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Journal articles on the topic 'Thermo Reversible Polymers'

Author: Grafiati

Published: 4 June 2025

Last updated: 1 August 2025

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1

Orozco, Felipe, Zafarjon Niyazov, Timon Garnier, et al. "Maleimide Self-Reaction in Furan/Maleimide-Based Reversibly Crosslinked Polyketones: Processing Limitation or Potential Advantage?" Molecules 26, no. 8 (2021): 2230. http://dx.doi.org/10.3390/molecules26082230.

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Polymers crosslinked via furan/maleimide thermo-reversible chemistry have been extensively explored as reprocessable and self-healing thermosets and elastomers. For such applications, it is important that the thermo-reversible features are reproducible after many reprocessing and healing cycles. Therefore, side reactions are undesirable. However, we have noticed irreversible changes in the mechanical properties of such materials when exposing them to temperatures around 150 °C. In this work, we study whether these changes are due to the self-reaction of maleimide moieties that may take place a

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2

Pal, Sunirmal, Megan R. Hill, and Brent S. Sumerlin. "Doubly-responsive hyperbranched polymers and core-crosslinked star polymers with tunable reversibility." Polymer Chemistry 6, no. 45 (2015): 7871–80. http://dx.doi.org/10.1039/c5py01295c.

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Thermo- and redox-responsive hyperbranched copolymers were prepared by statistical copolymerization of N-isopropylacrylamide (NIPAM) and N,N′-bis(acryloyl)cystamine (BAC) by reversible addition–fragmentation chain transfer (RAFT) polymerization.

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3

Kim, Young-Jin, and Yukiko T. Matsunaga. "Thermo-responsive polymers and their application as smart biomaterials." Journal of Materials Chemistry B 5, no. 23 (2017): 4307–21. http://dx.doi.org/10.1039/c7tb00157f.

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4

TAKIGUCHI, Yasuhiro, Ryoichi KISHI, Hisao ICHIJO, and Okihiko HIRASA. "Polymers and Environment II. Thermo-Reversible Separation of Organic Substances by Using Thermo-Responsive Polymer Gel." KOBUNSHI RONBUNSHU 50, no. 11 (1993): 905–8. http://dx.doi.org/10.1295/koron.50.905.

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5

Li, Boyu, Joey Kim, and Julie Kornfield. "A Molecular Picture for the Thermo-Reversibility of Gels Formed by Isophthalic Acid-Ended Telechelic Polymers." MRS Proceedings 1794 (2015): 9–14. http://dx.doi.org/10.1557/opl.2015.638.

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ABSTRACTWe demonstrate that isophthalic acid-ended telechelic poly(1,5-cyclooctadiene)s (A-PCODs) form thermo-reversible gels in non-polar solvent with a unique molecular mechanism for their thermo-reversibility. Like other associative telechelic polymers, A-PCODs form “flower-like” micelles at low concentration and form gels through bridging at higher concentration which exhibit linear viscoelasticity. However, unlike the widely studied hydrophobically end-capped PEOs, A-PCODs show clear thermo-reversibility in viscosity and dynamic modulus around 30 °C due to the hydrogen-bonding end groups.

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6

Gao, Yulei, Zhou Deng, Fenfen Wang, and Pingchuan Sun. "Achieving long lifetime of room-temperature phosphorescence via constructing vitrimer networks." Materials Chemistry Frontiers 6, no. 8 (2022): 1068–78. http://dx.doi.org/10.1039/d2qm00003b.

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Fluorescence and RTP dual emission polymers exhibit reversible temperature responsiveness, tunable mechanical properties, remarkable thermostability and thermo-adaptive self-healing ability based on a dynamic covalently crosslinked 3D network.

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7

Abend, Zechel, Schubert, and Hager. "Detailed Analysis of the Influencing Parameters on the Self-Healing Behavior of Dynamic Urea-Crosslinked Poly(methacrylate)s." Molecules 24, no. 19 (2019): 3597. http://dx.doi.org/10.3390/molecules24193597.

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For this paper, the self-healing ability of poly(methacrylate)s crosslinked via reversible urea bonds was studied in detail. In this context, the effects of healing time and temperature on the healing process were investigated. Furthermore, the impact of the size of the damage (i.e., area of the scratch) was monitored. Aging processes, counteracting the self-healing process, result in a decrease in the mechanical performance. This effect diminishes the healing ability. Consequently, the current study is a first approach towards a detailed analysis of self-healing polymers regarding the influen

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8

Ni, Yiping, Frédéric Becquart, Jianding Chen, and Mohamed Taha. "Polyurea–Urethane Supramolecular Thermo-Reversible Networks." Macromolecules 46, no. 3 (2013): 1066–74. http://dx.doi.org/10.1021/ma302421r.

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9

Wang, Tao Xi, Hong Mei Chen, Abhijit Vijay Salvekar, et al. "Vitrimer-Like Shape Memory Polymers: Characterization and Applications in Reshaping and Manufacturing." Polymers 12, no. 10 (2020): 2330. http://dx.doi.org/10.3390/polym12102330.

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The shape memory effect (SME) refers to the ability of a material to recover its original shape, but only in the presence of a right stimulus. Most polymers, either thermo-plastic or thermoset, can have the SME, although the actual shape memory performance varies according to the exact material and how the material is processed. Vitrimer, which is between thermoset and thermo-plastic, is featured by the reversible cross-linking. Vitrimer-like shape memory polymers (SMPs) combine the vitrimer-like behavior (associated with dissociative covalent adaptable networks) and SME, and can be utilized t

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10

Uddin, Md Hanif, Sultan Alshali, Esam Alqurashi, Saber Alyoubi, Natalia Walters, and Ishrat M. Khan. "Recyclable Thermoplastic Elastomer from Furan Functionalized Hairy Nanoparticles with Polystyrene Core and Polydimethylsiloxane Hairs." Polymers 16, no. 22 (2024): 3117. http://dx.doi.org/10.3390/polym16223117.

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Polymers synthesized with end-of-life consideration allow for recovery and reprocessing. “Living-anionic polymerization (LAP)” and hydrosilylation reaction were utilized to synthesize hair-end furan functionalized hairy nanoparticles (HNPs) with a hard polystyrene (PS) core and soft polydimethylsiloxane (PDMS) hairs via a one-pot approach. The synthesis was carried out by first preparing the living core through crosslinking styrene with divinylbenzene using sec-butyl lithium, followed by the addition of the hexamethylcyclotrisiloxane (D3) monomer to the living core. The living polymer was term

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11

Li, Min-Hui, and Patrick Keller. "Artificial muscles based on liquid crystal elastomers." Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 364, no. 1847 (2006): 2763–77. http://dx.doi.org/10.1098/rsta.2006.1853.

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This paper presents our results on liquid crystal (LC) elastomers as artificial muscle, based on the ideas proposed by de Gennes. In the theoretical model, the material consists of a repeated series of main-chain nematic LC polymer blocks, N, and conventional rubber blocks, R, based on the lamellar phase of a triblock copolymer RNR. The motor for the contraction is the reversible macromolecular shape change of the chain, from stretched to spherical, that occurs at the nematic-to-isotropic phase transition in the main-chain nematic LC polymers. We first developed a new kind of muscle-like mater

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12

Petrauskas, Rokas, Sigita Grauzeliene, and Jolita Ostrauskaite. "Thermo-Responsive Shape-Memory Dual-Cured Polymers Based on Vegetable Oils." Materials 17, no. 1 (2023): 24. http://dx.doi.org/10.3390/ma17010024.

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The development of thermo-responsive shape-memory polymers has attracted attention due to their ability to undergo reversible deformations based on temperature changes. Vegetable oils are confirmed to be an excellent biorenewable source of starting materials for the synthesis of polymers. Therefore, the objective of this research was to synthesize thermo-responsive shape-memory polymers based on vegetable oils by using the dual-curing technique and obtaining polymers with tailorable properties. Acrylated epoxidized soybean oil and two epoxidized vegetable oils, linseed oil and camelina oil, we

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13

Wang, J. Q., and M. Satoh. "A novel reversible thermo-swelling hydrogel." Express Polymer Letters 4, no. 7 (2010): 450–54. http://dx.doi.org/10.3144/expresspolymlett.2010.56.

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14

Parmar, Indravadan A., Aarti S. Shedge, Manohar V. Badiger, Prakash P. Wadgaonkar, and Ashish K. Lele. "Thermo-reversible sol–gel transition of aqueous solutions of patchy polymers." RSC Advances 7, no. 9 (2017): 5101–10. http://dx.doi.org/10.1039/c6ra27030a.

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Aqueous solutions of an amphiphilic thermoreversible patchy polymer show abrupt gelation upon cooling by the combined effect of percolation and transition from intra to intermolecular hydrophobic associations.

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15

Li, Yan-Yun, Xiao-Qin Jiang, Min Zhang, and Guoyue Shi. "A visual and reversible assay for temperature using thioflavin T-doped lanthanide/nucleotide coordination polymers." Analyst 141, no. 8 (2016): 2347–50. http://dx.doi.org/10.1039/c6an00274a.

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16

Manfredini, Nicolò, Marco Tomasoni, Mattia Sponchioni, and Davide Moscatelli. "Influence of the Polymer Microstructure over the Phase Separation of Thermo-Responsive Nanoparticles." Polymers 13, no. 7 (2021): 1032. http://dx.doi.org/10.3390/polym13071032.

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Thermo-responsive nanoparticles (NPs), i.e., colloids with a sharp and often reversible phase separation in response to thermal stimuli, are coming to the forefront due to their dynamic behavior, useful in applications ranging from biomedicine to advanced separations and smart optics. What is guiding the macroscopic behavior of these systems above their critical temperature is mainly the microstructure of the polymer chains of which these NPs are comprised. Therefore, a comprehensive understanding of the influence of the polymer properties over the thermal response is highly required to reprod

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17

Bat, Erhan, En-Wei Lin, Sina Saxer, and Heather D. Maynard. "Morphing Hydrogel Patterns by Thermo-Reversible Fluorescence Switching." Macromolecular Rapid Communications 35, no. 14 (2014): 1260–65. http://dx.doi.org/10.1002/marc.201400160.

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18

Xue, Xuan, Feifei Wang, Minhao Shi, and Faez Iqbal Khan. "Synthesis of Thermo-Responsive Monofunctionalized Diblock Copolymer Worms." Polymers 15, no. 23 (2023): 4590. http://dx.doi.org/10.3390/polym15234590.

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Poly(glycerol monomethacrylate)-block-poly(2-hydroxypropyl methacrylate) (PGMA-PHPMA) with worm-like morphology is a typical example of reversible addition–fragmentation chain transfer (RAFT) dispersion polymerized thermo-responsive copolymer via polymerization-induced self-assembly (PISA) in aqueous solution. Chain transfer agents (CTAs) are the key component in controlling RAFT, the structures of which determine the end functional groups of the polymer chain. It is therefore of interest to monofunctionalize the polymers via CTA moiety, for bioactive functionality conjugation and in the meant

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19

Echeverría, Coro, Miguel Rubio, and Daniel López. "Thermo-Reversible Hybrid Gels Formed from the Combination of Isotactic Polystyrene and [Fe(II) (4-Octadecyl-1,2,4-Triazole)3(ClO4)2]n Metallo-Organic Polymer: Thermal and Viscoelastic Properties." Polymers 11, no. 6 (2019): 957. http://dx.doi.org/10.3390/polym11060957.

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Nano-sized one-dimensional metallo-organic polymers, characterized by the phenomenon of spin transition, are excellent candidates for advanced technological applications such as optical sensors, storage, and information processing devices. However, the main drawback of this type of polymers is their fragile mechanical properties, which hinders its processing and handling, and makes their practical use unfeasible. To overcome this problem, in this work, hybrid thermo-reversible gels are synthesized by combination of a metallo-organic polymer and isotactic polystyrene (iPS) in cis-decaline. A de

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20

Lorero, Isaac, Álvaro Rodríguez, Mónica Campo, and Silvia G. Prolongo. "Development of an Electroactive and Thermo-Reversible Diels–Alder Epoxy Nanocomposite Doped with Carbon Nanotubes." Polymers 15, no. 24 (2023): 4715. http://dx.doi.org/10.3390/polym15244715.

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The manufacturing of Diels–Alder (D-A) crosslinked epoxy nanocomposites is an emerging field with several challenges to overcome: the synthesis is complex due to side reactions, the mechanical properties are hindered by the brittleness of these bonds, and the content of carbon nanotubes (CNT) added to achieve electroactivity is much higher than the percolation thresholds of other conventional resins. In this work, we develop nanocomposites with different D-A crosslinking ratios (0, 0.6, and 1.0) and CNT contents (0.1, 0.3, 0.5, 0.7, and 0.9 wt.%), achieving a simplified route and avoiding the

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21

Padhan, Anil K., and Debaprasad Mandal. "Thermo-reversible self-healing in a fluorous crosslinked copolymer." Polymer Chemistry 9, no. 23 (2018): 3248–61. http://dx.doi.org/10.1039/c8py00471d.

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22

Zhao, Jing, Victoria E. Lee, Rui Liu, and Rodney D. Priestley. "Responsive Polymers as Smart Nanomaterials Enable Diverse Applications." Annual Review of Chemical and Biomolecular Engineering 10, no. 1 (2019): 361–82. http://dx.doi.org/10.1146/annurev-chembioeng-060718-030155.

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Responsive polymers undergo reversible or irreversible physical or chemical modifications in response to a change in environment or stimulus, e.g., temperature, pH, light, and magnetic or electric fields. Polymeric nanoparticles (NPs), which constitute a diverse set of morphologies, including micelles, vesicles, and core-shell geometries, have been successfully prepared from responsive polymers and have shown great promise in applications ranging from drug delivery to catalysis. In this review, we summarize pH, thermo-, photo-, and enzymatic responsiveness for a selection of polymers. We then

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23

Teramoto, Naozumi, Yohei Arai, and Mitsuhiro Shibata. "Thermo-reversible Diels–Alder polymerization of difurfurylidene trehalose and bismaleimides." Carbohydrate Polymers 64, no. 1 (2006): 78–84. http://dx.doi.org/10.1016/j.carbpol.2005.10.029.

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24

Yamagami, Mao, Hiroshi Kamitakahara, Arata Yoshinaga, and Toshiyuki Takano. "Thermo-reversible supramolecular hydrogels of trehalose-type diblock methylcellulose analogues." Carbohydrate Polymers 183 (March 2018): 110–22. http://dx.doi.org/10.1016/j.carbpol.2017.12.006.

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25

Aguilar, Nery M., José Manuel Pérez-Aguilar, Valeria J. González-Coronel, et al. "Reversible Thermo-Optical Response Nanocomposites Based on RAFT Symmetric Triblock Copolymers (ABA) of Acrylamide and N-Isopropylacrylamide and Gold Nanoparticles." Polymers 15, no. 8 (2023): 1963. http://dx.doi.org/10.3390/polym15081963.

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The development of composite materials with thermo-optical properties based on smart polymeric systems and nanostructures have been extensively studied. Due to the fact of its ability to self-assemble into a structure that generates a significant change in the refractive index, one of most attractive thermo-responsive polymers is poly(N-isopropylacrylamide) (PNIPAM), as well as its derivatives such as multiblock copolymers. In this work, symmetric triblock copolymers of polyacrylamide (PAM) and PNIPAM (PAMx-b-PNIPAMy-b-PAMx) with different block lengths were prepared by reversible addition−fra

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26

Giuliano, Elena, Donatella Paolino, Massimo Fresta, and Donato Cosco. "Drug-Loaded Biocompatible Nanocarriers Embedded in Poloxamer 407 Hydrogels as Therapeutic Formulations." Medicines 6, no. 1 (2018): 7. http://dx.doi.org/10.3390/medicines6010007.

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Hydrogels are three-dimensional networks of hydrophilic polymers able to absorb and retain a considerable amount of water or biological fluid while maintaining their structure. Among these, thermo-sensitive hydrogels, characterized by a temperature-dependent sol–gel transition, have been massively used as drug delivery systems for the controlled release of various bioactives. Poloxamer 407 (P407) is an ABA-type triblock copolymer with a center block of hydrophobic polypropylene oxide (PPO) between two hydrophilic polyethyleneoxide (PEO) lateral chains. Due to its unique thermo-reversible gelat

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27

Ramírez-Jiménez, Montoya-Villegas, Licea-Claverie, and Gónzalez-Ayón. "Tunable Thermo-Responsive Copolymers from DEGMA and OEGMA Synthesized by RAFT Polymerization and the Effect of the Concentration and Saline Phosphate Buffer on its Phase Transition." Polymers 11, no. 10 (2019): 1657. http://dx.doi.org/10.3390/polym11101657.

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Thermo-responsive polymers and copolymers derivatives of oligo(ethylene glycol) methyl ether methacrylate (Mn = 300 g mol−1) (OEGMA) and di(ethylene glycol) methyl ether methacrylate (DEGMA) have been synthesized by reversible addition fragmentation chain transfer polymerization (RAFT) using 5-amino-4-methyl-4-(propylthiocarbonothioylthio)-5-oxopentanoic acid (APP) as chain transfer agent (CTA). The monomer conversion was evaluated by hydrogen nuclear magnetic resonance (1H-NMR); number average molecular weights (Mn), weight average molecular weight (Mw), and dispersity (Đ) were obtained by ge

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28

Zhang, Liangdong, Teng Qiu, Zhiqiang Zhu, Longhai Guo, and Xiaoyu Li. "Self-Healing Polycaprolactone Networks through Thermo-Induced Reversible Disulfide Bond Formation." Macromolecular Rapid Communications 39, no. 20 (2018): 1800121. http://dx.doi.org/10.1002/marc.201800121.

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29

Wang, Ruomiao, Xingcheng Xiao, and Tao Xie. "Viscoelastic Behavior and Force Nature of Thermo-Reversible Epoxy Dry Adhesives." Macromolecular Rapid Communications 31, no. 3 (2009): 295–99. http://dx.doi.org/10.1002/marc.200900594.

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30

Ren, Q., X. J. Wang, Y. Q. Zhao, et al. "Thermo-Responsive Shape Memory Behavior of Methyl Vinyl Silicone Rubber/Olefin Block Copolymer Blends via Co-Crosslinking." International Polymer Processing 36, no. 1 (2021): 26–34. http://dx.doi.org/10.1515/ipp-2020-3927.

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Abstract Shape memory polymers (SMPs) are developed by blending and cross-linking polymers which include crystalline domains and cross-linked networks. In this paper, we describe the morphology, thermal and shape memory behavior of methyl vinyl silicone rubber (MVMQ)/olefin block copolymer (OBC) blends prepared by a melt-blending and chemical cross-linking method. MVMQ without crystalline domains could not hold its temporary shape. After introducing the OBC, the obtained blends exhibited excellent dual shape memory properties. The cross-linking networks of MVMQ acted as reversible domains, whi

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31

Kishi, Hajime, Takuya Nakamura, Seitaro Hagiwara, and Yoshiaki Urahama. "Thermo-reversible phase structures of lightly cross-linked PDMS/MQ silicone polymer blends." Polymer 200 (June 2020): 122574. http://dx.doi.org/10.1016/j.polymer.2020.122574.

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32

Hao, Ran. "Responsive self-assembly of nanomaterials: Mechanisms, applications, and future perspectives." Applied and Computational Engineering 60, no. 1 (2024): 191–96. http://dx.doi.org/10.54254/2755-2721/60/20240871.

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In the development of nanotechnology, responsive self-assembly has been an important research theme. Responsive self-assembly is a technique where nanoparticles form structures in response to external stimuli like temperature and light. Thermo-responsive and photo-controlled self-assembly processes are outstanding compared with traditional methods, and theyve been applied in drug delivery and smart surfaces. Yet, the two processes still have their own challenges in practical applications. This review explores both techniques for explaining how these external stimuli work and the role of nanoma

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33

Mizoue, Yoko, Rintaro Takahashi, Kazuo Sakurai, and Shin-ichi Yusa. "A Thermo-Responsive Polymer Micelle with a Liquid Crystalline Core." Polymers 15, no. 3 (2023): 770. http://dx.doi.org/10.3390/polym15030770.

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An amphiphilic diblock copolymer (PChM-PNIPAM), composed of poly(cholesteryl 6-methacryloyloxy hexanoate) (PChM) and poly(N-isopropyl acrylamide) (PNIPAM) blocks, was prepared via reversible addition–fragmentation chain transfer radical polymerization. The PChM and PNIPAM blocks exhibited liquid crystalline behavior and a lower critical solution temperature (LCST), respectively. PChM-PNIPAM formed water-soluble polymer micelles in water below the LCST because of hydrophobic interactions of the PChM blocks. The PChM and PNIPAM blocks formed the core and hydrophilic shell of the micelles, respec

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34

Wu, Yufeng, Dingwei Zhu, Zanru Guo, and Yujun Feng. "Rheology and phase behavior of thermo-reversible pentablock terpolymer hydrogel." Journal of Polymer Science Part B: Polymer Physics 51, no. 18 (2013): 1335–42. http://dx.doi.org/10.1002/polb.23343.

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35

Defize, Thomas, Raphaël Riva, Jean-Michel Thomassin, Christine Jérôme, and Michaël Alexandre. "Thermo-Reversible Reactions for the Preparation of Smart Materials: Recyclable Covalently-Crosslinked Shape Memory Polymers." Macromolecular Symposia 309-310, no. 1 (2011): 154–61. http://dx.doi.org/10.1002/masy.201100036.

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36

Satoh, Hiroyuki, Aya Mineshima, Taro Nakamura, Naozumi Teramoto, and Mitsuhiro Shibata. "Thermo-reversible Diels–Alder polymerization of difurfurylidene diglycerol and bismaleimide." Reactive and Functional Polymers 76 (March 2014): 49–56. http://dx.doi.org/10.1016/j.reactfunctpolym.2014.01.009.

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37

Janssen, Rob H. C., Volker Stümpflen, Marysia C. W. van Boxtel, et al. "Thermo-reversible gelation of liquid crystals using di-benzylidene-D-sorbitol." Macromolecular Symposia 154, no. 1 (2000): 117–26. http://dx.doi.org/10.1002/1521-3900(200004)154:1<117::aid-masy117>3.0.co;2-7.

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38

Yoon, Jun Hyok, Taehyoung Kim, Myungeun Seo, and Sang Youl Kim. "Synthesis and Thermo-Responsive Behavior of Poly(N-isopropylacrylamide)-b-Poly(N-vinylisobutyramide) Diblock Copolymer." Polymers 16, no. 6 (2024): 830. http://dx.doi.org/10.3390/polym16060830.

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Thermo-responsive diblock copolymer, poly(N-isopropylacrylamide)-block-poly(N-vinylisobutyramide) was synthesized via switchable reversible addition–fragmentation chain transfer (RAFT) polymerization and its thermal transition behavior was studied. Poly(N-vinylisobutyramide) (PNVIBA), a structural isomer of poly(N-isopropylacrylamide) (PNIPAM) shows a thermo-response character but with a higher lower critical solution temperature (LCST) than PNIPAM. The chain extension of the PNVIBA block from the PNIPAM block proceeded in a controlled manner with a switchable chain transfer reagent, methyl 2-

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39

Lv, Weiyi, Yaseen El-Hebshi, Bo Li, Yuzheng Xia, Riwei Xu, and Xiaonong Chen. "Investigation of thermo-reversibility of polymer crosslinked by reversible covalent bonds through torque measurement." Polymer Testing 32, no. 2 (2013): 353–58. http://dx.doi.org/10.1016/j.polymertesting.2012.11.017.

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40

Kayalvizhi, M., E. Vakees, J. Suresh, S. Nagarajan, and A. Arun. "Spacer length controlled highly thermo reversible polyurethane-urea based on polystyrene: synthesis and crystallization studies." Polymers for Advanced Technologies 26, no. 2 (2014): 160–66. http://dx.doi.org/10.1002/pat.3441.

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41

Yang, ChangAn, Ling Chen, He Huang, et al. "Controllable fabrication of novel pH-, thermo-, and light-responsive supramolecular dendronized copolymers with dual self-assembly behavior." Polymer Chemistry 9, no. 22 (2018): 3080–87. http://dx.doi.org/10.1039/c8py00448j.

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42

Van Damme, Jonas, Otto van den Berg, Joost Brancart, et al. "Anthracene-Based Thiol–Ene Networks with Thermo-Degradable and Photo-Reversible Properties." Macromolecules 50, no. 5 (2017): 1930–38. http://dx.doi.org/10.1021/acs.macromol.6b02400.

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43

Guo, Ya-kun, Han Li, Peng-xiang Zhao, Xiao-fang Wang, Didier Astruc, and Mao-bing Shuai. "Thermo-reversible MWCNTs/epoxy polymer for use in self-healing and recyclable epoxy adhesive." Chinese Journal of Polymer Science 35, no. 6 (2017): 728–38. http://dx.doi.org/10.1007/s10118-017-1920-y.

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44

Nishimura, Shin-nosuke, Dan Sato, and Tomoyuki Koga. "Mechanically Tunable Hydrogels with Self-Healing and Shape Memory Capabilities from Thermo-Responsive Amino Acid-Derived Vinyl Polymers." Gels 9, no. 10 (2023): 829. http://dx.doi.org/10.3390/gels9100829.

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In this study, we report the fabrication and characterization of self-healing and shape-memorable hydrogels, the mechanical properties of which can be tuned via post-polymerization crosslinking. These hydrogels were constructed from a thermo-responsive poly(N-acryloyl glycinamide) (NAGAm) copolymer containing N-acryloyl serine methyl ester (NASMe) units (5 mol%) that were readily synthesized via conventional radical copolymerization. This transparent and free-standing hydrogel is produced via multiple hydrogen bonds between PNAGAm chains by simply dissolving the polymer in water at a high temp

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45

Yoshie, Naoko, Mariko Watanabe, Hitomi Araki, and Kazuki Ishida. "Thermo-responsive mending of polymers crosslinked by thermally reversible covalent bond: Polymers from bisfuranic terminated poly(ethylene adipate) and tris-maleimide." Polymer Degradation and Stability 95, no. 5 (2010): 826–29. http://dx.doi.org/10.1016/j.polymdegradstab.2010.01.032.

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46

Lukáš Petrova, Svetlana, Martina Vragović, Ewa Pavlova, et al. "Smart Poly(lactide)-b-poly(triethylene glycol methyl ether methacrylate) (PLA-b-PTEGMA) Block Copolymers: One-Pot Synthesis, Temperature Behavior, and Controlled Release of Paclitaxel." Pharmaceutics 15, no. 4 (2023): 1191. http://dx.doi.org/10.3390/pharmaceutics15041191.

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This paper introduces a new class of amphiphilic block copolymers created by combining two polymers: polylactic acid (PLA), a biocompatible and biodegradable hydrophobic polyester used for cargo encapsulation, and a hydrophilic polymer composed of oligo ethylene glycol chains (triethylene glycol methyl ether methacrylate, TEGMA), which provides stability and repellent properties with added thermo-responsiveness. The PLA-b-PTEGMA block copolymers were synthesized using ring-opening polymerization (ROP) and reversible addition–fragmentation chain transfer (RAFT) polymerization (ROP-RAFT), result

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47

Riaz, Maria, Muhammad Zaman, Huma Hameed, et al. "Lamotrigine-Loaded Poloxamer-Based Thermo-Responsive Sol–Gel: Formulation, In Vitro Assessment, Ex Vivo Permeation, and Toxicology Study." Gels 9, no. 10 (2023): 817. http://dx.doi.org/10.3390/gels9100817.

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The present study aimed to prepare, characterize, and evaluate a thermo-responsive sol–gel for intranasal delivery of lamotrigine (LTG), which was designed for sustained drug delivery to treat epilepsy. LTG sol–gel was prepared using the cold method by changing the concentrations of poloxamer 407 and poloxamer 188, which were used as thermo-reversible polymers. The optimized formulations of sol–gel were analyzed for clarity, pH, viscosity, gelation temperature, gelation time, spreadability, drug content, in vitro drug release studies, ex vivo permeation studies, and in vivo toxicological studi

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48

Nishinari, Katsuyoshi, Mineo Watase, Kaoru Kohyama, et al. "The Effect of Sucrose on the Thermo-Reversible Gel-Sol Transition in Agarose and Gelatin." Polymer Journal 24, no. 9 (1992): 871–77. http://dx.doi.org/10.1295/polymj.24.871.

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Zhang, Rongsheng. "Synthesis, characterization and reversible transport of thermo-sensitive carboxyl methyl dextran/poly (N-isopropylacrylamide) hydrogel." Polymer 46, no. 8 (2005): 2443–51. http://dx.doi.org/10.1016/j.polymer.2005.02.006.

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Huang, Guixian, Jian Zhu, Zhengbiao Zhang, Wei Zhang, Nianchen Zhou, and Xiulin Zhu. "Reversible Photo- and Thermo-Responsive Block Copolymer Micelles Functionalized by NIPAM and Azobenzene." Journal of Macromolecular Science, Part A 50, no. 2 (2013): 193–99. http://dx.doi.org/10.1080/10601325.2013.742788.

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