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Dissertations / Theses on the topic 'Synthetic host-guest chemistry'

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Published: 4 June 2021

Last updated: 6 February 2022

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1

Ng, Joe Cho Yan. "Host-guest chemistry : physicochemical aspects of cyclodextrin-drug and lithium-crown ether interactions." Thesis, University of Surrey, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.308555.

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2

Smith, Richard John Alan. "The synthesis of macrocyclic receptor compounds." Thesis, University of Liverpool, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.328435.

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3

Flack, Stephen Sean. "Studies towards synthetic receptors for small peptides and sugars." Thesis, University of Southampton, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.261284.

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4

Waymark, Christopher Peter. "Studies towards a novel synthetic receptor for small peptides." Thesis, University of Southampton, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.294980.

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5

Zayed, Jameel Majed. "Self-assembly of synthetic and biological components in water using cucurbit[8]uril." Thesis, University of Cambridge, 2012. https://www.repository.cam.ac.uk/handle/1810/242016.

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This thesis discusses progress made towards assembling molecular building blocks in the presence of our molecular host of choice, cucurbit[8]uril (CB[8]). Our studies on the self-assembly of synthetic and biological components in water bridge overlapping conceptsand techniques drawn from the fields of synthetic organic chemistry, supramolecular self-assembly, and applied NMR techniques. Chapter 1 introduces the reader to chemical complexity, and how supramolecular chemistshave advanced in their capability of assembling more complex molecular architectures. The discussion focusses particularly

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6

Ibbett, Ashley James. "Synthesis and host-guest chemistry of organic polycations." Thesis, University College London (University of London), 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.264211.

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7

Iwamoto, Takahiro. "Studies on Synthesis and Host-Guest Chemistry of Cycloparaphenylenes." 京都大学 (Kyoto University), 2014. http://hdl.handle.net/2433/188613.

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8

Lam, Ho-chuen, and 林浩銓. "Design, synthesis and host-guest chemistry of rhodamine derivatives and their transition metal complexes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2012. http://hdl.handle.net/10722/198806.

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New classes of luminescent transition metal complexes, including the systems of rhenium(I) tricarbonyl diimine, cyclometalated iridium(III) diimine, cyclometalated rhodium(III) diimine, ruthenium(II) diimine and ruthenium(II) terpyridine complexes tethered with rhodamine moieties, have been synthesized. The X-ray crystal structure of one of the cyclometalated rhodium(III) diimine complexes with rhodamine pendants, [Rh(SPLC2N2)(ppy)2](PF6) has been determined. The molecular structure of [Rh(SPLC2N2)(ppy)2](PF6) showed a distorted octahedral geometry and the rhodamine moiety was found in a spiro

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9

Haueisen, Renate H. "The synthesis and host-guest activity of novel cyanoborate salts." Doctoral thesis, University of Cape Town, 1994. http://hdl.handle.net/11427/21429.

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Molecular recognition is a dynamic process based on distinct chemical interactions and not on passive fitting of a lock and key. Complex formation between host and guest molecules is often accompanied by conformational reorganisation, which makes it possible to engineer and fine-tune synthetic receptor analogues for optimal function and selectivity. This thesis primarily describes a supramolecular study of a novel family of airstable cyanoborate host compounds. The discovery of this clathrand family came about as a result of a study relating to the synthesis of an electrolyte for the Zebra car

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10

Pohl, Pieter Lourens. "Tetrol and derivatives: synthesis, host-guest properties and racemate resolutions." Thesis, Nelson Mandela Metropolitan University, 2015. http://hdl.handle.net/10948/2879.

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In this study, we investigated the potential of a novel chiral host compound (+)-(2R,3R)-1,1,4,4-tetraphenylbutane-1,2,3,4-tetraol (TETROL) and its derivatives for use in racemate resolution using host-guest chemistry. The parent TETROL molecule is composed of a butane chain bearing a hydroxy functionality on each carbon, and two phenyl rings on each of the terminal carbons. The two internal carbon atoms are chiral. The syntheses of TETROL and derivatives were carried out by modifying the diester of naturally-occurring optically active tartaric acid using a variety of aromatic Grignard reagent

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11

García, Simón Cristina. "Synthesis of molecular nanocapsules for supramolecular host-guest chemistry and enzyme-like catalysis." Doctoral thesis, Universitat de Girona, 2015. http://hdl.handle.net/10803/289567.

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Coordination-driven self-assembly has led to the realization of an increasing number of elegant and sophisticated functional structures, the structural complexity of which would be difficult to achieve using conventional covalent chemistry. The synthesis of three-dimensional coordination capsule-like structures is of particular interest due to their multiple potential applications, particularly their use in selective molecular recognition (host-guest chemistry), reactivity modulation (nanoreactors), molecular sensors or biological applications. The main goal of this doctoral thesis, performed

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12

Hutcherson, Robert George. "New lower rim calix[4]arene derivatives containing mixed donor atoms, synthesis, characterisation and binding properties." Thesis, University of Surrey, 1997. http://epubs.surrey.ac.uk/842777/.

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Novel P-tert-butylcalix[4]arene derivatives (L-3-10) containing mixed donor atoms (O, N, S) have been synthesised in a two stage reaction, the first part of which involves the preparation of L-2 using 18-crown-6 as a phase transfer catalyst and K2CO3 as a weak base. These conditions lead to the removal of two distal protons from the lower rim, allowing the 1,3-bis-niethylethylthio ether derivative (L-2) to be synthesised in a reduced reaction time with greater yield and purity than previously published. The final two protons were removed using NaH, sites to which a variety of amine, amide and

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13

Yip, Sung-kong, and 葉崇江. "Design, synthesis, characterization and luminescence properties of alkynylgold(I) complexes: strategies towardssupramolecular architectures and host guest chemistry." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2005. http://hub.hku.hk/bib/B31941734.

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14

White, Tim Chemistry Australian Defence Force Academy UNSW. "Supramolecular chemistry and synthesis of Cucurbit[n]uril." Awarded by:University of New South Wales - Australian Defence Force Academy. School of Chemistry, 2003. http://handle.unsw.edu.au/1959.4/38643.

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The recently discovered cucurbit[n]uril are a range of macrocyclic hosts which have enormous potential in industrial, medical and academic applications. Cucurbit[n]uril have a rigid repeating structure of methylene bridged glycouril, which give cucurbit[n]uril their gourd like shape of a cavity with two carbonyl fringed portals. In this thesis the host-guest binding abilities of three cucurbit[n]uril (n = 6, 7, 8) have been examined for a range of potential guests. These guests ranged from simple alkyl amines through globular alkyl and carboranyl amines to bipyridyl systems. In total 45 g

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15

Severance, Michael A. "Nanocrystalline Zeolites: Synthesis, Mechanism, and Applications." The Ohio State University, 2014. http://rave.ohiolink.edu/etdc/view?acc_num=osu1387817713.

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16

Jin, Ping Atwood J. L. "Synthesis of mixed metal-organic pyrogallol[4]arene nanocapsules and their host-guest chemistry." Diss., Columbia, Mo. : University of Missouri--Columbia, 2009. http://hdl.handle.net/10355/6874.

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Title from PDF of title page (University of Missouri--Columbia, viewed on Feb 24, 2010). The entire thesis text is included in the research.pdf file; the official abstract appears in the short.pdf file; a non-technical public abstract appears in the public.pdf file. Dissertation advisor: Dr. Jerry L. Atwood. Vita. Includes bibliographical references.

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17

Laughery, Zachary. "Synthesis of Molecular Baskets and Introduction of Inward Facing Functionality." ScholarWorks@UNO, 2006. http://scholarworks.uno.edu/td/328.

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As a first step to producing a shape selective catalysts or enzyme mimic, two preorganized host molecules were synthesized. Binding studies of the two hosts with a variety of guests in three solvents demonstrated that an important driving force in the association was the formation of C-H???X-R hydrogen bonds (X = halogen). A deuterated host was utilized to further examine the formation of the C-H???X-R hydrogen bonds. In an effort to place functionality in the hydrophobic pocket of these hosts, two methods were developed. The first utilized directed ortho metallation to place electrophiles abo

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18

Lo, Hiu-suet, and 盧曉雪. "Design and syntheses of luminescent alkynyl complexes containing multinuclear platinum (II) and coinage metal centres: from photophysics to host-guest chemistry andsupramolecular architectures." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2009. http://hub.hku.hk/bib/B41633714.

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19

Yip, Sung-kong. "Design, synthesis, characterization and luminescence properties of alkynylgold(I) complexes strategies towards supramolecular architectures and host guest chemistry /." Click to view the E-thesis via HKUTO, 2005. http://sunzi.lib.hku.hk/hkuto/record/B31941734.

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20

Tang, Pui-ling, and 鄧佩玲. "Synthesis, luminescence and host-guest chemistry of mono- and dinuclear platinum(II) complexes of pyridyl and diphosphine ligands." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2002. http://hub.hku.hk/bib/B31243654.

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21

Tang, Pui-ling. "Synthesis, luminescence and host-guest chemistry of mono- and dinuclear platinum(II) complexes of pyridyl and diphosphine ligands /." Hong Kong : University of Hong Kong, 2002. http://sunzi.lib.hku.hk/hkuto/record.jsp?B25155040.

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22

Tang, Hau-san, and 鄧巧珊. "Design and synthesis of metal phosphine complexes of palladium(II) andgold(I) with various receptor ligands for ion-controlled orphotoresponsive host-guest chemistry." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2006. http://hub.hku.hk/bib/B37877422.

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23

He, Xiaoming. "Design, synthesis and characterization of alkynyl- and thiolato- gold (I) complexes with various receptor groups for host-guest chemistry." Click to view the E-thesis via HKUTO, 2010. http://sunzi.lib.hku.hk/hkuto/record/B43571979.

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24

Ioup, Sarah E. "Water-Soluble Deep-Cavity Cavitands: Synthesis, Molecular Recognition, and Interactions with Phospholipid Membranes." ScholarWorks@UNO, 2012. http://scholarworks.uno.edu/td/1572.

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Water-soluble deep-cavity cavitands provide a rare opportunity to study self-assembly driven by the hydrophobic effect. These molecular hosts dimerize in the presence of certain guest molecules to form water-soluble molecular capsules. These systems have given rise to numerous novel chemical phenomena and have potential use in drug delivery. The host octaacid (OA) has been particularly well-characterized, but studies are limited to basic pH because of limited host solubility. Herein we report an improved synthesis of OA and the syntheses of three new water-soluble deep-cavity cavitands. The ne

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25

Heck, Elizabeth Maria. "Synthesis of Poly(p-phenylene vinylene) within Faujasite and Linde Type A Zeolites: Encapsulation for Improved Optical Properties." The Ohio State University, 2011. http://rave.ohiolink.edu/etdc/view?acc_num=osu1306333964.

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26

ZEHNDER, DONALD WILLIAM. "HOST-[2]ROTAXANE: A NOVEL MOLECULAR MACHINE." University of Cincinnati / OhioLINK, 2003. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1051188602.

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27

Kato, Ryosuke. "Synthesis and Properties of P-Stereogenic Cyclic Phosphines." 京都大学 (Kyoto University), 2016. http://hdl.handle.net/2433/215570.

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28

Hausner, Sven H. "Part I: Dibenzotetraaza Crown Ethers. Part II: Synthesis and Characterization of Chlorophenyplumbates." University of Cincinnati / OhioLINK, 2001. http://rave.ohiolink.edu/etdc/view?acc_num=ucin998489402.

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29

Li, Chi-kwan, and 李志君. "Gold(I) and Gold(II) phosphine complexes exhibiting weak AuI... AuI interactions and unsupported AuII-AuII bonds: syntheses, spectroscopy, host-guest chemistry and reactivity studies." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2002. http://hub.hku.hk/bib/B31243332.

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30

Yeung, Ching-lam Margaret, and 楊靖琳. "Design and synthesis of luminescent alkynylplatinum (II) terpyridine complexes and their function as optical probes for biomolecules and ions : from self-aggregarion, supramolecular assembly to host-guest chemistry." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2013. http://hdl.handle.net/10722/208590.

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A number of cationic water-soluble alkynylplatinum(II) terpyridine complexes, [Pt(tpy){C≡CCH2OC6H3-(CH2OH)2-3,5}]OTf, [Pt(tBu3tpy){C≡CCH2OC6H3- (CH2OH)2-3,5}]Cl, [Pt(tpy){C≡CCH2OC6H4-(CH2OH)-4}]OTf, [Pt(tpy){C≡CC6H3- (CH2OH)2-3,5}]OTf, [Pt(tpy){C≡CC6H4-(CH2OH)-4}]OTf, [Pt(tpy)(C≡C－C≡CH)]OTf and [Pt(tpy){C≡CC6H4(CH2NMe3)-4}](OTf)2, have been synthesized. Phosphate anion derivatives of polyanionic nature, e.g. adenosine triphosphate and tyrosine-containing phosphopeptide, were employed to investigate the induced supramolecular helical assembly behaviors of several of the water-soluble pla

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31

Chen, Zhibing. "Synthesis and host-guest interaction of cage-annulated podands, crown ethers, cryptands, cavitands and non-cage-annulated cryptands." Thesis, University of North Texas, 2003. https://digital.library.unt.edu/ark:/67531/metadc4229/.

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Symmetrical cage-annulated podands were synthesized via highly efficient synthetic strategies. Mechanisms to account for the key reaction steps in the syntheses are proposed; the proposed mechanisms receive support from the intermediates that have been isolated and characterized. An unusual complexation-promoted elimination reaction was studied, and a mechanism is proposed to account for the course of this reaction. This unusual elimination may generalized to other rigid systems and thus may extend our understanding of the role played by the host molecules in "cation-capture, anion-activatio

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32

Lai, Huiguo. "Design and Synthesis of Novel Cage-Functionalized Crown Ethers: A New Class of Ag Complexants." Thesis, University of North Texas, 2003. https://digital.library.unt.edu/ark:/67531/metadc4314/.

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Three different types of cage crown ethers have been prepared and their complexation properties with Ag(I) have been studied. Atomic absorption, fluorescence quenching, and UV absorption have been used to study the interaction between the hosts (cage crown ethers) and guests (Ag+). For the cage-annulated crown ethers that contain aromatic rings, cation-π and π-π interactions may contribute significantly to the overall complexation ability of the host system. Piperazine groups may cooperate, and the piperazine nitrogen atoms provide unshared electrons, which may form a complex with Ag+. In addi

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33

Galstyan, Anzhela [Verfasser], Bernhard [Akademischer Betreuer] Lippert, and Jens [Gutachter] Müller. "Discrete supramolecular metal complexes : Synthesis, structures, host-guest chemistry with anions, and DNA binding properties / Anzhela Galstyan. Betreuer: Bernhard Lippert. Gutachter: Jens Müller." Dortmund : Universitätsbibliothek Dortmund, 2011. http://d-nb.info/1103472453/34.

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34

Tang, Hau-san. "Design and synthesis of metal phosphine complexes of palladium(II) and gold(I) with various receptor ligands for ion-controlled or photoresponsive host-guest chemistry." Click to view the E-thesis via HKUTO, 2006. http://sunzi.lib.hku.hk/hkuto/record/B37877422.

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35

Polavarapu, Anjaneya Prasad. "Exploring Molecular Interactions : Synthesis and Studies of Clip-Shaped Molecular Hosts." Doctoral thesis, Uppsala : Acta Universitatis Upsaliensis, 2007. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-8220.

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36

Faust, Thomas Benjamin. "On the synthesis, measurement and applications of octanuclear heterometallic rings." Thesis, University of Manchester, 2012. https://www.research.manchester.ac.uk/portal/en/theses/on-the-synthesis-measurement-and-applications-of-octanuclear-heterometallic-rings(a9697906-50e4-4d0a-9eda-bfd09b9e12f8).html.

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Inorganic macrocycles have stimulated interest in recent years for their magnetic properties, their associated host-guest chemistry and their aesthetically appealing structures. These characteristics have led to suggestions that they could be exploited for the purposes of ion recognition, catalysis, as single molecule magnets, MRI agents, antibacterial agents and as part of larger architectures in a molecular machine. This thesis explores the properties of a group of chromium(III) macrocycles, with functionality tailored towards different pursuits. Firstly the magnetic properties of a newly sy

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37

Sun, Qingqing. "Aryl and Super Aryl-Extended Calix[4]pyrroles: Synthesis and Applications." Doctoral thesis, Universitat Rovira i Virgili, 2021. http://hdl.handle.net/10803/672268.

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Aquesta tesi doctoral descriu el disseny i la síntesi d’una sèrie de receptors supramoleculars que presenten cavitats aromàtiques polars. Els receptors preparats inclouen receptors organometàl·lics, contenidors moleculars solubles en aigua, caixes moleculars basades en enllaços de coordinació i metal·lo-cavitands. S’han seleccionat unitats de calix[4]pirrole aril i super-aril estesos (AEC[4]P i SAE-C[4]P) com a components principals. S’han estudiat les propietats de reconeixement molecular dels receptors sintètics amb sals de clorur de tetraalquilamoni, així com de molècules polars neutres, en

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38

Lee, Minjae. "Design, Synthesis and Self-Assembly of Polymeric Building Blocks and Novel Ionic Liquids, Ionic Liquid-Based Polymers and Their Properties." Diss., Virginia Tech, 2010. http://hdl.handle.net/10919/77166.

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The convergence of supramolecular and polymer sciences has led to the construction of analogs of traditional covalently-constructed polymeric structures and architectures by supramolecular methods. Host-guest complexations of polymers are also possible through well-defined synthesis of polymeric building blocks, for novel supramolecular polymers. Monotopic polymeric building blocks were synthesized by controlled radical polymerizations with a crown or paraquat initiator. The combinations of terminal and central functionalities of host and guest polymeric building blocks provided chain-extended

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39

Roche, Cécile. "Porphyrin-based [3]- and [4]rotaxanes : towards an adaptable molecular receptor." Phd thesis, Université de Strasbourg, 2012. http://tel.archives-ouvertes.fr/tel-00763533.

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Rotaxanes and porphyrins are two particularly active fields of research in chemistry. However,molecules that combine the interesting properties of these types of structures are not so common. In this thesis we describe new porphyrin-based multi-rotaxanes, whose syntheses constitute interesting challenges.Porphyrins linked to two or four coordinating macrocycles were synthesised. The "gathering-andthreading" effect of copper(I) was used to thread molecular rods through the rings; the subsequent introduction of stoppers led to the formation of rotaxanes. In the case of the porphyrinic bis-macroc

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40

Wang, Yi. "Aqueous Desolvation and Molecular Recognition: Experimental and Computational Studies of a Novel Host-Guest System Based on Cucurbit[7]uril." Diss., 2012. http://hdl.handle.net/10161/6160.

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<p>Molecular recognition is arguably the most elementary physical process essential for life that arises at the molecular scale. Molecular recognition drives events across virtually all length scales, from the folding of proteins and binding of ligands, to the organization of membranes and the function of muscles. Understanding such events at the molecular level is massively complicated by the unique medium in which life occurs: water. In contrast to recognition in non-aqueous solvents, which are driven largely by attractive interactions between binding partners, binding reactions in water ar

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41

Manjula, A. "Studies in supramolecular chemistry: Synthesis and host-guest interactions of some oxygen macrocycles and podands." Thesis, 1997. http://hdl.handle.net/2009/732.

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42

Shen, Wei-Zheng [Verfasser]. "Cyclic, cationic complexes of Pt'' and Pd'' with heterocyclic ligands, including nucleobases : synthesis, structure, host-guest chemistry with anions and non-covalent interactions with DNA / Wei-Zheng Shen." 2007. http://d-nb.info/997589558/34.

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