Academic literature on the topic 'Quaternary carbons'

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Journal articles on the topic "Quaternary carbons"

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ROUHI, MAUREEN. "QUATERNARY CARBONS." Chemical & Engineering News 79, no. 19 (2001): 53. http://dx.doi.org/10.1021/cen-v079n019.p053.

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Li, Bi-Jie, and Xin Sun. "Acyclic Quaternary Carbon Stereocenters through Transition-Metal-Catalyzed Enantioselective Functionalization of Unsaturated Hydrocarbons." Synthesis 54, no. 09 (2022): 2103–18. http://dx.doi.org/10.1055/s-0040-1719899.

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AbstractAcyclic quaternary carbon stereocenters occur frequently in natural products, bioactive molecules, and pharmaceutical compounds. Construction of a carbon stereogenic center attached to four different carbons with defined spatial arrangement is a daunting challenge in asymmetric catalysis. Significant efforts have been directed towards the stereoselective construction of such acyclic quaternary carbon stereocenters. In particular, catalytic generation of acyclic quaternary carbon stereocenters through functionalization of unsaturated hydrocarbons is an extremely attractive approach beca
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Kita, Yasuyuki, and Hiromichi Fujioka. "Enantioselective constructions of quaternary carbons and their application to the asymmetric total syntheses of fredericamycin A and discorhabdin A." Pure and Applied Chemistry 79, no. 4 (2007): 701–13. http://dx.doi.org/10.1351/pac200779040701.

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An efficient enantioselective construction of quaternary carbons including spiro carbons is an area of intense interest due to the importance of these units as components of biologically active natural products. Prominent methods are presented for the synthesis of chiral, nonracemic quaternary carbon centers by (i) stereospecific rearrangement of optically active epoxides, (ii) enzyme-catalyzed resolution, and (iii) hypervalent iodine reagent-induced ipso-substitution of para-substituted phenol derivatives. These methods were applied to the total syntheses of fredericamycin A and discorhabdin
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Palao, Eduardo, Enol López, Iván Torres-Moya, Antonio de la Hoz, Ángel Díaz-Ortiz, and Jesús Alcázar. "Formation of quaternary carbons through cobalt-catalyzed C(sp3)–C(sp3) Negishi cross-coupling." Chemical Communications 56, no. 59 (2020): 8210–13. http://dx.doi.org/10.1039/d0cc02734k.

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Eggert, Alina, Christoph Etling, Dennis Lübken, Marius Saxarra, and Markus Kalesse. "Contiguous Quaternary Carbons: A Selection of Total Syntheses." Molecules 25, no. 17 (2020): 3841. http://dx.doi.org/10.3390/molecules25173841.

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Contiguous quaternary carbons in terpene natural products remain a major challenge in total synthesis. Synthetic strategies to overcome this challenge will be a pivotal prerequisite to the medicinal application of natural products and their analogs or derivatives. In this review, we cover syntheses of natural products that exhibit a dense assembly of quaternary carbons and whose syntheses were uncompleted until recently. While discussing their syntheses, we not only cover the most recent total syntheses but also provide an update on the status quo of modern syntheses of complex natural product
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Gutman, Ivan, Dusica Vidovic, and Dragan Stevanovic. "Chemical applications of the Laplacian spectrum. VI On the largest Laplacian eigenvalue of alkanes." Journal of the Serbian Chemical Society 67, no. 6 (2002): 407–13. http://dx.doi.org/10.2298/jsc0206407g.

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The largest Lapacian eigenvalue ?1 of the molecular graph is a quantity important in the theory of the photoelectron spectra of saturated hydrocarbons. It is shown that in the case of alkanes, the presence or absence of quaternary carbon atoms is the main structural feature on which ?1 depends. Within sets of all alkanes with a given number of carbon atoms the species (with and without quaternary carbons atoms) whose ?1-values are minimal and maximal are determined.
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Gan, Xu-cheng, Benxiang Zhang, Nathan Dao, et al. "Carbon quaternization of redox active esters and olefins by decarboxylative coupling." Science 384, no. 6691 (2024): 113–18. http://dx.doi.org/10.1126/science.adn5619.

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The synthesis of quaternary carbons often requires numerous steps and complex conditions or harsh reagents that act on heavily engineered substrates. This is largely a consequence of conventional polar-bond retrosynthetic disconnections that in turn require multiple functional group interconversions, redox manipulations, and protecting group chemistry. Here, we report a simple catalyst and reductant combination that converts two types of feedstock chemicals, carboxylic acids and olefins, into tetrasubstituted carbons through quaternization of radical intermediates. An iron porphyrin catalyst a
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Liu, Yiyang, Marc Liniger, Ryan M. McFadden, et al. "Formal total syntheses of classic natural product target molecules via palladium-catalyzed enantioselective alkylation." Beilstein Journal of Organic Chemistry 10 (October 28, 2014): 2501–12. http://dx.doi.org/10.3762/bjoc.10.261.

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Pd-catalyzed enantioselective alkylation in conjunction with further synthetic elaboration enables the formal total syntheses of a number of “classic” natural product target molecules. This publication highlights recent methods for setting quaternary and tetrasubstituted tertiary carbon stereocenters to address the synthetic hurdles encountered over many decades across multiple compound classes spanning carbohydrate derivatives, terpenes, and alkaloids. These enantioselective methods will impact both academic and industrial settings, where the synthesis of stereogenic quaternary carbons is a c
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Krebs, H. C., and T. Carl. "Retrorsine: Correct Assignment of Quaternary Carbons." Magnetic Resonance in Chemistry 34, no. 12 (1996): 1046–47. http://dx.doi.org/10.1002/(sici)1097-458x(199612)34:12<1046::aid-omr12>3.0.co;2-u.

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Villalgordo-Hernández, David, Aida Grau-Atienza, Antonio A. García-Marín, Enrique V. Ramos-Fernández, and Javier Narciso. "Manufacture of Carbon Materials with High Nitrogen Content." Materials 15, no. 7 (2022): 2415. http://dx.doi.org/10.3390/ma15072415.

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Nowadays one of the biggest challenges for carbon materials is their use in CO2 capture and their use as electrocatalysts in the oxygen reduction reaction (ORR). In both cases, it is necessary to dope the carbon with nitrogen species. Conventional methods to prepare nitrogen doped carbons such as melamine carbonization or NH3 treatment generate nitrogen doped carbons with insufficient nitrogen content. In the present research, a series of activated carbons derived from MOFs (ZIF-8, ZIF-67) are presented. Activated carbons have been prepared in a single step, by pyrolysis of the MOF in an inert
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Dissertations / Theses on the topic "Quaternary carbons"

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Manthorpe, Jeffrey Michael. "A general method for the asymmetric synthesis of quaternary carbons : reductive formation and alkylation of [alpha],[alpha]-disubstituted enolates." Thesis, McGill University, 2003. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=82927.

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A new, general method for the asymmetric synthesis of quaternary carbons is described. This technique involves stereocontrolled generation of alpha,alpha-disubstituted amide enolates via reduction of bicyclic alpha,alpha-disubstituted alpha-thioglycolate lactams using one-electron transfer reagents. A model of the geometric constraints necessary to reductively prepare alpha,alpha-disubstituted amide enolates with control of enolate E/Z stereochemistry is described and several chiral auxiliaries were prepared to test this design.<br>Successful preparation, trapping, isolation and charact
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Xue, Sijing. "Dual Transition Metal/Photoredox Catalysis for the Synthesis of Quaternary Carbon Stereocenters." Doctoral thesis, Universitat Rovira i Virgili, 2021. http://hdl.handle.net/10803/673186.

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Els estereocentres de carboni quaternaris són omnipresents en molècules bioactives i farmacèuticament rellevants. No obstant això, la construcció d'enllaços C-C que condueixen a carbonis quaternaris quirals segueix sent poc desenvolupada. El nostre grup ha explorat reaccions de substitució al·lílica mitjançant l'ús de carbonats cíclics de vinil (VCC) com a motius de substrat privilegiats, permetent així la formació versàtil de blocs de construcció estereodefinits. Tanmateix, en el moment de l'inici d'aquest treball de tesi, l'enfocament s'havia centrat només en mètodes preparatius que don
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Wei, Lai. "Asymmetric organocatalysis in the Michael reaction of cyclic α-alkyl ketones : enantioselective synthesis of suberosanes and succinimides". Thesis, Université Paris-Saclay (ComUE), 2018. http://www.theses.fr/2018SACLS325.

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La découverte des activités cytotoxiques impressionnantes des subérosanes, des sesquiterpènes d’origine marine isolées dès 1996 de la gorgone Subergorgia suberosa, ainsi que leurs structures tricycliques complexes possédant jusqu’à cinq centre stéréogènes contigus dont un centre quaternaire central, ont fait de ces molécules des cibles de choix tant pour les acteurs de la chimie médicinale que pour ceux travaillant dans le domaine de la synthèse totale. Enfin, une molécule d’origine synthétique « simplifiée » de cette famille, la nor-subérosénone, a également montré des activités cytotoxiques
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Frimpong, Kwame. "Synthesis of Quaternary Carbon Centers via Hydroformylation." Thesis, Boston College, 2011. http://hdl.handle.net/2345/2413.

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Thesis advisor: Kian L. Tan<br>Utilization of directing groups in a general and efficient manner for highly regioselective hydroformylation of 1,1-disubstituted olefins<br>Thesis (MS) — Boston College, 2011<br>Submitted to: Boston College. Graduate School of Arts and Sciences<br>Discipline: Chemistry
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Jones, Dyfyr Heulyn. "Approaches to quaternary carbon centres using organoboron chemistry." Thesis, Cardiff University, 2013. http://orca.cf.ac.uk/50197/.

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The main focus of the work contained within this thesis was to explore the possible use of novel organoboron chemistry in generating quaternary carbon centres, with the ultimate aim of developing new routes for the asymmetric synthesis of chiral quaternary carbon centres. Chapter 1 contains a general introduction to the literature of organoboron chemistry, focusing particularly on organoboron reactions that contain 1, 2 - boron to carbon migrations. Chapters 2 and 3 contain attempts at generating tertiary alkyl groups bonded to boron in an asymmetric fashion. Chapter 2 specifically deals with
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Minicone, Fabrizio. "Stereoselective synthesis of cyclopropanes with quaternary carbon centres." Thesis, Queen Mary, University of London, 2014. http://qmro.qmul.ac.uk/xmlui/handle/123456789/8766.

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Multi-substituted optically pure cyclopropanes are important motifs present in many agrochemicals, pharmaceuticals and materials employed in manifold applications. Their synthesis is challenging due to both the strained conformation and the need to control both the relative and absolute stereochemistry. This thesis describes an investigation of the scope of the Wadsworth-Emmons cyclopropanation, highlighting it as a potential efficient methodology for diastereoselective and enantiospecific synthesis of these valuable ring systems. Chapter 1 is an introduction to the cyclopropanation protocols
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Dabrowski, Jennifer A. "Development of Selective Methods to Form C-C Bonds. Enantioselective Formation of Tertiary and Quaternary Stereogenic Centers." Thesis, Boston College, 2013. http://hdl.handle.net/2345/3771.

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Thesis advisor: Amir H. Hoveyda<br>Formation of C-C bonds is an invaluable tool for the construction of materials, pharmaceuticals, natural products, and the building blocks of life. Although great strides in this area have been made, there remain several limitations in regio-, site-, and enantioselective additions of carbon-based nucleophiles. Solving these challenges by expanding the scope, efficiency, and selectivity of alkyl, aryl, heteroaryl, vinyl, and alkynyl additions to carbon-based electrophiles is the topic of this dissertation<br>Thesis (PhD) — Boston College, 2013<br>Submitted to:
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Oliveira, Marllon Nascimento de. "Palladium-catalyzed asymmetric allylic alkylations : control of all-carbon quaternary centers." Thesis, Paris 6, 2017. http://www.theses.fr/2017PA066612/document.

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Dans le cadre de nos travaux, nous avons développé une méthode extrêmement douce et particulièrement efficace d’accès à des γ-butyrolactones possédant un centre stéréogène quaternaire en α à partir d’énols carbonates d’allyle cycliques et exocycliques en utilisant la réaction d’alkylation allylique asymétrique décarboxylante pallado-catalysée (Pd-DAAA). Remarquablement, cette méthode a permis d’étendre l’utilisation de l’allylation asymétrique décarboxylante à des substrats sans précèdent dans la littérature, tels que les énols carbonates allyliques exocycliques. Cette réaction a été utilisée
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May, Tricia Lee. "Copper-Based N-Heterocyclic Carbene Complexes for Catalytic Enantioselective Conjugate Additions of Alkyl-, Aryl- and Vinyl-Based Nucleophiles to Form All-Carbon Quaternary Stereogenic Centers." Thesis, Boston College, 2011. http://hdl.handle.net/2345/2650.

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Thesis advisor: Amir H. Hoveyda<br>Chapter 1 Enantioselective Conjugate Additions of Carbon Nucleophiles to Activated Olefins: Preparation of Enantioenriched Compounds Containing All-Carbon Quaternary Stereogenic Centers. Methods for enantioselective conjugate addition of nucleophiles to activated olefins generating products containing all-carbon quaternary stereogenic centers are critically reviewed. Enantioselective conjugate addition has been shown to be a powerful and concise approach to construct carbon-carbon bonds to prepare compounds containing sterically hindered stereogenic centers a
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Doda, Kanae. "Development of Asymmetric Carbon-Carbon Bond-Forming Reactions Using Novel Catalysis of Chiral Quaternary Ammonium Fluorides." 京都大学 (Kyoto University), 2004. http://hdl.handle.net/2433/147843.

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Books on the topic "Quaternary carbons"

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Williamson, Douglas S. Asymmetric synthesis of compounds containing quaternary carbon stereocentres. UMIST, 1997.

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Farmer, Jesse Robert. Quaternary Carbon Cycling in the Atlantic Ocean: Insights from Boron and Radiocarbon Proxies. [publisher not identified], 2016.

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Schubert, Carsten J. Organischer Kohlenstoff in spätquartären Sedimenten des Arktischen Ozeans: Terrigener Eintrag und marine Produktivität = Organic carbon in late Quaternary Arctic Ocean sediments : terrigenous supply and marine productivity. Alfred-Wegener-Institut für Polar- und Meeresforschung, 1995.

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Boucsein, Bettina. Organic carbon in late Quaternary sediments: Responses to paleoenvironmental changes in the Laptev and Kara seas (Arctic Ocean) = Organisches Material in spätquartären Sedimenten : Rekonstruktion der Paläoumweltbedingungen in der Laptev- und Karasee (Arktischer Ozean). Alfred-Wegener-Institut für Polar- und Meeresforschung, 2000.

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1968-, Baker Andy, ed. Speleothem science: From process to past environments. Wiley, 2012.

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Kummer, David Anthony. I. Sterocontrolled Construction of Quaternary Carbon Centers by the Alkylation of Pseudoephedrine Amides. II. A Practical, Convergent Route to the Key Precursor to the Tetracycline Antibiotics. 2011.

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Book chapters on the topic "Quaternary carbons"

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Itoh, Ryusei, Keiji Tanino, and Fumihiko Yoshimura. "A Journey to the Total Synthesis of Brasilicardins." In Modern Natural Product Synthesis. Springer Nature Singapore, 2024. http://dx.doi.org/10.1007/978-981-97-1619-7_1.

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AbstractC(sp3)-rich natural products with quaternary carbon stereocenters have recently received increasing attention as formidable synthetic targets and higher lead and drug compounds. Among them, brasilicardins, which are terpenoids–amino acids–saccharide(s) hybrids, share a unique and highly strained anti-syn-anti-fused 6,6,6-tricyclic terpenoid skeleton containing two adjacent quaternary carbon stereocenters and have attracted attention as promising immunosuppressive drug lead compounds. Herein, we describe our endeavor toward a unified total synthesis of brasilicardins A–D, focusing on ov
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Ajay, G. V. S., and Sarada Musala. "Quaternary Multiplier with Modified Carry Using Carbon Nanotube FETs." In Lecture Notes in Electrical Engineering. Springer Nature Singapore, 2023. http://dx.doi.org/10.1007/978-981-99-4795-9_11.

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Pedersen, T. F., R. François, L. François, K. Alverson, and J. McManus. "The Late Quaternary History of Biogeochemical Cycling of Carbon." In Paleoclimate, Global Change and the Future. Springer Berlin Heidelberg, 2003. http://dx.doi.org/10.1007/978-3-642-55828-3_4.

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Schlitzer, R., R. Usbeck, and G. Fischer. "Inverse Modeling of Particulate Organic Carbon Fluxes in the South Atlantic." In The South Atlantic in the Late Quaternary. Springer Berlin Heidelberg, 2003. http://dx.doi.org/10.1007/978-3-642-18917-3_1.

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Cramer, Nicolai, and Tobias Seiser. "Quaternary Stereogenic Centers by Enantioselective â-Carbon Eliminations fromtert-Cyclobutanols." In Asymmetric Synthesis II. Wiley-VCH Verlag GmbH & Co. KGaA, 2013. http://dx.doi.org/10.1002/9783527652235.ch8.

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Kleinen, Thomas, Elena Bezrukova, Victor Brovkin, et al. "Comparison of Climate and Carbon Cycle Dynamics During Late Quaternary Interglacials." In Integrated Analysis of Interglacial Climate Dynamics (INTERDYNAMIC). Springer International Publishing, 2014. http://dx.doi.org/10.1007/978-3-319-00693-2_2.

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Schulte, S., A. Benthien, N. Andersen, P. J. Müller, C. Rühlemann, and R. R. Schneider. "Stable Carbon Isotopic Composition of the C37:2 Alkenone: A Proxy for CO2(aq) Concentration in Oceanic Surface Waters?" In The South Atlantic in the Late Quaternary. Springer Berlin Heidelberg, 2003. http://dx.doi.org/10.1007/978-3-642-18917-3_10.

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Berkenheger, I., A. Heuchert, S. de Silva, and U. Fischer. "Heterotrophic Particle-Associated Bacteria from the South Atlantic: A Community of Marine Microorganisms with a High Organic Carbon Degradation Potential." In The South Atlantic in the Late Quaternary. Springer Berlin Heidelberg, 2003. http://dx.doi.org/10.1007/978-3-642-18917-3_4.

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Wagnerl, T., M. Zabel, L. Dupont, J. Holtvoeth, and C. J. Schubert. "Terrigenous Signals in Sediments of the Low Latitude Atlantic — Implications for Environmental Variations during the Late Quarternary: Part I: Organic Carbon." In The South Atlantic in the Late Quaternary. Springer Berlin Heidelberg, 2003. http://dx.doi.org/10.1007/978-3-642-18917-3_15.

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Solomon, Allen M., and M. Lynn Tharp. "Simulation Experiments with Late Quaternary Carbon Storage in Mid-Latitude Forest Communities." In The Carbon Cycle and Atmospheric CO2: Natural Variations Archean to Present. American Geophysical Union, 2013. http://dx.doi.org/10.1029/gm032p0235.

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Conference papers on the topic "Quaternary carbons"

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Li, Xiaoji, Sandeep Chawla, Jose Vera, William Durnie, and Richard Woollam. "Correlation between Critical Micelle Concentration and CO2 Corrosion Inhibition Efficiency of Quaternary Ammonium Compounds." In CORROSION 2018. NACE International, 2018. https://doi.org/10.5006/c2018-11476.

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Abstract Rotating cylinder electrode (RCE) methodology with electrochemical impedance spectroscopy (EIS) measurement was applied to study the inhibition behavior of quaternary ammonium compounds on CO2 corrosion of X65 carbon steel. The test program, consisting of 50 tests, investigated the inhibition performance of a homologous series of quaternary ammonium surfactants with different alkyl chain length (C12, C14, C16) at different salinities (0.1%, 1%, 10% wt. NaCl), and temperatures (30°C, 50°C, 70°C). Corrosion rate as a function of inhibitor dosage was determined for each test condition de
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De Turris, Antonio, Matilde de Romero, Sankara Papavinasam, and Lisseth Ocando. "Synergistic Effect of Sulphate-Reducing Bacteria and CO2 on the Corrosion of Carbon Steel and Chemical Treatment to Control it." In CORROSION 2014. NACE International, 2014. https://doi.org/10.5006/c2014-3749.

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Abstract The combined effect of sulphate-reducing bacteria (SRB) and CO2 on the corrosion of carbon steel in produced water were investigated using a rotating cage. During the experiment, pH, planktonic SRB, and concentrations of sulphide, sulphate, iron, calcium and magnesium ions were monitored. After the experiment, the sessile SRB were enumerated by serial dilution and optical microscopy, scanning electron microscopy, mass loss and laser profilometry were used to identify corrosion products, bacterial cell and corrosion rate. Both mass loss and localized pitting corrosion were two and thre
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Zelinka, S. L., D. R. Rammer, and D. S. Stone. "Evaluating the Corrosiveness of Southern Pine Treated with Several Wood Preservatives Using Electrochemical Techniques." In CORROSION 2009. NACE International, 2009. https://doi.org/10.5006/c2009-09172.

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Abstract Chromated copper arsenate (CCA), the most widely used wood preservative of the past 50 years, has been replaced for most uses with alkaline-copper systems such as alkaline copper quaternary (ACQ), copper azole (CuAz) and micronized copper quaternary (MCQ). Preliminary research using high-temperature, high-humidity environments have shown that some of these wood preservatives are more corrosive than CCA, although it is unclear how the results of these extreme tests correlate to performance at temperatures and humidities seen in-service. Recently, the authors developed an electrochemica
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da T. Silva, Mayara A., Jean V. Ferrari, and Idalina V. Aoki. "Corrosion Behavior of Halloysite Nanotubes Loaded with Quaternary Imidazoline Based Inhibitor." In LatinCORR 2023. AMPP, 2023. https://doi.org/10.5006/lac23-20403.

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In oil exploitation, carbon dioxide, hydrogen sulfide, and dissolved salts (mainly sodium chloride) can cause severe substantial corrosion to the pipelines. Additives such as corrosion inhibitors are one of the most viable solutions for dealing with corrosion problems arising from different process conditions in oil and gas production [1]. Typically, film former inhibitors are used on a large scale, and aliphatic diamines or imidazolines with long carbon chains are examples of effectiveness [2]. This study aims to evaluate the corrosion performance of quaternary imidazoline loaded on halloysit
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De Turris, Antonio, Matilde de Romero, Sankara Papavinasam, and Rolando Lastra. "Effect of SRB, CO2, Crude Oil and Chemical Treatment on the Corrosivity of Synthetic Produced Water." In CORROSION 2013. NACE International, 2013. https://doi.org/10.5006/c2013-02213.

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Abstract The combined effect of sulphate-reducing bacteria (SRB), CO2 and crude oil on the corrosion of carbon steel in produced water were investigated using a rotating cage. During the experiment, pH, planktonic SRB, and concentrations of sulphide, sulphate, iron, calcium and magnesium ions were monitored. After the experiment, the sessile SRB were enumerated by serial dilution and optical microscopy, scanning electron microscopy, mass loss and laser profilometry were used to identify corrosion products, bacterial cell and corrosion rate. Both mass loss and localized pitting corrosion were t
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Eskinja, Magdalena, Gregor Mori, Masoud Moshtaghi, Stefan Hönig, and Gerald Zehethofer. "The Interaction of Quaternary Ammonium Compounds Based Corrosion Inhibitor with Carbon Steel in CO2 Saturated NaCl Solution." In CONFERENCE 2023. AMPP, 2023. https://doi.org/10.5006/c2023-19515.

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Abstract Carbon steel is commonly used structural material for pipelines in oil and gas industry due to its economic feasibility. However, it is characterized by high susceptibility to corrosion attack and for this reason corrosion inhibitors are in majority of cases utilized to protect the steel. This paper investigates the interaction between quaternary ammonium compound-based inhibitor and carbon steel, C1020. The efficiency and impact of inhibitor on corrosion rate behavior of carbon steel was assessed through linear polarization resistance (LPR) under conditions representative in oil fiel
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Al Hashem, A., J. Carew, A. Al-Borno, and M. Brown. "The Synergistic / Antagonistic Effect of Water Treatment Chemicals on Corrosion Inhibition of Carbon Steel in the Water Injection System of West Kuwait Oil Fields." In CORROSION 2005. NACE International, 2005. https://doi.org/10.5006/c2005-05279.

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Abstract This study evaluated the corrosion inhibition of three corrosion inhibitors and particularly the influence of their complementary biocide and scale inhibitors to treat aquifer and effluent brines used in water injection systems of West Kuwait oil fields. The Rotating Cylinder Electrode (RCE) test was first used to measure the performance of the chemicals under shear conditions. The best two performing inhibitors were then tested in an autoclave to observe their performance under actual system pressure and temperature. In the RCE test the biocide and the scale inhibitors from each supp
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Xu, Limin, Tao Chen, Ming Han, and Mohammed Bataweel. "Corrosion Inhibition of Carbon Steel in Carbonate Acidizing at Elevated Temperature." In CONFERENCE 2022. AMPP, 2022. https://doi.org/10.5006/c2022-17562.

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Abstract This paper presents an investigation on the performance of corrosion inhibitors in reducing corrosion loss of N80 steel coupons at high temperature in 15 wt.% and 28 wt.% HCl solutions. This work studied the effect of temperature and acid concentration on corrosion inhibitor performance and provided an efficient corrosion inhibitor for application at elevated temperature of 120°C. Five corrosion inhibitors including Mannich base derivatives and pyridine quaternary ammonium salt were selected. The corrosion rates of N80 steel in concentrated HCl solution with and without corrosion inhi
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Zhang, Yucheng, Kewei Gao, and Guenter Schmitt. "Inhibition of Steel Corrosion under Aqueous Supercritical CO2 Conditions." In CORROSION 2011. NACE International, 2011. https://doi.org/10.5006/c2011-11379.

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Abstract Rotated cage corrosion experiments (4 m/s) were performed with flat coupons of 2 carbon steels (38Mn6/C75, X65) and 3 corrosion resistant alloys [X20Cr13, X2CrNiMoN22-5-3 (1.4462, duplex) and X1NiCrMoCu 25-20-5 (1.4539; alloy 904L)] in water saturated with CO2 under conditions of supercritical carbon dioxide (scCO2). In this corrosion system the performance of inhibitors (oleic acid-based imidazolines, alkenylsuccinic acid anhydrides, and quaternary ammonium salts) was studied at 50, 80, 110 and 130°C using mass loss measurements and topographical scanning (in case of localized attack
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Singh, Himanshu, and Sumit Sharma. "Understanding the Adsorption Morphologies of Quaternary Ammonium-based Corrosion Inhibitors at Metal-Water Interfaces via Molecular Simulations." In CORROSION 2021. AMPP, 2021. https://doi.org/10.5006/c2021-16638.

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Abstract In this work, we perform all-atom molecular dynamics simulations to study the adsorption morphology of alkyldimethylbenzyl ammonium bromides (henceforth referred as q-c molecules). Our simulations reveal that q-c12 molecules (inhibitor molecules with 12 carbon atom long tail) adsorb in an ordered, standing-up orientation on the metal surface, whereas the adsorption of q-c4 molecules (inhibitor molecule with 4 carbon atom long tail) is rather disordered. Our free energy calculations further support that because of an ordered adsorption, a greater number of q-c12 molecules adsorb onto t
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