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Academic literature on the topic 'Rare earths. Rocks, Sedimentary. Rocks, Carbonate'
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Journal articles on the topic "Rare earths. Rocks, Sedimentary. Rocks, Carbonate"
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Peter, Jan M., and Wayne D. Goodfellow. "Mineralogy, bulk and rare earth element geochemistry of massive sulphide-associated hydrothermal sediments of the Brunswick Horizon, Bathurst Mining Camp, New Brunswick." Canadian Journal of Earth Sciences 33, no. 2 (February 1, 1996): 252–83. http://dx.doi.org/10.1139/e96-021.
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Massive sulphides are spatially and temporally associated with iron formation (IF) and other hydrothermal sedimentary rocks in the vicinity of the Brunswick No. 12, Brunswick No. 6, and Austin Brook deposits, Bathurst Mining Camp. Sulphide-, carbonate-, oxide-, and silicate-predominant IF is present. Carbonate-predominant IF is best developed in and around the Brunswick No. 12 deposit, whereas hematite-bearing IF is absent here but prominent in the Austin Brook–Brunswick No. 6 area. The IF is composed dominantly of Si, CO2, Fe, Mn, and Ca. Minor constituents include Mg, P, Ti, Al, and S. Statistically significant interelement correlations between Eu, Fe, Mn, Pb, Zn, Cd, Au, Ca, Sr, Ba, P, CO2, and S indicate that these elements were precipitated from hydrothermal fluids vented onto the seafloor. Positive interelement correlations between Si, Ti, Al, Mg, K, Zr, rare earth elements (REE's) except Eu, Se, V, Y, Yb, Co, Ni, and Cr reflect the presence of detrital clastic mafic and aluminosilicate minerals and hydrogenous sedimentary components. Felsic volcanic and pyroclastic rocks are considered to be the source for the detritus. REE patterns of IF at Brunswick No. 12 display similarities with those of modern high-temperature hydrothermal vent solutions, sea water, and host rhyolitic tuff and sedimentary rocks. These patterns are largely controlled by the relative proportions of hydrothermal and detrital components. The IF formed from reduced hydrothermal fluids vented into a stratified marine basin. The mineral precipitates were widely dispersed from the sites of venting and massive sulphide accumulation.
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Dub, S. A., N. V. Cherednichenko, D. V. Kiseleva, N. P. Gorbunova, T. Ya Gulyaeva, and L. K. Deryugina. "Trace element behaviour in acidic leachates (acetic, nitric and hydrochloric) from siliciclastic-carbonate rocks of the Upper Riphean Uk formation in the Southern Urals." LITHOSPHERE (Russia) 19, no. 6 (January 3, 2020): 919–44. http://dx.doi.org/10.24930/1681-9004-2019-19-6-919-944.
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Research subject. 14 samples of limestone and one sample of carbonate-siliciclastic rock from siliciclastic-carbonate deposits of the Upper Riphean Uk Formation (the Southern Urals) were studied.Methods. Mineral and chemical composition of the samples were determined; the main tool for detecting the concentrations of trace elements was the ICPMS method. X-ray diffraction analysis was carried out using a Shimadzu XRD-7000 diffractometer, the content of major (rock-forming) oxides in bulk samples was established by X-ray fluorescence spectrometry on the SRM-35 and Shimadzu XRF 1800 spectrometers. Microelement composition of bulk samples and acidic leachates obtained with using acetic (10%), nitric (36%) and hydrochloric (17%) acids was determined on a Perkin Elmer ELAN 9000 spectrometer.Results. The distribution of lithophile, rare-earth and a number of other elements (Sr, Ni, U) both in bulk samples and in acidic leachates was analyzed. The main carrier phases of these elements were revealed.Conclusions. 1. The use of any listed acids leads to the non-carbonate component entering the solution, including contamination of the “carbonate” leachates by lithophile elements. In particular, a transition Rb, Zr, Li, Th, Ti, Sc to leachates was noted. This process is most active in nitric and hydrochloric acids, less intensive in acetic acid. 2. Among the carriers of rare earth elements (REE) in the studied rocks are clays (1), accessory minerals (2), including phosphate-bearing grains, secondary carbonate phases represented by dolomite and, possibly (3), finely disseminated iron and manganese (oxy)hydroxides (4). It is assumed that the REE pattern in limestones is determined by the content of the epigenetic dolomite. The contribution of lanthanides bound in the sedimentary calcite crystal lattice in the total REE pattern is rather large only in relatively “pure” limestones. However, the use of acids with such concentrations did not allow to obtain a leachate, which the REE pattern with high probability corresponds to the distribution of REE in the Uk time seawater. But acetic acid is more effective for achieving this goal than the others. 3. In addition to Sr, sedimentary calcite also contains Ni and U.
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Giuliani, Gaston, Lee Groat, Anthony Fallick, Isabella Pignatelli, and Vincent Pardieu. "Ruby Deposits: A Review and Geological Classification." Minerals 10, no. 7 (June 30, 2020): 597. http://dx.doi.org/10.3390/min10070597.
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Corundum is not uncommon on Earth but the gem varieties of ruby and sapphire are relatively rare. Gem corundum deposits are classified as primary and secondary deposits. Primary deposits contain corundum either in the rocks where it crystallized or as xenocrysts and xenoliths carried by magmas to the Earth’s surface. Classification systems for corundum deposits are based on different mineralogical and geological features. An up-to-date classification scheme for ruby deposits is described in the present paper. Ruby forms in mafic or felsic geological environments, or in metamorphosed carbonate platforms but it is always associated with rocks depleted in silica and enriched in alumina. Two major geological environments are favorable for the presence of ruby: (1) amphibolite to medium pressure granulite facies metamorphic belts and (2) alkaline basaltic volcanism in continental rifting environments. Primary ruby deposits formed from the Archean (2.71 Ga) in Greenland to the Pliocene (5 Ma) in Nepal. Secondary ruby deposits have formed at various times from the erosion of metamorphic belts (since the Precambrian) and alkali basalts (from the Cenozoic to the Quaternary). Primary ruby deposits are subdivided into two types based on their geological environment of formation: (Type I) magmatic-related and (Type II) metamorphic-related. Type I is characterized by two sub-types, specifically Type IA where xenocrysts or xenoliths of gem ruby of metamorphic (sometimes magmatic) origin are hosted by alkali basalts (Madagascar and others), and Type IB corresponding to xenocrysts of ruby in kimberlite (Democratic Republic of Congo). Type II also has two sub-types; metamorphic deposits sensu stricto (Type IIA) that formed in amphibolite to granulite facies environments, and metamorphic-metasomatic deposits (Type IIB) formed via high fluid–rock interaction and metasomatism. Secondary ruby deposits, i.e., placers are termed sedimentary-related (Type III). These placers are hosted in sedimentary rocks (soil, rudite, arenite, and silt) that formed via erosion, gravity effect, mechanical transport, and sedimentation along slopes or basins related to neotectonic motions and deformation.
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Li, Ying Shu, Yan Cai, Jiao Jiao Chen, Nan Chen, Lun Wang, Yi Ke Zhang, and Da Qing He. "Isotopic Dating and Geological Significance of Stratiform Orebody in Gejiu Tin Deposit, Yunnan, China." Advanced Materials Research 616-618 (December 2012): 43–47. http://dx.doi.org/10.4028/www.scientific.net/amr.616-618.43.
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Gejiu tin ore deposit is a famous tin-polymetallic deposit in the world because of its enormous metal reserves. Besides tin, there are copper, lead, zinc, silver, iron, sulphur, tungsten, bismuth, indium and rare earth elements. It was believed that there mainly are skarn-type tin deposit, stratiform tin deposit and basalt-type copper deposit in Gejiu tin orefield. The stratiform tin deposit are distributed in Lutangba, Malage and Huangmaoshan, which are hosted by carbonate rocks of Gejiu formation in Middle Triassic Series. 40Ar-39Ar dating of cassiterite from the sratiform tin deposit in Lutangba yields plateau age of 202.18±2.35Ma and isochron age of 206.81±3.23 Ma respectively. The ages are obviously older than those of the ore of the skarn type deposit of the Yanshanian epoch．The mineralization is the seabed exhalative hydrothermal sedimentary mineralization of the Indosinia epoch.
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James, Noel P., Guy M. Narbonne, and T. Kurtis Kyser. "Late Neoproterozoic cap carbonates: Mackenzie Mountains, northwestern Canada: precipitation and global glacial meltdown." Canadian Journal of Earth Sciences 38, no. 8 (August 1, 2001): 1229–62. http://dx.doi.org/10.1139/e01-046.
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The 3-27 m-thick cap carbonate overlying "Marinoan" Ice Brook Formation glacigene sediments and Keele Formation carbonate and terrigenous clastic rocks consists of two distinctive stratigraphic units. A lower, splintery, buff-weathering, microcrystalline dolostone of extensive lateral uniformity comprises mm-laminated peloidal sediment with local, low-angle, hummocky-like cross-stratification, micro-ridges, and synsedimentary tepees, all elongated perpendicular to depositional strike. This dolostone is unconformably overlain by an upper limestone that exhibits pronounced facies variation from inboard peloidal lime grainstone and mudstone to shelf-edge cementstone to outboard lime wackestone and mudstone. Calcite cementstones range from isolated crystal fans in laminated limestone to huge, decimetre-scale crystal arrays, to hemispherical and elongate crystal stromatolites wholly composed of acicular crystals that form decametre-scale reeflike structures. Crystal stromatolites are precipitates and replaced microbiolites that constructed biostromes and bioherms, like those on many flat-topped, reef-rimmed platforms. The calcite crystals have all the physical and chemical attributes of neomorphosed aragonite. This aragonite extensively replaced sediment and microbiolite just below the sea floor and grew upward into the overlying water column. Such interpreted massive synsedimentary replacement is rare in geological history and attests to the highly saturated state of the immediate postglacial ocean. All sediment is interpreted to have been CaCO3 originally. Low and constant δ18O values reflect diagenetic modification of these carbonates, although chemical attributes, such as Sr and C isotopes in some lithologies, are near pristine. Lower dolostones, virtually identical to most other coeval Marinoan caps worldwide, were part of a global precipitation event of remarkable similarity. Upper limestones are a more local phenomenon, deposited during sea-level rise in an aragonitic sea returning to equilibrium after global glaciation. Low 87Sr/86Sr ratios and varying δ13C values with carbonate sedimentary facies indicate that both units must have formed relatively rapidly, prior to significant fluvioglacial runoff, or that the influence of this runoff on the chemistry of seawater along continental shelves was minimal. The cap carbonate is thus interpreted to have formed in two steps: (1) during initial marine ice melting accompanied by oceanic overturn and upwelling, preceding continental margin rebound, and (2) during initial stages of sea-level rise accompanying continental deglaciation. While confirming brief, but extensive, carbonate precipitation from an ocean highly perturbed by global glaciation, the rocks also suggest that this event did not permanently affect either late Neoproterozoic ocean chemistry or the contained marine biosphere.
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Corriveau, Louise, and Anne-Laure Bonnet. "Pinwarian (1.50 Ga) volcanism and hydrothermal activity at the eastern margin of the Wakeham Group, Grenville Province, Quebec." Canadian Journal of Earth Sciences 42, no. 10 (October 1, 2005): 1749–82. http://dx.doi.org/10.1139/e05-086.
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Volcanic belts developed along the southeastern continental margin of Laurentia between 1.70 and 1.30 Ga and subsequently metamorphosed at high grade are today largely concealed among gneiss complexes of the Grenville Province. At the eastern end of the Wakeham Group and in the La Romaine Supracrustal Belt to the east, four 1.50 Ga volcanic centres were found among gneissic synvolcanic intrusions typical of the 1.521.46 Ga Pinwarian continental magmatic arc. Upper amphibolite- to granulite-facies rhyolitic to dacitic lavas and coarse lapillistone overlie or are intimately associated with arenites typical of the Wakeham Group. Garnetite, ironstone, carbonate rock, calc-silicate rock, and sillimanite-bearing nodules, veins, and gneiss, locally preserving lapilli, are also present. The distribution, paragenesis, and modes of most of these latter units differ from those of normal metasediments but are diagnostic of metamorphosed exhalites and hydrothermal alteration zones. In the La Romaine Supracrustal Belt, they are associated with pyroclastic horizons and a mineralized composite amphibolite unit. Volcanic textures include flow banding, wispy lapilli moulding fragmented lapilli and rounded lapilli with quartz-feldspar mosaics (filled vesicles), and in situ shattering of lapilli. These textures and the presence of advanced argillic alteration point to vesicular volcanism and hydrothermal activity in a subaerial to shallow submarine environment. Rare mafic lapilli attest to coeval mafic magmatism. The pervasive calc-alkaline signature of the eruptive and intrusive felsic to mafic rocks and their distribution are compatible with the development of 1.50 Ga intra-arc volcano-sedimentary belts stemming from the Wakeham Group basin and extending eastward within the Pinwarian continental magmatic arc.
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Brugger, J., J. Ogierman, A. Pring, H. Waldron, and U. Kolitsch. "Origin of the secondary REE-minerals at the Paratoo copper deposit near Yunta, South Australia." Mineralogical Magazine 70, no. 6 (December 2006): 609–27. http://dx.doi.org/10.1180/0026461067060361.
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AbstractThe Paratoo copper deposit, located in the Neoproterozoic to Cambrian Adelaide Geosyncline, South Australia, produced around 360 tons of Cu between 1888 and 1967 from oxidized ores. The deposit is located in the core of a breached, doubly plunging anticline, near a zone of disruption containing brecciated Adelaidean sedimentary rocks and dolerite (‘Paratoo Diapir’), and hosted in dolomitic shales of the Neoproterozoic Burra Formation. Near the surface, the mineralization resides mainly in deeply weathered quartz-magnetite-sulphide (pyrite, chalcopyrite) veins (⩽10 cm wide). At depth, drill cores reveal disseminated magnetite, pyrite, chalcopyrite, copper sulphide and native copper associated with extensive potassic alteration. K-Na-rich fluids also affected the dolerite in the ‘Paratoo diapir’, resulting in the precipitation of K-feldspar, dravite and K-bearing chabazite-Na. The most likely scenario for the genesis of the Paratoo deposit involves circulation of basinal fluids, focusing into the ‘Paratoo Diapir’, and ore precipitation through neutralization by fluid-rock interaction with the dolomitic shales hosting the mineralization.The Paratoo deposit is deeply weathered, with malachite and chrysocolla (± tenorite and cuprite) containing the bulk of the copper recovered from the shallow workings. A diverse assemblage of secondary REE-bearing carbonate minerals, including the new species decrespignyite-(Y) and paratooite-(La), is associated with the weathered base metal and magnetite ores. Whole-rock geochemical analyses of fresh and mineralized host rock and of vein material reveals that the mineralization is associated with a strong, albeit highly variable, enrichment in light rare earth elements (LREE). This association indicates that REE and base metals were introduced by the same hydrothermal fluid. The strong negative Ce anomaly found in secondary REE minerals and mineralized rock samples suggests an upgrade of the REE contents in the weathering zone, insoluble Ce4+ being left behind.The Fe-oxide-REE-base metal association at Paratoo is also characteristic of the giant Mesoproterozoic Fe oxide copper gold deposit of Olympic Dam, located 350 km to the NW. A similar association is found in the Palaeozoic deposits of the Mt Painter Inlier, 300 km to the NNE. The widespread occurrence of this elemental association in the Province probably reflects the geochemistry of the basement, which contains numerous Mesoproterozoic granites enriched in REE and U.
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Lodes, Emma, Nancy R. Riggs, Michael E. Smith, and Paul Stone. "Cordilleran Subduction Initiation: Retroarc Timing and Basinal Response in the Inyo Mountains, Eastern California." Lithosphere 2020, no. 1 (December 24, 2020): 1–20. http://dx.doi.org/10.2113/2020/9406113.
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Abstract Subduction zones drive plate tectonics on Earth, yet subduction initiation and the related upper plate depositional and structural kinematics remain poorly understood because upper plate records are rare and often strongly overprinted by magmatism and deformation. During the late Paleozoic time, Laurentia’s western margin was truncated by a sinistral strike-slip fault that transformed into a subduction zone. Thick Permian strata in the Inyo Mountains of central-eastern California record this transition. Two basins that were separated by a transpressional antiform contain sedimentary lithofacies that record distinct patterns of shoaling and deepening conditions before and during tectonism associated with subduction initiation. Sandstone petrography and lithofacies analysis show that rocks in a southeastern basin are dominated by carbonate grains derived from adjacent carbonate shelves, whereas sandstones in a northwestern basin are predominantly quartzose with likely derivation from distant ergs or underlying strata. Detrital zircon spectra from all but the youngest strata in both basins are typical of Laurentian continent spectra with prominent peaks that indicate ultimate sources in Appalachia, Grenville, Yavapai/Mazatzal, and the Wyoming or Superior cratons. The first Cordilleran arc-derived detrital zircon grains appear in the uppermost strata of the northwestern basin and record Late Permian (ca. 260 Ma) Cordilleran arc magmatism at this approximate latitude, and a possible source area is suggested by geochemical similarities between these detrital zircons and broadly coeval magmatic zircons in the El Paso Mountains to the southwest. Deformation responsible for basin partitioning is consistent with sinistrally oblique contraction in the earliest Permian time. The data presented from the Inyo Mountains shed more light on the nature of Cordilleran subduction initiation and the upper-crustal response to this transition.
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Landing, Ed, Georgia Pe-Piper, William SF Kidd, and Karem Azmy. "Tectonic setting of outer trench slope volcanism: pillow basalt and limestone in the Taconian orogen of eastern New York." Canadian Journal of Earth Sciences 40, no. 12 (December 1, 2003): 1773–87. http://dx.doi.org/10.1139/e03-076.
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The only pillow basalt in synorogenic sedimentary rocks at the exterior margin of the Taconic orogen in eastern North America is at Stark's Knob in eastern New York. Earlier reported as extrusive into allochthonous Ordovician slope and rise facies, this small lens (ca. 125+ m long, 39 m thick) is a fault-bounded block in Upper Ordovician melange under the Taconian frontal thrust. Its N-MORB (normal mid-ocean ridge basalt) basalt geochemistry and spinel composition are characteristic of oceanic ridge settings at a water depth of 2 km or more. Abundant limestone lenses on pillows and lava shelves within pillows yielded a middle Late Ordovician gastropod. The limestones are reconciled with this extrusion depth and with limited early Paleozoic pelagic carbonate production by lime mud transport from the Laurentian platform or abiotic carbonate precipitation with sea-water heating during basalt extrusion. A genetic relationship between the parautochthonous Stark's Knob basalts and the allochthonous Jonestown volcanics in slope and rise facies of the Hamburg klippe, eastern Pennsylvania, is likely. Both are Ordovician MORB basalts that reflect volcanism on the subducting outer trench slope prior to the Taconic arc Laurentia collision. Taconic orogenesis may have led to basalt production on the subducting plate by (1) the setting up of orogen-parallel, predominantly strike-slip motion on the subducting slab with MORB basalt generated at offsets in a setting analogous to the Gulf of California or (2) development of faults in a flexure-induced extensional regime. By either process, mafic volcanism appears to be a rare but tectonically significant process on outer trench slopes as continental margins or oceanic plates enter subduction zones.
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Tolstov, Alexander, Vladimir Cherenkov, and Leonid Baranov. "GENESIS AND AGE OF THE TOMTOR Nb AND RARE-EARTH DEPOSIT ORE SEQUENCE, NORTHEASTERN SIBERIAN PLATFORM." Ores and metals, no. 4 (February 2, 2021): 32–44. http://dx.doi.org/10.47765/0869-5997-2020-10026.
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The northeastern Siberian platform (Republic of Sakha, Yakutia) hosts the Udzhinskaya province of alkaline ultrabasic massifs with carbonatites as final phases of magmatic system evolution; they form i ts central carbonatite core and are characterized by elevated Fe, Al and P concentrations. They also contain a complex of rare and rare-earth elements. Crust of laterite weathering of up to 400 m thick is present within the massifs. Phosphate, Nb, Y, Sc and TR content in crust of carbonatite weathering is much higher compared to unaltered rock differences. Their maximum values are in the sequence of specific sedimentary deposits f ormed a s denudation products of ore-bearing carbonatite crust precipitated in minor lake depressions and due to their intensive chemogenic transformation in hot humid climate. They are unique high-grade ores, with no world analogs in terms of mineral potential. Sometimes, these rocks are their natural concentrates averaging (in weight %) 7,21 Nb2O5, 0,578 Y2O3, 0,045 Sc2O3 and 10,16 TR2O3. The rocks composing the ore-bearing sequence show distinct evidence of sedimentary genesis: well-pronounced layered texture and facial zoning, presence of carbonized vegetable detrite and bacteriomorphic aggregates. Therefore, it is reasonable to regard a set of these formations as an independent stratigraphic unit, Tomtor sequence. Geological data suggest that it formed 340-280 Ma. Tomtor sequence can be an important prospecting criteria in prospecting for rare and rare-earth elements.
Books on the topic "Rare earths. Rocks, Sedimentary. Rocks, Carbonate"
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E, Baranov I͡U︡, Burenkov Ė K, Filatov E. I, and Institut mineralogii, geokhimii, i kristallokhimii redkikh ėlementov (Russia), eds. Metodicheskie rekomendat͡s︡ii po ispolʹzovanii͡u︡ geologo-geokhimicheskikh kriteriev ot͡s︡enki osadochnykh i vulkanogenno-osadochnykh format͡s︡iĭ na redkie i soputstvui͡u︡shchie metally. Moskva: IMGRĖ, 1990.
Find full textBook chapters on the topic "Rare earths. Rocks, Sedimentary. Rocks, Carbonate"
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Marsh, Erin E., Murray W. Hitzman, and David L. Leach. "Critical Elements in Sediment-Hosted Deposits (Clastic-Dominated Zn-Pb-Ag, Mississippi Valley-Type Zn-Pb, Sedimentary Rock-Hosted Stratiform Cu, and Carbonate-Hosted Polymetallic Deposits)A Review." In Rare Earth and Critical Elements in Ore Deposits. Society of Economic Geologists, 2016. http://dx.doi.org/10.5382/rev.18.12.
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