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Artículos de revistas sobre el tema "Chloronitrobenzene hydrogenation"

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1

Wu, Jie, Guang Yin Fan, and Wen Jun Huang. "Selective Hydrogenation of p-Chloronitrobenzene Catalyzed by FexOY@C Supported Pt-Catalyst." Advanced Materials Research 960-961 (June 2014): 221–24. http://dx.doi.org/10.4028/www.scientific.net/amr.960-961.221.

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FexOy@C nanocomposites were synthesized and used as carriers for depositing Pt nanoparticles. Catalytic properties of the nanocomposites were investigated for the hydrogenation of p-chloronitrobenzene at room temperature and balloon hydrogen pressure. The catalyst Pt/FexOy@C was extremely active for the hydrogenation of p-chloronitrobenzene. Completely conversion of p-chloronitrobenzene was achieved with a selectivity of 99.7 % in ethanol-water mixture in a reaction time of 40 min. Moreover, it can be reused four times without loss of any activity.
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2

Chen, Hu, Daiping He, Qingqing He, Ping Jiang, Gongbing Zhou, and Wensheng Fu. "Selective hydrogenation of p-chloronitrobenzene over an Fe promoted Pt/AC catalyst." RSC Advances 7, no. 46 (2017): 29143–48. http://dx.doi.org/10.1039/c7ra04700b.

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3

Wang, Ping, Shiyi Wang, Ronghe Lin, Xiaoling Mou, and Yunjie Ding. "Pre-Coking Strategy Strengthening Stability Performance of Supported Nickel Catalysts in Chloronitrobenzene Hydrogenation." Catalysts 11, no. 10 (2021): 1156. http://dx.doi.org/10.3390/catal11101156.

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Supported nickel catalysts represent a class of important catalytic materials in selective hydrogenations, but applications are frequently limited by metal agglomeration or active-site blocking induced by the presence of hydrogen halides. Herein, we report a novel pre-coking strategy, exposing the nickel nanoparticles under methane dry reforming conditions to manipulate performance in the continuous-flow hydrogenation of 1,2-dichloro-4-nitrobenzene. Compared with the pristine nickel catalyst, the nanotube-like coke-modified nickel catalyst showed weakened hydrogenating ability, but much improv
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4

Zhu, Donghong, Xin Weng, Yuqiong Tang, Jingya Sun, Shourong Zheng, and Zhaoyi Xu. "Pt/Al2O3 coated with N-doped carbon as a highly selective and stable catalyst for catalytic hydrogenation of p-chloronitrobenzene to p-chloroaniline." RSC Advances 10, no. 24 (2020): 14208–16. http://dx.doi.org/10.1039/d0ra01578d.

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5

Liu, Hongmei, Kai Tao, Chunrong Xiong, and Shenghu Zhou. "Controlled synthesis of Pd–NiO@SiO2 mesoporous core–shell nanoparticles and their enhanced catalytic performance for p-chloronitrobenzene hydrogenation with H2." Catalysis Science & Technology 5, no. 1 (2015): 405–14. http://dx.doi.org/10.1039/c4cy00996g.

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6

Pietrowski, Mariusz, Michał Zieliński, and Maria Wojciechowska. "Nanocolloidal Ru/MgF2 Catalyst for Hydrogenation of Chloronitrobenzene and Toluene." Polish Journal of Chemical Technology 16, no. 2 (2014): 63–68. http://dx.doi.org/10.2478/pjct-2014-0031.

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Abstract The use of magnesium fluoride support for ruthenium active phase allowed obtaining new catalysts of high activities in the hydrogenation of toluene and ortho-chloronitrobenzene. Ruthenium colloid catalysts (1 wt.% of Ru) were prepared by impregnation of the support with the earlier produced polyvinylpyrrolidone (PVP)-stabilized ruthenium colloids. The performances of the colloidal catalysts and those obtained by traditional impregnation were tested in the reactions of toluene hydrogenation to methylcyclohexane and selective hydrogenation of ortho-chloronitrobenzene (o-CNB) to ortho-ch
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7

Fan, Guang Yin, and Chun Zhang. "Effective Hydrogenation of p-Chloronitrobenzene over Iridium Nanoparticles Entrapped in Aluminum Oxy-Hydroxide under Mild Conditions." Advanced Materials Research 881-883 (January 2014): 267–70. http://dx.doi.org/10.4028/www.scientific.net/amr.881-883.267.

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The Ir/AlO(OH) catalyst was prepared by sol-gel method and used for selective hydrogenation of p-chloronitrobenzene (p-CNB) to p-chloroniamine (p-CAN). The mechanism of p-CNB hydrogenation over the catalyst was discussed. The hydrogen bond between the surface hydroxyl groups of the catalyst and the nitrogen present in p-CNB facilitated the hydrogenation of nitro group. On the other hand, the formation of hydrogen bond between the hydrogenation product and water promotes the rapid desorption of the hydrogenation product on the surface of the catalyst. Thus the activity and selectivity were grea
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8

Chen, Yin-Zu, and Yih-Chung Chen. "Hydrogenation of para-chloronitrobenzene over nickel borides." Applied Catalysis A: General 115, no. 1 (1994): 45–57. http://dx.doi.org/10.1016/0926-860x(94)80377-3.

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9

Wang, Xiao Zhen, Yi Feng Zhu та Xiao Nian Li. "Kinetics of ο-Chloronitrobenzene Hydrogenation on Palladium/Carbon Catalyst". Advanced Materials Research 239-242 (травень 2011): 161–67. http://dx.doi.org/10.4028/www.scientific.net/amr.239-242.161.

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A 2 wt % Pd/C catalyst has been prepared by chemical impregnation and used to catalyze the hydrogenation of o-chloronitrobenzene (o-CNB) to o-chloroaniline (o-CAN) in solvent-free conditions. The effects of reaction temperature, H2 pressure, and stirring intensity on the hydrogenation kinetics have been investigated. The hydrogenation reaction showed very high selectivity with dehalogenation side products as low as 0.3% of total yield. The favorable reaction conditions were found to be temperature T = 383 K, stirring speed = 900 rpm, and feeding ratio CNB/catalyst = 200/1 (m/m). The recycled P
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10

Dobrosielska, Marta, Michał Zieliński, Miłosz Frydrych, et al. "Sol–Gel Approach for Design of Pt/Al2O3-TiO2 System—Synthesis and Catalytic Tests." Ceramics 4, no. 4 (2021): 667–80. http://dx.doi.org/10.3390/ceramics4040047.

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Al2O3-TiO2 systems with Ti:Al 0.1, 0.5 and 1.0 molar ratio obtained by the sol–gel method have been used as a platinum support. As a precursor of alumina gel, aluminum isopropoxide has been chosen. Titanium tert-butoxylate was applied to obtain titania gel and hexachloroplatinic acid was applied as a source of platinum. The systems have been characterized by the following methods: thermogravimetric analysis (TGA), Fourier transformation infrared spectroscopy (FTIR), X-ray powder diffraction (XRPD), low-temperature nitrogen adsorption–desorption isotherms (BET, BJH), temperature-programmed redu
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11

Zhao, Bin, Chun-Jen Chou, and Yu-Wen Chen. "Hydrogenation ofp-Chloronitrobenzene on Tungsten-Modified NiCoB Catalyst." Industrial & Engineering Chemistry Research 49, no. 4 (2010): 1669–76. http://dx.doi.org/10.1021/ie901606b.

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12

Tijani, Amina, Bernard Coq, and François Figueras. "Hydrogenation ofpara-chloronitrobenzene over supported ruthenium-based catalysts." Applied Catalysis 76, no. 2 (1991): 255–66. http://dx.doi.org/10.1016/0166-9834(91)80051-w.

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13

Mo, Min, Ling Han, Jiangang Lv, et al. "Noncrystalline NiPB nanotubes for hydrogenation of p-chloronitrobenzene." Chemical Communications 46, no. 13 (2010): 2268. http://dx.doi.org/10.1039/b922256a.

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14

Chen, Yu-Wen, Natarajan Sasirekha, and Yu-Chan Liu. "Hydrogenation of p-chloronitrobenzene over NiPtB nanoalloy catalysts." Journal of Non-Crystalline Solids 355, no. 22-23 (2009): 1193–201. http://dx.doi.org/10.1016/j.jnoncrysol.2009.05.007.

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15

Wu, Mei Xia, Yong Guo, Jian Guo Zhao, and Ke Yi Tao. "Chitosan-Mediated Preparation of Porous Amorphous NiB Nanoparticles from Silver-Catalyzed Electroless Plating." Advanced Materials Research 361-363 (October 2011): 565–68. http://dx.doi.org/10.4028/www.scientific.net/amr.361-363.565.

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The chitosan-mediated synthesis of porous nanosized NiB alloy catalysts could be achieved by silver-catalysed electroless plating (EN). The unsupported and supported NiB-CS catalysts with particle size of ~25 nm were produced. The as-prepared catalysts exhibited superior catalytic activities in p-chloronitrobenzene and sulfolene hydrogenation to those of the NiB catalysts.
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16

Wei, Qian, Yu-Sheng Shi, Ke-Qiang Sun, and Bo-Qing Xu. "Pd-on-Si catalysts prepared via galvanic displacement for the selective hydrogenation of para-chloronitrobenzene." Chemical Communications 52, no. 14 (2016): 3026–29. http://dx.doi.org/10.1039/c5cc07474f.

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17

Huang, Xing, Mang Zheng, Yu Xiang Wang, Dan Dan Li, and Ya Juan Zhao. "Selective Reduction of Chloronitrobenzene to Chloroaniline on Ni/Al2O3 Catalysts Got-up Ionic Liquids." Advanced Materials Research 233-235 (May 2011): 2904–8. http://dx.doi.org/10.4028/www.scientific.net/amr.233-235.2904.

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Ionic liquids-modified Ni/Al2O3 catalysts are found to be alternatively excellent media for the heterogeneously catalyzed hydrogenation of halonitrobenzenes to corresponding haloanilines.It gives rise to higher selectivity and lower dehalogenation in the hydrogenating process compared with that observed in conventional nickel catalyst.
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18

Chen, Yu-Wen, and Der-Shing Lee. "Selective Hydrogenation of p-Chloronitrobenzene on Nanosized PdNiB Catalysts." Journal of Nanoparticles 2013 (March 18, 2013): 1–10. http://dx.doi.org/10.1155/2013/132180.

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A series of PdNiB bimetallic nanoalloy catalysts with various Pd contents was prepared. Pd was well dispersed in NiB. Even adding a small amount of Pd in NiB had a significant effect on activity and selectivity in hydrogenation of p-chloronitrobenzene (p-CNB) to p-chloroaniline (p-CAN). High activity and selectivity on PdNiB could be attributed to both ensemble effect and electronic effect. The particle size in PdNiB decreased with an increase in Pd content. Electron-enriched Ni could activate the polar-NO2 groups of p-CNB and depress the dehalogenation of p-CAN.
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19

Su, Jenn-Fang, Bin Zhao, and Yu-Wen Chen. "Hydrogenation ofp-Chloronitrobenzene on Mo-Doped NiB Cluster Catalysts." Industrial & Engineering Chemistry Research 50, no. 3 (2011): 1580–87. http://dx.doi.org/10.1021/ie1016865.

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20

Liu, Yu-Chang, and Yu-Wen Chen. "Hydrogenation ofp-Chloronitrobenzene on Lanthanum-Promoted NiB Nanometal Catalysts." Industrial & Engineering Chemistry Research 45, no. 9 (2006): 2973–80. http://dx.doi.org/10.1021/ie0509847.

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21

Wang, Wei-Jye, Jia-Huei Shen, and Yu-Wen Chen. "Hydrogenation ofp-Chloronitrobenzene on Ni-P-B Nanoalloy Catalysts." Industrial & Engineering Chemistry Research 45, no. 26 (2006): 8860–65. http://dx.doi.org/10.1021/ie0605736.

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22

Chen, Yu-Wen, and Der-Shing Lee. "Hydrogenation of p-Chloronitrobenzene on Nanosized Modified NiMoB Catalysts." Catalysis Surveys from Asia 16, no. 4 (2012): 198–209. http://dx.doi.org/10.1007/s10563-012-9144-1.

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23

Liu, Yu-Chang, Chung-Yin Huang, and Yu-Wen Chen. "Hydrogenation of p-chloronitrobenzene on Ni–B Nanometal Catalysts." Journal of Nanoparticle Research 8, no. 2 (2006): 223–34. http://dx.doi.org/10.1007/s11051-005-5944-9.

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24

Li, Feng, Wenxi Zhu, Jinrong Liang, Hua Song, Keliang Wang, and Cuiqin Li. "Carbon Nanotube-Supported Amorphous Co–B for Hydrogenation of M-chloronitrobenzene." Journal of Chemical Research 42, no. 3 (2018): 170–74. http://dx.doi.org/10.3184/174751918x15222671415597.

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A series of carbon nanotube (CNT)-supported amorphous Co–B alloy catalysts were prepared by selectively depositing Co–B particles inside and/or outside of CNTs. The effects of the nanotubular structure on the physiochemical properties of the amorphous Co–B alloys were studied. It was found that the internal loading enhanced the thermal stability of the amorphous Co–B alloys and inhibited the loss of Co compared with the external loading. The internal loading also increased the proportion of elemental Co in the Co–B alloys, while the loading method did not change the valence states of either Co
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25

Li, Xin, Yue Wang, Liqun Li, et al. "Deficient copper decorated platinum nanoparticles for selective hydrogenation of chloronitrobenzene." Journal of Materials Chemistry A 5, no. 22 (2017): 11294–300. http://dx.doi.org/10.1039/c7ta01587a.

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26

MAO, Jianzhong, Xinhuan YAN, Huizi GU, and Lingchao JIANG. "Hydrogenation of o-Chloronitrobenzene by Platinum Nanoparticles on Activated Carbon." Chinese Journal of Catalysis 30, no. 3 (2009): 182–84. http://dx.doi.org/10.1016/s1872-2067(08)60095-9.

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27

Lee, Der-Shing, and Yu-Wen Chen. "Hydrogenation of p-chloronitrobenzene on La-doped NiMoB nanocluster catalysts." Chinese Journal of Catalysis 34, no. 11 (2013): 2018–28. http://dx.doi.org/10.1016/s1872-2067(12)60687-1.

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28

Cárdenas-Lizana, Fernando, Santiago Gómez-Quero, Claudia Amorim, and Mark A. Keane. "Gas phase hydrogenation of p-chloronitrobenzene over Pd–Ni/Al2O3." Applied Catalysis A: General 473 (March 2014): 41–50. http://dx.doi.org/10.1016/j.apcata.2014.01.001.

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29

Xiong, Jun, Jixiang Chen, and Jiyan Zhang. "Liquid-phase hydrogenation of o-chloronitrobenzene over supported nickel catalysts." Catalysis Communications 8, no. 3 (2007): 345–50. http://dx.doi.org/10.1016/j.catcom.2006.06.028.

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30

Oubenali, Mustapha, Giuditta Vanucci, Bruno Machado, et al. "Hydrogenation of p-Chloronitrobenzene over Nanostructured-Carbon-Supported Ruthenium Catalysts." ChemSusChem 4, no. 7 (2011): 950–56. http://dx.doi.org/10.1002/cssc.201000335.

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31

Ge, Xianghong, Hui Liu, Xingxing Ding, et al. "Ru@Carbon Nanotube Composite Microsponge: Fabrication in Supercritical CO2 for Hydrogenation of p-Chloronitrobenzene." Nanomaterials 12, no. 3 (2022): 539. http://dx.doi.org/10.3390/nano12030539.

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Novel heterogeneous catalysts are needed to selectively anchor metal nanoparticles (NPs) into the internal space of carbon nanotubes (CNTs). Here, supercritical CO2 (SC-CO2) was used to fabricate the Ru@CNT composite microsponge via impregnation. Under SC-CO2 conditions, the highly dispersive Ru NPs, with a uniform diameter of 3 nm, were anchored exclusively into the internal space of CNTs. The CNTs are assembled into a microsponge composite. The supercritical temperature for catalyst preparation, catalytic hydrogenation temperature, and time all have a significant impact on the catalytic acti
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32

Liu, Manhong, Weiyong Yu, and Hanfan Liu. "Selective hydrogenation of o-chloronitrobenzene over polymer-stabilized ruthenium colloidal catalysts." Journal of Molecular Catalysis A: Chemical 138, no. 2-3 (1999): 295–303. http://dx.doi.org/10.1016/s1381-1169(98)00159-9.

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33

Zhang, Zhiguo, Yange Suo, Jiapin He, Guoneng Li, Guilin Hu, and Youqu Zheng. "Selective Hydrogenation of ortho-Chloronitrobenzene over Biosynthesized Ruthenium–Platinum Bimetallic Nanocatalysts." Industrial & Engineering Chemistry Research 55, no. 26 (2016): 7061–68. http://dx.doi.org/10.1021/acs.iecr.5b04977.

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34

Liu, Yu-Chang, Chung-Yin Huang, and Yu-Wen Chen. "Liquid-Phase Selective Hydrogenation ofp-Chloronitrobenzene on Ni−P−B Nanocatalysts." Industrial & Engineering Chemistry Research 45, no. 1 (2006): 62–69. http://dx.doi.org/10.1021/ie050477p.

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35

Liu, Manhong, Xinxin Mo, Yanyan Liu, et al. "Selective hydrogenation of o-chloronitrobenzene using supported platinum nanoparticles without solvent." Applied Catalysis A: General 439-440 (October 2012): 192–96. http://dx.doi.org/10.1016/j.apcata.2012.07.006.

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36

Hu, Zhun, Shunquan Tan, Rongli Mi, Xiang Li, Dan Li, and Bolun Yang. "Solvent-Controlled Reactivity of Au/CeO2 Towards Hydrogenation of p-Chloronitrobenzene." Catalysis Letters 148, no. 5 (2018): 1490–98. http://dx.doi.org/10.1007/s10562-018-2351-2.

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37

Khilnani, Veena L., and S. B. Chandalia. "Selective Hydrogenation. I.para-Chloronitrobenzene topara-Chloroaniline Platinum on Carbon As Catalyst." Organic Process Research & Development 5, no. 3 (2001): 257–62. http://dx.doi.org/10.1021/op9900380.

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38

Tsu, Ya-Ting, and Yu-Wen Chen. "Hydrogenation of p-Chloronitrobenzene on Au Nano-Clusters: Effects of Support." Journal of Nanoscience and Nanotechnology 18, no. 1 (2018): 301–8. http://dx.doi.org/10.1166/jnn.2018.14608.

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39

Pietrowski, Mariusz, and Maria Wojciechowska. "An efficient ruthenium-vanadium catalyst for selective hydrogenation of ortho-chloronitrobenzene." Catalysis Today 142, no. 3-4 (2009): 211–14. http://dx.doi.org/10.1016/j.cattod.2008.09.040.

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40

McManus, Iain J., Helen Daly, Haresh G. Manyar, S. F. Rebecca Taylor, Jillian M. Thompson, and Christopher Hardacre. "Selective hydrogenation of halogenated arenes using porous manganese oxide (OMS-2) and platinum supported OMS-2 catalysts." Faraday Discussions 188 (2016): 451–66. http://dx.doi.org/10.1039/c5fd00227c.

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Porous manganese oxide (OMS-2) and platinum supported on OMS-2 catalysts have been shown to facilitate the hydrogenation of the nitro group in chloronitrobenzene to give chloroaniline with no dehalogenation. Complete conversion was obtained within 2 h at 25 °C and, although the rate of reaction increased with increasing temperature up to 100 °C, the selectivity to chloroaniline remained at 99.0%. Use of Pd/OMS-2 or Pt/Al<sub>2</sub>O<sub>3</sub> resulted in significant dechlorination even at 25 °C and 2 bar hydrogen pressure giving a selectivity to chloroaniline of 34.5% and 77.8%, respectivel
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41

Kannapu, Hari Prasad Reddy, Young-Woong Suh, Veeralakshmi Vaddeboina, Anand Narani, David Raju Burri та Seetha Rama Rao Kamaraju. "Nano CoO-Cu-MgO catalyst for vapor phase simultaneous synthesis of ortho-chloroaniline and γ-butyrolactone from ortho-cholonitrobenzne and 1,4-butanediol". Characterization and Application of Nanomaterials 4, № 1 (2021): 1. http://dx.doi.org/10.24294/can.v4i1.523.

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The article aims at developing an efficient and stable catalysts for simultaneous hydrogenation of o-chloronitrobenzene to o-chloroaniline and 1,4-butanediol dehydrogenation to γ-butyrolactone. A series of CoO-Cu-MgO catalysts, composed of 10 wt% of copper, various amount of cobalt loadings (1, 5 and 10 wt%) and remaining of MgO were developed by co-precipitation followed by thermal treatment. o-Chloroaniline and γ-butyrolactone were the main products with high yield of 85% and 90%, respectively. The advantage of the coupling process is that the hydrogenation reaction was conducted without ext
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42

Chen, Zhijun, Yanhua Wang, Wenjiang Li, Jingyang Jiang, and Zilin Jin. "Thermoregulated phase-transfer Rh nanoparticle catalyst for selective hydrogenation of ortho-chloronitrobenzene." Chinese Journal of Catalysis 35, no. 12 (2014): 1917–20. http://dx.doi.org/10.1016/s1872-2067(14)60216-3.

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43

Yang, Xinlin, Hanfan Liu, and Hao Zhong. "Hydrogenation of o-chloronitrobenzene over polymer-stabilized palladium–platinum bimetallic colloidal clusters." Journal of Molecular Catalysis A: Chemical 147, no. 1-2 (1999): 55–62. http://dx.doi.org/10.1016/s1381-1169(99)00128-4.

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44

Chen, Yi-Ching, and Chung-Sung Tan. "Hydrogenation of p-chloronitrobenzene by Ni–B nanocatalyst in CO2-expanded methanol." Journal of Supercritical Fluids 41, no. 2 (2007): 272–78. http://dx.doi.org/10.1016/j.supflu.2006.10.009.

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45

Jaf, Zainab N., Mohammednoor Altarawneh, Hussein A. Miran, Mansour H. Almatarneh, Zhong-Tao Jiang та Bogdan Z. Dlugogorski. "Catalytic Hydrogenation of p-Chloronitrobenzene to p-Chloroaniline Mediated by γ-Mo2N". ACS Omega 3, № 10 (2018): 14380–91. http://dx.doi.org/10.1021/acsomega.8b01936.

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46

Cárdenas-Lizana, Fernando, Xiaodong Wang, Daniel Lamey, Maoshuai Li, Mark A. Keane, and Lioubov Kiwi-Minsker. "An examination of catalyst deactivation in p-chloronitrobenzene hydrogenation over supported gold." Chemical Engineering Journal 255 (November 2014): 695–704. http://dx.doi.org/10.1016/j.cej.2014.04.116.

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47

Liang, Chunhua, Jianguo Han, Kaihua Shen, Legang Wang, Defeng Zhao, and Harold S. Freeman. "Palladium nanoparticle microemulsions: Formation and use in catalytic hydrogenation of o-chloronitrobenzene." Chemical Engineering Journal 165, no. 2 (2010): 709–13. http://dx.doi.org/10.1016/j.cej.2010.10.022.

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48

Cárdenas-Lizana, Fernando, Santiago Gómez-Quero, Noémie Perret, and Mark A. Keane. "Support effects in the selective gas phase hydrogenation ofp-chloronitrobenzene over gold." Gold Bulletin 42, no. 2 (2009): 124–32. http://dx.doi.org/10.1007/bf03214922.

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49

Shen, Jia-Huei, and Yu-Wen Chen. "Catalytic properties of bimetallic NiCoB nanoalloy catalysts for hydrogenation of p-chloronitrobenzene." Journal of Molecular Catalysis A: Chemical 273, no. 1-2 (2007): 265–76. http://dx.doi.org/10.1016/j.molcata.2007.04.015.

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50

Zhang, Lianyang, Zheming Ni, Jilong Xue, Hongfei Qian, Yue Liu, and Chengan Jin. "Selective hydrogenation of p-chloronitrobenzene on nanosized gold clusters: A theoretical study." Chemical Physics Letters 703 (July 2018): 23–28. http://dx.doi.org/10.1016/j.cplett.2018.04.046.

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