Tesis sobre el tema "Double 11"
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Barry, Marie Porterfield. "Lesson 10: The Northern Renaissance and Arnolfini Double Portrait". Digital Commons @ East Tennessee State University, 2020. https://dc.etsu.edu/art-appreciation-oer/11.
Texto completoFranco, Alejandro Antonio Maschke Bernhard. "Un modèle physique multiéchelle de la dynamique électrochimique dans une pile à combustible à électrolyte polymère une approche Bond Graph dimension infinie /". Villeurbanne : Université Claude Bernard, 2005. http://tel.archives-ouvertes.fr/docs/00/11/09/68/PDF/PhDThesis_Alejandro_A_FRANCO.pdf.
Texto completoPant, Lok Raj. "The Radiative Lifetime Measurement on 61Σ+g (v = 9, 10, 11, J = 31) Excited States of Molecular Sodium Using Time Resolved High Resolution Doubled Resonance Spectroscopy". Miami University / OhioLINK, 2021. http://rave.ohiolink.edu/etdc/view?acc_num=miami1626966676896514.
Texto completoLima, Fábio Francisco de. "Gestão de risco em propriedades com sistemas de produção de algodão, soja e milho em Mato Grosso, Brasil". Universidade de São Paulo, 2018. http://www.teses.usp.br/teses/disponiveis/11/11153/tde-21012019-135242/.
Texto completoWith the few cultivation options, the cotton-grower in Mato Grosso concentrates its production model on cotton, soybeans and corn, which has contributed to the state being the largest national producer of these three crops. In the last harvests, cotton production migrated to the double harvest model, dividing space with corn and placing soybeans as the main option of summer cultivation. In addition, in the last five harvests, cotton seed technologies changes were intense, further shifting the production systems. Due to the recent changes, doubts still rest on the financial-economic efficiency and the risk assumed with the new production model. Based on this lacuna in the research, the objective of this study was to describe how cotton properties were configured between the 2012/13 and the 2015/16 harvests, to subsidize the measurement of the risk of cotton, soybean and corn crops and their respective systems. At the end, the study develops a model that optimizes the income and risk of the crop combination (crop cotton, soybean, 2nd cotton crop and second corn harvest), to assist the rural property management. To study all the productive systems, two regions were delimited: North Aggregate and Eastern Center. The first comprises the production of soybeans in the summer and cotton and corn in the second crop, while the second is restricted to the cotton and soybeans cultivation in the summer and corn succeeded by the oilseed. For the analysis of the crops and production systems risk, the Monte Carlo method was used, involving random elements simulation. To build an efficient frontier of possible combinations of crops in the property, analyzing the return-risk relationship, the genetic algorithm was the basis for the simulation optimization model. The results point to the soybeans production being the one with the lowest risk, while systems with second harvests are more risky. However, the introduction of cotton in succession to soybeans brought significant net revenue gains to the system, while the second corn crop little increased the income or else reduced in response to the large increase in production risk. The Eastern Center proved to be less risky for cotton and grain production, especially in terms of productivity. In the portfolio theory, model data show that soybean cultivation in the entire summer area results in higher profitability gains, while revenue maximization occurs with cotton area increase in the summer crop, but exposes the farm to the highest production risk. The introduction of area in the second harvest helps to mitigate property risks. Thus, the crops diversification in the property proved to be the best route for risk management, as the use of the greatest number of crops resulted in the best relation between return and risk.
Lombardi, Simone Pacheco. "Estudo funcional de um locus de regeneração (Rg1) vindo de Solanum peruvianum, uma espécie selvagem relacionada ao tomateiro". Universidade de São Paulo, 2008. http://www.teses.usp.br/teses/disponiveis/11/11144/tde-22072008-161223/.
Texto completoThe In vitro regeneration process is widely used in plant biotechnology. However, the mechanisms involved in the acquisition of competence for organ formation are hitherto unknown. In tomato (S. lycopersicum), the high capacity for in vitro regeneration is attributed to the Rg1 allele from S. peruvianum, which is present in the cv MsK (S. lycopersicum x S. peruvianum). The dwarfism genes of the cv Micro-Tom (MT) were transferred to MsK, and, after 8 generations of selfing (F8), the cv Micro-Msk was obtained. Here, after 6 generations of backcrosses (BC6Fn), we created the MT-Rg1, which has Rg1 isogenic to MT. Tests of in vitro regeneration showed that shoot formation in MT-Rg1 and Micro-MsK are equivalent, suggesting that the high capacity of regeneration of Micro-MsK is basically due to Rg1. Comparing MT-Rg1 with the control MT, we noticed a high frequency of 3 cotyledon formation, increased shoot branching and late senescence, which are absent in the parentals. These pleiotropic effects of Rg1 coincide with those described for plants with alterations in the hormone cytokinin. Tests of sensitivity for cytokinin and senescence behavior carried out by us, as well as dosage of that hormone made by other researches, discarded that hypothesis. Reciprocal grafting showed that the promotion of shoot branching by Rg1 is not a transmissible signal, but seems to be an inherent characteristic of the tissue. Rg1 also increases adventitious roots formation of ex vitro cuttings, suggesting that it affects the process of competence, which is common for shoots and roots, instead of the specific induction of shoots. Double mutants between Rg1 and mutants with alteration in the sensitivity/metabolism of plant hormones (dgt, brt and pro), as well as mutants with absence of shoot branching (ls) and accelerated senescence (l) were obtained and tested for the capacity of in vitro regeneration. The presence of Rg1 suppressed the phenotype of less dissected leaves of the mutant hypersensitive to gibberrellin (pro) and rescued the phenotype of poor developed root system of the mutant with low auxin sensitivity (dgt). Rg1 was also able to revert the absence of axillary shoot formation in ls, whereas the mutant Me, which represents an over expression of a KNOX gene was not. This result suggests that Rg1 is not a KNOX gene, although those genes are considered the main controllers of the competence. Analyzing different types of explants in independent experiments, it was verified that, in general, the mutations brt (low sensibility to cytokinin), dgt and ls decreased the regeneration capacity of Rg1, while l increased it. Rg1 was particularly epistatic to the pro mutation, reverting the phenotype of little shoot formation of that mutant. Surprisingly, Rg1 proved to be more sensitive to auxin in the hypocotyl segment elongation test, being able to revert the phenotype of the mutant dgt in the same test. Together, these results confirm the role of the Rg1 in the process of acquisition of the competence and suggest an interaction of the hormones gibberellin and auxin in this process.
Marouf, Louisa. "Introduction aux rythmes scolaires, évaluation chronopsychologiques des modalités organisationnelles du temps scolaire à l'école algérienne : étude comparative entre la double et la simple vacation chez les enfants âgés de 11-12 ans". Thesis, Tours, 2012. http://www.theses.fr/2012TOUR2020.
Texto completoThe purpose of this study is to make a chrono-psychological assessment of the type of time organization applied in Algerian schools. Comparison was made between the single and double vacation types of school timing organization based on a sample of pupils aged between 11 and 12 years. The results of the study highlight the physiological and psychological impact of the two types of school vacation on Algerian pupils. Furthermore the daily and weekly attention levels of pupils in the double vacation type of organization indicate that this type of time organization is well suited for Algerian pupils who seem well adapted to their school timing. With regard to the behavior of the two children observed during the study it was found that those in the double vacation type were better adapted to daily school life compared to their peers in the single type of vacation. However during the week it is the pupils in the single vacation type who showed a better level of adaptation. The results also indicate that regardless of the type of time organization and the time of school entrance the subjects showed no troubles with regard to time of sleeping or awaking: Pupils from the two types of time organization slept more than the average time indicated by chrono-psychological research. However it was also shown that the brake taken tuesday afternoon by pupils from the double vacation type - unlike their peers in the single vacation type- had no positive effects, but the brake taken in the weekend by all pupils regardless of the type of vacation was useful for since it enabled them to take a rest and overcome their fatigue. With regard to extra- curricular school activities they clearly appear to be the same for all pupils
Tomaz, Halan Vieira de Queiroz. "Sistema de preparo profundo do solo e sua influência no desenvolvimento da cana-de-açúcar". Universidade de São Paulo, 2014. http://www.teses.usp.br/teses/disponiveis/11/11136/tde-05022014-093232/.
Texto completoSugarcane is one of the most important crops in the Brazilian agribusiness chain, besides its great branch in the international context as a renewable and sustainable energy source. Through the competitiveness that sugar mills experience and through the growth perspectives of the sector, this study focuses the deep soil preparation for sugarcane crop renewal, since it provides a larger soil volume to be explored by the root system. Furthermore, the machinery traffic controlled by a smaller number of soil preparation operations, reduces farmer´s production costs. The general objective was, therefore, evaluate soil preparation methods and develop a controlled traffic system in the area, in order to propose to the farmer a cost reduction in the farm soil management along with yield increase and extension of the longevity of the crop. As a result of the imposed treatments it was possible to conclude that by the root length analysis in all depths of the Deep Soil Preparation, root length, area and volume were greater. Soil resistance to penetration in the Deep Soil Preparation system was much less in relation to the other treatments, assuming values of 0.29 MPa and 0.45 Mpa in the 20-40 and 40-60 cm layers, respectively. The above ground evaluations showed leaf area index of 7.1 for the Deep Soil Preparation, much higher in relation to the other treatments. Operation costs at planting time were much less for the Deep Soil Preparation, 33% and 58% smaller than for the Double Minimum Tillage and Double conventional, respectively. Soil movement caused by Deep Preparation was up to 80% less in relation to the Double conventional. The controlled machinery traffic that the Deep Soil Preparation provides, reduced up to 70% the farming operations, therefore presenting a lower fuel consumption, a reduction of the time used in farming operations, reduction of the machinery park, and a lower operational cost.
Gusson, Eduardo. "Avaliação de métodos para a quantificação de biomassa e carbono em florestas nativas e restauradas da Mata Atlântica". Universidade de São Paulo, 2013. http://www.teses.usp.br/teses/disponiveis/11/11150/tde-13022014-084600/.
Texto completoThe biomass and carbon quantification requires the application of appropriate methods to obtain reliable estimates of their stocks in natural and planted forests. The aim of this study was to evaluate different applicable methods to estimate biomass in both, natural and restored Atlantic Forests. The first chapter discusses the use of the vegetation index (NDVI) as an auxiliary tool in the inventory of biomass stocks in forest restoration areas. Different sampling methods were compared in terms of its accuracy and conservativeness. The results shown an adequate correlation between the vegetation index and the measured biomass, making the NDVI applicable either as supporting decision tool to define strata in the stratified sampling or as a predictor in the double sampling procedure. The last method allowed to the minimization of the uncertainties related to the biomass estimation combined to the reduction of sampling efforts. It makes the approach very interesting, especially in the context of large-scale surveys. The second chapter discusses the methodological approach used to evaluate the quality of predictive models applied to biomass studies in natural forests. For this, six models were fitted from 80 sample trees, using different combinations of predictor variables, such as, total height and information of wood density. The predictive equations generated by the models were evaluated according to their quality of fit and prediction performance. In order to evaluate its prediction performance, the equations were applied to the dataset of another 146 sample trees measured in nine destructive sample plots. The plots were located in different forest successional stages allowing the evaluation of model predictive bias among the stages. A third step of the analysis was the application of literature equations to a dataset of a forest inventory conducted in the study area, in order to verify the discrepancies in the estimates due to the use of these different models. The study confirms the empirical nature of the biomass equations and the need of previous evaluation in terms of prediction performance. This conclusion is even more relevant when we consider the equations that were obtained from other forests types, exposing some of the key factors associated to the causes of uncertainty in the biomass estimation applied to natural forests.
Zhang, Jing. "An integrative model to predict scholastic performance". Doctoral thesis, Humboldt-Universität zu Berlin, Mathematisch-Naturwissenschaftliche Fakultät, 2016. http://dx.doi.org/10.18452/17558.
Texto completoThis dissertation deals with the prediction of scholastic performance in Chinese culture. The thesis uses the constructs of fluid intelligence (Gf), broad personality traits (Big Five), narrow personality traits (i.e., self-beliefs and learning approaches), and their complex interplay as predictors of scholastic performance. Following a general introduction summarizing the theoretical foundations as well as outlining the derivation of the Big Five Narrow Trait (B5NT) Model, three papers are presented. In the context of Chinese secondary school students, Paper 1 examined the predictive power of figural reasoning as an indicator of Gf and personality traits on school grades in three subjects (i.e., Mathematics, Chinese, and English), and further investigated their potential interactions. Paper 2 integrated the findings of Paper 1 with the aforementioned B5NT. Within the study, the B5NT is empirically tested and compared to an alternative model proposed in earlier work, the Double Mediation model [DM]. Self-beliefs and learning approaches were considered as relevant mediators within those analyses. In this cross-sectional study, the B5NT model was strongly supported, whereas the DM model did not find strong empirical support. In order to empirically verify the underlying processes from a longitudinal perspective, Paper 3 expanded on the B5NT related findings in a three-wave longitudinal panel design. The findings supported the B5NT model and further warranted a revision model in which reciprocal effects from performance to big traits are suggested. Thus, the presented thesis provides a theoretical model explaining the influence of the Big Five on scholastic performance. Moreover, empirical support for the proposed model from cross-sectional and longitudinal data was found. Finally, integrating interactions with cognitive ability rounds off the perspective.
Modzelewski, Kenneth Paul. "DC parameter extraction technique for independent double gate MOSFETs a thesis presented to the faculty of the Graduate School, Tennessee Technological University /". Click to access online, 2009. http://proquest.umi.com/pqdweb?index=11&did=1759989211&SrchMode=1&sid=1&Fmt=6&VInst=PROD&VType=PQD&RQT=309&VName=PQD&TS=1250600320&clientId=28564.
Texto completoPaya, Christophe. "Analyse narrative du "discours missionnaire" dans l'Évangile de Matthieu (Mt 9. 35-11. 1)". Montpellier 3, 2008. http://www.theses.fr/2008MON30050.
Texto completoThe rise of narrative criticism raises the question of the place and function of Jesus’ discourses in the Gospel of Matthew. If the recent readings have sometimes had the effect of minimizing their importance for the benefit of the plot, it is difficult to avoid noting that they contribute significantly to the elaboration of a portrait of Jesus and the disciples’ community. Paradoxically, it’s also from the side of narrative criticism that a renewed reading of these texts could intervene nowadays. The argument is the following : the mission discourse (Mt. 9. 35-11. 1) is devised to play a formative role for the readers’ community. This community, through the collective character of the Twelve, is drawn into a non-geographic movement. After having studied preliminary points such as the place and function of the discourses in the plan of the first Gospel (chap. I) and having analysed the situation in the field of research (chap. II), we shall study, by means of narrative criticism, the figure of the disciples as it is painted at the beginning of the discourse (chap. III). Three themes of the tenth chapter will be chosen and analysed in their narrative context : household/family, universality and violence (chap. IV). They will constitute the background for the exegesis of the discourse which will be read in the perspective of the study of the engendered movement (chap. V). The synthesis and the conclusion will show that the movement bears on the Christological perspective, on the soteriological perspective and on the connection with the time of the mission (chap. VI)
Dherbecourt, Jean-Baptiste. "Processus non linéaires pour la génération d'impulsions picosecondes accordables dans l'infrarouge moyen". Phd thesis, Palaiseau, Ecole polytechnique, 2011. http://pastel.archives-ouvertes.fr/docs/00/59/92/11/PDF/JBthese.pdf.
Texto completoMany applications, like time-resolved spectroscopy, require the development of new coherent light sources emitting tunable short pulses in the mid-infrared. In this field, nonlinear optics offer particularly attractive solutions. First of all, the parametric generation process allows extension of the spectral coverage of conventionnal laser sources. Secondly, nonlinear processes display specific properties, which can be controlled in order to create original fast optical functions. In this work, we use these properties to realize picosecond pulses generation devices. We begin with the realization of a synchronously pumped OPO based on a ZGP crystal, emitting tunable picosecond pulses in the 3,8 µm- 5,6 µm spectral range. The performances of the different conversion stages are discussed from experimental and numerical considerations. Then we adress optical sources including a laser medium and a nonlinear crystal. We build a nonlinear mirror using a PPLN crystal and insert it in a Cr2+:ZnSe laser to produce tunable picosecond pulses by passive modelocking in the 2,45 µm - 2,55 µm range. The nonlinear mirror is designed and characterized in an extracavity experiment, then we detail the mode-locking experiment. Finally, we generalize the nonlinear mirror concept, by proposing means of getting passive mode-locking by combination of amplitude and phase modulation in the laser cavity
Landoulsi, Jessem. "Influence des réactions enzymatiques sur le comportement électrochimique de l'acier inoxydable EN X2CrNiMo17-11-2 (AISI 316L) en biocorrosion : rôle des processus interfaciaux sur la modification du film passif". Compiègne, 2008. http://www.theses.fr/2008COMP1729.
Texto completoThe outstanding corrosion behavior of stainless steels (SS) results from the presence of thin oxide layer (some nanometers). Ln non sterile aqueous media, stainless steels may exhibit a non stable behavior resulting from interactions between microbial species and passive film. Ln fact, microorganisms can be deeply involved in the corrosion processes usually reported as Microbial Influenced Corrosion (MIC). They can induce the initiation or the acceleration of this phenomenon and they do so when organized in biofilms. From the electrochemical point of view, stainless steels showed an increase of the free corrosion potential (Ecorr) attributed to the biofilm settlement. The Eco" ennoblement was broadly reported in seawaters and seems to be confirmed in fresh water according to recent findings. A considerable progress in the comprehension of MIC processes was related to the role of extracellular species, essentially enzymes. Many enzymatic reactions occurring in biofilms consist on using oxygen as electron acceptor to generate hydrogen peroxide and related species. The aim of this work is to understand the mechanisms involved in the electrochemical behavior of stainless steel according to an enzymatic approach in medium simulating fresh water. To this end, glucose oxidase was chosen to globalize aerobic activities of biofilms. Electrochemical measurements in situ and surface analysis allow the comprehension of the role and the nature of interfacial processes. Surface characterization was performed with the help of a new quantitative utilization of XPS analysis and AFM. Results show a significant evolution in term of (I) morphology (surface organization), (II) chemical composition (passive layer, adsorbed organic species) and (III) chemical reaction (oxidation, dissolution, effect of enzyme). Finally, a new enzymatic system is proposed to mimic specific physicochemical conditions at the SS / biofilm interface, in particular enzymatic generation of oxidant species in diffusion limiting conditions
Watt, Diane P. "Juxtaposing Sonare and Videre Midst Curricular Spaces: Negotiating Muslim, Female Identities in the Discursive Spaces of Schooling and Visual Media Cultures". Thèse, Université d'Ottawa / University of Ottawa, 2011. http://hdl.handle.net/10393/19973.
Texto completoChin, Jia-hung y 秦嘉宏. "Research on Shopping Carnival: Based on Double 11 and Black Friday". Thesis, 2018. http://ndltd.ncl.edu.tw/handle/4hyqee.
Texto completo國立中山大學
國際經營管理碩士學程
106
As consumers begin to lose interest in daily sales and discounts, many companies are looking for new methods to drive new consumption in term of motivating the collective consumption behavior, such as Alibaba’s Double 11 in China (also known as Singles’ Day on November 11 or Chinese National Ecommerce Day) and Black Friday in United States. These two shopping events are according to the phenomenon in Bakhtin’s carnival theory which allows consumers to be liberated from the shopping events and carnival spirits. These carnival spirits combine with shopping events is not only happen in China, but also, in the other side of the world, in the United States. Brick-and-mortars celebrate the Black Friday after Thanksgiving holiday, the entire USA falls into a crazy, passion, and high-pitched shopping mood. After several years, Alibaba’s “Cat’s head” (a mascot of Tmall) become the symbolic of Double 11, and walk around in the shopping malls has been parts of ritual after the Thanksgiving holiday in the United States. The paper analyzed two studies on Double 11 and Black Friday, and mapped out those similarities. The author concluded these two events have successfully implemented five critical periods which associated with preheat stage, awaken stage, specific stage, high-pitched stage, and rational stage. Along with these five periods, companies who rely on the carnival spirits to hold the event can reference this study as applications.
HUNG, MIN-SHAN y 洪敏珊. "Exploring Factors Influencing Consumers’ Participation in Online Shopping Days: Using Double 11 Day as an Example". Thesis, 2019. http://ndltd.ncl.edu.tw/handle/jq8xq3.
Texto completo國立臺北大學
企業管理學系
107
Purpose - There are more and more people decide to attend online shopping days. However, little research has been done to understand why consumers want to attend online shopping days. Therefore, the purpose of this study is to find the values which consumers want to achieve and how those values influence participators’ group norms, attitudes, positive and negative emotion, subjective norm, social identify, desires, we-intentions and participation behavior. The research findings can help marketers devise strategies attracting consumers to participate in online shopping days. Design/methodology/approach – The research method is developed based on the means-end chain and the model of goal-directed behavior (MGB). First, we use interviews with laddering method to find the chains of “attributes-consequences-values” from consumer and conclude the values that drive consumers to attend online shopping days. After that, in order to test our research model, we conduct two online survey to collect questionnaires in Taiwan and mainland China. Findings – This study discovers the values, containing “Fun and Enjoyment of Life” “A Sense of Accomplishment,” “A Sense of Belonging,” “Self-Respect,” and “Excitement,” which consumers want to achieve from attending online shopping days. Furthermore, we find that group norms, positive anticipated emotions and social identity can positive drive participants’ desires, we-intentions and the participation behavior during online shopping day. We also find that the control variables, containing past behavior and perceived behavioral control, partly positive influence desires, we-intentions, shopping behavior and socializing behavior. Research limitation and implications – The participants of this study are mainly from Taiwan and this study uses Double 11 Day as the study case, the findings could not be generalized to another country or shopping day. Therefore, in the future, researchers can summarize the participation motivation between different online shopping days
"THE DOUBLE BED: SEX, HETEROSEXUAL MARRIAGE AND THE BODY IN POSTWAR ENGLISH CANADA, 1946-1966". Thesis, 2013. http://hdl.handle.net/10388/ETD-2013-11-1303.
Texto completo(8850251), Ghaleb Alomaish. "“DOUBLE REFRACTION”: IMAGE PROJECTION AND PERCEPTION IN SAUDI-AMERICAN CONTEXTS: A COMPARATIVE STUDY". Thesis, 2020.
Buscar texto completoThis dissertation aims to create a scholarly space where a seventy-five-year-old “special relationship” (1945-2020) between the Kingdom of Saudi Arabia and the United States is examined from an interdisciplinary comparativist perspective. I posit that a comparative study of Saudi and American fiction goes beyond the limitedness of global geopolitics and proves to uncover some new literary, sociocultural, and historical dimensions of this long history, while shedding some light on others. Saudi writers creatively challenge the inherently static and monolithic image of Saudi Arabia, its culture and people in the West. They also simultaneously unsettle the notion of homogeneity and enable us to gain new insight into self-perception within the local Saudi context by offering a wide scope of genuine engagements with distinctive themes ranging from spatiality, identity, ethnicity, and gender to slavery, religiosity and (post)modernity. On the other side, American authors still show some signs of ambivalence towards the depiction of the Saudi (Muslim/Arab) Other, but they nonetheless also demonstrate serious effort to emancipate their representations from the confining legacy of (neo)Orientalist discourse and oil politics by tackling the concepts of race, alterity, hegemony, radicalism, nomadism and (un)belonging.
Tzeng, Chin-Yu y 曾瑾瑜. "Synthesis of Arenes-Fused Tetracyclo[6. 2. 2. 13, 6. 02, 7]trideca-4, 9, 11-trienes and Tetracyclo[6. 2. 2. 23, 6. 02, 7]tetradeca-4, 9, 11, 13-tetraenes, contaning parallel carbon-carbon double bonds". Thesis, 2006. http://ndltd.ncl.edu.tw/handle/29973822118217254567.
Texto completo東海大學
化學系
94
The Diels-Alder reaction of conjugated cyclohexadiene analog 39 with 1, 4-anthraquinone produced stereoselectively cycloadduct 54, which was then converted to 55 by oxidation-photocyclization steps. Similary, Diels-Alder reaction of 39 with 1, 4-naphthoquinone gave 57 as the only product, which was then oxidized to naphthoquinone 59 during the work-up steps of enolization. Methylation of cycloadduct 57 with dimethyl sulfate followed by dechlorination and Birch reduction yielded 61. Hydrolysis of acetal 61 with 3M perchloric acid gave compound 62. Condensation of 62 with malononitrile gave 63 which was then subjected to oxidation by DDQ to afford 64. Diels-Alder reaction of exocyclic 1, 3-butadiene 32 with 1, 4-naphthoquinone produced cycloadduct 65. Reduction of the carbonyl group in 65 by sodium borohydride gave diol 66. Dehydration of the resulting diol 66 was carried out in a mixture of phosphorous oxychloride and pyridine to furnish 67. Finally, aromatization of 67 with DDQ afforded 68 in 62% yield.