Relevant bibliographies by topics / Sonogashira cross-coupling reaction

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Academic literature on the topic 'Sonogashira cross-coupling reaction'

Author: Grafiati
Published: 4 June 2021
Last updated: 25 July 2025

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Journal articles on the topic "Sonogashira cross-coupling reaction"

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Rifhat Bibi, Rifhat Bibi, Muhammad Yaseen Muhammad Yaseen, Haseen Ahmad Haseen Ahmad, Ismat Ullah Khan Ismat Ullah Khan, Shaista Parveen Shaista Parveen, and Abbas Hassan Abbas Hassan. "Palladium Catalyzed Synthesis of Phenylquinoxaline-Alkyne Derivatives via Sonogashira Cross Coupling Reaction." Journal of the chemical society of pakistan 43, no. 1 (2021): 95. http://dx.doi.org/10.52568/000550.

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Transition metals mediated cross coupling methodologies provide an extremely powerful versatile pathway in organic syntheses undoubtedly, a facile route for syntheses and derivatization of biologically important heterocycles from easily available precursors. Sonogashira coupling reaction, a leading method to Csp-Csp2 bond formation is one of the most important and rapid pathways to couple aryl/vinyl halides with terminal alkynes. Current research study deals with the synthesis of alkyne substituted quinoxaline derivatives. The quinoxalines class of aromatic heterocycles exhibits a wide variety
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Rifhat Bibi, Rifhat Bibi, Muhammad Yaseen Muhammad Yaseen, Haseen Ahmad Haseen Ahmad, Ismat Ullah Khan Ismat Ullah Khan, Shaista Parveen Shaista Parveen, and Abbas Hassan Abbas Hassan. "Palladium Catalyzed Synthesis of Phenylquinoxaline-Alkyne Derivatives via Sonogashira Cross Coupling Reaction." Journal of the chemical society of pakistan 43, no. 1 (2021): 95. http://dx.doi.org/10.52568/000550/jcsp/43.01.2021.

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Transition metals mediated cross coupling methodologies provide an extremely powerful versatile pathway in organic syntheses undoubtedly, a facile route for syntheses and derivatization of biologically important heterocycles from easily available precursors. Sonogashira coupling reaction, a leading method to Csp-Csp2 bond formation is one of the most important and rapid pathways to couple aryl/vinyl halides with terminal alkynes. Current research study deals with the synthesis of alkyne substituted quinoxaline derivatives. The quinoxalines class of aromatic heterocycles exhibits a wide variety
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Rifhat Bibi, Rifhat Bibi, Muhammad Yaseen Muhammad Yaseen, Haseen Ahmad Haseen Ahmad, Ismat Ullah Khan Ismat Ullah Khan, Shaista Parveen Shaista Parveen, and Abbas Hassan Abbas Hassan. "Palladium Catalyzed Synthesis of Phenylquinoxaline-Alkyne Derivatives via Sonogashira Cross Coupling Reaction." Journal of the chemical society of pakistan 43, no. 1 (2021): 95. http://dx.doi.org/10.52568/000009.

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Transition metals mediated cross coupling methodologies provide an extremely powerful versatile pathway in organic syntheses undoubtedly, a facile route for syntheses and derivatization of biologically important heterocycles from easily available precursors. Sonogashira coupling reaction, a leading method to Csp-Csp2 bond formation is one of the most important and rapid pathways to couple aryl/vinyl halides with terminal alkynes. Current research study deals with the synthesis of alkyne substituted quinoxaline derivatives. The quinoxalines class of aromatic heterocycles exhibits a wide variety
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Albano, Gianluigi, and Laura Antonella Aronica. "Acyl Sonogashira Cross-Coupling: State of the Art and Application to the Synthesis of Heterocyclic Compounds." Catalysts 10, no. 1 (2019): 25. http://dx.doi.org/10.3390/catal10010025.

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The acyl Sonogashira reaction represents an extension of Sonogashira cross-coupling to acid chlorides which replace aryl or vinyl halides, while terminal acetylenes are used as coupling partners in both reactions. The introduction of a carbonyl functional group on the alkyne backbone determines a radical change in the reactivity of the products. Indeed, α,β-alkynyl ketones can be easily converted into different heterocyclic compounds depending on the experimental conditions employed. Due to its potential, the acyl Sonogashira reaction has been deeply studied with particular attention to the na
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Wang, Lei, Jincan Yan, Pinhua Li, Min Wang, and Caina Su. "The effects of amines on oxidative homo-coupling of terminal alkynes promoted by copper salts." Journal of Chemical Research 2005, no. 2 (2005): 112–15. http://dx.doi.org/10.3184/0308234054497083.

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The effects of all kinds of amines on homo-couplings (Glaser reactions) of terminal alkynes promoted by copper salts and the Sonogashira coupling reactions were studied systematically. Diethylamine (2° amine) can serve as an excellent solvent, base and coordination ligand in the oxidative homo-coupling of terminal alkynes and several modified Glaser coupling procedures have been developed which are based on a catalytic amount of cuprous salts (CuI, CuBr or CuCl) with diethylamine systems. Homo-coupling of terminal acetylenes in the Sonogashira reaction could be inhibited by using triethylamine
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Murata, Yuki, Yuya Nishi, Mio Matsumura, and Shuji Yasuike. "Palladium-Catalyzed Cross-Coupling Reaction of Bis(cyclopentadienyl)diaryltitaniums with Terminal Alkynes." Reactions 4, no. 4 (2023): 657–66. http://dx.doi.org/10.3390/reactions4040037.

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Organotitanium compounds find application in diverse reactions, including carbon–carbon bond formation and oxidation. While titanium (IV) compounds have been used in various applications, the potential of bis(cyclopentadienyl)diaryltitanium in cross-coupling reactions remains unexplored. This study focuses on Sonogashira-type cross-coupling reactions involving terminal alkynes and organotitanium compounds. Diaryltitanocenes were synthesized using titanocene dichloride with lithium intermediates derived from aryl iodide. Under open-flask conditions, reactions of diphenyltitanocenes with ethynyl
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Murashkina, A. V., A. Yu Mitrofanov, and I. P. Beletskaya. "Copper in Cross-Coupling Reactions: I. Sonogashira-Hagihara Reaction." Russian Journal of Organic Chemistry 55, no. 10 (2019): 1445–58. http://dx.doi.org/10.1134/s1070428019100014.

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Mohajer, Fatemeh, Majid M. Heravi, Vahideh Zadsirjan, and Nargess Poormohammad. "Copper-free Sonogashira cross-coupling reactions: an overview." RSC Advances 11, no. 12 (2021): 6885–925. http://dx.doi.org/10.1039/d0ra10575a.

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Kanwal, Iram, Aqsa Mujahid, Nasir Rasool, et al. "Palladium and Copper Catalyzed Sonogashira cross Coupling an Excellent Methodology for C-C Bond Formation over 17 Years: A Review." Catalysts 10, no. 4 (2020): 443. http://dx.doi.org/10.3390/catal10040443.

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Sonogashira coupling involves coupling of vinyl/aryl halides with terminal acetylenes catalyzed by transition metals, especially palladium and copper. This is a well known reaction in organic synthesis and plays a role in sp2-sp C-C bond formations. This cross coupling was used in synthesis of natural products, biologically active molecules, heterocycles, dendrimers, conjugated polymers and organic complexes. This review paper focuses on developments in the palladium and copper catalyzed Sonogashira cross coupling achieved in recent years concerning substrates, different catalyst systems and r
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Venkata Krishna Reddy, Motakatla, Peddiahgari Vasu Govardhana Reddy, and Cirandur Suresh Reddy. "PEPPSI-SONO-SP2: a new highly efficient ligand-free catalyst system for the synthesis of tri-substituted triazine derivatives via Suzuki–Miyaura and Sonogashira coupling reactions under a green approach." New Journal of Chemistry 40, no. 6 (2016): 5135–42. http://dx.doi.org/10.1039/c5nj03299g.

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Dissertations / Theses on the topic "Sonogashira cross-coupling reaction"

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Hussain, Jakir. "Approaches toward the synthesis of lactonamycin utilising a new benzannulation reaction." Thesis, University of Manchester, 2013. https://www.research.manchester.ac.uk/portal/en/theses/approaches-toward-the-synthesis-of-lactonamycin-utilising-a-new-benzannulation-reaction(1157cbe4-21f4-4d9e-a10d-cf20518eb30b).html.

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The Bull-Hutchings-Quayle (BHQ) reaction is a novel method for the synthesis of 1-(bromo/chloro)napthalenes from 2-allyphenyl-2’,2’,2’-tri(bromo/chloro)acetates. The reaction is also known as Atom Transfer Radical Cyclisation-Benzannulation (ATRC-Benzannulation). The ATRC-Benzannulation of structurally diverse 2-(cyclohex-1-en-1-ylmethyl)phenyl 2’,2’,2’-trichloroacetates in the presence of 1,3bis-(2,6diisopropylphenyl)imidazolium copper(I) chloride [“Nolan NHC-CuCl”] complexes, using microwave or thermolytic methods, afford a range of 9-chloro-1,2,3,4-tetrahydroanthracenes. Efficient ATRC-Be
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D'Attoma, Joseph. "Conception, synthèses et évaluations biologiques d’inhibiteurs à double cible : ALK et la restriction calorique." Thesis, Lyon 1, 2013. http://www.theses.fr/2013LYO10243.

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Les lymphomes à grandes cellules anaplasiques ou ALCL (Anaplastic Large-Cell Lymphoma) sont des cancers appartenant à la famille des lymphomes de type non-Hodgkin. La majorité des ALCL est issue d'une translocation t(2;5)(p23;q35) donnant lieu à la formation d'une protéine de fusion appelée NPM-ALK. A ce jour, peu d'inhibiteurs présentent de bonnes activités contre cette protéine chimérique. L'obésité représente un problème socio-médical d'envergure, à la fois pour ses effets directs et indirects ; le surpoids étant un facteur primaire dans de nombreuses maladies, tout particulièrement les dia
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Karabiyikoglu, Sedef. "Synthesis Of Ferrocenyl Substituted Pyrazoles By Sonogashira And Suzuki-miyaura Cross-coupling Reactions." Master's thesis, METU, 2010. http://etd.lib.metu.edu.tr/upload/3/12612139/index.pdf.

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Pyrazoles constitute one of the most important classes of heterocyclic compounds due to their interesting chemical and biochemical features. Researchers have studied many pyrazole containing structures for almost over a century in order to investigate the various biological activities possessed by these molecules. A new and important trend in these studies is to produce ferrocenyl substituted pyrazoles since ferrocene attracts considerable interest in the research field of organometallic and bioorganometallic chemistry because of its valuable chemical characteristics like high stability, low t
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Allouch, Fatima. "Synthèse et applications de nouveaux complexes métallocéniques multidentes." Thesis, Dijon, 2013. http://www.theses.fr/2013DIJOS002.

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Ce mémoire porte sur l’accès simple et peu coûteux à de nouveaux ligands ferrocéniques aminés et aminophosphinés et leur coordination avec des métaux de transition pour des applications en catalyse homogène.Des métallo-ligands aminés flexibles ont été obtenus et caractérisés après amination réductrice du 1,1’-diformylferrocène. D’autres ligands (N,N) rigides ont été isolés au départ du précurseur du 1,1’-di-tert-butyl-3,3’-diformylferrocène. Des aza-ferrocénophanes ont également été facilement préparés avec ces deux précurseurs carbonylés. Lors de la coordination de ces ligands avec le palladi
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MELI, Alessandro. "DEEP EUTECTIC SOLVENTS E LIQUIDI IONICI: SOLVENTI PER LO SVILUPPO DI PROCESSI ECO-COMPATIBILI." Doctoral thesis, Università degli Studi di Palermo, 2020. http://hdl.handle.net/10447/395244.

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L’obiettivo di questi tre anni di Dottorato è stato lo studio e l’utilizzo nuovi solventi di reazione in grado di sostituire i solventi organici classici. In particolare sono stati studiati i Deep Eutectic Solvent (DES) e le miscele di Liquidi Ionici (IL). I DES sono stati utilizzati come solventi per lo studio di reazioni organiche, usate per la formazione di nuovi legami C-C. Nello specifico sono state studiate la reazione di Diels-Alder, e diverse reazioni di coupling C-C catalizzate da Pd. In seguito, i DES sono stati utilizzati per la formazione di nuovi gel supramolecolari, chiamati eu
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Tsai, Wan-Ting, and 蔡宛廷. "1.Microwave-Assisted Copper-Catalyzed Sonogashira Type Cross-Coupling Reaction2.Microwave-Promoted Rhodium and Copper Catalyzed C-S Bond Cross-Coupling Reaction." Thesis, 2013. http://ndltd.ncl.edu.tw/handle/wnhhwc.

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碩士<br>國立中興大學<br>化學系所<br>101<br>The coupling of aryl halides with terminal alkynes catalyzed by palladium and copper is commonly called Sonogashira cross-coupling reaction.This method is one of the most important ways to prepare internal alkynes. In the first part of this thesis, we found CuI(xantphose) can be used as an efficient catalyst under the microwave, promoted coupling reaction of aryl or vinyl halides with terminal alkynes to provide the corresponding alkynes and enynes with excellent yields in short reaction time. In the second part, we will study the rhodium and copper-catalyzed
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Makelane, Hlamulo Reply. "Regioselectivity of palladium-catalyzed sonogashira cross-coupling of 2-aryl-4-chloro-3-iodoquinoline- derivatives with terminal alkynes." Diss., 2010. http://hdl.handle.net/10500/3838.

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Please note that the structures do not display correctly in the pdf document. Therefore the original manuscript in MSWord has also been uploaded. Please contact us email if you cannot view these files.<br>Sonogashira cross-coupling of 2-aryl-4-chloro-3-iodoquinoline derivatives with stoichiometric amount of terminal alkynes in the presence of bis(triphenylphosphine)palladium(II)chloride and copper iodide in triethylamine afforded the 3-(alkynyl)-2-aryl-4-chloroquinoline, exclusively. On the other hand, the 2-aryl-4-chloro-3-iodoquinolines with excess (2.5 equiv.) of terminal alkynes in the pre
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Lin, Zhe-Yi, and 林哲毅. "The study in cascade reactions of Csp2-Csp cross-coupling(Sonogashira-type reaction)、cyclization and Csp2-S cross-coupling(Ullmann-type reaction) for one-pot three-step synthesis of benzo[b]thiophene derivatives using a simple copper-chloride system." Thesis, 2010. http://ndltd.ncl.edu.tw/handle/31214405631202089597.

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碩士<br>國立中興大學<br>化學系所<br>98<br>It has been known that 2,3-disubstituted benzo[b]thiophenes have been prepared in excellent yields via coupling of terminal alkynes with commercially available o-iodothioanisole in the presence of a palladium catalyst and subsequent electrophilic cyclization of the resulting o-(1-alkynyl)thioanisole derivatives. We have developed a new synthetic method that by using copper choride-mediated cascade reactions of Csp2-Csp coupling, intramolecular cyclization, and Csp2-S coupling without using palladium catalyst and any ligand for one-pot three-step syntheses of 2,3
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Shih, Hong-Pin, and 施宏儐. "I. Formation of N-embedded polyacene ladder polymer from polyaniline II. Desulfitative Sonogashira-type cross-coupling reaction of poly(3-alkylthiothiophene) with terminal alkyne." Thesis, 2018. http://ndltd.ncl.edu.tw/handle/kxf327.

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Lesenyeho, Lehlogonolo Godfrey. "Palladium-catalyzed heteroannulation of 2-ARYL- 3-IODO-4-(Phenylamino)quinolines and 4-(N,N-allylphenylamino)-2-ARYL-3-iodoquinolines." Diss., 2010. http://hdl.handle.net/10500/3970.

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The previously described 2-aryl-4-chloro-3-iodoquinolines were prepared following literature procedure and in turn converted to the corresponding hitherto unknown 2-aryl-3-iodo-4-(phenylamino)quinoline derivatives using aniline in refluxing ethanol. These 2-aryl-3-iodo-4-(phenylamino)quinolines were reacted with allybromide in ethanol at room temperature to afford 4-(N,N-allylphenylamino)-2-aryl-3-iodoquinoline derivatives. The 2-aryl-3-iodo-4-(phenylamino)quinoline and 4-(N,N-allylphenylamino)-2-aryl-3-iodoquinoline derivatives were subjected to metal-catalysed carbon-carbon bond formations.
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Book chapters on the topic "Sonogashira cross-coupling reaction"

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García Melchor, Max. "The Cu-Free Sonogashira Reaction Mechanism." In A Theoretical Study of Pd-Catalyzed C-C Cross-Coupling Reactions. Springer International Publishing, 2013. http://dx.doi.org/10.1007/978-3-319-01490-6_5.

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Griesbeck, A. G., and A. Soldevilla. "Palladium-Catalyzed Cross Coupling (Copper-Free Sonogashira Reaction)." In Polyynes, Arynes, Enynes, and Alkynes. Georg Thieme Verlag KG, 2008. http://dx.doi.org/10.1055/sos-sd-043-00326.

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Griesbeck, A. G., and A. Soldevilla. "Metal-Free Cross Coupling (Metal-Free Sonogashira Reaction)." In Polyynes, Arynes, Enynes, and Alkynes. Georg Thieme Verlag KG, 2008. http://dx.doi.org/10.1055/sos-sd-043-00333.

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Griesbeck, A. G., and A. Soldevilla. "Copper/Palladium-Catalyzed Cross Coupling of Haloarenes and Terminal Alkynes (The Sonogashira–Hagihara Cross-Coupling Reaction)." In Polyynes, Arynes, Enynes, and Alkynes. Georg Thieme Verlag KG, 2008. http://dx.doi.org/10.1055/sos-sd-043-00321.

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Oestreich, M. "sp–sp Cross-Coupling Reactions of Electrophilic Arenecarbaldehydes (Sonogashira Coupling)." In Aldehydes. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-025-00478.

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Migliorini, F., S. Puglioli, D. Neri, S. Cazzamalli, and N. Favalli. "2.2 Metal-Promoted DEL-Compatible C—C Bond Forming Reactions." In DNA-Encoded Libraries. Georg Thieme Verlag KG, 2024. http://dx.doi.org/10.1055/sos-sd-241-00025.

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AbstractDNA-encoded library (DEL) technology relies on the availability of robust and DNA-compatible chemical transformations. Metal-promoted C—C bond forming reactions are widely applied for the synthesis of fine chemicals such as pharmaceuticals. However, their application in DEL technology represents a challenge due to the use of metal catalysts, high temperatures, and organic solvents. In this chapter, we report tailored conditions for the on-DNA application of the Suzuki, Sonogashira, Heck, and Giese reactions. The conditions presented in this chapter have been systematically explored acr
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Choy, Pui Ying, Xinwei He, and Fuk Yee Kwong. "Palladacycles as Precatalysts for Heck and Sonogashira Cross-Coupling Reactions." In Palladacycles. Elsevier, 2019. http://dx.doi.org/10.1016/b978-0-12-815505-9.00003-2.

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Griesbeck, A. G., and A. Soldevilla. "Sonogashira Cross-Coupling Reactions for Bromoarenes Using Specially Designed Ligands." In Polyynes, Arynes, Enynes, and Alkynes. Georg Thieme Verlag KG, 2008. http://dx.doi.org/10.1055/sos-sd-043-00322.

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Conference papers on the topic "Sonogashira cross-coupling reaction"

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NAKAMURA, HIDEKI, KENICHI KOMURA, and YOSHIHIRO SUGI. "QUINOLINE-CARBOIMINE PALLADIUM COMPLEX IMMOBILIZED ON MCM-41 AS A VERSATILE CATALYST FOR SONOGASHIRA CROSS-COUPLING REACTION." In Proceedings of the 5th International Symposium. WORLD SCIENTIFIC, 2008. http://dx.doi.org/10.1142/9789812779168_0057.

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Carvalho, Diego B., Camila B. Andrade, Carla R. Z. Miranda, et al. "Synthesis of Thiophene Acetylenes via Sonogashira Cross- Coupling Reactions." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_2013820103940.

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Iglesias, Bernardo A., Henrique E. Toma, and Koiti Araki. "Synthesis of poly(pyridyl)porphyrins by Heck and Sonogashira cross-coupling reactions." In 14th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-14bmos-r0096-1.

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