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Journal articles on the topic 'Palladium-catalysed reactions'

Author: Grafiati

Published: 7 September 2021

Last updated: 29 July 2025

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1

P., G. MORE, J. DESAI B., and N. POWAR T. "Transition Metal catalysed Reactions of Organomercurials. II. Palladium-catalysed Carbonylation Reactions." Journal of Indian Chemical Society Vol. 72, Mar 1995 (1995): 191–92. https://doi.org/10.5281/zenodo.5902010.

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Shivraj College of Science, Gadhinglaj-416 502 <em>Manuscript received 12 August 1993, accepted 16 November 1993</em> Transition Metal catalysed Reactions of Organomercurials. II. Palladium-catalysed Carbonylation Reactions

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2

Cooper, Alasdair K., Paul M. Burton, and David J. Nelson. "Nickel versus Palladium in Cross-Coupling Catalysis: On the Role of Substrate Coordination to Zerovalent Metal Complexes." Synthesis 52, no. 04 (2019): 565–73. http://dx.doi.org/10.1055/s-0039-1690045.

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A detailed comparison of the effect of coordinating functional groups on the performance of Suzuki–Miyaura reactions catalysed by nickel and palladium is reported, using competition experiments, robustness screening, and density functional theory calculations. Nickel can interact with a variety of functional groups, which manifests as selectivity in competitive cross-coupling reactions. The presence of these functional groups on exogenous additives has effects on cross-coupling reactions that range from a slight improvement in yield to the complete cessation of the reaction. In contrast, palla

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3

Fanning, Kate, Andrew Jamieson, and Andrew Sutherland. "Palladium(II)-Catalysed Rearrangement Reactions." Current Organic Chemistry 10, no. 9 (2006): 1007–20. http://dx.doi.org/10.2174/138527206777435490.

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4

Silva, Vera L. M., and Artur M. S. Silva. "Palladium-Catalysed Synthesis and Transformation of Quinolones." Molecules 24, no. 2 (2019): 228. http://dx.doi.org/10.3390/molecules24020228.

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Palladium-catalysed reactions have had a large impact on synthetic organic chemistry and have found many applications in target-oriented synthesis. Their widespread use in organic synthesis is due to the mild conditions associated with the reactions together with their tolerance of a wide range of functional groups. Moreover, these types of reactions allow the rapid construction of complex molecules through multiple bond-forming reactions in a single step, the so-called tandem processes. Pd-catalysed reactions have been applied to the synthesis of a large number of natural products and bioacti

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5

Payne, China M., Kyulee Cho, and David S. Larsen. "5-Bromo-norborn-2-en-7-one derivatives as a carbon monoxide source for palladium catalyzed carbonylation reactions." RSC Advances 9, no. 53 (2019): 30736–40. http://dx.doi.org/10.1039/c9ra06594f.

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Norbornenone (5b), obtained from the reaction of 2,5-dimethyl-3,4-diphenylcyclopentadienone dimer (3) with bromomaleic anhydride (4b), provides an excellent base-triggered source of carbon monoxide for palladium-catalysed carbonylation reactions.

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6

Mitchell, Terence N. "Palladium-Catalysed Reactions of Organotin Compounds." Synthesis 1992, no. 09 (1992): 803–15. http://dx.doi.org/10.1055/s-1992-26230.

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7

de Vries, Johannes G. "ChemInform Abstract: Palladium-Catalysed Coupling Reactions." ChemInform 44, no. 11 (2013): no. http://dx.doi.org/10.1002/chin.201311247.

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8

Boruah, Preeti Rekha, Abdul Aziz Ali, Bishwajit Saikia, and Diganta Sarma. "A novel green protocol for ligand free Suzuki–Miyaura cross-coupling reactions in WEB at room temperature." Green Chemistry 17, no. 3 (2015): 1442–45. http://dx.doi.org/10.1039/c4gc02522a.

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A highly efficient green protocol for palladium acetate-catalysed ligand-free Suzuki–Miyaura cross-coupling reactions in neat ‘water extract of banana (WEB)’ was developed. Suzuki–Miyaura reaction proceeds in WEB at very short reaction times under ‘ligand/external base/external promoters/organic medium’ free conditions.

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9

Gao, Run-Duo, Scott A. Shuler, and Donald A. Watson. "Tandem aza-Heck Suzuki and carbonylation reactions of O-phenyl hydroxamic ethers: complex lactams via carboamination." Chemical Science 12, no. 25 (2021): 8859–64. http://dx.doi.org/10.1039/d1sc02075g.

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10

Chen, Weiping, Lijin Xu, Craig Chatterton, and Jianliang Xiao. "Palladium catalysed allylation reactions in ionic liquids." Chemical Communications, no. 13 (1999): 1247–48. http://dx.doi.org/10.1039/a903323h.

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11

Grigg, Ronald, and Visuvanathar Sridharan. "Palladium catalysed intermolecular cascade cyclisation - cyclopropanation reactions." Tetrahedron Letters 33, no. 51 (1992): 7965–68. http://dx.doi.org/10.1016/s0040-4039(00)74790-3.

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12

Legros, Jean-Yves, Martial Toffano, André Boutros, Christophe Moinet, and Jean-Claude Fiaud. "Control of selectivities in palladium-catalysed reactions." Comptes Rendus de l'Académie des Sciences - Series IIC - Chemistry 3, no. 1 (2000): 3–10. http://dx.doi.org/10.1016/s1387-1609(00)00104-3.

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13

Kalinin, Valery N., Fedor S. Denisov, and Yurii N. Bubnov. "Allylboranes in palladium-catalysed cross-coupling reactions." Mendeleev Communications 6, no. 5 (1996): 206–7. http://dx.doi.org/10.1070/mc1996v006n05abeh000648.

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14

Smith, Catherine J., Tessa R. Early, Andrew B. Holmes, and Richard E. Shute. "Palladium catalysed cross-coupling reactions of silylamines." Chem. Commun., no. 17 (2004): 1976–77. http://dx.doi.org/10.1039/b406868h.

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15

Dey, Aniruddha, Soumitra Agasti, and Debabrata Maiti. "Palladium catalysed meta-C–H functionalization reactions." Organic & Biomolecular Chemistry 14, no. 24 (2016): 5440–53. http://dx.doi.org/10.1039/c6ob00395h.

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16

Gadge, Sandip T., and Bhalchandra M. Bhanage. "Recent developments in palladium catalysed carbonylation reactions." RSC Advances 4, no. 20 (2014): 10367. http://dx.doi.org/10.1039/c3ra46273k.

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17

Gu, Binjie, Xiaoli Yu, Zhaojun Xu, Feng Pan, and Dawei Wang. "A Single-Step Palladium-Catalysed Synthesis of Naphtho[2,3-b]Benzofuran-6,11-Diones and 2-(Hydroxyphenyl)Naphthalene-1,4-Diones." Journal of Chemical Research 41, no. 10 (2017): 564–68. http://dx.doi.org/10.3184/174751917x15045169836235.

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Palladium-catalysed competitive three-component C–H functionalisation reactions and cascade coupling ring-closing reactions of quinones with iodophenols in dihaloalkanes are described. During initial attempts to conduct C–H functionalisation reactions of quinones with iodophenols in dihaloalkanes, surprisingly a three-component C–H functionalisation reaction was discovered. Furthermore, as the reaction of chloroquinones with iodophenols was in progress, another surprising cascade coupling with ring closure was achieved. This provided an efficient single-step synthesis of naphtho[2,3- b]benzofu

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18

Pahlevanneshan, Zari, Majid Moghadam, Valiollah Mirkhani, Shahram Tangestaninejad, Iraj Mohammadpoor-Baltork, and Saghar Rezaei. "Suzuki–Miyaura C–C coupling reactions catalysed by a homogeneous and nanosilica supported palladium(ii) N-heterocyclic carbene complex derived from 3,5-di(1-imidazolyl)pyridine." New Journal of Chemistry 39, no. 12 (2015): 9729–34. http://dx.doi.org/10.1039/c5nj01517k.

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19

Fischer, Carolin, and Burkhard Koenig. "Palladium- and copper-mediated N-aryl bond formation reactions for the synthesis of biological active compounds." Beilstein Journal of Organic Chemistry 7 (January 14, 2011): 59–74. http://dx.doi.org/10.3762/bjoc.7.10.

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N-Arylated aliphatic and aromatic amines are important substituents in many biologically active compounds. In the last few years, transition-metal-mediated N-aryl bond formation has become a standard procedure for the introduction of amines into aromatic systems. While N-arylation of simple aromatic halides by simple amines works with many of the described methods in high yield, the reactions may require detailed optimization if applied to the synthesis of complex molecules with additional functional groups, such as natural products or drugs. We discuss and compare in this review the three mai

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20

Langer, Peter, Stefan Jopp, Marko Liesegang та ін. "Palladium-Catalysed Sonogashira Reactions of 16-(Hydroxymethylidene)-3-methoxy-α-estrone". Synlett 28, № 19 (2017): 2647–49. http://dx.doi.org/10.1055/s-0036-1588537.

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Sonogashira reactions of steroids have been studied. The reaction of α-estron-16-methylidenyloxy triflate with various alkynes afforded novel alkynylvinylidene steroids. The reactions proceeded in good to quantitative yields, with excellent E-selectivity and with a broad synthetic scope.

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21

Parrot, Isabelle, Susheel Nara, Jean Martinez, and Camille-Georges Wermuth. "Palladium-Catalysed Cross-Coupling Reactions on Pyridazine Moieties." Synlett 2006, no. 19 (2006): 3185–204. http://dx.doi.org/10.1055/s-2006-951528.

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22

Sherwood, James, James H. Clark, Ian J. S. Fairlamb, and John M. Slattery. "Solvent effects in palladium catalysed cross-coupling reactions." Green Chemistry 21, no. 9 (2019): 2164–213. http://dx.doi.org/10.1039/c9gc00617f.

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23

van Heerden, Fanie R., Johan J. Huyser, D. Bradley, G. Williams, and Cedric W. Holzapfel. "Palladium-catalysed substitution reactions of geminal allylic diacetates." Tetrahedron Letters 39, no. 29 (1998): 5281–84. http://dx.doi.org/10.1016/s0040-4039(98)01000-4.

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24

Dell'Anna, M. M., M. Gagliardi, P. Mastrorilli, G. P. Suranna, and C. F. Nobile. "Hydrogenation reactions catalysed by a supported palladium complex." Journal of Molecular Catalysis A: Chemical 158, no. 2 (2000): 515–20. http://dx.doi.org/10.1016/s1381-1169(99)00445-8.

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25

Bräse, Stefan, Jan H. Kirchhoff, and Johannes Köbberling. "Palladium-catalysed reactions in solid phase organic synthesis." Tetrahedron 59, no. 7 (2003): 885–939. http://dx.doi.org/10.1016/s0040-4020(02)01425-4.

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26

Červený, Libor, Nguyen Thi Du, and Ivo Paseka. "Model reactions for the study of hydrogenation and acidic activity of palladium catalysts." Collection of Czechoslovak Chemical Communications 52, no. 8 (1987): 2019–27. http://dx.doi.org/10.1135/cccc19872019.

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Palladium catalysts have been used to study the hydrogenation of 1-phenyl-2-butene-1-ol which is accompanied by several side reactions considered to be acid-catalysed. Another model reaction studied was dehydration and subsequent hydrogenation or hydrogenolysis of 1-phenyl-1,3-propanediol to 3-phenyl-1-propanol, accompanied by formation of propylbenzene. The dehydration and propylbenzene formation can be again classified as acid-catalysed reactions. Another one is methanolysis of styrene oxide taking place under conditions of liquid phase hydrogenation due to the acid properties of Pd-H system

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27

Banwell, Martin G., Jennifer M. Cameron, Maree P. Collis, and G. Lance Gravatt. "Syntheses and ipso-Substitution Reactions of Some C-Stannylated Troponoids." Australian Journal of Chemistry 50, no. 4 (1997): 395. http://dx.doi.org/10.1071/c96167.

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The C-stannylated troponoids (2){(8) have been prepared and two of these shown to undergo palladium(0)-catalysed cross-coupling with bromobenzene to give the corresponding phenyl-substituted tropone. Compounds (3), (5) and (6){(8) all react with electrophiles to give products of ipso-substitution.

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28

Saha, Debasree, and Chhanda Mukhopadhyay. "Metal Nanoparticles: An Efficient Tool for Heterocycles Synthesis and Their Functionalization via C-H Activation." Current Organocatalysis 6, no. 2 (2019): 79–91. http://dx.doi.org/10.2174/2213337206666181226152743.

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Background: Metal nanoparticles have been extensively used in the synthesis of organic molecules during the last few decades especially due to their high catalytic activity. Organic reactions involving C-H functionalisations are very much in demand as they provide a direct method of derivatisation of organic molecules, thus making the process economical. In the recent years, metal nanoparticles catalysed C-H activation reactions have led to the design of useful molecules especially heterocyclic motifs which form the core structure of drugs and thus have high biological and industrial importanc

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29

Heumann, Andreas, and Marius Réglier. "The stereochemistry of palladium catalysed cyclisation reactions part C: Cascade reactions." Tetrahedron 52, no. 28 (1996): 9289–346. http://dx.doi.org/10.1016/0040-4020(96)00545-5.

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30

Kundu, Nitya G., M. Wahab Khan, and Jyan S. Mahanty. "Palladium-catalysed Heteroannulation with Acetylenic Carbinols: Synthesis of 3-Acylmethylisoindolin-1-ones." Journal of Chemical Research 23, no. 8 (1999): 460–61. http://dx.doi.org/10.1177/174751989902300803.

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Palladium-catalysed reactions of 2-iodobenzamides 1–6 with acetylenic carbinols 7–12 having a terminal acetylenic group and an adjacent carbinol functionality result in the formation of the 3-acylmethylisoindolin-1-ones 13–23 in one step.

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31

Yuan, Jia, Ying Zhang, Hong Yu, et al. "Transition metal complexes with functionalized indenyl phosphine ligands: structures and catalytic properties." Organic & Biomolecular Chemistry 20, no. 3 (2022): 485–97. http://dx.doi.org/10.1039/d1ob01884a.

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This review summarizes the recent development of the use and impact of indenyl phosphines in the coordination chemistry and transition-metal-catalysed transformations, especially in E–H (E = H, C, Si and B) bonds activation, and palladium-catalyzed cross-coupling reactions.

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32

Smith, Catherine J., Melanie W. S. Tsang, Andrew B. Holmes, Rick L. Danheiser, and Jefferson W. Tester. "Palladium catalysed aryl amination reactions in supercritical carbon dioxide." Organic & Biomolecular Chemistry 3, no. 20 (2005): 3767. http://dx.doi.org/10.1039/b509345g.

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33

Lang, Stuart. "Unravelling the labyrinth of palladium-catalysed reactions involving isocyanides." Chemical Society Reviews 42, no. 12 (2013): 4867. http://dx.doi.org/10.1039/c3cs60022j.

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34

Early, Tessa R., Richard S. Gordon, Michael A. Carroll, Andrew B. Holmes, Richard E. Shute, and Ian F. McConvey. "Palladium-catalysed cross-coupling reactions in supercritical carbon dioxide." Chemical Communications, no. 19 (2001): 1966–67. http://dx.doi.org/10.1039/b106808c.

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35

Kapeller, H., C. Marschner, M. Weißenbacher, and H. Grieng. "Synthesis of cyclopentenyl carbanucleosides via palladium(0) catalysed reactions." Tetrahedron 54, no. 8 (1998): 1439–56. http://dx.doi.org/10.1016/s0040-4020(97)10380-5.

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36

Ali, Hasrat, та Johan E. van Lier. "Synthesis of β-substituted porphyrins using palladium catalysed reactions". Tetrahedron 50, № 41 (1994): 11933–44. http://dx.doi.org/10.1016/s0040-4020(01)89306-6.

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37

Benn, R., G. Gabor, P. W. Jolly, R. Mynott, and B. Raspel. "Intermediates in the palladium-catalysed reactions of 1,3- dienes." Journal of Organometallic Chemistry 296, no. 3 (1985): 443–47. http://dx.doi.org/10.1016/0022-328x(85)80374-0.

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38

Grigg, Ronald, Michael Monteith, Visuvanathar Sridharan, and Catherine Terrier. "Palladium catalysed reactions of allenes, carbon monoxide and nucleophiles." Tetrahedron 54, no. 15 (1998): 3885–94. http://dx.doi.org/10.1016/s0040-4020(98)00115-x.

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39

Banwell, Martin G., Thomas E. Goodwin, Sarah Ng, Jason A. Smith, and David J. Wong. "Palladium-Catalysed Cross-Coupling and Related Reactions Involving Pyrroles." European Journal of Organic Chemistry 2006, no. 14 (2006): 3043–60. http://dx.doi.org/10.1002/ejoc.200500911.

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40

Naciuk, Fabrício F., Joaquim A. M. Castro, Bruno K. Serikava, and Paulo C. M. L. Miranda. "Straightforward Synthesis of Isoellipticine by Palladium-Catalysed Coupling Reactions." ChemistrySelect 3, no. 2 (2018): 436–39. http://dx.doi.org/10.1002/slct.201702602.

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41

Sithebe, Siphamandla, and Ross S. Robinson. "Palladium-catalysed cross-coupling reaction of ultra-stabilised 2-aryl-1,3-dihydro-1H-benzo[d]1,3,2-diazaborole compounds with aryl bromides: A direct protocol for the preparation of unsymmetrical biaryls." Beilstein Journal of Organic Chemistry 10 (May 13, 2014): 1107–13. http://dx.doi.org/10.3762/bjoc.10.109.

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There has been a significant interest in organoboron compounds such as arylboronic acids, arylboronate esters and potassium aryltrifluoroborate salts because they are versatile coupling partners in metal-catalysed cross-coupling reactions. On the other hand, their nitrogen analogues, namely, 1,3,2-benzodiazaborole-type compounds have been studied extensively for their intriguing absorption and fluorescence characteristics. Here we describe the first palladium-catalysed Suzuki–Miyaura cross-coupling reaction of easily accessible and ultra-stabilised 2-aryl-1,3-dihydro-1H-benzo[d]1,3,2-diazaboro

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42

Crisp, Antony L., Jiwen Li, Ping Lan, Jeremy Nugent, Eliška Matoušová, and Martin G. Banwell. "The Palladium-Catalysed Intramolecular Alder-ene (IMAE) Reactions of Certain Heteroatom-Linked 1,6-Enynes: The Formation of Hexahydro-Indoles and -Benzofurans." Australian Journal of Chemistry 68, no. 8 (2015): 1183. http://dx.doi.org/10.1071/ch15340.

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A short review of the literature on palladium-catalysed intramolecular Alder-ene reactions of C-, N-, and O-linked 1,6-enynes is provided with a particular focus on the use of the latter two processes in the authors’ laboratories for the purposes of constructing various alkaloids.

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43

Tonks, Louise, Michael S. Anson, Klaus Hellgardt, Amin R. Mirza, David F. Thompson, and Jonathan MJ Williams. "Palladium catalysed heck reactions and allylic substitution reactions using glass bead technology." Tetrahedron Letters 38, no. 24 (1997): 4319–22. http://dx.doi.org/10.1016/s0040-4039(97)00890-3.

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44

Jouffroy, Matthieu, Rafael Gramage-Doria, David Sémeril, et al. "Phosphinocyclodextrins as confining units for catalytic metal centres. Applications to carbon–carbon bond forming reactions." Beilstein Journal of Organic Chemistry 10 (October 15, 2014): 2388–405. http://dx.doi.org/10.3762/bjoc.10.249.

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The capacity of two cavity-shaped ligands, HUGPHOS-1 and HUGPHOS-2, to generate exclusively singly phosphorus-ligated complexes, in which the cyclodextrin cavity tightly wraps around the metal centre, was explored with a number of late transition metal cations. Both cyclodextrin-derived ligands were assessed in palladium-catalysed Mizoroki–Heck coupling reactions between aryl bromides and styrene on one hand, and the rhodium-catalysed asymmetric hydroformylation of styrene on the other hand. The inability of both chiral ligands to form standard bis(phosphine) complexes under catalytic conditio

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45

Lambert, Richard M., and R. Mark Ormerod. "Heterogeneously catalysed cyclisation reactions of ethyne over single crystal palladium and palladium catalysts." Materials Chemistry and Physics 29, no. 1-4 (1991): 105–15. http://dx.doi.org/10.1016/0254-0584(91)90008-i.

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46

Mahuya, De, P. Majumdar Dyuti, and G. Kundu Nitya. "A concerted synthesis ofhydroxychalcones, flavanones and benzo[b]furans through palladium-catalysed reactions." Journal of Indian Chemical Society Vol. 76, Nov-Dec 1999 (1999): 665–74. https://doi.org/10.5281/zenodo.5862165.

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Department of Organic Chemistry, Indian Association for the Cultivation of Science, Jadavpur, Calcutta-700 032, India Manuscript received 13 September 1999 A convenient palladium-catalysed procedure for the synthesis of <em>o-</em>hydroxychalcones, flavariones and ·benzo[<em>b</em>] furans is described where <em>o</em>-iodophenyl acetate was used as a common precursor.

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47

Arambasic, Milan, Manjeet K. Majhail, Robert N. Straker, James D. Neuhaus, and Michael C. Willis. "A rhodium-catalysed Sonogashira-type coupling exploiting C–S functionalisation: orthogonality with palladium-catalysed variants." Chemical Communications 55, no. 19 (2019): 2757–60. http://dx.doi.org/10.1039/c9cc00092e.

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48

Goonesinghe, Chatura, Mohamed Shaik, Rivi Ratnaweera, K. M. Nalin De Silva, and Rohini M. De Silva. "A magnetically retrievable air and moisture stable gold and palladium nanocatalyst for efficient C−C coupling reactions." Royal Society Open Science 7, no. 9 (2020): 200916. http://dx.doi.org/10.1098/rsos.200916.

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In this study, we report the synthesis of a highly stable, magnetically retrievable gold and palladium nanocatalyst (AuPd@AMNPs), highly active in Suzuki cross-coupling and related homocoupling reactions. The active catalytic component in this system is palladium, which can only be stabilized in the presence of gold nanoparticles. There is no significant loss of activity even after prolonged storage exposed air and moisture. The versatile nature AuPd@AMNPs is demonstrated through the selective catalysis of the homocoupling of phenylboronic acid under low concentrations of O 2 and the oxidation

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49

Purkayastha, A., and J. B. Baruah. "Palladium(II) Catalysed Silicon-Oxygen Bond Formation Versus Rearrangement Reactions." Phosphorus, Sulfur, and Silicon and the Related Elements 169, no. 1 (2001): 9–14. http://dx.doi.org/10.1080/10426500108546578.

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50

Scott, William J. "Palladium catalysed coupling reactions of chloroaryl Cr(CO)3 complexes." Journal of the Chemical Society, Chemical Communications, no. 23 (1987): 1755. http://dx.doi.org/10.1039/c39870001755.

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