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Journal articles on the topic 'Photo-oxidation Polymerization'

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1

Ito, A., T. Morikawa, and T. Takahashi. "Photo-induced polymerization and oxidation of C60 observed by photoelectron spectroscopy." Chemical Physics Letters 211, no. 4-5 (1993): 333–36. http://dx.doi.org/10.1016/0009-2614(93)87068-e.

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2

Kumar, P. Senthil, S. Karuthapandian, S. Balakumar, S. Thanikaikarasan, Peggy Alvarez, and D. D. Eapen. "Preparation and Characterization of SrO/Cu2O for Phorocatalytic Oxidation of Diphenylamine under UV Light." Journal of New Materials for Electrochemical Systems 17, no. 3 (2014): 191–95. http://dx.doi.org/10.14447/jnmes.v17i3.421.

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Generally cuprous oxide has higher photocatalytic activity in the visible region. It is widely applicable in the field of dye degradation. SrO/Cu2O nanocomposites were synthesized by sol-gel method and characterized using SEM, EDAX, AFM and particle size analyzer. SEM, EDAX, AFM and particle size analysis studies indicate that SrO/Cu2O composites are in nano-size range. The catalytic efficiency of nanocomposites was compared with commercial mixture of SrO/Cu2O photocatalyzed oxidation of diphenylamine (DPA) using UV light of wavelength 365 nm on SrO/Cu2O nanocomposites and SrO/Cu2O semiconduct
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3

Mu, Xuan, Jugal Kishore Sahoo, Peggy Cebe, and David L. Kaplan. "Photo-Crosslinked Silk Fibroin for 3D Printing." Polymers 12, no. 12 (2020): 2936. http://dx.doi.org/10.3390/polym12122936.

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Silk fibroin in material formats provides robust mechanical properties, and thus is a promising protein for 3D printing inks for a range of applications, including tissue engineering, bioelectronics, and bio-optics. Among the various crosslinking mechanisms, photo-crosslinking is particularly useful for 3D printing with silk fibroin inks due to the rapid kinetics, tunable crosslinking dynamics, light-assisted shape control, and the option to use visible light as a biocompatible processing condition. Multiple photo-crosslinking approaches have been applied to native or chemically modified silk
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4

Bartuš, J., J. Beniska, A. Hrivík, and A. Malíková. "Study of the photo-oxidation process in polyethylene by a polymerization method." Polymer Degradation and Stability 14, no. 2 (1986): 139–46. http://dx.doi.org/10.1016/0141-3910(86)90012-1.

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5

Малов, Илья, and Ilya Malov. "Investigation of oxidizing polymerization processes at high velocities of initiation in technique of laser stereolithography." Science intensive technologies in mechanical engineering 1, no. 9 (2016): 37–41. http://dx.doi.org/10.12737/21238.

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The paper deals with the investigation of polymerization processes in acryl compositions which were developed first for stereolithography using a promising photo-initiating laser emission of a visible range. The processes of oxidizing polymerization of a photo-polymerizing composition at very low concentrations of an antioxidant [X] and a concentration of dissolved oxygen [O2] > 10-7 ÷ 10-8 mole/l are considered. It is shown that the appearance of an induction period is typical just of reactions passing in a closed system, and in an open one a reaction passes without an induction perio
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6

Rahal, Mahmoud, Bernadette Graff, Joumana Toufaily, et al. "3-Carboxylic Acid and Formyl-Derived Coumarins as Photoinitiators in Photo-Oxidation or Photo-Reduction Processes for Photopolymerization upon Visible Light: Photocomposite Synthesis and 3D Printing Applications." Molecules 26, no. 6 (2021): 1753. http://dx.doi.org/10.3390/molecules26061753.

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In this paper, nine organic compounds based on the coumarin scaffold and different substituents were synthesized and used as high-performance photoinitiators for free radical photopolymerization (FRP) of meth(acrylate) functions under visible light irradiation using LED at 405 nm. In fact, these compounds showed a very high initiation capacity and very good polymerization profiles (both high rate of polymerization (Rp) and final conversion (FC)) using two and three-component photoinitiating systems based on coum/iodonium salt (0.1%/1% w/w) and coum/iodonium salt/amine (0.1%/1%/1% w/w/w), respe
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7

Sbardella, Francesca, Lucilla Pronti, Maria Santarelli, José Asua Gonzàlez, and Maria Bracciale. "Waterborne Acrylate-Based Hybrid Coatings with Enhanced Resistance Properties on Stone Surfaces." Coatings 8, no. 8 (2018): 283. http://dx.doi.org/10.3390/coatings8080283.

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The application of coating polymers to building materials is a simple and cheap way to preserve and protect surfaces from weathering phenomena. Due to its environmentally friendly character, waterborne coating is the most popular type of coating, and improving its performance is an important key of research. The study presents the results regarding the mechanical and photo-oxidation resistance of some water-based acrylic coatings containing SiO2 nanoparticles obtained by batch miniemulsion polymerization. Coating materials have been characterized in terms of hydrophobic/hydrophilic behavior, m
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8

Tomal, Pilch, Chachaj-Brekiesz, and Ortyl. "Development of New High-Performance Biphenyl and Terphenyl Derivatives as Versatile Photoredox Photoinitiating Systems and Their Applications in 3D Printing Photopolymerization Processes." Catalysts 9, no. 10 (2019): 827. http://dx.doi.org/10.3390/catal9100827.

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Novel 2-amino-4-methyl-6-phenyl-benzene-1,3-dicarbonitrile derivatives were proposed as photosensitizes of iodonium salt for a highly effective bimolecular photoinitiating system upon soft irradiation conditions under long-wave ultraviolet (UV-A) and visible light. Remarkably, these structures are highly versatile, allowing access to photoinitiating systems for the free-radical polymerization of acrylates, the cationic photopolymerization of epoxides, glycidyl, and vinyl ethers, the synthesis of interpenetrated polymer networks (IPNs) and the thiol-ene photopolymerization processes. Excellent
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9

Abdallah, Mira, Akram Hijazi, Jui-Teng Lin, Bernadette Graff, Frédéric Dumur, and Jacques Lalevée. "Coumarin Derivatives as Photoinitiators in Photo-Oxidation and Photo-Reduction Processes and a Kinetic Model for Simulations of the Associated Polymerization Profiles." ACS Applied Polymer Materials 2, no. 7 (2020): 2769–80. http://dx.doi.org/10.1021/acsapm.0c00340.

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10

Henschen, A. H. "63. Protection by the fibrin gel structure of certain histidines essential for polymerization against photo-oxidation." Fibrinolysis 10 (August 1996): 24. http://dx.doi.org/10.1016/s0268-9499(96)80825-3.

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11

Hou, Jiangyan, Tianyi Wang, Yao Wang, Xinhao Feng, and Xinyou Liu. "Research on the Rapid Curing Mechanism and Technology of Chinese Lacquer." Polymers 17, no. 12 (2025): 1596. https://doi.org/10.3390/polym17121596.

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Chinese lacquer, a historically significant bio-based coating, has garnered increasing attention in sustainable materials research due to its outstanding corrosion resistance, thermal stability, and environmental friendliness. Its curing process relies on the laccase-catalyzed oxidation and polymerization of urushiol to form a dense lacquer film. However, the stringent temperature and humidity requirements (20–30 °C, 70–80% humidity) and a curing period that can extend over several weeks severely constrain its industrial application. Recent studies have significantly enhanced the curing effici
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12

Chen, Minjun, Guido Bolognesi, and Goran T. Vladisavljević. "Crosslinking Strategies for the Microfluidic Production of Microgels." Molecules 26, no. 12 (2021): 3752. http://dx.doi.org/10.3390/molecules26123752.

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This article provides a systematic review of the crosslinking strategies used to produce microgel particles in microfluidic chips. Various ionic crosslinking methods for the gelation of charged polymers are discussed, including external gelation via crosslinkers dissolved or dispersed in the oil phase; internal gelation methods using crosslinkers added to the dispersed phase in their non-active forms, such as chelating agents, photo-acid generators, sparingly soluble or slowly hydrolyzing compounds, and methods involving competitive ligand exchange; rapid mixing of polymer and crosslinking str
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13

Zou, Yang, Yuye Zhong, Houbin Li, Fuyuan Ding, and Xiaowen Shi. "Electrodeposition of Polysaccharide and Protein Hydrogels for Biomedical Applications." Current Medicinal Chemistry 27, no. 16 (2020): 2610–30. http://dx.doi.org/10.2174/0929867326666191212163955.

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In the last few decades, polysaccharide and protein hydrogels have attracted significant attentions and been applied in various engineering fields. Polysaccharide and protein hydrogels with appealing physical and biological features have been produced to meet different biomedical applications for their excellent properties related to biodegradability, biocompatibility, nontoxicity, and stimuli responsiveness. Numerous methods, such as chemical crosslinking, photo crosslinking, graft polymerization, hydrophobic interaction, polyelectrolyte complexation and electrodeposition have been employed t
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14

Ermakova, Lydia V., Alexey M. Sergeev, Valentina G. Smyslova, Daria E. Lelekova, Tatyana B. Shatalova, and Petr S. Sokolov. "ALIPHATIC ETHYLENE GLYCOL MONOMERS AS A BASIS FOR PHOTOPOLYMERIZABLE SUSPENSIONS." ChemChemTech 68, no. 2 (2024): 88–95. https://doi.org/10.6060/ivkkt.20256802.7131.

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A comprehensive study of the influence of the nature of aliphatic monomers of ethylene glycol diacrylates on the properties of photo-cured suspensions based on a complex oxide powder with a garnet structure of the (Gd,Y)3Al2Ga3O12:Ce composition for three-dimensional printing by Digital Light Processing (DLP) has been carried out. The rheological characteristics of suspensions, as well as the polymerization depth, were studied using both the model HDDA monomer and the specified diacrylates, when filled with solid particles of 30 vol.% (70 wt.%). The viscosity of the photo-cured suspensions sys
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15

Briede, Sabine, Oskars Platnieks, Anda Barkane, et al. "Tailored Biobased Resins from Acrylated Vegetable Oils for Application in Wood Coatings." Coatings 13, no. 3 (2023): 657. http://dx.doi.org/10.3390/coatings13030657.

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The modern coating market is dominated by acrylic, polyurethane, and polyester polymer resins produced from unsustainable fossil resources. Herein, we propose the preparation of resins from biobased components to produce functional and solvent-free wood coatings with enhanced performance properties. Acrylated rapeseed, linseed, and grapeseed oils were prepared via a one-step synthesis and used as a basis for the control of resin viscosity and fatty acid content. A combination of vegetable oil acrylates was used as a matrix and the biobased monomer propoxylated glycerol triacrylate (GPT) was se
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16

Zhong, Jie, Bin Yang, Yong Feng, et al. "Enhanced Photo–Fenton Removal Efficiency with Core-Shell Magnetic Resin Catalyst for Textile Dyeing Wastewater Treatment." Water 13, no. 7 (2021): 968. http://dx.doi.org/10.3390/w13070968.

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Heterogeneous photo–Fenton reactions have been regarded as important technologies for the treatment of textile dyeing wastewaters. In this work, an efficient core-shell magnetic anion exchange resin (MAER) was prepared through in situ polymerization and used to remove reactive brilliant red (X-3B) in a UV–Fenton system. The MAER exhibited satisfactory removal efficiency for X-3B because of its highly effective catalytic activity. More than 99% of the X-3B (50 mg/L) was removed within 20 min in the UV–Fenton reaction. This is because the uniformly dispersed core-shell magnetic microsphere resin
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17

Maraveas, Chrysanthos. "Environmental Sustainability of Greenhouse Covering Materials." Sustainability 11, no. 21 (2019): 6129. http://dx.doi.org/10.3390/su11216129.

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The fundamental objective of the review article was to explore the ecological sustainability of greenhouse covering material based on the following themes; considerations for greenhouse materials, properties of polymers and glass, additives, fillers, stabilizers and reinforcements, performance, Ultraviolet (UV) transmittance, phase change materials (PCMs), and environmental sustainability. A comparison of various polymers (polyvinyl chloride (PVC), acrylic, D-polymer, Linear low-density polyethylene (LLDPE), polyolefins), and silica glasses illustrated that each type of greenhouse cladding mat
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18

Suzuki, Ayumu, and Katsumi Yamada. "Photoelectrochemical Three-Dimensional Fabrication of Conductive Polymers Using Multi-Photon Absorption Process." ECS Meeting Abstracts MA2024-02, no. 38 (2024): 2565. https://doi.org/10.1149/ma2024-02382565mtgabs.

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Micro-nano 3D printing of conductive polymers is a technology developed by our research group for the first time in the world. Many monomers of conductive polymers are liquid state at normal pressure, but when polymerized, the product becomes an infusible and insoluble solid state, so three-dimensional structures can be obtained. Pyrrole undergoes polymerization through oxidation to become polypyrrole, and in this research, the photo-electrochemical oxidation reaction is achieved by multi-photon absorption sensitization. The multi-photon absorption reactions have extremely high spatial selecti
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19

Hasani, Mahdiyeh, Tracey Campbell, Fan Wu, and Keith Warriner. "Decontamination of N95 and surgical masks using a treatment based on a continuous gas phase-Advanced Oxidation Process." PLOS ONE 16, no. 3 (2021): e0248487. http://dx.doi.org/10.1371/journal.pone.0248487.

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A gas-phase Advanced Oxidation Process (gAOP) was evaluated for decontaminating N95 and surgical masks. The continuous process was based on the generation of hydroxyl-radicals via the UV-C (254 nm) photo-degradation of hydrogen peroxide and ozone. The decontamination efficacy of the gAOP was dependent on the orientation of the N95 mask passing through the gAOP unit with those positioned horizontally enabling greater exposure to hydroxyl-radicals compared to when arranged vertically. The lethality of gAOP was independent of the applied hydrogen peroxide concentration (2–6% v/v) but was signific
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20

Kumbhar, Shweta Gurudas, and Mahuya De. "Photoelectrochemical Oxidation of Glycerol over g-C3N4 Nanosheets Coupled with Metal-Assisted Hybrid Carbon Quantum Dots." ECS Meeting Abstracts MA2024-01, no. 23 (2024): 1365. http://dx.doi.org/10.1149/ma2024-01231365mtgabs.

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Carbon quantum dots (CDs) are the most promising candidates of the carbon family with a size of less than 10nm. They owned superior properties such as high solubility in aqueous medium, low toxicity, biocompatibility, stable photoluminescence, spectral convertor, and act as electron reservoirs. These properties make CDs suitable for photo-electrochemical catalytic applications. Low quantum yield and activity in the visible light spectrum of CDs may restrict their applicability. To address this issue, doping and surface passivation of CDs is the only approach to improve their physicochemical ch
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21

Haridevi, M., S. Prabu, M. Lakshmi Devi, et al. "Synthesis and Characterization Polyaniline/Cobalt Oxide Nanocomposite by Chemical Oxidation Method." Nanoscale Reports 1, no. 1 (2018): 9–20. http://dx.doi.org/10.26524/nr1812.

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The Co3O4-PANI nanocomposites has been synthesized by chemical oxidative polymerization method using cobalt chloride. It is a simple and low cost method to prepare nanocomposite. The prepared samples were characterized by using Scanning Electron Microscope (SEM), X-ray diffraction (XRD) and Fourier Transform Spectroscopy (FTIR) to get surface morphology, idea of getting particles of nano sized range so that further characterization can be done, to study the net surface charge of the nanoparticles by Zeta potential, photoluminescence of synthesized nanocomposite and measure photocatalytic activ
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22

Chopan, Nisar Ahmad, Aabid Hussain Bhat, and Hamida-Tun-Nisa Chishti. "Fabrication of polypyrrole-sensitized Ag3PO4/g-C3N4 Z-scheme heterojunction for photocatalytic and antibacterial activity." New Journal of Chemistry, 2023. http://dx.doi.org/10.1039/d3nj02774k.

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Ag3PO4/PPy/g-C3N4 nanocomposite synthesized by hydrothermal and in situ chemical oxidation polymerization exhibits tremendous photocatalytic activity, and photo-antimicrobial activity under visible light irradiation.
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23

Jeon, Woojin, Yonghwan Kwon, and Min Sang Kwon. "Highly efficient dual photoredox/copper catalyzed atom transfer radical polymerization achieved through mechanism-driven photocatalyst design." Nature Communications 15, no. 1 (2024). http://dx.doi.org/10.1038/s41467-024-49509-1.

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AbstractAtom transfer radical polymerization (ATRP) with dual photoredox/copper catalysis combines the advantages of photo-ATRP and photoredox-mediated ATRP, utilizing visible light and ensuring broad monomer scope and solvent compatibility while minimizing side reactions. Despite its popularity, challenges include high photocatalyst (PC) loadings (10 to 1000 ppm), requiring additional purification and increasing costs. In this study, we discover a PC that functions at the sub-ppm level for ATRP through mechanism-driven PC design. Through studying polymerization mechanisms, we find that the ef
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24

Iwata, Nobuyuki, Daiki Koide, Syouta Katou, Eri Ikeda, and Hiroshi Yamamoto. "Hole or Electron Doped C60 Polymer Using Free Electron Laser Irradiation." MRS Proceedings 1284 (2011). http://dx.doi.org/10.1557/opl.2011.642.

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ABSTRACTPolymerized C60 crystals were grown using the free electron laser (FEL) irradiation. In order to promote the polymerization degree, hole or electron was doped in the C60 crystals grown by the liquid-liquid interfacial precipitation (LLIP) method to eliminate the degradation by oxidation. The specimen grown with the I2 dissolved butylalcohol (BTA, CH3(CH2)3OH) and the C60 saturation o-xylene solution, subsequently pressed at 7GPa, showed only Ag(2)-derived mode at 1456 cm-1 after the FEL irradiation. The specimen belonged to so-called F phase, which is not obtained by the typical photo-
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25

Daniele, Ciofini, Striova Jana, Camaiti Mara, and Siano Salvatore. "Photo-oxidative kinetics of solvent and oil-based terpenoid varnishes." November 15, 2019. https://doi.org/10.5281/zenodo.3543551.

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Here, the photo-oxidative degradation of several terpenoid varnishes usually encountered in conservation of cultural heritage has been investigated. Samples were prepared by dissolving dammar, mastic, colophony, sandarac and bleached shellac in suitable solvents or by heating mastic, colophony, sandarac and Manila copal with linseed oil. The alteration effects of this broad set of samples induced by light exposure in an ageing chamber, were thoroughly characterized using transmission FTIR spectroscopy, colorimetry, and gravimetric measurements. The various varnishes exhibited a similar saturat
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26

Rodgers, Ryan P., Martha L. Chacón-Patiño, Sydney F. Niles, et al. "High Resolution Mass Spectrometry Advances in Oil Spill Analysis." International Oil Spill Conference Proceedings 2021, no. 1 (2021). http://dx.doi.org/10.7901/2169-3358-2021.1.685482.

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Abstract Oil is a complex mixture of alkanes, cycloalkanes, aromatics, nitrogen/sulfur/oxygen (N/S/O) heterocycles, alcohols, ketones, carboxylic acids, porphyrins, and myriad possible combinations therein. Once introduced into the environment, some weathering processes reduce this complexity through evaporative losses (loss to atmosphere) as well as water washing of low ring number aromatics, N/S/O heterocycles, alcohols, ketones, and carboxylic acids (loss to seawater). However, Gulf of Mexico Research Initiative (GoMRI) supported research has revealed that the contributions of these mechani
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27

"Inside Cover Picture." Chinese Journal of Chemistry 42, no. 10 (2024): 1062. http://dx.doi.org/10.1002/cjoc.202490102.

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Triphenylamine and its derivatives (TPAs) are promising for the photocatalytic oxidative coupling of thiols to disulfides, but suffer from the easy polymerization and difficult separation. In this paper, by immobilizing the TPAs into MOF with photoredox inert Sr nodes, the photo‐generated electrons were successfully controlled to transfer from the excited TPAs to O2, and finally realize the heterogeneous catalytic oxidation of thiols to disulfides. More details are discussed in the article by Zhang et al. on page 1093—1099.image
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28

Wen, Jie, Zan Li, Jianhua Hu, Xingchen Cui, Zhina Ji, and Tieqiang Wang. "Preparation of Photo-thermal Responsive Soft Actuating Hydrogel Materials through Combining UV-Initiated Polymerization and <i>In Situ</i> Oxidation Polymerization." Daxue Huaxue, 2023, 2211090. http://dx.doi.org/10.3866/pku.dxhx202211090.

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29

Rabia, Mohamed, Asmaa M. Elsayed, and Maha Abdallah Alnuwaiser. "Mn(IV) oxide/Mn(IV) sulfide/poly-2-amino-1-mercaptobenzene for green hydrogen generation from sewage water through the photoelectrocatalytic process." Surface Innovations, September 29, 2023, 1–8. http://dx.doi.org/10.1680/jsuin.23.00031.

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The Mn(IV) oxide/Mn(IV) sulfide/poly-2-amino-1-mercaptobenzene (MnO2-MnS2/P2AMB) nanocomposite is prepared through a polymerization reaction (oxidation) and is utilized as a highly photo-electrocatalytic material for green hydrogen generation from sewage water. The MnO2-MnS2/P2AMB nanocomposite demonstrates remarkable optical properties, characterized by a bandgap of 1.81 eV. To promote the water splitting reaction by the synthesized MnO2-MnS2/P2AMB nanocomposite photoelectrode, sewage water is utilized as a sacrificial agent to effectively facilitate the generation of hydrogen gas through the
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30

Ito, Shosuke, Ludger Kolbe, Gudrun Weets, et al. "Exogenous Ochronosis by Hydroquinone is not caused by Inhibition of Homogentisate Dioxygenase but potentially by Tyrosinase-catalyzed Metabolism of Hydroquinone." British Journal of Dermatology, July 15, 2025. https://doi.org/10.1093/bjd/ljaf273.

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Abstract Background Hydroquinone (HQ) is widely used for its hypopigmenting effects in treating hyperpigmentation disorders. However, its topical application has been linked to adverse effects, notably exogenous ochronosis (EO), raising concerns about its safety and mechanisms of action. Objective This study aims to elucidate the metabolic pathway of HQ in human melanocytes and clarify the role of tyrosinase in the development of EO. Methods We conducted an in vitro investigation utilizing human tyrosinase to analyze the metabolism of HQ. The study involved assessing the oxidation of HQ in the
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31

Dar, Sami Ullah, Zizhao Wu, Linyi Zhang, et al. "On the quest for novel bio-degradable plastics for agricultural field mulching." Frontiers in Bioengineering and Biotechnology 10 (August 8, 2022). http://dx.doi.org/10.3389/fbioe.2022.922974.

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Plasticulture, the practice of using plastic materials in agricultural applications, consumes about 6.7 million tons of plastics every year, which is about 2% of the overall global annual plastics production. For different reasons, plastic material used for agriculture is difficult to recycle. Therefore, most of it is either buried in fertile soils, thereby significantly causing deterioration of their properties, or, at best case, end in landfills where its half-life is measured in decades and even centuries. Hence, developing biodegradable plastic materials that are suitable for agricultural
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