Academic literature on the topic 'Suzuki-Miyaura reaction'

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Journal articles on the topic "Suzuki-Miyaura reaction"

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Akkarasamiyo, Sunisa, Somsak Ruchirawat, Poonsaksi Ploypradith та Joseph S. M. Samec. "Transition-Metal-Catalyzed Suzuki–Miyaura-Type Cross-Coupling Reactions of π-Activated Alcohols". Synthesis 52, № 05 (2020): 645–59. http://dx.doi.org/10.1055/s-0039-1690740.

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The Suzuki–Miyaura reaction is one of the most powerful tools for the formation of carbon–carbon bonds in organic synthesis. The utilization of alcohols in this powerful reaction is a challenging task. This short review covers progress in the transition-metal-catalyzed Suzuki­–Miyaura-type cross-coupling reaction of π-activated alcohol, such as aryl, benzylic, allylic, propargylic and allenic alcohols, between 2000 and June 2019.1 Introduction2 Suzuki–Miyaura Cross-Coupling Reactions of Aryl Alcohols2.1 One-Pot Reactions with Pre-activation of the C–O Bond2.1.1 Palladium Catalysis2.1.2 Nickel
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Bhatt, Nikita, Smriti, Richa Khare, and Monika Kamboj. "Suzuki-Miyaura Cross Coupling Reaction in Various Green Media." Asian Journal of Chemistry 33, no. 9 (2021): 1976–84. http://dx.doi.org/10.14233/ajchem.2021.22584.

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Suzuki-Miyaura cross-coupling reaction is an efficient and utilized method for the direct formation of carbon-carbon bonds. The effectiveness and efficiency of Suzuki-Miyaura cross-coupling reaction and its applications have been the topic of interest for synthetic chemists for the last few decades. Green chemistry is the area where we use eco-friendly products. Suzuki coupling includes palladium or nickel catalyzed coupling reaction, which involves ester of boric acids or simply boric acids with the organic halides or pseudohalide. In recent years, these catalytic systems have been developed
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Snieckus, Victor, and Claude Quesnelle. "The Directed ortho Metalation (DoM)–Cross-Coupling Connection: Synthesis of Polyfunctional Biaryls." Synthesis 50, no. 22 (2018): 4413–28. http://dx.doi.org/10.1055/s-0037-1610273.

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A comparative evaluation of the combined directed ortho metalation (DoM)–Suzuki–Miyaura and DoM–Negishi cross-coupling reactions with aryl triflates for the synthesis of substituted biaryls is described. Both ortho-zinc and ortho-boron aryl directed metalation group (DMG = CON(i-Pr)2, OCONEt2, OMOM, NHBoc) substrates were evaluated. The superiority of the DoM–Negishi over the DoM–Suzuki–Miyaura reaction in operational convenience and mild reaction conditions is noted. Orthogonal Negishi and Suzuki–Miyaura with Corriu–Kumada reactions for the synthesis of a teraryl derivative is also reported.
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Boruah, Preeti Rekha, Abdul Aziz Ali, Bishwajit Saikia, and Diganta Sarma. "A novel green protocol for ligand free Suzuki–Miyaura cross-coupling reactions in WEB at room temperature." Green Chemistry 17, no. 3 (2015): 1442–45. http://dx.doi.org/10.1039/c4gc02522a.

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A highly efficient green protocol for palladium acetate-catalysed ligand-free Suzuki–Miyaura cross-coupling reactions in neat ‘water extract of banana (WEB)’ was developed. Suzuki–Miyaura reaction proceeds in WEB at very short reaction times under ‘ligand/external base/external promoters/organic medium’ free conditions.
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Çakır, Sinem, Serdar Batıkan Kavukcu, Hande Karabıyık, Senthil Rethinam, and Hayati Türkmen. "C(acyl)–C(sp2) and C(sp2)–C(sp2) Suzuki–Miyaura cross-coupling reactions using nitrile-functionalized NHC palladium complexes." RSC Advances 11, no. 60 (2021): 37684–99. http://dx.doi.org/10.1039/d1ra07231e.

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Nitrile-functionalized Pd(ii) complexes have evaluated for the Suzuki–Miyaura cross-coupling reactions. The highest TON value was reached for the acylative Suzuki–Miyaura cross-coupling reaction of acyl chlorides with phenylboronic acids.
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Khabiyev, A. T., and B. S. Selenova. "Palladium(II)-catalyzed Suzuki–Miyaura Reactions of Arylboronic Acid with Aryl Halide in the Presence of Aryl-Ferrocenyl-Phosphines." Eurasian Chemico-Technological Journal 16, no. 1 (2013): 79. http://dx.doi.org/10.18321/ectj172.

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<p>This study examined investigation of catalytic activity of aryl-ferrocenyl-phosphine (2-methoxyphenyl diferrocenyl phosphine (cat. 1), 2-tert-butyloxyphenyl diferrocenyl phosphine (cat. 2), 2-methoxynaphtyl diferrocenyl phosphine (cat. 3), 1,1’-bis(diphenylphosphino) ferrocene (cat. 4), phenyl diferrocenyl phosphine (cat. 5)) ligands with palladium salts as precursors in Suzuki–Miyaura reaction. Suzuki–Miyaura reaction is one of the important cross-coupling reactions and extremely powerful in forming C–C bonds. Aryl-ferrocenyl-phosphine ligands confer unprecedented activity for these
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Pruschinski, Lucas, Ana-Luiza Lücke, Tyll Freese, Sean-Ray Kahnert, Sebastian Mummel, and Andreas Schmidt. "Suzuki–Miyaura Cross-Couplings under Acidic Conditions." Synthesis 52, no. 06 (2019): 882–92. http://dx.doi.org/10.1055/s-0039-1691487.

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Suzuki–Miyaura reactions with Pd(PPh3)4 have been carried out using lithium N-phenylsydnone-4-carboxylate as additive, which gave best yields at pH 5.7 in a mixture of acetic acid, water, and sodium carbonate. Reaction parameters such as the Pd source, the solvent, reaction time and temperature, acid, base and carboxylate have been varied and some representative examples of the Suzuki–Miyaura reaction have been examined.
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Vaaland, Ingrid Caroline, and Magne Olav Sydnes. "Consecutive Palladium Catalyzed Reactions in One-Pot Reactions." Mini-Reviews in Organic Chemistry 17, no. 5 (2020): 559–69. http://dx.doi.org/10.2174/1570193x16666190716150048.

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Combining palladium catalyzed reactions in one-pot reactions represents an efficient and economical use of catalyst. The Suzuki-Miyaura cross-coupling has been proven to be a reaction which can be combined with other palladium catalyzed reactions in the same pot. This mini-review will highlight some of the latest examples where Suzuki-Miyaura cross-coupling reactions have been combined with other palladium catalyzed reactions in one-pot reaction. Predominantly, examples with homogeneous reaction conditions will be discussed in addition to a few examples from the authors where Pd/C have been us
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Len, Christophe. "Catalysts for Suzuki–Miyaura Coupling Reaction." Catalysts 10, no. 1 (2020): 50. http://dx.doi.org/10.3390/catal10010050.

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Sharif, Muhammad, Khurram Shoaib, Shahzad Ahmed, et al. "Synthesis of functionalised fluorinated pyridine derivatives by site-selective Suzuki-Miyaura cross-coupling reactions of halogenated pyridines." Zeitschrift für Naturforschung B 72, no. 4 (2017): 263–79. http://dx.doi.org/10.1515/znb-2016-0213.

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AbstractThe Suzuki-Miyaura reaction of 2,6-dichloro-3-(trifluoromethyl)pyridine with 1 equiv of arylboronic acids resulted in site-selective formation of 2-aryl-6-chloro-3-(trifluoromethyl)pyridine. Due to electronic reasons, the reaction takes place at the sterically more hindered position. The selectivity was rationalised by DFT calculations. The one-pot reaction with two different arylboronic acids afforded 2,6-diaryl-3-(trifluoromethyl)pyridine containing two different aryl substituents. The reactions proceeded smoothly in the absence of phosphine ligands. In addition, Suzuki-Miyaura react
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Dissertations / Theses on the topic "Suzuki-Miyaura reaction"

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Hashimoto, Toru. "Development of Iron-Catalyzed Suzuki-Miyaura Coupling Reaction." 京都大学 (Kyoto University), 2012. http://hdl.handle.net/2433/159407.

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Geogheghan, Katherine Jayne. "Boronic acid speciation in Suzuki-Miyaura cross-coupling." Thesis, University of Edinburgh, 2018. http://hdl.handle.net/1842/33092.

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Since its discovery in 1979, the Suzuki-Miyaura (SM) reaction has become one of the most widely utilised tools for carbon-carbon bond formation. The palladium catalysed coupling of an organoboron and organohalide compounds proceeds through a three-stage mechanism of oxidative addition, transmetalation and reductive elimination. The transmetalation of boronic acids to a palladium(II) complex has been widely studied. However, very little is known about the transmetalation of boronic esters, which are commonly used as an alternative to unstable boronic acids. Whether these species undergo direct
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Bourouina, Amine. "Desperately Seeking For The Catalytic Species In Suzuki-Miyaura Reaction." Thesis, Lyon, 2019. http://www.theses.fr/2019LYSE1258.

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L’état de l’art montre que l’utilisation de Pd supporté sans ligand est une idée séduisante car elle permet d’éviter les problèmes liés à la présence des ligands potentiellement coûteux et toxiques, et également de récupérer plus facilement le catalyseur en fin de réaction. Ainsi, il est plus aisé de respecter la réglementation fixant la teneur maximale de Pd dans les principes actifs pharmaceutiques (IPA) à une concentration inférieure à 10 ppm. Cependant, la présence des espèces (moléculaires ou nanoparticules) de Pd en solution lors de l’utilisation de catalyseurs solides a créé un débat im
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Payard, Pierre-Adrien. "Mechanistic studies of metal-catalyzed reactions : predicting tools for reaction optimization." Thesis, Paris Sciences et Lettres (ComUE), 2019. http://www.theses.fr/2019PSLEE009/document.

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Cette thèse est consacrée à l’étude de mécanismes de réactions catalysées par des métaux ainsi qu’au développement de nouveaux outils pour la rationalisation et la prévision du comportement catalytique. L’étape de transmétallation entre le bore et le nickel a été étudiée en détail à l’aide de méthodes expérimentales variées (electrochimie, RMN, cinétiques) et par DFT, permettant d’expliquer certaines limitations rencontrées par les experimentateurs. La seconde partie de cette thèse est dédiée à la rationalisation du comportement d’une famille d’acides de Lewis : les sels de triflate et de trif
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Lobrégat, Virginie. "Immobilisation d'organobores sur resines ioniques et reaction multi-composants pour la synthese de macrocycles par couplage de suzuki-miyaura." Rennes 1, 2000. http://www.theses.fr/2000REN10063.

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Ce memoire traite de l'immobilisation d'organobores sur des resines ioniques et de l'utilisation de reactions multi-composants pour la synthese de macrocycles par couplage de suzuki-miyaura decrochant. Dans un premier temps, des acides aryl et vinylboroniques ont ete quaternarises et immobilises sur des resines ioniques de type dowex a contre ion hydroxyle, sous la forme de borates effectuant l'etape de transmetallation dans le couplage de suzuki-miyaura. Le greffage peut etre controle par rmn 1 1b et 1 3c dans des conditions standard. Les supports reactifs ont ete engages dans des couplages d
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Peramo, Arnaud. "Modification sélective de protéines en milieu biologique par réaction de Suzuki-Miyaura nanocatalysée PLGA-PEG-supported Pd nanoparticles as efficient catalysts for Suzuki-Miyaura coupling reactions in water Selective modification of a native protein in a patient tissue homogenate using palladium nanoparticles A Self-Assembling Palladium-Loaded Calixarene as a Potent Catalyst for the Suzuki-Miyaura Cross-coupling Reaction in Water." Thesis, Université Paris-Saclay (ComUE), 2019. http://www.theses.fr/2019SACLS600.

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Les nanotechnologies ont ouvert de nouvelles perspectives pour l’administration ciblée des médicaments. Les approches actuelles en nanomédecine sont basées sur l’encapsulation d’un principe actif dans un nano-vecteur. Nous proposons dans ce travail l’utilisation de nanoparticules non plus pour adresser un médicament encapsulé vers sa cible, mais pour manipuler une protéine d’intérêt en milieu biologique, ce qui constitue une nouvelle stratégie thérapeutique. Avec cet objectif, nous avons identifié une formulation de nanoparticules de palladium, stable, non toxique et dotée d’un pouvoir catalyt
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Alrawashdeh, Albara I. S. "From Mono- to Tetraphosphines – A Contribution to the Development of Improved Palladium Based Catalysts for Suzuki- Miyaura Cross Coupling Reaction." Doctoral thesis, Universitätsbibliothek Chemnitz, 2011. http://nbn-resolving.de/urn:nbn:de:bsz:ch1-qucosa-80110.

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Im ersten Teil der Arbeit wird die Synthese neopentyl- und neosilylsubstituierter Phosphane zur Verwendung als Liganden in katalytisch aktiven Palladiumkomplexen beschrieben. Die Aktivität wurde in der Suzuki-Miyaura Kreuzkupplungsreaktion getestet. Während die neosilylsubstituierten Phosphane 2:1 Addukte (5b und 5d) mit geeigneten Palladiumsalzen bilden, welche moderate Katalyseaktivität zeigen, untergehen die neopentylsubstituierten Komplexe schnelle Cyclometalierungsreaktionen in Gegenwart von Basen und bilden die katalytisch wenig aktiven Palladacyclen (6a, 6e, and 6g). Die deaktivierende
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Green, Anthony Laine. "The Directed ortho Metalation of pyridine derivatives with in situ boronation and links to the Suzuki-Miyaura cross coupling reaction." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 2001. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp04/MQ63310.pdf.

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Balanta, Castillo Angelica. "Novel molecular and colloidal catalysts for c-c bond formation processes." Doctoral thesis, Universitat Rovira i Virgili, 2011. http://hdl.handle.net/10803/66243.

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Esta tesis doctoral se centró en la síntesis y la caracterización de nanopartículas metálicas (Pd, Ni, Pt) estabilizadas por varios tipos de ligandos y el uso de estas nanopartículas en reacciones de formación de nuevos C-C o C-heteroatomo: a) Reacción de substitución alílica catalizadas por Pd; b) Reacción de acoplamiento asimétrico de Suzuki-Miyaura; c) Reacción de acoplamiento de Suzuki-Miyaura; d) reacción de adición 1,4 de ácidos borónicos a cetonas. En cada una de estas reacciones se llevó a cabo la síntesis y caracterización de nanoparticulas metálica y complejos moleculares usando muc
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Cerezo, Frias Vanessa. "Síntesi de base sòlida de pèptids biarílics contenint 5-arilhistidines." Doctoral thesis, Universitat de Girona, 2009. http://hdl.handle.net/10803/8054.

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Els aminoàcids biarílics es troben en una àmplia varietat de pèptids naturals amb important activitat biològica. Concretament, les arilhistidines formen part de les aciculitines, pèptids amb activitat citotòxica i antifúngica, La reacció de Suzuki-Miyaura és el mètode més versàtil per obtenir biarils assimètrics, encara que, fins el moment, no s'havia aplicat per a l'arilació de l'imidazole de la histidina. L'objectiu general d'aquesta tesi fou demostrar que es podia arilar l'imidazole de la histidina en fase sòlida mitjançant una reacció de Suzuki-Miyaura. En primer lloc, es sintetitzaren 4(5
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Books on the topic "Suzuki-Miyaura reaction"

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Suzuki–Miyaura Cross-Coupling Reaction and Potential Applications. MDPI, 2017. http://dx.doi.org/10.3390/books978-3-03842-557-1.

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Book chapters on the topic "Suzuki-Miyaura reaction"

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Valente, Cory, and Michael G. Organ. "The Contemporary Suzuki-Miyaura Reaction." In Boronic Acids. Wiley-VCH Verlag GmbH & Co. KGaA, 2011. http://dx.doi.org/10.1002/9783527639328.ch4.

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García Melchor, Max. "An Asymmetric Suzuki-Miyaura Reaction Mechanism." In A Theoretical Study of Pd-Catalyzed C-C Cross-Coupling Reactions. Springer International Publishing, 2013. http://dx.doi.org/10.1007/978-3-319-01490-6_6.

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Oishi, Tohru. "A Long Journey Toward Structure Revision and Total Synthesis of Amphidinol 3." In Modern Natural Product Synthesis. Springer Nature Singapore, 2024. http://dx.doi.org/10.1007/978-981-97-1619-7_3.

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AbstractAmphidinol 3 (AM3) is a super-carbon-chain compound isolated from the dinoflagellate Amphidinium klebsii. Although the absolute configuration of AM3 was determined in 1999 by instrumental analysis in combination with degradation of the natural product, it was a daunting task because of its limited availability from natural sources and presence of around 70% of chiral centers on the acyclic carbon chain. During the course of our synthetic studies of AM3, the originally proposed structure was revised, which was confirmed by the first total synthesis of AM3 in 2020, more than 20 years sin
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Seo, Tamae. "Solid-State Suzuki–Miyaura Cross-Coupling Reaction Using Mechanochemistry." In Palladium-Catalyzed Mechanochemical Cross-Coupling Reactions. Springer Nature Singapore, 2024. http://dx.doi.org/10.1007/978-981-97-1991-4_3.

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Roy, Moumita, Pravin R. Likhar, and M. Lakshmi Kantam. "Polyaniline-Immobilized Palladium for Suzuki-Miyaura Coupling Reaction in Water." In Solid-Phase Organic Syntheses. John Wiley & Sons, Inc., 2012. http://dx.doi.org/10.1002/9781118336953.ch9.

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Sun, Ho-Yan, and Dennis G. Hall. "At the Forefront of the Suzuki–Miyaura Reaction: Advances in Stereoselective Cross-Couplings." In Synthesis and Application of Organoboron Compounds. Springer International Publishing, 2015. http://dx.doi.org/10.1007/978-3-319-13054-5_7.

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Glegola, Katarzyna, and Eric Framery. "Synthesis of Polymer-Supported Aryldicyclohexylphosphine for an Efficient Recycling in Suzuki-Miyaura Reaction." In Solid-Phase Organic Syntheses. John Wiley & Sons, Inc., 2012. http://dx.doi.org/10.1002/9781118336953.ch10.

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Li, Jie Jack. "Suzuki–Miyaura coupling." In Name Reactions. Springer International Publishing, 2014. http://dx.doi.org/10.1007/978-3-319-03979-4_269.

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Li, Jie Jack. "Suzuki–Miyaura coupling." In Name Reactions. Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-642-01053-8_250.

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Li, Jie Jack. "Suzuki–Miyaura Coupling." In Name Reactions. Springer International Publishing, 2021. http://dx.doi.org/10.1007/978-3-030-50865-4_147.

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Conference papers on the topic "Suzuki-Miyaura reaction"

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Lee, Tae-Kyung, Bikashý Manandhar, and Jung-Mo Ahn. "Peptide Ligation via Suzuki-Miyaura Cross-Coupling Reaction." In The 24th American Peptide Symposium. Prompt Scientific Publishing, 2015. http://dx.doi.org/10.17952/24aps.2015.268.

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Bayar, İrem, and Senem Akkoc. "Catalysis of NHC–Pd Complexes in the Suzuki–Miyaura Cross-Coupling Reaction." In International Electronic Conference on Processes. MDPI, 2024. http://dx.doi.org/10.3390/proceedings2024105007.

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Castro, Kelly Leite dos Santos, Rodrigo Octavio Mendonça Alves de Souza, and Leandro Soter de Mariz e. Miranda. "Ionic liquids derived from pyridine and their application in Suzuki-Miyaura reaction under microwave irradiation." In 14th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-14bmos-r0098-2.

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Lucio Martinez, Fatima, Adofo Fernández-Figueiras, Francisco Reigosa, et al. "Synthesis and catalytic study in the Suzuki-Miyaura reaction of a family of palladium compounds." In The 21st International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2017. http://dx.doi.org/10.3390/ecsoc-21-04754.

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Munín-Cruz, Paula, Marcos Rúa-Sueiro, Juan Manuel Ortigueira, María Teresa Pereira, and José Manuel Vila. "Study on the Effect of the Ligand Structure in Palladium Organometallic Catalysts in the Suzuki–Miyaura Cross-Coupling Reaction." In ECSOC-25. MDPI, 2021. http://dx.doi.org/10.3390/ecsoc-25-11730.

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Saha, Pritam. "Zinc aluminate (ZnAl2O4) supported and catalyzed highly effective Suzuki–Miyaura cross-coupling reaction under microwave irradiation: Application to fused tricyclic oxa-aza-quinoline." In PROCEEDINGS OF THE 11TH INTERNATIONAL ADVANCES IN APPLIED PHYSICS AND MATERIALS SCIENCE CONGRESS & EXHIBITION. AIP Publishing, 2023. http://dx.doi.org/10.1063/5.0139059.

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"Convenient and Efficient Suzuki Miyaura Coupling Reactions of Meso-Halogenated BODIPYs." In Chemical technology and engineering. Lviv Polytechnic National University, 2021. http://dx.doi.org/10.23939/cte2021.01.184.

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Silva, Aires da Conceição, Jaqueline D. Senra, Lúcia C. S. Aguiar, Alessandro B. C. Simas, Andréa Luzia F. de Souza, and Luiz Fernando B. Malta. "Room-temperature Suzuki-Miyaura reactions mediated by native and derivatized b−cyclodextrins." In 14th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-14bmos-r0021-1.

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Thiemann, Thies, and Kyoko Yamamoto. "Suzuki-Miyaura cross-coupling and Heck reactions catalysed by Pd on carbon nanofibres." In The 13th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2009. http://dx.doi.org/10.3390/ecsoc-13-00173.

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Thiemann, Thies, Christian Burmester, Kodai Shiine, and Shuntaro Mataka. "From Suzuki-Miyaura cross coupling reactions of 2-bromo- and 4-bromoestranes to fluorinated benzofuranoestranes." In The 17th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2013. http://dx.doi.org/10.3390/ecsoc-17-a028.

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