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Journal articles on the topic 'Tetralone'

Author: Grafiati

Published: 4 June 2021

Last updated: 25 July 2025

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1

Casey, Brian M., Dhandapani V. Sadasivam та Robert A. Flowers II. "Mechanistic studies on the CAN-mediated intramolecular cyclization of δ-aryl-β-dicarbonyl compounds". Beilstein Journal of Organic Chemistry 9 (23 липня 2013): 1472–79. http://dx.doi.org/10.3762/bjoc.9.167.

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The synthesis of 2-tetralones through the cyclization of δ-aryl-β-dicarbonyl substrates by using CAN is described. Appropriately functionalized aromatic substrates undergo intramolecular cyclizations generating 2-tetralone derivatives in moderate to good yields. DFT computational studies indicate that successful formation of 2-tetralones from δ-aryl-β-dicarbonyl radicals is dependent on the stability of the subsequent cyclohexadienyl radical intermediates. Furthermore, DFT computational studies were used to rationalize the observed site selectivity in the 2-tetralone products.

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2

Chaitramallu, M1 Devaraju Kesagodu1 Dakshayini Chandrashekarachar2. "SYNTHESIS AND BIOLOGICAL SCREENING OF ANALOGS OF ARYL TETRALONE." INDO AMERICAN JOURNAL OF PHARMACEUTICAL RESEARCH 07, no. 01 (2017): 7392–98. https://doi.org/10.5281/zenodo.1006777.

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The aryl tetralone as potential antimitotic agents were synthesized in four step reactions using Grignard reagent. The first step is the synthesis of trimethoxy phenyl naphthol (2a-f) by the reaction of substituted tetralone with 3, 4, 5-trimethoxy 1-bromobenzene in magnesium metal using tetrahydrofuran as a solvent. The resulted phenyl naphthol was hydrogenated to give phenyl tetralin 3(a-f). The substituted phenyl tetralone were prepared by the oxidation of trimethoxy phenyl tetralin 4(a-f). The structures of the synthesized compounds were confirmed by spectral and elemental analysis data. T

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3

Amakali, Klaudia, Lesetja Legoabe, Anél Petzer, and Jacobus Petzer. "Synthesis and in vitro Evaluation of 2-heteroarylidene-1-tetralone Derivatives as Monoamine Oxidase Inhibitors." Drug Research 68, no. 12 (2018): 687–95. http://dx.doi.org/10.1055/a-0620-8309.

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AbstractThe present study investigates the human monoamine oxidase (MAO) inhibition properties of a series of twelve 2-heteroarylidene-1-tetralone derivatives. Also included are related cyclohexylmethylidene, cyclopentylmethylidene and benzylidene substituted 1-tetralones. These compounds are related to the 2-benzylidene-1-indanone class of compounds which has previously been shown to inhibit the MAOs, with specificity for the MAO-B isoform. The target compounds were synthesised by the Claisen-Schmidt condensation between 7-methoxy-1-tetralone or 1-tetralone, and various aldehydes, under acid

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4

Wang, An-dong, Chao-jie Xie, Yun-qiang Zhang та ін. "α-Tetralonyl Glucosides from the Green Walnut Husks of Juglans mandshurica and Their Antiproliferative Effects". Planta Medica 85, № 04 (2019): 335–39. http://dx.doi.org/10.1055/a-0832-2328.

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AbstractTwo new α-tetralonyl glucosides, (4S)-4,5,8-trihydroxy-α-tetralone-5-O-β-D-glucopyranosyl(1 → 6)-β-D-glucopyranoside (1) and (4S)-4,8-dihydroxy-α-tetralone-4-O-β-D-glucopyranosyl(1 → 6)-β-D-glucopyranoside (2), together with eight known compounds (3 – 10) were isolated from the green walnut husks of Juglans mandshurica. The structural characterization of all compounds was performed by spectroscopic analyses, including 1D and 2D NMR and HR-ESI-MS experiments. The isolated compounds were assayed for their cytotoxicity against two human cancer cell lines, A549 and HeLa. Four compounds (7

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5

Banerjee, Ajoy K., Liadis Bedoya, Alexis Maldonado, Lisbeth Mendoza, and Elvia V. Cabrera. "Synthesis of 8-Methoxy-1-Tetralone." International Journal of Chemistry 16, no. 2 (2024): 24. http://dx.doi.org/10.5539/ijc.v16n2p24.

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Several methods have been developed for the synthesis of 8-methoxy-1- tetralone 4. The applications of some named organic reactions can be observed during the synthesis of tetralone 4. Attempts have been made to achieve the direct conversion of 5-methoxy-1-tetralone into the tetralone 4. The method for the ring expansion of tertiary cyclobutanol 30 catalyzed by silver salts has proved useful to obtain the title tetralone 4.

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6

Yao, Xudong, and Ralph M. Pollack. "Electronic effects on enol acidity and keto-enol equilibrium constants for ring-substituted 2-tetralones." Canadian Journal of Chemistry 77, no. 5-6 (1999): 634–38. http://dx.doi.org/10.1139/v99-006.

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Equilibrium constants for the ionization of a variety of phenyl-substituted 2-tetralones (pKaK), for the ionization of their enols (pKaE), and for keto-enol tautomerization (pKE) were determined. Hammett plots of pKaK and pKaE vs. σ- are linear with slopes (-ρ) of -1.66 ± 0.06 and -0.90 ± 0.03, respectively, except for deviations of the points corresponding to 6-nitro-2-tetralone (1b) and its enol. We have previously attributed the negative deviation of 1b from the correlation for the acidities of the ketones obtained with the more limited set of data to the lack of a free electron pair on C-1

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7

Jiang, Yan, Shuo-Wen Yu, Yi Yang та ін. "Facile synthesis of fused polycyclic compounds via intramolecular oxidative cyclization/aromatization of β-tetralone or β-tetralone oximes". Organic & Biomolecular Chemistry 16, № 46 (2018): 9003–10. http://dx.doi.org/10.1039/c8ob02031k.

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8

XU, Lixin, Peijie LI, Weiwei LIU, Yanyan XU та Zhicai WANG. "Cr2O3/γ-Al2O3Catalyzed Oxidation of Tetralin Toward α-Tetralone". Acta Agronomica Sinica 30, № 11 (2013): 1304. http://dx.doi.org/10.3724/sp.j.1095.2013.30059.

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9

Bhattacharjee, Samiran, Yu-Ri Lee, and Wha-Seung Ahn. "Oxidation of tetralin to 1-tetralone over CrAPO-5." Korean Journal of Chemical Engineering 34, no. 3 (2016): 701–5. http://dx.doi.org/10.1007/s11814-016-0310-4.

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10

Ali, Karim Ben, Najeh Boukamcha, Abdelkader Khemiss, and Marie-Thérèse Martin. "Synthesis and Structural Elucidation of Novel Spiropyrazolines Precursors to Spiro-gem-dimethylcyclopropanes." Journal of Chemical Research 2005, no. 8 (2005): 498–501. http://dx.doi.org/10.3184/030823405774663192.

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1,3-dipolar cycloaddition reaction of 2-diazopropane (DAP) 1 with 2-arylidene-1-tetralone 2a–b led exclusively to spiro-Δ1-pyrazolines 3a–b. When 4-methyl-2-arylidene-1-tetralones 2c–d was used as starting dipolarophile a mixture of diastereiosomeric cycloadducts 4a–b and 5a–b was obtained. The photochemical nitrogen-extrusion studied for spiropyrazolines 3a–b and 4a–b led stereospecifically to spiro-gem-dimethylcyclopropanes. In all cases, the reaction regiochemistry and stereochemistry was discussed on the basis of 2D-NMR experiments.

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11

Banerjee, Ajoy K., Liadis Bedoya, Maria E. Adherían, William J. Vera, Elvia V. Cabrera, and Elidig R. Kariney. "Transformation of 5-methoxy-1-tetralone into 8-methoxy-1-tetralone." Journal of Chemical Research 34, no. 9 (2010): 522–24. http://dx.doi.org/10.3184/030823410x12843943759969.

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12

Rahmadani, Agung, Indriana Tasya, Wahyu Yunita Lestari, et al. "Sintesis, Molecular Docking dan Aktivitas Sitotoksik Senyawa Analog Kalkon Berbasis Alfa Tetralone terhadap Sel Kanker Payudara MCF-7." Jurnal Sains dan Kesehatan 6, no. 1 (2024): 149–57. http://dx.doi.org/10.25026/jsk.v6i1.2092.

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The chalcone compound is a precursor of flavonoid and pyrazoline compounds. Chalcone has two aromatic rings (A and B) and one ?,?-unsaturated carbon atom. Chalcone compounds can be synthesized via the Claisen Schmidt condensation reaction. Chalcone synthesis uses the basic ingredients of alpha tetralone and benzaldehyde analogues. In this research, chalcone synthesis took place for 48 hours at room temperature. Synthetic materials using ethanol solvent and sodium hydroxide catalyst, as well as basic ingredients alpha tetralone, 3,4-dimethoxybenzaldehyde and 4-methoxybenzaldehyde. Characterizat

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13

Zhang, Qiongwen, Junyuan Zhang, Xia Wang, Jia Yu, and Xingjie Guo. "Enantioseparation of Eight Pairs of Tetralone Derivative Enantiomers on Cellulose Based Chiral Stationary Phase by HPLC." Current Pharmaceutical Analysis 16, no. 5 (2020): 539–47. http://dx.doi.org/10.2174/1573412915666181130111103.

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Background: Tetralone derivatives, important resources for the development of new drugs which can act in the treatment of central nervous system disorders or participate in synthesis reaction for the synthesis of various pharmaceuticals, have great research value and a bright prospect in exploitation. Methods: A novel chiral HPLC method for efficient enantioseparation of eight tetralone derivative enantiomers was developed on cellulose based CHIRALPAK IC chiral stationary phase under normal mode by investigating the effects of type and content of organic modifier, column temperature and flow r

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14

Campbell, Malcolm M., Nabeeha Abbas, and Malcolm Sainsbury. "Spiroheterocycles derived prom tetralone." Tetrahedron 41, no. 23 (1985): 5637–44. http://dx.doi.org/10.1016/s0040-4020(01)91367-5.

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15

Abaee, M. Saeed, Esmail Doustkhah, Mohaddeseh Mohammadi, Mohammad M. Mojtahedi, and Klaus Harms. "Tandem aldol condensation-Diels–Alder-aromatization sequence of reactions: a new pathway for the synthesis of 2-tetralone derivatives." Canadian Journal of Chemistry 94, no. 9 (2016): 733–37. http://dx.doi.org/10.1139/cjc-2016-0246.

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A series of new polysubstituted derivatives of 2-tetralones possessing two ester groups were synthesized via a tandem aldol condensation-Diels–Alder-aromatization sequence of reactions. All the three steps took place in one pot and in the presence of aminofunctionalized silica coated Fe3O4 nanoparticles as the catalyst. In situ formed dienes reacted with diethyl acetylenedicarboxylate at room temperature and the process was followed by spontaneous aromatization of the cycloadducts to produce high yields of the final tetralone products. Further studies suggest that the process goes through an i

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16

Li, Ruipeng, Zhenren Liu, Liang Chen, Jing Pan, and Weicheng Zhou. "Enantioselective phase-transfer catalyzed alkylation of 1-methyl-7-methoxy-2-tetralone: an effective route to dezocine." Beilstein Journal of Organic Chemistry 14 (June 11, 2018): 1421–27. http://dx.doi.org/10.3762/bjoc.14.119.

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In order to prepare asymmetrically (R)-(+)-1-(5-bromopentyl)-1-methyl-7-methoxy-2-tetralone (3a), a key intermediate of dezocine, 17 cinchona alkaloid-derived catalysts were prepared and screened for the enantioselective alkylation of 1-methyl-7-methoxy-2-tetralone with 1,5-dibromopentane, and the best catalyst (C7) was identified. In addition, optimizations of the alkylation were carried out so that the process became practical and effective.

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17

Demir, Ayhan S., Zuhal Gercek, Nese Duygu, A. Cigdem Igdir, and Omer Reis. "Butenolide annelation using a manganese(III) oxidation. A synthesis of chromolaenin (Laevigatin)." Canadian Journal of Chemistry 77, no. 8 (1999): 1336–39. http://dx.doi.org/10.1139/v99-136.

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A procedure was developed for the annelation of a butenolide to an aromatic ketone that highlighted a manganese(III) oxidation of an aromatic ketone. The merit of this procedure was illustrated in a synthesis of Chromolaenin (Laevigatin) (1) from 4,7-dimethyl-1-tetralone (2c). Oxidation of tetralone and indanone with manganese(III) acetate in the presence of chloro- or bromopropionic acid or their Mn(II) salts furnished a α-haloesters 3a-d. An Arbuzov reaction of haloesters with triethylphosphite and an intramolecular Horner-Watsworth-Emmons cyclization of the resulting phosphonate gave buteno

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18

Gogoi, Dimpee, Runjun Devi, Pallab Pahari, Bipul Sarma, and Sajal Kumar Das. "cis-Diastereoselective synthesis of chroman-fused tetralins as B-ring-modified analogues of brazilin." Beilstein Journal of Organic Chemistry 12 (December 21, 2016): 2816–22. http://dx.doi.org/10.3762/bjoc.12.280.

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We have synthesized a series of cis-6a,7,8,12b-tetrahydro-6H-naphtho[2,1-c]chromen-6a-ols as B-ring-modified analogues of (±)-brazilin. A completely regio- and cis-diastereoselective intramolecular Friedel–Crafts epoxy–arene cyclization of 1-tetralone-derived glycidyl ethers catalyzed by Brønsted acids was used as the key step. Our worries concerning the formation of cis–trans product mixtures and their probable conversion to naphthopyran derivatives via dehydration of the tertiary hydroxy group were laid to rest. Additionally, the angular hydroxy group of one of the synthesized products has b

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19

Sultan, Aeysha, Abdul Rauf Raza, Mian Habib Ur Rehman Mehmood та ін. "An Overview of Synthetic Approaches towards of Nitration of α-Tetralones". Material Science Research India 16, № 3 (2019): 189–97. http://dx.doi.org/10.13005/msri/160301.

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The 1-tetralone scaffold and its derivatives are not only important as pharmacological agents but these also serve as precursors for natural products and compounds of medicinal importance. The easiest way to introduce a substituent on an aromatic as well as aliphatic system is nitration. Once introduced, the –NO2 group can be easily replaced by a wide range of functional groups. The review aims to highlight strategies for nitration of substituted and unsubstituted 1-tetralone which led to introduction of NO2 functionality at various positions.

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20

Oloo, Eliud O., J. Wilson Quail, Pál Perjési, and Jonathan R. Dimmock. "2-(2,4-Dichlorophenylmethylene)-1-tetralone." Acta Crystallographica Section E Structure Reports Online 58, no. 5 (2002): o580—o581. http://dx.doi.org/10.1107/s160053680200747x.

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21

Oloo, Eliud O., J. Wilson Quail, Pál Perjési, and Jonathan R. Dimmock. "2-(2,4-Dichlorophenylhydroxymethyl)-1-tetralone." Acta Crystallographica Section E Structure Reports Online 58, no. 5 (2002): o582—o583. http://dx.doi.org/10.1107/s1600536802007481.

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22

Vera, William J., and Ajoy K. Banerjee. "Synthesis of 5-Methoxy-6-isopropyl-1-tetralone." Natural Product Communications 11, no. 5 (2016): 1934578X1601100. http://dx.doi.org/10.1177/1934578x1601100530.

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23

Zou, Ge, Taobo Li, Wencong Yang, et al. "Antioxidative Indenone and Benzophenone Derivatives from the Mangrove-Derived Fungus Cytospora heveae NSHSJ-2." Marine Drugs 21, no. 3 (2023): 181. http://dx.doi.org/10.3390/md21030181.

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Seven new polyketides, including four indenone derivatives, cytoindenones A–C (1, 3–4), 3′-methoxycytoindenone A (2), a benzophenone derivative, cytorhizophin J (6), and a pair of tetralone enantiomers, (±)-4,6-dihydroxy-5-methoxy-α-tetralone (7), together with a known compound (5) were obtained from the endophytic fungus Cytospora heveae NSHSJ-2 isolated from the fresh stem of the mangrove plant Sonneratia caseolaris. Compound 3 represented the first natural indenone monomer substituted by two benzene moieties at C-2 and C-3. Their structures were determined by the analysis of 1D and 2D NMR,

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24

Jha, Amitabh, Nawal K. Paul, Smriti Trikha, and T. Stanley Cameron. "Novel synthesis of 2-naphthol Mannich bases and their NMR behaviour." Canadian Journal of Chemistry 84, no. 6 (2006): 843–53. http://dx.doi.org/10.1139/v06-081.

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A novel two-step procedure involving the formation of 1-arylidene-2-tetralones from 2-tetralone and subsequent Michael addition of a cyclic secondary amine on the alkenone followed by in situ aerial oxidation was developed to produce 2-naphthol Mannich bases. A simple microwave-assisted one-pot synthesis of 2-naphthol Mannich bases was also carried out under solvent-free conditions from 2-naphthol and corresponding aldehydes and amines in the presence of p-toluenesulfonic acid. The compounds of this series displayed interesting NMR behaviour. Extensive variable-temperature NMR investigations,

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25

N., Vijaya Bhaskar Rao, and Anand Rao M. "Kinetics and mechanism of RuIII catalysed oxidation of 1,2,3,4-tetrahydronaphthalene (tetralin ) by CeIV in aqueous nitric acid medium." Journal of Indian Chemical Society Vol. 86, Sep 2009 (2009): 976–78. https://doi.org/10.5281/zenodo.5819768.

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Department of Chemistry, Osmania University, Hyderabad-500 007, India <em>E-mail </em>: marao_9@yahoo.com <em>Manuscript received 6 August 2008, revised 11 May 2009, accepted 19 May 2009</em> The kinetics and mechanism of Rulli catalysed oxidation of 1,2,3,4-tetrahydronaphthalene (tetralin) by Ce<sup>IV</sup> in aqueous nitric acid to tetralone under the conditions [TL] > > [Ce<sup>IV</sup>] at different temperatures (30-50 °C) have been studied In 3.0 mol dm<sup>-3 </sup>nitric acid medium. The experimentally observed rate law conforms to -d[Ce<sup>IV</sup>]/<em>dt</em> = <em>k

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26

Gautam, Yashveer, Sonam Dwivedi, Ankita Srivastava, et al. "2-(3′,4′-Dimethoxybenzylidene)tetralone induces anti-breast cancer activity through microtubule stabilization and activation of reactive oxygen species." RSC Advances 6, no. 40 (2016): 33369–79. http://dx.doi.org/10.1039/c6ra02663j.

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27

Yasui, Takeshi, Tomohiro Kikuchi, and Yoshihiko Yamamoto. "Rhodium-catalyzed cycloisomerization of ester-tethered 1,6-diynes with cyclopropanol moiety leading to tetralone/exocyclic diene hybrid molecules." Chemical Communications 56, no. 84 (2020): 12865–68. http://dx.doi.org/10.1039/d0cc05429a.

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28

Wang, Daniel Zerong, Yeong-Joon Kim та Andrew Streitwieser. "Aggregation and Alkylation of Enolates of 2-Phenyl-α-tetralone and 2,6-Diphenyl-α-tetralone1". Journal of the American Chemical Society 122, № 44 (2000): 10754–60. http://dx.doi.org/10.1021/ja0010002.

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29

Haroon, Muhammad, Tashfeen Akhtar, and Muhammad Nawaz Tahir. "Crystal structure of (E)-2-(4-chlorobenzylidene)-3,4-dihydronaphthalen-1(2H)-one: a second monoclinic polymorph." Acta Crystallographica Section E Crystallographic Communications 71, no. 10 (2015): o741—o742. http://dx.doi.org/10.1107/s2056989015016151.

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The title compound, C17H13ClO, is the second monoclinic polymorph to crystallize in the space groupP21/c. The first polymorph crystallized with two independent molecules in the asymmetric unit [Bolognesiet al.(1975).Acta Cryst.A31, S119;Z′ = 2; no atomic coordinates available], whereas the title compound hasZ′ = 1. In the title polymorph, the dihedral angle between the plane of the benzene ring of the tetralone moiety and that of the 4-chlorobenzyl ring is 52.21 (11)°. The cyclohex-2-en-1-one ring of the tetralone moiety has a screw-boat conformation. In the crystal, molecules are liked by pai

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30

Cabrera, Elvia V., Carlos Reyes, Néstor Peña, Kelly P. Marrugo, Liadis Bedoya, and Ajoy K. Banerjee. "Isopropylation of 5-methoxy-1-tetralone." Organic Preparations and Procedures International 47, no. 5 (2015): 379–83. http://dx.doi.org/10.1080/00304948.2015.1066649.

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31

Banerjee, Ajoy K., Liadis Bedoya, Jossblerys DaSilva, et al. "Isopropylation of 6-Methoxy-1-tetralone." Organic Preparations and Procedures International 51, no. 5 (2019): 503–6. http://dx.doi.org/10.1080/00304948.2019.1651173.

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32

Oloo, Eliud O., J. Wilson Quail, Maniyan P. Padmanilayam, and Jonathan R. Dimmock. "(E)-1-(4-Carboxyphenylmethylene)-2-tetralone." Acta Crystallographica Section E Structure Reports Online 58, no. 6 (2002): o687—o688. http://dx.doi.org/10.1107/s1600536802008668.

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33

Dewprashad, Brahmadeo, Anthony Nesturi та Joel Urena. "Acid-Catalyzed Enolization of β-Tetralone". Journal of Chemical Education 85, № 6 (2008): 829. http://dx.doi.org/10.1021/ed085p829.

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34

Auamcharoen, Wanida, Anake Kijjoa, Angsumarn Chandrapatya, et al. "A new tetralone from Diospyros cauliflora." Biochemical Systematics and Ecology 37, no. 5 (2009): 690–92. http://dx.doi.org/10.1016/j.bse.2009.10.004.

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35

Vera, William J., and Ajoy K. Banerjee. "An efficient approach for the synthesis of 6,7-dimethoxy-2-tetralone and 5,6-dimethoxy-1-tetralone." Arkivoc 2009, no. 11 (2009): 228–34. http://dx.doi.org/10.3998/ark.5550190.0010.b20.

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36

UPADHYAY, HARISH C., RAM K. VERMA та SANTOSH K. SRIVASTAVA. "A simple and reliable method for the determination of tetralone-4-O- ß -D-glucopyranoside and 4-hydroxy- α -tetralone in three species of Ammannia by reversed-phase HPLC". Journal of Medicinal and Aromatic Plant Sciences 35, № 2013 (2013): 136–42. http://dx.doi.org/10.62029/jmaps.v35i3.upadhyay.

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The species of genus Ammannia have proven medicinal efficacies, being frequently used in traditional Chinese and Indian systems of medicine. The compounds 4-hydroxy-α-tetralone and its glucoside have been identified as the major bioactive constituents in Ammannia species. A rapid, reliable and reproducible reversed-phase HPLC method was developed for the determination of tetralone-4-O-ß-D-glucopyranoside (1) and 4-hydroxy- α - tetralone (2) in three species of Ammannia namely, A. coccinea, A. verticillata and A. tenuis is repoted here. The chromatographic separation of compounds was performed

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37

Bognár, Gábor, Fatemeh Kenari, Zoltán Pintér, et al. "(E)-2-Benzylidenecyclanones: Part XX—Reaction of Cyclic Chalcone Analogs with Cellular Thiols: Unexpected Increased Reactivity of 4-Chromanone- Compared to 1-Tetralone Analogs in Thia-Michael Reactions." Molecules 29, no. 23 (2024): 5493. http://dx.doi.org/10.3390/molecules29235493.

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In vitro relative cytotoxicity (IC50 (IIb)/IC50 (IIIb) of (E)-3-(4′-methylbenzylidene)-4-chromanone (IIIb) towards human Molt 4/C8 and CEM T-lymphocytes showed a >50-fold increase in comparison to those of the respective tetralone derivative (IIb). On the other hand, such an increase was not observed in the analogous 4-OCH3 (IIc and IIIc) derivatives. In order to study whether thiol reactivity—as a possible basis of the mechanism of action—correlates with the observed cytotoxicities, the kinetics of the non-enzyme catalyzed reactions with reduced glutathione (GSH) and N-acetylcysteine (NAC)

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38

Wang, Yongtao, Zeyu Wen, Yue Zhang, Xinyu Wang, Jia Yao та Haoran Li. "Aerobic α-hydroxylation of 2-Me-1-tetralone in 1-alkyl-3-methylimidazolium ionic liquids". Physical Chemistry Chemical Physics 23, № 10 (2021): 5864–69. http://dx.doi.org/10.1039/d0cp06047j.

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39

Roiban, Gheorghe-Doru, Rubén Agudo, Adriana Ilie, Richard Lonsdale, and Manfred T. Reetz. "CH-activating oxidative hydroxylation of 1-tetralones and related compounds with high regio- and stereoselectivity." Chem. Commun. 50, no. 92 (2014): 14310–13. http://dx.doi.org/10.1039/c4cc04925j.

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Mutants of P450-BM3 evolved by directed evolution are excellent catalysts in the CH-activating oxidative hydroxylation of 1-tetralone derivatives and of indanone, with unusually high regio- and enantioselectivity being observed.

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40

Lian, Xiangjin, Lili Lin, Kai Fu, Baiwei Ma, Xiaohua Liu, and Xiaoming Feng. "A new approach to the asymmetric Mannich reaction catalyzed by chiral N,N′-dioxide–metal complexes." Chemical Science 8, no. 2 (2017): 1238–42. http://dx.doi.org/10.1039/c6sc03902b.

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An efficient asymmetric Mannich-type reaction between α-tetralone-derived β-keto esters/amides and 1,3,5-triaryl-1,3,5-triazinanes was realized catalyzed by chiral N,N'–dioxide-Ni(ii)/Mg(ii) complexes.

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41

Zhang, Zhenzhen, Xueqian He, Congcong Liu, et al. "Clindanones A and B and cladosporols F and G, polyketides from the deep-sea derived fungus Cladosporium cladosporioides HDN14-342." RSC Advances 6, no. 80 (2016): 76498–504. http://dx.doi.org/10.1039/c6ra14640f.

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Seven tetralone derivatives (1–7) were isolated from the deep-sea derived fungus Cladosporium cladosporioides. Compounds 1 and 2 possessed a new dimeric forms of the skeleton, and the new compound 4 was cytotoxic.

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42

Tisovský, Pavol, Mária Mečiarová, and Radovan Šebesta. "Asymmetric organocatalytic SOMO reactions of enol silanes and silyl ketene (thio)acetals." Org. Biomol. Chem. 12, no. 46 (2014): 9446–52. http://dx.doi.org/10.1039/c4ob01385a.

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The reactivity of aldehydes and ketones in asymmetric organo-SOMO reactions with enol silanes was explored. The best results were obtained with 3-phenylpropanal and tetralone-derived silyl enol ether and silyl ketene thioacetal.

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43

Balijapalli, Umamahesh, Saravanakumar Manickam, Manojkumar Dhanthalu Thiyagarajan, and Sathiyanarayanan Kulathu Iyer. "Highly emissive, naked-eye solvatochromic probe based on styryl tetrahydrodibenzo[a,i]phenanthridine for acidochromic applications." RSC Advances 6, no. 63 (2016): 58549–60. http://dx.doi.org/10.1039/c6ra09359k.

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A new series of 5-styryl tetrahydrodibenzo[a,i]phenanthridines was readily synthesized from β-tetralone, ammonium acetate and cinnamaldehydes and successfully applied to quantitatively detect pH in biological fluids and acid impurities in solvents.

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44

Zhou, Bei, Guangming Wang, Xuepu Wang, Wang Guo, Junbo Li, and Kaka Zhang. "Highly efficient room-temperature organic afterglow achieved by collaboration of luminescent dimeric TADF dopants and rigid matrices." Journal of Materials Chemistry C 9, no. 11 (2021): 3939–47. http://dx.doi.org/10.1039/d0tc05464j.

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Dopant–matrix systems of difluoroboron β-diketonate TADF emitters and rigid crystalline tetralone matrices display greenish yellow afterglow emission that can last for 4 s and possess an afterglow quantum yield up to 26% under ambient conditions.

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45

Wan, Chao, Mengyan Zhu, Lin Du, Lixin Xu, Mingfu Ye та Yue An. "Highly efficient aerobic oxidation of tetralin to α-tetralone over MnOx–CoOy/γ-Al2O3 catalysts". Catalysis Communications 125 (травень 2019): 87–92. http://dx.doi.org/10.1016/j.catcom.2019.04.003.

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46

Xu, Leichuan, Haoyun Ma, Xinkun An, et al. "Total synthesis, structure revision and cytotoxic activity of Sch 53825 and its derivatives." RSC Advances 12, no. 27 (2022): 17629–36. http://dx.doi.org/10.1039/d2ra02898k.

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The first total synthesis of Sch 53825 (14) was achieved in 12 steps from 5-hydroxy-1-tetralone in 16% overall yield through N-benzyl cinchoninium chloride-catalyzed asymmetric epoxidation and a Mitsunobu reaction as the key steps.

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47

Curley, Regina K., Andrew W. Macfarlane, and Clodagh M. King. "Contact dermatitis to 2, phenyl tetralone tosylhydrazone." Contact Dermatitis 14, no. 4 (1986): 257–58. http://dx.doi.org/10.1111/j.1600-0536.1986.tb01245.x.

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48

Kokubun, Tetsuo, Nigel C. Veitch, Paul D. Bridge, and Monique S. J. Simmonds. "Dihydroisocoumarins and a tetralone from Cytospora eucalypticola." Phytochemistry 62, no. 5 (2003): 779–82. http://dx.doi.org/10.1016/s0031-9422(02)00606-4.

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49

Lahiri, Saswata, C. Ramarao, B. Venkateswara Rao, A. V. Rama Rao, and Mukund S. Chorghade. "Facile Synthesis of 5,6-Dimethoxy-1-tetralone†." Organic Process Research & Development 3, no. 1 (1999): 71–72. http://dx.doi.org/10.1021/op970111r.

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50

Krishna, M. H., Y. B. Basavaraju, B. Umesha, and S. B. Shivakumar. "Synthesis and characterization of new tetralone esters." Pure and Applied Chemical Sciences 2 (2014): 31–39. http://dx.doi.org/10.12988/pacs.2014.413.

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