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Relevant bibliographies by topics / Organometallic compounds. Carbonyl compounds. Complex compounds / Dissertations / Theses

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Dissertations / Theses on the topic 'Organometallic compounds. Carbonyl compounds. Complex compounds'

Author: Grafiati

Published: 4 June 2021

Last updated: 18 February 2022

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1

Williams, Michael Lloyd. "New aspects of organometallic chemistry /." Title page, contents and abstract only, 1985. http://web4.library.adelaide.edu.au/theses/09PH/09phw725.pdf.

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2

Kavakli, Cuneyt. "Synthesis And Characterization Of Carbonyl - Tungsten(0) Complexes Of [n,n&#039." Master's thesis, METU, 2005. http://etd.lib.metu.edu.tr/upload/12606101/index.pdf.

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In this study a bidentate ligand containing two ferrocenyl moieties, N,N&#039<br>-bis(ferrocenylmethylene)ethylenediamine, was prepared by condensation reaction of ferrocenecarboxyaldehyde and ethylenediamine on refluxing in benzene. The molecule was identified by IR, Raman, UV-VIS, 1H-, 13C-NMR spectroscopies. Then, this bidentate ligand was reacted with pentacarbonylbis-(trimethyl)silylethyne)tungsten(0). The ligand substitution reaction in dichloromethane yielded the new complex, tetracarbonyl [N,N&#039<br>-bis(ferrocenylmethylene)ethylenediamine]tungsten(0) (W(CO)4(BFEDA)). This new com

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3

Scheuermann, Margaret L. "Reactivity of PtII "Pincer" Complexes with Carbon Monoxide." Scholarship @ Claremont, 2008. https://scholarship.claremont.edu/scripps_theses/6.

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ABSTRACT Upon addition of carbon monoxide (CO) to a solution of (k-N, C, N-2, 6-bis(diethylaminomethyl)-phenyl)methyl platinum(II),[NCN]PtMe,(1), a ligand arm is displaced to form [SP-4-2] ((k-N,C-2,6-bis(diethylaminomethyl)-phenyl) carbonmethyl platinum(II), N[CN]Pt(CO)(Me),(2). Addition of CO to a THF solution of 2 results in the formation of [SP-4-3]((k-N,C-2,6-bis(diethylaminomethyl)-phenyl)acylcarbonyl platinum(II),N[CN]pt(Ac)(CO),(3). In THF ,2 partially isomerizes in the presence of CO to form [SP-4-4]((k-N,C-2,6-bis(diethylaminomethyl)-phenyl)carbonylmethyl platinum(II), N[CN]

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4

Wong, Wai-yeung. "The chemistry of triosmium alkylidyne carbonyl clusters /." Hong Kong : University of Hong Kong, 1995. http://sunzi.lib.hku.hk/hkuto/record.jsp?B18061606.

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5

黃維揚 and Wai-yeung Wong. "The chemistry of triosmium alkylidyne carbonyl clusters." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1995. http://hub.hku.hk/bib/B31234537.

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6

Liao, Jing-Piin. "A Reinvestigation of the Kinetics and Mechanism of Ligand Exchange in Mu-(2,2,8,8-Tetramethyl-3, 7-Dithianonane)-Decacarbonylditungsten(0)." Thesis, University of North Texas, 1988. https://digital.library.unt.edu/ark:/67531/metadc500831/.

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This student is interested in reinvestigating the kinetics and mechanism of the bridged compound in l,2-dichloroethane with triisopropyl phosphite and in finding the reasons why the values of competition ratio k₋₂ /k₃ in this reaction are so large.

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7

Pan, Jie. "Organometallic porphyrin based complexes for photophysical and biological application." HKBU Institutional Repository, 2016. https://repository.hkbu.edu.hk/etd_oa/331.

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This thesis focuses on the development of porphyrin-based complexes as multi-modal bio-imaging probes. Detailed studies of photophysical and biological properties were included.;In chapter 1, the general background of porphyrin and its derivatives, their structure specialty, synthetic methods, photophysical properties, and applications in biological system were described.;Curcumin-bridged porphyrin-copper complex (Por-Cu-Cur) which can permeate through the high blood-brain barrier, accumulate fast in brain tissues, and emit brilliant and stable two photon excited emission has been developed. A

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8

Fernández, Mateos Emilio. "New methodologies for the catalytic enantioselective addition of organometallic reagents to carbonyl compounds." Doctoral thesis, Universidad de Alicante, 2015. http://hdl.handle.net/10045/50227.

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9

Curtis, H. "Synthesis, characterisation and reactivity of transition metal carbido-carbonyl cluster and other organometallic compounds." Thesis, University of Cambridge, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.377825.

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10

Law, Man Chun 1979. "Organometallic reaction in ionic liquids : alkylation of carbonyl compounds with organozinc and organoaluminum reagents." Thesis, McGill University, 2004. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=82271.

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Alkylation of carbonyl compounds with diorganozinc, organozinc halides and organoaluminium reagents has been conducted in ionic liquids. Systems studied included solvents such as N-butylpyridinium tetrafluoroborate, 1-butyl-3-methylimidazolium tetrafluoroborate and 1-butyl-2,3-dimethylimidazolium tetrafluoroborate. Interestingly, reactivities of organometallics towards ionic liquids were revealed, yielding the imidazolylidene zinc complex formation in the case of alkylation with diethylzinc. Thus, different ways of ionic liquid preparations and purification methods were studied. The rea

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11

Gatter, Michael George. "Molecular orbital studies on the reactivity of organometallic hydride complexes and related species /." The Ohio State University, 1985. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487261919110337.

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12

Lock, S. J. "Water-tolerant organometallic reactions : nucleophilic additions to carbonyl compounds using allyl metals in aqueous solution." Thesis, Swansea University, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.637942.

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Against a background of the reactivity of traditional organometallics, this work describes nucleophilic addition reactions that take place <i>via</i> the intervention of metals in the presence of water. The experimental work focuses on allylation of aldehydes in water-containing solvents using nickel, bismuth and aluminium. Chapter 1 outlines the current influence of environmental issues on the practice of chemistry and the value of water as a solvent. Carbon-carbon bond formation is discussed in the context of mechanism and common methods are reviewed, particularly with respect to reaction of

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13

Chi, Xiang-yong. "A Sythetic Study of a Cyclic Siloxydiyne and its Iron Carbonyl Complex." Thesis, University of North Texas, 1989. https://digital.library.unt.edu/ark:/67531/metadc500871/.

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The synthetic studies include the synthesis of the cyclic siloxydiyne, 3,3,5,5,8,8,10,10-octamethyl-4,9-dioxa-3,5,8,10-tetrasilacyclodeca-1,6- diyne [VI] and its novel iron carbonyl complex. In the preparation of [VI] by HBr promoted condensation of bis (methoxydimethylsilyl) acetylene, a minor product, a cyclic trimer was always formed along with the major product [VI]. No evidence of an equilibrium between the trimerization product and the dimerization product was found. Compound [VI] can react with iron carbonyl reagents to produce a novel binuclear iron complex of trimethylenemethane [VII]

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14

McQuaid, Michael James. "Spectroscopic characterization of metal-based complexes and metal-based complex oxidation processes." Diss., Georgia Institute of Technology, 1989. http://hdl.handle.net/1853/30334.

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15

Gitlits, Alexander 1975. "Synthesis and structural survey of novel rare earth aryloxide and pyrazolate complexes." Monash University, Dept. of Chemistry, 2001. http://arrow.monash.edu.au/hdl/1959.1/8996.

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16

Guo, Jianping. "Synthesis, structure and characterization of long distance electrostatic force and hydrogen bond supramolecular polymers synthesis, structure and characterization of bis[2,4-di(pyridyl)-1,3,5-triazapenta-dienato] metal complexes." HKBU Institutional Repository, 2004. http://repository.hkbu.edu.hk/etd_ra/506.

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17

Ladogana, Santino. "Kinetics and Mechanisms of Metal Carbonyls." Thesis, University of North Texas, 1998. https://digital.library.unt.edu/ark:/67531/metadc278709/.

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Pulsed laser flash photolysis with both visible and infrared detection has been applied to the study of the displacement of weakly coordinating ligands (Lw) by strongly "trapping" nucleophiles (Ls) containing either an olefinic functionality (Ls = 1-hexene, 1-decene, 1-tetradecene) or nitrogen (Ls = acetonitrile, hydrocinnamonitrile) from the photogenerated 16 electron pentacarbonylchromium (0) intermediate. 5-Chloropent-l-ene (Cl-ol), a potentially bidentate ligand, has been shown to form (ol-Cl) pentacarbonylchromium (0), in which Cl-ol is bonded to Cr via a lone pair on the chlorine, and is

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18

Van, der Merwe Madelein. "Nuwe groep 6 metaalkarbonielkomplekse met tiofeenligande en Au(I)komplekse met tiasole." Thesis, Stellenbosch : Stellenbosch University, 2003. http://hdl.handle.net/10019.1/49774.

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19

Escárcega, Bobadilla Martha Verónica. "Organometallic compounds and metal nanoparticles as catalysts in low environmental impact solvents." Doctoral thesis, Universitat Rovira i Virgili, 2011. http://hdl.handle.net/10803/9114.

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Durant les darreres dècades, el disseny de processos en el marc de la química sostenible ha anat creixent de forma exponencial. La recerca constant de processos mes benignes amb el medi ambient ha implicat un gran esforç per obtenir millors rendiments mitjançant l'activació de llocs específics, i possant especial èmfasi amb el control de la quimio-, la regio- i la enantioselectivitat, punts crucials per a l'economia atómica. En aquest sentit, els dissolvents juguen un paper crític, i com podrà veure's al llarg d'aquesta memòria..<br/>Aquesta Tesi s'enfoca en l'ús de mitjans de reacció alternat

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20

Kjellgren, Johan. "Employment of Palladium Pincer Complex Catalysts and Lewis Acids for Synthesis and Transformation of Organometallic Compounds." Doctoral thesis, Stockholm : Dept. of Organic chemistry, Arrhenius Laboratory, Univ, 2005. http://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-416.

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21

Veenboer, Richard M. P. "Synthesis, study and application of NHC-gold(I) complexes." Thesis, University of St Andrews, 2017. http://hdl.handle.net/10023/12169.

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The development of procedures for the synthesis of valuable organic molecules constitutes an important part of chemistry. The goal of improving the efficiency of existing methodologies can be fulfilled by use of metal catalysts. Recent developments in the field of homogeneous gold catalysis have contributed to these efforts and continued investigations assure future innovations. Chapter 1 summarises the properties of gold and ligand-supported gold(I) complexes and demonstrates how a detailed understanding of its reactivity and possible bonding interactions with various substrates facilitates t

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22

Zhang, Hongyang. "Synthesis, characterization and properties of self-assembled metal complex nanosheets heterostructured organic microrods." HKBU Institutional Repository, 2019. https://repository.hkbu.edu.hk/etd_oa/607.

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Molecular self-assembly or ligand-metal assembly is a process in which several individual molecules and metal ions organize themselves into an ordered arrangement without external stimuli, the defined structures can lead to distinctive electronic and photonic performances. In the meantime, as the scale of materials decreases, various unique properties arise from their minute scaled dimensions, such as surface effect, volume effect, quantum effect and dielectric confinement effect, etc. Therefore, the design and fabrication of the micro- and nanomaterial via the technique of molecular self-asse

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23

Kocak, Fatma Sanem. "Synthesis And Characterization Of Tetracarbonyl[n,n&#039." Master's thesis, METU, 2005. http://etd.lib.metu.edu.tr/upload/12606094/index.pdf.

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In this study a bidentate ligand containing two ferrocenyl moieties, N,N&#039<br>-bis(ferrocenylmethylene)ethylenediamine, was prepared by condensation reaction of ferrocenecarboxyaldehyde and ethylenediamine on refluxing in benzene. The molecule was identified by IR, Raman, UV-Vis, 1H-, 13C-NMR spectroscopies. Then, this bidentate molecule was reacted with tetracarbonyl(bicyclo[2.1.1] hepta-2,5-diene)molybdenum(0). The ligand substitution reaction in toluene yielded the new complex, tetracarbonyl[N,N&acute<br>-bis(ferrocenylmethylene)ethylenediamine] molybdenum(0). This new complex could be i

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24

Edinc, Pelin. "Synthesis And Characterization Of Tetracarbonyl[6-ferrocenyl-2,2&#039." Master's thesis, METU, 2005. http://etd.lib.metu.edu.tr/upload/12606594/index.pdf.

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In this study, a bidentate ligand, 6-ferrocenyl-2,2&#039<br>-bipyridine, was prepared by the reaction of lithiated ferrocene with bipyridine. The ligand was identified by 1H, 13C- NMR and HMQC and UV-Vis spectroscopies. Then, bidentate molecule was reacted with pentacarbonylbis-(trimethylsilylethyne)tungsten(0). The ligand substitution reaction in CH2Cl2 yielded the new complex, tetracarbonyl(6-ferrocenyl-2,2&#039<br>bipyridine)tungsten(0). The isolated and purified complex was fully characterized by elemental analysis, IR, UV-Vis, MS, 1H and 13C- NMR spectroscopies. Tetracarbonyl(6-ferrocenyl

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25

Scott, Natalie M(Natalie Maree) 1976. "Diverse lanthanoid and lithium complexes with pendant donor amide ligands." Monash University, Dept. of Chemistry, 2001. http://arrow.monash.edu.au/hdl/1959.1/8984.

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26

Ercan, Bayram. "Substitution Kinetics Of The Pentacarbonylbis(trimethylsilyl)ethynetungsten(0) With Triphenylbismuthine." Master's thesis, METU, 2003. http://etd.lib.metu.edu.tr/upload/12604980/index.pdf.

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The reaction between pentacarbonylbis(trimethylsilyl)ethynetungsten(0), W(CO)5(&amp<br>#951<br>2-btmse), and triphenylbismuthine, Bi&Oslash<br>3, yields pentacarbonyltriphenylbismuthinetungsten(0), W(CO)5(Bi&Oslash<br>3), as the sole product. The kinetics of the substitution of btmse by Bi&Oslash<br>3 was studied by means of quantitative FT-IR Spectroscopy. The starting complex was prepared photochemically from hexacarbonyltungsten, W(CO)6, in the presence of excess btmse in n-hexane and identified by FT-IR and NMR Spectroscopies. The substitution reactions were performed in cyclohexane

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27

Wang, Dongqing. "NMR Study of the Reorientational and Exchange Dynamics of Organometallic Complexes." Thesis, University of North Texas, 1996. https://digital.library.unt.edu/ark:/67531/metadc278073/.

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Investigations presented here are (a) the study of reorientational dynamics and internal rotation in transition metal complexes by NMR relaxation experiments, and (b) the study of ligand exchange dynamics in transition metal complexes by exchange NMR experiments. The phenyl ring rotation in Ru3(CO)9(μ3-CO)(μ3-NPh) and Re(Co)2(CO)10(μ3- CPh) was monitored by 13C NMR relaxation experiments to probe intramolecular electronic and/or steric interactions. It was found that the rotation is relatively free in the first complex, but is restrained in the second one. The steric interactions in the compl

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28

Akyol, Ceyhun. "Tetracarbonyl[n,n." Master's thesis, METU, 2005. http://etd.lib.metu.edu.tr/upload/12605941/index.pdf.

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N,N&rsquo<br>-bis(ferrocenylmethylene)ethylenediamine was prepared from the reaction of ferrocenecarboxaldehyde and ethylenediamine and characterized by IR, Raman, 1H and 13C-NMR spectroscopy. The electrochemical behaviour of this ligand was also studied for the first time by cyclic voltammetry. Diferrocenyl diimine ligand was used in the thermal substitution of 1,5-cyclooctadiene in Cr(CO)4(2:2-1,5-cyclooctadiene) at 38&deg<br>C in toluene for two hours to form the tetracarbonyl[N,N&rsquo<br>-bis(ferrocenylmethylene)ethylenediamine]chromium(0), [Cr(CO)4(BFEDA)]. This complex was succesfully i

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29

Tumay, Tulay Asli. "Synthesis Of Ferrocenyl Cyclopentenones." Master's thesis, METU, 2005. http://etd.lib.metu.edu.tr/upload/3/12606372/index.pdf.

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ABSTRACT SYNTHESIS OF FERROCENYL CYCLOPENTENONES TUMAY, T&uuml<br>lay Asli M.S., Department of Chemistry Supervisor: Assoc. Prof. Dr. Metin Zora August 2005, 80 pages Construction of highly functionalized five-membered rings via cycloaddition reaction of cyclopropylcarbene-chromium complex with alkynes has become a very active area of research in recent years by virtue of their presence in antitumour natural products. Also with the finding that ferrocene derivatives are active against various tumours, considerable interest has been devoted to the synthesis of new ferrocene derivatives

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30

GOMES, DE LIMA LUIS CARLOS. "Reactions d'alcynes cyanes (monocyanoacethylene et dicyanoacethylene), vis-a-vis de complexes organometalliques du fer, du cobalt, du molybdene et du tungstene." Brest, 1986. http://www.theses.fr/1986BRES2009.

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Etude de la reactivite de complexes thiolates du fer et du tungstene (cp(co)::(n) m(sch::(3))) vis a vis du mono et du dicyanoacetylene. Aptitude des complexes de co(i) a intervenir dans la formation de molecules organiques. Nature des liaisons m-pb(m=mo ou w) dans les complexes cp(co)::(3)m-pbr::(3) et (cp(co)::(3)m)::(2) pbr::(2). Donnes de rmn de **(95)mo et **(207)pb

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31

Rouida, Bouchaïb. "Syntheses diastereoselectivites de complexes chiraux du molybdene et du fer carbonyle par action de derives asymetriques du phosphore." Paris 6, 1988. http://www.theses.fr/1988PA066515.

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La reaction photochimique de plusieurs phosphines asymetriques avec des complexes carbonyles du fer et du molybdene cyclopentadienyls fournit des complexes chiraux. Ceux-ci se forment par couples de diastereoisomeres en proportions variables. L'effet sterique de ces phosphines sur le mecanisme de reaction est etudie. D'autre part, lorsque le complexe cyclopentadienyl carbonyle du fer comporte une liaison fer-silicium, fer-germanium ou fer-etain il se produit des interactions conduisant a des inductions diastereotopiques importantes

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32

Binding, Samantha Carys. "Synthesis and characterisation of permethylpentalene complexes and permethylpentalene derivatives." Thesis, University of Oxford, 2015. http://ora.ox.ac.uk/objects/uuid:7855e90d-7ce9-42eb-b962-b68606ade746.

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This thesis expands the scope for using the permethylpentalene ligand and its precursors in the synthesis of organometallic complexes. <strong>Chapter one</strong> begins with a brief review of linked metallocenes, with which multimetallic compounds bridged by pentalene ligands have often been compared, followed by a comprehensive review of the routes used to make pentalenes and substituted pentalenes. Organometallic compounds of pentalenes are introduced, with a focus on bimetallic systems. <strong>Chapter two</strong> explores the diversification of substituents added to the permethylpentale

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33

Nuel, Didier. "Etude de la reactivite de fragments alkylidynes dans des clusters trinucleaires du fer." Toulouse 3, 1986. http://www.theses.fr/1986TOU30206.

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Reactivite des complexes fe::(3)(co)::(9)(cch::(3))(coc::(2)h::(5)) ou fe::(3)(co)::(10)(cch::(3))(h). Les reactions de couplage des groupes alkylidynes avec les algues sont faciles. L'action de co a mis en evidence le couplage reversible dans des conditions douces de 2 fragments alkylidynes. En general, la presence du coordinat hydruro rend les reactions plus complexes

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34

Gomes, de Lima Bernardes Miriam. "Réactivité de complexes organométalliques mono- et dinucléaires : synthèse de thiolato-composés du molybdène, du tungstène et du cobalt : étude de la formation de liaisons c-c dans la sphère de coordination du métal." Brest, 1986. http://www.theses.fr/1986BRES2008.

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Caracterisation des complexes ((c::(5)h::(5))(co)::(2) lwc(cf::(3)) = c(cf::(3))h) et (c::(5)h::(5))(co) lwc(o)c(cf::(3)) = c(cf::(3))h) (l=co,pr::(3),p(or)::(3)) synthese de complexes dinucleaires de mo et w. L'addition oxydante de dialkylsulfure a des derives biportes de mo(ii) et w(ii) a donne lieu a la formation de complexes thiolato triportes ((c::(5)h::(5))(co)m(mu -sr)::(3)m(co)(c::(5)h::(5)))tx**(-)

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35

Caminade, Anne-Marie. "Stabilisation par complexation d'entites phosphorees de basse coordinence." Toulouse 3, 1988. http://www.theses.fr/1988TOU30073.

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On obtient selon le substituant organique du phosphore, des complexes de phosphines, diphosphanes halogenes et de derives phosphores a base coordinence (phosphine, phosphalcine, diphosphine, phosphacumulene

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36

Foulet-Fonseca, Gloria. "Etude par spectroscopie vibrationnelle des complexes méthylcarbyniques et méthylcarbéniques de chrome." Paris 13, 1987. http://www.theses.fr/1987PA132028.

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Etude en particulier de complexes, du type br(co)::(4)crcch::(3), br(co)::(4)crcchd::(2) et d'une série de mélanges isotopiques. Mise en évidence de la non-équivalence des liaisons c-h du groupe methyle. Etablissement d'un champ de forces pour les complexes méthylcarbyniques

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37

Etienne, Michel. "Réactivité de complexes dinucléaires hydrure et alcénylidène ponte du fer vis-a-vis d'hydrocarbures cyanes insatures (mono et dicyanoacétylène, tétracyanoethylène)." Brest, 1988. http://www.theses.fr/1988BRES2009.

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Preparation de complexes avec des coordinats cyano-4 butadienyldene portants. On obtient egalement des complexes dinucleaires avec le tricyano-3,4,4 butadienylidene-1,3. Mecanisme ses reactions de migration de l'hydrogene allylique

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38

Jund, Rodolphe. "Electrochimie de clusters mixtes tetrametalliques." Université Louis Pasteur (Strasbourg) (1971-2008), 1987. http://www.theses.fr/1987STR13175.

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39

Laurent, Pascale. "Complexes acyl, alcoxycarbonyl et alkyl tetracarbonylfer : intermédiaires dans la carbonylation catalytique d'halogénures d'alkyle." Brest, 1989. http://www.theses.fr/1989BRES2002.

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40

Neff, Denis. "Complexes alleniques de cyclopentadienyle manganese dicarbonyle : acces aux allenes optiquement actifs, etude de photodecomplexations et syntheses de complexes difonctionnels." Université Louis Pasteur (Strasbourg) (1971-2008), 1988. http://www.theses.fr/1988STR13122.

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41

Tingry, Sophie. "Synthèse et application en hydrogénation électrocatalytique de films de polypyrrole fonctionnalisés par des complexes du rhodium et de l'iridium." Université Joseph Fourier (Grenoble ; 1971-2015), 1996. http://www.theses.fr/1996GRE10137.

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Ce memoire est consacre a la synthese d'electrodes modifiees (em) par des films de polypyrroles fonctionnalises par des complexes polypyridiniques de metaux de transition et a leur application en electrocatalyse en milieu aqueux. Une partie de ce travail de recherche a ete orientee vers l'amelioration de l'efficacite, de la stabilite et de la selectivite de films de polymeres derives des complexes rh(l)#2(cl)#2#+ (l=2,2'-bipyridine ou 1,10-phenanthroline substituees), vis-a-vis de l'hydrogenation electrocatalytique (hec) de substrats organiques insatures. En particulier, nous avons montre que

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42

Boukhris, Abdallah. "Étude par diffraction des rayons X des porphyrines de gallium, germanium et indium, synthons potentiels de conducteurs électriques unidimensionnels." Nancy 1, 1986. http://www.theses.fr/1986NAN10038.

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Étude des composés GA(OEP)(SO::(3)CH::(3)), GA(OEP)N::(3), GE(TPMEPP)(N::(3))::(2), GE(OEP)F::(2) et (OEP) IN-MN(CO)::(5). Caractérisation des groupements azido dans les porphyrines de gallium et de germanium. Première liaison simple métat-métal dans la série des métalloporphyrines. Dopage de fluoro-octaethylporphyrines de gallium et d'octaméthylporphyrines de nickel par l'iode moléculaire. Incommensurabilité des réseaux iode et porphyrine, caractère polymérique des métalloporphyrines. Étude de la conductivité électrique

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43

Makunya, Ntaoleng Maureen. "Tertiary phosphine induced migratory carbonyl insertion in cyclopentadienyl complexes of iron." Thesis, 2008. http://hdl.handle.net/10210/393.

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The aim of this study was to investigate the mechanism of phosphine induced migratory carbonyl insertion in the monocyclopentadienyliron(II) carbonyl complex, [η5- (C5H5)Fe(CO)2Me], upon variation of different parameters such as the type and the concentration of the phosphine ligand and the solvent. The mechanism that agrees with the results obtained is presented below.<br>Prof. A. Roodt

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Kruger, Friedrich Wilhelm Hein. "Die sintese en reaksies van [pie]-trikarbonielchroomindoolderivate." Thesis, 2014. http://hdl.handle.net/10210/9298.

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"1,2-rearrangements of porphyrinato rhodium (III) alkyls- mechanistic investigation." 1998. http://library.cuhk.edu.hk/record=b6073084.

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by Kin Wah Mak.<br>Thesis (Ph.D.)--Chinese University of Hong Kong, 1998.<br>Includes bibliographical references (p. 180-195).<br>Electronic reproduction. Hong Kong : Chinese University of Hong Kong, [2012] System requirements: Adobe Acrobat Reader. Available via World Wide Web.<br>Mode of access: World Wide Web.

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"Selective carbon(carbonyl)-carbon(α) bond activation of ketones by group 9 metalloporphyrins". 2012. http://library.cuhk.edu.hk/record=b5549608.

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本文主要探討在有水的條件下，分別以銠卟啉和鈷卟啉絡合物與無張酮反應發生選擇羰基碳及α碳(C(CO)-C(α))鍵活化（下稱碳碳鍵活化）的反應活性和反應機。<br>在200°C，無張芳香和脂肪酮與5, 10, 15, 20-(四甲苯) 銠卟啉絡合物（RhIII(ttp)X，X = Cl 和Me）進反應，生成相對應的碳碳鍵活化產物－銠卟啉酰基絡合物，產最高可達97%。與甲基和乙基酮衍生物相比，丙基酮衍生物有較高的活性,而且丙基酮衍生物的碳碳鍵活化反應甚至能在50°C 的低溫條件下進。<br>根據化學計學，環酮的碳碳鍵開環反應顯示RhIII(ttp)OH 是斷開C(CO)-C(α)鍵的中間體。<br>進一步的反應機研究表明， RhIII(ttp)OH 的羥基是從水中得。RhIII(ttp)X首先進α碳氫鍵活化生成動學產物。經過水解，α碳氫鍵活化產物可以重新形成RhIII(ttp)OH。然後，RhIII(ttp)OH 繼續進碳碳鍵活。<br>另外，經濟的5, 10, 15, 20-(四甲苯) 鈷卟啉絡合物與丙基酮衍生物反應，在室溫下可選擇性進碳碳鍵活化並得到鈷卟啉酰基化合物，產最高達82%。根據化學計學，CoIII(ttp)OH 被認為是碳碳鍵活化的中間體。CoIII(ttp)OH很有可能是通過鈷卟啉與水的歧化反應生成的。<br>This thesis focuses on the rea

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47

Shawkataly, Omar bin. "Some aspects of the chemistry of metal clusters / by Omar bin Shawkataly." 1987. http://hdl.handle.net/2440/21530.

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One microfiche--`Data from crystal structures solved by the author`--in pocket<br>Bibliography: leaves 172-174<br>174 leaves : ill ; 30 cm.<br>Title page, contents and abstract only. The complete thesis in print form is available from the University Library.<br>Thesis (Ph.D.)--University of Adelaide, Dept. of Physical and Inorganic Chemistry, 1987

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Muller, Alfred Johannes. "Steric and electronic effects of phosphine and phosphite ligands in vaska-type complexes of rodium." Thesis, 2008. http://hdl.handle.net/10210/1201.

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Ph.D.<br>In order for any new useful complexes to be developed, whether of catalytic, biological or of other importance, it is very important that sufficient knowledge exists regarding the fundamental principles applying to the chemistry involved. In all chemical processes involving metal complexes, the coordinated ligands govern the reactions to a great extent. It is thus very important that the properties (solubility, reactivity, steric bulk, etc.) of various ligands of these complexes is clearly understood in order to enable intelligent adjustments to be made, inducing the effects of choice

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Valadez, Travis N. "Reactions of Group 4 Diene Complexes with Isonitriles and Carbon Monoxide." Thesis, 2016. https://doi.org/10.7916/D8028RRQ.

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Organometallic chemistry is a powerful tool for the coupling of simple unsaturated molecules to form complex organic structures. Isonitriles (RNCs) are an attractive alternative to isoelectronic CO as C₁ sources in the pursuit of C,C coupling reactions. The electronic properties of the substituent on nitrogen in RNCs can bring about insertion chemistry that is different from the insertion reactions of CO. The insertion chemistry of RNCs with Group 4 (Ti, Zr, and Hf) butadiene complexes will be described. Cp*(Cl)Ti(2,3-dimethylbutadiene) (2.1) reacts with two equivalents of RNC

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Liu, Pey-Horng, and 劉沛宏. "Oxygen Transfer and Electron Transfer in the Reduction of Nitro- Compounds by Rhodium Carbonyl Complex." Thesis, 1994. http://ndltd.ncl.edu.tw/handle/54227817907979822319.

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