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Journal articles on the topic 'Ruthenium nitrosyle complexe'

Author: Grafiati

Published: 4 June 2021

Last updated: 17 February 2022

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1

Ford, Peter C. "Photochemical reactions of metal nitrosyl complexes. Mechanisms of NO reactions with biologically relevant metal centers." International Journal of Photoenergy 3, no. 3 (2001): 161–69. http://dx.doi.org/10.1155/s1110662x01000204.

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The discoveries that nitric oxide (a.k.a. nitrogen monoxide) serves important roles in mammalian bioregulation and immunology have stimulated intense interest in the chemistry and biochemistry of NO and derivatives such as metal nitrosyl complexes. Also of interest are strategies to deliver NO to biological targets on demand. One such strategy would be to employ a precursor which displays relatively low thermal reactivity but is photochemically active to release NO. This proposition led us to investigate laser flash and continuous photolysis kinetics of nitrosyl complexes such as the Roussin's

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2

Ashok, R. F. N., M. Gupta, K. S. Arulsamy та U. C. Agarwala. "Cyclopentadienyl ruthenium complexes. Part III. Reactivity of some η5-cyclopentadienylbis(triphenylphosphine)ruthenium(II) complexes with nitrosyl tribromide and dinitrogen trioxide". Canadian Journal of Chemistry 63, № 4 (1985): 963–70. http://dx.doi.org/10.1139/v85-160.

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Mixed ruthenium(II) nitrosyls have been synthesized in yields larger than 60% by a general reaction of [Ru(η5-C5H5)(PPh3)L]+X− (L = 2,2′-bipyridine or 1,10-phenanthroline, X = Cl or Br) or [Ru(η5-C5,H5)(PPh3)(L)X] (L = PPh3, pyridine, 3-picoline, 4-picoline, [Formula: see text], or [Formula: see text]; X− = Cl−, Br−, I−, CN−, NCS−, H−, or SnCl3−) with NOBr3 and N2O3. In these complexes NO seems to bind with the metal ion as NO+. The reactions of N2O3 gave either nitrito or nitrosyl dinitrito complexes. The reactions of NOBr3 with trichlorostannate complexes did not yield nitrosyl complexes, in

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3

Metzker, Gustavo, Inara de Aguiar, Maykon Lima Souza, Daniel Rodrigues Cardoso, and Douglas Wagner Franco. "Reaction of ruthenium(II) complexes with 2,2-diphenyl-1-picrylhydrazyl (DPPH•) and hydroxyl radicals." Canadian Journal of Chemistry 92, no. 8 (2014): 788–93. http://dx.doi.org/10.1139/cjc-2014-0082.

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The reaction of the complexes trans-[RuII(NO+)(NH3)4L] and [RuII(NO+)HEDTA] with 2,2-diphenyl-1-picrylhydrazyl (DPPH•) and hydroxyl (OH•) radicals has been investigated at 25.0 ± 0.1 °C using spectroscopic (UV-vis and electron paramagnetic resonance) and electrochemical techniques (differential pulse voltammetry and cyclic voltammetry). The redox potential of RuIII/RuII for the ruthenium nitrosyl complexes was determined and is in the range of +2.2 V (L = HEDTA) to +2.6 V (L = isn) versus the normal hydrogen electrode . The trans-[RuII(NO+)(NH3)4L]3+ and [RuII(NO+)HEDTA] complexes do not react

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4

Mir, Jan Mohammad, Bashir Ahmad Malik, and Ram Charitra Maurya. "Nitric oxide-releasing molecules at the interface of inorganic chemistry and biology: a concise overview." Reviews in Inorganic Chemistry 39, no. 2 (2019): 91–112. http://dx.doi.org/10.1515/revic-2018-0017.

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AbstractThe useful aspects of nitric oxide (NO) are nowadays widely known. Due to the need for this molecule in the maintenance of homeostasis, NO-releasing compounds are tested every year to optimize its levels in a patient suffering from low NO production. This manuscript is an update of some important historical concerns about nitrosyl complexes having the ability to act as NO-releasing compounds under the influence of different chemically modified environments. At present, the search for efficient and less harmful NO-releasing molecules at desirable targets and concentrations has gained co

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5

Su, Xianlong, Rongqing Zeng, Xianghong Li, Weijie Dang, Kaiyue Yao, and Dingguo Tang. "Cycloruthenated complexes: pH-dependent reversible cyclometallation and reactions with nitrite at octahedral ruthenium centers." Dalton Transactions 45, no. 17 (2016): 7450–59. http://dx.doi.org/10.1039/c6dt00576d.

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6

Barth, Michael, Xaver Kästele, and Peter Klüfers. "Nitrosyl Ruthenium Diolato Complexes." European Journal of Inorganic Chemistry 2005, no. 7 (2005): 1353–59. http://dx.doi.org/10.1002/ejic.200300925.

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7

Amabilino, Silvia, Marine Tasse, Pascal G. Lacroix, et al. "Photorelease of nitric oxide (NO) on ruthenium nitrosyl complexes with phenyl substituted terpyridines." New Journal of Chemistry 41, no. 15 (2017): 7371–83. http://dx.doi.org/10.1039/c7nj00866j.

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8

Krishnan, V. Mahesh, Hadi D. Arman, and Zachary J. Tonzetich. "Synthesis and characterisation of ruthenium–nitrosyl complexes in oxygen-rich ligand environments." Dalton Transactions 46, no. 4 (2017): 1186–93. http://dx.doi.org/10.1039/c6dt04717c.

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9

Ng, Ho-Yuen, Wai-Man Cheung, Enrique Kwan Huang, et al. "Ruthenium chalcogenonitrosyl and bridged nitrido complexes containing chelating sulfur and oxygen ligands." Dalton Transactions 44, no. 42 (2015): 18459–68. http://dx.doi.org/10.1039/c5dt02513c.

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10

Liu, Yingying, Siu-Mui Ng, Shek-Man Yiu, and Tai-Chu Lau. "Catalytic water oxidation by an in situ generated ruthenium nitrosyl complex bearing a bipyridine-bis(alkoxide) ligand." Dalton Transactions 50, no. 35 (2021): 12316–23. http://dx.doi.org/10.1039/d1dt01918j.

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A ruthenium(iii) water oxidation catalyst bearing a bipyridine-bis(alkoxide) ligand is readily converted by (NH4)2[Ce(NO3)6] to a ruthenium(ii) nitrosyl complex which is also an active water oxidation catalyst.

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11

Roose, Max, Marine Tassé, Pascal G. Lacroix, and Isabelle Malfant. "Nitric oxide (NO) photo-release in a series of ruthenium–nitrosyl complexes: new experimental insights in the search for a comprehensive mechanism." New Journal of Chemistry 43, no. 2 (2019): 755–67. http://dx.doi.org/10.1039/c8nj03907k.

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12

de Lima Batista, Ana P., Antonio G. S. de Oliveira-Filho, and Sérgio E. Galembeck. "Photophysical properties and the NO photorelease mechanism of a ruthenium nitrosyl model complex investigated using the CASSCF-in-DFT embedding approach." Physical Chemistry Chemical Physics 19, no. 21 (2017): 13860–67. http://dx.doi.org/10.1039/c7cp01642e.

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13

Kumar, Rajan, Sushil Kumar, Manju Bala, Anand Ratnam, U. P. Singh, and Kaushik Ghosh. "Site-specific orthometallation via C–H bond activation and syntheses of ruthenium(iii) organometallics: studies on nitric oxide (NO) reactivity and photorelease of coordinated NO." RSC Advances 6, no. 76 (2016): 72096–106. http://dx.doi.org/10.1039/c6ra17223g.

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σ-Aryl ruthenium(iii) complexes were synthesized by C–H bond activation and organometallic nitrosyl complexes were synthesized and characterized by spectroscopy and crystal structure. Coordinated NO molecule was found to be photolabile.

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14

Batista, Alzir A., Salete L. Queiroz, Peter C. Healy, et al. "A novel coordination mode for a pyridylphosphine ligand. X-ray structures of [RuCl2(NO)L] (I) and [RuCl2(NO)L]·DMSO (II) (L = [(2-py)2PC2H4POO(2-py)2]-)." Canadian Journal of Chemistry 79, no. 5-6 (2001): 1030–35. http://dx.doi.org/10.1139/v01-038.

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The ruthenium(II) complex, [RuCl2(NO)L] (I), (L = [(2-py)2PC2H4PO2(2-py)]-) was obtained from recrystallization of RuCl3NO(d2pype) (d2pype = (2-py)2PC2H4P(2-py)2) in the presence of HNO3, crystallizing in the monoclinic space group P21 (no. 4), with a = 8.012(4) Å, b = 14.454(4) Å, c = 9.353(3) Å, β = 105.77(3)°, and Z = 2. Crystals of the DMSO solvate of the complex (II) were obtained from (CD3)2SO solution, crystallizing in the monoclinic space group P21/c (no.14) with a = 9.7080(2) Å, b = 22.2920(5) Å, c = 11.5230(3) Å, β = 92.0450(10)°, and Z = 4. In both complexes, the geometry about the

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15

Mikhailov, Artem A., Darya V. Khantakova, Vladislav A. Nichiporenko та ін. "Photoinduced inhibition of DNA repair enzymes and the possible mechanism of photochemical transformations of the ruthenium nitrosyl complex [RuNO(β-Pic)2(NO2)2OH]". Metallomics 11, № 12 (2019): 1999–2009. http://dx.doi.org/10.1039/c9mt00153k.

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16

Vorobyev, Vasily, Artem A. Mikhailov, Vladislav Yu Komarov, Alexander N. Makhinya, and Gennadiy A. Kostin. "Tuning the structure and photoinduced linkage isomerism of tetrapyridine nitrosyl ruthenium(ii) complexes by changing the trans-to-NO coordinated ligand." New Journal of Chemistry 44, no. 12 (2020): 4762–71. http://dx.doi.org/10.1039/c9nj05862a.

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Ruthenium nitrosyl complexes were prepared with various trans-to-NO ligands. These compounds form Ru–ON metastable states upon blue-light excitation and the corresponding thermal stabilities were determined.

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17

Giri, Bishnubasu, Taruna Saini, Sadananda Kumbhakar, et al. "Near-IR light-induced photorelease of nitric oxide (NO) on ruthenium nitrosyl complexes: formation, reactivity, and biological effects." Dalton Transactions 49, no. 31 (2020): 10772–85. http://dx.doi.org/10.1039/d0dt01788d.

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Two new polypyridyl backboned ruthenium nitrosyl complexes have been synthesized which shows efficient NO photorelease and exhibits significant phototoxicity upon irradiation with the visible light in the VCaP prostate cancer cell line.

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18

Freitag, Leon, Stefan Knecht, Sebastian F. Keller, et al. "Correction: Orbital entanglement and CASSCF analysis of the Ru–NO bond in a Ruthenium nitrosyl complex." Physical Chemistry Chemical Physics 17, no. 20 (2015): 13769. http://dx.doi.org/10.1039/c5cp90073e.

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19

Tfouni, Elia, Daniela Ramos Truzzi, Aline Tavares, Anderson Jesus Gomes, Leonardo Elias Figueiredo, and Douglas Wagner Franco. "Biological activity of ruthenium nitrosyl complexes." Nitric Oxide 26, no. 1 (2012): 38–53. http://dx.doi.org/10.1016/j.niox.2011.11.005.

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20

Hadadzadeh, Hassan, Maria C. DeRosa, Glenn P. A. Yap, Ali R. Rezvani, and Robert J. Crutchley. "Cyclometalated Ruthenium Chloro and Nitrosyl Complexes." Inorganic Chemistry 41, no. 24 (2002): 6521–26. http://dx.doi.org/10.1021/ic020451f.

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21

Pandey, Krishna K., Dileep T. Nehete, and Morteza Massoudipour. "Disulphidothionitrate nitrosyl complexes of ruthenium(II)." Inorganica Chimica Acta 129, no. 2 (1987): 253–56. http://dx.doi.org/10.1016/s0020-1693(00)86670-0.

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22

Sasaki, Isabelle, Silvia Amabilino, Sonia Mallet-Ladeira, et al. "Further studies on the photoreactivities of ruthenium–nitrosyl complexes with terpyridyl ligands." New Journal of Chemistry 43, no. 28 (2019): 11241–50. http://dx.doi.org/10.1039/c9nj02398d.

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23

Osti, Renata Z., Fabiana A. Serrano, Thaysa Paschoalin, et al. "The In Vitro and In Vivo Antitumour Activities of Nitrosyl Ruthenium Amine Complexes." Australian Journal of Chemistry 65, no. 9 (2012): 1333. http://dx.doi.org/10.1071/ch12245.

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Ruthenium compounds of the type trans-[Ru(NO)(NH3)4(L)]X3, L = N-heterocyclic ligands, P(OEt)3, SO32–, X = BF4– or PF6–, or [Ru(NO)Hedta], were tested for antitumour activity in vitro against murine melanoma and human tumour cells. The ruthenium complexes induced DNA fragmentation and morphological alterations suggestive of necrotic tumour cell death. The calculated IC50 values were lower than 100 μM. Complexes for which L = isn or imN were partially effective in vivo in a syngeneic model of murine melanoma B16F10, increasing animal survival. In addition, the same ruthenium complexes effective

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24

Talotta, Francesco, Leticia González, and Martial Boggio-Pasqua. "CASPT2 Potential Energy Curves for NO Dissociation in a Ruthenium Nitrosyl Complex." Molecules 25, no. 11 (2020): 2613. http://dx.doi.org/10.3390/molecules25112613.

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Ruthenium nitrosyl complexes are fascinating photoactive compounds showing complex photoreactivity, such as N→O linkage photoisomerism and NO photorelease. This dual photochemical behavior has been the subject of many experimental studies in order to optimize these systems for applications as photoswitches or therapeutic agents for NO delivery. However, despite recent experimental and computational studies along this line, the underlying photochemical mechanisms still need to be elucidated for a more efficient design of these systems. Here, we present a theoretical contribution based on the ca

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25

Whillock, Guy O. H., Kim A. Summers, and Angela Jackson. "The Effect of Ruthenium on the Corrosion of Stainless Steel in Nitric Acid Liquors." CORROSION 76, no. 1 (2020): 93–102. http://dx.doi.org/10.5006/3402.

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Nuclear reprocessing plant liquors resulting from the PUREX process contain ruthenium present as a mixture of nitrosyl complexes in nitric acid. Ruthenium is not corrosive toward stainless steels unless the conditions are sufficiently oxidizing to promote the decomposition of one or more of the nitrosyl complexes present, in which case the production of finely-divided RuO2 occurs. In this work, the corrosive effect of RuO2 coatings that were produced by the thermal decomposition of RuCl3 is reported. The corrosion potential and corrosion rate of stainless steel were found to be significantly i

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26

Giri, Bishnubasu, Sadananda Kumbhakar, Kalai Selvan K, Arabinda Muley, and Somnath Maji. "Ruthenium nitrosyl complexes with the molecular framework [RuII(dmdptz)(bpy)(NO)]n+ (dmdptz: N,N-dimethyl-4,6-di(pyridin-2-yl)-1,3,5-triazin-2-amine and bpy: 2,2′-bipyridine). Electronic structure, reactivity aspects, photorelease, and scavenging of NO." New Journal of Chemistry 44, no. 43 (2020): 18732–44. http://dx.doi.org/10.1039/d0nj03923c.

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Two ruthenium nitrosyl complexes have been stabilized both in {Ru–NO}<sup>6</sup> and {Ru–NO}<sup>7</sup> configurations which show facile photocleavage of Ru–NO bond on exposure to visible light. The photo liberated NO is captured by reduced myoglobin.

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27

Bastos, Tanira M., Marília I. F. Barbosa, Monize M. da Silva, et al. "Nitro/Nitrosyl-Ruthenium Complexes Are Potent and Selective Anti-Trypanosoma cruzi Agents Causing Autophagy and Necrotic Parasite Death." Antimicrobial Agents and Chemotherapy 58, no. 10 (2014): 6044–55. http://dx.doi.org/10.1128/aac.02765-14.

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ABSTRACTcis-[RuCl(NO2)(dppb)(5,5′-mebipy)] (complex 1),cis-[Ru(NO2)2(dppb)(5,5′-mebipy)] (complex 2),ct-[RuCl(NO)(dppb)(5,5′-mebipy)](PF6)2(complex 3), andcc-[RuCl(NO)(dppb)(5,5′-mebipy)](PF6)2(complex 4), where 5,5′-mebipy is 5,5′-dimethyl-2,2′-bipyridine and dppb is 1,4-bis(diphenylphosphino)butane, were synthesized and characterized. The structure of complex 2 was determined by X-ray crystallography. These complexes exhibited a higher anti-Trypanosoma cruziactivity than benznidazole, the current antiparasitic drug. Complex 3 was the most potent, displaying a 50% effective concentration (EC5

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28

Ballester-Reventos, Loreto, Angel Gutierrez-Alonso, and Maria Felisa Perpiñan-Vielba. "Formation of heterobimetallic ruthenium-mercury nitrosyl complexes." Polyhedron 10, no. 10 (1991): 1013–17. http://dx.doi.org/10.1016/s0277-5387(00)81363-7.

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29

Metzker, Gustavo, Daniel Rodrigues Cardoso, and Douglas Wagner Franco. "Reaction of ruthenium nitrosyl complexes with superoxide." Polyhedron 50, no. 1 (2013): 328–32. http://dx.doi.org/10.1016/j.poly.2012.11.021.

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30

Pandey, Krishna K., and Ku Hemlata Garg. "Organometallic thionitrosyl and nitrosyl complexes of ruthenium." Polyhedron 14, no. 13-14 (1995): 1987–91. http://dx.doi.org/10.1016/0277-5387(94)00454-m.

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31

Borges, Simone da S. S., Celso U. Davanzo, Eduardo E. Castellano, Julio Z-Schpector, Sebastião C. Silva, and Douglas W. Franco. "Ruthenium Nitrosyl Complexes with N-Heterocyclic Ligands." Inorganic Chemistry 37, no. 11 (1998): 2670–77. http://dx.doi.org/10.1021/ic951563s.

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32

Lopes, Luiz G. F., Maria G. Gomes, Simone S. S. Borges, and Douglas W. Franco. "Correlation Between the Lever Parameter and Electronic Properties of Nitrosyl Ruthenium(II) Complexes." Australian Journal of Chemistry 51, no. 9 (1998): 865. http://dx.doi.org/10.1071/c97216.

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The Lever parameter (EL), for a series of ruthenium nitrosyl complexes of the type [Ru(NH3)4NOL] n+, where ligand L = nicotinamide (nic), isonicotinamide (isn), pyrazine (pz), pyridine (py), imidazole (imN), L-histidine (L-hist), NH3, trimethyl phosphite [P(OMe)3] and triethyl phosphite [P(OEt)3], is correlated to Epc1 (the potential for the reduction RuNO++e- → RuNO 0) and v(NO) data. A correlation is observed between ∑EL and Epc1, and between ∑EL and v(NO), since these parameters are dependent on electronic characteristics of the nitrosyl group. For ∑EL v. Epc1, the slope, SL, and intercept,

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33

Bukhanko, Valerii, Isabelle Malfant, Zoia Voitenko, and Pascal Lacroix. "Isoindole and isomeric heterocyclic donating substituents in ruthenium(II)nitrosyl complexes with large first hyperpolarizabilities and potential two-photon absorption capabilities: a computational approach." French-Ukrainian Journal of Chemistry 5, no. 1 (2017): 8–23. http://dx.doi.org/10.17721/fujcv5i1p8-23.

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A set of 22 ruthenium nitrosyl complexes of general formula [RuII(L)Cl2(NO)]+ is investigated computationally by the density functional theory. L is a terpyridine ligand substituted by different R isomers of formula C12H8N, either indole, isoindole, or carbazole, proposed as alternative donors to the electron-rich fluorene substituent. The computed resulting nonlinear optical (NLO) properties are found to strongly depend on the isomer. While the ruthenium complexes exhibit modest efficiencies at the second-order (two-photon absorption) level, some of the R isomers lead to complexes of enhanced

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34

Mikhailov, Artem A., Emmanuel Wenger, Gennadiy A. Kostin, and Dominik Schaniel. "Room‐Temperature Photogeneration of Nitrosyl Linkage Isomers in Ruthenium Nitrosyl Complexes." Chemistry – A European Journal 25, no. 31 (2019): 7569–74. http://dx.doi.org/10.1002/chem.201901205.

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35

Cheung, Wai-Man, Qian-Feng Zhang, Chui-Ying Lai, Ian D. Williams, and Wa-Hung Leung. "Ruthenium and rhodium nitrosyl complexes containing dichalcogenoimidodiphosphinate ligands." Polyhedron 26, no. 16 (2007): 4631–37. http://dx.doi.org/10.1016/j.poly.2007.04.002.

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36

Melo Pereira, José Clayston, Vanessa Carregaro, Diego Luís Costa, João Santana da Silva, Fernando Q. Cunha, and Douglas Wagner Franco. "Antileishmanial activity of ruthenium(II)tetraammine nitrosyl complexes☆." European Journal of Medicinal Chemistry 45, no. 9 (2010): 4180–87. http://dx.doi.org/10.1016/j.ejmech.2010.06.010.

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37

Barbosa, Guilherme A., Juliana P. da Silva, Patrícia Appelt, Otávio Fuganti, Fábio S. Murakami, and Márcio P. de Araujo. "Antibacterial activity of DPEphos-containing ruthenium-nitrosyl complexes." Inorganic Chemistry Communications 90 (April 2018): 108–11. http://dx.doi.org/10.1016/j.inoche.2018.02.012.

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38

Ashok, R. F. N., M. Gupta, K. S. Arulsamy та U. C. Agarawala. "Cyclopentadienyl ruthenium complexes. Part II. Reactivity of some η5-cyclopentadienylbis(triphenylphosphine)ruthenium(II) complexes with nitrosyl chloride and nitrosyl bromide". Inorganica Chimica Acta 98, № 3 (1985): 169–79. http://dx.doi.org/10.1016/s0020-1693(00)87600-8.

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39

Zarhloul, Redouane, Ren� Faure, and Jean Pierre Deloume. "Structural study of bonding in halogeno ruthenium complexes: Application to ruthenium nitrosyls." Journal of Crystallographic and Spectroscopic Research 22, no. 5 (1992): 601–6. http://dx.doi.org/10.1007/bf01161346.

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40

Scoles, Ludmila, Brian T. Sterenberg, Konstantin A. Udachin, and Arthur J. Carty. "The synthesis and reactivity of a mixed nitrosylphosphinidene cluster of ruthenium: Formation of nitride and nitrene clusters." Canadian Journal of Chemistry 80, no. 11 (2002): 1538–45. http://dx.doi.org/10.1139/v02-100.

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Reaction of the aminophosphinidene complex [Ru5(CO)15(µ4-PN-i-Pr2)] (1) with [PPN][NO2] (PPN = Ph3P=N=PPh3) led to the mixed nitrosyl phosphinidene cluster complex [PPN][Ru5(CO)13(µ2-NO)(µ4-PN-i-Pr2)] (2). Reaction of 2 with HBF4·Et2O led to a mixture of the nitridophosphido cluster [Ru5(CO)13(µ5-N){µ2-P(F)N-i-Pr2}] (3) and the nitrenephosphinidene cluster [Ru5(CO)10(µ-CO)2(µ3-CO)(µ4-NH)(µ3-PN-i-Pr2)] (4). If the BF4 counterion is avoided through use of trifluoromethanesulfonic acid, 4 is the only isolated product. Reaction of 2 with methyltrifluoromethanesulfonate leads to the nitridoph

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41

Sizova, O. V., N. V. Ivanova, V. V. Sizov, and A. B. Nikol'skii. "Electronic Spectra of Ruthenium Nitrosyl Complexes with Macrocyclic Ligands." Russian Journal of General Chemistry 74, no. 4 (2004): 481–85. http://dx.doi.org/10.1023/b:rugc.0000031843.26412.10.

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42

Orenha, Renato Pereira, Nelson Henrique Morgon, Graziele Cappato Guerra Silva, Giovanni Finoto Caramori та Renato Luis Tame Parreira. "The π-donor/acceptor trans effect on NO release in ruthenium nitrosyl complexes: a computational insight". New Journal of Chemistry 45, № 20 (2021): 8949–57. http://dx.doi.org/10.1039/d1nj00939g.

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43

Freitag, Leon, Stefan Knecht, Sebastian F. Keller, et al. "Orbital entanglement and CASSCF analysis of the Ru–NO bond in a Ruthenium nitrosyl complex." Physical Chemistry Chemical Physics 17, no. 22 (2015): 14383–92. http://dx.doi.org/10.1039/c4cp05278a.

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44

Sellmann, Dieter, Michael Geck, and Matthias Moll. "Übergangsmetallkomplexe mit Schwefelliganden, LXXXI [Ru(NO)('S5')]Br, ein reaktiver Ruthenium-Schwefelligand- Nitrosyl-Komplex: Synthese und Reaktionen mit Azid und Amid/Transition Metal Complexes with Sulfur Ligands, LXXXI [Ru(NO)('S5')]Br, a Reactive Ruthenium Sulfur Ligand Nitrosyl Complex: Synthesis and Reactions with Azide and Amide." Zeitschrift für Naturforschung B 47, no. 1 (1992): 74–78. http://dx.doi.org/10.1515/znb-1992-0115.

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In order to investigate the potential conversion of coordinated NO into N2 ligands at Ru sulfur centers, the cationic Ru nitrosyl complex meso-[Ru(NO)('S5')]Br (1)** was synthesized by template alkylation of [NBu4][Ru(NO)('S2')2]** with (BrC2H4)2S. 1 is reactive towards nucleophiles. Reaction with azide yields N2O, N2 and [Ru('S5')]2 (2), reaction with LiNH2, NH3 and NEt3 leads to C-S bond cleavage in the 'S5' ligand of 1 and to the formation of a Ru nitrosyl vinylthioetherthiolate complex.

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45

Kumar, Amit, Rampal Pandey, Rakesh Kumar Gupta, Kaushik Ghosh, and Daya Shankar Pandey. "Synthesis, characterization and photochemical properties of some ruthenium nitrosyl complexes." Polyhedron 52 (March 2013): 837–43. http://dx.doi.org/10.1016/j.poly.2012.07.032.

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46

Caramori, Giovanni F., Alexandre O. Ortolan, Renato L. T. Parreira, and Eder H. da Silva. "Ruthenium nitrosyl complexes containing pyridine-functionalized carbenes – A theoretical insight." Journal of Organometallic Chemistry 799-800 (December 2015): 54–60. http://dx.doi.org/10.1016/j.jorganchem.2015.08.018.

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47

Chan, Ka-Wang, Wai-Ming Ng, Wai-Man Cheung, et al. "Di- and tri-nuclear ruthenium nitrosyl complexes containing thiolate ligands." Journal of Organometallic Chemistry 812 (June 2016): 151–57. http://dx.doi.org/10.1016/j.jorganchem.2016.02.004.

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48

Sizova, O. V., N. V. Ivanova, O. O. Lyubimova, and V. V. Sizov. "Electronic structure and spectra of binuclear bridged nitrosyl ruthenium complexes." Russian Journal of Coordination Chemistry 33, no. 7 (2007): 523–29. http://dx.doi.org/10.1134/s1070328407070081.

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49

Miranda, Katrina M., Xianhui Bu, Ivan Lorković, and Peter C. Ford. "Synthesis and Structural Characterization of Several Ruthenium Porphyrin Nitrosyl Complexes." Inorganic Chemistry 36, no. 21 (1997): 4838–48. http://dx.doi.org/10.1021/ic970065b.

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50

McQuarters, Ashley B., and Nicolai Lehnert. "{RuNO}6vs. co-ligand oxidation: two non-innocent groups in one ruthenium nitrosyl complex." Dalton Trans. 43, no. 37 (2014): 13835–38. http://dx.doi.org/10.1039/c4dt01388c.

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Abstract:

The one-electron oxidation of the {RuNO}<sup>6</sup> complex [Ru(L)(PPh<sub>3</sub>)(NO)(Cl)]<sup>2+</sup> (where L = 1-phenyl-1-(pyridin-2-yl)-2-(pyridin-2-ylmethylene)hydrazine) leads to the generation of a co-ligand radical. This complex therefore represents a rare example of a ruthenium complex with two different non-innocent ligands bound.

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