Academic literature on the topic 'Schiff Base Chelates'

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Journal articles on the topic "Schiff Base Chelates"

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Varshney, Anshita, and A. P. Mishra. "Novel Ni(II) and Zn(II) Schiff base metal chelates as promising DNA binder, Antioxidant and Antifungal agents." Mediterranean Journal of Chemistry 14, no. 2 (2024): 94. http://dx.doi.org/10.13171/mjc02405211777varshney.

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<p>Schiff base ligands and their 3d-metal chelates have gained significant attention due to various applications in various scientific platforms. Due to their chelating propensity, they possess a wide range of biological, biochemical, catalytic, clinical, dying, and pharmacological properties.<strong> </strong>Here, in present studies,<strong> </strong>two novel Ni(II) and Zn(II) transition metal chelates have been synthesized by condensing their metal salts with Schiff base ligand 4-chloro-2-(2,5-dimethoxybenzylideneamino)-5-nitrophenol<strong> </strong&
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Okada, Chiaki, Noriyuki Hatae, and Eiko Toyota. "Structural study of the Schiff base copper(II) chelates as thrombin inhibitor." Acta Crystallographica Section A Foundations and Advances 70, a1 (2014): C1665. http://dx.doi.org/10.1107/s205327331408334x.

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Thrombin is a trypsin-like serine protease that plays a critical role in the blood coagulation cascade. Thus, studies on thrombin-specific inhibitor are useful for the design of clinical useful compounds. We have previously reported of the Schiff base metal chelates carrying benzamidine and amino acid moieties. More than 50 kinds of Schiff base copper(II) chelates were synthesized fromp- orm-amidinosalicylaldehyde and various L- or D-amino acids. These chelates have effective inhibitory activity for trypsin and thrombin (Ki= 10-5~ 10-6M). In this series of inhibitors, the copper(II) chelate de
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El-ajaily, M. M., H. A. Abdullah, Ahmed Al-janga, E. E. Saad, and A. A. Maihub. "Zr(IV), La(III), and Ce(IV) Chelates with 2-[(4-[(Z)-1-(2-Hydroxyphenyl)ethylidene]aminobutyl)-ethanimidoyl]phenol: Synthesis, Spectroscopic Characterization, and Antimicrobial Studies." Advances in Chemistry 2015 (February 1, 2015): 1–15. http://dx.doi.org/10.1155/2015/987420.

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La(III), Zr(IV), and Ce(IV) chelates of 2-[(4-[(Z)-1-(2-hydroxyphenyl)ethylidene]aminobutyl)-ethanimidoyl]phenol were synthesized and characterized by using several physical techniques. The Schiff base was obtained by refluxing of o-hydroxyacetophenone with 1,4-butanediamine in 2 : 1 molar ratio. The CHN elemental analysis results showed the formation of the Schiff base and the chelates has been found to be in 1 : 1 [M : L] ratio. The molar conductance measurements revealed that all the chelates are nonelectrolytes. Structural elucidations of the ligand and its chelates were based on compatibl
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O. Sobola, A., G. M. Watkins, R. O. Shaibu, S. Adewuyi, and S. A. Amolegbe. "Synthesis, characterization and antimicrobial activity of copper(II) Schiff base adducts of some p-substituted aniline Schiff bases." Bulletin of the Chemical Society of Ethiopia 35, no. 1 (2021): 33–42. http://dx.doi.org/10.4314/bcse.v35i1.3.

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The synthesis, characterization and antimicrobial activity of Cu(II) complexes of some p-substituted aniline Schiff base ligands have been carried out. The Schiff bases were obtained from salicylaldehyde and o-vanillin. The Cu(II) complexes have been characterized by elemental analysis, conductivity measurement, infrared and electronic spectral data. The complexes were obtained either as metal chelates [Cu(L)2] or Schiff base adducts (CuCl2.2LH).xH2O. The metal chelates were non-electrolytes while the Schiff base adducts exhibited 1:1 or 2:1 electrolytes in methanol. The Cu(II) complexes exhib
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Hamil, Abdusalam, Marei El-ajaily, Lila Basher, Asma ramli, Miloud Miloud, and S. A. Saad. "Synthesis, Characterization and Antimicrobial evaluation of some mixed ligand chelates using 2-aminobenzoic acid as a secondary ligand." Libyan Journal of Medical Research 18, no. 1 (2024): 18–27. http://dx.doi.org/10.54361/10.26719/ljm18-1.02.

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The present work deals with the preparation of four mixed ligand chelates that resulted from the reaction of Schiff base[coupling of 2-hydroxyacetophenone and 2,4-dinitrophenylhydrazine (HL1) and 2-aminobenzoic acid (L2)]. The Schiff base, 2-aminobenzoic acid and their mixed ligand chelates were offered to several physicochemical tools; CHN elemental analyses, molar conductivity, magnetic moments, thermogravimetric analysis, IR and 1HNMR, Basis on the obtained results, the mixed ligand chelates appeared in the 1:1:1 [M:L1:L2] ratio as found from the elemental analysis data and found to have th
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Veeravel C, Rajasekar K, Balasubramanian S, and Selvarani R. "Green Route Synthesis of Bio-active Cd(II) and Hg(II) Complexes With ‘N’ Donor Novel Schiff base and Oxalate ion." International Journal of Research in Pharmaceutical Sciences 12, no. 2 (2021): 1689–94. http://dx.doi.org/10.26452/ijrps.v12i2.4768.

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Green route synthesis of bio-active diamagnetic Cd(II) and Hg(II) complexes with Schiff base and oxalate ion were synthesized using water as a solvent and characterized by using electronic spectra (UV-visible), Fourier transforms infrared (FT-IR), 1H and 13C-NMR spectroscopy, mass spectra and physical characterization such as CHN analysis, metal estimation and molar conductivity. 1H- and 13C-NMR spectra of ligand complex compared with Schiff base. The complexes have the general formula of ML2X (M= Cd(II) & Hg(II), L-C15H13N, X-C2O4 ) confirmed based on the results of elemental analysis, me
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Cai, Wen-Xuan, Qi-Wei Zhang, Hong Su та Yun-Long Feng. "catena-Poly[[bis(μ-3-dimethylamino-N-salicylidenepropylamine)isothiocyanatodicadmium(II)]-μ-isothiocyanato]". Acta Crystallographica Section E Structure Reports Online 62, № 7 (2006): m1572—m1574. http://dx.doi.org/10.1107/s160053680602085x.

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The deprotonated 3-dimethylamino-N-salicylidenepropylamine Schiff base chelates to a Cd atom in the polymeric title compound with a dinuclear building block, [Cd2(NCS)2(C12H17N2O)2] n . The O atom of the Schiff base also engages in bridging. The bridging NCS group links adjacent dinuclear entities into a helical chain that runs along the b axis of the monoclinic unit cell.
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Mohamed, Amira A., Fatma M. Ahmed, Wael A. Zordok, Walaa H. El-Shwiniy, Sadeek A. Sadeek, and Hazem S. Elshafie. "Novel Enrofloxacin Schiff Base Metal Complexes: Synthesis, Spectroscopic Characterization, Computational Simulation and Antimicrobial Investigation against Some Food and Phyto-Pathogens." Inorganics 10, no. 11 (2022): 177. http://dx.doi.org/10.3390/inorganics10110177.

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Condensation of the reaction between enrofloxacin and ethylenediamine in the existence of glacial acetic acid produced a new N,N-ethylene (bis 1-cyclopropyl-7-(4-ethylpiperazin-1-yl)-6-fluoro-1,4-dihydroquinoline-3-carboxylic acid Schiff base (H2Erx-en). H2Erx-en was used as a tetra-dentate ligand to produce novel complexes by interacting with metal ions iron(III), yttrium(III), zirconium(IV), and lanthanum(III). The synthetic H2Erx-en and its chelates had been detected with elemental analysis, spectroscopic methods, mass spectrometry, thermal studies, conductometric and magnetic measurements
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Hamil, Abdusalam, Marei El-ajaily, Lila Basher, Asma Ramli, Miloud Miloud, and S. A. Saad. "Mixed ligand chelates using Schiff base and 2-aminobenzoic acid as ligands." Libyan Journal of Medical Research 18, no. 1 (2024): 1–17. http://dx.doi.org/10.54361/10.26719/llmr18-1.01.

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The ligands under investigation were used to form five mixed ligand chelates with some transition metal ions. The ligands and their chelates were offered to several analytical and spectroscopic tools. Based on the obtained results; an octahedral structure was proposed for all the chelates. Also, the antibacterial activity was tested on two types of bacteria; Staphylococcus aureus and E.coli species.
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Saha, Sanjoy, Dhiraj Brahman, and Biswajit Sinha. "Cu(II) complexes of an ionic liquid-based Schiff base [1-{2-(2-hydroxy benzylidene amino) ethyl}-3-methyl­imidazolium]Pf6: Synthesis, characterization and biological activities." Journal of the Serbian Chemical Society 80, no. 1 (2015): 35–43. http://dx.doi.org/10.2298/jsc140201078s.

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Two Cu(II) complexes of an ionic liquid based Schiff base 1-{2-(2-hydroxybenzylideneamino) ethyl}-3-methylimidazolium hexaflurophosphate, were prepared and characterized by different analytical and spectroscopic methods such as elemental analysis, magnetic susceptibility, UV-Vis, IR, NMR and mass spectroscopy. The Schiff base ligand was found to act as a potential bidentate chelating ligand with N, O donor sites and formed 1:2 metal chelates with Cu(II) salts. The synthesized Cu(II) complexes were tested for biological activity.
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Dissertations / Theses on the topic "Schiff Base Chelates"

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Morale, Francesca. "Metallomesogens derived from Schiff-base chelates and related co-ordination chemistry." Thesis, University of Nottingham, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.269486.

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Griffiths, Kieran. "Catalytic and topological aspects of Schiff base supported 3d-4f polynuclear coordination complexes." Thesis, University of Sussex, 2018. http://sro.sussex.ac.uk/id/eprint/75278/.

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The work presented in this thesis deals with the employment of Schiff base ligands used to synthesise novel 3d-4f polynuclear coordination clusters (PCCs) and the investigation into their potential magnetic, luminescent and catalytic properties. Chapter one provides a general introduction to the chemistry described in the thesis. It includes a general overview of 3d-4f PCC chemistry and the applications of these materials and previous synthetic strategies for the preparation of Schiff base PCCs. A rationale is presented for the ligands employed in the thesis and a synthetic strategy is devised
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Olalekan, Temitope Elizabeth. "Synthesis, characterisation and biological activity of 2-(methylthiomethyl)anilines, 2-(methylthio)anilines, their Schiff-base derivatives and metal(II) (Co, Ni, Cu) complexes." Thesis, Rhodes University, 2013. http://hdl.handle.net/10962/d1020868.

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A series of 31 sulfur-nitrogen donor ligands and 64 metal(II) complexes have been investigated. The thiomethylated aniline ligands 2–(methylthiomethyl)aniline 2MT and 2–(methylthio)aniline 2MA were synthesized with their substituted derivatives (-Me, -MeO, -Cl, -Br, -NO2) to serve as chelating agents. These ligands behave as bidentate ligands with SN donor group with Co(II), Ni(II) and Cu(II). The Co(II) and Ni(II) complexes have the ML2Cl2 molecular formula while the Cu(II) complexes formed with MLCl2 stoichiometry where L is the bidentate ligand. The ligands and their metal(II) complexes hav
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Potgieter, Kim Carey. "Complexes of the ReO³⁺/Re(CO)₃cores with multidentate N,O-Donor chelates." Thesis, Nelson Mandela Metropolitan University, 2009. http://hdl.handle.net/10948/1225.

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This study investigates the coordination modes of multidentate N,O-donor ligands toward the [ReVO]3+ and fac-[ReI(CO)3]+ cores. The reactions of trans-[ReOX3(PPh3)2] (X = Cl, Br) with 4-aminoantipyrine (H2pap) were studied, and the complexes cis-[ReX2(pap)(H2pap)(PPh3)](ReO4) were isolated. The X-ray crystal structures show that both complexes display a distorted octahedral geometry around the central rhenium atom, and are mirror images of each other. The ligand pap is coordinated monodentately through the doubly deprotonated amino nitrogen as an imide, and H2pap acts as a neutral bidentate ch
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Ländner, Alexander. "Komplexe achtfach koordinierter Lanthanoid(III, IV)-Tetrapyrrolverbindungen mit dem vierzähnigen 2N-2O-Schiff-Base-Chelat-Liganden N-Salicyliden-N'-(2-hydroxyethyl)ethylendiamin." [S.l. : s.n.], 2004. http://elib.tu-darmstadt.de/diss/000463.

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Salmond, Rosanne C. "Synthesis and characterisation of new Schiff base chelates of platinum group metals." Thesis, 2011. http://hdl.handle.net/10413/8403.

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The principal goal of this work was to synthesise and fully characterise a range of platinum group metal chelates of bis(pyridine-imine) ligands. These four-nitrogen donor Schiff base ligands are underdeveloped relative to their salen (ONNO donor) counterparts. The purified metal complexes were to be tested for their cytotoxicity against cancer cell lines and their mode of interaction (expected to be intercalation) studied. The syntheses, spectroscopic and structural properties of some novel and some already known bis(pyridine-imine) ligands are described. Furthermore, UV-Vis, IR and NMR spect
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Laendner, Alexander. "Komplexe achtfach koordinierter Lanthanoid(III,IV)-Tetrapyrrolverbindungen mit dem vierzähnigen 2N-2O-Schiff-Base-Chelat-Liganden N-Salicyliden-N’-(2-hydroxyethyl)ethylendiamin." Phd thesis, 2004. https://tuprints.ulb.tu-darmstadt.de/463/1/dissAL.PDF.

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In dieser Arbeit wurde erstmalig eine umfassende Synthesemethode zur Darstellung von Lanthanoid-Monoporphyrinaten und Lanthanoid-Monophthalo-cyaninaten vorgestellt. Durch Metallierung der Porphyrinsysteme [5,10,15,20-Tetraphenylporphyrin; 2,3,7,8,12,13,17,18-Octaethylporphyrin; 5,10,15,20-Tetrakis(pentafluorphenyl)porphyrin] mit Lanthanoid(III)-Acetaten als Metallspender und 1,2,4-Trichlorbenzol als Lösungsmittel bilden sich jeweils über OH- und Lösungsmittel-Molekuele verbrückte dimere Monoporphyrinate aus. Diese Aggregation zu dimeren Strukturen ist von der Konzentration der Porphyrinat-Lösu
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Ländner, Alexander [Verfasser]. "Komplexe achtfach koordinierter Lanthanoid(III,IV)-Tetrapyrrolverbindungen mit dem vierzähnigen 2N-2O-Schiff-Base-Chelat-Liganden N-Salicyliden-N'-(2-hydroxyethyl)ethylendiamin / vorgelegt von Alexander Ländner." 2004. http://d-nb.info/971845492/34.

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Book chapters on the topic "Schiff Base Chelates"

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of iron(II) chelate with Schiff base." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-54231-6_91.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of iron(II) chelate with Schiff base." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-54231-6_92.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of nickel(II) chelate with Schiff-base." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-54234-7_248.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of nickel(II) chelate with Schiff-base." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-54234-7_249.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of cobalt(II) chelate(1:1) with 3-methoxy-salicylidene-2-aminothiophenol Schiff-base." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-54231-6_583.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of cobalt(II) chelate(1:2) with 3-methoxy-salicylidene-2-aminothiophenol Schiff-base." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-54231-6_584.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of copper(II) chelate(1:1) with 3-methoxy-salicylidene-2-aminothiophenol Schiff-base." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-54237-8_299.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of copper(II) chelate(1:2) with 3-methoxy-salicylidene-2-aminothiophenol Schiff-base." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-54237-8_300.

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Martell, A. E., K. Tatsumotoc, and P. Taylor. "NMR Detection of a Delocalized Carbanion Intermediate in the Transamination Reactions of the Metal Chelates of Schiff Bases of Vitamin B6." In Biochemistry of Vitamin B6. Birkhäuser Basel, 1987. http://dx.doi.org/10.1007/978-3-0348-9308-4_64.

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Edozie Otuokere, Ifeanyi, Brendan Chidozie Asogwa, Felix Chigozie Nwadire, et al. "Biological Potentials of Some Schiff Bases and Their Chelates: A Short Review." In Novelties in Schiff Bases. IntechOpen, 2024. http://dx.doi.org/10.5772/intechopen.114862.

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In the twenty-first century, the most significant task for scientists has been the development of novel and effective therapeutic agents. Many natural chemicals have been discovered and identified as having biological functions in the body that are beneficial to maintaining a healthy lifestyle. In addition, various classes of compounds are synthesized and assessed for their potential use in biological systems. Schiff bases have the capacity to react and form complexes with metals and proteins due to their superior basic characteristics; hence, the synthesis and pharmacological application of S
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Conference papers on the topic "Schiff Base Chelates"

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Baral, Minati, Amit Gupta, and B. K. Kanungo. "Development of a dipodal Schiff base ligand with N-imine and O-naphtholate donors: A potential chelator towards Cu(II) metal ion established through potentiometric and spectrophotometric studies." In ADVANCED MATERIALS AND RADIATION PHYSICS (AMRP-2015): 4th National Conference on Advanced Materials and Radiation Physics. AIP Publishing LLC, 2015. http://dx.doi.org/10.1063/1.4929176.

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