no. 9 (2007): 1269–77. http://dx.doi.org/10.1134/s1070428007090023.

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47

AKITA, Munetaka, and Yoshihiko MORO-OKA. "Elucidation of Mechanisms of Syngas Reactions by Employing Organometallic Model Compounds." Journal of Synthetic Organic Chemistry, Japan 50, no. 8 (1992): 726–36. http://dx.doi.org/10.5059/yukigoseikyokaishi.50.726.

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48

S.J.S. "Spectroscopic properties of inorganic and organometallic compounds, vol. 21." Journal of Molecular Structure 222, no. 3-4 (1990): 509–10. http://dx.doi.org/10.1016/0022-2860(90)85058-q.

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49

Feshin, Valentin P., and Mikhail G. Voronkov. "The EFG Asymmetry Parameters at 35 Cl Nuclei and the Electronic Effects in Chlorine-Containing Organic and Complex Compounds of Group IVA and VA Elements." Zeitschrift für Naturforschung A 45, no. 3-4 (1990): 213–18. http://dx.doi.org/10.1515/zna-1990-3-404.

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Abstract The 35 CL NQR method and, in particular, the EFG asymmetry parameters at 35 Cl nuclei were used for the solution of a number of principal problems of theoretical organic and organometallic chemistry, such as the mechanism of non-induction influence of the heteroatom M on the atom Y in the non-linear Y-Z-M or Y-Z = M group, M-Cl bond multiplicity in planar molecular fragments and the asymmetry of halogen atom electron distribution in organic and organometallic molecules. In tetrahedral molecules this distribution is nearly axially symmetric for different M. This symmetry is also charac

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50

Ashraf, Adnan, Muhammad Hanif, Mario Kubanik, et al. "Aspirin-inspired organometallic compounds: Structural characterization and cytotoxicity." Journal of Organometallic Chemistry 839 (June 2017): 31–37. http://dx.doi.org/10.1016/j.jorganchem.2017.01.016.

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