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Relevant bibliographies by topics / Thermo Reversible Polymers

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Journal articles
Dissertations / Theses
Book chapters
Conference papers

Academic literature on the topic 'Thermo Reversible Polymers'

Author: Grafiati

Published: 4 June 2025

Last updated: 1 August 2025

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Journal articles on the topic "Thermo Reversible Polymers"

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Orozco, Felipe, Zafarjon Niyazov, Timon Garnier, et al. "Maleimide Self-Reaction in Furan/Maleimide-Based Reversibly Crosslinked Polyketones: Processing Limitation or Potential Advantage?" Molecules 26, no. 8 (2021): 2230. http://dx.doi.org/10.3390/molecules26082230.

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Polymers crosslinked via furan/maleimide thermo-reversible chemistry have been extensively explored as reprocessable and self-healing thermosets and elastomers. For such applications, it is important that the thermo-reversible features are reproducible after many reprocessing and healing cycles. Therefore, side reactions are undesirable. However, we have noticed irreversible changes in the mechanical properties of such materials when exposing them to temperatures around 150 °C. In this work, we study whether these changes are due to the self-reaction of maleimide moieties that may take place a

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Pal, Sunirmal, Megan R. Hill, and Brent S. Sumerlin. "Doubly-responsive hyperbranched polymers and core-crosslinked star polymers with tunable reversibility." Polymer Chemistry 6, no. 45 (2015): 7871–80. http://dx.doi.org/10.1039/c5py01295c.

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Thermo- and redox-responsive hyperbranched copolymers were prepared by statistical copolymerization of N-isopropylacrylamide (NIPAM) and N,N′-bis(acryloyl)cystamine (BAC) by reversible addition–fragmentation chain transfer (RAFT) polymerization.

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Kim, Young-Jin, and Yukiko T. Matsunaga. "Thermo-responsive polymers and their application as smart biomaterials." Journal of Materials Chemistry B 5, no. 23 (2017): 4307–21. http://dx.doi.org/10.1039/c7tb00157f.

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TAKIGUCHI, Yasuhiro, Ryoichi KISHI, Hisao ICHIJO, and Okihiko HIRASA. "Polymers and Environment II. Thermo-Reversible Separation of Organic Substances by Using Thermo-Responsive Polymer Gel." KOBUNSHI RONBUNSHU 50, no. 11 (1993): 905–8. http://dx.doi.org/10.1295/koron.50.905.

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Li, Boyu, Joey Kim, and Julie Kornfield. "A Molecular Picture for the Thermo-Reversibility of Gels Formed by Isophthalic Acid-Ended Telechelic Polymers." MRS Proceedings 1794 (2015): 9–14. http://dx.doi.org/10.1557/opl.2015.638.

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ABSTRACTWe demonstrate that isophthalic acid-ended telechelic poly(1,5-cyclooctadiene)s (A-PCODs) form thermo-reversible gels in non-polar solvent with a unique molecular mechanism for their thermo-reversibility. Like other associative telechelic polymers, A-PCODs form “flower-like” micelles at low concentration and form gels through bridging at higher concentration which exhibit linear viscoelasticity. However, unlike the widely studied hydrophobically end-capped PEOs, A-PCODs show clear thermo-reversibility in viscosity and dynamic modulus around 30 °C due to the hydrogen-bonding end groups.

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Gao, Yulei, Zhou Deng, Fenfen Wang, and Pingchuan Sun. "Achieving long lifetime of room-temperature phosphorescence via constructing vitrimer networks." Materials Chemistry Frontiers 6, no. 8 (2022): 1068–78. http://dx.doi.org/10.1039/d2qm00003b.

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Fluorescence and RTP dual emission polymers exhibit reversible temperature responsiveness, tunable mechanical properties, remarkable thermostability and thermo-adaptive self-healing ability based on a dynamic covalently crosslinked 3D network.

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Abend, Zechel, Schubert, and Hager. "Detailed Analysis of the Influencing Parameters on the Self-Healing Behavior of Dynamic Urea-Crosslinked Poly(methacrylate)s." Molecules 24, no. 19 (2019): 3597. http://dx.doi.org/10.3390/molecules24193597.

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For this paper, the self-healing ability of poly(methacrylate)s crosslinked via reversible urea bonds was studied in detail. In this context, the effects of healing time and temperature on the healing process were investigated. Furthermore, the impact of the size of the damage (i.e., area of the scratch) was monitored. Aging processes, counteracting the self-healing process, result in a decrease in the mechanical performance. This effect diminishes the healing ability. Consequently, the current study is a first approach towards a detailed analysis of self-healing polymers regarding the influen

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Ni, Yiping, Frédéric Becquart, Jianding Chen, and Mohamed Taha. "Polyurea–Urethane Supramolecular Thermo-Reversible Networks." Macromolecules 46, no. 3 (2013): 1066–74. http://dx.doi.org/10.1021/ma302421r.

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Wang, Tao Xi, Hong Mei Chen, Abhijit Vijay Salvekar, et al. "Vitrimer-Like Shape Memory Polymers: Characterization and Applications in Reshaping and Manufacturing." Polymers 12, no. 10 (2020): 2330. http://dx.doi.org/10.3390/polym12102330.

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The shape memory effect (SME) refers to the ability of a material to recover its original shape, but only in the presence of a right stimulus. Most polymers, either thermo-plastic or thermoset, can have the SME, although the actual shape memory performance varies according to the exact material and how the material is processed. Vitrimer, which is between thermoset and thermo-plastic, is featured by the reversible cross-linking. Vitrimer-like shape memory polymers (SMPs) combine the vitrimer-like behavior (associated with dissociative covalent adaptable networks) and SME, and can be utilized t

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Uddin, Md Hanif, Sultan Alshali, Esam Alqurashi, Saber Alyoubi, Natalia Walters, and Ishrat M. Khan. "Recyclable Thermoplastic Elastomer from Furan Functionalized Hairy Nanoparticles with Polystyrene Core and Polydimethylsiloxane Hairs." Polymers 16, no. 22 (2024): 3117. http://dx.doi.org/10.3390/polym16223117.

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Polymers synthesized with end-of-life consideration allow for recovery and reprocessing. “Living-anionic polymerization (LAP)” and hydrosilylation reaction were utilized to synthesize hair-end furan functionalized hairy nanoparticles (HNPs) with a hard polystyrene (PS) core and soft polydimethylsiloxane (PDMS) hairs via a one-pot approach. The synthesis was carried out by first preparing the living core through crosslinking styrene with divinylbenzene using sec-butyl lithium, followed by the addition of the hexamethylcyclotrisiloxane (D3) monomer to the living core. The living polymer was term

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Dissertations / Theses on the topic "Thermo Reversible Polymers"

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Zhao, Feng D. "The processing of thermotropic liquid crystalline polymers within a polypropylene matrix for the production of oriented thermo-reversible blends." Thesis, University of Cambridge, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.338073.

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Wang, Chao. "EFFECT OF REVERSIBLE CROSSLINKS ON NANOSTRUCTURE AND PROPERTIES OF SUPRAMOLECULAR HYDROGELS." University of Akron / OhioLINK, 2018. http://rave.ohiolink.edu/etdc/view?acc_num=akron1532958316052167.

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Brunet, Juliette. "Harnessing boron reactivity for the synthesis of dynamic and reversible polymer networks." Thesis, Lyon, 2019. http://www.theses.fr/2019LYSE1198.

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Ces travaux de thèse portent sur l’élaboration et l’étude des propriétés thermomécaniques de polymères dynamiques incorporant des dérivés borés. Tout en appliquant ce concept sur une variété d’architectures macromoléculaires : copolymères fonctionnels, briques di- et tri-fonctionelles, deux réactivités distinctes du bore ont été étudiées et exploitées. Une large gamme de méthodes de caractérisation a été utilisée pour mener à bien ce projet : spectroscopies FTIR et RMN sous différents stimuli, ainsi que de nombreuses analyses thermiques et mécaniques. Dans un premier temps, nous avons considér

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Okhay, Nidhal. "Synthèse de réseaux polymères thermoréversibles par réaction de Diels-Alder." Phd thesis, Université Jean Monnet - Saint-Etienne, 2012. http://tel.archives-ouvertes.fr/tel-00951977.

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Cette étude porte sur l'application de la réaction de Diels-Alder dans la synthèse de réseaux polymères thermoréversibles ainsi que la compatibilisation de mélanges de polymères initialement immiscibles. Les polymères étudiés ne sont autres que le polyméthacrylate de méthyle et le polyuréthane. Les réseaux thermoréversibles sont obtenus par réaction de Diels-Alder faisant intervenir le couple furanne-maléimide. Les polymères fonctionnalisés furanne ou maléimide sont obtenus soit par modification chimique d'un polymère commercial (cas du PMMA) soit par réaction de polyaddition (cas du polyuréth

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Willett, Erik Amos. "CO2 Capture on Polymer-Silica Composites from Molecular Modeling to Pilot Scale." University of Akron / OhioLINK, 2018. http://rave.ohiolink.edu/etdc/view?acc_num=akron152147716339683.

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Book chapters on the topic "Thermo Reversible Polymers"

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Larsson, A., D. Kuckling, and M. Schönhoff. "1H-NMR-Investigation of the Phase Transition of Thermo-Reversible Polymers in Solution and at Interfaces." In Magnetic Resonance in Colloid and Interface Science. Springer Netherlands, 2002. http://dx.doi.org/10.1007/978-94-010-0534-0_58.

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J. Salavagione, Horacio, Araceli Flores, and Marián A. Gómez-Fatou. "Perspective Chapter: Harnessing the Photothermal Effect of Graphene for Self-Healing and Recycling of Polymers." In Graphene - The Next Generation Material [Working Title]. IntechOpen, 2025. https://doi.org/10.5772/intechopen.1010602.

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Graphene burst onto the material science scene around 20 years ago. Since then, countless investigations have been carried out in almost every field. In the particular case of polymer materials, their potential applications are mainly based on the combination of properties such as high surface area and low density, as well as their mechanical, electrical, and thermal properties, among others. Due to its excellent thermal conductivity, graphene is used in areas such as phase change materials, thermal interface materials, and aerospace. However, its thermal properties are underexploited as they

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Goyal, Priya, Anjana Sarkar, Sanjeeve Thakur, and Usama Ansari. "THERMORESPONSIVE SMART POLYMERS AND THEIR APPLICATIONS IN THE BIOMEDICAL FIELD." In Futuristic Trends in Chemical Material Sciences & Nano Technology Volume 3 Book 18. Iterative International Publishers, Selfypage Developers Pvt Ltd, 2024. http://dx.doi.org/10.58532/v3bdcs18ch31.

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Thermo-responsive polymers have gained significant attention in the realm of biological applications owing to their distinctive capacity to undergo reversible phase transitions in reaction to temperature variations. These polymers demonstrate a distinct shift from a water-loving (hydrophilic) to a water-repelling (hydrophobic) state across a limited temperature range. As a result, they are highly suitable for precise administration of drugs and use in tissue engineering. The chapter begins with providing insights of the smart polymers and their different categories based their sensitivity towa

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Mark, James E., Harry R. Allcock, and Robert West. "Ferrocene-Based Polymers, and Additional Phosphorus- and Boron-Containing Polymers." In Inorganic Polymers. Oxford University Press, 2005. http://dx.doi.org/10.1093/oso/9780195131192.003.0010.

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Ferrocene is an inexpensive, stable molecule with an interesting and reversible electrochemistry. It is synthesized by the metal-hydrogen exchange reaction of cyclopentadiene with sodium followed by treatment of the resultant sodium cyclopentadienide anion with ferrous chloride. The high stability and electroactivity of the ferrocene molecule has prompted numerous attempts to incorporate it into polymer structures. So, too, has the inherent torsional freedom of the cyclopentadienyl groups around the iron atoms and their capacity to serve as swivel group sites. Polymerization attempts range fro

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Zhang, Guiyang. "Applications of Covalent Organic Frameworks (COFs) in Oncotherapy." In Covalent Organic Frameworks [Working Title]. IntechOpen, 2022. http://dx.doi.org/10.5772/intechopen.106969.

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Covalent organic frameworks (COFs) are emerging organic crystalline polymer materials, which are formed by reversible condensation reactions between lightweight molecular fragments. They have excellent properties such as low density, good porosity and crystallinity, and high thermal stability. These materials are biodegradable due to the reversible condensation process between the monomers. Compared with another widely studied material with metal-organic frameworks, COFs have no additional toxicity caused by introducing metal ions. Therefore, a high potential exists in biomedicine. The chapter

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Farooq, Owais, Neelima Mahato, Malik Abdul Wahid, Yashwant Mehta, and Hardeep Kaur. "Conducting Polymer-Carbon Material-Based Nanostructured Composites for Energy Storage and Conversion." In Advances in Chemical and Materials Engineering. IGI Global, 2024. http://dx.doi.org/10.4018/979-8-3693-4397-5.ch013.

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Nanomaterials have gained tremendous applications in multiple fields like biomedical, environmental and energy storage applications. Their versatility and multifunctionality makes them an exquisite choice in such fields which is a direct consequence of features like increased surface area to volume ratio, quantum confinement, increased chemical reactivity, tailored functionalization, tunable emission, enhanced mechanical and thermal conductivity along with drug delivery and diagnostics. Conducting polymers, on the other hand, offer high electrical conductivity and high mechanical strength in a

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Zainal, Nurfarahin, Ku Marsilla Ku Ishak, and Yazmin Bustami. "Smart Hydrogel Film of Bionanocellulose/Alginate/Polyethylene Glycol/Thermochromic Dye (BNC/ALG/PEG/TD) with Thermo-Responsive Behavior." In Application of Alginate - Based Smart Materials [Working Title]. IntechOpen, 2025. https://doi.org/10.5772/intechopen.1008224.

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We aim to explore bionanocellulose/alginate/polyethylene glycol/thermochromic dye (BNC/ALG/PEG/TD) as a thermo-responsive hydrogel film. In this study, BNC was produced using Pichia kudriavzevii USM-YBP2. Then, the morphology of BNC was observed using transmission electron microscope (TEM). The formation of hydrogel film utilized the ionic crosslinking technique by mixing BNC, ALG, PEG, and thermochromic dye (TD) with Ca2+ ions. Then, the hydrogel film was evaluated for its swelling property, thermo-responsive behavior, and biodegradability. BNC exhibits aggregated fiber and clusters of spheri

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Bustamante-Torres, Moises, David Romero-Fierro, Bryan Chiguano-Tapia, Estefani Chichande-Proaño, and Emilio Bucio. "Hydrogels and Nanohydrogels." In Frontiers in Nanomedicine. BENTHAM SCIENCE PUBLISHERS, 2023. http://dx.doi.org/10.2174/9789815136920123030009.

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Hydrogels and nanogels are exciting and promising materials for many applications due to their versatile features, such as interacting and absorbing a significant amount of water and other solvents, excellent mechanical properties, and adhesiveness. These materials are obtained based on the nature of the raw materials (natural or synthetic) and the synthesis route. There are many ways to synthesize hydrogels and nanogels; however, these routes can be classified as physical or chemical. Physical synthesis forms a reversible cross-linking. In contrast, chemical synthesis can generate a stable, r

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Peri, Angela Denise. "A Smart Materials Driven Approach to the Interior Design of Cruise Ships." In Progress in Marine Science and Technology. IOS Press, 2023. http://dx.doi.org/10.3233/pmst230027.

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The cruise ship unit is often defined as a “floating city” where the presence of large, open and closed spaces reproduces, in terms of dimensions and functions, those of public and private civil architecture. The aim of this research activity is to identify a theoretical process of mutual interaction among these two fields and functional links between material, technology and design, starting from a scoping activity review of the currently constituent finishing materials. This can lead to a possible application of adaptive solutions, which mainly rely on the use of smart materials, where exter

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Conference papers on the topic "Thermo Reversible Polymers"

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Advincula, Rigoberto C. "3D Printing High Performance Polymers and the Oil and Gas Industry." In CORROSION 2019. NACE International, 2019. https://doi.org/10.5006/c2019-13505.

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Abstract Additive manufacturing and 3D printing hold a number of promise in bringing on-demand and high-performance parts production capable of adding high value to the oil and gas industry. Non-metallic parts offer a number of advantages in reducing corrosion issues and enabling properties such as high-temperature resistance or reversibly, dissolvable or degradable properties. However, most parts used for completion and down-hole tools are still based on traditional molding, extrusion, thermoforming, etc. methods. 3D printing methods (FDM, SLA, SLA, VSP, etc.) holds promise in fabricating par

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Growcock, F. B. "Inhibition of Steel Corrosion in Hydrochloric Acid by Acetylenic Alcohols." In CORROSION 1988. NACE International, 1988. https://doi.org/10.5006/c1988-88338.

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Abstract We have elucidated the mechanisms by which some aliphatic and aromatic acetylenic alcohols inhibit corrosion of steel in hydrochloric acid. Corrosion kinetics, electrochemical measurements and product analyses of systems containing l-octyn-3-ol, 3-phenyl-2-propyn-1-ol (3-PPO) and 1-phenyl-2-propyn-1-ol (1-PPO) indicate that, in all cases, the active inhibitor is first protonated, reversibly adsorbs and then undergoes irreversible reactions to form a polymer film. The chemisorbed inhibitor provides the majority of the corrosion protection, but the polymer film offers some protection as

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Prasad, Aayush, Swapnil Moon, Fangda Cui, and I. J. Rao. "Constitutive Modeling of Viscoelastic Photo-Adaptable Thermally Activated Shape Memory Polymers." In ASME 2021 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2021. http://dx.doi.org/10.1115/imece2021-70514.

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Abstract Shape memory polymer (SMPs) are a class of smart materials that have the ability to retain multiple temporary shapes and recover original shapes as they exhibit deformation in response to external stimuli. The shape change in these polymers can be triggered using different stimuli like temperature, light, water, pH, magnetism, and their mechanisms can be easily altered. SMPs are capable of displaying multiple temporary and one permanent shape by either creating a multiphase system or by undergoing a very broad thermal transition. SMPs and their composites are also easy to manufacture,

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Singh, Praveen Kumar, Abhishek Sahu, Bhaskara Chirravuri, and Ronald Miller. "Low Cycle Thermo-Mechanical Fatigue Life of Solder Joints Using Cohesive Zone Model." In 11th SAEINDIA International Mobility Conference (SIIMC 2024). SAE International, 2024. https://doi.org/10.4271/2024-28-0253.

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<div class="section abstract">A temperature dependent cohesive zone model considering the thermo-mechanical fatigue loadings are used to simulate and predict the failure process of solder joint interface in power electronics modules. Cohesive Zone Models (CZMs) are gaining popularity for modeling the fracture and fatigue behavior in various class of materials such as metals, polymers, ceramics, and their composite materials. Unlike the traditional fracture mechanics which considers concept of infinitesimal crack, CZMs assume a fracture process zone in which external energy is distributed

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Boluk, Yaman, Xiaoyi Lan, and Adetola Adesida. "Additive Manufacturing by Gel-in-Gel Printing." In The Nordic Rheology Conference. University of Stavanger, 2024. http://dx.doi.org/10.31265/atnrs.778.

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Additive manufacturing by the 3D-printing processes enables solid free-form fabrication of three-dimensional objects directly from the digital images by melt prepolymers and gels following the post-curing of deposited polymers. Those processes have limitations due to long printing times, low-quality materials, and costs. The gel in gel printing by printing low viscosity materials in a support gel environment addresses those limitations. This process deposits a relatively low viscosity but curable liquids or gels into a medium of support gel. The support gel prevents the collapse or deformity o

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Barrett, C., A. Natansohn, P. Rochon, and S. Xie. "Thermal Cis-Trans Isomerization Rates Of Azobenzenes Bound In Acrylate Polymers." In Organic Thin Films for Photonic Applications. Optica Publishing Group, 1993. http://dx.doi.org/10.1364/otfa.1993.wd.26.

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Amorphous high glass transition polymer films containing electron-donor electron-acceptor substituted azobenzene groups can be used as materials for reversible optical storage1. A polarized argon laser beam is used for "writing" while a low power HeNe laser can "read" the resulting oriented regions, and irradiation with circularly polarized light destroys the order, effectively "erasing" the signal. As orientation is induced by a series of trans-cis-trans isomerizations of the azo groups, writing speeds and efficiencies depend on the rates of these isomerizations. Films of a series of azo poly

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Shahinpoor, Mohsen. "Electrically Controllable Deformations in Ionic Polymer Metal Composite Actuators." In ASME 2002 International Mechanical Engineering Congress and Exposition. ASMEDC, 2002. http://dx.doi.org/10.1115/imece2002-39037.

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Ionic polymer metal composites (IPMC’s) exhibit spectacular coupling between electrical and mechanical domains. Sensing and actuation properties of these materials and the force and displacement characteristics have been investigated as a means of determining the electromechanical coupling coefficients of the material. An electric field applied across the thickness of the polymer causes electrophoretic ionic migration within the material. Electro-osmotic drag induces solvent migration in addition to the ion motion, and a stress is generated within the material causing the material to deform. T

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Halter, J. M., and N. E. Iwamoto. "Thermal-Mechanical Modeling Of A Reversible Dye-Polymer Media." In 1988 Los Angeles Symposium--O-E/LASE '88, edited by Donald B. Carlin, Albert A. Jamberdino, and Yoshito Tsunoda. SPIE, 1988. http://dx.doi.org/10.1117/12.944626.

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Kimura, Daisuke, Toshihira Irisawa, Wataru Takarada, and Masatoshi Shioya. "The relation between reversible thermal shrinkage and orientation change of polyamide fibers." In PROCEEDINGS OF THE 37TH INTERNATIONAL CONFERENCE OF THE POLYMER PROCESSING SOCIETY (PPS-37). AIP Publishing, 2023. http://dx.doi.org/10.1063/5.0169287.

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Anand, V. S., K. V. Vimal, and Susy Varughese. "Solvent Induced Shape Memory Behaviour of Sulfonated Poly Ether Ether Ketone (SPEEK)." In ASME 2012 Conference on Smart Materials, Adaptive Structures and Intelligent Systems. American Society of Mechanical Engineers, 2012. http://dx.doi.org/10.1115/smasis2012-7968.

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Shape memory polymers (SMPs) are a widely studied class of materials due to their numerous applications in various fields of engineering. They find applications in deployable structures, biomedical devices, adaptive optical devices, sensors and actuators, in textiles etc. Recent studies have shown shape memory behavior in many polymers. Sulfonated poly ether ether ketone (SPEEK) is an ionic polymer which is being extensively studied for its application in fuel cells as a Proton Exchange Membrane (PEM) polymer due to its relatively higher thermal and mechanical stability over other PEMs in addi

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