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Journal articles on the topic 'Organometallic mercury compounds'

Author: Grafiati

Published: 5 June 2025

Last updated: 1 August 2025

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1

Deacon, GB, and GN Stretton. "Organomercury Compounds. XXVII. The Synthesis and Properties of Some Carboxylato- and Carboxy-pyridinylmercurials." Australian Journal of Chemistry 38, no. 3 (1985): 419. http://dx.doi.org/10.1071/ch9850419.

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Decarboxylation of mercuric pyridine-2,3-dicarboxylate in hot dimethyl sulfoxide or hexamethylphosphoramide gives a mixture of 2-carboxylatopyridin-3-ylmercury(II) (major product) and 3- carboxylatopyridin-2-ylmercury(II) (minor product). The mixture reacts ( i ) with acidified halide ions ( Cl - or I-) to yield a mixture of the corresponding carboxypyridinyl ( halogeno )mercury(II) derivatives, (ii) with tribromide ions to give the bromo ( carboxypyridinyl )mercury(ii) complexes, 3-bromopyridine-2-carboxylic acid, and 2-bromopyridine-3- carboxylic acid, and (iii) with iodide ions in hot aqueo

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2

Moscoso-Pérez, C., V. Fernández-González, J. Moreda-Piñeiro, P. López-Mahía, S. Muniategui-Lorenzo, and D. Prada-Rodríguez. "Multivariate optimization of PTV-GC-MS method for simultaneous determination of organometallic compounds of mercury, lead and tin." Analytical Methods 8, no. 42 (2016): 7702–10. http://dx.doi.org/10.1039/c6ay02212j.

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3

Hoke, W. E., P. J. Lemonias, and R. Korenstein. "An examination of organometallic thermal stability and its relevance to low-temperature MOCVD growth of HgCdTe." Journal of Materials Research 3, no. 2 (1988): 329–34. http://dx.doi.org/10.1557/jmr.1988.0329.

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A well-established stability model for hydrocarbon molecules is reviewed and then applied to organometallic compounds used in the epitaxial growth of HgCdTe films. For hydrocarbon molecules, the strength of carbon-hydrogen bonds is modified by neighboring organic groups. The mechanism for this effect is delocalization of the free radical electronic charge by the neighboring groups. The delocalization effect is present in organometallic compounds and is illustrated for tellurium, mercury, and cadmium compounds. An important application of the delocalization effect is the development of a low-te

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4

Schwerdtfeger, Peter, Peter D. W. Boyd, Stephane Brienne, et al. "The mercury-mercury bond in inorganic and organometallic compounds. A theoretical study." Inorganica Chimica Acta 213, no. 1-2 (1993): 233–46. http://dx.doi.org/10.1016/s0020-1693(00)83833-5.

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5

Al-Rubaie, Ali Z., Shaker A. S. Al-Jadaan, Anwar T. Abd Al-Wahed, and Ibraheem A. Raadah. "Synthesis, characterization and biological studies of some new organometallic compounds containing mercury, selenium and tellurium based on p-aminobenzoic acid." Journal of Physics: Conference Series 2063, no. 1 (2021): 012003. http://dx.doi.org/10.1088/1742-6596/2063/1/012003.

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Abstract Ten chalcogen and mercury bearing compounds based on 4-aminobenzoic acid (i.e., (2-amino-5-(ethoxycarbonyl)phenyl)mercury(II) chloride (1), (2-amino-5-(ethoxycarbonyl)phenyl) phenyl selenide (2), (2-amino-5-(ethoxycarbonyl)phenyl) phenyl telluride (3), (4-carboxyphenyl)mercury(II) chloride (4), 4-selenocyanatobenzoic acid (5), 4-tellurocyanatobenzoic acid (6), bis(4-carboxyphenyl) diselenide (7) bis(4-carboxyphenyl) ditelluride (8), bis(4-carboxyphenyl) selenide (9) bis(4-carboxyphenyl) telluride (10) were prepared and characterized by various spectroscopic techniques. All compounds w

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6

Busato, Matteo, Jesús Castro, Domenico Piccolo, and Marco Bortoluzzi. "Mercury Monohalides as Ligands in Transition Metal Complexes." Molecules 30, no. 1 (2025): 145. https://doi.org/10.3390/molecules30010145.

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The main categories of transition metal–mercury heterometallic compounds are briefly summarized. The attention is focused on complexes and clusters where the {Hg-Y} fragment, where Y represents a halide atom, interacts with transition metals. Most of the structurally characterized derivatives are organometallic compounds where the transition metals belong to the Groups 6, 8, 9 and 10. More than one {Hg-Y} group can be present in the same compound, interacting with the same or with different transition metals. The main synthetic strategies are discussed, and structural data of representative co

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7

Holloway, Clive E., and Milan Melník. "Mercury organometallic compounds. Classification and analysis of crystallographic and structural data." Journal of Organometallic Chemistry 495, no. 1-2 (1995): 1–31. http://dx.doi.org/10.1016/0022-328x(95)05395-6.

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8

Bond, A. M., R. T. Gettar, N. M. McLachlan, and G. B. Deacon. "Oxidation of mercury electrodes in the presence of phenyl-mercury, -lead and -bismuth organometallic compounds in dichloromethane." Inorganica Chimica Acta 166, no. 2 (1989): 279–89. http://dx.doi.org/10.1016/s0020-1693(00)80821-x.

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9

HOLLOWAY, C. E., and M. MELNIK. "ChemInform Abstract: Mercury Organometallic Compounds. Classification and Analysis of Crystallographic and Structural Data." ChemInform 26, no. 44 (2010): no. http://dx.doi.org/10.1002/chin.199544282.

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10

Schumann, Herbert, Silke Freitag, Frank Girgsdies, Holger Hemling, and Gabriele Kociok-Köhn. "Homoleptic Organometallic Compounds of Zinc, Cadmium, and Mercury, Intramolecularly Stabilized by Amine Ligands." European Journal of Inorganic Chemistry 1998, no. 2 (1998): 245–52. http://dx.doi.org/10.1002/(sici)1099-0682(199802)1998:2<245::aid-ejic245>3.0.co;2-t.

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11

Sokolov, Viatcheslav I., and Vasily V. Bashilov. "New Studies in Fullerene Chemistry." Platinum Metals Review 42, no. 1 (1998): 18–24. http://dx.doi.org/10.1595/003214098x4211824.

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Studies on fullerene chemistry carried out in the Laboratory of Organometallic Stereochemistry at INEOS, Moscow, are briefly reported. These include work with platinum metals complexes, in particular, on novel methods of preparing η2if fullerene (C60 and C70) complexes of platinum, palladium, rhodium and iridium. A new approach is the use of mercury-platinum bimetallic compounds, R-Hg-PtL2-X, as a source of the PtL2 moiety to be transferred onto a (6:6) double bond in fullerenes. Bis(aryl)platinum(II) complexes can react similarly. Other products of this reaction are discussed. The first optic

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12

El-Hamruni, Salima M., Sebnem E. Sözerli, J. David Smith, Martyn P. Coles, and Peter B. Hitchcock. "Tin and Mercury Compounds Supported by a Bulky Organometallic Ligand Incorporating a Pendant Guanidine Functionality." Australian Journal of Chemistry 67, no. 7 (2014): 1071. http://dx.doi.org/10.1071/ch14255.

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The structure of a triclinic form of the organolithium derivative LiR, R = C(SiMe3)2(SiMe2{hpp}) (1) (hppH = 1,3,4,6,7,8,-hexahydro-2H-pyrimido[1,2-a]pyrimidine) comprises dimers [1]2 held together by Li···H3C interactions like those in the polymeric structure [1]∞ of the previously described orthorhombic form. Compound 1 reacts with the chlorides MCl2 (M = Hg or Sn) to give compounds HgRCl (2) or SnRCl (3), which have been characterised by NMR spectroscopy and X-ray crystallography. The structural parameters and conformations of the metallacycles MRLn are compared with those in related compou

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13

K., BAG, and SINHA C. "Chemistry of N,S Donor Ligands : Synthesis and Spectral Characterisation of Thioazobenzene/Thioazomethine Mercury(II) Chloride." Journal of Indian Chemical Society Vol. 74, Oct 1997 (1997): 763–64. https://doi.org/10.5281/zenodo.5896708.

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Department of Chemistry, The University of Burdwan, Burdwan-713 1 04 <em>Manuscript received 5 June 1996, accepted 18 November 1996</em> Mercuric chloride reacts with thioazobenzenelthioazomethinc in methanol under refluxing condition and orange products are isolated on slow evaporation. The compounds are five-membered N,S chelate having tetrahedral structure of Hg(N,S)CI<sub>2</sub>.

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14

Fowley, Lissa A., Jesse C. Lee, Robert H. Crabtree та Per E. M. Siegbahn. "Formation of organometallic exciplexes of the type [Hg(η2-arene)] in mercury photosensitized reactions of aromatic compounds". Journal of Organometallic Chemistry 504, № 1-2 (1995): 57–67. http://dx.doi.org/10.1016/0022-328x(95)05613-t.

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15

Steigerwald, M. L., and C. R. Sprinkle. "Organometallic synthesis of II-VI semiconductors. 1. Formation and decomposition of bis(organotelluro)mercury and bis(organotelluro)cadmium compounds." Journal of the American Chemical Society 109, no. 23 (1987): 7200–7201. http://dx.doi.org/10.1021/ja00257a055.

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16

Rosenkranz, B., J. Bettmer, W. Buscher, C. Breer, and K. Cammann. "The behaviour of different organometallic compounds in the presence of inorganic mercury(II): transalkylation of mercury species and their analysis by the GC-MIP-PED system." Applied Organometallic Chemistry 11, no. 9 (1997): 721–25. http://dx.doi.org/10.1002/(sici)1099-0739(199709)11:9<721::aid-aoc638>3.0.co;2-h.

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17

Centineo, Giuseppe, Elisa Blanco González, and Alfredo Sanz-Medel. "Multielemental speciation analysis of organometallic compounds of mercury, lead and tin in natural water samples by headspace-solid phase microextraction followed by gas chromatography–mass spectrometry." Journal of Chromatography A 1034, no. 1-2 (2004): 191–97. http://dx.doi.org/10.1016/j.chroma.2004.01.051.

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18

N. Kingsley, Owhonda. "Evaluation of Cadmium, Arsenic, Mercury, Lead, Nickel and Speciated Organometallic Compounds in Tilapia guineensis, Sarotherodon melanotheron and Mullet (Liza falcipinnis) Found in Buguma River, Rivers State, Nigeria." Journal of Environmental Science and Public Health 01, no. 01 (2017): 57–67. http://dx.doi.org/10.26502/jesph.9612006.

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19

Ólafsson, Sigurjon N., Águst Kvaran, Sigridur Jonsdottir, and Sigridur G. Suman. "Non-rigid coordination behavior of the ambidentate phosphinoyldithioformate ligands, [S 2 CP(O)R 2 ] - , (R = Ph, CH 2 Ph) in organometallic Lead(IV) and Mercury(II) compounds." Journal of Organometallic Chemistry 854 (January 2018): 38–48. http://dx.doi.org/10.1016/j.jorganchem.2017.11.002.

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20

Beceiro-González, E., A. Guimaraes, and M. F. Alpendurada. "Optimisation of a headspace-solid-phase micro-extraction method for simultaneous determination of organometallic compounds of mercury, lead and tin in water by gas chromatography–tandem mass spectrometry." Journal of Chromatography A 1216, no. 29 (2009): 5563–69. http://dx.doi.org/10.1016/j.chroma.2009.05.056.

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21

Sankar, P. Dey, and K. Mallik Asok. "Formation of organo-mercuric compounds by mercuric acetate oxidation of 2' -allyloxy-5-chloroacetophenone oxime and 2' -allyloxy-5-chloroacetophenone." J. Indian Chem. Soc. Vol. 88, Mar 2011 (2011): 437–41. https://doi.org/10.5281/zenodo.5766076.

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Department of Chemistry. Srikrishna College, Bagula-741 502, Nadia, West Bengal, India <em>E-mail</em> : deysp2002@yahoo.co. in Department of Chemistry, Jadavpur University, Kolkata-700 032, India <em>E-mail</em> : mallikak52@yahoo.co.in <em>Manuscript received 22 April 2010, revised 30 June 2010, accepted 07 July 2010</em> On treatment with mercuric acetate 2' -allyloxy-5-chloroacctophenone oxime and 2' -aryloxy-5-chloroacetophenonc afforded organo-mercuric compounds in excellent yield at room temperature.

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22

Bag, K., N. K. De, B. R. De, and C. Sinha. "Arylazopyridines-mercury(II) coordination and organometallic compounds: Theoretical support." Proceedings / Indian Academy of Sciences 109, no. 3 (1997). http://dx.doi.org/10.1007/bf02883484.

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23

Maqsood, Fozia, Sawsan S. Al-Rawi, Ahmad H. Ibrahim, et al. "Recent trends in medicinal applications of mercury based organometallic and coordination compounds." Reviews in Inorganic Chemistry, August 16, 2024. http://dx.doi.org/10.1515/revic-2024-0033.

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Abstract Metal-based drugs are finding new medical applications, particularly in antibacterial therapies. Compounds such as Prontosil and ciprofloxacin, as well as its derivatives such as beta-lactam drugs, aminoglycosides, vancomycin, fosfomycin, as well as tetracyclines, play critical roles in the prevention of bacterial and fungal infections. The increasing prevalence of microbial resistance is prompting the use of metal complexes to tackle fungal and bacterial strains. Mercury-based complexes, which are known for their unusual characteristics and reactivity, have received a lot of interest

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24

N.K, Owhonda,. "Analysis of cadmium, arsenic, mercury, lead, nickel and speciated organometallic compounds in the edible flesh of Tilapia guineensis, Sarotherodon melanotheron and mullet (Liza falcipinnis) found in Choba river (New Calabar River), Rivers State, Nigeria." Sustainable Marine Structures 2, no. 2 (2021). http://dx.doi.org/10.36956/sms.v2i2.301.

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The edible flesh of guinean tilapia (Tilapia guineensis), blackchin tilapia (Sarotherondon melanotheron) and mullet (Liza falcipinnis) were collected from Choba river for elemental studies of cadmium, mercury, arsenic, lead, nickel and speciated forms of elements using X-ray fluorescence (XRF) and Gas chromatography-mass spectrometer (GC-MS) respectively. The highest concentration of cadmium (4.3mg/kg) was observed in Sarotherodon melanotheron. They all contained about the same concentration of arsenic (0.5mg/kg) and mercury (1mg/kg). The highest concentration of lead was detected in mullet (1

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25

MIGINIAC, L. "ChemInform Abstract: Carbon - Carbon Bond Formation Using Organometallic Compounds of Zinc, Cadmium, and Mercury." Chemischer Informationsdienst 17, no. 33 (1986). http://dx.doi.org/10.1002/chin.198633332.

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26

Gedridge, Robert W., Kelvin T. Higa, and Robin A. Nissan. "New Organotellurium Precursors for the Pyrolytic and Photolytic Deposition of Hg1-xCdxTe." MRS Proceedings 131 (1988). http://dx.doi.org/10.1557/proc-131-69.

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ABSTRACTOrganometallic precursors with low decomposition temperatures are essential in the fabrication of high performance mercury cadmium telluride (Hg1-xCdxTe) infrared detectors by pyrolytic and photolytic metal-organic chemical vapor deposition (MOCVD). Film growth temperature is governed by the relative stability and/or reactivity of the organotellurium precursor, which is determined by the strength of the Te-C bonds. Since the rate-determining step in the pyrolysis of organometallic compounds involves bond breaking and free radical formation, we have concentrated on the synthesis of a va

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27

Tetteh, Samuel. "The Cambridge structural database (CSD): important resources for teaching concepts in structural chemistry and intermolecular interactions." Physical Sciences Reviews, January 19, 2023. http://dx.doi.org/10.1515/psr-2022-0325.

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Abstract The Cambridge Structural Database (CSD) is a repository of all published organic and metal-organic crystal structures of small molecules. These compounds have been crystallized under different conditions and have variable bond parameters and molecular landscapes. Entries in the database therefore serve as real models that can be used to illustrate structural properties such as bond angles, bond distances, torsion angles and other intra- and intermolecular interactions. This paper illustrates how the CSD programs ConQuest and Mercury can be used to search the database for 3D molecular

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28

STEIGERWALD, M. L., and C. R. SPRINKLE. "ChemInform Abstract: Organometallic Synthesis of II-VI Semiconductors. Part 1. Formation and Decomposition of Bis(organotelluro)mercury and Bis(organotelluro)cadmium Compounds." ChemInform 19, no. 10 (1988). http://dx.doi.org/10.1002/chin.198810292.

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29

Pearce, Kyle G., Chiara Dinoi, Ryan J. Schwamm, Laurent Maron, Mary F. Mahon, and Michael S. Hill. "Variable Ca‐C_aryl Hapticity and its Consequences in Arylcalcium Dimers." Advanced Science, September 15, 2023. http://dx.doi.org/10.1002/advs.202304765.

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AbstractThe dimeric β‐diketiminato calcium hydride, [(DippBDI)CaH]2 (DippBDI = HC{(Me)CN‐2,6‐i‐Pr2C6H3}2), reacts with ortho‐, meta‐ or para‐tolyl mercuric compounds to afford hydridoarylcalcium compounds, [(DippBDI)2Ca2(μ‐H)(μ‐o‐,m‐,p‐tolyl)], in which dimer propagation occurs either via μ2‐η1‐η1 or μ2‐η1‐η6 bridging between the calcium centers. In each case, the orientation and hapticity of the aryl units is dependent upon the position of the methyl substituent. While wholly organometallic meta‐ and para‐tolyl dimers, [(DippBDI)Ca(m‐tolyl)]2 and [(DippBDI)Ca(p‐tolyl)]2, can be prepared and a

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