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Dissertations / Theses on the topic 'Supramolecular complexes; Host-guest chemistry'

Author: Grafiati

Published: 4 June 2021

Last updated: 2 February 2022

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1

Waymark, Christopher Peter. "Studies towards a novel synthetic receptor for small peptides." Thesis, University of Southampton, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.294980.

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2

Farabi, Shiva. "Luminescent assemblies based on surface active transition metal complexes and supramolecular host-guest systems." Thesis, University of Birmingham, 2012. http://etheses.bham.ac.uk//id/eprint/3833/.

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Miniaturisation of devices and components is becoming increasingly important in the field of molecular devices. The design of multicomponent supramolecular systems that undergo photoinduced energy or electron transfer processes has been well recognised in view of its potential for development of nanosized molecular devices for solar energy conversion and components in photonic devices. Consequently research has expanded to the properties of monolayers formed from rather simple organic molecules to biological systems and metal complexes. In the present approach, surface active Ru(II) and Os(II)

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3

Löffler, Susanne. "Host-Guest Chemistry of Acridone-based Coordiantion Cages." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2018. http://hdl.handle.net/11858/00-1735-0000-002E-E415-6.

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4

He, Xiaoming. "Design, synthesis and characterization of alkynyl- and thiolato- gold (I) complexes with various receptor groups for host-guest chemistry." Click to view the E-thesis via HKUTO, 2010. http://sunzi.lib.hku.hk/hkuto/record/B43571979.

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5

Martínez, Agramunt Víctor. "Nickel and palladium supramolecular organometallic complexes based on NHC-ligands with polyaromatic moieties for host-guest chemistry studies." Doctoral thesis, Universitat Jaume I, 2020. http://dx.doi.org/10.6035/14104.2020.366143.

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Se ha obtenido una nueva familia de cuatro Complejos Organometálicos Supramoleculares (SOCs) basados en pireno. Dentro de los cuales se ha desarrollado un nuevo receptor de PAH, capaz de discernir entre los diferentes PAH en función de su forma, tamaño, y número de electrones-pi. Hemos desarrollado una estrategia eficiente para la extracción de PAH, que son compuestos tóxicos y carcinogénicos, en disolventes orgánicos. Paralelamente, se han obtenido dos receptores de fulereno, capaces de adaptar su tamaño a la forma del fulereno. Debido a la mayor afinidad respecto a un fulereno específico, mo

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6

Yip, Sung-kong. "Design, synthesis, characterization and luminescence properties of alkynylgold(I) complexes strategies towards supramolecular architectures and host guest chemistry /." Click to view the E-thesis via HKUTO, 2005. http://sunzi.lib.hku.hk/hkuto/record/B31941734.

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7

Panesar, Kuldeep Singh. "Quantum molecular dynamics of guest molecules in supramolecular complexes." Thesis, University of Nottingham, 2009. http://eprints.nottingham.ac.uk/10741/.

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The quantum motion of guest molecules has been studied in a variety of calixarene host-guest complexes, and in a endohedral fullerene complex. The guest molecules of the calixarene complexes studied each comprise weakly hindered methyl groups, which undergo rotation via quantum tunnelling, even at cryogenic temperatures. The rotational motion of the guest methyl-groups has been studied by making temperature and frequency-dependent measurements of proton T1, using field-cycling NMR, thus revealing the spectral density functions of the magnetic dipole-dipole interaction. Crystallographically ine

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8

Lo, Hiu-suet. "Design and syntheses of luminescent alkynyl complexes containing multinuclear platinum (II) and coinage metal centres from photophysics to host-guest chemistry and supramolecular architectures /." Click to view the E-thesis via HKUTO, 2009. http://sunzi.lib.hku.hk/hkuto/record/B41633714.

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9

Lo, Hiu-suet, and 盧曉雪. "Design and syntheses of luminescent alkynyl complexes containing multinuclear platinum (II) and coinage metal centres: from photophysics to host-guest chemistry andsupramolecular architectures." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2009. http://hub.hku.hk/bib/B41633714.

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10

Tang, Hau-san, and 鄧巧珊. "Design and synthesis of metal phosphine complexes of palladium(II) andgold(I) with various receptor ligands for ion-controlled orphotoresponsive host-guest chemistry." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2006. http://hub.hku.hk/bib/B37877422.

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11

Tang, Hau-san. "Design and synthesis of metal phosphine complexes of palladium(II) and gold(I) with various receptor ligands for ion-controlled or photoresponsive host-guest chemistry." Click to view the E-thesis via HKUTO, 2006. http://sunzi.lib.hku.hk/hkuto/record/B37877422.

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12

Galstyan, Anzhela [Verfasser], Bernhard [Akademischer Betreuer] Lippert, and Jens [Gutachter] Müller. "Discrete supramolecular metal complexes : Synthesis, structures, host-guest chemistry with anions, and DNA binding properties / Anzhela Galstyan. Betreuer: Bernhard Lippert. Gutachter: Jens Müller." Dortmund : Universitätsbibliothek Dortmund, 2011. http://d-nb.info/1103472453/34.

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13

Sun, Qingqing. "Aryl and Super Aryl-Extended Calix[4]pyrroles: Synthesis and Applications." Doctoral thesis, Universitat Rovira i Virgili, 2021. http://hdl.handle.net/10803/672268.

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Aquesta tesi doctoral descriu el disseny i la síntesi d’una sèrie de receptors supramoleculars que presenten cavitats aromàtiques polars. Els receptors preparats inclouen receptors organometàl·lics, contenidors moleculars solubles en aigua, caixes moleculars basades en enllaços de coordinació i metal·lo-cavitands. S’han seleccionat unitats de calix[4]pirrole aril i super-aril estesos (AEC[4]P i SAE-C[4]P) com a components principals. S’han estudiat les propietats de reconeixement molecular dels receptors sintètics amb sals de clorur de tetraalquilamoni, així com de molècules polars neutres, en

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14

Escobar, González Luis. "Molecular containers based on aryl-extended calix[4]Pyrroles." Doctoral thesis, Universitat Rovira i Virgili, 2019. http://hdl.handle.net/10803/668442.

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Aquesta Tesi s'ocupa del disseny i síntesi de receptors còncaus que posseeixen cavitats hidrofíliques: receptors covalents, caixes metàl·liques i càpsules no covalents. Per a la seva construcció, triem la bastida de calix[4]pirrol aril-estès (C[4]P-AE), que proporciona una cavitat aromàtica profunda tancada en un extrem per un lloc d'unió polar i oberta a l'extrem oposat. També investiguem les propietats de reconeixement dels receptors sintetitzats en dissolvents orgànics així com en aigua. Específicament, descrivim un mètode sintètic per l'allargament de la cavitat de C[4]P-AEs que condueix a

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15

Yeung, Ching-lam Margaret, and 楊靖琳. "Design and synthesis of luminescent alkynylplatinum (II) terpyridine complexes and their function as optical probes for biomolecules and ions : from self-aggregarion, supramolecular assembly to host-guest chemistry." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2013. http://hdl.handle.net/10722/208590.

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A number of cationic water-soluble alkynylplatinum(II) terpyridine complexes, [Pt(tpy){C≡CCH2OC6H3-(CH2OH)2-3,5}]OTf, [Pt(tBu3tpy){C≡CCH2OC6H3- (CH2OH)2-3,5}]Cl, [Pt(tpy){C≡CCH2OC6H4-(CH2OH)-4}]OTf, [Pt(tpy){C≡CC6H3- (CH2OH)2-3,5}]OTf, [Pt(tpy){C≡CC6H4-(CH2OH)-4}]OTf, [Pt(tpy)(C≡C－C≡CH)]OTf and [Pt(tpy){C≡CC6H4(CH2NMe3)-4}](OTf)2, have been synthesized. Phosphate anion derivatives of polyanionic nature, e.g. adenosine triphosphate and tyrosine-containing phosphopeptide, were employed to investigate the induced supramolecular helical assembly behaviors of several of the water-soluble pla

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16

Hui, Chi-kuen, and 許志權. "Design and synthesis of novel classes of alkynyl-containing platinum (II) complexes as building blocks for supramolecular assemblies andhost-guest chemistry." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2003. http://hub.hku.hk/bib/B31244257.

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17

Daver, Henrik. "Quantum Chemical Modeling of Phosphoesterase Mimics and Chemistry in Confined Spaces." Doctoral thesis, Stockholms universitet, Institutionen för organisk kemi, 2017. http://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-148259.

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In this thesis, density functional theory is employed in the study of two kinds of systems that can be considered to be biomimetic in their own ways. First, three binuclear metal complexes, synthesized by the group of Prof. Ebbe Nordlander, have been investigated. The complexes are designed to resemble the active sites of phosphatase enzymes and have been examined in complexes where either two Zn(II) ions or one Fe(III) and one Mn(II) ion are bound. These dinuclear compounds were studied as catalysts for the hydrolysis of bis(2,4-dinitrophenyl) phosphate and the transesterification of 2-hydrox

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18

He, Xiaoming, and 何晓明. "Design, synthesis and characterization of alkynyl- and thiolato-gold (I) complexes with various receptor groups for host-guestchemistry." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2010. http://hub.hku.hk/bib/B43571979.

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19

Le, ho Khanh hy. "Synthèse par « Click Chemistry » de matériaux hybrides et éudes de leurs assemblages supramoléculaires." Thesis, Paris 11, 2012. http://www.theses.fr/2012PA112285/document.

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L’approche « bottum-up » via l’auto-assemblage moléculaire est considéré comme une voie prometteuse pour contrôler la fabrication de nouveaux matériaux et leur intégration dans des dispositifs hybrides présentant de propriétés nouvelles. Dans ce travail, nous avons synthétisé plusieurs hybrides à base de molécules organiques (fullerène, porphyrines, phtalocyanine), d’oligonucléotides ou de nanotubes de carbone.Dans un premier temps, nous nous sommes intéressés à la synthèse d’une nouvelle famille de produits constituée d’une unité C60 lié à deux chromophores positionnés face à face et permetta

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20

Guerra, Roberto, Andrea Benassi, Andrea Vanossi, Ming Ma, and Michael Urbakh. "Friction and adhesion mediated by supramolecular host–guest complexes." Royal Society of Chemistry, 2016. https://tud.qucosa.de/id/qucosa%3A36377.

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The adhesive and frictional response of an AFM tip connected to a substrate through supramolecular host–guest complexes is investigated by dynamic Monte Carlo simulations. Here, the variation of the pull-off force with the unloading rate recently observed in experiments is unraveled by evidencing simultaneous (progressive) breaking of the bonds at fast (slow) rates. The model reveals the origin of the observed plateaus in the retraction force as a function of the tip-surface distance, showing that they result from the tip geometrical features. In lateral sliding, the model exhibits a wide rang

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21

Gong, Jiachang. "Biomimetics and host-guest chemistry." ScholarWorks@UNO, 2004. http://louisdl.louislibraries.org/u?/NOD,186.

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Thesis (Ph. D.)--University of New Orleans, 2004.<br>Title from electronic submission form. "A dissertation ... in partial fulfillment of the requirements for the degree of Doctor of Philosophy in the Department of Chemistry."--Dissertation t.p. Vita. Includes bibliographical references.

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22

Bezuidenhout, Charl Xavier. "Polar ordering of guest molecules in host-guest inclusion complexes." Thesis, Stellenbosch : Stellenbosch University, 2011. http://hdl.handle.net/10019.1/18107.

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Thesis (MSc)--Stellenbosch University, 2011.<br>ENGLISH ABSTRACT: 2,7-dimethylocta-3,5-diyne-2,7-diol forms inclusion complexes with various guests molecules, where the guest molecules are polar-ordered. A Cambridge Structural Database (CSD) search revealed ten inclusion complexes where the guest molecules were polar-ordered. Using Density Functional Theory (DFT) computational methods (in the absence of the host), we evaluated the intra-channel and lateral guest-guest interactions between the guest molecules. Two polar-ordered inclusion complexes ((1,4,7-cyclohexane-1,2,4,5,7,8-hexaoxonane)·C

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23

Sebogisi, Baganetsi Karabo. "Separation of racemates via host-guest chemistry." Thesis, Cape Peninsula University of Technology, 2012. http://hdl.handle.net/20.500.11838/730.

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Thesis submitted in fulfilment of the requirements for the degree Magister Technologiae: Chemistry in the Faculty of Applied Science at the CAPE PENINSULA UNIVERSITY OF TECHNOLOGY 2012<br>Chirality is very important to the pharmaceutical industry as enantiomers have the same macroproperties except for their optical and pharmacological activity. Industrial research has thus focused to find the most effective resolution technique. However, our aim was to obtain more information regarding the discrimination process. In this project the structures of the hydrates of di-quininium L-malate, (2QUIN+)

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24

Tangouna, Liambo Bissa Marie-Louise. "Host-guest compounds : structure and thermal behaviour." Thesis, Cape Peninsula University of Technology, 2016. http://hdl.handle.net/20.500.11838/2442.

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Thesis (MTech (Chemistry))--Cape Peninsula University of Technology, 2016.<br>Inclusion compounds of two hydroxyl hosts with a variety of guests have been investigated. These host compounds are bulky molecules and have the ability to interact with smaller organic guests to form new compounds. The host 9-(1-naphthyl)-9H-xanthen-9-ol (H1), forms inclusion compounds with pyridine (PYR), N,N-dimethylacetamide (DMA), morpholine (MORP) and N-methyl-2-pyrrolidinone (NMP). The crystal structures of H1•NMP, H1•DMA and H1•MORP1 were successfully solved in the triclinic space group PĪ, whereas the inclus

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25

Clare, John P. "Cholapods as selective anion receptors : measuring high association constants and exploring host-guest selectivity." Thesis, University of Bristol, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.289557.

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26

Jin, Ping Atwood J. L. "Synthesis of mixed metal-organic pyrogallol[4]arene nanocapsules and their host-guest chemistry." Diss., Columbia, Mo. : University of Missouri--Columbia, 2009. http://hdl.handle.net/10355/6874.

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Title from PDF of title page (University of Missouri--Columbia, viewed on Feb 24, 2010). The entire thesis text is included in the research.pdf file; the official abstract appears in the short.pdf file; a non-technical public abstract appears in the public.pdf file. Dissertation advisor: Dr. Jerry L. Atwood. Vita. Includes bibliographical references.

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27

Goehry, Charles. "Computational studies on host-guest catalysis." Doctoral thesis, Universitat Rovira i Virgili, 2014. http://hdl.handle.net/10803/283265.

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La química supramolecular és la química dels enllaços no covalents. L'objectiu dels investigadors en aquest camp és entendre i predir el comportament i la interacció dels acoblaments de grans dimensions moleculars. Aquest treball se centra en l'estudi de dos sistemes supermoleculars independents que promouen una reacció clic en el seu nucli. Aquests sistemes són: un cucurbit[6]uril macrocicle i un calixerè autocomplementari que s'acobla en una càpsula. Presenten un gran espai intern capaç d'atrapar espècies reactives. El principal efecte de l'agregació és l'eliminació parcial de constriccio

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28

Chretien, Michelle N. "Photochemical, photophysical, and photobiological studies of zeolite guest-host complexes." Thesis, University of Ottawa (Canada), 2005. http://hdl.handle.net/10393/29205.

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This thesis focuses on the photochemistry and photophysics of a variety of zeolite complexes, from catalysts to sunscreens. The first chapter describes the preparation and photophysical and photochemical characterization of two new photocatalytic materials. The catalysts are based on a multi-component zeolite, host-guest complex and the interaction between components was probed using time-resolved spectroscopic techniques. The catalytic efficiency, in terms of the ability to photodegrade biological contaminants, was also investigated. These studies were performed with the aim of developing eff

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29

García, Simón Cristina. "Synthesis of molecular nanocapsules for supramolecular host-guest chemistry and enzyme-like catalysis." Doctoral thesis, Universitat de Girona, 2015. http://hdl.handle.net/10803/289567.

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Coordination-driven self-assembly has led to the realization of an increasing number of elegant and sophisticated functional structures, the structural complexity of which would be difficult to achieve using conventional covalent chemistry. The synthesis of three-dimensional coordination capsule-like structures is of particular interest due to their multiple potential applications, particularly their use in selective molecular recognition (host-guest chemistry), reactivity modulation (nanoreactors), molecular sensors or biological applications. The main goal of this doctoral thesis, performed

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30

Streb, Carsten. "Functional polyoxometalate assemblies : from host-guest complexes to porous frameworks." Thesis, University of Glasgow, 2008. http://theses.gla.ac.uk/120/.

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The host-guest chemistry of two sets of isopolyoxometalate clusters is investigated. In particular the binding modes of cationic alkali and alkali earth metals through coordinative interactions with the cluster anions {Mo36} and {W36} were compared and contrasted. It was shown that the ionic radii of the cations are crucial in the isolation of discrete molecules or infinite 3D frameworks. Crystal engineering allowed the introduction of organic amine guest molecules by the formation of a set of intermolecular interactions between the cluster anions and the amine cations. In addition it was show

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31

Meng, Wenjing. "Metal-organic polyhedra : subcomponent self-assembly, structural properties, host-guest behavior and system chemistry." Thesis, University of Cambridge, 2012. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.610719.

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32

White, Tim Chemistry Australian Defence Force Academy UNSW. "Supramolecular chemistry and synthesis of Cucurbit[n]uril." Awarded by:University of New South Wales - Australian Defence Force Academy. School of Chemistry, 2003. http://handle.unsw.edu.au/1959.4/38643.

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The recently discovered cucurbit[n]uril are a range of macrocyclic hosts which have enormous potential in industrial, medical and academic applications. Cucurbit[n]uril have a rigid repeating structure of methylene bridged glycouril, which give cucurbit[n]uril their gourd like shape of a cavity with two carbonyl fringed portals. In this thesis the host-guest binding abilities of three cucurbit[n]uril (n = 6, 7, 8) have been examined for a range of potential guests. These guests ranged from simple alkyl amines through globular alkyl and carboranyl amines to bipyridyl systems. In total 45 g

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33

Flack, Stephen Sean. "Studies towards synthetic receptors for small peptides and sugars." Thesis, University of Southampton, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.261284.

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34

Moncelsi, Giulia. "Stimuli-responsive host-guest systems decorated with hemithioindigo and spiropyran units." Doctoral thesis, Universitat Rovira i Virgili, 2019. http://hdl.handle.net/10803/668163.

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L’objectiu del treball de recerca d’aquesta tesis doctoral és el disseny i síntesis de contenidors moleculars que responguin a estímuls externs mitjançant la incorporació d’unitats foto-isomeritzables (photoswitchable units (PUs) en anglès) a les estructures tant del receptor com de la molècula reconeguda. S’han utilitzat dos tipus de PUs amb propietats diferenciades, hemitioindigos i espiropirans, incorporats a dos tipus de macrocicles, calix[4]arè i calix[4]pirrole. S’ha estudiat la isomerització de les PUs mitjançant la irradiació amb llum i el tractament àcid-base així com l’efecte d’aques

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35

Chopade, Prashant D. "From supramolecular selectivity to nanocapsules." Diss., Kansas State University, 2012. http://hdl.handle.net/2097/13529.

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Doctor of Philosophy<br>Department of Chemistry<br>Christer B. Aakeroy<br>A family of three 2-aminopyrazine derivatives were prepared and co-crystallized with thirty carboxylic acids. Our theoretical charge calculations and experimental results from 90 reactions demonstrated that decreasing the charge on the hydrogen-bond acceptor sites results in a decrease of the supramolecular yield (the frequency of occurrence of the desired outcome). However, synthon crossover (undesired connectivity) was observed 7/12 times and was unavoidable due to competitive binding sites present in the N-heterocycli

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36

Liu, Chenyan. "Hierarchical supramolecular assemblies based on host-guest chemistry between cucurbit[n]uril and azobenzene derivatives." Thesis, University of Cambridge, 2019. https://www.repository.cam.ac.uk/handle/1810/289435.

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Cucurbit[8]uril (CB[8]) has attracted great interest in the cucurbit[n]uril (CB[\textit{n}]) family on account of its capability to simultaneously accommodate two guests inside its cavity, to form strong yet dynamic ternary complexes. Owing to the photo-induced \textit{trans} to \textit{cis} isomerisation property, azobenzene (Azo) derivatives have been widely employed in several host-guest systems, leading to various light-responsive materials. This thesis focuses on CB[8]-based ternary complexes, especially those involving Azo derivatives. These systems can be exploited as a platform to hier

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Gil, Ramírez Guzmán. "Supramolecular chemistry of aryl extended calix [4] pyrroles." Doctoral thesis, Universitat Rovira i Virgili, 2009. http://hdl.handle.net/10803/9038.

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La presente tesis consta de dos vertientes interrelacionadas. La primera se centra en intentar cuantificar experimentalmente la contribución energética en disolución de la interacción anión-, mediante el uso de calix[4]pirroles aril substituidos en las posiciones meso- como moléculas modelo. El trabajo realizado muestra que la interacción anión- es repulsiva para anillos con valores de ESP negativos y a medida que el efecto electrón atrayente de los sustituyentes aumenta la interacción se vuelve menos repulsiva, hasta que, cuando el valor de ESP en el centro del anillo aromátic

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38

Rizzuto, Felix. "Allosteric interactions in coordination cages." Thesis, University of Cambridge, 2018. https://www.repository.cam.ac.uk/handle/1810/278963.

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Biomolecular receptors can catalyse reactions, alter their geometry, and inhibit their activity in response to molecules binding around their periphery. Synthetic receptors that can mimic this allosteric binding behaviour extend the potential applications of host-guest chemistry to programmable molecular systems. Modulating the degree and magnitude of interaction between components within these systems enables the design of chemical behaviour akin to biological complexity. With a view to developing artificial guest-binding regulation systems, a series of metal-organic cages capable of both the

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39

O'Brien, Mark. "Spectroscopic Studies of Inclusion Host-Guest Complexes Between Cyclophane Corrals and Polcyclic Aromatic Hydrocarbons." TopSCHOLAR®, 2005. http://digitalcommons.wku.edu/theses/470.

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Cyclophanes are macromolecules that are known to effectively bind with molecules to form host-guest complexes. Several cyclophane molecules, referred to as corrals (1-6) by their founders, have been synthesized. The characterization of these compounds and their complexes has been investigated using combined spectroscopic and theoretical methods. Hostguest interactions of cyclophane-anthracene (C-A), cyclophane-9-fluorenone (C-F) and cyclophane-pyrene (C-P) complex systems in dichloromethane are presented in this thesis. The stability constants, log Ka, for the C-A, C-F and C-P complexes are de

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40

Wahl, Helene. "Development of novel supramolecular framework materials based on organic salts." Thesis, Stellenbosch : Stellenbosch University, 2014. http://hdl.handle.net/10019.1/95858.

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Thesis (PhD)--Stellenbosch University, 2014.<br>ENGLISH ABSTRACT: The aim of the work presented in this thesis was to design ionic organic framework materials based on carboxylate salts with the intention of engineering interesting properties, such as porosity, into these framework materials. The first section focuses on the characterisation and porosity studies of an ionic framework material, 3,4-lutidinium pamoate hemihydrate, with THF-filled channels in the solid state. It was shown that this framework is able to exchange the THF in the channels for a wide variety of compounds, with many o

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41

Holman, K. Travis. "The host-guest chemistry of new members in the cyclotriveratrylene family of cavitands /." free to MU campus, to others for purchase, 1998. http://wwwlib.umi.com/cr/mo/fullcit?p9924887.

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42

Rieth, Stephen E. "An Investigation into the Effects of Gating in Artificial Host Systems." The Ohio State University, 2011. http://rave.ohiolink.edu/etdc/view?acc_num=osu1308098752.

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43

Zhenhui, Qi [Verfasser]. "Macrocycle functionalized supramolecular gels and the host-guest chemistry of dendrimers in the gas phase / Qi Zhenhui." Berlin : Freie Universität Berlin, 2013. http://d-nb.info/1036872556/34.

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44

Lam, Ho-chuen, and 林浩銓. "Design, synthesis and host-guest chemistry of rhodamine derivatives and their transition metal complexes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2012. http://hdl.handle.net/10722/198806.

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New classes of luminescent transition metal complexes, including the systems of rhenium(I) tricarbonyl diimine, cyclometalated iridium(III) diimine, cyclometalated rhodium(III) diimine, ruthenium(II) diimine and ruthenium(II) terpyridine complexes tethered with rhodamine moieties, have been synthesized. The X-ray crystal structure of one of the cyclometalated rhodium(III) diimine complexes with rhodamine pendants, [Rh(SPLC2N2)(ppy)2](PF6) has been determined. The molecular structure of [Rh(SPLC2N2)(ppy)2](PF6) showed a distorted octahedral geometry and the rhodamine moiety was found in a spiro

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Versäumer, Marina. "Supramolecular coordination cages based on bispyridyl-ligands with redox properties." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2016. http://hdl.handle.net/11858/00-1735-0000-002B-7C2F-E.

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Groom, Jazerie J. "Evaluation of Apparent Formation Constants of Host-Guest Inclusion Complexes of Solutes with Soluble Calixarenes Using High Performance Liquid Chromatography." Youngstown State University / OhioLINK, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=ysu1389273191.

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裴雍蓮 and Yung-lin Pui. "Syntheses, luminescence studies and host-guest chemistry of d10 and d6metal complexes containing diimine and/or chalcogenolate ligand." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2000. http://hub.hku.hk/bib/B43894367.

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Laughery, Zachary. "Synthesis of Molecular Baskets and Introduction of Inward Facing Functionality." ScholarWorks@UNO, 2006. http://scholarworks.uno.edu/td/328.

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As a first step to producing a shape selective catalysts or enzyme mimic, two preorganized host molecules were synthesized. Binding studies of the two hosts with a variety of guests in three solvents demonstrated that an important driving force in the association was the formation of C-H???X-R hydrogen bonds (X = halogen). A deuterated host was utilized to further examine the formation of the C-H???X-R hydrogen bonds. In an effort to place functionality in the hydrophobic pocket of these hosts, two methods were developed. The first utilized directed ortho metallation to place electrophiles abo

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Blom, Magnus. "Light-Triggered Conformational Switches for Modulation of Molecular Recognition : Applications for Peptidomimetics and Supramolecular Systems." Doctoral thesis, Uppsala universitet, Syntetisk organisk kemi, 2015. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-267845.

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The main focus of this thesis is on photochemical modulation of molecular recognition in various host-guest systems. This involves the design, synthesis and integration of light-triggered conformational switches into peptidomimetic guests and molecular tweezer hosts. The impact of the switches on guest and host structures has been assessed by spectroscopic and computational conformational analysis. Effects of photochemical structure modulation on molecular recognition in protein-ligand and supramolecular host-guest systems are discussed. Phototriggerable peptidomimetic inhibitors of the enzyme

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McCune, Jade Alexis. "Functionalisation of cucurbit[n]uril and exploring deep eutectic solvents as a medium for supramolecular chemistry." Thesis, University of Cambridge, 2018. https://www.repository.cam.ac.uk/handle/1810/278225.

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