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Journal articles on the topic 'Silatrane'

Author: Grafiati

Published: 4 June 2021

Last updated: 1 February 2022

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1

Istratov, V. V., E. V. Andreeva, V. I. Gomzyak, and V. A. Vasnev. "SILATRANE-CONTAINING POLYMETHACRYLATES." Fine Chemical Technologies 14, no. 1 (2019): 82–89. http://dx.doi.org/10.32362/2410-6593-2019-14-1-82-89.

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The possibility of synthesizing silatrane-containing polymers was investigated using three different synthetic methods: the formation of silatrane fragments from polymers with trialkoxysilyl groups, the copolymerization of silatrane-containing monomers, and the reaction of silatranes with functional copolymers. The obtained polymethacrylate copolymers were characterized using gel permeation chromatography, IR and NMR spectroscopy. It was shown that depending on the synthesis scheme used, polymers were obtained in the form of three-dimensional structures or soluble products. It was established

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2

Wagner, Gabriele, Rudolf Herrmann, BjØrn Pedersen, and Wolfgang Scherer. "Synthesis and Structure of Chiral Silatranes Derived from Terpenes." Zeitschrift für Naturforschung B 56, no. 1 (2001): 25–38. http://dx.doi.org/10.1515/znb-2001-0105.

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Abstract Starting with the chiral pool compounds (-)-menthone, (-)-limonene, (-)-β-pinene, and (-)-carvone, new homochiral triethanolamine derivatives were obtained and converted to chiral silatranes. These silatranes were characterized by crystal structure analyses and NMR techniques. Conformational analyses in the solid state and in solution show that the chiral terpene residues determine the direction of the ring puckering of the silatrane moiety.

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3

Singh, Gurjaspreet, Akshpreet Singh, Jasbhinder Singh, et al. "First synthesis of pyrene-functionalized silatranes for mechanistic insights into their potential anti-parasitic and anti-oxidation activities." New Journal of Chemistry 41, no. 24 (2017): 15165–72. http://dx.doi.org/10.1039/c7nj03338a.

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The known silatranes have attached substituents such as hydrogen, organyl, organoxy, aminoalkyl, thioorganyl, acyloxy, halogen, pseudohalogen, and other groups; however, their functionalization with any polycyclic aromatic hydrocarbon substituent is not recognized; this creates a niche in silatrane chemistry.

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4

Sakaki, Shigeyoshi, Daisuke Kawai, and Shinya Tsukamoto. "Theoretical study of metallasilatranes; Bonding nature and prediction of new metallasilatrane." Collection of Czechoslovak Chemical Communications 76, no. 5 (2011): 619–29. http://dx.doi.org/10.1135/cccc2011054.

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The new bond between Pt atom and hypervalent six-coordinate Si species in platinum-silatrane reported recently was theoretically investigated mainly with DFT method and in part with MP2 method. The DFT method with B3PW91 and M06 functionals reproduces well the Pt–Si, Pt–Cl and Si–N bond distances. Though the Si–Cl distance is overestimated by all functionals employed here when one d polarization function is added to each of Si and Cl, the M06-optimized Si–Cl distance is close to the experimental value when two d polarization functions are added to each of Si and Cl, suggesting that the functio

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5

Sonsilchai, Phawittra, and Duangdao Aht-Ong. "Investigation of Flame Retardant Properties of Poly(ethylene Terephthalate)/Silatrane Complex/Montmorillonite Nanocomposites." Advanced Materials Research 747 (August 2013): 43–46. http://dx.doi.org/10.4028/www.scientific.net/amr.747.43.

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Poly (ethylene terephthalate) or PET was used in many applications such as packagings, textiles, electrical devices, and auto parts as well due to its good mechanical properties and dimensional stabilities, etc. However, the main drawback of PET is poor flame retardant and melt-dripping, which needed to be solved. Therefore, the aim of this research was to improve the flame retardant properties of PET by investigating the synergistic effects of flame retardant agents between silatrane complex and montmorillonite (MMT) at various concentrations. Silatrane complex was synthesized from silica thr

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6

Kemmitt, Tim, and William Henderson. "A New Route to Silicon Alkoxides from Silica." Australian Journal of Chemistry 51, no. 11 (1998): 1031. http://dx.doi.org/10.1071/c98060.

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A novel route to tetraethoxysilane and other silicon alkoxides is described, from amorphous silica (SiO2.nH2O) as the raw material. The reaction of amorphous silica with triethanolamine is enhanced by using an alkali metal hydroxide catalyst, to form a range of triethanolamine-substituted silatrane species. These can undergo alkoxide exchange in acidic alcohols to form alkoxysilatranes, tetraalkoxysilanes, hexaalkoxydisiloxanes and higher siloxanes. Reaction of triethanolamine-substituted silatranes with acetic anhydride produces acetoxysilatrane. Products were identified by multinuclear (1H,

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7

Istratov, V. V., V. I. Gomzyak, O. V. Yamskova, et al. "Novel polymer surfactants based on the branched silatrane-containing polyesters and polyethers." Fine Chemical Technologies 14, no. 5 (2019): 61–70. http://dx.doi.org/10.32362/2410-6593-2019-14-5-61-70.

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Objectives. Biologically active polymeric surfactants are a new promising class of macromolecules that can find application in medicine, cosmetology, and agriculture. In this study, a number of new biologically active amphiphilic polymers based on branched silatrane-containing polyesters and polyethers were obtained, and their surface-active properties were investigated.Methods. The branched polymers were represented by polyethers and polyesters, obtained respectively via the anionic polymerization of 1,2-epoxypropanol or a combination of equilibrium polycondensation and ring opening polymeriz

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8

Kemmitt, Tim, and William Henderson. "Dendrimeric silatrane wedges." Journal of the Chemical Society, Perkin Transactions 1, no. 5 (1997): 729–40. http://dx.doi.org/10.1039/a605135i.

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9

Bessi, Matteo, Marco Monini, Massimo Calamante, et al. "Synthesis of Silatrane-Containing Organic Sensitizers as Precursors for the Silyloxyl Anchoring Group in Dye-Sensitized Solar Cells." Synthesis 49, no. 17 (2017): 3975–84. http://dx.doi.org/10.1055/s-0036-1588836.

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A series of organic D-π-A dyes, endowed with different silicon-based anchoring groups, has been prepared to assess the stability of such anchoring moieties on nanocrystalline TiO2 in dye-sensitized solar cells. Due to the difficulties encountered in finding a reliable and robust preparation protocol to obtain pure trialkoxysilanes, replacement with a silatrane moiety was evaluated. It was found that the silatrane group could be easily introduced on three different molecular scaffolds by using a simple amide coupling reaction mediated by EDC-Cl. Furthermore, the spectroscopic properties and anc

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10

Romanovs, Vitalijs, Valery Sidorkin, Elena Belogolova, and Viatcheslav Jouikov. "Radical cations of phenyl silatrane." Dalton Transactions 46, no. 27 (2017): 8849–54. http://dx.doi.org/10.1039/c7dt00447h.

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11

Grebneva, E. A., A. I. Albanov, O. M. Trofimova, and M. G. Voronkov. "Boratrane method of silatrane synthesis." Russian Journal of General Chemistry 81, no. 1 (2011): 147–48. http://dx.doi.org/10.1134/s1070363211010257.

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12

Grebneva, E. A., O. M. Trofimova, A. I. Albanov, and M. G. Voronkov. "1-(pyridine-2-carboxymethyl)silatrane." Russian Journal of General Chemistry 82, no. 1 (2012): 168–69. http://dx.doi.org/10.1134/s1070363212010276.

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13

Greenberg, Arthur, and Guanli Wu. "Structural relationships in silatrane molecules." Structural Chemistry 1, no. 1 (1990): 79–85. http://dx.doi.org/10.1007/bf00675787.

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14

Istratov, Vladislav V., Valerii A. Vasnev, and Galy D. Markova. "Biodegradable and Biocompatible Silatrane Polymers." Molecules 26, no. 7 (2021): 1893. http://dx.doi.org/10.3390/molecules26071893.

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In this study, new biodegradable and biocompatible amphiphilic polymers were obtained by modifying the peripheral hydroxyl groups of branched polyethers and polyesters with organosilicon substituents. The structures of the synthesized polymers were confirmed by NMR and GPC. Organosilicon moieties of the polymers were formed by silatranes and trimethylsilyl blocks and displayed hydrophilic and hydrophobic properties, respectively. The effect of the ratio of hydrophilic to hydrophobic organosilicon structures on the surface activity and biological activity of macromolecules was studied, together

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15

Materna, Kelly L., Robert H. Crabtree, and Gary W. Brudvig. "Anchoring groups for photocatalytic water oxidation on metal oxide surfaces." Chemical Society Reviews 46, no. 20 (2017): 6099–110. http://dx.doi.org/10.1039/c7cs00314e.

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16

Singh, Gurjaspreet, Shally Girdhar, Akshpreet Singh, et al. "Selective mercury ion recognition using a methyl red (MR) based silatrane sensor." New Journal of Chemistry 42, no. 8 (2018): 6315–21. http://dx.doi.org/10.1039/c8nj00728d.

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17

Singh, Gurjaspreet, Akshpreet Singh, Pinky Satija, et al. "First report of silver ion recognition via a silatrane-based receptor: excellent selectivity, low detection limit and good applicability." New Journal of Chemistry 43, no. 14 (2019): 5525–30. http://dx.doi.org/10.1039/c9nj00288j.

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18

White, J. M., and S. Jones. "Low-temperature structure of allyl silatrane." Acta Crystallographica Section C Crystal Structure Communications 55, no. 6 (1999): 962–63. http://dx.doi.org/10.1107/s0108270199002371.

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19

Mizumo, Tomonobu, Risa Fujita, Hiroyuki Ohno, and Joji Ohshita. "Lithium Ion Conduction in Silatrane Matrices." Chemistry Letters 40, no. 8 (2011): 798–800. http://dx.doi.org/10.1246/cl.2011.798.

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20

Kilesso, V. M., V. I. Kopkov, A. S. Shashkov, and B. N. Stepanenko. "Ring expansion of 1-(chloromethyl)silatrane." Bulletin of the Academy of Sciences of the USSR Division of Chemical Science 35, no. 6 (1986): 1276–80. http://dx.doi.org/10.1007/bf00956615.

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21

Istratov, V. V., та V. A. Vasnev. "Silatrane-containing poly(β-amino esters)". Russian Chemical Bulletin 69, № 6 (2020): 1134–37. http://dx.doi.org/10.1007/s11172-020-2879-3.

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22

Singh, Gurjaspreet, Sunita Rani, Amandeep Saroa, et al. "Organosilatranes with thioester-anchored heterocyclic ring assembly: Cu2+ ion binding and fabrication of hybrid silica nanoparticles." RSC Advances 5, no. 81 (2015): 65963–74. http://dx.doi.org/10.1039/c5ra09004k.

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Thioester allied organosilatranes were synthesized by the CDI mediated coupling of carboxylic acids with mercaptopropylsilatrane. One of the silatrane was further immobilized onto silica nanospheres, characterized and tested for copper ion binding.

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23

Phiriyawirut, Phairat, Alexander M. Jamieson, and Sujitra Wongkasemjit. "VS-1 zeolite synthesized directly from silatrane." Microporous and Mesoporous Materials 77, no. 2-3 (2005): 203–13. http://dx.doi.org/10.1016/j.micromeso.2004.09.005.

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24

Sterkhova, I. V., I. M. Lazarev, V. I. Smirnov, and N. F. Lazareva. "1-(Methylaminomethyl)silatrane: Synthesis, characterization and reactivity." Journal of Organometallic Chemistry 775 (January 2015): 27–32. http://dx.doi.org/10.1016/j.jorganchem.2014.10.005.

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25

Alam, Sarfaraz, M. Nasim, L. D. Kandpal, and G. N. Mathur. "Silatrane based imide resins: synthesis and characterization." Die Angewandte Makromolekulare Chemie 269, no. 1 (1999): 1–7. http://dx.doi.org/10.1002/(sici)1522-9505(19990801)269:1<1::aid-apmc1>3.0.co;2-y.

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26

Alentiev, D. A., D. M. Dzhaparidze, and M. V. Bermeshev. "Addition Polymerization of Tricyclononene Containing Silatrane Groups." Polymer Science, Series B 61, no. 6 (2019): 806–11. http://dx.doi.org/10.1134/s1560090419060010.

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27

Hencsei, P. "Evaluation of silatrane structures by correlation relationships." Structural Chemistry 2, no. 1 (1991): 21–26. http://dx.doi.org/10.1007/bf00673485.

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28

Eujen, Reint, Achim Roth, and David J. Brauer. "Preparation and Structure of 1-(Trifluoromethyl)silatrane." Monatshefte für Chemie / Chemical Monthly 130, no. 1 (1999): 109–15. http://dx.doi.org/10.1007/pl00000112.

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29

Stachel, Shawn J., Joseph W. Ziller, and David L. Van Vranken. "A chiral C3 triisopropylamine and its silatrane derivatives." Tetrahedron Letters 40, no. 32 (1999): 5811–12. http://dx.doi.org/10.1016/s0040-4039(99)01135-1.

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30

Hencsei, P., L. Párkányi, V. Fülöp, V. P. Baryshok, M. G. Voronkov та G. A. Kuznetsova. "The molecular structure of 1-(γ-hydroxypropyl)silatrane". Journal of Organometallic Chemistry 346, № 3 (1988): 315–20. http://dx.doi.org/10.1016/0022-328x(88)80131-1.

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31

Hencsei, P., I. Kovács та V. Fülöp. "The crystal structure of 1-(γ-mercaptopropyl)silatrane". Journal of Organometallic Chemistry 377, № 1 (1989): 19–23. http://dx.doi.org/10.1016/0022-328x(89)80047-6.

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32

Gurkova, S. N., A. I. Gusev, N. V. Alekseev, and M. A. Ignatenko. "Crystal and molecular structure of 1-(cyclopropyl)silatrane." Journal of Structural Chemistry 29, no. 2 (1988): 345–47. http://dx.doi.org/10.1007/bf00748006.

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33

Materna, Kelly L., Benjamin Rudshteyn, Bradley J. Brennan, et al. "Heterogenized Iridium Water-Oxidation Catalyst from a Silatrane Precursor." ACS Catalysis 6, no. 8 (2016): 5371–77. http://dx.doi.org/10.1021/acscatal.6b01101.

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34

Lazareva, N. F., and I. V. Sterkhova. "1-[N-phenyl(aminomethyl)]silatrane: Synthesis, reactivity and structure." Journal of Organometallic Chemistry 898 (October 2019): 120870. http://dx.doi.org/10.1016/j.jorganchem.2019.120870.

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35

Voronkov, M. G., Yu I. Bolgova, V. V. Belyaeva, A. I. Emel’yanov, O. M. Trofimova, and G. F. Prozorova. "Complexes of 1-(methylaminomethyl)silatrane with transition metal chlorides." Russian Journal of Organic Chemistry 49, no. 3 (2013): 472–74. http://dx.doi.org/10.1134/s1070428013030275.

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36

Voronkov, M. G., E. A. Zelbst, Yu I. Bolgova, et al. "Synthesis and molecular structure of 1-(2-pyridyloxy)silatrane." Russian Journal of General Chemistry 78, no. 12 (2008): 2333–38. http://dx.doi.org/10.1134/s1070363208120074.

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37

HENCSEI, P. "ChemInform Abstract: Evaluation of Silatrane Structures by Correlation Relationships." ChemInform 22, no. 26 (2010): no. http://dx.doi.org/10.1002/chin.199126063.

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38

Hencsei, P., L. P�rk�nyi, and I. Kov�cs. "Crystal structure of 1-[N-2-aminoethyl)-aminopropyl]silatrane." Chemistry of Heterocyclic Compounds 32, no. 11-12 (1997): 1376–80. http://dx.doi.org/10.1007/bf01169968.

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39

Adamovich, Sergei N., Evgeny Kh Sadykov, Igor A. Ushakov, Elizaveta N. Oborina, and Lydmila A. Belovezhets. "Antibacterial activity of new silatrane pyrrole-2-carboxamide hybrids." Mendeleev Communications 31, no. 2 (2021): 204–6. http://dx.doi.org/10.1016/j.mencom.2021.03.019.

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40

Singh, Gurjaspreet. "Reactivity of 1-Isothiocyanato Six Membered Silatrane towards Lewis Acids." International Journal of Innovative Research in Science, Engineering and Technology 03, no. 08 (2014): 15752–57. http://dx.doi.org/10.15680/ijirset.2014.0308090.

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41

Lazareva, N. F., I. V. Sterkhova, I. M. Lazarev, and V. I. Smirnov. "1-[(N-Methyl-N-tritylamino)methyl]silatrane: Synthesis and structure." Polyhedron 117 (October 2016): 377–80. http://dx.doi.org/10.1016/j.poly.2016.05.066.

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42

Voronkov, M. G., L. Ya Tsvetkova, E. B. Solovich, N. V. Novoselova, G. A. Kuznetsova, and V. P. Baryshok. "Thermodynamic properties of 1,3-dimethylsilatrane and 1-(2-cyanoethyl)silatrane." Russian Journal of General Chemistry 77, no. 12 (2007): 2128–29. http://dx.doi.org/10.1134/s1070363207120092.

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43

Sathupunya, Mathavee, Erdogan Gulari, and Sujitra Wongkasemjit. "Microwave preparation of Li-zeolite directly from alumatrane and silatrane." Materials Chemistry and Physics 83, no. 1 (2004): 89–95. http://dx.doi.org/10.1016/j.matchemphys.2003.09.023.

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44

Istratov, V. V., O. V. Yamskova, V. A. Vasnev, D. V. Kurilov, T. A. Bondareva, and N. I. Bondarev. "Synthesis the of silatrane-containing branched polymers – biologically active substances." Technology and the study of mer-chandise of innovative foodstuffs 61, no. 2 (2020): 3–9. http://dx.doi.org/10.33979/2219-8466-2020-61-2-3-9.

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45

Singh, Gurjaspreet, Sheenam Girdhar, Raj Pal Sharma, Przemysław Starynowicz, and Baljinder Singh. "Carbofunctional Silatrane Possessing Imidazole Moiety: Synthesis, Characterization, and Antibacterial Studies." Phosphorus, Sulfur, and Silicon and the Related Elements 189, no. 11 (2014): 1732–45. http://dx.doi.org/10.1080/10426507.2014.902822.

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46

Stachel, Shawn J., Joseph W. Ziller, and David L. van Vranken. "ChemInform Abstract: A Chiral C3 Triisopropylamine and Its Silatrane Derivatives." ChemInform 30, no. 42 (2010): no. http://dx.doi.org/10.1002/chin.199942080.

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47

Longloilert, Rujirat, Thanyalak Chaisuwan, Apanee Luengnaruemitchai, and Sujitra Wongkasemjit. "Synthesis of MCM-48 from silatrane via sol–gel process." Journal of Sol-Gel Science and Technology 58, no. 2 (2011): 427–35. http://dx.doi.org/10.1007/s10971-011-2409-8.

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48

Voronkov, M. G., È. A. Zel’bst, V. S. Fundamensky, V. V. Gurzhiy, Yu I. Bolgova, and O. M. Trofimova. "Crystal and molecular structure of 1-(3-ammoniopropyl)silatrane chloride." Journal of Structural Chemistry 55, no. 2 (2014): 370–73. http://dx.doi.org/10.1134/s0022476614020280.

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49

Singh, Gurjaspreet. "Reactivity of 1-Isothiocyanato Six Membered Silatrane towards Transition Metal Carbonyls." International Journal of Innovative Research in Science, Engineering and Technology 03, no. 08 (2014): 15758–63. http://dx.doi.org/10.15680/ijirset.2014.0308091.

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50

Sathupunya, Mathavee, Erdogan Gulari, Alexander Jamieson, and Sujitra Wongkasemjit. "Microwave-assisted preparation of zeolite K–H from alumatrane and silatrane." Microporous and Mesoporous Materials 69, no. 3 (2004): 157–64. http://dx.doi.org/10.1016/j.micromeso.2004.02.003.

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