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Relevant bibliographies by topics / Resonance and Steric Effects

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Academic literature on the topic 'Resonance and Steric Effects'

Author: Grafiati

Published: 5 June 2025

Last updated: 1 August 2025

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Journal articles on the topic "Resonance and Steric Effects"

1

KULANDAIVELU, KARUNAKARAN, GURUMURTHY RAJAGOPALA, and PITCHAIMUTHU ELANGO KUPPANNAGOUNDER. "Steric and Resonance Effects on the Kinetics of Oxidation of Organic Sulfides by Quinolinium Fluorochromate." Journal of Indian Chemical Society Vol. 75, May 1998 (1998): 297–99. https://doi.org/10.5281/zenodo.5927158.

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Department of Chemistry, Annamalai University, Annamalainagar-608 002 Department of Chemistry, Gandhigram Rural Institute, Gandhigram-624 302 <em>Manuscript received 25 March 1996, revised 20 August 1997, accepted 30 September 1997</em> Kinetics of oxidation of dialkyl, alkyl phenyl and benzal methyl phenyl sulfides to their sulfoxides by quinolinium fluorochromate (QFC) have been followed in aqueous acetic acid. The order of the reaction is found to be one each with respect to QFC, H<sub>3</sub>O<sup>+</sup> and the sulfide. Increase in the dielectric constant of the medium decreases the rate

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V., BALIAH, and UMA M. "Influence of ortho-Substituents on the + M and - M Effects of SCH3 Group in Aryl Methyl Sulphides. A Study by Dipole Moments." Journal of Indian Chemical Society Vol. 69, Jan 1992 (1992): 21–23. https://doi.org/10.5281/zenodo.5991471.

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Department of Chemistry, Annamalai University, Annsmalainagat-008 002 <em>Manuscript received 10 April 1991, revised 12 September 1991, accepted 7 January 1992</em> The dipole moments of twelve aryl methyl sulphides have been determined. The effect of mono-<em>ortho</em>- and di-<em>ortho-</em>substitution on the +M and -M effects of the SCH, group has been analysed by a comparison of the observed and calculated dipole moments of aryl methyl sulphides A single substituent ortho to SCH, group is found to cause a slight steric enhancement of both the donor and acceptor resonances of SCH, Di

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Císařová, Ivana, Jaroslav Podlaha, Stanislav Böhm, and Otto Exner. "Steric Effects and Steric Inhibition of Resonance in Benzene Derivatives: 2,3-Dimethylbenzoic Acid." Collection of Czechoslovak Chemical Communications 65, no. 2 (2000): 216–26. http://dx.doi.org/10.1135/cccc20000216.

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Structure of 2,3-dimethylbenzoic acid was determined both by single-crystal X-ray diffraction and by ab initio calculation at an RHF/6-31+G** level. Comparing with a previous X-ray analysis of another crystal modification of the same compound, it was possible to estimate the effect of crystal forces on the conformation. The isolated molecule is not planar as deduced previously, mainly from IR spectra, but the carboxyl group is twisted out of the ring plane by a torsion angle ϕ = 12°. In the crystal, the molecule is more flat and ϕ is reduced to 7 and 1° in the two modifications, respectively.

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A., Abdul Jameel, and Krishna Pillay M. "Nature of ortho effect in the oxidation of ortho-substituted-benzaldehydes with pyridinium chlorochromate." Journal of Indian Chemical Society Vol. 76, Feb 1999 (1999): 101–3. https://doi.org/10.5281/zenodo.5852439.

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Department of Chemistry, Jamal Mohamed College, Tiruchirappalli-620 020, India Department of Chemistry, Bharathidasan University, Tiruchirappalli-620 024, India <em>Manuscript received 10 February 1998, revised 25 August 1998, accepted 9 September 1998</em> Rate constants for the oxidation reaction of ortlzo-substituted benzaldehydes with pyridinium chlorochromate are correlated with equations log <em>k</em><sub>2</sub>= ασ<sub>1</sub> + β σ<sub>k</sub> + <sup>\(\Psi\)</sup>  v +<em> h</em> log <em>k</em><sub>2</sub>= ασ<sub>1</sub> + β &s

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Ploom, Anu, Ants Tuulmets, and Jaak Järv. "Structure-reactivity relationships in organosilicon chemistry revisited." Open Chemistry 9, no. 5 (2011): 910–16. http://dx.doi.org/10.2478/s11532-011-0075-x.

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AbstractAvailable quantitative data of the reactivity of organosilicon compounds were subjected to correlation analysis. As an alternative to the carbon chemistry values, the scale of steric constants E S (Si) can be used for organosilicon compounds and the inductive effect is best expressed by two terms, involving the parameter of electronegativity of substituents. Alkyl substituents contribute to the reactivity exclusively through their steric effects, steric and polar effects in silicon compounds are additive and the resonance effect is insignificant. The correlation analysis can be employe

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Böhm, Stanislav, and Otto Exner. "Steric effects and steric inhibition of resonance: structure and ionization of 2-tert-butylbenzoic acid." New Journal of Chemistry 25, no. 2 (2001): 250–54. http://dx.doi.org/10.1039/b005691j.

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Fiedler, Pavel, Jiří Kulhánek, Michèle Decouzon, Jean-François Gal, Pierre-Charles Maria, and Otto Exner. "Steric Effects and Steric Inhibition of Resonance in Isopropylbenzoic Acids in the Gas Phase and in Solution." Collection of Czechoslovak Chemical Communications 64, no. 9 (1999): 1433–47. http://dx.doi.org/10.1135/cccc19991433.

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The substituent effects of the isopropyl group in 2-, 3- and 4-isopropylbenzoic acids were investigated on the enthalpies of formation, gas-phase acidities, acidities in methanol and in dimethyl sulfoxide, and on the IR spectra in tetrachloromethane. Particular attention was given to the influence of variable conformation on the observed steric effect. In contrast to 2-tert-butylbenzoic acid and similarly to 2-methylbenzoic acid, 2-isopropylbenzoic acid exists in two planar conformations in equilibrium. Due to this conformational freedom, the steric effects of the isopropyl group on the confor

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Kulhánek, Jiří, Michèle Decouzon, Jean-François Gal, et al. "Steric Effects and Steric Hindrance to Resonance intert-Butylbenzoic Acids in the Gas Phase and in Solution." European Journal of Organic Chemistry 1999, no. 7 (1999): 1589–94. http://dx.doi.org/10.1002/(sici)1099-0690(199907)1999:7<1589::aid-ejoc1589>3.0.co;2-s.

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Jovanovic, Bratislav, Fathi Assaleh, and Aleksandar Marinkovic. "Kinetics of the reaction of 5-substituted orotic acids with diazodiphenylmethane." Journal of the Serbian Chemical Society 69, no. 11 (2004): 949–53. http://dx.doi.org/10.2298/jsc0411949j.

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Rate konstants for the reaction of eight 5-substituted orotic acids with diazodiphenylmethane (DDM) in dimethylformamide (DMF) were determined at 30 ?C by the known spectrophotometricmethod. The determined rate constants were correlated with the equations: logk2 = ??1+??R+h logk2 = ??1+??R+??+h to detect the presence and investigate the influence of both electrical and steric substituent effects. The obtained results show that the electrical effect (the localized ? field and delocalized ? resonance) is predominant and that the steric effect, althought present, is releatively small in this reac

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Yamagami, C., N. Takao та Y. Takeuchi. "15N Nuclear Magnetic-Resonance Spectra of ortho-Substituted Phenylacetanilides: The Origin of γ-syn Effects". Australian Journal of Chemistry 42, № 4 (1989): 463. http://dx.doi.org/10.1071/ch9890463.

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The 15N chemical shifts of X α and Y α, i.e., the nuclei through which the side chains, X and Y, respectively, of o-substituted phenylacetanilides (2a) are bonded to the aromatic ring were determined. There was observed a uniform upfield shift (γsyn effect). In order to explore the origin of the γ effect, other o-disubstitutes benzenes (2b-d) were also examined. The values of D, defined as the difference between γ α substituent chemical shifts of the ortho (2) and para (3) series of compounds, and considered as a measure of the γ-syn effect, were correlated with various electronic and steric s

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Dissertations / Theses on the topic "Resonance and Steric Effects"

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Liu, Sung Ying. "Steric effects in Lanthanide pyrazolylborate chemistry." Thesis, University College London (University of London), 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.561271.

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Massat, Alain. "Spectroscopie infra-rouge de cetones aliphatiques saturees : comportement associatif et analyse du massif nu(c=0) : apport a l'elucidation des effets de structure, de solvant et de conformation." Paris 7, 1987. http://www.theses.fr/1987PA077002.

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Un modele conformationnel est etabli pour une population de cetones aliphatiques saturees a partir des massifs nu (oh) de phenols associes aux cetones et des massifs nu (co) des cetones du splitting de ces massifs sont analyses: existance de deux complexes dimeres supposes n et pi; existence d'equilibres conformationnels; resonance de fermi

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McLachlan, Lorna J. "Steric and electronic effects on the structures of substituted silicon compounds." Thesis, University of Edinburgh, 2004. http://hdl.handle.net/1842/15345.

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This thesis is concerned with the application of the SARACEN method to a range of molecules with interesting structural properties and applications in industry. The gas-phase structures of a series of compounds have been obtained, combining gas-phase electron diffraction and <i>ab initio </i>molecular orbital theory. For each compound a series of the potential energy surface was carried out to investigate the number of conformational minima and to locate the global energy minimum. The gas-phase structures of <i>trans-</i>1,2-dichloro-1,2-disilylethene (1), 1,1-bromosilylethene (2) and 1,1,1,4,

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Bachir, Alexia. "Characterization of quantum dot blinking and steric effects on fluorescence-based biophysical techniques." Thesis, McGill University, 2008. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=19293.

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Semiconductor nanoparticles, or quantum dots (QDs) are being increasingly applied as luminescent labels in optical studies for biophysical and cell biological applications due to their unique spectroscopic properties as compared to traditional organic fluorescent probes. However, the intermittency in the fluorescence emission of QDs, commonly referred to as 'blinking', is suggested to affect transport studies using fluctuation correlation techniques. The QD size has also been suggested to be sterically limiting for some st

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Laitinen, R. (Riitta). "New heterodonor phosphine and bipyridine ligands." Doctoral thesis, University of Oulu, 1999. http://urn.fi/urn:isbn:9514252292.

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Abstract Twenty-seven phosphine and six bipyridine ligands were synthesised and characterized. Additionally, a new route to the family of phosphine ligands via o-thioanisyldichlorophosphine was found. The phosphine ligands contain thiomethylphenyl, methoxyphenyl, dimethylaminophenyl, pyridyl, naphthyl and anthracenyl groups, and the bipyridine ligands thiomorpholine and piperidine groups. Metal complexes of 3-pyridyldiphenylphosphine, 6,6'-bis(methylthiomorpholine)-2,2'-bipyridine and 4,4'-dimethyl-6,6'-bis(methylthiomorpholine)-2,2'-bipyridine were prepared. Ligands and complexes were charac

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Smith, Adam C. R. "The Effects of Carrier Ligands on Cisplatin Binding to Cysteine and Methionine." TopSCHOLAR®, 2017. http://digitalcommons.wku.edu/theses/1969.

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We have reacted several derivatives of the anticancer drug cisplatin with N-acetyl-Lcysteine (N-AcCys) and N-acetyl-L-methionine (N-AcMet), which are two of the primary amino acid targets of platinum. NMR spectroscopy was used to monitor the reactions and determine the effect the different ligands would have on the platinum reactivity. Several of the platinum compounds were tested at pH of 4 and 7, and with platinum:amino acid ratios of 1:1, 2:1 and 1:2. Competition reactions between cysteine and methionine were done to confirm which would react with the platinum compound first. [Pt(dien)(NO3)

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Rowland, Keith E. (Keith Edward). "An NMR Investigation of Aryl Mercury Compounds." Thesis, North Texas State University, 1987. https://digital.library.unt.edu/ark:/67531/metadc500453/.

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A variable temperature ^13 C and ^199 Hg NMR study has been conducted for diphenyl-, bis(o-tolyl)-, bis(m-tolyl)-, and bis(2, 6-xylyl)mercury in dimethyl sulfoxide and 1,1,2,2 tetrachloroethane; ^13 C T1 relaxation times are reported as a function of temperature. Barriers to rotation of the aryl rings are obtained. Chemical shifts and couplings in CDCl_3 are given for bis(p-tolyl)-, bis(2, 5-xylyl)-, bis(mesityl)-,phenyl(o-tolyl)-, phenyl(m-tolyl)mercury, and the compounds listed above. The steric interactions of these aryl mercury compounds are discussed.

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Sethuraman, Swaminathan. "New measures and effects of stochastic resonance." Thesis, Texas A&M University, 2004. http://hdl.handle.net/1969.1/2705.

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In the case of wideband (aperiodic) signals, the classical signal and noise measures used to characterize stochastic resonance do not work because their way of distinguishing signal from noise fails. In a study published earlier (L. B. Kish, 1996), a new way of measuring and identifying noise and aperiodic (wideband) signals during strongly nonlinear transfer was introduced. The method was based on using cross-spectra between the input and the output. According to the study, in the case of linear transfer and sinusoidal signals, the method gives the same results as the classical method and in

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Liau, Joy. "Baseline effects in functional magnetic resonance imaging." Diss., Connect to a 24 p. preview or request complete full text in PDF format. Access restricted to UC campuses, 2008. http://wwwlib.umi.com/cr/ucsd/fullcit?p3330237.

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Thesis (Ph. D.)--University of California, San Diego, 2008.<br>Title from first page of PDF file (viewed February 6, 2009). Available via ProQuest Digital Dissertations. Vita. Includes bibliographical references (p. 125-131).

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Kahan, Rachel Jennifer. "Investigating the steric and electronic effects of low-valent uranium complexes on the activation of small molecules." Thesis, University of Sussex, 2015. http://sro.sussex.ac.uk/id/eprint/54170/.

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In the last decade substantial progress has been made in our understanding of uranium organometallic chemistry, specifically regarding the activation of small molecules by uranium(III) complexes. Research by Cloke and colleagues has employed dianionic eight- and monoanionic five-membered aromatic ligands around a uranium(III) centre to make mixed-sandwich systems, which have demonstrated novel reactivity with carbon monoxide and carbon dioxide. This thesis continues this work and furthers our understanding of the properties and reactivity of these complexes. The first part of this thesis descr

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Books on the topic "Resonance and Steric Effects"

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Yadav, Veejendra K. Steric and Stereoelectronic Effects in Organic Chemistry. Springer International Publishing, 2021. http://dx.doi.org/10.1007/978-3-030-75622-2.

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Yadav, Veejendra K. Steric and Stereoelectronic Effects in Organic Chemistry. Springer Singapore, 2016. http://dx.doi.org/10.1007/978-981-10-1139-9.

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D, Peyerimhoff Sigrid, Deutsche Forschungsgemeinschaft, and Collaborative Research Centre 334 "Wechselwirkung in Molekülen: Synthese, spektroskopische Analyse und quatentheoretische Behandlung charakteristischer Strukturen.", eds. Interactions in molecules: Electronic and steric effects. Wiley-VCH, 2003.

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Allinger, Norman L. Molecular structure: Understanding steric and electronic effects from molecular mechanics. Wiley, 2010.

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Geru, Ion, and Dieter Suter. Resonance Effects of Excitons and Electrons. Springer Berlin Heidelberg, 2013. http://dx.doi.org/10.1007/978-3-642-35807-4.

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1936-, Tawara H., and Dunn G. H. 1932-, eds. Resonance effects in electron-ion collisions. Institute of Plasma Physics, Nagoya University, 1986.

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Yoder, Bruce L. Steric Effects in the Chemisorption of Vibrationally Excited Methane on Nickel. Springer Berlin Heidelberg, 2012. http://dx.doi.org/10.1007/978-3-642-27679-8.

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Shellock, Frank G. Magnetic resonance procedures: Health effects and safety. CRC Press, 2001.

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1946-, Berger Stefan, ed. Isotope effects in NMR spectroscopy. Springer-Verlag, 1990.

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1942-, Francik A., ed. Instrumental effects in homodyne electron paramagnetic resonance spectrometers. E. Horwood, 1989.

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Book chapters on the topic "Resonance and Steric Effects"

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Gallo, Roger. "Treatment of Steric Effects." In Progress in Physical Organic Chemistry. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470171936.ch3.

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Carey, Francis A., and Richard J. Sundberg. "Conformational, Steric, and Stereoelectronic Effects." In Advanced Organic Chemistry. Springer US, 1990. http://dx.doi.org/10.1007/978-1-4613-9795-3_3.

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Unger, S. H., and Corwin Hansch. "Quantitative Models of Steric Effects." In Progress in Physical Organic Chemistry. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470171912.ch4.

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Grote, W., M. Hoffmeister, R. Schleysing, H. Zerhau-Dreihöfer, and H. J. Loesch. "Rotational and Steric Effects in Three Centre Reactions." In Selectivity in Chemical Reactions. Springer Netherlands, 1988. http://dx.doi.org/10.1007/978-94-009-3047-6_3.

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Caldin, E. F., and A. Queen. "Diffusion and Steric Effects in Very Fast Reactions." In Reactions in Compartmentalized Liquids. Springer Berlin Heidelberg, 1989. http://dx.doi.org/10.1007/978-3-642-74787-8_23.

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Buckingham, D. A., and A. M. Sargeson. "Conformational Analysis and Steric Effects in Metal Chelates." In Topics in Stereochemistry. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470147153.ch5.

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Yadav, Veejendra K. "Steric and Stereoelectronic Control of Organic Molecular Structures and Organic Reactions." In Steric and Stereoelectronic Effects in Organic Chemistry. Springer Singapore, 2016. http://dx.doi.org/10.1007/978-981-10-1139-9_1.

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Yadav, Veejendra K. "Reactions at Saturated and Unsaturated Carbons." In Steric and Stereoelectronic Effects in Organic Chemistry. Springer Singapore, 2016. http://dx.doi.org/10.1007/978-981-10-1139-9_2.

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Yadav, Veejendra K. "Diastereoselectivity in Organic Reactions." In Steric and Stereoelectronic Effects in Organic Chemistry. Springer Singapore, 2016. http://dx.doi.org/10.1007/978-981-10-1139-9_3.

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Yadav, Veejendra K. "A(1,2) and A(1,3) Strains." In Steric and Stereoelectronic Effects in Organic Chemistry. Springer Singapore, 2016. http://dx.doi.org/10.1007/978-981-10-1139-9_4.

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Conference papers on the topic "Resonance and Steric Effects"

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Ristau, D., H. P. Geromiller, S. Weiss, D. Hansen, and A. Kost. "Investigation of Resonance Effects in GTEM-Cell 1750." In 1996_EMC-Europe_Roma. IEEE, 1996. https://doi.org/10.23919/emc.1996.10783821.

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Glushkov, Evgeny V., Natalia V. Glushkova, and Alexander A. Tatarkin. "Guided Waves and Resonance Effects in Piezoelectric Laminate Structures." In 2024 Days on Diffraction (DD). IEEE, 2024. https://doi.org/10.1109/dd62861.2024.10768012.

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Gonschorek, K. H., V. Schmidt, and H. E. Tode. "The Effects of Resonance in Cable-to-Cable Coupling." In 8th International Zurich Symposium and Technical Exhibition on Electromagnetic Compatibility. IEEE, 1989. https://doi.org/10.23919/emc.1989.10779074.

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Janda, Martin, Hans Bärnklau, and Jaroslav Dragoun. "Electric Resonance Effects in Electric Machines – How to Measure Them?" In 2024 IEEE 21st International Power Electronics and Motion Control Conference (PEMC). IEEE, 2024. http://dx.doi.org/10.1109/pemc61721.2024.10726393.

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Holzmann, Simon, Kai Franck, and Christian Schumann. "Measuring of Parasitic Inductances Through Resonance Effects in GaN Half-Bridges." In 2024 IEEE Design Methodologies Conference (DMC). IEEE, 2024. https://doi.org/10.1109/dmc62632.2024.10812127.

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Benincori, T., E. Brenna, F. Sannicolo, et al. "Steric effects in polybitniophenes." In International Conference on Science and Technology of Synthetic Metals. IEEE, 1994. http://dx.doi.org/10.1109/stsm.1994.835413.

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Gordon, Philip H., and Edwin C. Kan. "Dynamic modeling of steric effects on polarizable electrodes." In 2017 19th International Conference on Solid-State Sensors, Actuators and Microsystems (TRANSDUCERS). IEEE, 2017. http://dx.doi.org/10.1109/transducers.2017.7994336.

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Garg, Himanshu, and Pradeep R. Nair. "Stochastic Modeling of Steric Hindrance Effects in Biosensors." In 2018 IEEE Sensors. IEEE, 2018. http://dx.doi.org/10.1109/icsens.2018.8589812.

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Boldini, Alain, and Maurizio Porfiri. "What are steric effects? A purely continuum model." In Electroactive Polymer Actuators and Devices (EAPAD) XXV, edited by John D. Madden, Iain A. Anderson, and Herbert R. Shea. SPIE, 2023. http://dx.doi.org/10.1117/12.2658452.

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Afonja, Adetoso Justus, and Stefano Brizzolara. "Dynamic Response of a Wave Energy Converter With Resonant U-Tank." In ASME 2020 39th International Conference on Ocean, Offshore and Arctic Engineering. American Society of Mechanical Engineers, 2020. http://dx.doi.org/10.1115/omae2020-18553.

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Abstract This paper describes the concept design and preliminary dynamic analysis of a pitching wave energy converter (WEC) device, based on a pitching resonant floater, a pitch resonance tuning tank system and Wells turbines in regular head waves. The device has a bow/stern symmetry, which gives an advantage of the U-tank been strongly coupled with the floater in the pitch degree of freedom and both chambers will have their separate pneumatic turbines. The integrated dynamic model coupling the U-tank system as given with the motion of the floating body in regular waves and the power take off

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Reports on the topic "Resonance and Steric Effects"

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Jacobs, Dennis C. Energetic and Steric Effects in Ion/Surface Reactive Scattering. Defense Technical Information Center, 1998. http://dx.doi.org/10.21236/ada341374.

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Lynn, J. E. Resonance effects in neutron scattering lengths. Office of Scientific and Technical Information (OSTI), 1989. http://dx.doi.org/10.2172/5691315.

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Sofield, Chadwick Dean. Steric and electronic effects of 1,3-disubstituted cyclopentadienyl ligands on metallocene derivatives of Cerium, Titanium, Manganese, and Iron. Office of Scientific and Technical Information (OSTI), 2000. http://dx.doi.org/10.2172/764394.

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Zweiback, J. S. Direct observation of resonance effects in laser cluster interactions. Office of Scientific and Technical Information (OSTI), 1999. http://dx.doi.org/10.2172/11313.

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Pack, R., B. Kendrick, J. Kress, et al. Quantum resonance effects in exchange, photodissociation, and recombination reactions. Office of Scientific and Technical Information (OSTI), 1996. http://dx.doi.org/10.2172/212473.

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Satogata, Todd Jeffrey. Nonlinear Resonance Islands and Modulational Effects in a Proton Synchrotron. Office of Scientific and Technical Information (OSTI), 1993. http://dx.doi.org/10.2172/1372845.

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Yabana, K., and G. F. Bertsch. Ionic core effects on the Mie resonance in lithium clusters. Office of Scientific and Technical Information (OSTI), 1994. http://dx.doi.org/10.2172/10166478.

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Urban, Jeffry Todd. Nuclear magnetic resonance studies of quadrupolar nuclei and dipolar field effects. Office of Scientific and Technical Information (OSTI), 2004. http://dx.doi.org/10.2172/836811.

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Demgen, John Gibney. Nuclear Effects in Quasi-Elastic and Delta Resonance Production at Low Momentum Transfer. Office of Scientific and Technical Information (OSTI), 2015. http://dx.doi.org/10.2172/1221359.

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Kramer, G. J., R. Nazikian, and E. Valeo. Effects of Finite Density Fluctuations and of the Upper Hybrid Resonance on O-X Correlation Reflectometry. Office of Scientific and Technical Information (OSTI), 2001. http://dx.doi.org/10.2172/775581.

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